Academic literature on the topic '5-dioxepan-2-one'

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Journal articles on the topic "5-dioxepan-2-one"

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Kafrawy, Adel, Dennis D. Jamiolkowski, and Shalaby W. Shalaby. "Radiation Sterilizable Bioabsorbable Monofilaments Based on Copolymers of Glycolide and 1, 5-Dioxepan-2-One." Journal of Bioactive and Compatible Polymers 2, no. 4 (1987): 305–11. http://dx.doi.org/10.1177/088391158700200402.

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Xu, Jinbao, Yang Chen, Wenhao Xiao, et al. "Studying the Ring-Opening Polymerization of 1,5-Dioxepan-2-one with Organocatalysts." Polymers 11, no. 10 (2019): 1642. http://dx.doi.org/10.3390/polym11101642.

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Three different organocatalysts, namely, 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris (dimethylamino) phosphoranylidenamino]-2Λ5,4Λ5-catenadi(phosphazene) (t-BuP4), 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), have been used as 1,5-dioxepan-2-one (DXO) ring-opening polymerization (ROP) catalysts at varied reaction conditions. 1H NMR spectra, size exclusion chromatography (SEC) characterizations, and kinetic studies prove that the (co)polymerizations are proceeded in a controlled manner with the three organocatalysts. It is deduced that t-BuP4 a
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Edlund, Ulrica, and Ann-Christine Albertsson. "Morphology engineering of a novel poly(L-lactide)/poly(1,5-dioxepan-2-one) microsphere system for controlled drug delivery." Journal of Polymer Science Part A: Polymer Chemistry 38, no. 5 (2000): 786–96. http://dx.doi.org/10.1002/(sici)1099-0518(20000301)38:5<786::aid-pola2>3.0.co;2-7.

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Dissertations / Theses on the topic "5-dioxepan-2-one"

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Srivastava, Rajiv. "Novel methods to synthesize aliphatic polyesters of vivid architectures." Licentiate thesis, KTH, Fibre and Polymer Technology, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-511.

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<p>Cross-linked films of ε-caprolactone (CL) and 1,5-dioxepan-2-one (DXO) having various mole fractions of monomers and different cross-link densities were prepared using 2,2’-bis-(-caprolactone-4-yl) propane (BCP) as cross-linking agent and Sn(Oct)2 as catalyst. Reaction parameters were examined to optimize the film-forming conditions. Networks obtained were elastomeric materials, easy to cast and remove from the mould. Effect of CL content and cross-link density on the final properties of the polymer network was evaluated. Thermal, mechanical and surface properties of the films were control
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Höglund, Anders. "Controllable degradation product migration from biomedical polyester-ethers." Licentiate thesis, KTH, Fibre and Polymer Technology, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4366.

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<p>The use of degradable biomedical materials has during the past decades indeed modernized medical science, finding applications in e.g. tissue engineering and drug delivery. The key question is to adapt the material with respect to mechanical properties, surface characteristics and degradation profile to suit the specific application. Degradation products are generally considered non-toxic and they are excreted from the human body. However, large amounts of hydroxy acids may induce a pH decrease and a subsequent inflammatory response at the implantation site.</p><p>In this study, macromolecu
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Finne, Anna. "Novel Possibilities for Advanced Molecular Structure Design for Polymers and Networks." Doctoral thesis, KTH, Polymerteknologi, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3623.

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Synthetic and degradable polymers are an attractive choicein many areas, since it is possible to control the way in whichthey are manufactured; more specifically, pathways tomanipulate the architecture, the mechanical properties and thedegradation times have been identified. In this work,L-lactide, 1,5-dioxepan-2-one and ε-caprolactone were usedas monomers to synthesize polymers with different architecturesby ring-opening polymerization. By using novel initiators,triblock copolymers, functionalized linear macromonomers andstar-shaped aliphatic polyesters with well-defined structureshave been s
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