Academic literature on the topic '-2-thiones'

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Journal articles on the topic "-2-thiones"

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Thokchom, Herojit S., Anita D. Nongmeikapam, and Warjeet S. Laitonjam. "Synthesis of fused pyrazolo-, isoxazolo-, pyrimido-, and pyridopyrimidines." Canadian Journal of Chemistry 83, no. 8 (2005): 1056–62. http://dx.doi.org/10.1139/v05-054.

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A systematic study of the synthesis of the 5,7-diaryl-4-oxo-pyrazolo[3,4-d]pyrimidin-6-thiones (3), 2-phenyl-5,7-bis(2′-methylphenyl)-4-oxo-pyrazolo[3,4-d]pyrimidin-6-thiones (4b), 2(3H)-3-phenyl-5,7-diaryl-4-oxo-pyrazolo[3,4-d]pyrimidin-6-thiones (5), 5,7-diaryl-4-oxo-isoxazolo[5,4-d]pyrimidin-6-thiones (7), 3,5,7-triaryl-2,3-dihydro-4-oxo-isoxazalo[5,4-d]pyrimidin-6-thiones (8), 2-amino-6,8-diaryl-5-oxo-pyrimido[4,5-d]pyrimidin-7-thiones (9), 3,4-dihydro-2-amino-4-phenyl-6,8-diaryl-5-oxo-pyrimido[4,5-d]pyrimidin-7-thiones (10), 3-cyano-6,8-diaryl-2,5-dioxo-pyrido[2,3-d]pyrimidin-7-thiones (1
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Dölling, Wolfgang, Almut Vogt, and Manfred Augustin. "Synthesen von 1,3-Dithiol-2-on-Derivaten,2-Ethylthio-1,3-dithiolium-tetrafluoroboraten und Thieno[2,3-d]-1,3-dithiol-2-thionen / Synthesis of 1,3-Dithiole-2-one Derivatives, 2-Ethylthio-1,3-dithiolium Tetrafluoroborates, and Thieno[2,3-d]-1,3-dithiole-2-thiones." Zeitschrift für Naturforschung B 46, no. 2 (1991): 133–38. http://dx.doi.org/10.1515/znb-1991-0201.

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Substituted 1,3-dithiole-2-ones 2 a - f are obtained by reaction of 1,3-dithiole-2-thiones 1 a - f with mercuric acetate. The thiones 3 react with triethyloxoniumtetrafluoroborate giving 1.3-dithiolium salts 4 a - h . The cyclocondensation of compounds 3 to thieno[2,3-d]-1,3-dithiole- 2-thiones 6 a - c is described. The first synthesis of 5-methylthio-2-thioxo-1,3-dithiole- 4-carboxylic acid is reported.
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Shimada, Kazuaki, Kodai Fukuma, and Toshinobu Korenaga. "Synthesis of Functionalized Chiral Imidazole Derivatives Based on a Bornane Skeleton Bearing a Sterically Crowded Spirocyclic Substituent at the C-3 Position." Natural Product Communications 14, no. 9 (2019): 1934578X1987893. http://dx.doi.org/10.1177/1934578x19878930.

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10-Imidazolylbornane-2-one bearing a sterically crowded spirocyclic substituent at the C-3 position was prepared from d-camphor through the procedure involving the formation of 10-bromobornane-2-thiones or 10-iodobornane-2-thiones and the subsequent conversion into the corresponding 10-imidazolylbornane-2-thiones followed by an efficient oxidative S-O exchange via thione S-oxides.
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Koner, Abhishek, Spencer C. Serin, Gregor Schnakenburg, Brian O. Patrick, Derek P. Gates, and Rainer Streubel. "Exploring the chemistry of backbone amino(chloro)phosphanyl-substituted imidazole-2-thiones." Dalton Transactions 46, no. 31 (2017): 10504–14. http://dx.doi.org/10.1039/c7dt01859b.

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Ziyaei Halimehjani, Azim, Petr Beier, Maryam Khalili Foumeshi, Ali Alaei та Blanka Klepetářová. "Tandem Alkylation/Michael Addition Reaction of Dithiocarbamic Acids with Alkyl γ-Bromocrotonates: Access to Functionalized 1,3-Thiazolidine-2-thiones". Synthesis 53, № 13 (2021): 2219–28. http://dx.doi.org/10.1055/a-1372-1619.

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AbstractThiazolidine-2-thiones were prepared via a novel multicomponent reaction of primary amines (amino acids), carbon disulfide, and γ-bromocrotonates. The reaction proceeds via a domino alkylation/intramolecular Michael addition to provide the corresponding thiazolidine-2-thiones in high to excellent yields. By using diamines in this protocol, bis(thiazolidine-2-thiones) derivatives were synthesized. The synthetic utility of the adducts was demonstrated by hydrolysis, amidation, and oxidation reactions.
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Chunduru, Venkata Sreenivasa Rao, and Rajeswar Rao Vedula. "Synthesis of Coumarin-Substituted 1,3,4-Thiadizine-2-thiones and 1,3-Thiazoline-2-thiones." Synthetic Communications 42, no. 13 (2012): 2014–21. http://dx.doi.org/10.1080/00397911.2010.551698.

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Munive, Laura, Veronica M. Rivas, Aurelio Ortiz, and Horacio F. Olivo. "Oxazolidine-2-thiones and Thiazolidine-2-thiones as Nucleophiles in Intermolecular Michael Additions." Organic Letters 14, no. 13 (2012): 3514–17. http://dx.doi.org/10.1021/ol301489y.

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A.K., Khalafallah, and A. Ahmed M. "A novel and efficient method for the synthesis of 6-amino-pyrimidine-2(1H)-thiones derivatives, pyrido [2,3-d] pyrimidine-2(1H)-thiones derivatives and their glycosides." Chemistry International 3, no. 4 (2017): 469–76. https://doi.org/10.5281/zenodo.1473402.

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Simple condensation reaction of 6-amino-pyrimidine-2(1H)-thiones with aromatic aldhydes afforded 6-(arylidene-amino)-pyrimidine-2-(1H)-thiones derivatives, that react with -nitrostyrene to give pyrido[2,3-d] pyrimidine-2-(1H)-thiones derivatives , the latter compounds served as key intermediate for the synthesis of a new class of pyrimidine-S-glycosides by the reaction with α-bromoglucose tetracetate. Deacetylation of glycoside have been achieved The structure of the compounds were established and confirmed on the basis of their elemental analysis and spectral data.
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Yadav, Lal Dhar Singh, Ankita Rai, Vijai Kumar Rai, and Chhama Awasthi. "Cu(OTf)2-catalysed synthesis of structurally novel bicyclic 1,3-oxazines via condensation-dehydrazinative ring transformation cascades." Journal of Chemical Research 2009, no. 8 (2009): 520–26. http://dx.doi.org/10.3184/030823409x466753.

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The Cu(OTf)2-catalysed expeditious synthesis of 1,3-oxazin-2-ones(thiones) from unprotected D-glucose and D-xylose in excellent yields is reported. Cu(OTf)2 plays a dual role of a Lewis acid and an oxidant for dehydrazination, which is the cornerstone in the present investigation. The 1,3-oxazin-2-ones(thiones) serve as synthons for diversity oriented synthesis of structurally distinct bicyclic 1,3-oxazin-2-ones(thiones), when subjected to Malaprade reaction, followed by Cu(OTf)2-catalysed cyclisation with an appropriate traditional reagent such as phenylhydrazine, amidines, hydroxylamine, or
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Becher, Jan, Ole Simonsen, Helle Sæycher, Thomas Kruse Hansen, Tine Jørgensen, and Søren Bøwadt. "Spiro 1,3,4,6-Tetrathiapentalene-2-thiones." HETEROCYCLES 35, no. 1 (1993): 445. http://dx.doi.org/10.3987/com-92-s56.

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Dissertations / Theses on the topic "-2-thiones"

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Guio, Laurence V. Y. "Polynuclear clusters in desulfurisation reactions of 1,3-dithiole-2-thiones." Thesis, University of Sheffield, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.275037.

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Martens, Thierry. "Comportement physico-chimique de dithiolel, 2 thiones-3 : relation structure- activite antibilharzienne." Paris 6, 1988. http://www.theses.fr/1988PA066397.

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La reduction electrochimique de (pyradinyl-2)-5- ou (pyridyl-2)-5 methyl-4 dithiole-1,2 thiones-3 est etudiee; elle conduit a des pyrrolo (1,2-a) pyrazines, ou des indolizines respectivement. Des hypotheses sont proposees pour expliquer l'activite anthelminthique des composes du titre
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Silva, Sandrina Ribeiro Martins da. "1,3-Oxazoline-2-thiones saccharidiques : synthèse et réactivité de structures bio-actives originales." Thesis, Orléans, 2009. http://www.theses.fr/2009ORLE2083.

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A nos jours, la résistance des microorganismes aux antibiotiques est l'un des plus gros problèmes de la santé publique. La recherche de nouvelles familles de composés naturelles ou synthétiques nous amène vers la découverte des méthodologies innovantes conduisant à de nouveaux antibiotiques. Dans le présent travail, nous vous invitons à plonger dans le "nouveau monde" de la synthèse, la réactivité et l'activité biologique de 1,3-oxazoline-2-thiones (OXTs). En effet, cet hétérocycle peu exploré est un facilement obtenu par condensation entre _-hydroxycarbonyle et l'acide thiocyanique. Lorsque l
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Begum, Imtiaz [Verfasser]. "From C-phosphanylated thiazole-2-thiones to phosphaalkenes and tricyclic 1,4-diphosphinines / Imtiaz Begum." Bonn : Universitäts- und Landesbibliothek Bonn, 2019. http://d-nb.info/1188730932/34.

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Saidi, Mokhtar. "Comportement electrochimique de quelques dithiole-1. 2 thiones-3, dithiole-1. 2 ones-3 et cations methylthio-3 dithiole-1. 2 yluim." Rennes 1, 1988. http://www.theses.fr/1988REN10061.

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Tardy, Sébastien. "Méthodologie de N-vinylation de spiro-1,3-oxazolidine-2-thiones sur charpentes saccharidiques et évaluation en hétérocycloaddition de Diels-Alder [4+2] à demande inverse." Phd thesis, Université d'Orléans, 2007. http://tel.archives-ouvertes.fr/tel-00152838.

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Les 1,3-oxazolidinethione-2-thiones (OZT), fonctions thionocarbamates cycliques, ancrées sur des charpentes saccharidiques font l'objet de notre étude. Les travaux menés ont été axés vers l'emploi des OZT chirales en synthèse asymétrique. Dans ce but, nous avons développé une méthodologie de synthèse d'OZT spiraniques sur charpentes saccharidiques ainsi qu'une méthode de N-vinylation des OZT, en poursuivant les connaissances acquises au sein du laboratoire. La chiralité inhérente aux sucres, couplée à la réactivité toute particulière des OZT obtenues, nous a permis d'explorer la réactivité d'a
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Jagenbrein, Martin. "Complexes of Bi, Pd, Ir and Hg and N-heterocyclic ligands." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF023.

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L’objectif de cette thèse était la synthèse de nouveaux pro-ligands NHC et de leurs complexes métalliques correspondants, en particulier de l’iridium. La tentative de trouver de nouvelles voies de synthèse de complexes NHC à partir des imidazole-2-thiones correspondants n’a pas donné les résultats attendus.Cependant, il a été possible de préparer des composés de coordination intéressants de ces imidazole-2-thiones : ainsi, un complexe de Bi a été préparé et a pu servir d’agent de transmétallation vers le Pd. De nouveaux proligands NHC de type « pince » et plusieurs de leurs complexes d’iridium
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Belot, Vincent. "Accès à une bibliothèque ciblée de n-aryl-thiazoline-2-thiones pour l'établissement d'une nouvelle échelle de taille de substituants usuels." Thesis, Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0408/document.

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Une échelle de taille contenant 20 substituants usuels en chimie a été construite à partir des barrières de rotations de N-aryl-thiazoline-2-thiones. L’énergie d’activation ΔG≠rot qui est mesurée reflète l’encombrement stérique du substituant en ortho du cycle benzénique. Les perturbations électroniques, et les facteurs externes tels que la température ou le solvant sont négligeables. La grande sensibilité du modèle proposé conduit au classement suivant Me > Cl et CN > OMe > OH. Ces classements divergents décrits dans la littérature seront discutés. Une limitation du modèle proposé co
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Belot, Vincent. "Accès à une bibliothèque ciblée de n-aryl-thiazoline-2-thiones pour l'établissement d'une nouvelle échelle de taille de substituants usuels." Electronic Thesis or Diss., Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0408.

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Une échelle de taille contenant 20 substituants usuels en chimie a été construite à partir des barrières de rotations de N-aryl-thiazoline-2-thiones. L’énergie d’activation ΔG≠rot qui est mesurée reflète l’encombrement stérique du substituant en ortho du cycle benzénique. Les perturbations électroniques, et les facteurs externes tels que la température ou le solvant sont négligeables. La grande sensibilité du modèle proposé conduit au classement suivant Me > Cl et CN > OMe > OH. Ces classements divergents décrits dans la littérature seront discutés. Une limitation du modèle proposé co
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Zang, Hong Zang Hong. "Part 1, Investigations of DNA damage mechanisms of azinomycin analogs and the natural product leinamycin ; Part 2, Biologically relevant chemical reactions of 1,2-dithiole-3-thiones as cancer preventive agents /." free to MU campus, to others for purchase, 2001. http://wwwlib.umi.com/cr/mo/fullcit?p3036872.

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Books on the topic "-2-thiones"

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Litvinov, V. Advances in the Chemistry of 3-Cyanopyridin-2 (ih)-Ones, -Thiones, and -Selenones. Taylor & Francis Group, 1994.

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Book chapters on the topic "-2-thiones"

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Kensler, T. W., J. D. Groopman, B. D. Roebuck, and T. J. Curphey. "Chemoprotection by l,2-Dithiole-3-thiones." In ACS Symposium Series. American Chemical Society, 1993. http://dx.doi.org/10.1021/bk-1994-0546.ch011.

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Laughlin, Thomas J., Joshua S. Yoo, and Ram S. Mohan. "Synthesis of 3,4-Dihydropyrimidin-2(1H)-Ones/Thiones and Polyhydroquinolines via Multicomponent Reactions." In Multicomponent Reactions. CRC Press, 2017. http://dx.doi.org/10.1201/9781315369754-13.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex of 5, 2-diphenyl-6H-pyrazolo-[1, 5-c] pyrimidine-7-thiones." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49202-4_186.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex of 5-(p-methoxyphenyl)-2-phenyl-6H-pyrazolo- [1, 5-c]pyrimidine-7-thiones." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49202-4_185.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex of 5-p-chlorophenyl-2-phenyl-6H-pyrazolo- [1, 5-c]pyrimidine-7-thiones." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49202-4_187.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex of 5-p-bromophenyl-2-phenyl-6H-pyrazolo- [1, 5-c]pyrimidine-7-thiones." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49202-4_188.

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Afarinkia, K., and V. Vinader. "2-Pyran-2-thiones." In Six-Membered Hetarenes with One Chalcogen. Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-014-00244.

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Faulkner, S., R. C. Whitehead, and R. J. Aarons. "2-Thiopyran-2-thiones." In Six-Membered Hetarenes with One Chalcogen. Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-014-00926.

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S. Laitonjam, Warjeet, and Nimalini Moirangthem. "Construction of Biologically Active Five- and Six-Membered Fused Ring Pyrimidine Derivatives from 1,3-Diarylthiobarbituric Acids (DTBA)." In Strategies Towards the Synthesis of Heterocycles and Their Applications [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.108842.

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Several derivatives of fused pyrimidines were synthesized in maximum yields by using the respective condensation products, namely, 5-ethoxymethylene-1,3-diaryl-2-thiobarbituric acids and 5-phenyl-methylene-1,3-diaryl-2-thiobarbituric acids, which can be obtained from 1,3-diarylthiobarbituric acids (DTBA). These condensation products possessing three electrophilic centres could undergo cyclocondensation with various binucleophiles to give various fused heterocycles of pyrimidine derivatives, such as pyrazolo[3,4-d]pyrimidine-6-thiones, 5,7-diaryl-4-oxo-isoxazolo[5,4-d]pyrimidine-6-thiones, 5-ox
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Williams, A. C., and N. Camp. "2-1-Benzopyran-2-thiones." In Six-Membered Hetarenes with One Chalcogen. Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-014-00407.

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Conference papers on the topic "-2-thiones"

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Shutalev, Anatoly, Ekaterina Kishko, and Natalie Sivova. "A New Approach to 5-Functionalized Pyrimidine-2-Thiones." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02012.

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Shutalev, Anatoly, and Anastasia Fesenko. "Synthesis of 5-(diethoxyphosphoryl)-substituted Hydrogenated Pyrimidine-2-thiones." In The 11th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2007. http://dx.doi.org/10.3390/ecsoc-11-01328.

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Shutalev, Anatoly. "Synthesis and Reactivity of 5-Functionalized 4-Hydroxyhexahydropyrimidine-2- thiones/ones." In The 3rd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1999. http://dx.doi.org/10.3390/ecsoc-3-01749.

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Toda, Hiroyuki, Carl M. Verber, and Daniel P. Campbell. "Use of Z-scan measurement technique to characterize nonlinear optical properties of imidazole-2-thiones." In OSA Annual Meeting. Optica Publishing Group, 1991. http://dx.doi.org/10.1364/oam.1991.mgg2.

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The Z-scan technique for measuring third-order optical nonlinearities has been proposed and demonstrated recently.1 Using this technique, we measured the optically induced index change Δn for derivatives of imidazole-2-thione at a wavelength of 532 nm. In these materials, which are optically clear, we detected a quadratic relationship between the index change and the intensity in a 30–100-MW/cm2 range, as opposed to the linear relationship we observed in absorptive materials. We also observed that the distance between peak and valley of the Z-scan data was less than predicted for third-order e
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Tikhomolova, Alexandra S., and Alevtina Yu Yegorova. "Transamination of 3-[(Dimethylamino)methylidene]-5-arylfuran-2(3H)-thiones with the Participation of 1,2-Phenylenediamine." In ECSOC 2024. MDPI, 2024. https://doi.org/10.3390/ecsoc-28-20121.

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CIOBANU, Natalia, and Fliur МACAEV. "Selection of the optimum method for the synthesis of dihydropyrimidin-2-ones(thiones) using various biocatalysts." In International Congress "Research – Innovation – Innovative Entrepreneurship". Ion Creangă Pedagogical State University, 2024. https://doi.org/10.46727/c.17-18-05-2024.p264-267.

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The relevance of pyrimidines is well known due to their wide range of biological activities, pharmacophoric fragments of their constituent structures. Their use in the field of drug research has stimulated the expansion of the range of synthetic production methods, especially in conditions of respect for the protection of ecology and the environment in general.
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Nikalje, Anna Pratima, Urja Nimbalkar, Dr Santosh Tupe, Julio Seijas Vázquez, and M. Pilar Vazquez-Tato. "Molecular sieves and Ultrasound assisted Synthesis of Novel 1,3,4-oxadiazole-2-thiones derivatives as potential antifungal Agents." In The 19th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2015. http://dx.doi.org/10.3390/ecsoc-19-b008.

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Hartung, Jens, Markus Heubes, Rainer Kneuer, and Michaela Schwarz. "Dynamic Behaviour of Cyclic Thiohydroxamic Acid Derivatives Barrier to Rotation about N2O Bonds in 4-Substituted N-Isopropoxythiazole-2(3H)-thiones and N-Isopropoxypyridine-2(1H)-thione." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01931.

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Shutalev, Anatoly, Anastasia Fesenko, and Natalia Lonina. "Synthesis of 5-R-thio, 5-R-sulfinyl, 5-R-sulfonyl and 5-di(R-oxy)phosphoryl Substituted Hydrogenated Pyrimidine-2-thiones/ones." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01943.

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MamleDessai, S. N., Priyanka Tiwari, Soniya Phadte, and Sanket Naik. "Design, synthesis of a series of 6-substituted- 4-hydroxy-1-[(-4-substitutedphenyl)sulfonyl]quinolin-2(1<em>H</em>)-thiones derivatives and evaluation of their <em>in vitro</em> anticancer activity." In 7th International Electronic Conference on Medicinal Chemistry. MDPI, 2021. http://dx.doi.org/10.3390/ecmc2021-11389.

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