Academic literature on the topic 'Acetylacetonate'

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Journal articles on the topic "Acetylacetonate"

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Zhu, Yuner, and Philip D. Evans. "Surface Protection of Wood with Metal Acetylacetonates." Coatings 11, no. 8 (2021): 916. http://dx.doi.org/10.3390/coatings11080916.

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Metal acetylacetonates are coordination complexes of metal ions and the acetylacetonate anion with diverse uses including catalysts, cross-linking agents and adhesion promotors. Some metal acetylacetonates can photostabilize polymers whereas others are photocatalysts. We hypothesize that the ability of metal acetylacetonates to photostabilize wood will vary depending on the metal in the coordination complex. We test this hypothesis by treating yellow cedar veneers with different acetylacetonates (Co, Cr, Fe, Mn, Ni, and Ti), exposing veneers to natural weathering in Australia, and measuring ch
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Abu-Rayyan, Ahmed, Qutaiba Abu-Salem, Eyad Mallah, et al. "The Acetylacetonate Ion as its E/Z-Isomer in 1,3-Diisopropyl-4,5- dimethylimidazolium Acetylacetonate." Zeitschrift für Naturforschung B 63, no. 12 (2008): 1438–40. http://dx.doi.org/10.1515/znb-2008-1216.

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1,3-Diisopropyl-4,5-dimethylimidazolium acetylacetonate (2) is obtained from 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol- 2-ylidene (1) and acetylacetone. Its crystal structure reveals the presence of ion pairs linked by C-H ··· O hydrogen bonds. In 2, the acetylacetonate ion adopts the structure of its E/Z-isomer (C).
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Warneke, Jonas, Willem F. Van Dorp, Petra Rudolf, et al. "Acetone and the precursor ligand acetylacetone: distinctly different electron beam induced decomposition?" Physical Chemistry Chemical Physics 17, no. 2 (2015): 1204–16. http://dx.doi.org/10.1039/c4cp04239e.

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Dikio, Charity W., Ikechukwu P. Ejidike, Fanyana M. Mtunzi, Michael J. Klink, and Ezekiel D. Dikio. "HYDRAZIDE SCHIFF BASES OF ACETYLACETONATE METAL COMPLEXES: SYNTHESIS, SPECTROSCOPIC AND BIOLOGICAL STUDIES." International Journal of Pharmacy and Pharmaceutical Sciences 9, no. 12 (2017): 257. http://dx.doi.org/10.22159/ijpps.2017v9i12.22225.

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Objective: The study was focused on the synthesis and spectroscopic studies of metal acetylacetonates and their complexes using bidentate Schiff-base ligands (NO), evaluation of their in-vitro antibacterial potentials against pathogenic microorganism.Methods: Acetylacetonate salts of Cobalt(II), Manganese(II) and Magnesium(II) were prepared by reacting their metal hydroxides with acetylacetone. The metal complexes of N'-{(E)-[4-(diethylamino)-2-hydroxyphenyl]methylidene}-4-nitrobenzohydrazide (HL1), N'-{(E)-[4-(diethylamino)-2-hydroxyphenyl]methylidene}-4-methoxybenzohydrazide (HL2) obtained f
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Зломанов, Владимир Павлович, Родион Сергеевич Эшмаков, and Игорь Владиславович Пролубщиков. "Formation of a solvate of manganese(III) acetylacetonate with chloroform." Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases 24, no. 1 (2022): 29–32. http://dx.doi.org/10.17308/kcmf.2022.24/9052.

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Metal acetylacetonates are coordination compounds consisting of the acetylacetonate anion (CH3COCHCOCH3, indicated as acac) and metal ions. Typically, both oxygen atoms of the anion bind with the metal and form a six-membered chelate ring. The simplest complexes have the formulas M(acac)3 and M(acac)2. Many complexes are soluble in organic solvents, and such solutions are used for the synthesis of catalysts. The processes of formation of solvates of acetylacetonates of various metals have not been studied properly. It should be noted that the determination of the composition and properties of
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Baldo, Bianca, Carlos Cruz, Diego Venegas-Yazigi, Andres Vega та Verónica Paredes-García. "catena-Poly[tris(μ3-acetylacetonato)nickelate(II)sodium(I)]". Acta Crystallographica Section C Crystal Structure Communications 69, № 5 (2013): 506–8. http://dx.doi.org/10.1107/s0108270113009797.

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The title complex, [NaNi(C5H7O2)3]n, contains an anionic tris(acetylacetonato)nickelate(II) unit, [Ni(acac)3]−(acac is acetylacetonate), with a highly regular octahedral coordination geometry. The NiIIcation lies on a Wyckoffasite, resulting inD3symmetry of the anion. Charge balance is provided by sodium cations, which occupy Wyckoff typebsites. Each sodium cation is surrounded by two [Ni(acac)3]−anions, each of which is connected to the alkali metal through three O atoms, in afacconfiguration. This arrangement leads to the formation of linear [Na{Ni(acac)3}]nchains along thecaxis. The Ni...Na
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Bennett, Martin A., Thomas R. Mitchell, Mark R. Stevens та Anthony C. Willis. "Mono- and bis-(acetylacetonato) complexes of arene-ruthenium(II) and arene-osmium(II): variation of the binding mode of η1-acetylacetonate with the nature of the arene". Canadian Journal of Chemistry 79, № 5-6 (2001): 655–69. http://dx.doi.org/10.1139/v01-076.

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The mono(acetylacetonato) complexes [MCl(O,O'-acac)(η6-arene)] (M = Ru, Os, arene = C6H6, 1,3,5-C6H3Me3, C6Me6; M = Os, arene = 1,2-C6H4Me2, 1,2,3-C6H3Me3), which are formed from [MCl2(η6-arene)]2 and thallium or sodium acetylacetonate, react with thallium acetylacetonate to give bis(acetylacetonato) complexes [M(O,O'-acac)(η1-acac)(η6-arene)]. The η1-acac ligand is bound through the gamma-carbon atom for M = Ru, Os, arene = C6H6; M = Os, arene = 1,2-C6H4Me2, 1,2,3-C6H3Me3 and through a keto-oxygen atom for M = Ru, Os, arene = 1,3,5-C6H3Me3, C6Me6, the difference being attributed to a combinat
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Makarenko, Alexander M., Sergey V. Trubin, and Kseniya V. Zherikova. "Breaking through the Thermodynamics “Wilds” of Metal–Organic Chemical Vapor Deposition Precursors: Metal tris-Acetylacetonates." Coatings 13, no. 8 (2023): 1458. http://dx.doi.org/10.3390/coatings13081458.

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Metal acetylacetonates belong to the β-diketonate family and are considered as classics among precursors for metal–organic chemical vapor deposition (MOCVD). The success of film preparation is crucially dependent on the volatilization thermodynamics of the precursors used. Data on the volatilization thermodynamics of metal acetylacetonates are in huge disarray. We amassed and analyzed experimental data on the vapor pressures and on the enthalpies and entropies of fusion, vaporization, and sublimation of acetylacetonate tris-complexes of metals(III) (Al, Sc, Cr, Mn, Fe, Co, Ru, Rh, In, and Ir)
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Atencio, Reinaldo, Gustavo Chacón, Lisbeth Mendoza, et al. "Chemistry of transition-metal complexes containing functionalized phosphines: synthesis and structural analysis of rhodium(I) complexes containing allyl and cyanoalkylphosphines." Acta Crystallographica Section C Structural Chemistry 76, no. 9 (2020): 932–46. http://dx.doi.org/10.1107/s2053229620011420.

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A series of related acetylacetonate–carbonyl–rhodium compounds substituted by functionalized phosphines has been prepared in good to excellent yields by the reaction of [Rh(acac)(CO)2] (acac is acetylacetonate) with the corresponding allyl-, cyanomethyl- or cyanoethyl-substituted phosphines. All compounds were fully characterized by 31P, 1H, 13C NMR and IR spectroscopy. The X-ray structures of (acetylacetonato-κ2 O,O′)(tert-butylphosphanedicarbonitrile-κP)carbonylrhodium(I), [Rh(C5H7O2)(CO)(C8H13N2)] or [Rh(acac)(CO)(tBuP(CH2CN)2}] (2b), (acetylacetonato-κ2 O,O′)carbonyl[3-(diphenylphosphanyl)
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David, Lawrence D., Ronald M. Anderson, Joseph M. Dynys, Charles C. Goldsmith, and Andrew Szule. "Synthesis and characterization of cordierite from acetylacetonate/alkoxide precursors." Journal of Materials Research 8, no. 7 (1993): 1697–702. http://dx.doi.org/10.1557/jmr.1993.1697.

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Syntheses of ultrafine glass powders in the MgO–Al2O3–SiO2 ternary oxide system were effected by drying and calcining sols derived from acetylacetonate-tetraethoxysilane ethanol solutions. A mixture of magnesium and aluminum acetylacetonates, dissolved with Si(OC2H5)4 in an ethanol solution in a 2:4:5 Mg: Al: Si mole ratio, was hydrolyzed, spray-dried, and calcined to yield a glass powder of 70 Å primary particle size, which sintered to densities ≥ 2.5 g/cm3 and which formed μ-cordierite as the only crystalline phase below 1000 °C. Incorporation of dopant quantities of boron and phosphorus, vi
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Dissertations / Theses on the topic "Acetylacetonate"

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Keceli, Ezgi. "Ruthenium(iii) Acetylacetonate." Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/3/12607230/index.pdf.

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Ruthenium(III) acetylacetonate was employed for the first time as homogeneous catalyst in the hydrolysis of sodium borohydride. Ruthenium(III) acetylacetonate was not reduced by sodium borohydride under the experimental conditions and remains unchanged after the catalysis, as shown by FT-IR and UV-Vis spectroscopic characterization. Poisoning experiments with mercury, carbon disulfide or trimethylphosphite provide compelling evidence that ruthenium(III) acetylacetonate is indeed a homogenous catalyst in the hydrolysis of sodium borohydride. Kinetics of the ruthenium(III) acetylacetonate ca
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Khosla, Chetna Templeton J. L. "Intermediate oxidation state tungsten acetylacetonate complexes." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2009. http://dc.lib.unc.edu/u?/etd,2296.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2009.<br>Title from electronic title page (viewed Jun. 26, 2009). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.
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Cross, Peggi Sue 1960. "The synthesis of aluminum hydrous oxide from aluminum acetylacetonate." Thesis, The University of Arizona, 1990. http://hdl.handle.net/10150/277276.

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A method for the preparation of submicron, monodispersed, spherical particles of aluminum hydrous oxide has been developed. The method consists of the hydrolysis of aluminum acetylacetonate in alcoholic solution by the direct addition of a base at room temperature. The effects of the process parameters including temperature, solvent, type and concentration of base, aluminum acetylacetonate concentration, and stirring time are examined as well as the process reproducibility, particle composition and particle stability. Results obtained have shown that monodispersed particles can be formed with
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Unel, Ebru. "Ruthenium(iii) Acetylacetonate As Catalyst Precursor In The Dehydrogenation Of Dimethylamine-borane." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12612980/index.pdf.

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Amine boranes have recently been considered as solid hydrogen storage materials with high capability of hydrogen storage. Dimethylamine borane is one of the promising amine boranes with high theoretical gravimetric capacity of 16.9 wt%. Dimethylamine borane can undergo dehydrogenation only in the presence of a suitable catalyst at moderate temperature. In this project, throughout the dehydrogenation of dimethylamine borane (DMAB), the catalytic activity of ruthenium(III) acetylacetonate was examined for the first time. During the catalytic reaction, formation of a new in-situ ruthenium(II) s
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De, Dea Silvia. "Nano-scale magnetic film formation by decompression of supercritical CO₂/ferric acetylacetonate solutions." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2008. http://wwwlib.umi.com/cr/ucsd/fullcit?p3296800.

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Thesis (Ph. D.)--University of California, San Diego, 2008.<br>Title from first page of PDF file (viewed March 24, 2008). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references.
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O'Connor, Helen. "The use of acetylacetonate-based paramagnetic metalloligands in the construction of supramolecular magnetic coordination capsules." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/29547.

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In molecular magnetism, rational design and serendipity have played complementary roles in the synthesis of complexes which display a breadth of interesting physical characteristics. These range from the basic understanding of magneto‐structural correlations, to more complicated phenomena such as slow relaxation of the magnetisation, spin frustration effects, and tuning magnetic interactions with a view to spintronics. The inherent physical properties of these complexes has already afforded molecules which can behave as single‐molecule magnets, singlechain magnets, single‐ion magnets, magnetic
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Saraidaridis, James D. "Analysis and performance of symmetric nonaqueous redox flow batteries." Thesis, University of Oxford, 2017. http://ora.ox.ac.uk/objects/uuid:2e3533c8-7540-4c14-858f-782292343ae3.

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Symmetric nonaqueous redox flow batteries (RFBs) use negative and positive battery solutions of the same solution composition to operate at high cell voltages. This research effort targets these systems since they offer performance improvements derived from using nonaqueous systems and symmetric active species. Nonaqueous solutions permit significantly higher cell voltages than state-of-the-art aqueous RFBs and symmetric active species chemistries reduce the required complexity of cell reactors. Both performance advantages correspond to significant cost improvements beyond already commercially
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Winter, Silke. "Koordinationspolymere auf der Basis neuer oligofunktioneller Pyridinliganden." Doctoral thesis, Technische Universitaet Bergakademie Freiberg Universitaetsbibliothek &quot;Georgius Agricola&quot, 2009. http://nbn-resolving.de/urn:nbn:de:swb:105-6346328.

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Gegenstand der vorliegenden Arbeit ist der Entwurf und die Realisierung kristalliner organisch-anorganischer Festkörper mit wohldefinierten Hohlraumstrukturen auf der Grundlage von Metallkoordinationen. Basierend auf generellen Prinzipien des Crystal Engineering wurden anhand von drei Typen oligofunktioneller Liganden und ausgewählter koordinationschemischer Synthesemethoden neue polymere Komplexverbindungen hergestellt, die im Hinblick auf Koordinationsgeometrie und Liganddimensionalität strukturspezifische Unterschiede aufweisen. Diese sind durch Anwendung von strukturanalytischen Methoden b
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Nielsen, Guilherme Fernandes [UNESP]. "Filmes orgânicos contendo óxido de alumínio depositados a plasma." Universidade Estadual Paulista (UNESP), 2011. http://hdl.handle.net/11449/99661.

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Made available in DSpace on 2014-06-11T19:30:18Z (GMT). No. of bitstreams: 0 Previous issue date: 2011-06-20Bitstream added on 2014-06-13T21:00:48Z : No. of bitstreams: 1 nielsen_gf_me_bauru.pdf: 1826165 bytes, checksum: 6fa4e6c04592e7eb812d72fe4f9a2db3 (MD5)<br>Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)<br>Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)<br>Filmes finos de alumina vêm sendo amplamente estudados em função de suas propriedades físicas e químicas. Em aplicações industriais, filmes de alumina são utilizados, por exemplo, em ferrament
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Demiralp, Tulin. "Testing The Ruthenium(iii) Acetylacetonate And 1,2-bis(diphenylphosphino)ethane System As Homogeneous Catalyst In The Hydrolysis Of Sodium Borohydride." Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609539/index.pdf.

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Recent studies have shown that ruthenium(III) acetylacetonate is acting as homogeneous catalyst in the hydrolysis of sodium borohydride. Although trimethlyphosphite is found to be a poison for the catalytic hydrolysis of sodium borohydride, a longer observation of the reaction in the presence of ruthenium(III) acetylacetonate and 2 equivalent trimethylphosphite shows an unexpected enhancement in the catalytic activity after an induction period. The same rate enhancement is observed when 2 equivalent triphenylphosphine is added into the reaction solution. Addition of 1 equivalent 1,2-bis(diphen
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Books on the topic "Acetylacetonate"

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Xia, Wenyu. The keto-enol equilibrium of pure acetylacetone investigated by nuclear magnetic resonance: A thesis in Chemistry. 1995.

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Book chapters on the topic "Acetylacetonate"

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Fernelius, W. Conard, Julian E. Blanch, Burl E. Bryant, Kazuji Terada, Russell S. Drago, and John K. Stille. "Chromium(III) Acetylacetonate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132364.ch35.

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Bryant, Burl E., W. Conard Fernelius, Daryle H. Busch, R. Carl Stoufer, and Wilmer Stratton. "Cobalt(III) Acetylacetonate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132364.ch53.

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Charles, Robert G., Sam N. Holter, and W. Conard Fernelius. "Manganese(II) Acetylacetonate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132371.ch51.

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Bryant, Burl E., W. Conard Fernelius, Daryle H. Busch, R. Carl Stoufer, and Wilmer Stratton. "Vanadium(IV) Oxy(acetylacetonate)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132364.ch30.

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Young, Ralph C., Arnold Arch, Marvin R. Frederick, and W. Conard Fernelius. "Zirconium Acetylacetonate [Tetrakis(2,4-pentanediono)zirconium]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch35.

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Young, Ralph C., Julian Kovitz, and L. E. Marchi. "Thorium Acetylacetonate (Tetrakis(2,4-Pentanediono)Thorium)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch36.

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Arch, Arnold, Ralph C. Young, and Edgar E. Lineken. "Beryllium Acetylacetonate: [Bis(2,4-pentanediono)beiyllium]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch5.

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Young, Ralph C., and James P. McReynolds. "Aluminum Acetylacetonate: [Tris (2,4-pentanediono) aluminum]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch9.

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Manríquez, J. M., E. E. Bunel, B. Oelckers, E. Román, C. Vv́squez, and J. S. Miller. "Bis(2,4-Pentanedionato)Iron(II) [Iron(II) Bis(Acetylacetonate)]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132623.ch44.

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Davydenko, Lyudmyla, Yuri Plyuto, and Eva Maria Moser. "Sol-Gel Silica Films Doped with Chromium (III) Acetylacetonate on Aluminium Substrate." In Sol-Gel Methods for Materials Processing. Springer Netherlands, 2008. http://dx.doi.org/10.1007/978-1-4020-8514-7_18.

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Conference papers on the topic "Acetylacetonate"

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Osadchuk, Oleksandr, Volodymyr Martyniuk, Olena Semenova, Iaroslav Osadchuk, Mariya Evseeva, and Tetyana Yushchenko. "Electrical Properties of Semiconducting Heterometallic (Copper, Yttrium)-Containing Acetylacetonate." In 2020 IEEE 40th International Conference on Electronics and Nanotechnology (ELNANO). IEEE, 2020. http://dx.doi.org/10.1109/elnano50318.2020.9088825.

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Pakhnutova, Evgeniya, and Yuriy Slizhov. "Adsorption properties of Silochrom chemically modified with nickel acetylacetonate." In PROSPECTS OF FUNDAMENTAL SCIENCES DEVELOPMENT (PFSD-2017): Proceedings of the XIV International Conference of Students and Young Scientists. Author(s), 2017. http://dx.doi.org/10.1063/1.5009831.

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Hongyu Zhang, Yanyan Wang, Guoqiang Tao, Yongming Chai, and Guohe Que. "Chemical synthesis of Fe nanocrystals via hydrogenation of ferric acetylacetonate." In Environment (ICMREE). IEEE, 2011. http://dx.doi.org/10.1109/icmree.2011.5930744.

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Dampf, Sara J., and Timothy M. Korter. "Deriving Elastic Parameters from Lattice Vibrations in Copper (II) Acetylacetonate." In 2019 44th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz). IEEE, 2019. http://dx.doi.org/10.1109/irmmw-thz.2019.8873864.

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Baum, T. H. "Laser-induced vapor deposition of gold." In International Laser Science Conference. Optica Publishing Group, 1986. http://dx.doi.org/10.1364/ils.1986.fg4.

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Dimethylgold (III) acetylacetonate and its fluorinated derivatives are ideal precursors for the deposition of gold. Thermal decomposition from the vapor phase allows high quality metal to be produced. A comparison of the gold complex utilized and the overall rates of deposition are highlighted; the presence of fluorine substituents in the complex causes an increase in the complex vapor pressure and in the observed rates of gold deposition.
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Mata, V., A. Maldonado, and M. de la L. Olvera. "Effect of milling speed on the precursor zinc acetylacetonate destined to obtain ZnO thin films." In 2016 13th International Conference on Electrical Engineering, Computing Science and Automatic Control (CCE). IEEE, 2016. http://dx.doi.org/10.1109/iceee.2016.7751260.

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Shedd, G. M., H. Lezec, A. D. Dubner, and J. Melngailis. "Gold Deposition From an Organometallic Gas Induced by Incident Ga+, Ar+, or Si+ Ions*." In Microphysics of Surfaces, Beams, and Adsorbates. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/msba.1987.tua4.

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If a local gas ambient of 10−3 to 10−2 torr pressure of a metal halide, organometallic, or hydrocarbon gas is produced at a surface, deposition of material can be induced where ions are incident. The ion beam is thought to cause the breakup of molecules adsorbed on the surface. Deposition of a mixture of Al, C, and O has been reported(1) from a gas of Al(CH3)3 and mixture of W and O from a gas of WF6. We have used a capillary gas feed of dimethyl gold hexafluoro acetylacetonate (C7H7F6O2Au) and induced gold deposition using a focused 15kV Ga+ ion beam or broad beams of 50kV Si+ and 0.75kV Ar+.
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Shafeev, George A., and Lucien D. Laude. "Laser-assisted deposition of thin films onto transparent substrates from liquid-phase organometallic precursor: iron acetylacetonate." In ECO4 (The Hague '91), edited by Tommaso Letardi and Lucien D. Laude. SPIE, 1991. http://dx.doi.org/10.1117/12.46964.

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Kusaka, Y., J. Leppäniemi, A. Sneck, et al. "Reverse offset printing of metal acetylacetonate inks and its applications to a solution-processed IGZO-TFT." In 2018 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2018. http://dx.doi.org/10.7567/ssdm.2018.j-4-02.

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Zhuang, Junping, Lu Lin, Chunsheng Pang, and Beixiao Zhang. "Catalytic Conversion of Glucose to 5-hydroxymethylfurfural over Aluminum Acetylacetonate in the Two-phase Water-Methylisobutylketone System." In 2010 International Conference on Digital Manufacturing and Automation (ICDMA 2010). IEEE, 2010. http://dx.doi.org/10.1109/icdma.2010.327.

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Reports on the topic "Acetylacetonate"

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Jones, A., A. Packard, S. Treves, and A. Davison. Studies in technetium chemistry, Project 1: Evaluation of technetium acetylacetonates as potential cerebral blood flow agents, Project 2. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7002570.

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