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Journal articles on the topic '3-chloroaniline'

Author: Grafiati

Published: 7 June 2025

Last updated: 2 August 2025

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1

Porselvi, L., and S. Jhancy Mary. "Synthesis and Studies on Electroactive Poly(3-chloroaniline), Poly(3-chloroaniline)- Blend-polyethyleneglycol and Poly(3-chloroaniline)-Blend-Poly(vinyl alcohol)." Asian Journal of Chemistry 26, no. 3 (2014): 783–89. http://dx.doi.org/10.14233/ajchem.2014.15540.

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2

Ge, Hui Lin, Shu Shen Liu, Hong Qiu Yuan, Gui Hao Yin, Yi Xie, and Ling Yun Mo. "Assessment and Prediction of Joint Toxicity of Aniline Derivatives." Applied Mechanics and Materials 448-453 (October 2013): 217–20. http://dx.doi.org/10.4028/www.scientific.net/amm.448-453.217.

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The joint toxicity of aniline, 2-methylaniline, 3-methylaniline, 4-methylaniline, 2-nitroaniline, 3-nitroaniline, 4-nitroaniline, 2-chloroaniline, 3-chloroaniline, and 4-chloroaniline on photobacterium were predicted and evaluated by using concentration addition (CA) and independent action (IA) models, and joint effect indices including toxic units, additive index, mixture toxicity index, and similarity parameter. The tested mixture presented synergism.

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3

Ge, Hui Lin, Shu Shen Liu, Jin Hui Luo, Qiong Fan, Yue Zhang, and Ling Yun Mo. "Predicting Mixture Toxicities of Aniline Derivatives on Photobacterium." Advanced Materials Research 807-809 (September 2013): 684–87. http://dx.doi.org/10.4028/www.scientific.net/amr.807-809.684.

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The low-dose and combined effects of aniline, 2-methylaniline, 3-methylaniline, 4-methylaniline, 2-nitroaniline, 3-nitroaniline, 4-nitroaniline, 2-chloroaniline, 3-chloroaniline, and 4-chloroaniline on photobacterium Vibrio qinghaiensis were predicted and evaluated by using concentration addition (CA) and independent action (IA) models. The mixtures effects can be predicted by CA and IA models, which indicate that aniline derivatives present additive toxicity.

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4

Zhang, Li-li, Dan He, Jian-meng Chen, and Yu Liu. "Biodegradation of 2-chloroaniline, 3-chloroaniline, and 4-chloroaniline by a novel strain Delftia tsuruhatensis H1." Journal of Hazardous Materials 179, no. 1-3 (2010): 875–82. http://dx.doi.org/10.1016/j.jhazmat.2010.03.086.

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5

Mohammed, Nidhal S., T. H. Flowers, and H. J. Duncan. "Adsorption of 3-Chloroaniline on Potato Skin in Aqueous Solution." Indian Journal of Materials Science 2016 (July 25, 2016): 1–7. http://dx.doi.org/10.1155/2016/1972395.

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The adsorption behaviour of aromatic amine 3-chloroaniline (3-CA) from aqueous solution on fresh potato skin was investigated. A series of batch experiments were conducted under different experimental conditions of contact time, 3-chloroaniline concentration, weight of potato skin, pH, temperature, and ionic strength using RP-HPLC analysis. Adsorption equilibrium of 3-chloroaniline at concentration of 10 µg/mL on 1 g weight of chopped potato skin was achieved in 24 hours. Using different varieties of potato skin showed that the adsorption of 3-CA on Nicola variety is higher compared to Sante a

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6

Rafalska-Łasocha, A., and W. Łasocha. "X-ray powder diffraction studies of aniline derivatives." Powder Diffraction 18, no. 3 (2003): 266–68. http://dx.doi.org/10.1154/1.1604126.

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The X-ray powder diffraction patterns of two liquid aniline derivatives o-chloroaniline, and m-chloroaniline were measured at 250 °K in a low temperature chamber. Both compounds crystallize in the orthorhombic system with the unit cell parameters refined to a=1.8391(3) nm, b=1.0357(2) nm, c=0.6092(1) nm, space group Pmmm(47) and a=0.450 39(9) nm, b=1.9820(4) nm, c=1.2699(4) nm, space group Pcca(54) for o-chloroaniline and m-chloroaniline, respectively. Investigated at room temperature, 2,6-dichloroaniline crystallizes in the monoclinic system, space group P21/c(14), a=1.1329(2) nm, b=0.41093(8

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7

Rai, Krishna Bahadur, Nabin Kumar Teemilsina, and Bijay Siwakoti. "First principles study of structural equilibrium configuration of Ortho-, Meta-, and Para-chloroaniline molecules." Scientific World 17, no. 17 (2024): 7–18. http://dx.doi.org/10.3126/sw.v17i17.66414.

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This work has studied the ground state energy, binding energy, equilibrium geometry, charge distribution, and dipole moment of ortho-, meta-, and para-chloroanilines using a wide range of advanced theoretical methods including first-principles Hartree-Fock (HF), Mϕller-Plesset (MP) perturbation theory, Configuration Interaction (CI) and Density Functional Theory [DFT (B3LYP)] with basis sets 3-21G, 4-31G, 6-31G, 6-31G*, 6-31G**, 6-311G, 6-311G*, and 6-311G**. The trend in ground state energy is obtained in EDFT < EHF+MP3 < EHF+MP2 < ECISD < EHF. The calculated binding energies for

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8

Chen, Si, Chao Yan, Bin Luo, and Bin Yang. "Study on the Terahertz Time Domain Spectrum of P-Chloroaniline." Advanced Materials Research 441 (January 2012): 741–45. http://dx.doi.org/10.4028/www.scientific.net/amr.441.741.

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P-chloroaniline is one of the most important azo dye intermediates. It is a highly desired research on the identification of P-chloroaniline. Terahertz time domain spectroscopy (THz-TDS) is sensitive to the molecule structure of compound. In this paper, the spectra of P-chloroaniline located at the region from 0.1 to 3 THz were tested by THz-TDS system, and then the geometry structure of p-chloroaniline at the range of 0 THz to 10 THz was optimized, resonance frequency was calculated by Gussian03 software based on the density functional theory (DFT). The results showed that the absorbance peak

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9

P. L. Harale, M. E. Shelke, D.T. Tayade, and A. R. Kurhe. "Synthesis of 3-(substitutedthiocarbamide)-aniline derivatives from di-tert-butyl dicarbonate (BoC) protected 3-chloroaniline." GSC Biological and Pharmaceutical Sciences 28, no. 3 (2024): 046–52. http://dx.doi.org/10.30574/gscbps.2024.28.3.0313.

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Synthesis of substituted thiocarbamide derivatives is important in the fields of medicinal, agricultural, chemical, and pharmaceutical. Thiocarbamides are commonly utilized as starting materials for several organic synthetic processes and have been studied in search for easy and effective methods of chemical synthesis. In the existing research work, 3-chloroaniline was protected by a di-tert-butyl dicarbonate (BoC) protecting agent. Substituted thiocarbamide derivatives were synthesized using condensation of various substituted thioureas with amino group-protected 3-chloroaniline. The structur

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10

P., L. Harale, E. Shelke M., Tayade D.T., and R. Kurhe A. "Synthesis of 3-(substitutedthiocarbamide)-aniline derivatives from di-tert-butyl dicarbonate (BoC) protected 3-chloroaniline." GSC Biological and Pharmaceutical Sciences 28, no. 3 (2024): 046–52. https://doi.org/10.5281/zenodo.14709141.

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Synthesis of substituted thiocarbamide derivatives is important in the fields of medicinal, agricultural, chemical, and pharmaceutical. Thiocarbamides are commonly utilized as starting materials for several organic synthetic processes and have been studied in search for easy and effective methods of chemical synthesis. In the existing research work, 3-chloroaniline was protected by a di-tert-butyl dicarbonate (BoC) protecting agent. Substituted thiocarbamide derivatives were synthesized using condensation of various substituted thioureas with amino group-protected 3-chloroaniline. The structur

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11

Dobija, Anna, Alicja Rafalska-Łasocha, and Wiesław Łasocha. "Powder diffraction data of novel complexes CdX2-2(NH2-PhY), part I." Powder Diffraction 25, no. 4 (2010): 359–67. http://dx.doi.org/10.1154/1.3503662.

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Four new compounds with general formula CdI2-2(NH2-PhX) (Ph represents phenyl radical; X represents Cl or H atoms) were obtained and characterized. Two of them, bisaniline diiodidecadmium(II) — CdI2⋅2[NH2–C6H5] {1} and bis(2-chloroaniline) diiodidecadmium(II) — CdI2⋅2[NH2–C6H4Cl] {2}, crystallize in monoclinic system, whereas another two, bis(3-chloroaniline) diiodidecadmium(II) — CdI2⋅2[NH2–C6H4Cl]{3} and bis(4-chloroaniline) diiodidecadmium(II) hemi(4-chloroanilate) — CdI2⋅2[NH2–C6H4Cl]½[NH2–C6H4Cl] {4}, crystallize in triclinic system. The investigated compounds, from chemical point of view

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12

Lu, Chun Shan, Jing Hui Lu, Lei Ma, Qun Feng Zhang, and Xiao Nian Li. "Effect of Solvent Polarity Properties on the Selectivity and Activity for 3,4-Dichloronitrobenzene Hydrogenation over Pd/C Catalyst." Advanced Materials Research 396-398 (November 2011): 2379–83. http://dx.doi.org/10.4028/www.scientific.net/amr.396-398.2379.

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Several representative solvents classified in three categories: 1) aprotic apolar solvents: 2) protic solvents; 3) aprotic polar solvents were chosen to investigate the effect on the catalytic activity and selectivity for the selective hydrogenation of 3,4-dichloronitrobenzene (3,4-DCNB) over Pd/C catalyst. The solvent polarity increases the hydrogenation rate apparently, but also increases the selectivity to 3-chloroaniline and 4-chloroaniline from dehalogenation reaction. The solvents with the high polarity and hydrogen-bond donation capability can generate the strong interaction and the H-b

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13

Słomkiewicz, Piotr M., Beata Szczepanik, Magdalena Garnuszek, Paweł Rogala, and Zygfryd Witkiewicz. "Determination of Adsorption Equations for Chloro Derivatives of Aniline on Halloysite Adsorbents Using Inverse Liquid Chromatography." Journal of AOAC INTERNATIONAL 100, no. 6 (2017): 1715–26. http://dx.doi.org/10.5740/jaoacint.17-0237.

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Abstract Chloro derivatives of aniline are commonly used in the production of dyes, pharmaceuticals, and agricultural agents. They are toxic compounds with a large accumulation ability and low natural biodegradability. Halloysite is known as an efficient adsorbent of toxic compounds, such as phenols or herbicides, from wastewater. Inverse LC was applied to measure the adsorption of aniline and 2-chloroaniline (2-CA), 3-chloroaniline (3-CA), and 4-chloroaniline (4-CA) on halloysite adsorbents. A peak division (PD) method was used to determine a Langmuir equation in accordance with the adsorptio

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14

Khosa, Muhammad Kaleem, Muhammad Asghar Jamal, Rubbia Iqbal, and Mazhar Hamid. "Synthesis and Characterization of Novel Processable and Flexible Polyimides Containing 3,6-Di(4-carboxyphenyl)pyromellitic Dianhydride." Advances in Chemistry 2014 (September 10, 2014): 1–10. http://dx.doi.org/10.1155/2014/759594.

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A series of six novel polyimides containing 3,6-di(4-carboxyphenyl)pyromellitic dianhydride were synthesized via two steps condensation method. Aromatic diamines monomers, 4-(4-aminophenoxy)-N-(4-(4-aminophenoxy)benzylidene)-3-chloroaniline (DA1), 4-(4-amino-3-methylphenoxy)-N-(4-(4-amino-3-methylphenoxy)benzylidene)-3-chloroaniline (DA2), 4-(4-amino-2-methylphenoxy)-N-(4-(4-amino-2-methylphenoxy)benzylidene)-3-chloroaniline (DA3) 4-(4-aminophenoxy)-N-(4-(4-aminophenoxy)benzylidene)-2-methylaniline (DA4), 4-(4-amino-3-methylphenoxy)-N-(4-(4-amino-3-methylphenoxy)benzylidene)-2-methylaniline (D

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15

Shukla, A. R., C. M. Pathak, N. G. Dongre, B. P. Asthana, and Jacob Shamir. "Infrared and Raman spectra of vicinally trisubstituted 2-methyl, 3-chloroaniline and 2-methyl, 6-chloroaniline." Proceedings / Indian Academy of Sciences 97, no. 5-6 (1986): 593–600. http://dx.doi.org/10.1007/bf02843506.

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16

Zhu, Donghong, Xin Weng, Yuqiong Tang, Jingya Sun, Shourong Zheng, and Zhaoyi Xu. "Pt/Al2O3 coated with N-doped carbon as a highly selective and stable catalyst for catalytic hydrogenation of p-chloronitrobenzene to p-chloroaniline." RSC Advances 10, no. 24 (2020): 14208–16. http://dx.doi.org/10.1039/d0ra01578d.

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17

Sharma, Sanjay Kumar, Sayeeda Sultana, and Ponnuchamy Singanan. "GREEN SYNTHESIS AND ANALYTICAL TECHNIQUE FOR THE SEPARATION OF SUBSTITUTED CHLOROPHENYL HYDRAZINE ISOMERS BY REVERSE PHASE HPLC METHOD." RASAYAN Journal of Chemistry 17, no. 04 (2024): 1924–33. http://dx.doi.org/10.31788/rjc.2024.1749036.

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4-Chlorophenylhydrazine hydrochloride (4-CPH) is a crucial intermediate in organic synthesis, utilized in various applications including the production of Carprofen and wastewater treatment. This study focuses on the synthesis and impurity analysis of 4-CPH on green approach, with particular emphasis on the detection and quantification of positional isomers 2-Chlorophenylhydrazine hydrochloride (2-CPH), 3-Chlorophenylhydrazine hydrochloride (3- CPH), and 4-Chloroaniline. A high-performance liquid chromatography (HPLC) method was developed using a Waters X-Bridge C18 column and optimized for re

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18

Król, J. E., J. T. Penrod, H. McCaslin та ін. "Role of IncP-1β Plasmids pWDL7::rfpand pNB8c in Chloroaniline Catabolism as Determined by Genomic and Functional Analyses". Applied and Environmental Microbiology 78, № 3 (2011): 828–38. http://dx.doi.org/10.1128/aem.07480-11.

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ABSTRACTBroad-host-range catabolic plasmids play an important role in bacterial degradation of man-made compounds. To gain insight into the role of these plasmids in chloroaniline degradation, we determined the first complete nucleotide sequences of an IncP-1 chloroaniline degradation plasmid, pWDL7::rfpand its close relative pNB8c, as well as the expression pattern, function, and bioaugmentation potential of the putative 3-chloroaniline (3-CA) oxidation genes. Based on phylogenetic analysis of backbone proteins, both plasmids are members of a distinct clade within the IncP-1β subgroup. The pl

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19

Swenson, William, Jeff Arendt, and David Sloan Wilson. "Artificial selection of microbial ecosystems for 3-chloroaniline biodegradation." Environmental Microbiology 2, no. 5 (2000): 564–71. http://dx.doi.org/10.1046/j.1462-2920.2000.00140.x.

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20

Chen, Hongfeng, Christopher N. Nilsen, Anusuya Choudhury, and Kirk L. Sorgi. "A safe and convenient synthesis of 4-benzyloxy-3-chloroaniline." Arkivoc 2008, no. 14 (2008): 1–6. http://dx.doi.org/10.3998/ark.5550190.0009.e01.

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21

BERGON, M., M. KOUDA-BONAFOS, and J. P. CALMON. "Mechanism for the hydrolytic degradation of barban to 3-chloroaniline." Agricultural and Biological Chemistry 51, no. 7 (1987): 1915–20. http://dx.doi.org/10.1271/bbb1961.51.1915.

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22

Bergon,, M., M. Kouda-Bonafos, and J. P. Calmon. "Mechanism for the Hydrolytic Degradation of Barban to 3-Chloroaniline." Agricultural and Biological Chemistry 51, no. 7 (1987): 1915–20. http://dx.doi.org/10.1080/00021369.1987.10868330.

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23

Babashkina, Maria G., Koen Robeyns, Yaroslav Filinchuk, and Damir A. Safin. "Detailed studies of the interaction of 3-chloroaniline with O,O′-diphenylphosphorylisothiocyanate." New Journal of Chemistry 40, no. 2 (2016): 1230–36. http://dx.doi.org/10.1039/c5nj02588e.

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The reaction of neat 3-chloroaniline with neat SCN–P(O)(OPh)<sub>2</sub> leads to 1. The same reaction in non-dried CH<sub>2</sub>Cl<sub>2</sub> or C<sub>6</sub>H<sub>6</sub> or Me<sub>2</sub>CO leads to 2, 3·0.5C6H6 and 4, respectively.

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24

Johmoto, Kohei, Takashi Ishida, Akiko Sekine, Hidehiro Uekusa, and Yuji Ohashi. "Relation between photochromic properties and molecular structures in salicylideneaniline crystals." Acta Crystallographica Section B Structural Science 68, no. 3 (2012): 297–304. http://dx.doi.org/10.1107/s0108768112010993.

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The crystal structures of the salicylideneaniline derivatives N-salicylidene-4-tert-butyl-aniline (1), N-3,5-di-tert-butyl-salicylidene-3-methoxyaniline (2), N-3,5-di-tert-butyl-salicylidene-3-bromoaniline (3), N-3,5-di-tert-butyl-salicylidene-3-chloroaniline (4), N-3,5-di-tert-butyl-salicylidene-4-bromoaniline (5), N-3,5-di-tert-butyl-salicylidene-aniline (6), N-3,5-di-tert-butyl-salicylidene-4-carboxyaniline (7) and N-salicylidene-2-chloroaniline (8) were analyzed by X-ray diffraction analysis at ambient temperature to investigate the relationship between their photochromic properties and mo

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25

Sihtmäe, Mariliis, Monika Mortimer, Anne Kahru, and Irina Blinova. "Toxicity of five anilines to crustaceans, protozoa and bacteria." Journal of the Serbian Chemical Society 75, no. 9 (2010): 1291–302. http://dx.doi.org/10.2298/jsc091219103s.

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Aromatic amines (anilines and related derivates) are an important class of environmental pollutants that can be released to the aquatic environment as industrial effluents or as breakdown products of pesticides and dyes. The toxicities of aniline, 2-chloroaniline, 3-chloroaniline, 4-chloroaniline and 3,5-dichloroaniline towards a multitrophic test battery comprised of bacteria Aliivibrio fischeri (formerly Vibrio fischeri), a ciliated protozoan Tetrahymena thermophila and two crustaceans (Daphnia magna and Thamnocephalus platyurus) were investigated. Under the applied test conditions, the toxi

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26

Le Thi Hong, Hai, Diep Dao Thi Bich, Ngan Nguyen Bich, and Luc Van Meervelt. "Crystal structures of organoplatinum complexes containing alkyleugenoxyacetate andp-chloroaniline." Acta Crystallographica Section E Crystallographic Communications 72, no. 7 (2016): 912–17. http://dx.doi.org/10.1107/s2056989016008872.

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In the title complexes,trans-dichlorido(4-chloroaniline-κN){3-methoxy-4-methoxycarbonylmethoxy-1-[(2,3-η)-prop-2-en-1-yl]benzene}platinum(II) 0.1-hydrate, [PtCl2(C6H6ClN)(C13H16O4)]·0.1H2O, (I), andtrans-dichlorido(4-chloroaniline-κN){4-ethoxycarbonylmethoxy-3-methoxy-1-[(2,3-η)-prop-2-en-1-yl]benzene}platinum(II), [PtCl2(C6H6ClN)(C14H18O4)], (II), the PtIImetal atom displays a slightly distorted square-planar coordination geometry defined by the aniline N atom, two chloride anions (trans-positioned) and one ethylenic double bond. The least-squares planes through the two aromatic ring systems

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27

Boon, Nico, Johan Goris, Paul De Vos, Willy Verstraete, and Eva M. Top. "Genetic Diversity among 3-Chloroaniline- and Aniline-Degrading Strains of theComamonadaceae." Applied and Environmental Microbiology 67, no. 3 (2001): 1107–15. http://dx.doi.org/10.1128/aem.67.3.1107-1115.2001.

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ABSTRACT We examined the diversity of the plasmids and of the genetdnQ, involved in the oxidative deamination of aniline, in five bacterial strains that are able to metabolize both aniline and 3-chloroaniline (3-CA). Three strains have been described and identified previously, i.e., Comamonas testosteroni I2 and Delftia acidovorans CA28 and BN3.1. Strains LME1 and B8c were isolated in this study from linuron-treated soil and from a wastewater treatment plant, respectively, and were both identified asD. acidovorans. Both Delftia andComamonas belong to the familyComamonadaceae. All five strains

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28

McManus, Iain J., Helen Daly, Haresh G. Manyar, S. F. Rebecca Taylor, Jillian M. Thompson, and Christopher Hardacre. "Selective hydrogenation of halogenated arenes using porous manganese oxide (OMS-2) and platinum supported OMS-2 catalysts." Faraday Discussions 188 (2016): 451–66. http://dx.doi.org/10.1039/c5fd00227c.

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Porous manganese oxide (OMS-2) and platinum supported on OMS-2 catalysts have been shown to facilitate the hydrogenation of the nitro group in chloronitrobenzene to give chloroaniline with no dehalogenation. Complete conversion was obtained within 2 h at 25 °C and, although the rate of reaction increased with increasing temperature up to 100 °C, the selectivity to chloroaniline remained at 99.0%. Use of Pd/OMS-2 or Pt/Al<sub>2</sub>O<sub>3</sub> resulted in significant dechlorination even at 25 °C and 2 bar hydrogen pressure giving a selectivity to chloroaniline of 34.5% and 77.8%, respectivel

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29

Dejonghe, Winnie, Johan Goris, Ann Dierickx, et al. "Diversity of 3-chloroaniline and 3,4-dichloroaniline degrading bacteria isolated from three different soils and involvement of their plasmids in chloroaniline degradation." FEMS Microbiology Ecology 42, no. 2 (2002): 315–25. http://dx.doi.org/10.1111/j.1574-6941.2002.tb01021.x.

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30

Rana, V. A., A. D. Vyas, and S. C. Mehrotra. "Dielectric relaxation study of mixtures of 1-propanol with aniline, 2-chloroaniline and 3-chloroaniline at different temperatures using time domain reflectometry." Journal of Molecular Liquids 102, no. 1-3 (2003): 379–91. http://dx.doi.org/10.1016/s0167-7322(02)00162-9.

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31

Tai, Xi Shi. "Preparation, Spectral Characterization and Crystal Structure 2-Acetyl-2'-Chloroacetanilide." Advanced Materials Research 396-398 (November 2011): 916–19. http://dx.doi.org/10.4028/www.scientific.net/amr.396-398.916.

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2-Acetyl-2'-chloroacetanilide has been prepared using 2-chloroaniline and ethyl acetoacetate as starting material in toluene solution. The compound was characterized by mass spectrum, infrared spectrum, 1HNMR, 13CNMR spectra and X-ray single crystal diffraction analysis. The results show that the C=O bond lengths are 1.206(3) Å and 1.195(3) Å, which implies that the molecule is in the keto form. The complex forms layered structure through ••• stacking interaction.

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32

Angeloff, Ariane, Jean-Jacques Brunet, Pierre Legars, Denis Neibecker, and Denis Souyri. "Regioselective dechlorination of 2,3-dichloronitrobenzene into 3-chloronitrobenzene and regioselective dechlorination–hydrogenation into 3-chloroaniline." Tetrahedron Letters 42, no. 12 (2001): 2301–3. http://dx.doi.org/10.1016/s0040-4039(01)00103-4.

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33

Dunstan, Pedro Oliver, and Abdul Majeed Khan. "Thermochemical Parameters of 3-Chloroaniline Complexes of Certain Bivalent Transition Metal Bromides." Open Journal of Physical Chemistry 03, no. 04 (2013): 163–69. http://dx.doi.org/10.4236/ojpc.2013.34020.

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34

David, B., M. Lhote, V. Faure, and P. Boule. "Ultrasonic and photochemical degradation of chlorpropham and 3-chloroaniline in aqueous solution." Water Research 32, no. 8 (1998): 2451–61. http://dx.doi.org/10.1016/s0043-1354(97)00477-6.

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35

Goris, Johan, Nico Boon, Liesbeth Lebbe, Willy Verstraete, and Paul Vos. "Diversity of activated sludge bacteria receiving the 3-chloroaniline-degradative plasmid pC1gfp." FEMS Microbiology Ecology 46, no. 2 (2003): 221–30. http://dx.doi.org/10.1016/s0168-6496(03)00231-9.

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36

Valenta, Vladimír, Jiří Holubek, Emil Svátek, Martin Valchář, Ivan Krejčí, and Miroslav Protiva. "Potential nootropic agents: Synthesis of some (2-oxo-1-pyrrolidinyl)acetamides and some related compounds." Collection of Czechoslovak Chemical Communications 55, no. 11 (1990): 2756–64. http://dx.doi.org/10.1135/cccc19902756.

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Ethyl (2-oxo-1-pyrrolidinyl)acetate was transformed by ester exchange to the 2-dimethylaminoethyl ester VI which was converted to the choline iodide ester VII. The mixed anhydride of (2-oxo-1-pyrrolidinyl)acetic acid and monoethyl carbonate was reacted with ethyl aminoacetate to give the ester VIII which was transformed on the one hand to the amide IX, and to the 2-dimethylaminoethyl ester X on the other. Reaction of the latter with methyl iodide afforded a further choline iodide ester XI. Reactions of (2-oxo-1-pyrrolidinyl)acetyl chloride with 4-chloroaniline and 3-aminopyridine gave the amid

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Oliva, Paola, Romeo Romagnoli, Barbara Cacciari, et al. "Synthesis and Biological Evaluation of Highly Active 7-Anilino Triazolopyrimidines as Potent Antimicrotubule Agents." Pharmaceutics 14, no. 6 (2022): 1191. http://dx.doi.org/10.3390/pharmaceutics14061191.

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Two different series of fifty-two compounds, based on 3′,4′,5′-trimethoxyaniline (7a–ad) and variably substituted anilines (8a–v) at the 7-position of the 2-substituted-[1,2,4]triazolo [1,5-a]pyrimidine nucleus, had moderate to potent antiproliferative activity against A549, MDA-MB-231, HeLa, HT-29 and Jurkat cancer cell lines. All derivatives with a common 3-phenylpropylamino moiety at the 2-position of the triazolopyrimidine scaffold and different halogen-substituted anilines at its 7-position, corresponding to 4′-fluoroaniline (8q), 4′-fluoro-3′-chloroaniline (8r), 4′-chloroaniline (8s) and

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Qiu, Ning, Wenjing Li, Jianna Jia, Guoqiang Ma, and Shitao Peng. "Effects of Sublethal Exposure to Three Water Pollutants on Scototaxis in Rare Minnow (Gobiocypris rarus)." Water 16, no. 20 (2024): 2948. http://dx.doi.org/10.3390/w16202948.

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The biological early warning system with fish behavior as the detection index is an efficient and rapid early warning technology for the ecological damage caused by water pollutants. However, the attempt to apply the scototaxis (dark preference) behavior of fish to biological early warning is still relatively lacking. In this study, we delved into the dark and light preferences of the rare minnows (Gobiocypris rarus), employing three distinct tank configurations. Additionally, we systematically examined the modulating effects of environmental illumination, nutritional status, and the number of

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Boon, Nico, Eva M. Top, Willy Verstraete, and Steven D. Siciliano. "Bioaugmentation as a Tool To Protect the Structure and Function of an Activated-Sludge Microbial Community against a 3-Chloroaniline Shock Load." Applied and Environmental Microbiology 69, no. 3 (2003): 1511–20. http://dx.doi.org/10.1128/aem.69.3.1511-1520.2003.

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ABSTRACT Bioaugmentation of bioreactors focuses on the removal of xenobiotics, with little attention typically paid to the recovery of disrupted reactor functions such as ammonium-nitrogen removal. Chloroanilines are widely used in industry as a precursor to a variety of products and are occasionally released into wastewater streams. This work evaluated the effects on activated-sludge reactor functions of a 3-chloroaniline (3-CA) pulse and bioaugmentation by inoculation with the 3-CA-degrading strain Comamonas testosteroni I2 gfp. Changes in functions such as nitrification, carbon removal, and

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Akdag, Abdurrahman, Gul Ozyilmaz, and Ali Tuncay Ozyilmaz. "Poly(2-chloroaniline) and poly(aniline-co-2-chloroaniline) films on ZnFe alloy plating." Anti-Corrosion Methods and Materials 65, no. 6 (2018): 580–86. http://dx.doi.org/10.1108/acmm-04-2018-1922.

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Purpose The purpose of this paper is to evaluate and compare the protective, anticorrosion behaviors and electrochemically synthesis of poly(2-chloroaniline) (PCANI) and poly(2-chloroaniline-co-aniline) P(CANI-co-ANI) films on thin zinc–iron plated carbon steel (CS). Design/methodology/approach Zinc–iron (ZnFe) alloy plating was successfully achieved on CS applying 3 mA constant current value. The PCANI and P(CANI-co-ANI) films on ZnFe-plated CS electrode were synthesized by cyclic voltammetry technique using monomer(s) containing 0.20 M sodium oxalate solution. The CS/ZnFe electrodes with and

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Falk, Michael W., Hari Seshan, Carlos Dosoretz, and Stefan Wuertz. "Partial bioaugmentation to remove 3-chloroaniline slows bacterial species turnover rate in bioreactors." Water Research 47, no. 19 (2013): 7109–19. http://dx.doi.org/10.1016/j.watres.2013.08.040.

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Duc, Ha Danh. "Biodegradation of 3-chloroaniline by suspended cells and biofilm of Acinetobacter baumannii GFJ1." Applied Biological Chemistry 59, no. 5 (2016): 703–9. http://dx.doi.org/10.1007/s13765-016-0216-1.

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Angeloff, Ariane, Jean-Jacques Brunet, Pierre Legars, Denis Neibecker, and Denis Souyri. "ChemInform Abstract: Regioselective Dechlorination of 2,3-Dichloronitrobenzene into 3-Chloronitrobenzene and Regioselective Dechlorination-Hydrogenation into 3-Chloroaniline." ChemInform 32, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.200127082.

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Boon, Nico, Johan Goris, Paul De Vos, Willy Verstraete, and Eva M. Top. "Bioaugmentation of Activated Sludge by an Indigenous 3-Chloroaniline-Degrading Comamonas testosteroni Strain, I2gfp." Applied and Environmental Microbiology 66, no. 7 (2000): 2906–13. http://dx.doi.org/10.1128/aem.66.7.2906-2913.2000.

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ABSTRACT A strain identified as Comamonas testosteroni I2 was isolated from activated sludge and found to be able to mineralize 3-chloroaniline (3-CA). During the mineralization, a yellow intermediate accumulated temporarily, due to the distalmeta-cleavage of chlorocatechol. This strain was tested for its ability to clean wastewater containing 3-CA upon inoculation into activated sludge. To monitor its survival, the strain was chromosomally marked with the gfp gene and designated I2gfp. After inoculation into a lab-scale semicontinuous activated-sludge (SCAS) system, the inoculated strain main

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Hinteregger, Christel, Michael Loidl, and Franz Streichsbier. "Characterization of isofunctional ring-cleaving enzymes in aniline and 3-chloroaniline degradation byPseudomonas acidovoransCA28." FEMS Microbiology Letters 97, no. 3 (1992): 261–66. http://dx.doi.org/10.1111/j.1574-6968.1992.tb05473.x.

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Boon, Nico, Leen De Gelder, Hanne Lievens, Steven D. Siciliano, Eva M. Top, and Willy Verstraete. "Bioaugmenting Bioreactors for the Continuous Removal of 3-Chloroaniline by a Slow Release Approach." Environmental Science & Technology 36, no. 21 (2002): 4698–704. http://dx.doi.org/10.1021/es020076q.

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Venkateswara Rao, P., L. Venkatramana, M. Gowrisankar, and K. Ravindranath. "Volumetric, acoustic and spectroscopic properties of 3-chloroaniline with substituted ethanols at various temperatures." Journal of Chemical Thermodynamics 94 (March 2016): 186–96. http://dx.doi.org/10.1016/j.jct.2015.11.012.

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Hinteregger, Christel, Andreas Ferschl, Michael Loidl, and Franz Streichsbier. "Metabolism of aniline and 3-chloroaniline inPseudomonas acidovorans CA28: Evidence of isofunctional muconate cycloisomerases." Journal of Basic Microbiology 33, no. 5 (1993): 301–9. http://dx.doi.org/10.1002/jobm.3620330504.

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Ademidun, Adeola ADESIBIKAN, and Sunday EMMANUEL Stephen. "Synthesis and Characterization of Co (ii) Complex with a Schiff Base Ligand Derived from Salicylaldehyde and 4-chloroaniline." International Journal of Novel Research in Physics Chemistry & Mathematics 10, no. 2 (2023): 12–17. https://doi.org/10.5281/zenodo.8023058.

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<strong>Abstract:</strong> This article presents synthesis of novel Schiff base ligand from N-salicylidene-p-chloroaniline and its Co (II) complex in ratio 1:2 metal-ligands. The complex formed was subjected to elemental analysis and spectroscopic studies (ultraviolet spectroscopy and infra-red spectroscopy) alongside melting point evaluation. From the infrared spectroscopy of the complex, an octahedral arrangement of the ligand around cobalt atom is proposed. The complex formed showed the stability at an ambient condition and it was soluble in most organic solvents. <strong>Keywords:</strong>

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P., Muralidhar Reddy, Shanker K., Usha Rani P., Krishna Rao B., and Ravinder V. "Spectral and catalytic hydrogenation studies of RuII organometallics containing substituted tertiary phosphines." Journal of Indian Chemical Society Vol. 84, May 2007 (2007): 411–17. https://doi.org/10.5281/zenodo.5819446.

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Department of Chemistry, Kakatiya University, Warangal-506 009, Andhra Pradesh, India <em>E-mail </em>: ravichemku@rediffmail.com <em>Manuscript received 6 March 2007, accepted 14 March 2007</em> The reaction of (RuCI<sub>2</sub>(COD)<sub>2</sub>] with acetylacetone (acac)/Na<sub>2</sub>CO<sub>3</sub> in the presence of dimethylformamide produces the precursor, (Ru(acac)<sub>2</sub>(COD)]. Using this precursor two series of organometallics were prepared by adopting different experimental conditions. The first series of Ru<sup>II</sup> organomctallics with the formula [Ru(acac)<sub>2</sub>L<sub

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