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Dissertations / Theses on the topic '1]octane'

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Published: 4 June 2021

Last updated: 3 February 2022

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1

Hazm, Jamal Eddine. "Silicates et aluminosilicates microporeux obtenus en milieu fluoré avec, comme structurants, le 1,4-diazabicyclo [2,2,2] octane (DABCO) ou le 1-azabicyclo [2,2,2] octane (quinuclidine)." Mulhouse, 1992. http://www.theses.fr/1992MULH0238.

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Ce travail s'inscrit dans le cadre de l'exploration d'une nouvelle voie de synthèse hydrothermale des zéolithes. L'ion mobilisateur hydroxyde habituellement utilisé est ici remplacé par l'ion fluorure, avec pour corollaire l'emploi de milieux de synthèse de pH typiquement compris entre environ 7 et 10. L'utilisation de 2 structurants organiques différents, le 1,4-diazabicyclo [2,2,2] octane (« DABCO » ou le 1-azabicyclo [2,2,2] octane (« quinuclidine ») - combiné à des rapports molaires Si/Al variables - a permis respectivement la préparation des zéolithes bêta et de type MTW d'une part, ainsi

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2

Boulebnane, Hassane. "Etude conformationnelle et structurale des molécules hétéro-1 spiro (2,5) octane par spectroscopie microonde." Grenoble 2 : ANRT, 1988. http://catalogue.bnf.fr/ark:/12148/cb37612079b.

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3

Boulebnane, Hassane. "Étude conformationnelle et structurale des molécules hétéro-1 spiro (2. 5) octane par spectroscopie micro-onde." Nancy 1, 1988. http://www.theses.fr/1988NAN10091.

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L'étude des spectres de rotation de cinq isomères entre 12 et 26 GHZ permet la détermination des constantes de rotation dans l'approximation du rotateur rigide. La valeur du défaut d'inertie permet d'estimer la géométrie probable de chaque isomère et d'observer une déformation du cycle héxanique qui se manifeste surtout par un aplatissement

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4

Masri, Fadi. "Synthèse de dérivés fonctionnalisés du 8-méthyl-8-azabicyclo[3. 2. 1]octane : vers de nouveaux marqueurs technétiés des transporteurs des monoamines." Université Joseph Fourier (Grenoble), 2003. http://www.theses.fr/2003GRE10029.

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5

Couturier, Cédric. "Etudes vers la synthèse totale de la (-)-lémonomycine. Synthèse d'acides beta-aminés fonctionnalisés par ouverture nucléophile d'aziridiniums dérivés de la sérine." Phd thesis, Palaiseau, Ecole polytechnique, 2005. http://www.theses.fr/2005EPXX0029.

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6

Mehmandoust, Maryam. "Synthèse de dihydro-1, 2 pyridines et d'équivalents de sels de dihydro-2, 5 pyridinium à partir d'amines primaires chirales : application à la synthèse énantiosélective de dérivés d'isoquinuclidines et de pipéridines 2-substituées." Paris 11, 1989. http://www.theses.fr/1989PA112254.

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Une méthode générale de synthèse des sels de pyridinium N-substitués par différents auxiliaires chiraux, une application de la réaction de Zincke, à partir des amines primaires chirales correspondantes, est décrite. Par réduction au borohydrure de sodium en milieu alcalin, ces sels de pyridinium conduisent aux dihydro-1,2 pyridines correspondantes dont les réactions de cycloaddition avec l'acrylate de méthyle ont été étudiées. Des composés azabicyclo[2. 2. 2]octane (isoquinuclidines), dont la configuration absolue a été établie, sont obtenus avec des e. D. De 20 à 33% et une bonne pureté optiq

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7

Rowen, Catherine Carmel, and n/a. "A New Approach Towards Bicyclo[4.2.0]octan-1-ols: Synthetic and Mechanistic Studies." Griffith University. School of Science, 2003. http://www4.gu.edu.au:8080/adt-root/public/adt-QGU20030602.131636.

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The reaction between the lithium enolate of cyclohexanone and phenyl vinyl sulfoxide resulted in the formation of the novel bicyclooctanol sulfoxides 215-217 and the monoalkylated sulfoxide 218. The effects of variation in reaction time, temperature and concentration were studied. Under optimal conditions (10 minutes, -10°C and 0.085 M) the ratio of the bicyclooctanol sulfoxides 215-217 (75% yield) to the monoalkylated sulfoxide 218 was 95:5. The bicyclooctanol sulfoxides 215-217 were characterised as the sulfone derivatives, bicyclooctanol sulfones 219 and 220. X-ray crystal structures we

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8

TABAI, SAID Rogalski Marek. "PROPRIETES THERMODYNAMIQUES DES CHLOROPHENOLS EN SOLUTIONS AQUEUSES ET 1-OCTANOL /." [S.l.] : [s.n.], 1997. ftp://ftp.scd.univ-metz.fr/pub/Theses/1997/Taibai.Saild.SMZ9730.pdf.

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9

Cordeiro, Guaraci Duran. "Fenologia reprodutiva, polinização e voláteis florais do cambuci (Campomanesia phaea - Myrtaceae)." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/59/59131/tde-20042015-222512/.

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A família Myrtaceae tem muitas espécies frutíferas, algumas são utilizadas comercialmente, entre elas o cambuci (Campomanesia phaea). Os objetivos deste trabalho foram descrever a fenologia reprodutiva, a biologia floral, o sistema reprodutivo e identificar os polinizadores do cambuci para gerar novos conhecimentos que possam contribuir com a produtividade desta espécie. O estudo de fenologia reprodutiva foi conduzido por dois anos, em área de ocorrência natural e área de cultivo comercial. As fenofases (floração e frutificação) foram monitoradas com duas métricas: Índice de atividade (sincron

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10

Bastien, Guillaume. "Synthèse, structure et dynamique de rotors moléculaires cristallins." Phd thesis, Université d'Angers, 2013. http://tel.archives-ouvertes.fr/tel-01064323.

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Dans le contexte du développement des machines moléculaires, l'objet de ce travail est la synthèse de solides cristallins amphidynamiques basés sur des rotors 1,4-diéthynylbicyclo[2.2.2]octane (BCO) fonctionnels, auto-assemblés ou organisés par coordination à un métal. Ces rotors chiraux possèdent deux degrés de liberté caractérisés à l'état solide de deux manières indépendantes. Des expériences de relaxation spin-réseau du proton en fonction de la température pour étudier le mouvement de rotation du rotor hélicoïdal sur son axe ont été réalisées. De plus, des expériences d'optique non-linéair

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11

Arenas, Leliz Ticona. "Síntese, caracterização e propriedades do polímero cloreto de 3-n-propil-1-azônia-4-azabiciclo[2.2.2]octano silsesquioxano." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2003. http://hdl.handle.net/10183/3451.

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Neste trabalho encontra-se descrita a síntese do polímero híbrido organo inorgânico, cloreto de 3-n-propil-1-azônia-4-azabiciclo [2.2.2] octano silsesquioxano (dabcosilsesquioxano), através do método sol-gel. O polímero foi obtido por reação entre o precursor orgânico cloreto de 3-n-propiltrimetoxisilano-1-azônia-4-azabiciclo[2.2.2]octano (dabcosil), obtido em nosso laboratório, e o precursor inorgânico tetraetilortosilicato (TEOS) usando relações molares TEOS/dabcosil de 0 até 49, em meio ácido (pH entre 3 e 4). A caracterização destes materiais, realizada por espectroscopia no infravermelho

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12

Mandelt, Klaus. "Synthese und Umlagerung von Bicyclobutyl-1-Olen und Spiro[3.4]Octan-5-Olen ein neuer Zugang zu (±)-endo-Capnellen /." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=961823461.

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13

Tabai, Saïd. "Contribution à la détermination des propriétés thermodynamiques des chlorophénols dans l'eau et dans le 1-octanol." Metz, 1997. http://docnum.univ-lorraine.fr/public/UPV-M/Theses/1997/Taibai.Saild.SMZ9730.pdf.

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Ce travail a pour but d'étudier les propriétés thermodynamiques des chlorophénols en solutions aqueuses et 1-octanol. Nous avons réalisé pour cela des mesures d'équilibres liquide-vapeur au moyen d'un ébulliomètre de type Swietoslawski, des mesures d'enthalpie d'excès grâce à un calorimètre de mélange C80 de SETARAM et des mesures de masses volumiques avec un densimètre vibrationnel Anton Paar. Ces études expérimentales ont été utilisées afin de déterminer les coefficients d'activités, des enthalpies molaires d'excès partielles et les volumes molaires partiels à dilution infinie, des phénols e

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14

Guilera, Sala Jordi. "Ethyl octyl ether synthesis from 1-octanol and ethanol or diethyl carbonate on acidic ion-exchange resins." Doctoral thesis, Universitat de Barcelona, 2013. http://hdl.handle.net/10803/120755.

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Ethyl octyl ether is a bioethanol-derived component that has excellent properties as diesel fuel. This work proved that ethyl octyl ether can be produced successfully in liquid-phase at the temperature range of 130-190ºC by using acidic ion-exchange resins, as suitable and economic catalysts. The use of two promising reactants that can be a renewable compound source, ethanol and diethyl carbonate, have been explored. Both reactants are able to ethylate 1-octanol and form the desired product. However, an identical industrial drawback is observed on both reactants, the loss of ethyl groups to fo

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15

Pina, Carla Garcia. "Estudo experimental e calculo pelo moedlo ERAS do volume em excesso de soluções de 1-heptanol/acetonitrila e 1-octanol/acetonitrila a 293,15K, 298,15K e 313,15K." [s.n.], 1995. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266357.

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Orientador: Artur Zaghini Francesconi<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Quimica<br>Made available in DSpace on 2018-07-20T14:08:07Z (GMT). No. of bitstreams: 1 Pina_CarlaGarcia_M.pdf: 2107786 bytes, checksum: 3a4caaf62273f3f6160b642d2c90388c (MD5) Previous issue date: 1995<br>Resumo: Este trabalho teve como objetivo a determinação experimental de dados de volume em excesso de soluções de l-alcanol/nitrila, e teste do modelo ERAS para este sistema. o volume em excesso foi determinado a partir de dados experimentais de densidade para soluçõe

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16

Leite, Daniel Fujimura. "Estudo teórico/experimental comparativo do catalisador brometo de 1-propil-4-azo-1-azôniobiciclo[2,2,2]octano (P-DABCO) para a ciclo-adição catalítica de CO2 aos epóxidos para a formação de ciclocarbonatos orgânicos." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/75/75134/tde-21092015-082950/.

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Com o aumento da consciência global sobre os riscos do Aquecimento do Planeta e de suas possíveis causas ficou claro que é necessário desenvolver ou adaptar processos industriais de maneira a aproveitar dejetos como o CO2. Dentre as formas de se aproveitar o CO2, destaca-se a ciclo-adição aos epóxidos, com a formação de ciclocarbonatos. A reação é tecnologicamente interessante, pois ciclocarbonatos possuem diversas aplicações como solventes polares apróticos, eletrólitos e matéria prima para compostos como purinas, carbamatos, glicóis, policarbonato e outros. Para que a reação ocorra em tempo

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17

D'Agostini, Luciane. "Estudo experimental e modelagem da entalpia em excesso de soluções liquidas binarias contendo 1-heptanol/acetonitrila e 1-octanol/acetonitrila a 298.15, 313,15, 323,15 K e pressão atmosterica." [s.n.], 2003. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266445.

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Orientador: Artur Zaghini Francesconi<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Quimica<br>Made available in DSpace on 2018-08-03T15:26:23Z (GMT). No. of bitstreams: 1 D'Agostini_Luciane_M.pdf: 2532270 bytes, checksum: 92d956cfa61fda6e6a4ccc4e62ab36d1 (MD5) Previous issue date: 2003<br>Resumo: o objetivo deste trabalho consistiu no levantamento de dados experimentais da entalpia em excesso em função da composição a diversas temperaturas de soluções binárias do tipo álcool + acetonitrila, e na aplicação do modelo de soluções ERAS para correlacionar

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18

Layne, Robert Michael. "The AIB interneurons are modulated by excitatory and inhibitory signaling pathways to shape aversive behaviors in response to 1-octanol." University of Toledo / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1445452178.

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Shaw, Jeremy Joseph Porter. "The Implications Of Gap Junction Inhibition In Jurkat Cell-CellCommunication And Proliferation." Kent State University Honors College / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1398988837.

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20

Lin, Ming-De, and 林明德. "Synthesis and Characterization of Ru(II)- Bisterpyridyltriferrocene Complex of 8-(2,2′: 6′,2′′- Terpyridin-4′-yloxy) octane-1-thiol." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/90420202431118172868.

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21

Slavik, Stefan. "Hochsubstituierte Azabicyclo[3.3.0]octane als Peptidmimetika." Phd thesis, 2005. http://tuprints.ulb.tu-darmstadt.de/594/1/Dissertation_Stefan_Slavik.pdf.

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Methoden zur asymmetrischen Synthese von Aza(poly)cyclen sind wertvolle Werkzeuge für das rationale Design potentieller Wirkstoffmoleküle. Im Rahmen dieser Arbeit sollte die von M. Reggelin entwickelte Sulfoximinauxiliar-basierte Methode zur asymmetrischen Synthese hochsubstituierter Aza(poly)cyclen strukturell und methodisch weiterentwickelt und auf die Synthese von potentiellen nichtpeptidischen Peptidmimetika angewandt werden. Im Hinblick auf mögliche Synthesen von Substanzbibliotheken wurde die Übertragung der aus γ-Hydroxyalkylierung und Michael-Addition bestehenden Synthesesequenz an lös

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22

Kung, Wei Chang, and 魏振剛. "Excess Enthalpies for Binary Systems Containing 1-Octanol." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/53076070755091226533.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>88<br>An isothermol flow microcalorimeter was utilized in this study to measure the excess enthalpies for the binary systems composed of 1-octanol + n-octane, + ethylbenzene, + anisole, + acetophenone, and + ethyl benzoate. Space the experiments were made at 298.15 K and 1atm. The magnitudes of the excess enthalpies follow the order of acetophenone > anisole > ethyl benzoate > ethylbenzene > n-octane. It is consistent with the dipole moments of the dissimilar components. The Redlich-Kister model correlated accurately the excess enthalpies. The P

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Ropel, Laurie Jo. "Diffusion coefficients and 1-octanol-water partition coefficients of ionic liquids." 2004. http://etd.nd.edu/ETD-db/theses/available/etd-12032004-144320/.

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Thesis (M.S. Ch. Eg.)--University of Notre Dame, 2004.<br>Thesis directed by Joan F. Brennecke for the Department of Chemical and Biomolecular Engineering. "December 2004." Includes bibliographical references (leaves 169-177).

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Nechad, Imane. "Caractérisation in vitro des interactions métaboliques entre le n-hexane, le toluène, le cyclohexane et l'isooctane chez le rat." Mémoire, 2011. http://www.archipel.uqam.ca/4314/1/M12204.pdf.

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Le toluène (TOL), le n-hexane (HEX), le cyclohexane (CHX) et l'isooctane (ISO) sont des composés organiques volatils (COVs) omniprésents dans les milieux industriels et résidentiels. L'exposition aux mélanges soulève de nombreuses interrogations en regard des possibilités d'interaction. L'inhibition métabolique étant le mécanisme d'interaction le plus plausible, pourrait aboutir à une augmentation de leur concentration interne et donc de leur toxicité. L'objectif de cette étude était de caractériser les interactions métaboliques entre le TOL, l'HEX, le CHX et l'ISO, en utilisant les préparatio

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25

Mandelt, Klaus. "SYNTHESE UND UMLAGERUNG VON BICYCLOBUTYL-1-OLEN UND SPIRO[3.4]OCTAN-5-OLEN: EIN NEUER ZUGANG ZU (±)-endo-CAPNELLEN." Doctoral thesis, 2001. http://hdl.handle.net/11858/00-1735-0000-0006-AE8B-C.

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26

Hung, Tsung-Tai, and 洪宗泰. "PART-1 Synthetic studies of the photochromic spiropyran dyesPART-2 Synthetic studies of the 8-hydroxy octanic acid." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/z7s932.

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碩士<br>朝陽科技大學<br>應用化學系碩士班<br>92<br>PART-1 Synthetic studies of the photochromic spiropyran dyes Abstract The major applications for the photochromic functional dyes are in the field of optical memory. In the past few years, these dyes combined with polymeric substrates to form several materials, which could be applied for the new high technology products, such as photochromic sunglasses, color filter, photochromic fiber, or ultraviolet indicator were developed expensively. The major purpose of this study is to synthesize different derivatives of spiro compound(1

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27

Mandelt, Klaus [Verfasser]. "Synthese und Umlagerung von Bicyclobutyl-1-Olen und Spiro[3.4]Octan-5-Olen : ein neuer Zugang zu (±)-endo-Capnellen / vorgelegt von Klaus Mandelt." 2000. http://d-nb.info/961823461/34.

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28

Hu, Xiaozhen, Jian Yang, Xinyue Jia, Shengshan Bi, and Jiangtao Wu. "Solubility of CO² in 2-butyl-1-octanol from (323.15 to 573.15) K at pressures up to 10 MPa." 2019. https://ul.qucosa.de/id/qucosa%3A72423.

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"Estudo experimental e modelagem da entalpia em excesso de soluções liquidas binarias contendo 1-heptanol/acetonitrila e 1-octanol/acetonitrila a 298.15, 313,15, 323,15 K e pressão atmosterica." Tese, Biblioteca Digital da Unicamp, 2003. http://libdigi.unicamp.br/document/?code=vtls000297404.

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Chang, Yi-Mei, and 張依湄. "Lewis acid-Promoted Intramolecular Cyclization Reaction of Six-Member Ring 4-Ene- and 1-Yne-Ynamides： Synthesis of 6-Azabicyclo[3.2.1]octanes, Spiro[3.5]nonanes, and Isoquinolines." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/y4x2du.

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碩士<br>國立臺灣師範大學<br>化學系<br>105<br>Abstract This dissertation covered Lewis acid-promoted intramolecular cyclization reactions of six-membered ring 4-ene- and 1-yne-ynamides afforded 6-azabicyclo[3.2.1]octane, spiro[3.5]nonane, and isoquinoline derivatives. （1） The aluminum(III) chloride-promoted cyclization/chlorination of six-membered ring 4-(N-ethynylamino)cyclohexene enabled a straight forward approach to the 6-azabicyclo[3.2.1]octane. Acid treatment of the resultant chlorinated arylideneazabicyclooctanes furnished 3-alkanoyl-4-chlorocyclohex anamines in excellent yields and high stereosel

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Tsau, Yu-Shuo, та 曹育碩. "一、Lewis Acid-Promoted Intramolecular Cyclization of Silyl-Protected 3-(3-Arylpropargyltosylamino)methylcyclohex-2-en-1-ols: Synthesis of Azaspiro[4.5]dec-6-ene Derivatives 二、Brønsted Acid-Catalyzed and Lewis Acid-Assisted Intramolecular Cyclization of 2-Methyl-2,3-epoxy-4-(3-arylpropargyl)cyclohexan-1- ones: Synthesis of 7-Benzoylbicyclo[3.2.1]octan-2-one and Ar-yl(halo)methylenebicyclo[3.2.1]octan-2-one Derivatives". Thesis, 2014. http://ndltd.ncl.edu.tw/handle/59021650894423613213.

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碩士<br>國立臺灣師範大學<br>化學系<br>102<br>This thesis focuses on acid-promoted intramolecular cyclization of O-silyl-protected 3-(3-arylpropargyltosylamino)methylcyclohex-2-en-1-ols and 2-methyl-2,3-epoxy-4-(3-arylpropargyl)cyclohexan-1-ones. Two major reactions are discussed. First, BF3•OEt2-promoted intramolecular cyclization/ fluorination of O-silyl-protected 3-(3-arylpropargyltosylamino)methylcyclo- hex-2-en-1-ols at room temperature under an atmosphere of nitrogen afforded N-containig spiro[4.5]dec-6-ene derivatives containing a C(sp2)-F bond. In this process, boron trifluoride diethyl etherate act

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YE, WUN-DE, and 葉文德. "Isobaric vapor-liquid equilibrium for binary mixtures containing of n-octanol、2-Ethyl-1-hexanol、Octanoic acid、2-Ethylhexanoic acid and 2-Ethyl-2-hexenal." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/59560869594737355402.

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33

Skrottová, Anežka. "Stanovení rozdělovacího koeficientu (Kow) perfluorovaných kyselin v systému oktan-1-ol/voda." Master's thesis, 2013. http://www.nusl.cz/ntk/nusl-324964.

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Perfluorinated compounds are organic compounds in which all hydrogen atoms in a carbon chain are substituted with fluorine atoms. These compounds are highly stable, persistent and bioaccumulative. They are purely anthropogenic compounds contained in biota and abiota. Partition coefficient between n-octanol and water is the essential toxicological parameter of a compound. This parameter helps us to assess behaviour of compound in the environment as well as in the living organisms. The shake flask method and the RP-HPLC method were employed to measure the Kow of nine perfluorinated acids. Using

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