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Relevant bibliographies by topics / Addition polymerization. Chemical kinetics

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Academic literature on the topic 'Addition polymerization. Chemical kinetics'

Author: Grafiati

Published: 4 June 2021

Last updated: 8 February 2022

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Journal articles on the topic "Addition polymerization. Chemical kinetics"

1

KROL, PIOTR, and JAN PIELICHOWSKI. "Kinetic models of the step-growth polymerization (condensation polymerization and addition polymerization) processes." Polimery 37, no. 07 (1992): 304–11. http://dx.doi.org/10.14314/polimery.1992.304.

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Ray, W. Harmon. "Modelling of addition polymerization processes - Free radical, ionic, group transfer, and ziegler-natta kinetics." Canadian Journal of Chemical Engineering 69, no. 3 (1991): 626–29. http://dx.doi.org/10.1002/cjce.5450690304.

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Wang, Guo-Xiang, Mang Lu, Zhao-Hui Hou, et al. "“Nascent” Fe(0)-mediated living radical copolymerization of styrene and acrylonitrile." e-Polymers 14, no. 3 (2014): 187–92. http://dx.doi.org/10.1515/epoly-2014-0012.

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AbstractIn this work, we reported the synthesis of copolymers of poly(styrene-co-acrylonitrile) via single-electron transfer-living radical polymerization using CCl4 as an initiator and Zn(0)/2,2′-bipyridine (Bpy)/FeCl2 as catalyst complexes. The polymerization was carried out at 25°C. The polymerization proceeded in a living fashion based on “nascent” Fe(0) as the source of the transition metal, which was prepared by Zn(0)/FeCl2 in situ. The kinetic experimental results showed that the copolymerization is first-order kinetics. The molecular weights increased linearly with respect to monomer c

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Liu, Pengfei, Charles M. Pearce, Rozalia-Maria Anastasiadi, Marina Resmini, and Ana M. Castilla. "Covalently Crosslinked Nanogels: An NMR Study of the Effect of Monomer Reactivity on Composition and Structure." Polymers 11, no. 2 (2019): 353. http://dx.doi.org/10.3390/polym11020353.

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Covalently crosslinked nanogels are widely explored as drug delivery systems and sensors. Radical polymerization provides a simple, inexpensive, and broadly applicable approach for their preparation, although the random nature of the reaction requires careful study of the final chemical composition. We demonstrate how the different reactivities of the monomers influence the total degree of incorporation into the polymer matrix and the role played by the experimental parameters in maximizing polymerization efficiency. Nanogels based on N-isopropylacrylamide, N-n-propylacrylamide, and acrylamide

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Mena Silva, Paola Andrea, Isadora Martini Garcia, Julia Nunes, et al. "Myristyltrimethylammonium Bromide (MYTAB) as a Cationic Surface Agent to Inhibit Streptococcus mutans Grown over Dental Resins: An In Vitro Study." Journal of Functional Biomaterials 11, no. 1 (2020): 9. http://dx.doi.org/10.3390/jfb11010009.

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This in vitro study evaluated the effect of myristyltrimethylammonium bromide (MYTAB) on the physical, chemical, and biological properties of an experimental dental resin. The resin was formulated with dental dimetacrylate monomers and a photoinitiator/co-initiator system. MYTAB was added at 0.5 (G0.5%), 1 (G1%), and 2 (G2%) wt %, and one group remained without MYTAB and was used as the control (GCtrl). The resins were analyzed for the polymerization kinetics, degree of conversion, ultimate tensile strength (UTS), antibacterial activity against Streptococcus mutans, and cytotoxicity against hu

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Ivanov, Alexander A., Irina V. Alexandrova, and Dmitri V. Alexandrov. "Phase transformations in metastable liquids combined with polymerization." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 377, no. 2143 (2019): 20180215. http://dx.doi.org/10.1098/rsta.2018.0215.

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This paper is concerned with the theory of nucleation and growth of crystals in a metastable polymer melt with allowance for the polymerization of a monomer. A mathematical model consisting of the heat balance equation, equations governing the particle-radius distribution function and the polymerization degree is formulated. The exact steady-state analytical solutions are found. In the case of unsteady-state crystallization with polymerization, the particle-size distribution function is determined analytically for different space–time regions by means of the Laplace transform. Two functional i

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Yang, Xiaoli, Limin Huang, Lihua Zhou, Hao Xu, and Zihan Yi. "A Photochromic Copolymer Hydrogel Contact Lens: From Synthesis to Application." International Journal of Polymer Science 2016 (2016): 1–8. http://dx.doi.org/10.1155/2016/4374060.

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A photochromic poly(2-hydroxyl-ethyl methacrylate-N-vinylpyrrolidone-spironaphthoxazine) hydrogel (p(HEMA-NVP-SPO)) has been designed and synthesized by free radical polymerization in this work. The chemical and structural information of hydrogels was investigated by IR spectra, equilibrium water content (EWC), and SEM. The IR spectra confirmed successful synthesis of copolymer. The domain of NVP contributed to not only EWC but also inner structure of hydrogel, while SPO had little influence on these properties of hydrogel. The photochromic behaviors of hydrogel including photochromic properti

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Tonoyan, Anahit O., Aram H. Minasyan, Anahit Z. Varderesyan, Armenuhi G. Ketyan, and Sevan P. Davtyan. "Influence of shrinkage of polymer on the stationarity of propagation of frontal polymerization heat waves." Journal of Polymer Engineering 39, no. 8 (2019): 769–73. http://dx.doi.org/10.1515/polyeng-2019-0160.

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Abstract The purpose of this work was to study the causes of the formation of nonlinear and spin modes in the process of frontal polymerization (FP). The latter is an autowave process of the propagation of polymerization heat waves, and is a nontraditional method for the synthesis of various polymers and polymeric composites. Monomers of metal-complexes of acrylamide with and without additions of inert and nano-fillers were chosen as objects of study. Research data on dilatometric analysis, as well as on kinetics and macrokinetics of the polymerization processes of the monomers in frontal mode

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Curteanu, Silvia. "Modeling and simulation of free radical polymerization of styrene under semibatch reactor conditions." Open Chemistry 1, no. 1 (2003): 69–90. http://dx.doi.org/10.2478/bf02479259.

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AbstractThe first part of this approach is concerned with the elaboration of a radical polymerization model of styrenne, based on a kinetic diagram that includes chemical and thermal initiation, propagation, termination by recombination and chain transfer to the monomer. Furthermore, volume contraction during polymerization is considered, as well as the gel and glass effects. The mathematical formalism that describes the model in terms of moments is explored in detail. The model was then used to predict the changes in monomer conversion and molecular weight after intermediate addition of initi

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Sobani, Masoud, Vahid Haddadi-Asl, Seyed-Ataollah Mirshafiei-Langari, Mehdi Salami-Kalajahi, Hossein Roghani-Mamaqani, and Khezrollah Khezri. "A kinetics study on thein situreversible addition–fragmentation chain transfer and free radical polymerization of styrene in presence of silica aerogel nanoporous particles." Designed Monomers and Polymers 17, no. 3 (2013): 245–54. http://dx.doi.org/10.1080/15685551.2013.840496.

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Dissertations / Theses on the topic "Addition polymerization. Chemical kinetics"

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Gwee, Liang Elabd Yossef A. "Ion transport in polymer/ionic liquid films /." Philadelphia, Pa. : Drexel University, 2010. http://hdl.handle.net/1860/3268.

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Rahmathullah, Mohamed Aflal Mohamed Palmese Giuseppe R. Elabd Yossef A. "Multifunctional polymers via incorporation of ionic groups at molecular and mesoscopic length scales /." Philadelphia, Pa. : Drexel University, 2008. http://hdl.handle.net/1860/2841.

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Lee, Jihean Palmese Giuseppe R. "Cationic polymerization of glycidyl ethers and furans : improved electron beam and UV cured epoxy networks /." Philadelphia, Pa. : Drexel University, 2007. http://hdl.handle.net/1860/2538.

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Chaffey-Millar, Hugh William Chemical Sciences &amp Engineering Faculty of Engineering UNSW. "An experimental and computational study of two state of the art living free radical polymerisation techniques." Awarded by:University of New South Wales. Chemical Sciences & Engineering, 2008. http://handle.unsw.edu.au/1959.4/41421.

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This thesis describes the research conducted by t he author in completion of a Doctor of Philosophy in the Centre for Advanced Macromolecular Design(CAMD), Univcrsity of New South Wales (UNSW) , Sydney, Australia; under the supervision of Professor Christopher Barner-Kowollik and Doctor Michelle L. Coote (Australian National University). The research has led to the creation of new knowledge in the fields of free radical polymerisation and chemical kinetics. Research was conducted in two main thrusts: (1) investigation into the governing kinetic processes behind star polymer synthesis via wha

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Karmore, Vishal K. "Kinetics Of Polymerization And Degradation By Non-Conventional Techniques." Thesis, Indian Institute of Science, 2001. http://hdl.handle.net/2005/269.

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Non-conventional techniques for polymerization and depolymerization were investigated. The rates of polymerization were enhanced higher in ultrasonic, supercritical fluids and microwaves. However in these system under certain conditions, simultaneous degradation also occurred. Depolymerization was studied by various methods like thermal degradation in supercritical fluids and in presence of oxidizers, Lewis acid and other organic acids. Degradation by ultrasound and thermal degradation of polymer mixtures were also investigated. The scission of the polymer backbone is random for thermal degrad

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Kumar, Vipul. "Pyrolysis and gasification of lignin and effect of alkali addition." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29609.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Sujit Banerjee; Committee Co-Chair: Wm. James Frederick, Jr.; Committee Member: John D. Muzzy; Committee Member: Kristiina Iisa; Committee Member: Preet Singh. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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Al-Saleh, Mohammad. "MODELING OLEFIN POLYMERIZATION USING MONTE CARLO SIMULATION: DETAILED COMONOMER DISTRIBUTION." Thesis, University of Waterloo, 2006. http://hdl.handle.net/10012/2863.

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In recent years there have been many efforts to develop and expand the ability of mathematical models capable of describing polymerization systems. Models can provide a key competitive advantage for the industry and research in terms of production and technology development. As new resins are continuously produced to meet the requirement of final applications and processability, it is imperative to pursue strong polymer characterization with special attention to detailed analysis of polymer microstructure. The microstructure of polyolefin is defined by its distribution of molecular weigh

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Temeng, Kwaku Ofosu. "The design and evaluation of a control scheme for emulsion polymerization in a tube-CSTR system." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/10019.

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Brennan, Daniel P. "Small molecule and polymer templating of inorganic materials." Diss., Online access via UMI:, 2006.

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Donato, Karen Ann Ehnot. "The kinetics of a methyl methacrylate polymerization initiated by the stable free radicals in irradiated polytetrafluoroethylene and properties of the resultant graft polymer." Ohio : Ohio University, 1987. http://www.ohiolink.edu/etd/view.cgi?ohiou1171670342.

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Books on the topic "Addition polymerization. Chemical kinetics"

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Kučera, Miloslav. Mechanism and kinetics of addition polymerizations. 2nd ed. Elsevier, 1992.

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Babkin, V. A. Quantum chemical aspects of cationic polymerization of olefins. Nova Science Publishers, 1997.

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Heterogeneous kinetics: Theory of Ziegler-Natta-Kaminsky polymerization. Kodansha, 2004.

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4

Organic chemistry: Block 3: Understanding reactions : Substitution: pathways and products : Elimination and addition: pathways and products : Making drugs. 3rd ed. Open University, 1996.

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5

Johannes, Smid, and Hogen-Esch Thieo E, eds. Recent advances in anionic polymerization: Proceedings of the International Symposium on Recent Advances in Anionic Polymerization, held April 13-18,1986 at the American Chemical Society Meeting in New York... Elsevier, 1987.

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International, Symposium on Recent Advances in Anionic Polymerization (1986 New York N. Y. ). Recent advances in anionic polymerization: Proceedings of the International Symposium on Recent Advances in Anionic Polymerization, held April 13-18, 1986, at the American Chemical Society Meeting in New York, New York, U.S.A. Elsevier, 1987.

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7

Caneba, Gerard. Emulsion-based Free-Radical Retrograde-Precipitation Polymerization. Springer-Verlag Berlin Heidelberg, 2011.

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International Symposium on Free-Radical Polymerization: Kinetics and Mechanism (4th 2006 Il Ciocco, Italy). Radical polymerization: Kinetics and mechanism ; selected contributions from the conference in Il Ciocco (Italy), September 3-8, 2006. Edited by Buback Michael and Herk Alex van. Wiley-VCH, 2007.

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service), SpringerLink (Online, ed. Free-Radical Retrograde-Precipitation Polymerization (FRRPP): Novel Concepts, Processes, Materials, and Energy Aspects. Springer-Verlag Berlin Heidelberg, 2010.

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Kucera, Miloslav, C. F. H. Tipper, and R. G. Compton. Comprehensive Chemical Kinetics. Elsevier Publishing Company, 1992.

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Book chapters on the topic "Addition polymerization. Chemical kinetics"

1

Fortin, Jeffrey B., and Toh-Ming Lu. "Deposition Kinetics for Polymerization via the Gorham Route." In Chemical Vapor Deposition Polymerization. Springer US, 2004. http://dx.doi.org/10.1007/978-1-4757-3901-5_5.

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"Comprehensive Chemical Kinetics." In Mechanism and Kinetics of Addition Polymerizations. Elsevier, 1992. http://dx.doi.org/10.1016/s0069-8040(08)70212-7.

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Helfferich, F. G. "Polymerization." In Comprehensive Chemical Kinetics. Elsevier, 2001. http://dx.doi.org/10.1016/s0069-8040(01)80031-5.

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"Chapter 1 Polymerization." In Mechanism and Kinetics of Addition Polymerizations. Elsevier, 1992. http://dx.doi.org/10.1016/s0069-8040(08)70218-8.

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Hutchinson, R. A. "Radical Polymerization Kinetics." In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2013. http://dx.doi.org/10.1016/b978-0-12-409547-2.05416-0.

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Painter, Paul C., and Michael M. Coleman. "Kinetics of Step-Growth and Addition Polymerization." In Fundamentals of Polymer Science. Routledge, 2019. http://dx.doi.org/10.1201/9780203755211-3.

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Kozlov, G., and G. Zaikov. "The Fractal Kinetics of Polymerization Catalyzed by Nanofillers." In Engineering of Polymers and Chemical Complexity, Volume II. Apple Academic Press, 2014. http://dx.doi.org/10.1201/b16876-5.

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"The Fractal Kinetics of Polymerization Catalyzed by Nanofi llers." In Engineering of Polymers and Chemical Complexity, Volume II. Apple Academic Press, 2014. http://dx.doi.org/10.1201/b16876-10.

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Yarmukhamedova, E., Yu Puzin, and Yu Monakov. "Radical polymerization of Methyl Methacrylate in the Presence of Nitrogen Compound." In Advances in Kinetics and Mechanism of Chemical Reactions. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b14794-9.

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Yarmukhamedova, E., Yu Puzin, and Yu Monakov. "the Ineration of Azobisisobutyronitrile with Diketocarboxylic Acid in the Polymerization of Methyl Methacrylate." In Advances in Kinetics and Mechanism of Chemical Reactions. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b14794-8.

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Conference papers on the topic "Addition polymerization. Chemical kinetics"

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Cheenkachorn, Kraipat, Wallis A. Lloyd, and Joseph M. Perez. "Use of Pressurized Differential Scanning Calorimetry (PDSC) to Evaluate Effectiveness of Additives in Vegetable Oil Lubricants." In ASME 2003 Internal Combustion Engine Division Spring Technical Conference. ASMEDC, 2003. http://dx.doi.org/10.1115/ices2003-0657.

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Use of renewable resources to replace petroleum base stocks in lubricants is attractive. Research on additives enhanced by current advances in genetic and chemical modifications has resulted in improved oxidative stability of vegetable oils. Like most oxidation processes, the oxidative degradation of vegetable oils is complex. The auto-oxidation free radical mechanisms and hydroperoxide theories of oxidation have been well studied. Factors that influence the degradation of oils include temperature, surface reactivity, rates of formation of radicals, chemical composition factors such as olefin

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Sanchez, M. A., W. Sutton, W. Rizk, and J. Tompkins. "Thermal Curing and Strength of PMMA Bone Cement." In ASME 2003 Heat Transfer Summer Conference. ASMEDC, 2003. http://dx.doi.org/10.1115/ht2003-47067.

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Many current bone cements have proprietary minor ingredients that affect the chemical kinetics and heat transfer modeling of the exothermic reaction during bone cement polymerization. In addition, the geometry and the method of cooling/curing the bone cement can vary by application. A method for modeling energy generation, based on temperature measurement of various geometries and conditions, expresses the exothermic reaction and the duration with respect to time. Reaction from the bone cement can yield temperatures above 110°C for the air convective cooling boundary condition. Experiments sho

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Yoshida, Jun-ichi, and Aiichiro Nagaki. "Flash Chemistry - Fast Chemical Synthesis in Micro Flow Systems." In ASME 2009 7th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2009. http://dx.doi.org/10.1115/icnmm2009-82157.

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Flash chemistry is a field of chemical synthesis where extremely fast reactions are conducted in a highly controlled manner. A key element of flash chemistry is the control of extremely fast reactions to obtain the desired products selectively. For extremely fast reactions, kinetics often cannot be used because of the lack of homogeneity of the reaction environment when they are conducted in conventional reactors such as flasks. Fast micromixing by virtue of short diffusion path solves such problems. Fast reactions are usually highly exothermic, and heat removal is an important factor in contr

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Hoyle, Charles E., Per-Erik Sundell, Martin A. Trapp, Doekman Kang, D. Sheng, and Rajamani Nagarajan. "Polymerization kinetics of mono- and multifunctional monomers initiated by high-intensity laser pulses: dependence of rate on peak-pulse intensity and chemical structure." In San Diego, '91, San Diego, CA, edited by Roger A. Lessard. SPIE, 1991. http://dx.doi.org/10.1117/12.50670.

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Jones, Nathan H., Paul G. A. Cizmas, and John C. Slattery. "Creating Reduced Kinetics Models That Satisfy the Entropy Inequality." In ASME Turbo Expo 2014: Turbine Technical Conference and Exposition. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/gt2014-25694.

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In simulating chemically reacting flows, the differential entropy inequality (the local form of the second law of thermodynamics) must be satisfied in addition to the differential mass, momentum and energy balances. Previously we have shown that entropy violations occur when using a global/reduced mechanism. Herein we show that entropy violations also occur when using a detailed/skeletal/reduced mechanism. Using a recent theorem [1], we illustrate how to modify a reduced chemical kinetics model to automatically satisfy the differential entropy inequality. The numerical solution of a methane la

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Mirzaee Kakhki, Iman, Majid Charmchi, and Hongwei Sun. "Computational Investigation of Gallium Nitrite Ammonothermal Crystal Growth." In ASME 2013 Heat Transfer Summer Conference collocated with the ASME 2013 7th International Conference on Energy Sustainability and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ht2013-17506.

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This paper presents a rigorous approach to the simulation of the GaN growth process, which involves dissolution kinetics, transport by thermal convection and crystallization kinetics. So far, a wide range of numerical efforts have been published which provide valuable information on the flow field and temperature distribution in the hydrothermal crystal growth processes; however, no research has attempted to model the mass transfer in the nutrient porous basket nor did they present a modeling of the nutrient/mineralizers/solvent chemical reactions. In addition, the rate of crystallization was

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Zhang, Qingguo, David R. Noble, Santosh J. Shanbhogue, and Tim Lieuwen. "Impacts of Hydrogen Addition on Near-Lean Blowout Dynamics in a Swirling Combustor." In ASME Turbo Expo 2007: Power for Land, Sea, and Air. ASMEDC, 2007. http://dx.doi.org/10.1115/gt2007-27308.

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This paper addresses the impact of H2 addition on lean blowout in premixed swirling flames. Previous work shows that the manner in which the flame blows off varies with percentage of H2 [1,2]. The objective of this paper is to follow up on these observations and systematically characterize the blowoff phenomenology as a function of the H2 levels in the fuel. This is accomplished through high speed visualizations of the flame emission and velocity field measurements. Near blowoff, a variety of highly dynamic flow features are observed, which vary substantially with the H2 levels in the fuel. Th

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Elkady, A. M., D. M. Kalitan, J. Herbon, et al. "Gas Turbine Emission Characteristics in Perfectly Premixed Combustion." In ASME 2011 Turbo Expo: Turbine Technical Conference and Exposition. ASMEDC, 2011. http://dx.doi.org/10.1115/gt2011-46470.

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In the present study, a simple perfectly premixed research burner was utilized at temperatures, pressures and residence times representative of an industrial gas turbine cycle to identify the lower limit of NOx and CO emissions, and to establish an emissions benchmark for practical gas turbine combustors. In addition to experimental data, a chemical reactor model has been utilized for the prediction of the NOx and CO, based on detailed chemical reaction mechanisms. Several current kinetics mechanisms were evaluated and subsequently compared to the experimental data. In addition, sensitivity an

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Roy, Shrabanti, and Omid Askari. "Chemical Kinetic Study on Reaction Pathway of Anisole Oxidation at Various Operating Condition." In ASME 2020 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/imece2020-24233.

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Abstract Biofuels are considered as an alternative source of energy which can decrease the growing consumption of fossil fuel, hence decreasing pollution. Anisole (methoxybenzene) is a potential source of biofuel produced from cellulose base compounds. It is mostly available as a surrogate of phenolic rich compound. Because of the attractive properties of this fuel in combustion, it is important to do detail kinetic study on oxidation of anisole. In this study a detail chemical mechanism is developed to capture the chemical kinetics of anisole oxidation. The mechanism is developed using an aut

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Cavanzo, E. A., S. F. Muñoz, A. Ordoñez, and H. Bottia. "Kinetics of Wet In-Situ Combustion: A Review of Kinetic Models." In SPE Heavy and Extra Heavy Oil Conference: Latin America. SPE, 2014. http://dx.doi.org/10.2118/171134-ms.

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Abstract In Situ Combustion is an enhanced oil recovery method which consists on injecting air to the reservoir, generating a series of oxidation reactions at different temperature ranges by chemical interaction between oil and oxygen, the high temperature oxidation reactions are highly exothermic; the oxygen reacts with a coke like material formed by thermal cracking, they are responsible of generating the heat necessary to sustain and propagate the combustion front, sweeping the heavy oil and upgrading it due to the high temperatures. Wet in situ combustion is variant of the process, in whic

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