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Journal articles on the topic 'Acid-base interaction'

Author: Grafiati

Published: 4 June 2021

Last updated: 6 February 2022

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1

Lin, Yun, Yuemeng Ji, Yixin Li, Jeremiah Secrest, Wen Xu, Fei Xu, Yuan Wang, Taicheng An, and Renyi Zhang. "Interaction between succinic acid and sulfuric acid–base clusters." Atmospheric Chemistry and Physics 19, no. 12 (June 18, 2019): 8003–19. http://dx.doi.org/10.5194/acp-19-8003-2019.

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Abstract. Dicarboxylic acids likely participate in the formation of pre-nucleation clusters to facilitate new particle formation in the atmosphere, but the detailed mechanism leading to the formation of multicomponent critical nuclei involving organic acids, sulfuric acid (SA), base species, and water remains unclear. In this study, theoretical calculations are performed to elucidate the interactions between succinic acid (SUA) and clusters consisting of SA-ammonia (AM)∕dimethylamine (DMA) in the presence of hydration of up to six water molecules. Formation of the hydrated SUA⚫SA⚫ base clusters is energetically favorable, triggering proton transfer from SA to the base molecule to form new covalent bonds or strengthening the preexisting covalent bonds. The presence of SUA promotes hydration of the SA⚫AM and SA⚫AM⚫DMA clusters but dehydration of the SA⚫DMA clusters. At equilibrium, SUA competes with the second SA molecule for addition to the SA⚫ base clusters at atmospherically relevant concentrations. The clusters containing both the base and organic acid are capable of further binding with acid molecules to promote subsequent growth. Our results indicate that the multicomponent nucleation involving organic acids, sulfuric acid, and base species promotes new particle formation in the atmosphere, particularly under polluted conditions with a high concentration of diverse organic acids.

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2

Shapiro, Yu M., A. V. Kuligina, and V. I. Nichepurenko. "Adducts of carboxylic acid salts and acid-base interaction." Russian Journal of Physical Chemistry A 84, no. 1 (December 29, 2009): 25–28. http://dx.doi.org/10.1134/s003602441001005x.

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3

MAEDA, Shigeyoshi. "Role of Acid Base Interaction in Adhesion." Journal of the Japan Society of Colour Material 70, no. 8 (1997): 526–37. http://dx.doi.org/10.4011/shikizai1937.70.526.

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4

Lutz, Peter L. "Interaction between hypometabolism and acid–base balance." Canadian Journal of Zoology 67, no. 12 (December 1, 1989): 3018–23. http://dx.doi.org/10.1139/z89-424.

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This review discusses the changes in acid–base balance that are produced during hypometabolism and the negative feedback role they play in maintaining the hypometabolic state. In prolonged hypometabolism, air-breathing animals consume internal stores of fat, protein, and carbohydrate, while glycogen is the primary fuel supporting anaerobic hypometabolism. Because the excretory processes are greatly reduced, the accumulation of waste products must be dealt with internally. Mitigating strategies to minimise acid–base disturbance are seen in higher buffer capacities, an acid shift in the pH optima of key enzymes, and the use of metabolic pathways that result in a reduction of net H+ production. In some hibernating animals, gut bacteria may play an important role in preventing [Formula: see text] accumulation. However, the compensatory mechanisms are only partially successful, and substantial alterations in acid–base status and related strong ion changes are common. Changes in intracellular pH have wide metabolic effects but the acid–base and ionic status of the cell is dependent on its energy expenditure. The most vulnerable tissue to reduced metabolism is the brain. The turtle brain can greatly lessen its energy requirements by reducing activity; this is achieved by (i) depression of synaptic transmission, (ii) membrane hyperpolarisation through opening of Cl− channels resulting from release of γ-aminobutyric acid, and (iii) slowing transmembrane ion flux by the selective closure of ion channels. CO2 retention is common in hypometabolic animals. Increased levels of CO2 and H+ and decreased [Formula: see text] can directly cause metabolic depression via a variety of mechanisms, as well as a reduction in neural tissue activity. It is concluded that the hypometabolic state represents a very general condition of temporarily reduced energy expenditure which embraces aestivation, hibernation, torpor, and sleep, and that the common phenomena of CO2 accumulation and consequent changes in acid–base balance play a role in the coordinated reductions in energy expenditure and energy cost.

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5

Danchenko, Yuliya, Mariya Kachomanova, and Yelena Barabash. "The Acid-Base Interaction Role in the Processes of the Filled Diane Epoxy Resins Structuring." Chemistry & Chemical Technology 12, no. 2 (June 25, 2018): 188–95. http://dx.doi.org/10.23939/chcht12.02.188.

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6

Berezin, B. D., P. A. Stuzhin, and O. G. Khelevina. "Acid-base interaction of tetraazaporphin in organic solvents." Chemistry of Heterocyclic Compounds 22, no. 12 (December 1986): 1358–62. http://dx.doi.org/10.1007/bf00474360.

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7

Cheng, Alan C., and Alan D. Frankel. "Ab Initio Interaction Energies of Hydrogen-Bonded Amino Acid Side Chain−Nucleic Acid Base Interactions." Journal of the American Chemical Society 126, no. 2 (January 2004): 434–35. http://dx.doi.org/10.1021/ja037264g.

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8

Singla, Saranshu, Michael C. Wilson, and Ali Dhinojwala. "Spectroscopic evidence for acid–base interaction driven interfacial segregation." Physical Chemistry Chemical Physics 21, no. 5 (2019): 2513–18. http://dx.doi.org/10.1039/c8cp06963h.

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9

KAMETANI, Fujio, Hakim BANGUN, Yukihiro IKEDA, and Saburo SHIMABAYASHI. "Interaction of Alginic Acid with Organic Diacidic Base Piperazine." Chemical and Pharmaceutical Bulletin 38, no. 10 (October 25, 1990): 2623–26. http://dx.doi.org/10.1248/cpb.38.2623.

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10

Ohsaki, Koji, Katsuaki Konishi, and Takuzo Aida. "Supramolecular acid/base catalysis via multiple hydrogen bonding interaction." Chemical Communications, no. 16 (July 8, 2002): 1690–91. http://dx.doi.org/10.1039/b202970g.

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11

Hu, J. Y., J. H. Shan, and S. L. Ong. "Improving rejection of organic fractions in reclaimed water based on intermolecular interaction effect." Water Science and Technology 58, no. 6 (October 1, 2008): 1299–304. http://dx.doi.org/10.2166/wst.2008.473.

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The interactions of complex organic matters in reclaimed water were studied for the rejection mechanisms for organics removal by nanofiltration (NF) membrane. Rejection study on single organic fractions showed that base fractions are the most difficult ones to be removed, with the removal efficiencies of 40.08–47.73% for hydrophobic-base (Hpo-B) and 75.51–79.14% for hydrophilic-base (Hpi-B), respectively. Experimental results for interaction studies showed that with the presence of hydrophilic-acid (Hpi-A) and hydrophobic-acid (Hpo-A) at a concentration ratio of 1, the average rejections for acid + base fractions were 11–30% and 9–26% higher than those for the two corresponding single fractions, respectively. It was noted that after the ratio reaches a certain range (>2 for Hpo-A in our case) the beneficial effects become less significant since the saturation of opportunities for interactions. With presence of acid and base fractions, the neutralization reactions and hydrophilic interactions would be the major beneficial interaction among different components. With the presence of hydrophobic-neutral (Hpo-N) at a concentration ratio of 1, the average rejections for neutral + base fractions were improved by 9–35% and when at a ratio of 2, the rejections only increased 2.28–8.87% more. The interaction between neutral organics and base organics would be due to the effect of coupling of different permeable components.

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12

Sychov, Maxim М., Sergey V. Mjakin, Alexander I. Ponyaev, and Victor V. Belyaev. "Acid-Base (Donor-Acceptor) Properties of Solids and Relations with Functional Properties." Advanced Materials Research 1117 (July 2015): 147–51. http://dx.doi.org/10.4028/www.scientific.net/amr.1117.147.

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Distribution of active surface centers (DAC) spectroscopy is applied to study acid-base properties of solids. Surface characteristics of solid influences interface interaction in which this solid participates. Efficient approach to consider such interactions is to view them as acid-base ones, since acid-base interactions determine adsorption and bonding of organic molecules to solid surface. Paper describes application of method to study surface properties of components of luminescent materials, catalysts, gas sensors, proton membranes and polymer composites, and it was shown that their functional properties strongly depend on distribution of acid-base active surface centers.

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13

Choi, Gun Young, Jung F. Kang, Abraham Ulman, Walter Zurawsky, and Cathy Fleischer. "Acid−Base Interaction in the Adhesion between Two Solid Surfaces." Langmuir 15, no. 26 (December 1999): 8783–86. http://dx.doi.org/10.1021/la991222h.

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14

Petrov, Oleg A., Galina V. Osipova, and Olga G. Khelevina. "Reactivity of Porphyrazines in Acid-Base Interaction with N-Bases." Macroheterocycles 2, no. 2 (2009): 151–56. http://dx.doi.org/10.6060/mhc2009.2.151.

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15

Šponer, Jiří, Petr Jurečka, and Pavel Hobza. "Accurate Interaction Energies of Hydrogen-Bonded Nucleic Acid Base Pairs." Journal of the American Chemical Society 126, no. 32 (August 2004): 10142–51. http://dx.doi.org/10.1021/ja048436s.

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16

Kurian, Anish, Shishir Prasad, and Ali Dhinojwala. "Direct Measurement of Acid−Base Interaction Energy at Solid Interfaces." Langmuir 26, no. 23 (December 7, 2010): 17804–7. http://dx.doi.org/10.1021/la103591f.

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17

Starostina, I. A., N. V. Sokorova, O. V. Stoyanov, and Yu N. Khakimullin. "The correspondence of detachment characteristics and acid-base interaction measures." Polymer Science Series D 6, no. 2 (April 2013): 154–56. http://dx.doi.org/10.1134/s1995421213020123.

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18

Kiyan, V. I., and A. B. Atkarskaya. "Acid-base interaction of the components in sodium-borosilicate glasses." Glass and Ceramics 64, no. 7-8 (July 2007): 221–25. http://dx.doi.org/10.1007/s10717-007-0055-y.

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19

Abtouche, Soraya, Thibaut Very, Antonio Monari, Meziane Brahimi, and Xavier Assfeld. "Insight on the interaction of polychlorobiphenyl with nucleic acid–base." Journal of Molecular Modeling 19, no. 2 (September 13, 2012): 581–88. http://dx.doi.org/10.1007/s00894-012-1580-3.

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20

Nakano, Shu-ichi, Masayuki Fujii, and Naoki Sugimoto. "Use of Nucleic Acid Analogs for the Study of Nucleic Acid Interactions." Journal of Nucleic Acids 2011 (2011): 1–11. http://dx.doi.org/10.4061/2011/967098.

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Unnatural nucleosides have been explored to expand the properties and the applications of oligonucleotides. This paper briefly summarizes nucleic acid analogs in which the base is modified or replaced by an unnatural stacking group for the study of nucleic acid interactions. We also describe the nucleoside analogs of a base pair-mimic structure that we have examined. Although the base pair-mimic nucleosides possess a simplified stacking moiety of a phenyl or naphthyl group, they can be used as a structural analog of Watson-Crick base pairs. Remarkably, they can adopt two different conformations responding to their interaction energies, and one of them is the stacking conformation of the nonpolar aromatic group causing the site-selective flipping of the opposite base in a DNA double helix. The base pair-mimic nucleosides can be used to study the mechanism responsible for the base stacking and the flipping of bases out of a nucleic acid duplex.

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21

Riel, Asia Marie S., Morly J. Jessop, Daniel A. Decato, Casey J. Massena, Vinicius R. Nascimento, and Orion B. Berryman. "Experimental investigation of halogen-bond hard–soft acid–base complementarity." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 73, no. 2 (March 29, 2017): 203–9. http://dx.doi.org/10.1107/s2052520617001809.

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The halogen bond (XB) is a topical noncovalent interaction of rapidly increasing importance. The XB employs a `soft' donor atom in comparison to the `hard' proton of the hydrogen bond (HB). This difference has led to the hypothesis that XBs can form more favorable interactions with `soft' bases than HBs. While computational studies have supported this suggestion, solution and solid-state data are lacking. Here, XB soft–soft complementarity is investigated with a bidentate receptor that shows similar associations with neutral carbonyls and heavy chalcogen analogs. The solution speciation and XB soft–soft complementarity is supported by four crystal structures containing neutral and anionic soft Lewis bases.

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22

Kuninobu, Yoichiro. "Development of Novel C–H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules." Synlett 29, no. 16 (July 26, 2018): 2093–107. http://dx.doi.org/10.1055/s-0037-1610531.

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This personal account summarizes our recent progress in the development of C–H transformations. We achieved ortho-selective C–H borylations and silylations by using Lewis acid–base interaction between two substrates and we achieved meta- and ortho-selective C–H borylations by using hydrogen bonding or Lewis acid–base interaction between a hydrogen donor or Lewis acid unit of a ligand and a functional group of a substrate. Regioselective C–H trifluoromethylations and related reactions of six-membered heteroaromatic compounds were realized at their 2- and 4-positions and at their benzylic positions. In addition, we developed C–H transformations directed towards the synthesis of organic functional materials, such as highly soluble polyimides or π-conjugated molecules containing either heteroatom(s) or a Lewis acid–base interaction.1 Introduction2 Regioselective C–H Transformations Controlled by Noncovalent Bond Interactions2.1 Regioselective C–H Transformations Controlled by Lewis Acid–Base Interaction between Two Substrates2.2 Regioselective C–H Transformation Controlled by Hydrogen Bonding between Ligand and Substrate2.3 Regioselective C–H Transformations Controlled by Lewis Acid–Base Interactions between Ligands and Substrates3 Trifluoromethylation and Related Transformations of Six-Membered Heteroaromatic Compounds3.1 2-Position-Selective C–H Trifluoromethylation of Six-Membered Heteroaromatic Compounds3.2 4-Position-Selective C–H Trifluoromethylation of Six-Membered Heteroaromatic Compounds3.3 Benzyl Position-Selective C–H Trifluoromethylation of Six-Membered Heteroaromatic Compounds4 C–H Transformations Leading to the Synthesis of Organic Functional Materials4.1 Heteroatom-Containing π-Conjugated Molecules4.2 π-Conjugated Molecules Containing a Lewis Acid–Base Interaction4.3 Soluble Polyimide Derivatives5 Conclusions

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23

Danilov, Victor, Vladimir Dailidonis, Tanja Mourik, and Herbert Früchtl. "A study of nucleic acid base-stacking by the Monte Carlo method: Extended cluster approach." Open Chemistry 9, no. 4 (August 1, 2011): 720–27. http://dx.doi.org/10.2478/s11532-011-0056-0.

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AbstractThe adenine-thymine (AT), adenine-uracil (AU) and guanine-cytosine (GC) base associates in clusters containing 400 water molecules were studied using a newly implemented Metropolis Monte Carlo algorithm based on the extended cluster approach. Starting from the hydrogen-bonded Watson-Crick geometries, all three base pairs are transformed into more favorable stacked configurations during the simulation. The obtained results show, for the first time, the transition from planar base pairs to stacked base associates in the Monte Carlo framework. Analysis of the interaction energies shows that, in the water cluster, the stacked dimers are energetically preferable compared to the corresponding Watson-Crick base pairs. This is due to the larger base-water interaction in the stacked structures. The water-water interaction is one of the main factors promoting the formation of stacked dimers, and the obtained data confirm the crucial role of the water-water interactions in base stacking.

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24

Kopylov, N. I., and V. A. Lata. "Acid-Base Properties of Sulfide–Sodium Systems." Eurasian Chemico-Technological Journal 5, no. 4 (April 6, 2016): 291. http://dx.doi.org/10.18321/ectj316.

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<p>Investigations of sulfide – sodium systems of heavy non-ferrous metals and their associated minerals have played an important part in course of development of modern technologies of complex processing of compound raw materials and semiproducts. Crystallization of generated structures as complex compounds – thiosalts takes place during cooling of these alloys. The reaction 3(NH<sub>4</sub>)<sub>2</sub>S + Sb<sub>2</sub>S<sub>5</sub> → 2(NH<sub>4</sub>)<sub>3</sub>SbS<sub>4</sub> is considered to be an example of acid-base interaction of substances which do not contain oxygen and hydrogen. Theory of acids and bases developed by M.I. Usanovich says that acidity (basicity) is a substance property, which is not connected with belonging to a certain class of compounds and is a functional characteristic of comparison of partners in a given reaction. Developing these ideas R.G. Pearson has introduced a notion of "hard" and "soft" acids and bases (HSAB) and formulated the basic principle postulating that "hard" acids preferably interact with "hard" bases, and "soft" acids – with "soft" bases. There are a number of suggestions in geological literature for the qualitative estimation of acid-base interaction in compounds which form basis of rocks. One of them, namely, acid-base characteristic that is conditional potential of ionization is the most applicable to thiosalts.</p>

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25

Galetich, I., S. G. Stepanian, V. Shelkovsky, M. Kosevich, Blagoi, and L. Adamowicz. "Structures and Interaction Energies of Nucleic Acid Base−Amino Acid Complexes. Methylcytosines−Acrylamide Model." Journal of Physical Chemistry B 103, no. 50 (December 1999): 11211–17. http://dx.doi.org/10.1021/jp990990e.

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26

TSUTSUI, Koichi, Tosikatu KOBAYASHI, Koji NISHIZAWA, Tasaburo UENO, and Hiroyuki KAGEYAMA. "A Development in Pigment Dispersion Technology Based on Acid-Base Interaction." Nihon Reoroji Gakkaishi(Journal of the Society of Rheology, Japan) 25, no. 5 (1997): 267–73. http://dx.doi.org/10.1678/rheology1973.25.5_267.

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27

Khelevina, O. G., N. V. Chizhova, A. S. Malyasova, and E. A. Kokareva. "Acid-base interaction of octaaryltetraazaporphyrin complexes in a proton-donor medium." Russian Journal of General Chemistry 82, no. 4 (April 2012): 759–63. http://dx.doi.org/10.1134/s1070363212040263.

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28

Liu, Qi, Yahui Zhang, and J. S. Laskowski. "The adsorption of polysaccharides onto mineral surfaces: an acid/base interaction." International Journal of Mineral Processing 60, no. 3-4 (December 2000): 229–45. http://dx.doi.org/10.1016/s0301-7516(00)00018-1.

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29

Li, Pengsong, Xu Lu, Zishan Wu, Yueshen Wu, Richard Malpass‐Evans, Neil B. McKeown, Xiaoming Sun, and Hailiang Wang. "Acid–Base Interaction Enhancing Oxygen Tolerance in Electrocatalytic Carbon Dioxide Reduction." Angewandte Chemie International Edition 59, no. 27 (April 21, 2020): 10918–23. http://dx.doi.org/10.1002/anie.202003093.

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30

Morioka, Kohei, Norio Tamagawa, Katsuhiro Maeda, and Eiji Yashima. "Dynamic Axial Chirality Control of a Carboxybiphenol through Acid–Base Interaction." Chemistry Letters 35, no. 1 (January 2006): 110–11. http://dx.doi.org/10.1246/cl.2006.110.

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31

Lustig, B. "RNA base-amino acid interaction strengths derived from structures and sequences." Nucleic Acids Research 25, no. 13 (July 1, 1997): 2562–65. http://dx.doi.org/10.1093/nar/25.13.2562.

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32

Starostina, I. A., R. M. Khuzakhanov, E. V. Burdova, E. K. Sechko, and O. V. Stoyanov. "Interaction of adhesives in metal-polymer systems in acid-base approach." Polymer Science. Series D 3, no. 1 (January 2010): 26–31. http://dx.doi.org/10.1134/s1995421210010041.

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33

Purse, Byron W., Sara M. Butterfield, Pablo Ballester, Alexander Shivanyuk, and Julius Rebek. "Interaction Energies and Dynamics of Acid−Base Pairs Isolated in Cavitands." Journal of Organic Chemistry 73, no. 17 (September 2008): 6480–88. http://dx.doi.org/10.1021/jo8008534.

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34

Granqvist, B., G. Hedström, and J. B. Rosenholm. "Acid–base interaction of probes at silica surface. Microcalorimetry and adsorption." Journal of Colloid and Interface Science 333, no. 1 (May 2009): 49–57. http://dx.doi.org/10.1016/j.jcis.2009.01.057.

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35

Uhl, S., K. Rempfer, H. J. Egelhaaf, B. Lehr, and D. Oelkrug. "Fluorescence characterization of acid-base interaction and mobility at Chromatographic interfaces." Analytica Chimica Acta 303, no. 1 (February 1995): 17–23. http://dx.doi.org/10.1016/0003-2670(94)00624-u.

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36

Stuzhin, P. A., O. G. Khelevina, M. N. Ryabova, and B. D. Berezin. "Spectroscopy of acid-base interaction of tetraazaporphyrin complexes in nonaqueous solutions." Journal of Applied Spectroscopy 52, no. 1 (January 1990): 70–75. http://dx.doi.org/10.1007/bf00664785.

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37

Sherer, Edward C., Darrin M. York, and Christopher J. Cramer. "Fast approximate methods for calculating nucleic acid base pair interaction energies." Journal of Computational Chemistry 24, no. 1 (January 15, 2003): 57–67. http://dx.doi.org/10.1002/jcc.10150.

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38

Li, Pengsong, Xu Lu, Zishan Wu, Yueshen Wu, Richard Malpass‐Evans, Neil B. McKeown, Xiaoming Sun, and Hailiang Wang. "Acid–Base Interaction Enhancing Oxygen Tolerance in Electrocatalytic Carbon Dioxide Reduction." Angewandte Chemie 132, no. 27 (April 21, 2020): 11010–15. http://dx.doi.org/10.1002/ange.202003093.

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39

Basílio Janke, Eline M., and Klaus Weisz. "Hydrogen Bond Mediated Association of Dinucleotide Analogs." Zeitschrift für Physikalische Chemie 217, no. 12 (December 1, 2003): 1463–72. http://dx.doi.org/10.1524/zpch.217.12.1463.20475.

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AbstractSeveral dinucleotide analogs, in which two of the nucleobases adenine, thymine and uracil are connected by a hexadecamethylene linker have been synthesized and studied for their base-base interaction in a chloroform solution. Using 1H NMR spectroscopic techniques intramolecular base pair formation through hydrogen bonding is observed at ambient temperatures but found to strongly depend on the identity of paired bases. Thus, whereas cyclization through intramolecular base-base interactions predominate for adenine–(CH2)16–thymine and adenine–(CH2)16–uracil, no intramolecular adenine-adenine pairing was observed. Upon addition of acetic acid to adenine–(CH2)16–thymine, strong adenine-acetic acid interactions result in the disruption of preformed intramolecular adenine-thymine base pairs.

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40

Chen, Jiao, Shuai Jiang, Yi-Rong Liu, Teng Huang, Chun-Yu Wang, Shou-Kui Miao, Zhong-Quan Wang, Yang Zhang, and Wei Huang. "Interaction of oxalic acid with dimethylamine and its atmospheric implications." RSC Advances 7, no. 11 (2017): 6374–88. http://dx.doi.org/10.1039/c6ra27945g.

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41

Lee, Albert S., Yoong-Kee Choe, Ivana Matanovic, and Yu Seung Kim. "The energetics of phosphoric acid interactions reveals a new acid loss mechanism." Journal of Materials Chemistry A 7, no. 16 (2019): 9867–76. http://dx.doi.org/10.1039/c9ta01756a.

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42

Absolínová, Helena, Luděk Jančář, Irena Jančářová, Jaroslav Vičar, and Vlastimil Kubáň. "Acid-base behaviour of sanguinarine and dihydrosanguinarine." Open Chemistry 7, no. 4 (December 1, 2009): 876–83. http://dx.doi.org/10.2478/s11532-009-0079-y.

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AbstractAcid-base and optical properties of sanguinarine and dihydrosanguinarine were studied in the presence of HCl, HNO3, H2SO4, H3PO4, CAPSO and acetic acid (HAc) of different concentrations and their mixtures. The equilibrium constants pKR+ of the transition reaction between an iminium cation Q+ of sanguinarine and its uncharged QOH (pseudo-base, 6-hydroxy-dihydroderivative) form were calculated. A numerical interpretation of the A-pH curves by a SQUAD-G computer program was used. Remarkable shifts of formation parts of absorbance-pH (A-pH) curves to alkaline medium were observed. The shifts depend on the type and concentration of inert electrolyte (the most remarkable for HNO3 and HCl). The corresponding pKR+ values ranged from 7.21 to 8.16 in the same manner (ΔpKR+ = 0.81 and 0.73 for HNO3 and HCl, respectively). The priority effect of ionic species and ionic strength was confirmed in the presence of NaCl and KCl. The strength of interaction of SA with bioactive compounds (i.e. receptors, transport proteins, nucleic acids etc.) may be affected because of the observed influence of both cations and anions of the inert electrolytes.

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43

Li, Chenchen, Dongmei Lu, and Chao Wu. "Multi-molar CO2 capture beyond the direct Lewis acid–base interaction mechanism." Physical Chemistry Chemical Physics 22, no. 20 (2020): 11354–61. http://dx.doi.org/10.1039/d0cp01493a.

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Competing with the Lewis acid-base reactions, proton transfer related interactions dominate the multi-molar CO₂ capture in three typical multiple-site ILs. For ammonium-based ILs, the proton transfer process is feasible only with the help of CO₂ molecule.

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44

Levina, Vladislava A., Andrea Rossin, Natalia V. Belkova, Michele R. Chierotti, Lina M. Epstein, Oleg A. Filippov, Roberto Gobetto, et al. "Acid-Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution." Angewandte Chemie 123, no. 6 (December 29, 2010): 1403–6. http://dx.doi.org/10.1002/ange.201005274.

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45

Levina, Vladislava A., Andrea Rossin, Natalia V. Belkova, Michele R. Chierotti, Lina M. Epstein, Oleg A. Filippov, Roberto Gobetto, et al. "Acid-Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution." Angewandte Chemie International Edition 50, no. 6 (December 29, 2010): 1367–70. http://dx.doi.org/10.1002/anie.201005274.

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46

Shim, Sangdeok. "Acid–Base Chemistry of Porphyrin/Graphene Oxide Complex: Role of Electrostatic Interaction." Bulletin of the Korean Chemical Society 40, no. 4 (March 5, 2019): 366–69. http://dx.doi.org/10.1002/bkcs.11700.

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Maeda, Katsuhiro, Norikazu Yamamoto, and Yoshio Okamoto. "Helicity Induction of Poly(3-carboxyphenyl isocyanate) by Chiral Acid−Base Interaction." Macromolecules 31, no. 17 (August 1998): 5924–26. http://dx.doi.org/10.1021/ma9804848.

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Berezin, B. D., O. G. Khelevina, and P. A. Stuzhin. "Spectroscopy of acid-base interaction of substituted tetraazaporphin derivatives in nonaqueous media." Journal of Applied Spectroscopy 46, no. 5 (May 1987): 510–15. http://dx.doi.org/10.1007/bf00657379.

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Gole, James L., and William Laminack. "Nanostructure-directed chemical sensing: The IHSAB principle and the dynamics of acid/base-interface interaction." Beilstein Journal of Nanotechnology 4 (January 14, 2013): 20–31. http://dx.doi.org/10.3762/bjnano.4.3.

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Abstract:

Nanostructure-decorated n-type semiconductor interfaces are studied in order to develop chemical sensing with nanostructured materials. We couple the tenets of acid/base chemistry with the majority charge carriers of an extrinsic semiconductor. Nanostructured islands are deposited in a process that does not require self-assembly in order to direct a dominant electron-transduction process that forms the basis for reversible chemical sensing in the absence of chemical-bond formation. Gaseous analyte interactions on a metal-oxide-decorated n-type porous silicon interface show a dynamic electron transduction to and from the interface depending upon the relative strength of the gas and metal oxides. The dynamic interaction of NO with TiO2, SnO2, NiO, Cu x O, and Au x O (x >> 1), in order of decreasing acidity, demonstrates this effect. Interactions with the metal-oxide-decorated interface can be modified by the in situ nitridation of the oxide nanoparticles, enhancing the basicity of the decorated interface. This process changes the interaction of the interface with the analyte. The observed change to the more basic oxinitrides does not represent a simple increase in surface basicity but appears to involve a change in molecular electronic structure, which is well explained by using the recently developed IHSAB model. The optical pumping of a TiO2 and TiO2− x N x decorated interface demonstrates a significant enhancement in the ability to sense NH3 and NO2. Comparisons to traditional metal-oxide sensors are also discussed.

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ZHANG, XINGMEI, XIAOLONG HAN, and WENHAO XU. "A COMPUTER SIMULATION STUDY ON LEWIS ACID–BASE INTERACTIONS AND COOPERATIVE C-H⋯O WEAK HYDROGEN BONDING IN VARIOUS CO2 COMPLEXES." Journal of Theoretical and Computational Chemistry 10, no. 04 (August 2011): 483–508. http://dx.doi.org/10.1142/s0219633611006591.

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Abstract:

The Lewis acid–base interaction and cooperative C-H⋯O weak hydrogen bonding have been widely suggested as two key factors in the solubility of CO2 -philic materials. In this work, both ab initio and Monte Carlo simulations were performed to investigate the properties of the two important interactions between CO2 and several common organic molecules. Binding energies, geometries and charge transfer were calculated by ab initio method, showing that the mutual enhancement between the two sorts of interactions plays an important role in the stability of the CO2 complexes. Monte Carlo simulations were employed to investigate the effect of many-body interactions in real solutions. The results show that the many-body interactions also have a significant impact on the energetic and geometric properties of the CO2 complexes. Moreover, the self-aggregation of strong polar molecules will greatly weaken the effective Lewis acid–base interaction due to the zone overlapping, which needs to be taken into account in the design of future CO2 -philes.

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