Relevant bibliographies by topics / Acetylacetonates

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  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters
  4. Conference papers
  5. Reports

Academic literature on the topic 'Acetylacetonates'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Acetylacetonates"

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Zhu, Yuner, and Philip D. Evans. "Surface Protection of Wood with Metal Acetylacetonates." Coatings 11, no. 8 (2021): 916. http://dx.doi.org/10.3390/coatings11080916.

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Metal acetylacetonates are coordination complexes of metal ions and the acetylacetonate anion with diverse uses including catalysts, cross-linking agents and adhesion promotors. Some metal acetylacetonates can photostabilize polymers whereas others are photocatalysts. We hypothesize that the ability of metal acetylacetonates to photostabilize wood will vary depending on the metal in the coordination complex. We test this hypothesis by treating yellow cedar veneers with different acetylacetonates (Co, Cr, Fe, Mn, Ni, and Ti), exposing veneers to natural weathering in Australia, and measuring ch
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Makarenko, Alexander M., Sergey V. Trubin, and Kseniya V. Zherikova. "Breaking through the Thermodynamics “Wilds” of Metal–Organic Chemical Vapor Deposition Precursors: Metal tris-Acetylacetonates." Coatings 13, no. 8 (2023): 1458. http://dx.doi.org/10.3390/coatings13081458.

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Metal acetylacetonates belong to the β-diketonate family and are considered as classics among precursors for metal–organic chemical vapor deposition (MOCVD). The success of film preparation is crucially dependent on the volatilization thermodynamics of the precursors used. Data on the volatilization thermodynamics of metal acetylacetonates are in huge disarray. We amassed and analyzed experimental data on the vapor pressures and on the enthalpies and entropies of fusion, vaporization, and sublimation of acetylacetonate tris-complexes of metals(III) (Al, Sc, Cr, Mn, Fe, Co, Ru, Rh, In, and Ir)
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David, Lawrence D., Ronald M. Anderson, Joseph M. Dynys, Charles C. Goldsmith, and Andrew Szule. "Synthesis and characterization of cordierite from acetylacetonate/alkoxide precursors." Journal of Materials Research 8, no. 7 (1993): 1697–702. http://dx.doi.org/10.1557/jmr.1993.1697.

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Syntheses of ultrafine glass powders in the MgO–Al2O3–SiO2 ternary oxide system were effected by drying and calcining sols derived from acetylacetonate-tetraethoxysilane ethanol solutions. A mixture of magnesium and aluminum acetylacetonates, dissolved with Si(OC2H5)4 in an ethanol solution in a 2:4:5 Mg: Al: Si mole ratio, was hydrolyzed, spray-dried, and calcined to yield a glass powder of 70 Å primary particle size, which sintered to densities ≥ 2.5 g/cm3 and which formed μ-cordierite as the only crystalline phase below 1000 °C. Incorporation of dopant quantities of boron and phosphorus, vi
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Зломанов, Владимир Павлович, Родион Сергеевич Эшмаков, and Игорь Владиславович Пролубщиков. "Formation of a solvate of manganese(III) acetylacetonate with chloroform." Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases 24, no. 1 (2022): 29–32. http://dx.doi.org/10.17308/kcmf.2022.24/9052.

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Metal acetylacetonates are coordination compounds consisting of the acetylacetonate anion (CH3COCHCOCH3, indicated as acac) and metal ions. Typically, both oxygen atoms of the anion bind with the metal and form a six-membered chelate ring. The simplest complexes have the formulas M(acac)3 and M(acac)2. Many complexes are soluble in organic solvents, and such solutions are used for the synthesis of catalysts. The processes of formation of solvates of acetylacetonates of various metals have not been studied properly. It should be noted that the determination of the composition and properties of
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Dziemidkiewicz, Anna, Magdalena Maciejewska, and Martyna Pingot. "Thermal analysis of halogenated rubber cured with a new cross-linking system." Journal of Thermal Analysis and Calorimetry 138, no. 6 (2019): 4395–405. http://dx.doi.org/10.1007/s10973-019-08881-7.

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Abstract The aim of this work was to examine the influence of new curing agents proposed for brominated butyl rubber (BIIR) on the cross-linking process of rubber compounds and the thermal behavior of the vulcanizates. Rubber blends that were filled with carbon black and contained acetylacetonates of different transition metals in the presence of triethanolamine (TEOA) as new cross-linking agents were prepared. The performed studies showed that metal acetylacetonates (Me(acac)) are effective cross-linking agents for BIIR, which was confirmed by high values of the torque increment (∆M) and sign
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Halz, Jan Henrik, Christian Heiser, Christoph Wagner, and Kurt Merzweiler. "Syntheses and crystal structures of three [M(acac)2(TMEDA)] complexes (M = Mn, Fe and Zn)." Acta Crystallographica Section E Crystallographic Communications 76, no. 1 (2020): 66–71. http://dx.doi.org/10.1107/s2056989019016372.

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The complexes bis(acetylacetonato-κ2 O,O′)(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)manganese(II), [Mn(C5H7O2)2(C6H16N2)], bis(acetylacetonato-κ2 O,O′)(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)iron(II), [Fe(C5H7O2)2(C6H16N2)], and bis(acetylacetonato-κ2 O,O′)(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)zinc(II), [Zn(C5H7O2)2(C6H16N2)], were synthesized from the reaction of the corresponding metal acetylacetonates [M(acac)2(H2O)2] with N,N,N′,N′-tetramethylethylenediamine (TMEDA) in toluene. Each of the complexes displays a central metal atom which is nearly octahedrally surrounded by
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Laode, A. Kadir, Azis Thamrin, . Imran, Ode Kadidae La, Usman Ida, and . Agusriyadin. "Synthesis and Characterization of Bis-Acetylacetonatozink (II) [(Zn(acac)2(H2o)]." International Journal of Current Science Research and Review 07, no. 06 (2024): 4315–19. https://doi.org/10.5281/zenodo.12577863.

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Abstract : The synthesis of the bis-acetylacetonate zink (II) monohydrate complex [Zn(acac)<sub>2</sub>(H<sub>2</sub>O)] has been conducted. FTIR analysis, TGA-DSC, and SEM micrographic analysis performed complex characterization. The yield of the complex compound [Zn(acac)<sub>2</sub>(H<sub>2</sub>O)] was 36.24% using NaOH as a pH regulator. Based on the FTIR characterization of the typical absorption complex [Zn(acac)<sub>2</sub>(H<sub>2</sub>O)] appears at 763.88 cm<sup>-1</sup>&nbsp;for Zn-O, C-H at 933.9 cm<sup>-1</sup>&nbsp;and 1020 cm<sup>-1</sup>, C=C and C=O at 1516 cm<sup>-1</sup>, 1
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Dziemidkiewicz, Anna, and Magdalena Maciejewska. "Manganese and Nickel Acetylacetonates as Curatives for Chloroprene Rubber Based on Heck’s Reaction." Materials 14, no. 4 (2021): 807. http://dx.doi.org/10.3390/ma14040807.

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The commonly used curing system for chloroprene rubber (CR) is a combination of two metal oxides, such as magnesium oxide (MgO) and zinc oxide (ZnO). Application of MgO and ZnO enables to obtain a good balance between processability of rubber compounds and mechanical properties of the vulcanizates. Despite high activity in crosslinking reactions, ZnO is classified as ecotoxic to aquatic organisms, thus environmental legislation requires its quantity in technology to be limited. In our studies more environmentally friendly curing systems were applied, which enabled eliminating ZnO from CR compo
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Panasenko, Alexander E., Lyudmila A. Zemnukhova, and Nicolay P. Shapkin. "Fabrication and extraction of silicon-containing products from rice husks." Butlerov Communications 61, no. 1 (2020): 133–39. http://dx.doi.org/10.37952/roi-jbc-01/20-61-1-133.

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To isolate silicon-containing products from plant materials, the reaction of interaction of rice husks with triethanolamine and ethylene glycol have been investigated. The effect of pretreatment of raw materials and the reaction conditions on the yield of soluble products containing silicon has been studied. It has been shown that the highest enrichment of rice husks with silicon occurs upon its treatment with concentrated hydrochloric acid and the Schweitzer's reagent. The highest degree of silicon extraction (69%) was achieved at using native rice husks and vanadyl acetylacetonate as a catal
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Dziemidkiewicz, Anna, Martyna Pingot, and Magdalena Maciejewska. "METAL COMPLEXES AS NEW PRO-ECOLOGICAL CROSSLINKING AGENTS FOR CHLOROPRENE RUBBER BASED ON HECK COUPLING REACTION." Rubber Chemistry and Technology 92, no. 3 (2019): 589–97. http://dx.doi.org/10.5254/rct.19.81465.

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ABSTRACT The influence of new pro-ecological curing agents on the crosslinking process of chloroprene rubber (CR) was examined. The proposed curing system used a simpler recipe (no need to apply harmful products such as zinc oxide and ethylene thiourea) and cost less than standard metal oxides. It was expected that the mechanism of crosslinking would be similar to that of Heck-type reactions. Heck-type reactions are powerful tools for the creation of new C=C bonds. They provide the simplest and most efficient way to synthesize a variety of important compounds used in many areas, such as pharma
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Dissertations / Theses on the topic "Acetylacetonates"

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FILOTTI, LIVIU. "Composites cerine - alumine. Preparation et caracterisation des precurseurs acetylacetonates de cerium. Reduction de la cerine en conditions douces. Essais de metallisation selective." Paris 7, 1998. http://www.theses.fr/1998PA077054.

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Des echantillons de cerine hautement dispersee sur l'alumine sont prepares soit par impregnation de ce(no#3)#3. 6h#2o soit par greffage du chelate ce(acac)#4 (acac = pentane-2,4-dionato-o,o). Plusieurs ameliorations sont d'abord apportees aux procedures de synthese et a la caracterisation de ce chelate de cerium(iv). Pour le complexe de cerium(iii) avec le meme ligand, ce(acac)#3. (h#2o)#2. H#2o, une structure est proposee a partir du diagramme de drx et de donnees spectrales (ir, uv-visible, proche ir). Les especes intermediaires resultant de l'impregnation ou du greffage sont ensuite analyse
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Keceli, Ezgi. "Ruthenium(iii) Acetylacetonate." Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/3/12607230/index.pdf.

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Ruthenium(III) acetylacetonate was employed for the first time as homogeneous catalyst in the hydrolysis of sodium borohydride. Ruthenium(III) acetylacetonate was not reduced by sodium borohydride under the experimental conditions and remains unchanged after the catalysis, as shown by FT-IR and UV-Vis spectroscopic characterization. Poisoning experiments with mercury, carbon disulfide or trimethylphosphite provide compelling evidence that ruthenium(III) acetylacetonate is indeed a homogenous catalyst in the hydrolysis of sodium borohydride. Kinetics of the ruthenium(III) acetylacetonate ca
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Khosla, Chetna Templeton J. L. "Intermediate oxidation state tungsten acetylacetonate complexes." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2009. http://dc.lib.unc.edu/u?/etd,2296.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2009.<br>Title from electronic title page (viewed Jun. 26, 2009). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.
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Cross, Peggi Sue 1960. "The synthesis of aluminum hydrous oxide from aluminum acetylacetonate." Thesis, The University of Arizona, 1990. http://hdl.handle.net/10150/277276.

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A method for the preparation of submicron, monodispersed, spherical particles of aluminum hydrous oxide has been developed. The method consists of the hydrolysis of aluminum acetylacetonate in alcoholic solution by the direct addition of a base at room temperature. The effects of the process parameters including temperature, solvent, type and concentration of base, aluminum acetylacetonate concentration, and stirring time are examined as well as the process reproducibility, particle composition and particle stability. Results obtained have shown that monodispersed particles can be formed with
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Nerbel, Jörg. "Darstellung, Charakterisierung und Umsetzung von Alkoxiden und Acetylacetonaten des Aluminiums." [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=967485274.

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Unel, Ebru. "Ruthenium(iii) Acetylacetonate As Catalyst Precursor In The Dehydrogenation Of Dimethylamine-borane." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12612980/index.pdf.

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Amine boranes have recently been considered as solid hydrogen storage materials with high capability of hydrogen storage. Dimethylamine borane is one of the promising amine boranes with high theoretical gravimetric capacity of 16.9 wt%. Dimethylamine borane can undergo dehydrogenation only in the presence of a suitable catalyst at moderate temperature. In this project, throughout the dehydrogenation of dimethylamine borane (DMAB), the catalytic activity of ruthenium(III) acetylacetonate was examined for the first time. During the catalytic reaction, formation of a new in-situ ruthenium(II) s
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De, Dea Silvia. "Nano-scale magnetic film formation by decompression of supercritical CO₂/ferric acetylacetonate solutions." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2008. http://wwwlib.umi.com/cr/ucsd/fullcit?p3296800.

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Thesis (Ph. D.)--University of California, San Diego, 2008.<br>Title from first page of PDF file (viewed March 24, 2008). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references.
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O'Connor, Helen. "The use of acetylacetonate-based paramagnetic metalloligands in the construction of supramolecular magnetic coordination capsules." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/29547.

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In molecular magnetism, rational design and serendipity have played complementary roles in the synthesis of complexes which display a breadth of interesting physical characteristics. These range from the basic understanding of magneto‐structural correlations, to more complicated phenomena such as slow relaxation of the magnetisation, spin frustration effects, and tuning magnetic interactions with a view to spintronics. The inherent physical properties of these complexes has already afforded molecules which can behave as single‐molecule magnets, singlechain magnets, single‐ion magnets, magnetic
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Saraidaridis, James D. "Analysis and performance of symmetric nonaqueous redox flow batteries." Thesis, University of Oxford, 2017. http://ora.ox.ac.uk/objects/uuid:2e3533c8-7540-4c14-858f-782292343ae3.

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Symmetric nonaqueous redox flow batteries (RFBs) use negative and positive battery solutions of the same solution composition to operate at high cell voltages. This research effort targets these systems since they offer performance improvements derived from using nonaqueous systems and symmetric active species. Nonaqueous solutions permit significantly higher cell voltages than state-of-the-art aqueous RFBs and symmetric active species chemistries reduce the required complexity of cell reactors. Both performance advantages correspond to significant cost improvements beyond already commercially
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Winter, Silke. "Koordinationspolymere auf der Basis neuer oligofunktioneller Pyridinliganden." Doctoral thesis, Technische Universitaet Bergakademie Freiberg Universitaetsbibliothek &quot;Georgius Agricola&quot, 2009. http://nbn-resolving.de/urn:nbn:de:swb:105-6346328.

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Gegenstand der vorliegenden Arbeit ist der Entwurf und die Realisierung kristalliner organisch-anorganischer Festkörper mit wohldefinierten Hohlraumstrukturen auf der Grundlage von Metallkoordinationen. Basierend auf generellen Prinzipien des Crystal Engineering wurden anhand von drei Typen oligofunktioneller Liganden und ausgewählter koordinationschemischer Synthesemethoden neue polymere Komplexverbindungen hergestellt, die im Hinblick auf Koordinationsgeometrie und Liganddimensionalität strukturspezifische Unterschiede aufweisen. Diese sind durch Anwendung von strukturanalytischen Methoden b
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Book chapters on the topic "Acetylacetonates"

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Malhotra, Ripudaman, and David S. Ross. "Aromatic Nitration in Liquid Nitrogen Tetroxide Promoted by Metal Acetylacetonates." In ACS Symposium Series. American Chemical Society, 1996. http://dx.doi.org/10.1021/bk-1996-0623.ch004.

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Fernelius, W. Conard, Julian E. Blanch, Burl E. Bryant, Kazuji Terada, Russell S. Drago, and John K. Stille. "Chromium(III) Acetylacetonate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132364.ch35.

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Bryant, Burl E., W. Conard Fernelius, Daryle H. Busch, R. Carl Stoufer, and Wilmer Stratton. "Cobalt(III) Acetylacetonate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132364.ch53.

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Charles, Robert G., Sam N. Holter, and W. Conard Fernelius. "Manganese(II) Acetylacetonate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132371.ch51.

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Charles, Robert G., and B. E. Bryant. "Acetylacetonato manganese(III)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132388.ch49.

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Bryant, Burl E., W. Conard Fernelius, Daryle H. Busch, R. Carl Stoufer, and Wilmer Stratton. "Vanadium(IV) Oxy(acetylacetonate)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132364.ch30.

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Young, Ralph C., Arnold Arch, Marvin R. Frederick, and W. Conard Fernelius. "Zirconium Acetylacetonate [Tetrakis(2,4-pentanediono)zirconium]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch35.

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Young, Ralph C., Julian Kovitz, and L. E. Marchi. "Thorium Acetylacetonate (Tetrakis(2,4-Pentanediono)Thorium)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch36.

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Arch, Arnold, Ralph C. Young, and Edgar E. Lineken. "Beryllium Acetylacetonate: [Bis(2,4-pentanediono)beiyllium]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch5.

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Young, Ralph C., and James P. McReynolds. "Aluminum Acetylacetonate: [Tris (2,4-pentanediono) aluminum]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch9.

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Conference papers on the topic "Acetylacetonates"

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Faustova, Zhanna, Tatiana Matveeva, and Yuriy Slizhov. "Effect of carrier properties on surface characteristics of sorbents modified with acetylacetonates Ni (II), Cu (II)." In PROSPECTS OF FUNDAMENTAL SCIENCES DEVELOPMENT (PFSD-2017): Proceedings of the XIV International Conference of Students and Young Scientists. Author(s), 2017. http://dx.doi.org/10.1063/1.5009835.

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Osadchuk, Oleksandr, Volodymyr Martyniuk, Olena Semenova, Iaroslav Osadchuk, Mariya Evseeva, and Tetyana Yushchenko. "Electrical Properties of Semiconducting Heterometallic (Copper, Yttrium)-Containing Acetylacetonate." In 2020 IEEE 40th International Conference on Electronics and Nanotechnology (ELNANO). IEEE, 2020. http://dx.doi.org/10.1109/elnano50318.2020.9088825.

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Pakhnutova, Evgeniya, and Yuriy Slizhov. "Adsorption properties of Silochrom chemically modified with nickel acetylacetonate." In PROSPECTS OF FUNDAMENTAL SCIENCES DEVELOPMENT (PFSD-2017): Proceedings of the XIV International Conference of Students and Young Scientists. Author(s), 2017. http://dx.doi.org/10.1063/1.5009831.

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Hongyu Zhang, Yanyan Wang, Guoqiang Tao, Yongming Chai, and Guohe Que. "Chemical synthesis of Fe nanocrystals via hydrogenation of ferric acetylacetonate." In Environment (ICMREE). IEEE, 2011. http://dx.doi.org/10.1109/icmree.2011.5930744.

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Dampf, Sara J., and Timothy M. Korter. "Deriving Elastic Parameters from Lattice Vibrations in Copper (II) Acetylacetonate." In 2019 44th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz). IEEE, 2019. http://dx.doi.org/10.1109/irmmw-thz.2019.8873864.

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Baum, T. H. "Laser-induced vapor deposition of gold." In International Laser Science Conference. Optica Publishing Group, 1986. http://dx.doi.org/10.1364/ils.1986.fg4.

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Dimethylgold (III) acetylacetonate and its fluorinated derivatives are ideal precursors for the deposition of gold. Thermal decomposition from the vapor phase allows high quality metal to be produced. A comparison of the gold complex utilized and the overall rates of deposition are highlighted; the presence of fluorine substituents in the complex causes an increase in the complex vapor pressure and in the observed rates of gold deposition.
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Shedd, G. M., H. Lezec, A. D. Dubner, and J. Melngailis. "Gold Deposition From an Organometallic Gas Induced by Incident Ga+, Ar+, or Si+ Ions*." In Microphysics of Surfaces, Beams, and Adsorbates. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/msba.1987.tua4.

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If a local gas ambient of 10−3 to 10−2 torr pressure of a metal halide, organometallic, or hydrocarbon gas is produced at a surface, deposition of material can be induced where ions are incident. The ion beam is thought to cause the breakup of molecules adsorbed on the surface. Deposition of a mixture of Al, C, and O has been reported(1) from a gas of Al(CH3)3 and mixture of W and O from a gas of WF6. We have used a capillary gas feed of dimethyl gold hexafluoro acetylacetonate (C7H7F6O2Au) and induced gold deposition using a focused 15kV Ga+ ion beam or broad beams of 50kV Si+ and 0.75kV Ar+.
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Mata, V., A. Maldonado, and M. de la L. Olvera. "Effect of milling speed on the precursor zinc acetylacetonate destined to obtain ZnO thin films." In 2016 13th International Conference on Electrical Engineering, Computing Science and Automatic Control (CCE). IEEE, 2016. http://dx.doi.org/10.1109/iceee.2016.7751260.

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Shafeev, George A., and Lucien D. Laude. "Laser-assisted deposition of thin films onto transparent substrates from liquid-phase organometallic precursor: iron acetylacetonate." In ECO4 (The Hague '91), edited by Tommaso Letardi and Lucien D. Laude. SPIE, 1991. http://dx.doi.org/10.1117/12.46964.

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Kusaka, Y., J. Leppäniemi, A. Sneck, et al. "Reverse offset printing of metal acetylacetonate inks and its applications to a solution-processed IGZO-TFT." In 2018 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2018. http://dx.doi.org/10.7567/ssdm.2018.j-4-02.

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Reports on the topic "Acetylacetonates"

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Jones, A., A. Packard, S. Treves, and A. Davison. Studies in technetium chemistry, Project 1: Evaluation of technetium acetylacetonates as potential cerebral blood flow agents, Project 2. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7002570.

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