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1

Hensena, Karl, Markus Kettner, Thorsten Stumpf, and Michael Bolte. "Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines." Zeitschrift für Naturforschung B 55, no. 10 (2000): 901–6. http://dx.doi.org/10.1515/znb-2000-1003.

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Abstract Trichlorosilane, HSiCl3, forms with 3,4-dimethylpyridine in aprotic solvents a crystalline l:2-compound which is stable at room temperature and readily soluble in CHCl3. Colourless crystals of the dicationic complex, [H2Si(3,4-dimethylpyridine)4]2+ 2Cl- · 6 CHCl3 (verified by X-ray structure analysis) are obtained by dismutation of HSiCl3(3,4-dimethylpyridine)2 in CHCl3 within one week at room temperature.29Si NM R indicates that SiCl4 is generated as a second product. H2SiCl2 with 2,4-dimethylpyridine as well as MeHSiBr2 with 3,5-dimethylpyridine in aprotic solvents form 1:2-compound
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2

Döring, Cindy, and Peter G. Jones. "Crystal structures of seven gold(III) complexes of the form LAuX 3 (L = substituted pyridine, X = Cl or Br)." Acta Crystallographica Section E Crystallographic Communications 80, no. 8 (2024): 894–909. http://dx.doi.org/10.1107/s2056989024007266.

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The structures of seven gold(III) halide derivatives of general formula LAuX 3 (L = methylpyridines or dimethylpyridines, X = Cl or Br) are presented: trichlorido(2-methylpyridine)gold(III), [AuCl3(C6H7N)], 1 (as two polymorphs 1a and 1b); tribromido(2-methylpyridine)gold(III), [AuBr3(C6H7N)], 2; tribromido(3-methylpyridine)gold(III), [AuBr3(C6H7N)], 3; tribromido(2,4-dimethylpyridine)gold(III), [AuBr3(C7H9N)], 4; trichlorido(3,5-dimethylpyridine)gold(III), [AuCl3(C7H9N)], 5; tribromido(3,5-dimethylpyridine)gold(III), [AuBr3(C7H9N)], 6, and trichlorido(2,6-dimethylpyridine)gold(III), [AuCl3(C7
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3

Khasaeva, Fatima M. "Utilisation of 2,6-dimethylpyridine by Arthrobacter sp." International Journal of Nanobiotechnology and Pharmacy, no. 1 (July 30, 2015): 19–22. https://doi.org/10.5281/zenodo.29598.

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4

Igor, A. Parshikov, I. Zaraisky Evgeny, and M. Khasaeva Fatima. "Degradation of 2,6-dimethylpyridine by Arthrobacter crystallopoietes." Ecology, Environment and Conservation 22, no. 4 (2017): 1673–76. https://doi.org/10.5281/zenodo.1157087.

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Degradation of pyridines in waste water is an important issue for chemical and pharmaceutical industries. The biodegradation of 2,6-dimethylpyridine was investigated by the bacterium Arthrobacter crystallopoietes KM-4, which resulted in the formation of three metabolites: 2,6-dimethylpyridin-3-ol, 2,6-dimethylpyridin-3,4-diol, and 2,4-dioxopentanoic acid.
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5

Abdel-Hafez, Shams H., Ragaa A. Ahmed, Mohamed A. Abdel-Azim, and Khairy M. Hassan. "Selenium containing Heterocycles: Part 1. Synthesis of Some New Substituted Pyrido[3′,2′:4,5]selenolo[3,2-d]pyrimidines and Related Fused Tetracyclic Systems." Journal of Chemical Research 2007, no. 10 (2007): 580–84. http://dx.doi.org/10.3184/030823407x25506.

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New series of selenolo[2,3- b]pyridine, pyrido[3′,2′:4,5]selenolo[3,2- d]pyrimidine, 7,8-dihydro-2,4-dimethylpyrrolo [1,2- a]pyrido[3′,2′:4,5]selenolo[3,2- d]pyrimidin-10(6 H)-one and 7,9-dimethylpyrido[3′,2′:4,5]selenolo[3,2- d][1,2,4] triazolo[4,3- c]pyrimidine derivatives were synthesised from 3-cyano-4,6-dimethylpyridine-2(1 H)-selenone (1). Spectroscopic (IR, 1H, MS) of the newly synthesised compounds are reported.
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6

Su, Biyun, Jianshe Zhao, Yong Cui, Yongqing Liang, and Wenhua Sun. "Controlled Synthesis of 2‐Acetyl‐6‐carbethoxypyridine and 2,6‐Diacetylpyridine from 2,6‐Dimethylpyridine." Synthetic Communications 35, no. 17 (2005): 2317–24. http://dx.doi.org/10.1080/00397910500186995.

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7

Tsygankova, VA, YaV Andrusevich, NM Vasylenko, et al. "The Use of Thioxopyrimidine Derivatives as New Regulators of Growth and Photosynthesis of Barley." Journal of Plant Science and Phytopathology 8, no. 2 (2024): 090–99. http://dx.doi.org/10.29328/journal.jpsp.1001139.

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New synthetic compounds - thioxopyrimidine derivatives as regulators of vegetative growth and photosynthesis of spring barley (Hordeum vulgare L.) variety Acordine were studied. The growth-regulatory effect of new synthetic compounds, thioxopyrimidine derivatives, used in a concentration of 10-6M, was compared with the growth-regulatory effect of a plant hormone auxin IAA (1H-indol-3-yl)acetic acid) or synthetic plant growth regulators, derivatives of sodium and potassium salts of 6-methyl-2-mercapto-4-hydroxypyrimidine (Methyur, Kamethur), N-oxide-2,6-dimethylpyridine (Ivin), used in a simila
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8

Dakhno, P. G., V. K. Kindop, K. V. Gordeev, et al. "Oxidation of 4,6-dimethyl-2-thioxo-1,2-dihydropyridine3-carbonitriles with potassium hexacyanoferrate(III): synthesis and molecular docking of bis(pyrid-2-yl)disulfides." Журнал общей химии 93, no. 12 (2023): 1833–45. http://dx.doi.org/10.31857/s0044460x2312003x.

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The reaction of 4,6-dimethyl-2-thioxo-1,2-dihydropyridin-3-carbonitriles with K3[Fe(CN)6] in an alkaline medium led to the formation of a mixture of oxidation products: bis(3-cyanopyridin-2-yl)disulfides and potassium 3-cyano-4,6-dimethylpyridine-2-sulfonates. Structure of the compounds was confirmed by NMR, IR spectroscopy and high-resolution mass spectrometry data. According to the results of molecular docking, 2,2′-dithiobis(5-butyl-4,6-dimethylnicotinonitrile) exhibits affinity for the zinc finger binding site of the HIV-1 p7 nucleocapsid protein.
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9

Lyczko, Krzysztof, Monika Lyczko, Sylwia Meczynska-Wielgosz, Marcin Kruszewski, and Józef Mieczkowski. "Tricarbonylrhenium(I) complexes with the N,6-dimethylpyridine-2-carbothioamide ligand: combined experimental and calculation studies." Journal of Coordination Chemistry 71, no. 14 (2018): 2146–64. http://dx.doi.org/10.1080/00958972.2018.1476686.

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10

Wucherer, Edward J., and Earl L. Muetterties. "Synthesis of bis(.eta.6-2,6-dimethylpyridine)metal complexes of titanium, molybdenum, and vanadium by metal vapor deposition. Spectral properties of bis(.eta.6-2,6-dimethylpyridine)metal complexes of chromium, titanium, vanadium, molybdenum, and chromium(1+)." Organometallics 6, no. 8 (1987): 1691–95. http://dx.doi.org/10.1021/om00151a014.

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11

Wucherer, Edward J., and Earl L. Muetterties. "Low-temperature x-ray diffraction studies of bis(.eta.6-2,6-dimethylpyridine)titanium, -vanadium, and -chromium(I)." Organometallics 6, no. 8 (1987): 1696–702. http://dx.doi.org/10.1021/om00151a015.

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12

Dyason, JC, LM Engelhardt, PC Healy, JD Kildea, and AH White. "Lewis-Base Adducts of Group 11 Metal-Compounds. XXXIII. Structural Characterization of Two Novel 'Trigonal Planar' Halobis(N-Base)Copper(I) Complexes." Australian Journal of Chemistry 41, no. 3 (1988): 335. http://dx.doi.org/10.1071/ch9880335.

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Single-crystal X-ray structure determinations are recorded for two unusual trigonal planar XCuL2 species, X = halogen, L = monodentate N- base. For iodobis (2-methylquinoline)copper(I) (1) crystals are orthorhombic, P212121, a 15.079(7), b 12.592(7), c 9.585(4)Ǻ, Z 4. R was 0.028 for 1285 independent 'observed' reflections; the copper(I) environment is trigonal planar [I-Cu, 2.533(2); Cu-N, 2.034(6), 2.0l5(7)Ǻ; I-Cu-N are 119.1(2), 120.4(2) and N-Cu-N, 120.4(2)°]. For the mixed base complex bromo (3,5-dimethylpyridine)(2,4,6-trimethylpyridine )copper(I) (2), crystals are triclinic, pī , a 13.6
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13

Bowmaker, Graham A., Effendy, John D. Kildea, and Allan H. White. "Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXVII Synthesis, Spectroscopy and Structural Systematics of Some 1 : 3 Adducts of Silver(I) Compounds with Triphenylarsine, [(Ph3As)3AgX], X = Cl, Br, I, SCN." Australian Journal of Chemistry 50, no. 6 (1997): 577. http://dx.doi.org/10.1071/c96034.

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The syntheses and room-temperature single-crystal X-ray structure determination of 1 : 3 adducts formed between silver(I) (pseudo-)halides, AgX, and triphenylarsine, AsPh3, are described (X = Cl, Br, I, SCN), [(Ph3As)3AgX], (1)–(4). The chloride (1) has been previously described as its acetone hemisolvate; other solvates (1a–d) (0·75 MeCN, MeOH, 1·5 pyridine, 0·75 2,6-dimethylpyridine) are isomorphous, being triclinic, P-1, a ≈ 13·5, b ≈ 14·0, c ≈ 14·25 Å, α ≈ 83, β ≈ 87, γ ≈ 76°, V ≈ 2600 Å3, Z = 2 f.u. The bromide (2), iodide (3) and thiocyanate (4) are isomorphous with [(Ph3P)3AgI], monocli
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14

Świątek, Piotr, Teresa Glomb, Benita Wiatrak, et al. "New 1,2,4-Triazole Derivatives with a N-Mannich Base Structure Based on a 4,6-Dimethylpyridine Scaffold as Anticancer Agents: Design, Synthesis, Biological Evaluation, and Molecular Modeling." International Journal of Molecular Sciences 26, no. 14 (2025): 6572. https://doi.org/10.3390/ijms26146572.

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A series of novel N-Mannich bases derived from a dimethylpyridine–1,2,4-triazole hybrid was synthesized and evaluated in vitro for cytotoxic activity on several human gastrointestinal cancer cells (EPG, Caco-2, LoVo, LoVo/Dx, and HT-29). Compound 6 bearing a phenyl group at the N-4 position and a 4-methylphenyl piperazine moiety at the N-2 position of the 1,2,4-triazole-3-thione scaffold exerted good cytotoxic activities on EPG and Caco-2 cell lines, along with pronounced selectivity, showing lower cytotoxicity against normal colonic epithelial cells (CCD 841 CoTr). Further evaluation revealed
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15

Tsygankova, V., V. Kopich, I. Voloshchuk, S. Pilyo, S. Klyuchko, and V. Brovarets. "NEW GROWTH REGULATORS OF BARLEY BASED ON PYRIMIDINE AND PYRIDINE DERIVATIVES." Sciences of Europe, no. 124 (September 8, 2023): 13–23. https://doi.org/10.5281/zenodo.8327852.

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This work is devoted to the screening for new effective plant growth regulators based on synthetic compounds, pyrimidine and pyridine derivatives. Study of the plant growth-regulating activity of synthetic compounds was carried out on spring barley (Hordeum vulgare L.) variety Avatar. The effect of synthetic compounds on the morphometric parameters of barley plants grown in laboratory conditions was studied. The plant growth-regulating activity of synthetic compounds was compared with the plant growth-regulating activity of phytohormones auxins IAA (1H-indol-3-yl)acetic acid) and NAA (1-naphth
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16

Bellucci, Cinzia, and Renzo Cini. "Synthesis and structural characterization of ruthenium(II) complexes with triphenylstibine, 1,9-dimethylpurine-6-thione, 3,5-dimethylpyridine and 1,4-pyrazine." Journal of Inorganic Biochemistry 76, no. 3-4 (1999): 243–50. http://dx.doi.org/10.1016/s0162-0134(99)00151-8.

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17

OKADA, Akiko, Yuko YAMAZAKI, Ayako GOTO, and Yasuhisa MIZUNOYA. "Polarography of 3, 5-Diacetyl-1, 4-dihydro-2, 6-dimethylpyridine and the Application to the Determination of Formaldehyde." YAKUGAKU ZASSHI 109, no. 8 (1989): 564–69. http://dx.doi.org/10.1248/yakushi1947.109.8_564.

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18

Dillinger, R., and G. Gliemann. "Polarized Low Temperature Luminescence of Single Crystal Pentacarbonylpyridinotungsten(0)-Complexes." Zeitschrift für Naturforschung A 41, no. 8 (1986): 1071–78. http://dx.doi.org/10.1515/zna-1986-0816.

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Polarized luminescence spectra of single crystal W (CO )5-X (with X = pyridine, 4-methylpyridine, 4-t-butylpyridine, 3,4-dimethylpyridine, 4-am inopyridine, 3-acetylpyridine, 3,5-dibromopyridine, 3-benzoylpyridine, 4-formylpyridine) at low temperatures (1.9 K≦ T ≦ 80 K) are reported.Depending on the nature of the pyridine substituent the emitting state is either a ligand field (LF) state or a metal to ligand charge transfer (CT) state. This results in drastic differences in both bandshape and temperature behaviour of the luminescence spectra. The CT-luminescence is structureless and is not inf
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19

Tsygankova, V.A, Ya.V Andrusevich, S. V. Klyuchko, et al. "Application of Pyrimidine and Pyridine Derivatives for Regulation of Chickpea (Cicer arietinum L.) Growth." International Journal of Innovative Science and Research Technology 8, no. 6 (2023): 19–28. https://doi.org/10.5281/zenodo.8020671.

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The effect of new synthetic pyrimidine derivatives on the growth and development of the chickpea (Cicer arietinum L.) variety Mexican was studied.The growth-regulating activity of pyrimidine derivatives was compared with the activity of phytohormones auxins, derivatives of 1H-indole-3-acetic acid (IAA) and 1-naphthylacetic acid (NAA), as well as plant growth regulators, derivatives of sodium and potassium salts of 6-methyl-2-mercapto-4- hydroxypyrimidine (Methyur and Kamethur), N-oxide2,6-dimethylpyridine (Ivin).The most biologically active synthetic compounds among pyrimidine derivatives were
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20

Yoshida, Toyokazu, Yuki Sada, and Toru Nagasawa. "Bioconversion of 2,6-dimethylpyridine to 6-methylpicolinic acid by Exophiala dermatitidis (Kano) de Hoog DA5501 cells grown on n-dodecane." Applied Microbiology and Biotechnology 86, no. 4 (2010): 1165–70. http://dx.doi.org/10.1007/s00253-009-2419-4.

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21

Graur, Ianina, Vasilii Graur, Marina Cadin, et al. "Synthesis and Characterization of Copper(II) and Nickel(II) Complexes with 3-(Morpholin-4-yl)propane-2,3-dione 4-Allylthiosemicarbazone Exploring the Antibacterial, Antifungal and Antiradical Properties." Molecules 29, no. 16 (2024): 3903. http://dx.doi.org/10.3390/molecules29163903.

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The eleven new copper(II) and nickel(II) coordination compounds [Cu(L)Br]2 (1), [Cu(L)Cl] (2), [Cu(L)NO3] (3), [Ni(L)Cl] (4), [Ni(HL)2](NO3)2 (5), and [Cu(A)(L)]NO3, where A is 1,10-phenanthroline (6), 2,2′-bipyridine (7), 3,4-dimethylpyridine (8), 3-methylpyridine (9), pyridine (10) and imidazole (11) were synthesized with 3-(morpholin-4-yl)propane-2,3-dione 4-allylthiosemicarbazone (HL). The new thiosemicarbazone was characterized by NMR and FTIR spectroscopy. All the coordination compounds were characterized by elemental analysis and FTIR spectroscopy. Also, the crystal structures of HL and
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22

Harvey, S., JD Kildea, BW Skelton, and AH White. "Lewis-Base Adducts of Main Group 1 Metal Compounds. XV. Adducts of Lithium(I) Perchlorate With o-Methyl-Substituted Monodentate Pyridine Bases of Increasing Bulk." Australian Journal of Chemistry 45, no. 7 (1992): 1135. http://dx.doi.org/10.1071/ch9921135.

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Whereas recrystallization of CuIClO4 from the progressively bulky pyridine bases (L) pyridine ( py ), 2-methylpyridine (2-mpy) and 2,6-dimethylpyridine (2,6-dmpy) yields adducts of progressively diminishing base stoichiometry , n = 4, 3, 2 (in [CuLn ](ClO4)), recrystallization of LiClO4 from the same bases yields adducts [Li( py )4](ClO4) and polymeric, perchlorate -bridged Li(2-mpy/2,6-dmpy)2 ClO4). The former is tetragonal, I4 a 12.479(5), c 7.009(8) � , Z 2, and isomorphous with the copper analogue; R was 0.057 for 324 'observed' reflections, and Li-N 2.O66(7)� [cf. Cu-N, 2.046(4) � ]. Li(2
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23

Dyason, JM, LM Engelhardt, PC Healy, and AH White. "Lewis-Base Adducts of Group-1B Metal(I) Compounds. XXIII. Synthesis and Structures of the 'Tris(3,5-Dimethylpyridine)Copper(I) Halides, [(C7H9N)3CuX], X = Cl, Br, I." Australian Journal of Chemistry 39, no. 7 (1986): 1043. http://dx.doi.org/10.1071/ch9861043.

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The crystal structures of the title compounds, (C7H9N)3CuX, X = Cl , Br, I [(1), (2), (3)], have been determined by single-crystal X-ray methods at 295 K, being refined to residuals of 0.022, 0.053, 0.047 for 151, 312, 720 independent 'observed' reflections respectively. The three structures containing 3,5-dimethylpyridine have an interesting relationship in symmetry: (1) is rhombohedral , R3m, a 9.050(3)Ǻ, α 110.89(3)°, Z 1; (2) is rhombohedral, R3c, a 10.328(5)Ǻ, α 95.60(4), Z 2; and (3), derived from (2), is monoclinic, Cc, a 13.233(6), b 15.083(7), c 11.491(6)Ǻ, β 98.27(4)°, Z 4. The dista
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24

V.A, Tsygankova, Voloshchuk I.V, Kopich V.M, Pilyo S.G, Klyuchko S. V, and Brovarets V.S. "And Kamethur on Growth And Productivity of Sunflowerstudying the Effect of Plant Growth Regulators Ivin, Methyur." JOURNAL OF ADVANCES IN AGRICULTURE 14 (June 17, 2023): 17–24. http://dx.doi.org/10.24297/jaa.v14i.9453.

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In field conditions, the effect of plant growth regulators Ivin (N-oxide-2,6-dimethylpyridine), Methyur (sodium salt of 6-methyl-2-mercapto-4-hydroxypyrimidine), Kamethur (potassium salt of 6-methyl-2-mercapto-4-hydroxypyrimidine) on growth and productivity of sunflower (Helianthus annuus L.) variety Bastion was studied. The growth-regulating activity of plant growth regulators Ivin, Methyur and Kamethur was compared with the growth-regulating activity of the auxin IAA (1H-Indol-3-yl)acetic acid). It was found that the treatment of seeds before planting in the soil with water solutions of Ivin
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25

Zhang, Daojun, Renchun Zhang, Jinping Li, Wanzhen Qiao, and Shuang Wang. "Two new 2D coordination polymers constructed from 2, 6-dimethylpyridine-3, 5-dicarboxylic acid ligands and alkaline earth metals (Sr and Ba)." Inorganic Chemistry Communications 35 (September 2013): 307–10. http://dx.doi.org/10.1016/j.inoche.2013.07.007.

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26

Abidov, I., and F. Hoshimov. "STUDY OF INTERACTIONS IN SYSTEMS CONSISTING OF N-OXY 2,6 DIMETHYLPYRIDINE, DIHYDROORTOPHOSPHATE AND AMMONIUM HYDROORTOPHOSPHATE." EURASIAN JOURNAL OF ACADEMIC RESEARCH 1, no. 3 (2021): 753–63. https://doi.org/10.5281/zenodo.5068379.

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<em>The article presents the results of studies on the interaction of N-hydroxy 2,6</em><em>-</em><em>dimethylpyridine introduced into the composition as a physiologically active substance with ammonium derivatives. The studied polytherms of the system are characterized by the presence of crystallization fields; triple points corresponding to certain compositions have been found. Isotherms are constructed on the basis of polythermal sections using interpolation.</em>
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27

Strzelecka, Małgorzata, Teresa Glomb, Małgorzata Drąg-Zalesińska, et al. "Synthesis, Anticancer Activity and Molecular Docking Studies of Novel N-Mannich Bases of 1,3,4-Oxadiazole Based on 4,6-Dimethylpyridine Scaffold." International Journal of Molecular Sciences 23, no. 19 (2022): 11173. http://dx.doi.org/10.3390/ijms231911173.

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Cancer is one of the greatest challenges in modern medicine today. Difficult and long-term treatment, the many side effects of the drugs used and the growing resistance to treatment of neoplastic cells necessitate new approaches to therapy. A very promising targeted therapy is based on direct impact only on cancer cells. As a continuation of our research on new biologically active molecules, we report herein the design, synthesis and anticancer evaluation of a new series of N-Mannich-base-type hybrid compounds containing morfoline or different substituted piperazines moieties, a 1,3,4-oxadiazo
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28

Nesmelov, A. I., V. B. Murachev, E. A. Ezhova, et al. "Cationic polymerization of hydrocarbon monomers induced by complexes of acyl halides with Lewis acids 6. The effect of 2,6-dimethylpyridine on the polymerization of isobutylene." Russian Chemical Bulletin 45, no. 5 (1996): 1120–23. http://dx.doi.org/10.1007/bf01431602.

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29

Rezaeifard, Abdolreza, Hossein Kavousi, Heidar Raissi, and Maasoumeh Jafarpour. "Significant hydrogen-bonding effect on the reactivity of high-valent manganese(V)–oxo porphyrins in C–H bond activation: A DFT study." Journal of Porphyrins and Phthalocyanines 19, no. 11 (2015): 1197–203. http://dx.doi.org/10.1142/s1088424615501035.

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The stereo electronic effects as well as hydrogen bonding effects of imidazole, pyridine and 2,6-dimethylpyridine as N-donor axial ligands on the C–H oxidation activity of high-valent manganese(V)–oxo meso-tetraphenylporphyrin (TPP) and meso-tetrakis(pentaflourophenyl)porphyrin (TPFPP), are investigated by DFT calculations. The electronic and steric properties of axial donors and porphyrin ligands affected on the activation energy of cyclohexane hydroxylation as well as the Mn–O bond strength of the oxo species in transition state. Imidazole with the strong [Formula: see text]-donating ability
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30

Inada, Y., Y. Tsutsui, H. Wasada, and S. Funahashi. "Solvation Structure of Solvated Cu(I) Ions in Non-Aqueous Solvents as Studied by EXAFS and ab initio Molecular Orbital Methods." Zeitschrift für Naturforschung B 54, no. 2 (1999): 193–99. http://dx.doi.org/10.1515/znb-1999-0207.

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The structure parameters around the Cu(I) ion in pyridine (PY), 4-methylpyridine (4MPY), 2-methylpyridine (2MPY), 2,6-dimethylpyridine (26DMPY), and acetonitrile (AN) were determined by the extended X-ray absorption fine structure (EXAFS) method. The solvation structures of the Cu(I) ion in PY, 4MPY, and AN are 4-coordinate tetrahedral with Cu-N bond lengths of 205, 205, and 200 pm, respectively. In the case of 2MPY and 26DMPY, the Cu(I) ion has a 3-coordinate triangular structure with a Cu-N bond length of 201 pm. Such a decrease in the coordination number was interpreted in terms of the bulk
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31

Tsygankova, V.A., A.M. Andreev, Ya.V. Andrusevich, et al. "USE OF IVIN, METHYUR, KAMETHUR AND MICROFERTILIZERS TO IMPROVE THE GROWTH OF OILSEED FLAX (LINUM USITATISSIMUM L.)." Annali d'Italia 48 (October 23, 2023): 3–7. https://doi.org/10.5281/zenodo.10034698.

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The article is devoted to the development of new environmentally friendly growth regulators of an important technical crop – oilseed flax (Linum usitatissimum L.) of the cultivar Iceberg based on synthetic compounds, derivatives of N-oxide-2,6-dimethylpyridine (Ivin), 6-methyl-2-mercapto-4-hydroxypyrimidine sodium and potassium salts (Methyur and Kamethur). The effect of synthetic plant growth regulators Ivin, Methyur and Kamethur used separately or in complex with microfertilizers Rostok Extra and Radix Tim forte+ on the growth of oilseed flax of the cultivar Iceberg during the vegetative per
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32

Tsygankova, VA, V. Andrusevich Ya, NM Vasylenko, SG Pilyo, SV Klyuchko, and VS Brovarets. "Screening of Auxin-like Substances among Synthetic Compounds, Derivatives of Pyridine and Pyrimidine." Journal of Plant Science and Phytopathology 7, no. 3 (2023): 151–56. http://dx.doi.org/10.29328/journal.jpsp.1001121.

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The effect of known synthetic compounds Ivin (N-oxide-2,6-dimethylpyridine), Methyur (sodium salt of 6-methyl-2-mercapto-4-hydroxypyrimidine), Kamethur (potassium salt of 6-methyl-2-mercapto-4-hydroxypyrimidine) and new synthetic compounds, derivatives of pyrimidine (No. 1 - 7) on the rooting of isolated stem cuttings of haricot bean (Phaseolus vulgaris L.) variety Bilozernaya was studied. The growth regulatory activity of synthetic compounds Ivin, Methyur, Kamethur, and synthetic compounds, derivatives of pyrimidine (No. 1 - 7) was compared with the activity of auxins IAA (1H-indol-3-yl)aceti
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Waters, AF, and AH White. "Synthesis and Structural Systematics of Nitrogen Base Adducts of Group 2 Salts. II. Some Adducts of Group 2 Salts With Pyridine." Australian Journal of Chemistry 49, no. 1 (1996): 35. http://dx.doi.org/10.1071/ch9960035.

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Recrystallization of Group 2 halides from pyridine ( py ) solution has yielded, in a number of cases, crystalline adducts MX2.npy which have been the subject of room-temperature single-crystal X-ray structural characterization. MgBr2.6py (1) is orthorhombic, Ccca, a 11.575(2), b 14.999(4), c 17.292(2) Ǻ, Z = 4; conventional R on [F] for No = 752 'observed' (I &gt; 3σ(I)) reflections was 0.043. The compound is formulated as [( py )4MgBr2].2py, the metal atom on a site of 222 symmetry having a trans-X2MN4 coordination environment. With CaCl2, a 1:2 adduct (2) is formed, orthorhombic, Fdd2, a 33.
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34

Aoki, Katsuyuki, Masamoto Inaba, Shousuke Teratani, Hiroshi Yamazaki, and Yoshikatsu Miyashita. "Interligand Interactions Affecting Site-Specific Metal Bonding. X-ray Crystal Structures of [Rh2(acetato)4(L)2], Where L = 2,4-Diamino-6-methyl-s-triazine, 2,6-Dimethyl-4-aminopyrimidine, and 2,6-Dimethylpyridine." Inorganic Chemistry 33, no. 13 (1994): 3018–20. http://dx.doi.org/10.1021/ic00091a050.

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35

Bowmaker, Graham A., Effendy, John D. Kildea, Eban N. de Silva, and Allan H. White. "Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXXI Synthesis, Spectroscopy and Structural Systematics of Some 1 : 2 Binuclear Adducts of Silver(I) Compounds with Triphenylarsine, [(Ph3As)2Ag(µ-X)2Ag(AsPh3)2], X = Cl, Br, I, SCN." Australian Journal of Chemistry 50, no. 6 (1997): 627. http://dx.doi.org/10.1071/c96037.

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The syntheses and room-temperature single-crystal X-ray structural characterization of binuclear 1 : 2 adducts formed between silver(I) (pseudo-)halides, AgX, and triphenylarsine, AsPh3, for X = Cl, Br, I, SCN (1)–(4), are described. The chloride (1), obtained from 2-methylpyridine, is triclinic, P-1, a 10·410(2), b 12·716(2), c 14·196(6) Å, α 113·38(2), β 109·41(2), γ 75·08(1)°, Z = 1 (dimer); conventional R on F was 0·037 for No 3979 independent ‘observed’ (I &gt; 3σ(I)) reflections. The bromide (2a), obtained from 2,6-dimethylpyridine, and iodide (3), obtained from a mixture of AgI/saturate
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36

Shulgau, Zarina, Irina Palamarchuk, Shynggys Sergazy та ін. "Synthesis, Computational Study, and In Vitro α-Glucosidase Inhibitory Action of Thiourea Derivatives Based on 3-Aminopyridin-2(1H)-Ones". Molecules 29, № 15 (2024): 3627. http://dx.doi.org/10.3390/molecules29153627.

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Reactions with allyl-, acetyl-, and phenylisothiocyanate have been studied on the basis of 3-amino-4,6-dimethylpyridine-2(1H)-one, 3-amino-4-phenylpyridine-2-one, and 3-amino-4-(thiophene-2-yl)pyridine-2(1H)-one (benzoyl-)isothiocyanates, and the corresponding thioureide derivatives 8-11a-c were obtained. Twelve thiourea derivatives were obtained and studied for their anti-diabetic activity against the enzyme α-glucosidase in comparison with the standard drug acarbose. The comparison drug acarbose inhibits the activity of α-glucosidase at a concentration of 15 mM by 46.1% (IC50 for acarbose is
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37

Rudenko, I. V., A. A. Kucherak, A. A. Tolmachev, and O. V. Hordiyenko. "4,6-Dimethylpyridine-2,3-dicarbonitrile and its reaction with N-acylhydrazines." Chemistry of Heterocyclic Compounds 47, no. 8 (2011): 964–69. http://dx.doi.org/10.1007/s10593-011-0861-6.

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Çaylak, Nagihan, Tuncer Hökelek, Orhan Büyükgüngör, Hakan Dal, Yasemin Süzen та Zeynel Kılıç. "4′,4′,6′,6′-Tetrachloro-3-(4,6-dimethylpyridin-2-yl)-3,4-dihydrospiro[1,3,2-benzoxazaphosphinine-2,2′-(2λ5,4λ5,6λ5-cyclotriphosphazene)]". Acta Crystallographica Section E Structure Reports Online 61, № 6 (2005): o1557—o1560. http://dx.doi.org/10.1107/s1600536805013383.

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39

Dega-Szafran, Z., E. Dulewicz, and M. Szafran. "Interaction of 2,6-dimethylpyridine with chloroacetic acid in some aprotic solvents: problem of stoichiometry." Journal of Molecular Structure 177 (July 1988): 317–25. http://dx.doi.org/10.1016/0022-2860(88)80096-6.

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40

Wang, Tingmin, Jerald S. Bradshaw, Peter Huszthy, and Reed M. Izatt. "Various aspects of enantiomeric recognition of (S,S)-dimethylpyridino-18-crown-6 by several organic ammonium salts." Supramolecular Chemistry 6, no. 3-4 (1996): 251–55. http://dx.doi.org/10.1080/10610279608032542.

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Li, Shi-Hui, Xu-Ze Hu та Yan Zhao. "Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni". Zeitschrift für Kristallographie - New Crystal Structures 231, № 1 (2016): 157–59. http://dx.doi.org/10.1515/ncrs-2015-0066.

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AbstractC40H40N4O12Ni, triclinic, P1̅, a = 7.6612(6) Å, b = 8.0725(7) Å, c = 16.3021(10) Å, α = 89.394(6)°, β = 77.966(6)°, γ = 69.868(8)°, V = 923.75(12) Å3, Z = 1, Rgt(F) = 0.0492, wRref(F2) = 0.1309, T = 293(2) K.
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42

Horváth, György, та Péter Huszthy. "Chromatographic enantioseparation of racemic α-(1-naphthyl)ethylammonium perchlorate by a Merrifield resin-bound enantiomerically pure chiral dimethylpyridino-18-crown-6 ligand". Tetrahedron: Asymmetry 10, № 23 (1999): 4573–83. http://dx.doi.org/10.1016/s0957-4166(99)00515-7.

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43

Mandal, SK, TC Woon, LK Thompson, MJ Newlands, and EJ Gabe. "Binuclear Copper(II) Complexes of Some Tetradentate Pyridyl Phthalazine Ligands. Structure, Electrochemistry and Magnetism - Crystal-Structure of Aqua-µ-[1,4-Di-(4',6'-Dimethylpyridin-2'-Ylamino)-Phthalazine-N1',µ-N2 ,µ-N3,N1'']-µ-Hydroxo-Dinitratodicopper(II) Nitrate." Australian Journal of Chemistry 39, no. 7 (1986): 1007. http://dx.doi.org/10.1071/ch9861007.

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The molecular structure of aqua-μ-[1,4-di(4′,6′-dimethylpyridin-2′- ylamino )phthalazine-N1′,μ-N2,μ-N3,N1′]-μ- hydroxo-dinitratodicopper (II) nitrate has been determined by single-crystal X-ray diffractometry . The compound is triclinic, space group Pī , with two molecules in the unit cell of dimensions a 7.8064(11), b 12.9137(14), c 14.8564(14), α 69.857(8), β 80.074(10), γ 83.659(11). The structure was refined by least-squares to a residual of 0.057 for 2806 reflections. The binuclear centre in the complex involves a five-coordinate and a tetragonally distorted six-coordinate copper atom, ea
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44

Huszthy, Peter, Jerald S. Bradshaw, Cheng Y. Zhu, Reed M. Izatt, and Shneior Lifson. "Recognition by new symmetrically substituted chiral diphenyl- and di-tert-butylpyridino-18-crown-6 and asymmetrically substituted chiral dimethylpyridino-18-crown-6 ligands of the enantiomers of various organic ammonium perchlorates." Journal of Organic Chemistry 56, no. 10 (1991): 3330–36. http://dx.doi.org/10.1021/jo00010a028.

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45

Zhang, Qiangsheng, Xi Hu, Guoquan Wan, et al. "Discovery of 3-(((9H-purin-6-yl)amino)methyl)-4,6-dimethylpyridin-2(1H)-one derivatives as novel tubulin polymerization inhibitors for treatment of cancer." European Journal of Medicinal Chemistry 184 (December 2019): 111728. http://dx.doi.org/10.1016/j.ejmech.2019.111728.

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46

HUSZTHY, P., J. S. BRADSHAW, C. Y. ZHU, R. M. IZATT, and S. LIFSON. "ChemInform Abstract: Recognition by New Symmetrically Substituted Chiral Diphenyl- and Di- tert-butylpyridino-18-crown-6 and Asymmetrically Substituted Chiral Dimethylpyridino-18-crown-6 Ligands of the Enantiomers of Various Organic Ammonium Perchlorates." ChemInform 22, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199139196.

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47

Kano, Tatsuo, Shigeyoshi Nakamura, and Katsuhide Nishi. "The electrophysiological effects of cyclopropylmethyl 4-(3-nitrophenyl) 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate (MPC-2101), the new calcium antagonist, on isolated rabbit myocardial tissues: comparison with nicardipine." Japanese Journal of Pharmacology 40 (1986): 197. http://dx.doi.org/10.1016/s0021-5198(19)59338-6.

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Li, Xiaoyuan, Ellyn Shocron, Aimin Song, Neela Patel, and Connie L. Sun. "Discovery of 5-substituted 2-amino-4-chloro-8-((4-methoxy-3,5-dimethylpyridin-2-yl)methyl)-7,8-dihydropteridin-6(5H)-ones as potent and selective Hsp90 inhibitors." Bioorganic & Medicinal Chemistry Letters 19, no. 10 (2009): 2860–64. http://dx.doi.org/10.1016/j.bmcl.2009.03.074.

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Wang, Tingmin, Jerald S. Bradshaw, Janet C. Curtis, Peter Huszthy, and Reed M. Izatt. "A structural analysis of the complexes of (S, S)-dimethylpyridino-18-crown-6 with (R) and (S)-[?-(1-naphthyl)ethyl]ammonium perchlorate by NMR techniques and molecular modeling." Journal of Inclusion Phenomena and Molecular Recognition in Chemistry 16, no. 2 (1993): 113–22. http://dx.doi.org/10.1007/bf00709146.

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Hartz, Richard A., Vijay T. Ahuja, Xiaoliang Zhuo, et al. "A Strategy to Minimize Reactive Metabolite Formation: Discovery of (S)-4-(1-Cyclopropyl-2-methoxyethyl)-6-[6-(difluoromethoxy)-2,5-dimethylpyridin-3-ylamino]-5-oxo-4,5-dihydropyrazine-2-carbonitrile as a Potent, Orally Bioavailable Corticotropin-Releasing Factor-1 Receptor Antagonist†." Journal of Medicinal Chemistry 52, no. 23 (2009): 7653–68. http://dx.doi.org/10.1021/jm900716v.

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