Academic literature on the topic '4-cyanopyridine'

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Journal articles on the topic "4-cyanopyridine"

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K., C. MALHOTRA, BALA NEERAJ SHARMA BRIJ, S. BHATI S., and CHAUDHRY S.C. "Adducts of 4-t-Butylphenoxo Complexes of Oxovanadium(v) with 2-, 3- and 4-Cyanopyridines." Journal of Indian Chemical Society Vol. 75, Mar 1998 (1998): 137–39. https://doi.org/10.5281/zenodo.5915570.

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Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla-171 005 <em>Manuscript received 27 May 1996, revised 14 March 1997, accepted 16 May 1997</em> 4-t-Butylphenoxo-complexes of oxovanadium(v) of composition <strong>VOCl<sub>3-x</sub>(OC<sub>6</sub>H<sub>4</sub>Bu<sup>t</sup>-4)<sub>x</sub></strong>, where x = 1 &rarr; 3, react with 2-, 3- and 4- cyanopyridines to give adducts of varying composition. 2-Cyanopyridine forms adduct of 1 : 1 composition, coordinating simultaneously through pyridine as well as nitrile nitrogens of the ligand, while 3- and 4-cyanopyridines forms
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Marchalín, Štefan, and Josef Kuthan. "Cyclocondensation reactions of 3-aryl-2-benzylidene-3-oxopropanenitriles with acetylaromatic derivatives." Collection of Czechoslovak Chemical Communications 50, no. 8 (1985): 1862–69. http://dx.doi.org/10.1135/cccc19851862.

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Cyclocondensation of 3-aryl-2-benzylidene-3-oxopropanenitriles Ia and Ib with acetyl aromatic derivatives IIa-IIc in the presence of ammonium acetate affords 2,6-diaryl-4-phenyl-3-cyanopyridines IV and V. Reaction of the nitrile Ib with 1,2-diphenylethanone (III) gave 2-(4-biphenylyl)-4,5,6-triphenyl-3-cyanopyridine (VI). The relation between the structure of the synthesized pyridine derivatives IV-VI and their spectral properties is discussed.
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Jochim, Aleksej, Inke Jess, and Christian Näther. "Structural diversity in Cd(NCS)2-3-cyanopyridine coordination compounds: synthesis, crystal structures and thermal properties." Zeitschrift für Naturforschung B 75, no. 1-2 (2020): 163–72. http://dx.doi.org/10.1515/znb-2019-0175.

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AbstractFive new compounds with the compositions [Cd(NCS)2(3-cyanopyridine)2]n · 3-cyanopyridine (1), [Cd(NCS)2(3-cyanopyridine)2]n · 1/3 3-cyanopyridine (2), [Cd(NCS)2(3-cyanopyridine)2]n (3), {[Cd(NCS)2]2(3-cyanopyridine)3}n (4), and {[Cd(NCS)2]3(3-cyanopyridine)4}n (5) have been obtained by the reaction of Cd(NCS)2 with 3-cyanopyridine in different solvents. While large amounts of compounds 1–4 could be prepared as powders, only a few single crystals of 5 were accidently obtained. Thermoanalytical investigations have shown that 4 could also be obtained by annealing of 1 or 2 and that under
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Zhang, Min, Dong Peng, Feifei Peng, et al. "Effects of Additives Containing Cyanopyridine on Electrodeposition of Bright Al Coatings from AlCl3-EMIC Ionic Liquids." Coatings 11, no. 11 (2021): 1396. http://dx.doi.org/10.3390/coatings11111396.

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The Al coatings were electrodeposited on the Cu substrate from AlCl3-EMIC ionic liquid (AlCl3:EMIC = 2:1 molar ratio) containing three cyanopyridine additives with different positions of the substituent group on the pyridine ring, which were 2-cyanopyridine, 3-cyanopyridine, and 4-cyanopyridine. The effects of cyanopyridine additives on the deposition potential, morphology, brightness, and corrosion properties of Al coatings were investigated. It was considered that the deposition potential of Al shifted to more negative overpotentials, the quality of Al coatings was promoted, and the corrosio
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Fu, Jie, Haoming Ren, Chaojun Shi, and Xiuyang Lu. "Hydrolysis kinetics of 2-cyanopyridine, 3-cyanopyridine, and 4-cyanopyridine in high-temperature water." International Journal of Chemical Kinetics 44, no. 9 (2012): 641–48. http://dx.doi.org/10.1002/kin.20707.

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Riedel, Sophie, Erica Brendler, Robert Gericke, Edwin Kroke, and Jörg Wagler. "Cyanopyridine adducts of SiF4 and SiCl4." Zeitschrift für Naturforschung B 79, no. 12 (2024): 675–85. https://doi.org/10.1515/znb-2024-0085.

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Abstract The formation of cyanopyridine (CN-py) adducts of silicon tetrahalides was investigated for 3- and 4-cyanopyridine in combination with SiF4 and SiCl4. Whereas bubbling of SiF4 through toluene solutions of 3-CN-py and 4-CN-py afforded white precipitates, which should possess the respective composition SiF4(CN-py)2, addition of SiCl4 did not cause any precipitation. Upon storage of the toluene solution of SiCl4 and 4-CN-py at 6 °C for several weeks, some crystals of the composition SiCl4(4-CN-py)2 ⋅ 2 (4-CN-py) ⋅ (toluene) were obtained. The use of SiCl4 as the solvent (i.e. SiCl4 in la
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Nasri, Soumaya, Nesrine Amiri, Ilona Turowska-Tyrk, Jean-Claude Daran та Habib Nasri. "Crystal structure of (4-cyanopyridine-κN){5,10,15,20-tetrakis[4-(benzoyloxy)phenyl]porphyrinato-κ4N}zinc–4-cyanopyridine (1/1)". Acta Crystallographica Section E Crystallographic Communications 72, № 2 (2016): 164–69. http://dx.doi.org/10.1107/s2056989016000062.

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In the title compound, [Zn(C72H44N4O8)(C6H4N2)]·C6H4N2or [Zn(TPBP)(4-CNpy]·(4-CNpy) [where TPBP and 4-CNpy are 5,10,15,20-(tetraphenylbenzoate)porphyrinate and 4-cyanopyridine, respectively], the ZnIIcation is chelated by four pyrrole-N atoms of the porphyrinate anion and coordinated by a pyridyl-N atom of the 4-CNpy axial ligand in a distorted square-pyramidal geometry. The average Zn—N(pyrrole) bond length is 2.060 (6) Å and the Zn—N(4-CNpy) bond length is 2.159 (2) Å. The zinc cation is displaced by 0.319 (1) Å from the N4C20mean plane of the porphyrinate anion toward the 4-cyanopyridine ax
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Topaçh, Arzu, and Sevgi Bayari. "Molecular Force Field of 4-Cyanopyridine and its Application to 4-Cyanopyridine Metal Complexes." Spectroscopy Letters 29, no. 2 (1996): 277–91. http://dx.doi.org/10.1080/00387019608001602.

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Jochim, Aleksej, Inke Jess та Christian Näther. "Crystal structure of diaquabis(4-cyanopyridine-κN)bis(thiocyanato-κN)iron(II) 4-cyanopyridine disolvate". Acta Crystallographica Section E Crystallographic Communications 73, № 4 (2017): 463–66. http://dx.doi.org/10.1107/s205698901700322x.

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The asymmetric unit of the title compound, [Fe(NCS)2(C6H4N2)2(H2O)2]·2C6H4N2, comprises one FeIIcation occupying an inversion centre as well as one thiocyanate anion, one water molecule and two 4-cyanopyridine molecules in general positions. The iron cations are coordinated by two N-bonded thiocyanate anions, two (pyridine)N-bonded 4-cyanopyridine ligands and two water molecules into discrete complexes. The resulting coordination polyhedron can be described as a slightly distorted octahedron. The discrete complexes are connected through centrosymmetric pairs of (pyridine)C—H...N(cyano) hydroge
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Näther, Christian, Asmus Müller-Meinhard, and Inke Jess. "Synthesis, crystal structure and properties of tetrakis(pyridine-3-carbonitrile)dithiocyanatoiron(II) and of diaquabis(pyridine-3-carbonitrile)dithiocyanatoiron(II) pyridine-3-carbonitrile monosolvate." Acta Crystallographica Section E Crystallographic Communications 79, no. 11 (2023): 1093–99. http://dx.doi.org/10.1107/s205698902300909x.

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The reaction of iron thiocyanate with 3-cyanopyridine (C6H4N2) leads to the formation of two compounds with the composition [Fe(NCS)2(C6H4N2)4] (1) and [Fe(NCS)2(C6H4N2)2(H2O)2]·2C6H4N2 (2). The asymmetric unit of 1 consists of one iron cation, two thiocyanate anions and four 3-cyanopyridine ligands in general positions. The iron cation is octahedrally coordinated by two N-bonded thiocyanate anions and four 3-cyanopyridine ligands. The complexes are arranged in columns along the crystallographic c-axis direction and are linked by weak C—H...N interactions. In 2, the asymmetric unit consists of
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Dissertations / Theses on the topic "4-cyanopyridine"

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PLUCHERY, OLIVIER. "Etude par spectroscopie non lineaire sfg et dfg de l'adsorption de la 4-cyanopyridine sur des electrodes d'or." Paris 11, 2000. http://www.theses.fr/2000PA112193.

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Les spectroscopies non lineaires par somme ou difference de frequence (sfg et dfg respectivement) sont utilisees pour etudier l'adsorption in situ de la 4-cyanopyridine sur une electrode d'or au(111). En focalisant deux faisceaux laser de pulsations 1 et 2 sur l'interface a etudier, un signal sfg ( s f g = 1 + 2) ou dfg ( d f g = 1 2) est obtenu. Pour interpreter les donnees experimentales, deux niveaux de modelisations physiques sont examines suivant que l'on souhaite analyser la signature vibrationnelles des adsorbats ou affiner la description des contributions des electrons du metal. Grace
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Wang, Hsiaowen, and 王筱文. "The Investigation of 4-cyanopyridine Bridged Binuclear Complex of Isonicotinamidetetraammineruthenium and Petacyanoferrate." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/63829478977201230457.

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碩士<br>東海大學<br>化學系<br>99<br>The binuclear complex trans-[(isn)(NH3)4Ru(4-NCpy)Fe(CN)5]- was prepared by mixing equimolar of trans-[Ru(NH3)4(isn)(4-NCpy)]2+ and [Fe(CN)5NH3]3- at pH=5 aqueous solution. The mixed valence complex trans-[(isn)(NH3)4Ru(4-NCpy)Fe(CN)5] was obtained by oxidation of trans-[(isn)(NH3)4Ru(4-NCpy)Fe(CN)5]- with one equivalent of peroxy disulfate. The results of UV-vis, infrared and electrochemical studies all suggested that the mixed valence species featured valence-trapped localized system with Ru(II)、Fe(III) oxidation states. The cyclic voltammogram of binuclear comp
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Lin, Xue-Ming, and 林學明. "Novel Synthesis and Mesophase Studies of a series of 2-(4-Alkoxybiphenyl-4’-yl)-5-cyanopyridine." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/ke35p5.

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碩士<br>輔仁大學<br>化學系<br>100<br>This study describes the facile synthesis of a homologous of pyridine-containing liquid crystalline 2-(4-Alkoxybiphenyl-4’-yl)-5-cyanopyridine(nO-PPPyCN, n=2-8). The subject liquid crystals were prepard in a short two-step reaction. First, 4-alkyloxybiphenylmagnesium bromides were added to N-phrnyloxycarbonyl-3-cyanopyridine,affording a dihydropyridine, which was then oxidized by o-chloranil. The resulting products,2-(4-Alkoxybiphenyl-4’-yl)-5-cyanopyridine, were obtained in fair yield(32%~68%). Thermotropic behaviors of these liquid crystals were investigated using
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Lu, Ru Sung, and 呂汝松. "Novel synthesis and mesophase studies on a series of 2-(4-alkylphenyl)-5-cyanopyridine." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/34261275873530046046.

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碩士<br>輔仁大學<br>化學系<br>93<br>This study describes a facile synthesis on a series of pyridine-containing liquid crystalline compounds, 2-(4’-alkylphenyl)-5-cyanopyridines. Preparation of these subject liquid crystals were completed in a sort two-step reactions, the addition of 4-alkylphenylmagnesium bromides to N-phenyloxycarbonyl-3-cyanopyridinium chloride afford a 1,2-dihydropyridine, which was then oxidized by o-chloronil. The resulted products, 2-(4’-alkylphenyl)-5-cyanopyridines, were obtained in good yields.
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Cheng, Yu-Wei, and 鄭有為. "Novel Synthesis and Mesophase Studies of A Series of 2-(4-Alkoxyphenyl)-5-cyanopyridines." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/92973702533516650411.

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碩士<br>輔仁大學<br>化學系<br>94<br>This study describes a facile synthesis on a series of pyridine-containing liquid crystalline compounds, 2-(4’-alkoxyphenyl)-5-cyanopyridines. Preparation of these subject liquid crystals was completed in a sort two-step reactions, the addition of 4-alkoxyphenylmagnesium bromides to N-phenyloxycarbonyl-3-cyanopyridinium chloride afford a 1,2-dihydropyridine, which was then oxidized by o-chloronil. The resulted products, 2-(4’-alkoxyphenyl)-5-cyanopyridines, were obtained in good yields.
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Book chapters on the topic "4-cyanopyridine"

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of heterobimetallic Mn(II)-Ag(I) coordination polymer having 4-cyanopyridine ligand." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 7. Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-65895-6_73.

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Conference papers on the topic "4-cyanopyridine"

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Dorman, P., Robert McMahon, R. Woods, and Brian Esselman. "BRIEF SUMMARY OF THE MILLIMETER-WAVE ROTATIONAL SPECTRA OF 2-, 3-, AND 4-CYANOPYRIDINE: THEIR VIBRATIONAL GROUND STATES AND THE CORIOLIS-COUPLED DYADS OF THEIR LOWEST-ENERGY VIBRATIONALLY EXCITED STATES." In 2020 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2020. http://dx.doi.org/10.15278/isms.2020.rj08.

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Dorman, P., Robert McMahon, R. Woods, and Brian Esselman. "BRIEF SUMMARY OF THE MILLIMETER-WAVE ROTATIONAL SPECTRA OF 2-, 3-, AND 4-CYANOPYRIDINE: THEIR VIBRATIONAL GROUND STATES AND THE CORIOLIS-COUPLED DYADS OF THEIR LOWEST-ENERGY VIBRATIONALLY EXCITED STATES." In 2021 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2021. http://dx.doi.org/10.15278/isms.2021.te02.

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