Academic literature on the topic 'Acetamide'

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Journal articles on the topic "Acetamide"

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Nagarsha, K. M., T. M. Sharanakumar, D. Ramesh, et al. "NOVEL SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY OF N-(5BROMO-2-(5-PHENYL1,3,4-OXADIAZOL-2-YL)NAPHTHA[2,1-B]FURAN-1- YL)ACETAMIDE AND N-(5-NITRO-2-(5-PHENYL-1,3,4- OXADIAZOL-2-YL)NAPHTHA[2,1-BFURAN-1-YL]ACETAMIDE AND THEIR DERIVATIVES." RASAYAN Journal of Chemistry 16, no. 01 (2023): 167–75. http://dx.doi.org/10.31788/rjc.2023.1618088.

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The novel derivatives of naphtho-furan such N-(5bromo-2-(5-phenyl-1,3,4-oxadiazol-2-yl)naphtha[2,1-b]furan-1- yl)acetamide (8), N-(5-bromo-2-(hydrazinecarbonyl)naphtha[2,1-b]furan-1-yl]acetamide (7), ethyl-1-acetamido-5- bromonaphtho[2,1-b]furan-2-carboxylate (6), N-(5-nitro-2-(5-phenyl-1,3,4-oxadiazol-2-yl)naphtha[2,1-bfuran-1- yl]acetamide (5),N-(2-(hydrazinecarbonyl)-5-nitronaphtho[2,1-b]furan-1-yl)acetamide (4), ethyl-1-acetamido-5- nitrpnaphtho[2,1-b]furan-2-carboxylate (3), are prepared by ethyl-1-acetamidonaphtho[2,1-b]furan-2-carboxyate and ethyl 1-aminonaphtho[2,1-b]furan-2-carboxylat
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Qiu, Guanyinsheng, Yuewen Li, Lele Ma, and Hongwei Zhou. "KBr/K2S2O8-mediated dibromohydration of N-(2-alkynylaryl)acetamide." Organic Chemistry Frontiers 4, no. 6 (2017): 1069–73. http://dx.doi.org/10.1039/c6qo00840b.

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Girel, Sergey, Vadim Schütz, Laurent Bigler, Peter Dörmann, and Margot Schulz. "Bioactive Nitrosylated and Nitrated N-(2-hydroxyphenyl)acetamides and Derived Oligomers: An Alternative Pathway to 2-Amidophenol-Derived Phytotoxic Metabolites." Molecules 27, no. 15 (2022): 4786. http://dx.doi.org/10.3390/molecules27154786.

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Incubation of Aminobacter aminovorans, Paenibacillus polymyxa, and Arthrobacter MPI764 with the microbial 2-benzoxazolinone (BOA)-degradation-product 2-acetamido-phenol, produced from 2-aminophenol, led to the recently identified N-(2-hydroxy-5-nitrophenyl) acetamide, to the hitherto unknown N-(2-hydroxy-5-nitrosophenyl)acetamide, and to N-(2-hydroxy-3-nitrophenyl)acetamide. As an alternative to the formation of phenoxazinone derived from aminophenol, dimers- and trimers-transformation products have been found. Identification of the compounds was carried out by LC/HRMS and MS/MS and, for the n
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Gowda, Basavalinganadoddy Thimme, Jozef Kožíšek, Ingrid Svoboda, and Hartmut Fuess. "Effect of Meta-Substitution on Solid State Geometry of N-(Aryl)-2,2,2-trichloro-acetamides, 3-XC6H4NH-CO-CCl3 and 3,5-X2C6H3NH-CO-CCl3 (X = Cl, CH3)." Zeitschrift für Naturforschung A 62, no. 1-2 (2007): 91–100. http://dx.doi.org/10.1515/zna-2007-1-213.

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The crystal structures of N-(meta-substituted phenyl)-2,2,2-trichloro-acetamides such as N- (3-methylphenyl)-2,2,2-trichloro-acetamide, 3-CH3C6H4NH-CO-CCl3 (3MPTCA); N-(3-chlorophenyl)- 2,2,2-trichloro-acetamide, 3-ClC6H4NH-CO-CCl3 (3CPTCA); N-(3,5-dimethylphenyl)- 2,2,2-trichloro-acetamide, 3,5-(CH3)2C6H3NH-CO-CCl3 (35DMPTCA) and N-(3,5-dichlorophenyl)- 2,2,2-trichloro-acetamide, 3,5-Cl2C6H3NH-CO-CCl3 (35DCPTCA) have been determined at room temperature. The crystal system, space group, formula units and lattice constants (Å ) of the new structures are: 3MPTCA: orthorhombic, Pbca, Z = 8, a = 1
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Alagarsamy, Veerachamy, Viswas Raja Solomon, Mohaideen Thasthagir Sulthana, Meduri Satyasai Vijay, and Bandi Narendhar. "Design and synthesis of quinazolinyl acetamides for their analgesic and anti-inflammatory activities." Zeitschrift für Naturforschung B 70, no. 8 (2015): 597–604. http://dx.doi.org/10.1515/znb-2015-0035.

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AbstractA variety of novel 2-(substituted)-N-(4-oxo-2-phenylquinazolin-3(3H)-yl)acetamides were synthesized by the reaction of 2-chloro-N-(4-oxo-2-phenylquinazolin-3(3H)-yl)acetamide with various amines. The starting material, 2-chloro-N-(4-oxo-2-phenylquinazolin-3(3H)-yl)acetamide, was synthesized from anthranilic acid by the multistep process. The title compounds were investigated for analgesic, anti-inflammatory, and ulcerogenic index activities. Among those, the compound 2-(ethylamino)-N-(4-oxo-2-phenylquinazolin-3(3H)-yl)acetamide (V9) showed most potent analgesic and anti-inflammatory ac
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Eagle, Cassandra T., Nkongho Atem-Tambe, Kenneth K. Kpogo, Jennie Tan та Fredricka Quarshie. "(3-Methylbenzonitrile-κN)tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-dirhodium(II)(Rh—Rh)". Acta Crystallographica Section E Structure Reports Online 69, № 12 (2013): m639. http://dx.doi.org/10.1107/s1600536813029838.

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In the title compound, [Rh2(C8H8NO)4(C8H7N)], the four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-transmanner. One RhIIatom is five-coordinate, in a distorted pyramidal geometry, while the other is six-coordinate, with a disorted octahedral geometry. For the six-coordinate RhIIatom, the axial nitrile ligand shows a non-linear Rh–nitrile coordination with an Rh—N—C bond angle of 166.4 (4)° and a nitrile N—C bond length of 1.138 (6) Å. Each unique RhIIatom is coordinated by atranspair of N atoms and atranspair of O atoms from the four acetamide ligands. The Neq—Rh—Rh—O
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Mahyavanshi, Vinay, and Sunil I. Marjadi. "Design and Synthesis of 1-(2-amino-1-(4-methoxyphenyl)ethyl) cyclohexanol Analogs as Potential Microbial Agents." International Journal of Drug Design and Discovery 2, no. 2 (2024): 474–82. https://doi.org/10.37285/ijddd.2.2.6.

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1-(2-amino-1-(4-methoxyphenyl)ethyl)cyclohexanol (1), on condensation with chloroacetyl chloride yielded 2-chloro-N-(2-(1-hydroxycyclohexyl)-2-(4-methoxyphenyl)ethyl)acetamide (2), which on amination with hydrazine hydrate yielded in turn 2-hydrazinyl-N-(2-(1-hydroxycyclohexyl)-2-(4-methoxyphenyl)ethyl)acetamide (3). Compound 3, on condensation with various aromatic aldehydes afforded a series of 2-(2-benzylidenehydrazinyl)-N-(2-(1-hydroxycyclohexyl)-2-(4-methoxyphenyl)ethyl)acetamides 4a-n, which upon dehydrative annulation in the presence of chloroacetyl chloride and triethylamine yielded 2-
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Chen, Xuanhua, Rongwei Guo, and Zhongyuan Zhou. "N-[3-Acetamido-1,3-bis(4-ethylphenyl)butenyl]acetamide." Acta Crystallographica Section E Structure Reports Online 58, no. 6 (2002): o671—o672. http://dx.doi.org/10.1107/s1600536802008607.

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Gowda, Basavalinganadoddy Thimme, Helmut Paulus, and Jozef Kožíšek. "Effect of Substitution on the Molecular Geometry of N-(2/3/4-Substituted-phenyl)-2,2-dichloro-acetamides, 2/3/4-XC6H4NH-CO-CHCl2 (X = CH3 or Cl)." Zeitschrift für Naturforschung A 61, no. 12 (2006): 675–82. http://dx.doi.org/10.1515/zna-2006-1210.

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2MPDCAThe effect of ring substitution on the molecular geometry of amides of the type 2/3/4-XC6H4NHCO- CHCl2 (X = CH3 or Cl) has been studied by determining the crystal structures of the compounds N-(2-methylphenyl)-2,2-dichloro-acetamide, 2-CH3C6H4NH-CO-CHCl2 (); N-(3-methylphenyl)- 2,2-dichloro-acetamide, 3-CH3C6H4NH-CO-CHCl2 (3MPDCA) and N-(3-chlorophenyl)- 2,2-dichloro-acetamide, 3-ClC6H4NH-CO-CHCl2 (3CPDCA). The results are analyzed along with our earlier crystal structures of the amides N-(phenyl)-2,2-dichloro-acetamide, C6H5NH-COCHCl2 (PDCA); N-chloro-N-(phenyl)-2,2-dichloro-acetamide,
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Que, Chuqiang, Peipei Huang, Zhanhui Yang, Ning Chen, and Jiaxi Xu. "Intramolecular Carbene C-H Insertion Reactions of 2-Diazo-2-sulfamoylacetamides." Molecules 24, no. 14 (2019): 2628. http://dx.doi.org/10.3390/molecules24142628.

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The intramolecular C-H insertions of carbenes derived from 2-diazo-2-sulfamoylacetamides were studied. 2-Diazo-2-sulfamoylacetamides were first prepared from chloroacetyl chloride and secondary amines through acylation followed by sequential treatments with sodium sulfite, phosphorus oxychloride, secondary amines, and 4-nitrobenzenesulfonyl azide. The results indicate that: (1) 2-diazo-N,N-dimethyl-2-(N,N-diphenylsulfamoyl)acetamide can take the formal aromatic 1,5-C-H insertion in its N-phenylsulfonamide moiety to afford the corresponding 1,3-dihydrobenzo[c]isothiazole-3-carboxamide 2,2-dioxi
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Dissertations / Theses on the topic "Acetamide"

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Gallagher, Julie Marie. "The synthesis of 1-acetamido-2,6-anhydro-1,7-deoxy-L-glycero-L-galactitol (N-[β-L-fucopyranosylomethyl]-acetamide) and related derivatives". Scholarly Commons, 1989. https://scholarlycommons.pacific.edu/uop_etds/2182.

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One important goal of this thesis is the hydrogenation of the glycosyl cyanide, which has never been mentioned by any of the groups who have done work in this area, except for B. Coxon and G. Fletcher, who in 1964, reduced a tetra-O-acetyl-β-D-galactopyranosyl cyanide with lithium aluminum hydride. We were hoping to obtain, by reduction with hydrogen on Pd/C, an aminomethyl C-glycoside. It is believed that these aminomethyl C-glycosides are of potential biological importance especially in the area of AIDS and HIV therapy.
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Issac, Ibrahim Youhanna. "Studies in the lower temperature molten salts eutectics." Thesis, University of Southampton, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252705.

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Marchand, Pascal. "Synthese et evaluation pharmacologique de derives indoliques a activites immunosuppressive et antitumorale (doctorat chimie therapeutique)." Nantes, 1999. http://www.theses.fr/1999NANT22VS.

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Zhang, Zichen. "Anticancer effects of hexamethylene bisacetamide on human colon carcinoma cells in vitro /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21021065.

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Lundell, Sandra J. "Quantum Mechanical Studies of N-H···N Hydrogen Bonding in Acetamide Derivatives and Amino Acids." DigitalCommons@USU, 2018. https://digitalcommons.usu.edu/etd/7309.

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Proteins are made of vast chains of amino acids that twist and fold into intricate designs. These structures are held in place by networks of noncovalent interactions. One of these, the hydrogen bond, forms bridges between adjacent pieces of the protein chain and is one of the most important contributors to the shape and stability of proteins. Hydrogen bonds come in all shapes and sizes and a full understanding of these not only aids in our understanding of proteins in general but can bridge the gap to finding cures to many protein-related diseases, such as sickle-cell anemia. The primary aim
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Borko, Matijević. "Građenje halogenidnih kompleksa kobalta(II) u rastopima smeše neorganskih soli i polarnih organskih jedinjenja." Phd thesis, Univerzitet u Novom Sadu, Prirodno-matematički fakultet u Novom Sadu, 2011. https://www.cris.uns.ac.rs/record.jsf?recordId=77320&source=NDLTD&language=en.

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U ovoj doktorskoj disertaciji proučavano je građenje&nbsp;kompleksa kobalta(II) sa hloridnim i &nbsp;bromidnim jonima u&nbsp;rastopima koji sadrže jednu neorgansku so i jedno organsko&nbsp;jedinjenje i/ili vodu pri različitom sastavu sistema i na različitim&nbsp;temperaturama. Jedan od sistema je amonijum-nitrat &ndash;&nbsp;acetamid &ndash; voda sastava NH<sub>4</sub>NO<sub>3</sub>∙(2,61-z)CH<sub>3</sub>CONH<sub>2</sub>∙zH<sub>2</sub>O (z =&nbsp;0,0 1,61 i 2,61), a drugi sistem je amonijum&ndash;nitrat &ndash; dimetilsulfoksid&nbsp;(DMSO) sastava NH<sub>4</sub>NO<sub>3</sub>∙zDMSO (z = 1 &nda
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劉汝這 and Yue-huen Thomas Lau. "Ultrastructural and stereological investigation of the effects of hexamethylene bisacetamide on human colon carcinoma LoVo cells invitro." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B29872972.

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DRUOT, HOULLEMARE SOPHIE. "Influence des interactions homo- et heterochirales lors du dedoublement par cristallisation preferentielle de deux derives de l'alpha-methylbenzylamine : le n-acetamide et le chloroacetate." Caen, 1999. http://www.theses.fr/1999CAEN2029.

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Une etude comparative du dedoublement par cristallisation preferentielle classique et auto-ensemencee des derives chloroacetate et n-acetyl de l'-methylbenzylamine est realisee. Les resultats sont largement inferieurs aux maxima autorises par la thermodynamique. L'etude detaillee des diagrammes binaires revele l'existence de compose racemique instable dans le premier cas ou metastable pour le n-acetyl. Il est montre que les interactions heterochirales peuvent inhiber la croissance selective d'un enantiomere dans une solution quasi racemique. Dans le cas du chloroacetate, des experiences de re-
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Meilhoc, Eliane. "Polyamines et differenciation induite par l'hexamethylene bis acetamide (hmba) de cellules erythroleucemiques de souris : role cle de la desacetylation de l'hmba dans cette differenciation." Clermont-Ferrand 2, 1986. http://www.theses.fr/1986CLF2D177.

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De nombreuses modifications membranaires, cytoplasmiques et nucleaires accompagnent ce processus de differenciation induite. La question fondamentale qui se pose est de savoir, lesquelles, parmi ces modifications sont necessaires a la differenciation des cellules de friend. Peu d'elements permettent d'y repondre actuellement. Nos travaux montrent que des changements dans le metabolisme des polyamines (baisse de l'activite de l'ornithine decarboxylase et des taux intracellulaires en putrescine et spermidine) sont necessaires a la differenciation induite des cellules de friend. Une ou plusieurs
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Conley, Matthew. "Supercritical Water Gasification of Two-Carbon Carboxylic Acid Derivatives." Ohio University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1542202432022198.

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Books on the topic "Acetamide"

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Scribner, Elisabeth A. Acetamide herbicides and their degradation products in ground water and surface water of the United States, 1993-2003. U.S. Department of the Interior, U.S. Geological Survey, 2004.

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Russlies, Martin. Untersuchungen zum Einfluss unterschiedlicher Diuresezustände auf die renale Elimination von 2-Oxo-pyrrolidin-1-acetamid [Oxo-pyrrolidin-acetamid] (Piracetam). [s.n.], 1989.

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Tou, Grace. The pharmacokinetics of 2-acetamido-P-cresol and the effects of deacetylation on its toxicodynamics. National Library of Canada, 1991.

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Lundkvist, J. R. Michael. Conformationally restricted analogues of the muscarinic agent N-methyl-N-<1-methyl-4-pyrrolidino-2-butynyl> acetamide . 1990.

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Wardle, N. J. Syntheses and characterisation of novel 1-acetamido-2,2-biscarbamyl-ethanephosphonate derivatives. 1998.

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Michnick, Thomas John. Asymmetric synthesis of acetamido boronic acids and asymmetric synthesis using boronic esters. 1990.

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Lübber, Friedhelm. Untersuchungen zur Verteilung und Elimination von 2-Oxo-pyrrolidin-1-acetamid im menschlichen Organismus. 1988.

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Tou, Grace. The pharmacokinetics of 2-acetamido-P-cresol and the effects of deacetylation on its toxicodynamics. 1991.

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Darmstadt, Technische Hochschule, ed. Kinetik und Mechanismus der Monokomplexbildung des Liganden 3-Acetamido-2,4-pentandion ( = Hacacam) mit Cobalt(II), Nickel(II) und Kupfer(II) in wässriger Lösung. 1994.

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Book chapters on the topic "Acetamide"

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Gooch, Jan W. "Acetamide." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_101.

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Lide, David R. "Acetamide." In Handbook of Organic Solvents. CRC Press, 2024. http://dx.doi.org/10.1201/9781003575191-3.

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Irvine, William M. "Acetamide." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-65093-6_5321.

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Irvine, William. "Acetamide." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-642-27833-4_5321-1.

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Gooch, Jan W. "Dimethyl Acetamide." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_3707.

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Gooch, Jan W. "Hydroxyethyl Acetamide." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_6156.

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Bährle-Rapp, Marina. "Acetamide MEA." In Springer Lexikon Kosmetik und Körperpflege. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_56.

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Gooch, Jan W. "N-Methyl Acetamide." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_7388.

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Demaison, J. "211 C2H5NO Acetamide." In Asymmetric Top Molecules. Part 1. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-10371-1_213.

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Simola, Nicola, Micaela Morelli, Tooru Mizuno, et al. "2-[(Diphenylmethyl)Sulfinyl]acetamide." In Encyclopedia of Psychopharmacology. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-540-68706-1_3009.

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Conference papers on the topic "Acetamide"

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Ilyushin, Vadim, Ruslan Porohovoi, Eugene Alekseev, et al. "The Third Excited Torsional State of Acetamide." In 2022 IEEE 2nd Ukrainian Microwave Week (UkrMW). IEEE, 2022. http://dx.doi.org/10.1109/ukrmw58013.2022.10037019.

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Coudert, L., J. C. Guillemin, H. Møllendal, et al. "THE MICROWAVE SPECTRUM OF MONODEUTERATED ACETAMIDE CH2DC(=O)NH2." In 69th International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2014. http://dx.doi.org/10.15278/isms.2014.fa07.

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Srinivasan, H., P. S. Dubey, V. K. Sharma, R. Biswas, S. Mitra, and R. Mukhopadhyay. "Molecular dynamics of acetamide based ionic deep eutectic solvents." In DAE SOLID STATE PHYSICS SYMPOSIUM 2017. Author(s), 2018. http://dx.doi.org/10.1063/1.5029015.

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Prathap, S., and J. Madhavan. "Synthesis, experimental and theoretical investigations of N-(3-nitrophenyl) acetamide (3NAA)." In SOLID STATE PHYSICS: Proceedings of the 56th DAE Solid State Physics Symposium 2011. AIP, 2012. http://dx.doi.org/10.1063/1.4710488.

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CHENG, YUCHUAN, JIANJUN GUO, XUEHUI LIU, GAOJIE XU, and PING CUI. "PREPARATION AND ELECTRORHEOLOGICAL EFFECT OF ACETAMIDE-MODIFIED TITANATE NANOTUBE SUSPENSIONS INSTRUCTIONS." In Proceedings of the 12th International Conference. WORLD SCIENTIFIC, 2011. http://dx.doi.org/10.1142/9789814340236_0054.

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Hemaraju, B. C., B. S. Madhukar, D. G. Bhadregowda, and A. P. Gnana Prakash. "Growth and characterization of new organic nonlinear optical crystal (R)-2-cyano-N-(1-phenylethyl) acetamide." In SOLID STATE PHYSICS: Proceedings of the 58th DAE Solid State Physics Symposium 2013. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4873089.

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"‘n-(P-TOLYL)ACETAMIDE‘ BİLEŞİĞİNİN XRD YÖNTEMİ İLE KRİSTAL YAPISININ AYDINLATILMASI VE HIRSHFELD YÜZEY ANALİZİ ÇALIŞMASI." In 2nd International Conference on Recent Academic Studies ICRAS 2023. All Sciences Academy, 2023. http://dx.doi.org/10.59287/as-proceedings.112.

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Kumar, Rohitash, Ravindra Kumar, and Ambesh Dixit. "Thermal phase diagram of acetamide-benzoic acid and benzoic acid-phthalimide binary systems for solar thermal applications." In INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC 2015): Proceeding of International Conference on Condensed Matter and Applied Physics. Author(s), 2016. http://dx.doi.org/10.1063/1.4946738.

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Lominoga, Elizaveta R., Pavlo V. Zadorozhnii, Valeria V. Kobets, Vadym V. Kiselev, and Aleksandr V. Kharchenko. "Synthesis, Spectral Characteristics, and Molecular Docking Studies of 2-(2,4-Dichlorophenoxy)-N-(2,2,2-trichloro-1-(3-arylthioureido)ethyl)acetamide." In The 4th International Electronic Conference on Applied Sciences. MDPI, 2023. http://dx.doi.org/10.3390/asec2023-15324.

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Asmatulu, R., S. Davluri, and W. Khan. "Fabrications of CNT Based Nanocomposite Fibers From the Recycled Plastics." In ASME 2009 International Mechanical Engineering Congress and Exposition. ASMEDC, 2009. http://dx.doi.org/10.1115/imece2009-12338.

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Electrospinning is a viable technique that spins fibers at different diameters starting from 3 nm to several micron meters. This technique allows the fabrication of random and aligned fibers of diverse structures, such as ribbon or cylindrical shapes. In this work, the spinning solution is prepared by dissolving recycled polystyrene and the mixture of polystyrene and polyvinyl chloride along with carbon nanotubes in dimethyl acetamide (DMAc). The dispersions were then electrospun at various DC voltage, pump speed, concentration and distance. The general morphology of the fibers has been studie
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Reports on the topic "Acetamide"

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Firman, Paul, Edward M. Eyring, Meizhen Xu, Andrea Marchetti, and Sergio Petrucci. Static, Microwave, Infrared, and Visible Permittivity Related to chemical Structure: N-Methylacetamide, N-dimethyl Acetamide and their Mixtures in CCl4 at 32 Deg. C. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada246364.

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