Academic literature on the topic 'Aggregation induced emission (AIE)'

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Journal articles on the topic "Aggregation induced emission (AIE)"

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Liu, Bin, and Ruoyu Zhang. "Aggregation induced emission: Concluding Remarks." Faraday Discussions 196 (2017): 461–72. http://dx.doi.org/10.1039/c6fd00258g.

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This article presents the Closing Remarks of the Faraday Discussion on aggregation induced emission (AIE) held in Guangzhou, China in November 2016. The history of the AIE phenomenon is summarized, from its discovery and mechanistic studies to real-life applications in optoelectronics, environmental monitoring and biomedical research. The paper concludes with comments on the future perspectives of the field.
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Zhao, Zujin, Bairong He, and Ben Zhong Tang. "Aggregation-induced emission of siloles." Chemical Science 6, no. 10 (2015): 5347–65. http://dx.doi.org/10.1039/c5sc01946j.

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Wang, Huan, Yiru Li, Yiyao Zhang, Ju Mei, and Jianhua Su. "A new strategy for achieving single-molecular white-light emission: using vibration-induced emission (VIE) plus aggregation-induced emission (AIE) mechanisms as a two-pronged approach." Chemical Communications 55, no. 13 (2019): 1879–82. http://dx.doi.org/10.1039/c8cc08513g.

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Liu, Bin, and Ben Zhong Tang. "Themed Issue on Aggregation‐Induced Emission (AIE)." Chemistry – An Asian Journal 14, no. 6 (March 2019): 672–73. http://dx.doi.org/10.1002/asia.201900185.

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Würthner, Frank. "Aggregation‐Induced Emission (AIE): A Historical Perspective." Angewandte Chemie International Edition 59, no. 34 (July 13, 2020): 14192–96. http://dx.doi.org/10.1002/anie.202007525.

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Nie, Han, Kun Hu, Yuanjing Cai, Qian Peng, Zujin Zhao, Rongrong Hu, Junwu Chen, Shi-Jian Su, Anjun Qin, and Ben Zhong Tang. "Tetraphenylfuran: aggregation-induced emission or aggregation-caused quenching?" Materials Chemistry Frontiers 1, no. 6 (2017): 1125–29. http://dx.doi.org/10.1039/c6qm00343e.

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Tetraphenylfuran, structurally similar to AIE-active siloles, exhibits the traditional aggregation-caused quenching, which is co-caused by the restriction of intramolecular rotation and the conjugation effect.
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Zhuang, Zeyan, Youhong Tang, Dan Ding, Youichi Tsuchiya, and Zujin Zhao. "Highlights from Faraday Discussion: aggregation-induced emission." Chemical Communications 53, no. 22 (2017): 3158–64. http://dx.doi.org/10.1039/c7cc90086d.

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Faraday Discussion 196: aggregation-induced emission brought together around 100 researchers to discuss recent progress, current challenges and potential breakthroughs in the design of new AIE luminogens, the understanding of AIE mechanisms and the exploration of advanced technological applications.
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Khuong Mai, Duy, Joomin Lee, Ilgi Min, Temmy Vales, Kyong-Hoon Choi, Bong Park, Sung Cho, and Ho-Joong Kim. "Aggregation-Induced Emission of Tetraphenylethene-Conjugated Phenanthrene Derivatives and Their Bio-Imaging Applications." Nanomaterials 8, no. 9 (September 15, 2018): 728. http://dx.doi.org/10.3390/nano8090728.

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In this study, a series of rationally designed emissive phenanthrene derivatives were synthesized and their aggregation-induced emission (AIE) properties in tetrahydrofuran (THF)/water mixtures were investigated. Two tetraphenylethene (TPE) segments were conjugated to both ends of the phenanthrene core at the para-positions and meta-positions, resulting in pTPEP and mTPEP derivatives, respectively. While the TPE-conjugated phenanthrene derivatives did not show any emission when dissolved in pure THF, they showed strong sky-blue emissions in water-THF mixtures, which is attributed to the restriction of intramolecular motions of TPE segments by aggregation. Furthermore, silica nanoparticles loaded with these AIE-active compounds were prepared and proved to be promising intracellular imaging agents.
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Feng, Guangxue, and Bin Liu. "Aggregation-Induced Emission (AIE) Dots: Emerging Theranostic Nanolights." Accounts of Chemical Research 51, no. 6 (May 7, 2018): 1404–14. http://dx.doi.org/10.1021/acs.accounts.8b00060.

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Shi, Zhengwei, Joshua Davies, Sei-Hum Jang, Werner Kaminsky, and Alex K. Y. Jen. "Aggregation induced emission (AIE) of trifluoromethyl substituted distyrylbenzenes." Chemical Communications 48, no. 63 (2012): 7880. http://dx.doi.org/10.1039/c2cc32380j.

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Dissertations / Theses on the topic "Aggregation induced emission (AIE)"

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Yu, Wai Hong. "Synthesis, Characterization and application studies of new aggregation-induced emission (AIE)-active materials." HKBU Institutional Repository, 2018. https://repository.hkbu.edu.hk/etd_oa/496.

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The structural design, synthesis and characterization of luminogens with aggregation-induced emission (AIE) properties are studied in this thesis. The remarkable emission properties, thermal stability and biocompatibility of the AIE-active materials demonstrate the promising applications in bioimaging and organic light-emitting diodes (OLEDs).;Chapter 1 introduces the existence of aggregation-caused quenching (ACQ) effect in most conventional organic dyes as well as phosphorescent transitional metal complexes. Discovery of AIE and its mechanical study allow further exploration of usage in organic luminescent materials. This chapter also gives some examples and the applications these AIE-active compounds.;In Chapter 2, a series of cyanostilbenes with simple electron donor (D)-p-electron acceptor (A) structure are presented and synthesized. They exhibit remarkable AIE effect as well as deep red emission peak in 95 % water fraction in THF. These results indicate that attachment of these electron acceptors provides alternative strategy for designing highly emissive AIE-active materials.;In Chapter 3, strongly emissive cyanostilbenes with phenothiazine unit are designed and synthesized. This chapter also investigates the effect of substituents in phenothiazine and terminal cyanostilbene on the photophysical properties and AIE effect. The results suggest that they are AIE-active with different sizes in nano-aggregates. Furthermore, these dyes exhibit clear and strong fluorescence in live cell imaging with excellent biocompatibility.;In Chapter 4, a series of AIE-active phosphorescent Pt(II) complexes made up of C^N^C tridentate ligands are designed and synthesized. They exhibit different morphologies and emission properties upon aggregation in 90 % water in acetonitrile although similar tridentate ligands are applied. One of the complexes in this chapter show nano-rod formation with the highest quantum efficiency in aggregated state, suggesting that rapid self-assembly process occurs to prevent non-radiative decay and oxygen quenching.;In Chapter 5, a series of bis-cyanostyryl fluorophores are designed and synthesized. They are emissive in solid state with colour range from orange to NIR region. Furthermore, they are AIE-active and some of them may contain hybridized local and charge transfer (HLCT) excited state to achieve highly efficient emission upon solvatochromic investigation. Some bis-cyanostyryl thiophenes are fabricated in OLED devices show deep-red to NIR emission, indicative of a promising way to design solid-state NIR-emissive compounds using bis-cyanostyryl derivatives.;Finally, Chapter 6 and 7 present the concluding remarks and the experimental details of the work in Chapters 2 to 5, respectively.
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Lau, Wai Sum. "Synthesis, characterization and application studies of cyanostilbene-based molecular materials with aggregation-induced emission (AIE) characteristics." HKBU Institutional Repository, 2014. https://repository.hkbu.edu.hk/etd_oa/70.

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The molecular design, synthesis, spectroscopic and photophysical characterization of a series of cyanostilbene-based compounds are studied in this thesis. The thermal, electrochemical and aggregation induced emission (AIE) properties of these cyanostilbene-based compounds, as well as their application in organic lighting-emitting diodes, live cell imaging, chemical vapor sensor were investigated. Chapter 1 gives a brief introduction on the aggregation-caused quenching (ACQ) behavior of the conventional organic luminogens and the discovery and proposed mechanism of AIE phenomenon. Furthermore, some examples and the applications of these AIE compounds will be discussed. In Chapter 2, triphenylamine- and carbazole-containing cyanostilbene-based derivatives are presented. From the examination of the emission profile, they are all AIE-active through comparison of the photoluminescence intensity in dissolved and in aggregated states. Additionally, the calculation of the enhancement ratio (I/I0 – 1) of each fluorophore was performed in order to quantify its AIE effect. One of our cyanostilbene-based luminogens has achieved an enhancement ratio with a value of 1128. This cyanostilbene-based luminogens has also shown good performance in OLED investigation. In addition to the OLEDs application, the selected cyanostilbene-based luminogens with solid-state emission, cell-permeability and reversible switch-on/off capability have illustrated the positive result in live-cell imaging and chemical vapor sensing. Conjugated polymer with high molecular weight is the superior option by overcoming the weaknesses of low-molecular-weight luminogens with excellent thin-film form ability and comparatively simple and inexpensive fabrication processes. The design and synthesis of the cyanostilbene-based polymeric chromophores are described in Chapter 3. The polymerization of the AIE-active diacetylene ligands by connection of trans-[Pt(PBu3)2] unit at both ends has successfully retained their AIE behavior. In contrast, the ACQ problem has occurred on the polymers with organic spacers and the AIE-active ligands. From the DFT calculation on the Pt polymers and the blue shift of emission spectra in high water content suggested that the AIE phenomenon of Pt polymers is probably originated from the elimination of the non-radiative intramolecular charge transfer (ICT) process. Owing to the high demand in red-emitting materials in the applications of electroluminescent devices, fluorescent sensing and bio-imaging, effort has been made to design a system with the new chromophores with donor (D) – acceptor (A) system and thus to synthesize phenothiazine (D)-containing cyanostilbene (A)-based derivatives which are depicted in Chapter 4. Consistent with the conventional AIE-active luminogens with a successively climb of photoluminescence intensities in response to the increase of water proportion, phenothiazine-containing cyanostilbene-based derivatives has exhibited a V-shape fashion of emission intensity. It suggests that the emission of chromophores started to be quenched due to the increase of solvent polarity, overriding that of the molecular aggregation when a “small” volume of water is being introduced. While aggregate formation was dominant from the addition of a “large” amount of poor solvent, less polar local environment was created which suppressed the non-radiative transition to the ICT state and intensified the emission efficiency. Phenothiazine (D) – cyanostilbene (A) system has created a series of red-emitting chromophores with great tunability for the sake of achieving the desired emission color and better emission efficiency. To functionalize these AIE-active cyanostilbene-based chromophores, pyridine group was attached to the compounds to take the advantage of its metal-chelating capability, which is discussed in Chapter 5. The AIE features of cyanostilbene-based compounds can be preserved after the introduction of the pyridyl unit. Even it possessed a weak photoluminescence in its dilute solution which suggest that the high electron delocalization within the molecule has rigidified the structure to some extent, it is transformed to a highly emissive state with a high proportion of water. The exclusive variation of emission behavior with obvious bathochromic shift and boost of emission spectrum in the presence of cadmium-(II) ion has demonstrated its potential metal ion sensing ability. Chapter 6 and 7 present the concluding remarks and the experimental data of the compounds of Chapter 2 to 5, respectively.
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Dong, Lei. "Conception et synthèse de glyco-sondes fluorescentes pour des applications en détection." Thesis, Lyon, 2019. http://www.theses.fr/2019LYSE1153/document.

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Avec le progrès scientifique et les besoins sociétaux, diverses méthodes de détection spécifiques et sensibles des métaux, des protéines et d’autres biomolécules sont largement utilisées dans la protection de l’environnement, la surveillance des maladies, la pharmacothérapie, la production agricole, l’industrie et d’autres domaines importants. Les sondes fluorescentes sont largement développées sur la base des phénomènes de transfert d’énergie (ICT, PET, FRET) et appliquées par exemple à la détection de contaminants ou à l'imagerie cellulaire. Mais l’effet d’agrégation (ACQ) atténue généralement l’intensité de la fluorescence et limite ainsi les applications de sondes organiques (souvent peu solubles dans l’eau) dans l’imagerie cellulaire et les systèmes vivants. Par conséquent, le concept d'« agregated induced emission » (AIE) représente une solution à ces problèmes d’agrégation et plusieurs glycoclusters, glyco-sondes et glyco-complexes fluorescents ont été conçus et reportés pour des applications en analyse biologique. Notre premier projet visait à concevoir et à synthétiser des glyco-polymères fluorescents pour le ciblage cellulaire et l’adressage de médicaments, tandis que la fluorescence permettrait la détection des cellules ciblées. Pour surmonter l'effet ACQ et les interférences provenant de la fluorescence biologique naturelle, nous avons conjugué le dicyanométhylène-4H-pyrane (DCM) et le tétraphényléthène (TPE) afin d'obtenir des sondes fluorescentes (AIE) émettant dans le proche infrarouge. Les glycosides ont fourni une bonne solubilité dans l'eau et l'auto-assemblage a conduit à des systèmes de détection et à une imagerie des cellules cancéreuses. Les glyco-polymères à base de TPE ont été synthétisés à partir de monomères de TPE incorporant deux monosaccharides par conjugaison azide-alcyne (CuAAC) et ces monomères ont été polymérisés par des réactions de CuAAC ou thiol-ène. Les glyco-polymères à base de TPE ne présentaient malheureusement pas une assez grande longueur de chaîne (généralement moins de 7 unités) et les propriétés fluorescentes attendues ne pouvaient donc pas être atteintes. Nous avons ensuite conçu et synthétisé des glyco-dots auto-assemblés par des sondes DCM et des glycoclusters à base de TPE. Les glyco-dots ont présenté une hydrosolubilité élevée et une réponse sélective au peroxynitrite (ONOO-) à la fois in vitro et dans des analyses cellulaires. Les glyco-dots pourraient détecter ONOO- endogène et exogène, mais sans reconnaissance cellulaire spécifique. Nous avons conçu et synthétisé des sondes fluorescentes AIE pouvant s'auto-assembler avec des glycoclusters à base de TPE. Les glyco-dots résultants étaient facilement solubles dans l'eau et présentaient une sensibilité et une sélectivité excellentes pour la détection du thiophénol in vitro et dans des échantillons d'eau environnementaux.Nous avons finalement combiné les deux fragments TPE et DCM pour synthétiser un nouveau fluorophore AIE (TPE-DCM) avec émission à longue longueur d'onde. Ensuite, la conjugaison avec des glycosides par CuAAC a conduit à des sondes AIE fluorescentes à émission de longue longueur d'onde, avec une excellente solubilité dans l'eau. Une application à la détection de glycosidases in vitro et dans des dosages cellulaires ou sur des modèles animaux a été possible avec ces sondes
With scientific and social progress, various methods for the specific and sensitive detection of metals, proteins and other biomolecules are widely utilized in environmental protection, disease surveillance, drug therapy, agricultural production, industry and other significant areas. Fluorescent probes are widely developed based on ICT, PET, FRET and other fluorescence mechanisms, and applied to the detection of contaminants or in cell imaging. But the ACQ effect usually quenched the fluorescence intensity and thus limited the applications of organic probes in cell imaging and living systems. Therefore, the concept of aggregated-induced emission (AIE) appears as a possible solution to these problems and several fluorescent glycoclusters, glyco-probes and glyco-complexes were designed and reported for biological analysis. Our first project aimed to design and synthesize fluorescent glyco-polymers with multiple glycosides for cell targeting and drug delivery while fluorescence will allow the detection of the targeted cells. To overcome the ACQ effect and interference from natural biological background fluorescence, we conjugated dicyanomethylene-4H-pyran (DCM) and tetraphenylethene (TPE) to obtain near-infrared AIE fluorescent probes. The glycosides provided good water solubility and self-assembly in water led to detection systems and imaging cancer cells. TPE-based glycopolymers were synthesized from TPE monomers incorporating two monosaccharides by CuAAC conjugation and these monomers were polymerized by either CuAAC or thiol-ene “click” reactions. The TPE-based glycopolymers did not display a large chain length (typically less than 7 units) and the expected fluorescent properties could not be reached. We then designed and synthesized glyco-dots self-assembled by DCM probes and TPE-based glycoclusters. The glyco-dots displayed high water-solubility and selective response to peroxynitrite (ONOO-) both in vitro and in cell assays. The glyco-dots could detect endogenous and exogenous ONOO- but no specific cell recognition. We designed and synthesized AIE fluorescent probes which could self-assemble with TPE-based glycoclusters. The resulting glyco-dots were readily water soluble and displayed excellent sensitivity and selectivity for thiophenol detection in vitro and in environmental water samples. We finally combined both TPE and DCM moieties to synthesize a novel AIE fluorophore (TPE-DCM) with long-wavelength emission. Then conjugation with glycosides through CuAAC led to AIE fluorescent probes with long-wavelength emission, excellent water-solubility. Application to the detection of glycosidases in vitro and in cell assays or animal models was possible with these probes
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Yu, Tingting. "Solid state luminescent molecules, macromolecules and materials, their response to stimuli and their applications in devices." Thesis, Lyon, 2020. http://www.theses.fr/2020LYSEN061.

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Au cours de cette thèse, nous avons développé de nouveaux chromophores conjugués luminescents présentant une alternance de groupements donneurs et accepteurs, avec une attention particulière quant à leurs propriétés d’émission dans le rouge et proche infra-rouge à l’état solide ou agrégats. Nous avons étudié l’influence de la longueur de chaine et de la nature de la substitution donneur/accepteur non seulement sur les propriétés optiques en solution mais aussi (et surtout) sur le matériau agrégé. Enfin, en utilisant les propriétés spécifiques de certains des composés développés selon cette approche, nous avons exploré leur potentiel pour des applications allant de matériaux fluorochrome stimuli-responsifs (sous forme de films) à l’élaboration de sondes à deux photons émettant dans le proche infra rouge pour l’imagerie biologique. Les principaux accomplissements de cette thèse sont les suivant: 1/ de nouveaux polymères alternant des motifs triarylamine (ou carbazole)/ tetraphenylethylene (TPE) dans leur chaine principale ont été synthétisés. Leurs propriétés d’émission à l’état solide présentent des caractéristiques d’agrégats-J, peu courant dans les dérivés TPE, ce que nous attribuons à l’arrangement linéaire des chaînes polymères; 2/ Une nouvelle famille de colorants diphenylamine/benzobisthiazole et leurs dérivés oligomères ont été synthétisés. Leurs propriétés de luminescence présentent une sensibilité marquée à la protonation, que nous avons utilisée dans la conceptions de dispositifs luminescents commutables par stimuli acide/base; 3/Nous avons exploré la possibilité d’introduire des modifications chimiques complémentaires sur cette nouvelle famille de chromophores, afin d’obtenir des composés luminescents à l’état solide dans le proche infrarouge, en particulier par un changement de la nature de la transition électronique à transfert de charge intramoléculaire vers une transition cyanine, par le biais d’une quaternarisation des fonction benzobisthiazole. D’autres modifications ont conduit à une amélioration de la biocompatibilté des molécules, de leurs propriétés AIE, ou encore de leur spécificité de marquage cellulaire; 4/ Ces nouveaux composés présentent une luminescence photo-commutable (de type allumé/éteint), qui pourrait présenter un intérêt dans l’élaboration d’agents de contraste pour l’imagerie de microscopie super-résolue
In this thesis, we developed new luminescent conjugated chromophores presenting an alternation of electron donor and acceptor groups, with a specific focus on their emission properties in aggregates or solid states in far-red or near infrared region. We studied the influence of chain length and donor/acceptor substitution not only on the optical properties of the isolated compounds, but also (and especially) on the material in its aggregated state. Finally, taking advantages of these specific properties of some of the as-designed candidates, we explored their potential applications ranging from fluorochromic stimuli-responsive sensors (in film form) to red and NIR luminescent two-photon probes for biological imaging. The main achievements of this thesis are the following: 1) new alternating triarylamine or carbazole / tetraphenylethylene (TPE) polymers were synthesized. Their solid state luminescence poseeses typical J-aggregates emission features in solid state, unusual in TPE derivatives that we relate to the linear polymeric nature of the object; 2) A new family of diphenylamine / benzobisthiazole chromophores and derived oligomers were synthesized . Their luminescence properties present a marked sensitivity to protonation, which we took advantage of in the making of acid-base responsive luminescent devices; 3) we explored the possibility of additional chemical transformations of the newly designed chromophore, in order to achieve solid state NIR emission, in particular by means of a change in the character of the electronic transition from Intra-Molecular Charge Tranfer (ICT) to Cyanine transition owing to benzothiazole quaternarization. Other modifications resulted in improvement of their AIE properties, bioavailability and selectivity of their cellular compartments staining ability; 4) These new compounds present a reversible photoinduced “on-off” switching of their luminescence properties, which might present an interest in the design of contrast-agents for super resolution imaging
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Dong, Yujie. "Synthesis, photophysical properties and applications of aggregation-induced emission materials based on cyanostilbene moiety." HKBU Institutional Repository, 2016. https://repository.hkbu.edu.hk/etd_oa/313.

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The concept of "aggregation-induced emission" (AIE) effect has induced a great deal of attention these days. Now, exploration of new AIE-active molecular system and multiple high technique applications for AIE materials are the two research hotspots. Cyanostilbene, as a classical structural unit in photoelectric functional materials, also exhibited this unique luminescence behavior. The research background was illustrated in Chapter 1, which mainly introduced the development of this subject. In this project, Chapter 2 and Chapter 3 presented two classes of functionalized AIE-active molecules based on cyanostilbene moiety, and their applications were investigated, while Chapter 4 demonstrated a series of donor-acceptor (D-A) molecules with highly emissive unit, and their photophysical properties were studied.;In Chapter 2, four different donor-substituted cyanostilbene-based dipyrrins were synthesized and characterized. The investigation of photophysical properties confirms that these molecules are AIE-active, which should be attributed to the cyanostilbene moiety. The introduction of different donor groups showed little impact on their luminescence. Furthermore, the emission properties of these molecules were found to be sensitive to Zn2+, that is, addition of Zn2+ enormously enhanced its fluorescence in THF. The titration experiments proved they showed good selectivity and sensitivity for Zn2+ detection with relatively low limit of detection. Job's curve and spectral studies of their corresponding zinc complex indicated that the ratio for dipyrrins and Zn2+ is 2:1, which suggested the formation of zinc complex by chelation-enhanced fluorescence (CHEF) effect should be the reason of the enhanced fluorescence. By combining dipyrrin with typical AIE-active moiety tetraphenylethylene (TPE), an AIE-active TPE-based dipyrrin was prepared. The studies of its fluorogenic Zn2+ detection confirmed that the CHEF effect together with AIE effect are responsible for the intense fluorescence, indicating the potential application as a Zn2+ detector in aqueous media.;In Chapter 3, the cyanostilbene backbone was functionalized with a terpyridine unit to construct four terpyridine-based cyanostilbene molecules with different donor substitutents. The investigation of their photophysical properties confirms that they are AIEE-active. With the effect of different electron-donating groups, their solid-state fluorescence color was adjusted from blue to orange-red successfully. According to the calculation results of their frontier molecular orbitals, terpyridine has little impacts on their luminescence, but would influence their solid-state emission obviously owing to its large steric hindrance. This class of molecules displayed higher luminescence efficiency in solid state than in their dissolved state. The twisted molecular conformation in single crystal, which effectively avoids close π-π stacking, was assumed to be responsible for the high luminescence efficiency in solid state. This kind of molecules show distinct switched fluorescence by stimuli of acid/base vapors, and this phenomenon derives from the protonation effect of nitrogen atoms in the terpyridine unit. Moreover, three of these molecules exhibit good electroluminescence properties. Especially, the crystal of non-donor substituted molecule show amplified spontaneous emission (ASE) properties, indicating this blue-emissive material can be used in multiple areas such as chemical sensor, organic light emitting diodes (OLEDs) and organic laser media.
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Ohtani, Shunsuke. "Creation of Emissive and Functional Materials Based on Fused-Boron Complexes." Kyoto University, 2021. http://hdl.handle.net/2433/261618.

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Ito, Shunichiro. "Synthesis and Photophysical Properties of Functional Luminescent Materials Based on β-Diiminate Complexes Composed of Main-Group Metals." Doctoral thesis, Kyoto University, 2020. http://hdl.handle.net/2433/245840.

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京都大学
0048
新制・課程博士
博士(工学)
甲第22155号
工博第4659号
新制||工||1727(附属図書館)
京都大学大学院工学研究科高分子化学専攻
(主査)教授 田中 一生, 教授 秋吉 一成, 教授 古賀 毅
学位規則第4条第1項該当
Doctor of Philosophy (Engineering)
Kyoto University
DGAM
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Suenaga, Kazumasa. "Precise Control of Highly-Efficient Solid-Emissive Property of Boron Ketoiminate." Kyoto University, 2019. http://hdl.handle.net/2433/242531.

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付記する学位プログラム名: 充実した健康長寿社会を築く総合医療開発リーダー育成プログラム
Kyoto University (京都大学)
0048
新制・課程博士
博士(工学)
甲第21793号
工博第4610号
新制||工||1718(附属図書館)
京都大学大学院工学研究科高分子化学専攻
(主査)教授 田中 一生, 教授 秋吉 一成, 教授 大内 誠
学位規則第4条第1項該当
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Arribat, Mathieu. "Acides aminés phosphole ou silole : vers de nouvelles sondes fluorescentes pour un marquage de peptide innovant." Thesis, Montpellier, 2018. http://www.theses.fr/2018MONTS144.

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La première partie de ces travaux de thèse concerne la synthèse d’acides aminés phosphole par formation d’une liaison P-C. Les propriétés de fluorescence (absorption, émission et rendement quantique) sont modulées à la fois par les différents substituants présents sur le phosphore (BH3, O, S…) ainsi que par le squelette aromatique du phosphole. Des couplages peptidiques modèles réalisés en solution et sur support solide démontrent la possibilité d’intégrer ces acides aminés dans des peptides d’intérêts. La deuxième partie concerne la synthèse de nouveaux phospholes fonctionnalisés ainsi que d’une nouvelle méthode d’accrochage pour les introduire sur différents groupes pendants (SH, NH2, OH) d’acide aminés et peptides via la formation de liaisons P-S, P-N ou P-O. La troisième partie de ce travail a consisté en la synthèse d’une nouvelle classe d’acides aminés tétraphénylsilole fluorescents qui présentent des propriétés d’AIE (aggregation-induced emission) et pourront être utilisés pour le marquage de peptides d’intérêts
The first part of this work is focused on phospholyl amino acids synthesis by formation of a P-C bond. The fluorescent properties (absorption, emission and quantum yield) are modulated either by the substituent on the phosphorus atom (BH3, O, S, …) or by the aromatic skeleton of the phosphole. Peptide coupling in solution or on solid support were performed and showed the possibility to introduce such amino acids into peptide of interest. The second part of this work is dedicated to the synthesis of new functionalized phospholes for a chemoselective grafting on amino acid and peptides pendant groups (SH, NH2, OH) via PS, P-N or P-O bonds. The third part consists into the synthesis of a new class of tetraphenylsilole amino acids which exhibit AIE (aggregation-induced emission) fluorescent properties. Those compounds were successfully incorporated into di- an tri- peptides in solution and on solid support
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Dong, Wenyue [Verfasser]. "The Design and Synthesis of Conjugated Polymers with Aggregation-Induced Emission and Their Application in Fluorescence Sensing / Wenyue Dong." Wuppertal : Universitätsbibliothek Wuppertal, 2015. http://d-nb.info/1076929885/34.

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Books on the topic "Aggregation induced emission (AIE)"

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Tang, Ben Zhong, and Anjun Qin. Aggregation-induced emission: Fundamentals. Chichester, West Sussex, United Kingdom: John Wiley & Sons Inc., 2014.

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Qin, Anjun, and Ben Zhong Tang, eds. Aggregation-Induced Emission: Fundamentals. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.

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Tang, Youhong, and Ben Zhong Tang, eds. Principles and Applications of Aggregation-Induced Emission. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-99037-8.

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Fujiki, Michiya, Bin Liu, and Ben Zhong Tang, eds. Aggregation-Induced Emission: Materials and Applications Volume 1. Washington, DC: American Chemical Society, 2016. http://dx.doi.org/10.1021/bk-2016-1226.

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Fujiki, Michiya, Bin Liu, and Ben Zhong Tang, eds. Aggregation-Induced Emission: Materials and Applications Volume 2. Washington, DC: American Chemical Society, 2016. http://dx.doi.org/10.1021/bk-2016-1227.

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Tang, Ben-Zhong, and Anjun Qin. Aggregation-Induced Emission: Fundamentals. Wiley & Sons, Incorporated, John, 2013.

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Tang, Ben-Zhong, and Anjun Qin. Aggregation-Induced Emission: Applications. Wiley & Sons, Incorporated, John, 2013.

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Tang, Ben-Zhong, and Anjun Qin. Aggregation-Induced Emission: Fundamentals. Wiley & Sons, Incorporated, John, 2013.

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Tang, Ben-Zhong, and Anjun Qin. Aggregation-Induced Emission: Fundamentals. Wiley & Sons, Incorporated, John, 2013.

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Tang, Ben-Zhong, and Anjun Qin. Aggregation-Induced Emission: Applications. Wiley & Sons, Incorporated, John, 2013.

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Book chapters on the topic "Aggregation induced emission (AIE)"

1

Hu, Rongrong, Jacky W. Y. Lam, and Ben Zhong Tang. "AIE-Active Polymers." In Aggregation-Induced Emission: Fundamentals, 253–83. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch12.

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Yuan Shen, Xiao, Anjun Qin, and Jing Zhi Sun. "Red-Emitting AIE Materials." In Aggregation-Induced Emission: Fundamentals, 155–67. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch07.

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Lin, Chiao-Wen, and Chin-Ti Chen. "AIE or AIEE Materials for Electroluminescence Applications." In Aggregation-Induced Emission: Fundamentals, 1–41. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch19.

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Peng, Qian, Yingli Niu, Qunyan Wu, Xing Gao, and Zhigang Shuai. "Theoretical Understanding of AIE Phenomena Through Computational Chemistry." In Aggregation-Induced Emission: Fundamentals, 357–98. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch17.

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Corey, Joyce Y. "Synthesis of Siloles (and Germoles) that Exhibit the AIE Effect." In Aggregation-Induced Emission: Fundamentals, 1–37. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch01.

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Chen, Qi, and Bao-Hang Han. "Carbohydrate-Functionalized AIE-Active Molecules as Luminescent Probes for Biosensing." In Aggregation-Induced Emission: Fundamentals, 189–207. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch27.

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Hua, Jianli, He Tian, and Hao Zhang. "Properties of Triarylamine Derivatives with AIE and Large Two-Photon Absorbing Cross-Sections." In Aggregation-Induced Emission: Fundamentals, 169–84. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch08.

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Liu, Jianzhao, Jacky W. Y. Lam, and Ben Zhong Tang. "AIE Materials Towards Efficient Circularly Polarized Luminescence, Organic Lasing, and Superamplified Detection of Explosives." In Aggregation-Induced Emission: Fundamentals, 107–29. Chichester, United Kingdom: John Wiley and Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118735183.ch23.

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Wang, Dan, and Jun Qian. "AIE Luminogens for Three-Photon Fluorescence Bioimaging." In Principles and Applications of Aggregation-Induced Emission, 425–55. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-99037-8_18.

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Yuvasri, Genji Srinivasulu, Nirmal Goswami, and Jianping Xie. "AIE-Type Metal Nanoclusters: Synthesis, Luminescence, Fundamentals and Applications." In Principles and Applications of Aggregation-Induced Emission, 265–89. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-99037-8_10.

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Conference papers on the topic "Aggregation induced emission (AIE)"

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Dong, Yongqiang, Jacky Wing Yip Lam, Anjun Qin, Zhen Li, Jiaxin Sun, Hoi Sing Kwok, and Ben Zhong Tang. "Aggregation-induced emission." In SPIE Optics + Photonics, edited by Zakya H. Kafafi and Franky So. SPIE, 2006. http://dx.doi.org/10.1117/12.679373.

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Hong, Yuning, Yongqiang Dong, Hui Tong, Zhen Li, Matthias Häußler, Jacky Wing Yip Lam, and Ben Zhong Tang. "Aggregation- and crystallization-induced light emission." In Integrated Optoelectronic Devices 2007, edited by James G. Grote, Francois Kajzar, and Nakjoong Kim. SPIE, 2007. http://dx.doi.org/10.1117/12.707609.

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Jumat, Saidatul Aisyah Haji, Nur Basirah Mohd Addie Sukaimi, Malai Haniti Sheikh Abdul Hamid, Ying Woan Soon, and Anwar Usman. "Aggregation-induced emission properties of trans-stilbene." In THE 5TH INTERNATIONAL TROPICAL RENEWABLE ENERGY CONFERENCE (THE 5TH iTREC). AIP Publishing, 2021. http://dx.doi.org/10.1063/5.0063770.

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Luo, Zhijun, Yanan Liu, Menglin Chen, Zongsong Gan, and Chang-Sheng Xie. "Aggregation induced emission molecule applied in optical data storage." In Information Storage System and Technology. Washington, D.C.: OSA, 2019. http://dx.doi.org/10.1364/isst.2019.jw4a.13.

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Pucci, Andrea, Giuseppe Iasilli, Francesco Tantussi, Francesco Fuso, and Giacomo Ruggeri. "Aggregation induced emission as a new tool for polymer traceability." In 6TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS (TOP) AND COMPOSITES. AIP, 2012. http://dx.doi.org/10.1063/1.4738407.

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Gear, A. R. L., and G. D. Jones. "SUB-SECOND CALCIUM DYNAMICS IN ADP AND THROMBIN-STIMULATED PLATELETS; ASSESSED BY A C0NTINU0US-EL0W APPROACH." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1644531.

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Abstract:
There is now evidence that many platelet reactions begin within 1 sec of platelet stimulation. These include "shape change," aggregation and biochemical events such as protein phosphorylation. Our laboratory has devised quenched-flow approaches for following such early events (J Lab Clin Med 100, 866, 1982) and we have extended these to fluorimetric analyses of rapid calcium changes. A micro, flow-through cell, with a sensing volume of 0.1 μ1, is placed on line from the quenched-flow apparatus. Indo-1 loaded, human platelets are pumped through the system and reaction times from 0.25 sec can be followed. Ratioing emission changes at 400 and 480 nm, after excitation at 355 nm, provides an index of free calcium. ADP (10 μM) induced a rapid increase in Ca++ to about 1 μM by 1.5 sec, beginning near 0.3 sec. This was faster and greater than the first increase caused by thrombin (10U/ml). However, thrombin induced a second (> 5s) and larger increase in free platelet calcium. Control experiments where the Indo-1 loaded platelets were simply pumped through the 0.3 mm ID reaction tubing, revealed a slight increase above resting calcium values, indicating some shear-induced activation. The use of the continuous-flow fluorescent cell coupled to the quenched-flow apparatus enables following calcium dynamics under Theological conditions very close to those iui vivo.Correlations with other early events, such as protein phosphorylation, become possible. Supported by NIH HL-27014.
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Mishra, Anasuya, Anshu Kumar, Anil Kumar, and Anindya Dutta. "Aggregation induced enhanced emission in Dimethyl-2,5-bis(4-methoxyphenylamino)terephthalate." In Reporters, Markers, Dyes, Nanoparticles, and Molecular Probes for Biomedical Applications XII, edited by Samuel Achilefu and Ramesh Raghavachari. SPIE, 2020. http://dx.doi.org/10.1117/12.2548917.

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Lili, Du, Cai Yuanjing, Phillips David Lee, and Tang Ben Zhong. "Time-resolved spectroscopy studies to understand aggregation induced emission properties and phenomena." In Asian Spectroscopy Conference 2020. Institute of Advanced Studies, Nanyang Technological University, 2020. http://dx.doi.org/10.32655/asc_8-10_dec2020.44.

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Lim, Chang-Keun, Anton Popov, Gleb Tselikov, Jeongyun Heo, Artem Pliss, Sehoon Kim, Andrei V. Kabashin, and Paras N. Prasad. "Laser-ablative synthesis of aggregation-induced enhanced emission luminophore dyes in aqueous solutions." In Synthesis and Photonics of Nanoscale Materials XVI, edited by Andrei V. Kabashin, Jan J. Dubowski, and David B. Geohegan. SPIE, 2019. http://dx.doi.org/10.1117/12.2513821.

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Yuan, Wang Zhang, Zhen Qiang Yu, Jacky Wing Yip Lam, Cathy K. W. Jim, and Ben Zhong Tang. "Main chain liquid crystalline polytriazoles with aggregation-induced emission characteristics: click polymerization, mesomorphic packing, and solid state emission." In SPIE Photonic Devices + Applications, edited by Iam Choon Khoo. SPIE, 2010. http://dx.doi.org/10.1117/12.861520.

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