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Dissertations / Theses on the topic 'Addition polymerization. Chemical kinetics'

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1

Gwee, Liang Elabd Yossef A. "Ion transport in polymer/ionic liquid films /." Philadelphia, Pa. : Drexel University, 2010. http://hdl.handle.net/1860/3268.

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2

Rahmathullah, Mohamed Aflal Mohamed Palmese Giuseppe R. Elabd Yossef A. "Multifunctional polymers via incorporation of ionic groups at molecular and mesoscopic length scales /." Philadelphia, Pa. : Drexel University, 2008. http://hdl.handle.net/1860/2841.

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3

Lee, Jihean Palmese Giuseppe R. "Cationic polymerization of glycidyl ethers and furans : improved electron beam and UV cured epoxy networks /." Philadelphia, Pa. : Drexel University, 2007. http://hdl.handle.net/1860/2538.

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4

Chaffey-Millar, Hugh William Chemical Sciences &amp Engineering Faculty of Engineering UNSW. "An experimental and computational study of two state of the art living free radical polymerisation techniques." Awarded by:University of New South Wales. Chemical Sciences & Engineering, 2008. http://handle.unsw.edu.au/1959.4/41421.

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This thesis describes the research conducted by t he author in completion of a Doctor of Philosophy in the Centre for Advanced Macromolecular Design(CAMD), Univcrsity of New South Wales (UNSW) , Sydney, Australia; under the supervision of Professor Christopher Barner-Kowollik and Doctor Michelle L. Coote (Australian National University). The research has led to the creation of new knowledge in the fields of free radical polymerisation and chemical kinetics. Research was conducted in two main thrusts: (1) investigation into the governing kinetic processes behind star polymer synthesis via wha
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5

Karmore, Vishal K. "Kinetics Of Polymerization And Degradation By Non-Conventional Techniques." Thesis, Indian Institute of Science, 2001. http://hdl.handle.net/2005/269.

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Non-conventional techniques for polymerization and depolymerization were investigated. The rates of polymerization were enhanced higher in ultrasonic, supercritical fluids and microwaves. However in these system under certain conditions, simultaneous degradation also occurred. Depolymerization was studied by various methods like thermal degradation in supercritical fluids and in presence of oxidizers, Lewis acid and other organic acids. Degradation by ultrasound and thermal degradation of polymer mixtures were also investigated. The scission of the polymer backbone is random for thermal degrad
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6

Kumar, Vipul. "Pyrolysis and gasification of lignin and effect of alkali addition." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29609.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Sujit Banerjee; Committee Co-Chair: Wm. James Frederick, Jr.; Committee Member: John D. Muzzy; Committee Member: Kristiina Iisa; Committee Member: Preet Singh. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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7

Al-Saleh, Mohammad. "MODELING OLEFIN POLYMERIZATION USING MONTE CARLO SIMULATION: DETAILED COMONOMER DISTRIBUTION." Thesis, University of Waterloo, 2006. http://hdl.handle.net/10012/2863.

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In recent years there have been many efforts to develop and expand the ability of mathematical models capable of describing polymerization systems. Models can provide a key competitive advantage for the industry and research in terms of production and technology development. As new resins are continuously produced to meet the requirement of final applications and processability, it is imperative to pursue strong polymer characterization with special attention to detailed analysis of polymer microstructure. The microstructure of polyolefin is defined by its distribution of molecular weigh
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8

Temeng, Kwaku Ofosu. "The design and evaluation of a control scheme for emulsion polymerization in a tube-CSTR system." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/10019.

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9

Brennan, Daniel P. "Small molecule and polymer templating of inorganic materials." Diss., Online access via UMI:, 2006.

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10

Donato, Karen Ann Ehnot. "The kinetics of a methyl methacrylate polymerization initiated by the stable free radicals in irradiated polytetrafluoroethylene and properties of the resultant graft polymer." Ohio : Ohio University, 1987. http://www.ohiolink.edu/etd/view.cgi?ohiou1171670342.

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11

Elmakki, Rihab Abdelrahman Mohamed. "The effect of extending four cements with limestone with addition of super-plasticisers on the hydration reaction of SCC cement paste." Thesis, Cape Peninsula University of Technology, 2016. http://hdl.handle.net/20.500.11838/2466.

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Thesis (MTech (Civil Engineering))--Cape Peninsula University of Technology, 2016.<br>The addition of certain fillers and additives in conventional concrete is imperative for improving its rheological properties. The effect of additives, namely limestone (LS) and superplasticisers (SP), on the hydration kinetics of self-compacting concrete (SCC) was investigated on cement paste scale. These additives interact mostly with cement paste, since aggregates are considered to be inert materials. An understanding of the effect of these additives on the hydration kinetics of cement paste is paramount t
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12

Zaro, Marcelo. "Avaliação dos processos de sorção de óleos em mantas não tecidas de PP." reponame:Repositório Institucional da UCS, 2014. https://repositorio.ucs.br/handle/11338/891.

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Os sorventes não tecidos de polipropileno (PP) são utilizados na recuperação de óleos devido às suas características hidrofóbicas e oleofílicas. O objetivo deste trabalho foi avaliar uma manta não tecida de PP quanto às suas características físico-químicas, capacidade de sorção e cinética de sorção e dessorção de óleos, potencial de reuso, flutuabilidade, resistência física em ambientes hostis e toxicidade. O estudo físico-químico da manta compreendeu a determinação da espessura, densidade, morfologia (microscopia eletrônica de varredura), propriedades térmicas (calorimetria diferencial de var
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13

Chami, Zoubida. "Addition de radicaux aryles generes electrochimiquement sur les olefines." Paris 7, 1988. http://www.theses.fr/1988PA077031.

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Reaction d'electrosynthese des liaisons carbone-carbone: addition de radicaux aryles produits par electrochimie-reduction des derives aromatiques halogenes sur des doubles liaisons olefiniques. Etudes theorique et experimentale. Discussion de la regioselectivite des reactions
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14

Lopez, Palacio Raul Ernesto. "Otimização da formulação e avaliação fisico-mecanica de biomateriais compositos para obturações odontologica." [s.n.], 1995. http://repositorio.unicamp.br/jspui/handle/REPOSIP/263361.

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Orientador: Cecilia Amalia de Carvalho Zavaglia<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica<br>Made available in DSpace on 2018-07-24T19:52:40Z (GMT). No. of bitstreams: 1 LopezPalacio_RaulErnesto_M.pdf: 4817935 bytes, checksum: b634da0ffd4f08cb1716f7bfe6bbf6c5 (MD5) Previous issue date: 1998<br>Resumo: Este trabalho teve comoobjetivoprincipala otimizaçãoda formulaçãoe a caracterizaçãode compósitosde matriz polimérica,reforçadoscom partículasde quartzo, para uso em odontologia com cura fotoquímica e química.Na otímízação da formulação foi d
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15

Banu, Ionut. "Modeling and optimization of tubular polymerization reactors." Phd thesis, Université Claude Bernard - Lyon I, 2009. http://tel.archives-ouvertes.fr/tel-00719401.

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The aim of this thesis is the investigation of modeling and optimization particularities of tubular polymerization reactors. The original work is divided in two sections, the first treating a modeling and optimization study of tubular reactors for methyl methacrylate polymerization in solution, and the second, an experimental and theoretical study of L-lactide reactive extrusion. In the first section, reactor simulations in similar operating conditions were performed in order to select a representative kinetic model among the published kinetic models for MMA solution polymerization. Two widely
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16

Baqar, Mohamed Saad. "Methylol-Functional Benzoxazines: Novel Precursors for Phenolic Thermoset Polymers and Nanocomposite Applications." Case Western Reserve University School of Graduate Studies / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=case1373319624.

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17

Le, Dao. "Synthèse, caractérisation et polymérisation par ouverture de cycle par métathèse de macromonomères cyclobuténiques obtenus par chimie " click " et polymérisation RAFT." Phd thesis, Université du Maine, 2012. http://tel.archives-ouvertes.fr/tel-00743217.

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Ce travail de thèse porte sur la synthèse de copolymères greffés à squelette 1,4-polybutadiène (PBu) et polyoxanorbornène par combinaison de ROMP et chimie click et/ou polymérisation RAFT selon la méthode grafting through. Une gamme de macromonomères symétriques et non symétriques originaux poly(oxyde d'éthylène) (POE), poly(acrylate d'éthyle), poly(acrylamide de N-isopropyle) (PNIPAM) et POE-b-PNIPAM ont été synthétisés à partir de précurseurs oxanorbornène et cyclobutène fonctionnalisés présentant un ou deux groupements clickables et/ou un agent RAFT par chimie click et polymérisation RAFT.
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18

Schapman, Fanny. "Fonctionnalisation et étude de la réticulation d'un polybutadiène hydroxy téléchélique." Rouen, 1996. http://www.theses.fr/1996ROUES035.

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Ce travail concerne la fonctionnalisation d'un polybutadiène hydroxytéléchélique (PBHT) par modification en une seule étape afin que la réticulation ultérieure soit menée sans utilisation de diisocyanate. Par addition radicalaire d'un thiol silylé (SISH) sur les doubles liaisons du PBHT, des fonctions alkoxysilane ont été greffées. Pour de faibles concentrations en SISH, l'addition se fait uniquement sur les doubles liaisons 1,2. Un nouveau modèle cinétique a été proposé. Par addition d'isocyanates hétérofonctionnels sur les fonctions OH du PBHT, différents prépolymères porteurs de fonctions s
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19

Prabhu, Achutha. "Agrégation irréversible par patchs de particules colloïdales : une étude par simulation numérique." Phd thesis, Université du Maine, 2012. http://tel.archives-ouvertes.fr/tel-00795636.

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La variété des structures colloïdales auto assemblées est principalement due à la présence d'interactions anisotropes. Nous présentons ici une méthode numérique pour étudier l'agrégation irréversible par patches de particules sphériques. Il s'agit d'une amélioration de la dynamique d'amas browniens prenant en compte les interactions par patches et les mouvements de rotation. Nous limitons notre étude aux particules à deux patches opposés de taille variable. Une interaction isotrope, faible, est également ajoutée pour modéliser une polymérisation par étape dans diverses conditions de solvant. C
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20

Boivin, Sylviane. "Modification chimique du polychloroformiate de vinyle dans les conditions de la catalyse par transfert de phase : étude d'un nouveau complexe de transfert de charge macromoléculaire à base de carbazole." Paris 6, 1986. http://www.theses.fr/1986PA066482.

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21

Soutif, Jean-Claude. "Etude de l'addition des acides carboxyliques sur les structures oxiranne : application aux polymeres epoxydes." Le Mans, 1987. http://www.theses.fr/1987LEMA1010.

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La modification chimique au deuxieme degre de polymeres epoxydes a ete etudiee pour developper une methode de fixation de principes actifs (medicaments, colorants, complexants) comportant des fonctions acides, sur des supports macromoleculaires. Le catalyseur est un sel de tetramethylammonium de l'acide a fixer. Epoxydation de polyisoprene et polybutadiene
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22

Cunge, Gilles. "Diagnostics optiques et électriques dans les plasmas : application à l'étude des interactions plasma-surface pour la micro-électronique." Université Joseph Fourier (Grenoble ; 1971-2015), 1997. http://www.theses.fr/1997GRE10104.

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Nous avons etudie la cinetique des radicaux cf et cf#2 dans un plasma pulse de cf#4 utilise pour la gravure de couches minces de si ou sio#2 dans l'industrie micro-electronique. Les profils de concentration spatiaux resolus dans le temps de ces especes ont ete determines par la technique de fluorescence induite par laser. Ils permettent d'etudier les mecanismes de perte et de production de ces radicaux en phase gazeuse et sur les surfaces du reacteur. Un nouveau mecanisme de production en surface de cf et de cf#2 a ainsi ete mis en evidence, en particulier sur un substrat de silicium. Nous avo
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23

Alshaiban, Ahmad. "Propylene Polymerization Using 4th Generation Ziegler-Natta Catalysts: Polymerization Kinetics and Polymer Microstructural Investigation." Thesis, 2011. http://hdl.handle.net/10012/6074.

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A systematic study of propylene polymerization using a 4th generation Ziegler-Natta catalyst is presented in this thesis. The apparent kinetic rate constants for propylene polymerization were estimated in the presence and absence of hydrogen and/or donor. The estimated activation energies for activation, propagation, and deactivation were found to be close to values previously reported in the literature for similar catalysts. The polypropylene samples were characterized using high-temperature gel permeation chromatography (GPC), carbon-13 nuclear magnetic resonance (13C NMR), and crystallizati
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24

Gonzalez-Ruiz, Ramon A. "Kinetics of the slurry polymerization of propylene using metallocene catalysts: Experiment and simulation." 2005. https://scholarworks.umass.edu/dissertations/AAI3163668.

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An experimental reaction polymerization facility was built to study polymerization kinetics using metallocene catalysts and it is described in detail. It has been used to evaluate the performance of methylaluminoxane (MAO)-activated metallocene catalysts in slurry-mode propylene homopolymerization. Experiments using two relatively low activity C2 symmetric catalytic species, rac-ethylenebis(1-indenyl)zirconium dichloride (I) and rac-ethylenebis(4,7-dimethyl-1-indenyl)zirconium dichloride (II) were performed at different process conditions where polymerization kinetics are the rate limiting ste
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25

Zhou, Mingxiao. "Investigation of Kinetics of Nitroxide Mediated Radical Polymerization of Styrene with a Unimolecular Initiator." Thesis, 2009. http://hdl.handle.net/10012/4327.

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This thesis presents the results of a study on the kinetics of nitroxide-mediated radical polymerization of styrene with a unimolecular initiator. The primary objective was to obtain a more comprehensive understanding of how a unimolecular-initiating system controls the polymerization process and to clarify the effects of various reaction parameters. Previous work in this field has met with some difficulties in the initiator synthesis, such as low yield and inconsistency of molecular weight. These problems were overcome by adjusting reaction conditions and procedures. Better yields of initia
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