Dissertations / Theses on the topic 'A-Mong'
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Ng, yin-wang Colin. "Urban design for renewal a legible Mong Kok /." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B42931113.
Full textShum, Eugene, and 岑宇舜. "An urban focus: a multi purposes complex in Mong Kok." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1994. http://hub.hku.hk/bib/B31982153.
Full textShum, Eugene. "An urban focus : a multi purposes complex in Mong Kok /." Hong Kong : University of Hong Kong, 1994. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25945270.
Full textKu, Yongli. "Chinese Investments and Conflict Resolution—A Case Study of Tasang (Mong Ton/Mai Dong) Dam, Myanmar." Thesis, Linnéuniversitetet, Institutionen för samhällsstudier (SS), 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-56574.
Full textTang, Hon-ting. "A study of Shi Daoxuan's (596-667) Guang Hongming Ji Shi Daoxuan "Guang hong mong ji" yan jiu /." Click to view the E-thesis via HKUTO, 1989. http://sunzi.lib.hku.hk/hkuto/record/B31949812.
Full textLow, Chien-tat, and 劉振達. "An exploratory study of environmental risk factors to elderly falls inHong Kong: a GIS case study of Mong Kok,2006-2007." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2008. http://hub.hku.hk/bib/B40887923.
Full textLow, Chien-tat. "An exploratory study of environmental risk factors to elderly falls in Hong Kong a GIS case study of Mong Kok, 2006-2007 /." Click to view the E-thesis via HKUTO, 2008. http://sunzi.lib.hku.hk/hkuto/record/B40887923.
Full textLei, Mei Fong Susanna. "The translator's attitude in news translation :a case analysis of the Hong Kong Mong Kok Incident on the Chinese new year 2016." Thesis, University of Macau, 2018. http://umaclib3.umac.mo/record=b3954317.
Full textPritchard-Wallis, Denise. "Mona maritime trail llwybr Mon a mor." Thesis, Bangor University, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.516128.
Full textAltarejos, Marina Obal. "Filipino basic ecclesial community between limitation and self-transcendence : a Lonergan-based elucidation of fundamental spirituality /." Nijmegen : Radboud University, 2008. http://webdoc.ubn.ru.nl/mono/a/altarejos_m/filibaecc.pdf.
Full text吳永順 and Wing-shun Anthony Vincent Ng. "Toward a low density urban form in Hong Kong." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1993. http://hub.hku.hk/bib/B31979890.
Full textLau, Wai-keung. "Recreation planning and provision of urban open spaces for elderly in Hong Kong : a case study in Mongkok /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B14803380.
Full textSun, Wai-choi Sunny. "A feasibility study of switching from the diesel to petrol light road transport to improve the urban air quality in Hong Kong /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B14723153.
Full textDo, Hoang Son. "Equations de Monge-Ampère complexes paraboliques." Thesis, Toulouse 3, 2015. http://www.theses.fr/2015TOU30113/document.
Full textThe aim of this thesis is to make a contribution to understanding parabolic complex Monge-Ampère equations on domains of Cn. Our study is centered around cases where the initial condition is irregular. We want to prove the existence of solutions which satisfies continuity up to the boundary and continuity up to the initial time
Ho, Sau-ling Connie, and 何秀齡. "Vertical adventure: a climbing gym in Mongkok." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31984599.
Full textErkelenz, Michael. "Shelley's 'Mont Blanc' : a critical interpretation." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.306727.
Full textStrnad, Jakub. "Ocenění společnosti PKS MONT, a. s." Master's thesis, Vysoká škola ekonomická v Praze, 2010. http://www.nusl.cz/ntk/nusl-71927.
Full textTam, Hiu-yuen Cecilia, and 譚曉婉. "A new type of guest houses." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31984812.
Full textPreator, Robin. "Conceptual design studies of a mono tiltrotor." College Park, Md. : University of Maryland, 2005. http://hdl.handle.net/1903/3051.
Full textThesis research directed by: Dept. of Aerospace Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
Teves, Juliana Simões. "Edifício (mono)matéria. A percepção da madeira." Master's thesis, Faculdade de Arquitectura de Lisboa, 2011. http://hdl.handle.net/10400.5/4052.
Full textPretende-se, através deste Relatório de Final de Mestrado, estudar a madeira e seus potenciais no campo da percepção, da estética e da técnica enquanto único material a ser utilizado na concepção do projecto final. Quer-se perceber que vantagens e contradições esta utilização traz na compreensão funcional, formal e de percepção tanto do edifício em si, na sua escala urbana, como dos seus espaços interiores. Intenta-se provar que os materiais escolhidos, como são tratados e como se os combina têm grande influência na forma como se experiência a arquitectura. Muitas vezes a resposta mais assertiva está no uso de técnicas e materiais ditos tradicionais de uma forma consciente, em prol de uma arquitectura que deve ser tratada para responder às necessidades contemporâneas e não a egos ou a uma sede desmesurada de explorar vários ou novos materiais com o intuito de enganar com impressões em vez de conquistar com experiências devidas. Acredita-se que less continua a ser more.
ABSTRACT - This “Relatório de Final de Mestrado” intends to study the wood and its potential in the field of perception, aesthetics and techniques as the only material to be used in the conception of the final project. It also wants to understand what advantages and contradictions this usage brings to the functional, formal and percept ional comprehension, both of the building itself in its urban scale and of the indoor spaces. It intends to show that the selected materials, the way they are treated and how they are combined have huge influence in the way the architecture is experienced. Many times, the most assertive response lies in the conscious use of traditionally considered techniques and materials, favouring an architecture that must be prepared to answer the contemporary needs and not to egos or to an enormous eagerness to explore several or new materials aiming to deceive with impressions, instead of conquering with relevant experiences. It is believed that less means more
Flowers, Johnathan Charles. "Mono no Aware as a Poetics of Gender." OpenSIUC, 2018. https://opensiuc.lib.siu.edu/dissertations/1589.
Full textShrestha, Amit. "Development and Performance Evaluation of a Mono-Valve Engine." Available to subscribers only, 2009. http://proquest.umi.com/pqdweb?did=1879983291&sid=1&Fmt=2&clientId=1509&RQT=309&VName=PQD.
Full textPanisson, Eliane. "Gaspar Monge e a sistematização da representação na arquitetura." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2007. http://hdl.handle.net/10183/14314.
Full textThis thesis is about the descriptive geometry contextualization as an Architecture representation system. It was developed after Gaspard Monge’s Géométrie descriptive deconstruction, published in 1799, accompanying its author exposition since its cover content until its last page, form where parts are detached to be studied among the texts, draws and the own handiwork presentation. To deconstruct Monge’s theory is relevantly presented in this study for investigate Monge’s lessons taught in 1799 that coexists until this moment with different representations, without any question and epistemology understanding. Considering that there are distortions in the original Monge lessons exposition in Géométrie descriptive following handiwork and that its representation concepts determinate limits to the space comprehension that imply the Architecture itself, this study gives opening to Monge’s original theory resignification in the Architecture teaching.
Behrens, Justin William. "Modification and Performance Evaluation of a Mono-valve Engine." OpenSIUC, 2011. https://opensiuc.lib.siu.edu/theses/638.
Full textNilsson, Fredrik. "Vehicle Tracking with Heading Estimation using a Mono Camera System." Thesis, Linköpings universitet, Reglerteknik, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-148495.
Full textFischer, Marie-Thérèse. "LE Mont Sainte-Odile et les Prémontrés : 1546 a 1797." Strasbourg 2, 1999. http://www.theses.fr/1999STR20059.
Full textBradley, Cullen Philip. "LADAR: A Mono-static System for Sense and Avoid Applications." University of Dayton / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1366631049.
Full textMoffatt, Nicholas Andrew. "The simulation and integration of a mono-pressure nitric acid process." Thesis, Queen's University Belfast, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317482.
Full textDonati, Antoine. "Planar polarization of a mono-ciliated epithelium : the zebrafish floor-plate." Electronic Thesis or Diss., Sorbonne université, 2019. http://www.theses.fr/2019SORUS078.
Full textPlanar cell polarization (PCP) of motile cilia allows directional fluid flow generation within body cavities. However the mechanisms underlying PCP of ciliated epithelia are still poorly understood. Here we use the zebrafish floor-plate (FP) to investigate these mechanisms. Using both fixed samples and live-imaging, we show that asymmetric cilia positioning at the posterior side of FP cells is a progressive and asynchronous process between neighbouring cells. As development proceeds, basal bodies (BB, modified centrioles at the base of cilia) spend more time in contact with the posterior membrane and stop making contacts with the anterior membranes. We investigate the role of Par3 in FP cells polarization. We find that Par3 is enriched at the posterior membrane, before the asymmetric positioning of cilia. Strikingly, at early stages, Par3 accumulates as patches at the level of apical junctions and BB only contact anterior or posterior membranes at the level of these patches. In addition, Par3 over-expression disrupts FP PCP. These results strongly suggest that Par3 is a critical player in FP polarization. Finally we show that in zebrafish vangl2 PCP mutants, Par3 patches intensity and polarisation are disrupted, which could explain FP polarization defects. Since Vangl2 is anteriorly enriched in FP cells, this suggests an antagonistic relationship between Par3 and Vangl2
Rao, Arvind Satya. "Weak solutions to a Monge-Ampère type equation on Kähler surfaces." Diss., University of Iowa, 2010. https://ir.uiowa.edu/etd/582.
Full textManeta, Georgia. "A Chair with a View : A Cultural Studies reading of Sue Monk Kidd’s The Mermaid Chair." Thesis, Högskolan Dalarna, Engelska, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:du-34427.
Full textZein, Samir. "Etudes Theoriques des Composes a Transition de Spin mono- et bi-nucleaires." Phd thesis, Université Claude Bernard - Lyon I, 2005. http://tel.archives-ouvertes.fr/tel-00193882.
Full textLa corrélation entre la position des noyaux et les propriétés magnétiques des composés mononucléaires a été faite sur la base des calculs DFT du gap énergétique entre les différents états de spin. Ces études ont permis de tirer des nouvelles conclusions qualitatives quant au rôle du phénomène d'ordre-désordre dans les composés à transition de spin. Certaines paramètres thermodynamiques ont pu être évalué à travers les calculs des fréquences vibrationnelles.
L'étude de systèmes binucléaires présentant un couplage magnétique intramoléculaire a permis l'interprétation des différents comportements magnétiques de ces systèmes (pas de transition, transition en une seule étape ou deux étapes). L'application de l'approche DFT/broken symmetry a permit la quantification des constantes d'échange, difficile d'accès aux mesures magnétochimiques traditionnelles.
Hebert, Joy A. Ms. "A Critical Study of Sue Monk Kidd's The Secret Life of Bees." Digital Archive @ GSU, 2011. http://digitalarchive.gsu.edu/english_theses/117.
Full textWambach, Mona [Verfasser]. "Controlled drug delivery of L-Arginine from a polymer matrix / Mona Wambach." Aachen : Hochschulbibliothek der Rheinisch-Westfälischen Technischen Hochschule Aachen, 2013. http://d-nb.info/1038571200/34.
Full textFerrari, Rubens. "Studio di fattibilità di un gomito protesico attivo a struttura mono-assiale." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2020. http://amslaurea.unibo.it/20255/.
Full textPeres, Clóvis Belbute. "A matéria escura no centro dos aglomerados de galáxias : MOND e neutrinos." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2009. http://hdl.handle.net/10183/16780.
Full textClusters of galaxies are the largest structures in the universe in a quasi-equilibrium state, but, despite research efforts in the past decades, their structure and composition are still poorly understood. Recent theoretical and abservational advances in the understanding of these structures motivate the present research work. Our focus lies on the understanding of the non-luminous component af galaxy clusters. Specifically, we investigate an alternative gravitational theory named MOND, or Madified Newtonian Dynamics, which aims at replacing the dark matter (DM) paradigm, but presents problems when applied to the centers of galaxy clusters. We have reviewed and summarized the state of the art on the modeling of the dark matter in the centers of clusters of galaxies and tested a proposal of solution: the inclusion of massive neutrinos in the MOND scenario. Besides testing MOND + v, we have analised how limits are imposed on the neutrino mass via the study of clusters of galaxies.
Ferreira, Mariane Gonçalves. "Herança da resistência de Solanum habrochaites a Phytophthora infestans (Mont.) De Bary." Universidade Federal de Viçosa, 2017. http://www.locus.ufv.br/handle/123456789/11697.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico
A requeima, causada por Phytophthora infestans (Mont.) De Bary, é a principal doença foliar do tomateiro. No manejo dessa doença, a estratégia mais promissora é o desenvolvimento de cultivares resistentes, havendo, portanto, a necessidade do entendimento da herança associada à resistência. Em programas de melhoramento os estudos dos parâmetros genéticos auxiliam na escolha do melhor método de melhoramento a ser utilizado. Para estimação desses parâmetros são empregados dados observados em linhagens contrastantes (P 1 e P 2 ) e das gerações F 1 , F 2 , RC 1:1 e RC 1:2 . No entanto, a ocorrência de gene de efeito maior e poligenes dificultam os estudos de herança, uma vez que as metodologias, normalmente, utilizadas não detectam as diferenças entre esses genes. Assim, o objetivo desse trabalho foi estudar a herança da resistência do tomateiro a P. infestans, utilizando a função de verossimilhança para modelar e estimar parâmetros relativos aos efeitos de gene maior e poligenes. Os experimentos foram conduzidos na Horta Experimental do Departamento de Fitotecnia da UFV. Como genitor feminino foi utilizado a cultivar susceptível Santa Clara (Solanum lycopersicum) e como genitor masculino o acesso do Banco de Germoplasma de Hortaliças da UFV BGH 6902 (Solanum habrochaites f. glabratum), resistente a requeima. As plantas F 1 , originadas do cruzamento, foram autofecundas para obtenção da geração F 2 e com posterior retrocruzamento entre os genitores para obtenção das gerações RC 1:1 e RC 1:2 . A inoculação das plantas ocorreu aos 50 dias após o transplantio no campo. A severidade da doença foi avaliada por meio de notas, utilizando escala diagramática. Os testes foram realizados no programa estatístico Monogen v 0.1. Na determinação dos modelos genéticos por meio da função de verossimilhança, a significância dos efeitos que comparam os modelos evidencia que a herança da resistência a requeima em tomateiro é conferida por gene maior, com efeito aditivo e dominante mais poligenes, com efeito aditivo mais os efeitos ambientais. A resistência vertical pode ser explorada com a utilização dos genes de efeito maior. Programas de seleção recorrente e a seleção assistida por marcadores moleculares poderão auxiliar o emprego da resistência conferida pelos poligenes.
Late blight, caused by Phytophthora infestans (Mont.) De Bary is a major foliar disease affecting tomato crops. Among management strategies, the most promising is definitely the development of resistant cultivars. Therefore, it is necessary to understand how resistance to this disease is inherited in tomato plants. In breeding programs, studies of genetic parameters have helped plant breeders to choose the best breeding method to be used. To estimate these parameters, researchers make use of data collected from trials at which contrasting inbred lines (P 1 and P 2 ) and their respective F 1 , F 2 , BC 1:1 e BC 1:2 generations were evaluated. However, occurrence of a major-effect gene and polygenes make it difficult to study inheritance patterns since the methodologies that are commonly used do not detect differences between those genes. Therefore, this work aimed to study inheritance of resistance to P. infestans in tomato plants, by using the function of maximum likelihood estimation to modeling and estimating parameters associated to the effects of major genes and polygenes. Field experiments were conducted at the Horticulture Research Farm, owned by the Federal University of Viçosa’s (UFV) Department of Plant Science. The susceptible cultivar Santa Clara (Solanum lycopersicum) was used as the female genitor and the resistant late-blight S. habrochaites f. glabratum accession (BGH 6902), obtained from the UFV Vegetable Gene Bank, was used as the male genitor. F 1 plants from the crossing were selfed up to produce the F 2 progenies, and also backcrossed with P 1 and P 2 producing BC 1:1 and BC 1:2 generations, respectively. The tomato plants were inoculated 50 days after transplanting. Disease severity was evaluated by notes, using a diagrammatic scale. Statistic tests were performed by the Monogen v 0.1 program. By comparing the genetic models created by using the maximum likelihood function, it was concluded that inheritance of resistance to late blight in tomato is conferred by a major gene, with additive and dominant effects, and polygenes, with additive effects, plus the environmental effect. Vertical resistance can be explored by using genes of major effect. Programs of recurrent and maker-assisted selection are considered more efficient strategies in selecting genotypes that hold resistance to late blight conferred by polygenes.
Ribeiro, Santana Menandro. "Monk: proposta de um motor de inferência híbrido para a web semântica." Universidade Federal de Pernambuco, 2010. https://repositorio.ufpe.br/handle/123456789/2314.
Full textConselho Nacional de Desenvolvimento Científico e Tecnológico
Devido às limitações da Web Atua iniciou-se o desenvolvimento de uma evolução da Web, denominada Web Semântica. Nesta nova Web, o conteúdo e a apresentação das informações devem estar separados e representados em uma notação adequada as novas necessidades da comunidade digital. Devido a isso, várias áreas de pesquisa, como por exemplo, a representação do conhecimento e o raciocínio automático, estão trabalhando com o intuito de tornar a Web Semântica uma realidade. Normalmente, o conhecimento é formado por várias partes e nem sempre é possível representá-lo, apropriadamente, utilizando um único formalismo de representação. Devido a isso, sistemas que lidam com representações diferentes podem ser de grande ajuda. O objetivo deste trabalho é estudar formalismos de representação de conhecimento e métodos de raciocínio automático, para propor um motor de inferência híbrido, chamado MONK, que possa ser utilizado na Web Semântica. Para a criação do MONK foi utilizado como base o projeto do sistema MANTRA. Foram mantidos os algoritmos de unificação (Martelli e Montanari) e inferência (t-entailment), pois são algoritmos decidíveis e eficientes, mas a arquitetura foi modificada para facilitar a inclusão futura de novos formalismos, como Frames, Redes Semânticas e Lógica de Descrições (usada na OWL, que é a linguagem padronizada para a Web Semântica). O MONK dá ênfase a Lógica de Primeira Ordem (baseada em uma Lógica de Quatro Valores), tornando-a seu formalismo padrão. Com isso, desde que algum formalismo possua um mapeamento para a Lógica de Primeira Ordem, ele poderá ser suportado pelo MONK sem que seja necessário implementar novos algoritmos de raciocínio
Sun, Wei. "On a Class of Complex Monge-Ampère Type Equations on Hermitian Manifolds." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1366286119.
Full textSoavelomandroso, Anna P., Françoise Gaudin, Sandra Hoys, Valérie Nicolas, Gayatri Vedantam, Claire Janoir, and Sylvie Bouttier. "Biofilm Structures in a Mono-Associated Mouse Model of Clostridium difficile Infection." FRONTIERS MEDIA SA, 2017. http://hdl.handle.net/10150/626057.
Full textLiu, Tianyi. "Control strategy for a mono-inverter multi-PMSM system - Stability and efficiency." Phd thesis, Toulouse, INPT, 2017. http://oatao.univ-toulouse.fr/19624/7/tianyi_liu.pdf.
Full textBoeke, Nick R. "Pastoral leadership in the transition of a mono-ethnic church to a multi-ethnic church." Online full text .pdf document, available to Fuller patrons only, 2001. http://www.tren.com.
Full textAngerville, Ruth. "Evaluation des risques écotoxicologiques liés au déversement de Rejets Urbains par Temps de Pluie (RUTP) dans les cours d'eau : Application à une ville française et à une ville haïtienne." Phd thesis, INSA de Lyon, 2009. http://tel.archives-ouvertes.fr/tel-00446988.
Full textBrum, Alessandra Souza Melett. "Hiroshima Mon Amour e a recepção da critica no Brasil." [s.n.], 2009. http://repositorio.unicamp.br/jspui/handle/REPOSIP/284097.
Full textTese (doutorado) - Universidade Estadual de Campinas, Instituto de Artes
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Resumo: O primeiro longa-metragem de Alain Resnais Hiroshima Mon Amour foi lançado em circuito comercial no Brasil em 1960, ano seguinte a sua estreia na França. O filme causou grande impacto entre a crítica especializada motivando inúmeros artigos em jornais e revistas. É em torno do amplo e rico material produzido pela crítica brasileira, motivada pelas inovações estéticas introduzidas pelo cineasta francês que essa pesquisa se desenvolve. A recepção crítica a Hiroshima Mon Amour irá refletir as transformações pela qual o cinema passava na época, adquirindo importância nos debates em torno do fazer e do pensar cinematográfico.
Abstract: The first Alain Resnais feature film, Hiroshima Mon Amour was issued in commercial circuit in Brazil in 1960, the year following their debut in France. The film has caused great impact on the specialized criticism motivating many articles in newspapers and magazines. This research embrace the abundant material produced by the Brazilian critic, which was motivated by aesthetic innovations introduced by French filmmaker. The criticizing reception to Hiroshima Mon Amour will reflect the changes that went through the cinema at the time, gaining importance in debates around the making and cinematographic thought.
Doutorado
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Doutor em Multimeios
D'Almada-Remedios, Michael Joseph. "Active stabilization and hull-form optimization of a high speed mono-hulled powerboat." Thesis, Nottingham Trent University, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293276.
Full textBianco, Susan. "A black monk in the rose garden : Lydgate and the dit amoureux tradition." Thesis, University of York, 1999. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.313858.
Full textPicard, Sebastien. "A priori estimates of the degenerate Monge-Ampère equation on compact Kähler manifolds." Thesis, McGill University, 2013. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=119756.
Full textLa question de la régularité des solutions de l'équation complexe Monge-Ampère dégénérée est étudiée. Premièrement, l'équation est considérée sur une variété compacte Kahler sans frontière. Une revue des concepts clés de la géométrie Kahler est présentée. Étant donné une solution de l'équation complexe Monge-Ampère dégénérée, il est démontré que la différence entre la borne supérieure et la borne inférieure de la solution est sous contrôle, et ainsi pour le gradient de la solution. Le Laplacien de la solution est également bornée. Cette borne du Laplacien est une amélioration de ce qui a été établi dans la littérature jusqu'à présent, mais par contre, l'argument tient seulement sous la condition que la variété a une courbure non-négative. Les résultats sont appliqués à un problème de Dirichlet dans l'espace complexe. L'existence et l'unicité d'une solution pluri-subharmonique de l'équation complexe Monge-Ampère dégénérée dans un domaine contenu dans l'espace complexe est démontré.
Franco, Cilene Meinberg. "Pesquisa experimental sobre a polimerização via radical livre com iniciadores mono e difuncional." [s.n.], 2006. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266156.
Full textDissertação (mestrado) - Universidade Estadual de Campinas. Faculdade de Engenharia Quimica
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Resumo: Iniciadores mono funcionais são largamente utilizados em polimerizações VIa radical livre. Muitas vezes, na busca de maiores produtividades, utilizam-se temperaturas de operação mais elevadas e/ou maiores concentrações iniciais de iniciador, que por conseqüência, geram polímeros com pesos moleculares mais baixos. O uso de iniciadores difuncionais permite o aumento da produtividade sem a redução no peso molecular do produto final, o que pode ser urna característica desejável. A pesquisa com iniciadores difuncionais é atual e de grande interesse industrial. O objetivo deste trabalho é analisar o efeito da funcionalidade do iniciador, no caso mono e difuncional, sobre a polimerização via radical livre, considerando corno caso estudo um polímero linear, o poliestireno, e um ramificado, o poli (acetato de vinila). Para isso, foram feitas, experimentalmente, reações de polimerização em ampolas de vidro (polimerização em massa), com o iniciador mono funcional (Luperox TBEC) e o di funcional (Luperox 531). Foram analisados também o efeito da temperatura de polimerização e a concentração de iniciador. Também neste trabalho é apresentado um estudo estatístico através de um Planejamento Fatorial, a fim de analisar o efeito das variáveis temperatura e concentração de iniciador na polimerização do estireno com iniciador difuncional. Observou-se, tanto para o estireno corno para o acetato de vinila, que quando utilizado o iniciador difuncional é possível obter conversões maiores, sem alterar o peso molecular médio mássico e numérico, sendo que em alguns casos pode se até obter um aumento no peso molecular. O uso de iniciador di funcional é também mais viável economicamente, pois apresenta melhores resultados frente ao monofuncional, mesmo quando utilizado em concentrações ou temperaturas menores do que as utilizadas com o iniciador mono funcional. É importante salientar o caráter inovador desta pesquisa, já que não foram encontrados, em literatura aberta, dados experimentais da polimerização do acetato de vinila (ou outro monômero que produza ramificações de cadeia longa) utilizando iniciadores difuncionais
Abstract: Monofunctional initiators are extensively utilized in free radical polymerization. In order to increase productivity, higher temperature or higher initial initiator concentration are used, therefore polymers with lower molecular weights are obtained. Bifunctional initiators increase the polymerization rate without decreasing the average molecular weight and this can be desirable. They are an important issue to be investigated and are of great interest to industries. The objective of this work is to analyze the effect of the functionality of the initiator, by using mono and bifunctional, in free radical polymerization, for linear polymer (poly styrene) and branched polymer (poly(vinyl acetate)). Polymerizations were experimentally performed in glass ampoules (bulk polymerization) using both mono(Luperox TBEC) and bi- (Luperox 531) functional initiators. The effects of temperature and initiator concentration were also analyzed for various polymerization conditions. This work includes a statistical study using the factorial design to analyze the effect of temperature and initiator concentration in styrene polymerization with bifunctional initiator. It is observed in this study, that high conversions with no effect in the molecular weigh of the dead polymer can be achieved using bifunctional initiators in the polymerization of styrene and vinyl acetate. In many cases, it is possible to obtain higher molecular weights. Bifunctional initiator can also be used to provide reduction costs to initiators. They showed better results than the monofunctional initiator when lower concentration or temperature lower were utilized.
Mestrado
Desenvolvimento de Processos Químicos
Mestre em Engenharia Química
Medina, Eduardo Ferreira. "Algumas respostas de mono- e dicotiledôneas a auxinas associadas à ação do etileno." Universidade Federal de Viçosa, 2013. http://locus.ufv.br/handle/123456789/4336.
Full textThe auxins IAA (indole-3-acetic, natural), 2,4-D (2,4-dichlorophenoxyacetic acid) and 2,4,5-T (2,4,5-trichlorophenoxyacetic acid, the latter two synthetic) were sprayed on corn (Zea mays, monocot) and beans (Phaseolus vulgaris, dicot), in order to investigate some differential responses of the two plant groups as associated to ethylene metabolism. Corn plants treated with the auxins did not produce ethylene, not exhibiting also any senescence symptom. Beans plants, on the other hand, produced large amounts of ethylene following treatment with auxins. Aminoethoxyvinylglycine (AVG) plus Co2+ (ethylene biosynthesis inhibitors) were not able to relieve the epinasty, drying and leaf wrinkling effects in bean plants, but leaf yellowing was considerebly reduced, suggesting this was an ethylene effect. Following spraying with auxins, corn plants showed no production of 1-aminocyclopropane-1-carboxylic acid (ACC), a response shown by beans plants. Therefore in the monocot, auxins seemed not to induce the expression of ACC synthase (ACS) or its activity. When treated with ACC, corn plants failed to produce any trace of ethylene, unlikely bean plants. This suggested that in monocot, auxins seemed also not to induce the expression or activity of ACC oxidase (ACO) or the enzyme is not activated. Potassium ferrocyanide, employed as a source of cyanide ions, was much more toxic to bean plants than to corn and so the monocot seemed to be more resistant than bean plants. Maximum quantum yield of photosystem II (Fv/Fm) and photosynthetic pigments contents kept unchanged in corn plants treated with the auxins. Bean plants showed significant decreases in both variables following spraying with 2,4-D and 2,4,5-T. Decreases in chlorophyll contents in bean plants treated with 2,4-D and 2,4,5-T correlated well with leaf chlorosis what was shown to be due to a more pronounced fall of chlorophyll contents rather than to an increase in carotenoid contents. The xanthophylls (neoxanthin, violaxanthin and anteraxantina) also showed a higher degradation than the alpha and beta carotenes in bean plants treated with 2,4-D and 2,4,5-T. When AVG and Co2+ were supplied together with auxin, no appreciable decrease in either the Fv/Fm ratio or pigment contents was observed, with the exception of alpha carotene. Also the ratio of chlorophyll a to chlorophyll b was also larger in bean plants treated with 2,4-D and 2,4,5-T than in the plants treated with 2,4-D and 2,4,5-T plus AVG and Co2+. The ratio of chlorophyll a to chlorophyll b did not show any significance in bean plants upon treatment with IAA.
As auxinas AIA (ácido indol-3-acético, natural), 2,4-D (ácido 2,4-diclorofenoxiacético) e 2,4,5-T (ácido 2,4,5-triclorofenoxiacético, as duas últimas sintéticas) foram aplicadas em plantas de milho (Zea mays, monocotiledônea) e feijão (Phaseolus vulgaris, dicotiledônea), visando investigarem-se algumas respostas diferenciais dos dois grupos em relação ao metabolismo do etileno. Plantas de milho tratadas com as auxinas não produziram etileno e não exibiram quaisquer sintomas de senescência e epinastia. O feijão produziu bastante etileno após tratamento. Quando se utilizou aminoetoxivinilglicina (AVG) mais Co2+ (inibidores da biossíntese de etileno), a epinastia das plantas de feijão foi mantida mas o amarelecimento das plantas mostrou-se reduzido, deduzindo-se ser o amarelecimento um sintoma da ação do etileno. Após pulverização com as auxinas, o milho não exibiu produção do ácido 1-carboxílico-1- amino-ciclopropano (ACC), fato observado no feijão. Assim, na monocotiledônea, as auxinas parecem não induzir a expressão da sintase do ACC (ACS) ou, pelo menos, sua atividade. Quando tratadas com o ACC, as plantas de milho não produziram qualquer traço de etileno, ao contrário as plantas de feijão. Daí deduzir-se que na monocotiledônea, as auxinas parecem também não induzir a expressão ou atividade da oxidase do ACC (ACO) ou a enzima não é ativada. Empregando-se K4Fe(CN)6 como fonte de íons cianeto, as plantas de milho pareceram se mostrar mais resistentes à intoxicação do que as plantas de feijão. O rendimento quântico máximo de fotossistema II (razão Fv/Fm) e os níveis dos pigmentos fotossintéticos não sofreram alterações em plantas de milho tratadas com as auxinas. As plantas de feijão mostraram quedas significativas em ambas variáveis após pulverização com 2,4-D e 2,4,5-T, mas não com o AIA. A redução nos níveis das clorofilas em plantas de feijão tratadas com 2,4-D e 2,4,5-T relacionou-se com a clorose observada, desde que ocorreu uma degradação mais acentuada das clorofilas do que dos carotenoides. As xantofilas (neoxantina, anteraxantina e violaxantina) também sofreram uma degradação mais acentuada do que o alfa e beta caroteno em plantas de feijão tratadas com 2,4-D e 2,4,5-T. Quando AVG e Co2+ foram fornecidos conjuntamente com as auxinas, não ocorreu queda na razão Fv/Fm e nem no nível dos pigmentos, com exceção do alfa caroteno. A razão entre clorofila a e clorofila b também mostrou-se maior nas plantas de feijão tratadas com 2,4-D e 2,4,5-T do que nas plantas tratadas com 2,4-D e 2,4,5-T mais AVG e Co2+. Nas plantas tratadas com AIA o aumento na razão entre clorofila a e clorofila b não foi significativo.
Ramírez, Flores Mauricio Andrés. "Susceptibilidad de cultivares de vid (Vitis vinifera L.) a Diplodia mutila (Fr.) Mont." Tesis, Universidad de Chile, 2014. http://repositorio.uchile.cl/handle/2250/148287.
Full textLa frecuencia de síntomas debido al ataque de hongos de la madera de la vid, ha aumentado significativamente en todo el mundo durante la última década. Las especies fungosas de la familia Botryosphaeriaceae provocan la muerte parcial de la planta, disminuyendo la productividad y la rentabilidad del cultivo. Una de las especies presentes en Chile es Diplodia mutila, asociada principalmente a la enfermedad del brazo muerto de la vid. El objetivo de esta investigación fue evaluar la susceptibilidad de sarmientos de cultivares de vid vinífera (Cabernet Franc, Malbec, Merlot, Sauvignon Blanc y Syrah) y de mesa (Crimson Seedless, Flame Seedless, Red Globe y Thompson Seedless) a D. mutila. Para ello, se realizó un ensayo “in vivo” usando sarmientos de un año, los cuales fueron inoculados con discos de agar con micelio de D. mutila, en el sector medio del entrenudo después de producir una herida. Los sarmientos fueron mantenidos en una cámara de crecimiento durante cuatro a seis semanas, en oscuridad, a una humedad relativa del 95% y a una temperatura de 25°C. Se consideraron 10 repeticiones por cultivar y al término del período de incubación, se evaluó la longitud de la lesión necrótica en forma independiente, en los cultivares viníferos de los de mesa. No se encontraron diferencias estadísticamente significativas al comparar la susceptibilidad de los cultivares viníferos y de mesa investigados, los que en su totalidad fueron susceptibles al patógeno.
The frequency of symptoms associated to fungal attack on grapevine trunk, increased significantly worldwide during the last decade. Fungal species belonging to the Botryosphaeriaceae family are responsible for the death of part of the plant, reducing productivity and profitability of this crop. Diplodia mutila is one of the species associated to the dead arm disease of grapevine in Chile. The objective of this research was to evaluate the susceptibility of vine shoots of wine grape cultivars (Cabernet Franc, Malbec, Merlot, Sauvignon Blanc and Syrah) and table grapes (Crimson Seedless, Flame Seedless, Red Globe and Thompson Seedless) to D. mutila. In vivo trials were performed using one year old vine shoots, inoculated with mycelia disks of D. mutila between the internode after performing a wound. The shoots were kept during four to six weeks in a growth chamber, in the dark, at 95% relative humidity and at 25 ° C. Ten replicates per cultivar were considered, where necrotic lesion length was evaluated. No significant differences were observed on susceptibility among wine and table grape cultivars, being all susceptible to the pathogen.