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Journal articles on the topic 'Alcohol oxidation'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Griffith, William P., and Maria Suriaatmaja. "Studies on transition-metal nitrido and oxo complexes. Part 20. Oxoruthenates and oxo-osmates in oxidation catalysis; cis-[Os(OH)2O4]2- as a catalytic oxidant for primary amines and for alcohols." Canadian Journal of Chemistry 79, no. 5-6 (2001): 598–606. http://dx.doi.org/10.1139/v00-181.

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cis-[Os(OH)2O4]2 with [Fe(CN)6]3 and other co-oxidants has been studied as a catalytic reagent for the oxidative dehydrogenation of primary aromatic and aliphatic amines to nitriles, the oxidation of primary alcohols to carboxylic acids and of secondary alcohols to ketones. Electronic and Raman spectroscopy have been used to elucidate the nature of the oxoruthenates and oxo-osmates present in a number of reported organic oxidations catalyzed by ruthenium and osmium species.Key words: oxidation catalysis, ruthenium, osmium, amine dehydrogenation, alcohol oxidation.

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2

Sohilait, Hanoch J. "OXIDATION OF BENZYLIC SECONDARY ALCOHOL WITH PYRIDINIUM CHLOROCHROMATE-ALUMINA (PCC-Al₂O₃)." Indonesian Journal of Chemistry 8, no. 1 (2010): 91–93. http://dx.doi.org/10.22146/ijc.21658.

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In these studies, Pyridinium chlorochromate-Alumina was used for oxidation of secondary alcohols (safryl alcohol and methyleugenyl alcohol) to ketone. The oxidation of safryl alcohol with PCC-Al2O3 followed by purification by potassium bisulfite yields safryl ketone (62,92%). The oxidation of methyleugenyl alcohol with PCC-Al2O3, followed by purification by potassium bisulfite yields methyleugenyl ketone (68,04%). The elucidation of these products was analyzed by FTIR, 1H-NMR and MS. Keywords : PCC-alumina, secondary alcohols, ketone

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3

Mobley, Justin, John Jennings, Tonya Morgan, Axel Kiefer, and Mark Crocker. "Oxidation of Benzylic Alcohols and Lignin Model Compounds with Layered Double Hydroxide Catalysts." Inorganics 6, no. 3 (2018): 75. http://dx.doi.org/10.3390/inorganics6030075.

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Alcohol oxidation to carbonyl compounds is one of the most commonly used reactions in synthetic chemistry. Herein, we report the use of base metal layered double hydroxide (LDH) catalysts for the oxidation of benzylic alcohols in polar solvents. These catalysts are ideal reagents for alcohol oxidations due to their ease of synthesis, tunability, and ease of separation from the reaction medium. LDHs synthesized in this study were fully characterized by means of X-ray diffraction, NH3-temperature programmed desorption (TPD), pulsed CO2 chemisorption, N2 physisorption, electron microscopy, and el

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4

PRATIK, KUMAR SEN, SANYAL ANKAN, and KALI SEN GUPTA KALYAN. "Oxidative Behaviour of Sodium Dodecyl Sulphate towards Acid Permanganate in the Absence and Presence of Benzyl Alcohol." Journal of Indian Chemical Society Vol. 70, Apr-May 1993 (1993): 341–45. https://doi.org/10.5281/zenodo.5930097.

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Department of Chemistry, Jadavpur University, Calcutta-700 032 <em>Manuscript received 13 January 1993</em> The oxidative behaviour of sodium dodecyl sulphate (SDS) towards permanganate in the absence and presence of benzyl alcohol has been investigated in perchloric acid medium. The reaction is first order with respect to [\(MNO_4^-\)] and [SDS] in the oxidation of SDS and the rate increases with an increase in [HCIO<sub>4</sub>]. For the SDS oxidation of benzyl alcohol the reaction is first order with respect to [\(MNO_4^-\)] as well as [benzyl alcohol], but a complex order with respect to [

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5

Şahin, Zeynel. "Oxidation of Benzyl Alcohols by Monomeric Iron Phthalocyanine Complexes: Substituents’ Effect on Their Catalytic Performance." Celal Bayar Üniversitesi Fen Bilimleri Dergisi 21, no. 2 (2025): 100–104. https://doi.org/10.18466/cbayarfbe.1570991.

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Iron phthalocyanines tetra substituted with either electron-donating n-hexyloxy or electron-withdrawing n-hexylsulfonyl substituents were prepared and tested as oxidation catalysts for benzyl alcohol, 4-bromobenzyl alcohol, 4-methylbenzyl alcohol and 4-tert-butylbenzyl alcohol. Oxidation reactions were performed at room temperature in acetonitrile, acetone, ethanol, toluene, and the best result was obtained in acetonitrile. Oxidation of alcohols using tert-butyl hydroperoxide as an oxidant in the presence of these iron(II) phthalocyanines resulted in the production of corresponding benzaldehyd

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6

Babayev, Elchin, Nargiz Rahimli, Ulviyya Mammadova, and Nizami Zeynalov. "Investigation of the Properties of Unsaturated Allyl Alcohol and its Oxidation Reaction Products." Nature & Science 6, no. 9 (2024): 17–20. http://dx.doi.org/10.36719/2707-1146/48/17-20.

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Abstract Organic substances in which the -OH group is directly attached to the carbon atom are called alcohols. Unsaturated alcohols are obtained by replacing the hydrogen of ethylene or acetylene-type compounds with a hydroxyl group. Allyl alcohol, the first representative of the class of unsaturated alcohols, contains oxygen. Allyl alcohol is used in optical resins, protective glasses, paints and coatings and polymer cross-linking agents, as well as in the production of pharmaceuticals, organic chemicals, plastics, herbicides, and pesticides. In organic chemistry, alcohols can be oxidized to

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7

Brei, Volodymyr. "OXIDATION OF ALCOHOLS OVER CERIUM-OXIDE CATALYST: CORRELATION BETWEEN THE ACTIVATION ENERGY OF THE REACTION AND THE CHEMICAL SHIFT δ (R13 COH)". Ukrainian Chemistry Journal 85, № 8 (2019): 66–72. http://dx.doi.org/10.33609/0041-6045.85.8.2019.66-72.

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The oxidation of thirteen alcohols over sup-ported CeO2/Al2O3 catalyst with 10 wt.% of CeO2 have been studied using a desorption mass-spec-trometry technique. A catalyst sample 4–6 mg in quartz cuvette was evacuated at 100 0C, cooled to room temperature, and then adsorption of a alco-hol was provided. After vacuumation of alcohol excess, the TPR profiles of products of alcohol oxidation were recorded at sweep rate 2 a.u.m./sec and heating rate of 15 0C/min using MX-7304A monopole mass- spectrometer. Identification of formed aldehydes and ketones was provided on the bases of their characteristi

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8

Krishnamoorthy, Guna Sekar, та Seplapatty Kalimuthu Periyasamy. "Oxidation of α,β-Unsaturated Alcohols by Quinaldinium Fluorochromate". International Letters of Chemistry, Physics and Astronomy 5 (вересень 2013): 8–19. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.5.8.

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The kinetics of oxidation of α,β-unsaturated alcohols (allyl alcohol, Crotyl alcohol, Cinnamyl alcohol) by quinaldinium fluorochromate has been studied in aqueous acid medium at 313 K. α,β-unsaturated alcohols were converted to the corresponding acrolein, crotonaldehyde and cinnamaldehyde. The reaction is first order each in oxidant, substrate and H+. The decrease in dielectric constant of the medium increases the rate of the reaction. Increase in ionic strength by the addition of sodium perchlorate has no effect on the rate constant. There is no polymerization with acrylonitrile. The reaction

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9

Krishnamoorthy, Guna Sekar, та Seplapatty Kalimuthu Periyasamy. "Oxidation of α,β-Unsaturated Alcohols by Quinaldinium Fluorochromate". International Letters of Chemistry, Physics and Astronomy 5 (19 грудня 2012): 8–19. http://dx.doi.org/10.56431/p-91l939.

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The kinetics of oxidation of α,β-unsaturated alcohols (allyl alcohol, Crotyl alcohol, Cinnamyl alcohol) by quinaldinium fluorochromate has been studied in aqueous acid medium at 313 K. α,β-unsaturated alcohols were converted to the corresponding acrolein, crotonaldehyde and cinnamaldehyde. The reaction is first order each in oxidant, substrate and H+. The decrease in dielectric constant of the medium increases the rate of the reaction. Increase in ionic strength by the addition of sodium perchlorate has no effect on the rate constant. There is no polymerization with acrylonitrile. The reaction

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10

Abad, Alberto, Avelino Corma, and Hermenegildo García. "Supported gold nanoparticles for aerobic, solventless oxidation of allylic alcohols." Pure and Applied Chemistry 79, no. 11 (2007): 1847–54. http://dx.doi.org/10.1351/pac200779111847.

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After giving some general considerations about the specific properties of nanoparticles below 20 nm, procedures for size stabilization, and the importance of developing green alcohol oxidation reactions, catalytic data are presented showing that gold nanoparticles (3-7 nm) supported on nanoparticulated ceria (4 nm) are far more chemoselective than related palladium catalysts for the aerobic oxidation of allylic alcohols. Using palladium catalysts, in addition to minor oxidation of the alcohol functional group, we have also observed polymerization, 1-2 hydrogen shift, and hydrogenation. In cont

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11

Shaw, J. P., F. Schwager, and S. Harayama. "Substrate-specificity of benzyl alcohol dehydrogenase and benzaldehyde dehydrogenase encoded by TOL plasmid pWW0. Metabolic and mechanistic implications." Biochemical Journal 283, no. 3 (1992): 789–94. http://dx.doi.org/10.1042/bj2830789.

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The substrate-specificities of benzyl alcohol dehydrogenase and benzaldehyde dehydrogenase, encoded by TOL plasmid pWW0 of Pseudomonas putida mt-2, were determined. The rates of benzyl alcohol dehydrogenase-catalysed oxidation of substituted benzyl alcohols and reduction of substituted benzaldehydes were independent of the electronic nature of the substituents at positions 3 and 4. Substitutions at position 2 of benzyl alcohol affected the reactivity of benzyl alcohol dehydrogenase: the velocity of the benzyl alcohol dehydrogenase-catalysed oxidation was lower for compounds possessing electron

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12

Levy-Ontman, Oshrat, Eliraz Stamker, and Adi Wolfson. "The Effect of Alcohol on Palladium Nanoparticles in i-Pd(OAc)2(TPPTS)2 for Aerobic Oxidation of Benzyl Alcohol." Metals 11, no. 9 (2021): 1443. http://dx.doi.org/10.3390/met11091443.

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In the heterogeneous catalyst i-Pd(OAc)2(TPPTS)2, Pd(II) was reduced to Pd(0) by using different alcohol solvents, and the catalyst’s activity was studied in the aerobic oxidation of benzyl alcohol. We studied the effects of the impregnation time in ethanol as a solvent and the use of various alcoholic solvents on the size of palladium nanoparticles. We found that the reduction of palladium by the various alcohols yielded palladium nanoparticles that were active in the aerobic oxidation of benzyl alcohol. As determined by DLS, TEM, and zeta potential analyses, both the impregnation time in eth

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13

S.M., TUWAR, T. NANDIBEWOOR S, and R. RAJU J. "Oxidation of Allyl Alcohol by Diperiodatonickelate(Iv) in Aqueous Alkaline Medium." Journal of Indian Chemical Society Vol. 69, Oct 1992 (1992): 651–53. https://doi.org/10.5281/zenodo.6018968.

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Department of Chemistry, Karnatak University, Dharwad- 80 003                                                                        <em>Manuscript received 9 July 1991, revised 26 June 1992, accepted 22 July 1992</em> The rate of oxidation of allyl alcohol (AA) by alkaline diperiodatonickelate(IV) (DPN)<em> is </em>found to decrease with increase in periodate concentration and increase with increasing OH<sup>-</sup>

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14

Chan-Thaw, Carine, Aditya Savara, and Alberto Villa. "Selective Benzyl Alcohol Oxidation over Pd Catalysts." Catalysts 8, no. 10 (2018): 431. http://dx.doi.org/10.3390/catal8100431.

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In the last decades, the selective liquid phase oxidation of alcohols to the corresponding carbonyl compounds has been a subject of growing interest. Research has focused on green methods that use “clean” oxidants such as O2 in combination with supported metal nanoparticles as the catalyst. Among the alcohols, benzyl alcohol is one of the most studied substrates. Indeed, benzyl alcohol can be converted to benzaldehyde, largely for use in the pharmaceutical and agricultural industries. This conversion serves as model reaction in testing new potential catalysts, that can then be applied to other

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15

Kim, Chang-Soo, and Kye Sang Yoo. "Preparation of Ag/TiO2Particle for Aerobic Benzyl Alcohol Oxidation." Applied Chemistry for Engineering 24, no. 6 (2013): 663–67. http://dx.doi.org/10.14478/ace.2013.1094.

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16

Kazuma, Hisazaki, Takahiro Maruyama, and Takahiro Saida. "(Digital Presentation) The Oxidation Behavior of Model Molecules for Electrolysis of Polymer Materials." ECS Meeting Abstracts MA2022-02, no. 64 (2022): 2359. http://dx.doi.org/10.1149/ma2022-02642359mtgabs.

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Most of the plastic recycling is thermal recycling by incineration. As a matter of course, thermal recycling is not a sustainable recycling method for plastic material. Material recycling is being carried out in which some used plastics are molded and reused.[1] However, material recycling has problems that cannot recover the monomer and separate the pigments and dyes. These problems degrade the quality of recycling plastics. Therefore, we focused on the depolymerization and re-polymerization between polymers and monomers by electrolysis in order to develop a new recycling method without degra

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17

Ikariya, Takao, Shigeki Kuwata, and Yoshihito Kayaki. "Aerobic oxidation with bifunctional molecular catalysts." Pure and Applied Chemistry 82, no. 7 (2010): 1471–83. http://dx.doi.org/10.1351/pac-con-09-09-11.

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A new series of half-sandwich group 8 and 9 metal complexes bearing a metal/NH bifunctional moiety were synthesized from benzylic amines. The isolable Ir amide complexes serve as effective catalysts for aerobic oxidative transformation of secondary and primary alcohols into the corresponding ketones and esters under mild conditions. The aerobic oxidative kinetic resolution of racemic secondary alcohols with chiral bifunctional Ir catalysts was found to proceed smoothly under mild conditions with high selectivity. A novel imido-bridged dirhodium complex, which may be regarded as a dinuclear var

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18

Zhyznevskiy, Vyacheslav, and Volodymyr Gumenetskiy. "Catalytic oxidation of tert-butyl alcohol to methacrolein." Chemistry & Chemical Technology 2, no. 1 (2008): 55–63. http://dx.doi.org/10.23939/chcht02.01.055.

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Oxidation of tert-butyl alcohol (TBA) to methacrolein (МA) over Fe-Te-Mo-Ox catalyst (Cat), promoted by Ca(NO3)2 has been investigated. Promoter concentration, which was optimal by the МA yield, has been established (Ca/Mo = 0.05). Using catalyst of such type the MA yield was 87.1 % (calculated for supplied TBA) at the temperature of 663 K, process time of 2.5 s and TBA concentration of 7.0 % with concentration of water vapour in the air of 20 %. Under mentioned conditions TBA conversion was 100 %, isobutylene conversion – 95.5 %, selectivity by MA was 87.6 % and by CO2 – 2.4 %.

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19

Zhou, Jin, Xiaoyan Li та Hongjian Sun. "Palladium-catalyzed aerobic alcohol oxidation supported by a new type of α-diimine ligands". Canadian Journal of Chemistry 86, № 8 (2008): 782–90. http://dx.doi.org/10.1139/v08-075.

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A series of new ionic sulfonated α-diimine ligands were prepared and employed as supporting ligands for the palladium-catalyzed aerobic alcohol oxidation. The electronic properties, rigidity, and steric hindrance of ligands have remarkable influences upon the catalytic activity of the palladium complexes. The best catalytic result could be achieved using ligand 9 with an electron-withdrawing sulfonyl substituent together with bulky groups (iso-propyl in 2,6-positions). This diimine/palladium-catalyzed system is highly efficient for the oxidation of various benzylic alcohols, and showed moderat

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20

Tiwari, Anjali, D. V. Prabhu, and Harichandra A. Parbat. "A Kinetic and Thermodynamic Study of Oxidation of Selective Alcohols Using Chromium-based Reagents and Silver Nanoparticle Catalyst: A Spectrophotometric Approach." Asian Journal of Chemical Sciences 15, no. 3 (2025): 68–81. https://doi.org/10.9734/ajocs/2025/v15i3374.

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Oxidation is a fundamental industrial process due to its ability to produce valuable compounds, particularly the transformation of alcohols into carbonyl derivatives. While extensive research has explored this conversion, limited attention has been given to the kinetic and thermodynamic aspects. This study investigates the oxidation kinetics of selected aliphatic and cyclic alcohols using PCC and PDC in an acidic medium. These oxidants are stable, easily accessible, and efficiently convert a variety of alcohols into corresponding carbonyl compounds. The reactions were found to follow first-ord

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21

Krogul-Sobczak, Agnieszka, Natalia Pisarek, Piotr Cieciórski, and Elżbieta Megiel. "Silver Nanoparticles Densely Grafted with Nitroxides as a Recyclable Green Catalyst in the Selective Oxidation of Alcohols." Nanomaterials 12, no. 15 (2022): 2542. http://dx.doi.org/10.3390/nano12152542.

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The selective oxidation of alcohols, leading to appropriate aldehydes, is widely recognised as one of the most important reactions in organic synthesis. With ever-increasing environmental concerns, much attention has been directed toward developing catalytic protocols that use molecular oxygen as an oxidant. An ideal green oxidation process should employ a highly active, selective and recyclable catalyst that can work with oxygen under mild conditions. This paper presents a successful application of densely grafted silver nanostructures with stable nitroxide radicals (N-AgNPs) as an effective,

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22

Dorado, Vicente, Clara I. Herrerías, and José M. Fraile. "Sulfonic Resins as Catalysts for the Oxidation of Alcohols with H2O2/KBr." Catalysts 14, no. 1 (2024): 74. https://doi.org/10.3390/catal14010074.

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Sulfonic resins can replace homogeneous sulfonic acids in the oxidation of alcohols with the H2O2/KBr system. The performance of different resins was tested with methyl 9(10)-hydroxystearate, a secondary fatty alcohol. The structural features of the resin were more important than the acid strength for the catalytic performance of this reaction. The optimization of the reaction conditions allows the recovery of the resin, although regeneration is required due to the active role of KBr, and a significant loss of sulfonic groups can be detected after nine runs. In the cas

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23

Uthoff, Stefan, and Alexander Steinbüchel. "Purification and Characterization of an NAD+-Dependent XylB-Like Aryl Alcohol Dehydrogenase Identified in Acinetobacter baylyi ADP1." Applied and Environmental Microbiology 78, no. 24 (2012): 8743–52. http://dx.doi.org/10.1128/aem.02224-12.

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ABSTRACTThe genexylBADP1fromAcinetobacter baylyiADP1 (gene annotation number ACIAD1578), coding for a putative aryl alcohol dehydrogenase, was heterologously expressed inEscherichia coliBL21(DE3). The respective aryl alcohol dehydrogenase was purified by fast protein liquid chromatography to apparent electrophoretic homogeneity. The predicted molecular weight of 39,500 per subunit was confirmed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis. According to the nativeMwas determined by gel filtration, the enzyme forms dimers and therefore seems to be XylB related. The enzyme showed

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24

T., Sankarshana, Bhagvanth Rao M., and S. Ramachandran P. "Kinetics of oxidation of alcohols : phase transfer catalysis." Journal of Indian Chemical Society Vol. 79, Aug 2002 (2002): 668–70. https://doi.org/10.5281/zenodo.5843325.

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University College of Technology, Osmania University, Hyderabad-500 007, India <em>E-mail : </em>univ_hyd_osmania@hotmail.com <em>Manuscript received 31 January 2001, revised 1 February 2002, accepted 15 February 2002</em> The study involves the phase transfer catalyzed oxidation of alcohols, namely, 2-ethyl-1-hexanol, <em>n</em>-heptanol and <em>n</em>-hexanol, and kinetics of the oxidation of the alcohols by quaternary ammonium permanganate (tricaprylylmethylammonitimpernianganate). The oxidation of each alcohol by permanganate ion is found to be first order with respect to each of the react

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25

Evtuguin, D. V., C. Pascoal Neto, H. Carapuça, and J. Soares. "Lignin Degradation in Oxygen Delignification Catalysed by [PMo7V5O40]8- Polyanion. Part II. Study on Lignin Monomeric Model Compounds." Holzforschung 54, no. 5 (2000): 511–18. http://dx.doi.org/10.1515/hf.2000.087.

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Summary Vanillyl and veratryl alcohols were used as monomeric lignin model compounds in experiments aiming to enhance the understanding of the lignin oxidation mechanisms involved in the oxygen delignification in acidic media catalysed by [PMo7V5O40]8− (HPA-5) heteropolyanion. Based on the model compound experiments, the first step of lignin oxidation is suggested to be a one-electron oxidation by the catalyst. This step is followed by coupling reactions and/or by further oxidation by the catalyst. The ratio of coupling/oxidation reaction products depends on the oxidation conditions and decrea

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26

Mombeini, Sara. "Acetylation of alcohols by acetic acid and alcohol oxidation with hydrogen peroxide adjacent to benzyl triphenylphosphonium." International Academic Journal of Science and Engineering 05, no. 02 (2018): 59–65. http://dx.doi.org/10.9756/iajse/v5i1/1810026.

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27

Hong, Yiming, Tiantian Fang, Meichao Li, et al. "2,3-Dichloro-5,6-dicyano-1,4-benzoquinone-catalyzed aerobic oxidation reactions via multistep electron transfers with iron(ii) phthalocyanine as an electron-transfer mediator." RSC Advances 6, no. 57 (2016): 51908–13. http://dx.doi.org/10.1039/c6ra08921f.

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28

Siboonruang, Tana, Colin Flynn Crago, Ashton M. Aleman, et al. "Material Dynamics of Nickel (oxy)Hydroxide As an Alcohol Oxidation Electrocatalyst." ECS Meeting Abstracts MA2024-01, no. 56 (2024): 2973. http://dx.doi.org/10.1149/ma2024-01562973mtgabs.

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Electrochemical alcohol oxidation is an attractive reaction for renewable-energy driven production of value-added chemicals, like precursors for acrylic (acrolein from glycerol) and nylon (adipic acid from cyclohexanol). Implementing selective, earth-abundant catalysts for alcohol oxidation can improve electrolyzer efficiency and economics. For example, replacing the energy intensive oxygen evolution reaction (OER) in CO2 electrolyzers with alcohol oxidation can decrease operating voltage by about 0.85 V and reduce electricity requirements up to 53% while also reducing carbon emissions from ch

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29

Beatty, Marissa, Alexis T. Haley, Nicole Llewelyn, and Daniel V. Esposito. "Enhancing Alcohol Oxidation Activity Using Carbon-Modified Silicon Oxide Encapsulated Pt Electrodes." ECS Meeting Abstracts MA2022-01, no. 45 (2022): 1901. http://dx.doi.org/10.1149/ma2022-01451901mtgabs.

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The performance of direct alcohol fuel cells (DAFCs) is frequently constrained by the efficiencies of the electrocatalysts used for the necessary alcohol oxidation reactions (AORs), which require high overpotentials to remove poisoning CO intermediates from the catalyst surface. Silicon Oxide (SiOx) encapsulated Pt electrodes have previously been shown to reduce the potential required to remove CO, and greatly enhance the activity of Pt-based catalysts for alcohol oxidation. To better understand the mechanism of this enhancement, silicon oxide layers with varying concentrations of residual car

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Om, Prakash, and K. Sharma Pradeep. "Correlation analysis of reactivity in the oxidation of substituted benzyl alcohols by quinolinium bromochromate." Journal of Indian Chemical Society Vol. 81, Jun 2004 (2004): 467–73. https://doi.org/10.5281/zenodo.5833394.

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Department of Chemistry, J. N. V. University, Jodhpur-342 005, India <em>Manuscript received 24 June 2003. revised 29 September 2003, accepted 14 January 2004</em> Oxidation of benzyl alcohol and some <em>ortho</em>- <em>meta</em>- and <em>para</em>-monosubstituted ones by quinolinium, bromochromatc (QBC) in dimethyl sulphoxide (OMSO) leads to the formation of corresponding benzaldehydes. The reaction is first order each in both QBC and the alcohol. The reaction is promoted by hydrogen ions; the hydrogen-ion dependence has the form <em>k</em><sub>obs</sub>= a + b [H<sup>+</sup>]. Oxidatio

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Marais, Lindie, and Andrew John Swarts. "Biomimetic Cu/Nitroxyl Catalyst Systems for Selective Alcohol Oxidation." Catalysts 9, no. 5 (2019): 395. http://dx.doi.org/10.3390/catal9050395.

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The oxidation of alcohols to the corresponding carbonyl products is an important organic transformation and the products are used in a variety of applications. The development of catalytic methods for selective alcohol oxidation have garnered significant attention in an attempt to find a more sustainable method without any limitations. Copper, in combination with 2,2,6,6-tetramethyl-1-piperidine N-oxyl (TEMPO) and supported by organic ligands, have emerged as the most effective catalysts for selective alcohol oxidation and these catalyst systems are frequently compared to galactose oxidase (GO

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32

Dorado, Vicente, Clara I. Herrerías, and José M. Fraile. "Sulfonic Resins as Catalysts for the Oxidation of Alcohols with H2O2/KBr." Catalysts 14, no. 1 (2024): 74. http://dx.doi.org/10.3390/catal14010074.

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Sulfonic resins can replace homogeneous sulfonic acids in the oxidation of alcohols with the H2O2/KBr system. The performance of different resins was tested with methyl 9(10)-hydroxystearate, a secondary fatty alcohol. The structural features of the resin were more important than the acid strength for the catalytic performance of this reaction. The optimization of the reaction conditions allows the recovery of the resin, although regeneration is required due to the active role of KBr, and a significant loss of sulfonic groups can be detected after nine runs. In the case of primary fatty alcoho

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33

Lee, Kyung-Seon, and John PN Rosazza. "Biocatalytic oxidation of 4-vinylphenol by Nocardia." Canadian Journal of Chemistry 80, no. 6 (2002): 582–88. http://dx.doi.org/10.1139/v02-034.

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Nocardia species NRRL 5646 stereospecifically hydrates 4-vinylphenol (15) to S-1-(4'-hydroxyphenyl)ethanol (17), and further oxidizes 17 to 4'-hydroxyacetophenone (18). Labeled metabolites 17 and 18 obtained from incubations in D2O and H218O support initial enzymatic tautomerization of 15 to a reactive quinone methide (16), which adds water in the first reaction. Commitment to catalysis is high in the hydration reaction, while the alcohol dehydrogenation reaction appears to be reversible. The stereochemical features of water addition, alcohol oxidations, and ketone reductions with growing cult

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34

D., V. Prabhu. "Kinetics and re action mechanism of the controlled oxidation of some industrial alcohols by haloamines." Journal of Indian Chemical Society Vol. 84, Nov 2007 (2007): 1135–39. https://doi.org/10.5281/zenodo.5824638.

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Department of Chemistry, Wilson College (University of Mumbai), Mumbai-400 007, India <em>E-mail </em>: dvprabhu@rediffmail.com <em>Manuscript received 17 April 2007, revised 23 August 2007, accepted 29 August 2007</em> A kinetic study of the controlled oxidation of perfumery alcohols, geraniol, 1-phenyl ethanol and benzyl alcohol by Chloramine T in alkaline medium and Chloramine B in acidic medium has been carried out in the temperature range 30 °C to 50 °C. The oxidation was monitored in the micellar phase using sodium dodecyl sulphate. The oxidation rate increases with alcohol

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Wang, Bei, Liu Tao, Yu Cheng, et al. "Electrocatalytic Oxidation of Small Molecule Alcohols over Pt, Pd, and Au Catalysts: The Effect of Alcohol’s Hydrogen Bond Donation Ability and Molecular Structure Properties." Catalysts 9, no. 4 (2019): 387. http://dx.doi.org/10.3390/catal9040387.

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The direct alcohol fuel cell is a kind of power generation device that directly converts the chemical energy of small molecule alcohols into electric energy. In this paper, the electro-oxidation behaviors of some typical alcohols (methanol, ethanol, ethylene glycol, n-propanol, 2-propanol, and glycerol) over Pt, Pd, and Au electrodes were investigated in acidic, neutral, and alkaline media, respectively. By analyzing the activity information from a cyclic voltammetry (CV) method and some dynamic tests, several regularities were revealed in those electro-oxidation behaviors. Firstly, alkaline m

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Agnihotri, Mamta, and Saras Tiwari. "Comparative Study of Oxidation of Unsaturated Alcohols in Micellar and Non-Micellar Media Using N-Chlorosaccharin." Journal of Advances and Scholarly Researches in Allied Education 22, no. 01 (2025): 151–62. https://doi.org/10.29070/97sb7b53.

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The oxidation of alcohols is a crucial process in organic synthesis, and comprehending its behaviour in various media offers significant insights for improving reaction efficiency. This research examines the oxidation kinetics of unsaturated alcohols—allyl alcohol and cinnamyl alcohol—utilizing N-chlorosaccharin (NCSA) as the oxidising agent in both micellar and non-micellar environments. Micellar media were formulated using sodium dodecyl sulphate (SDS) and cetyltrimethylammonium bromide (CTAB), which serve as anionic and cationic surfactants, respectively. Reaction rates were examined under

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Liang, Yan, Samantha M. Yeligar, and Lou Ann S. Brown. "Chronic-Alcohol-Abuse-Induced Oxidative Stress in the Development of Acute Respiratory Distress Syndrome." Scientific World Journal 2012 (2012): 1–9. http://dx.doi.org/10.1100/2012/740308.

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Chronic alcohol ingestion increases the risk of developing acute respiratory distress syndrome (ARDS), a severe form of acute lung injury, characterized by alveolar epithelial and endothelial barrier disruption and intense inflammation. Alcohol abuse is also associated with a higher incidence of sepsis or pneumonia resulting in a higher rate of admittance to intensive care, longer inpatient stays, higher healthcare costs, and a 2–4 times greater mortality rate. Chronic alcohol ingestion induced severe oxidative stress associated with increased ROS generation, depletion of the critical antioxid

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Tiwari, Anjali, D. V. Prabhu, and Harichandra A. Parbat. "BIOGENICALLY SYNTHESIZED SILVER NANOPARTICLES CATALYZED OXIDATION OF ALIPHATIC AND CYCLIC ALCOHOLS BY KIO4: KINETIC AND THERMODYNAMIC STUDY." RASAYAN Journal of Chemistry 17, no. 03 (2024): 1299–308. http://dx.doi.org/10.31788/rjc.2024.1738867.

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The ability to generate valuable products through oxidation makes it one of the most pivotal industrial processes. While organic oxidants have traditionally been the focus in converting alcohols into carbonyl compounds, inorganic oxidants have been relatively underutilized. In this study, we delve into the influence of Potassium periodate (KIO4) in an acidic environment on the oxidation of selected alcohols, comparing its performance with that of catalyst silver nanoparticles prepared from two distinct plant sources: Madhuca longifolia flowers and Ziziphus jujuba leaves. The reactions were int

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Romero, Elvira, and Giovanni Gadda. "Alcohol oxidation by flavoenzymes." Biomolecular Concepts 5, no. 4 (2014): 299–318. http://dx.doi.org/10.1515/bmc-2014-0016.

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AbstractThis review article describes the occurrence, general properties, and substrate specificity of the flavoenzymes belonging to the glucose-methanol-choline oxidoreductase superfamily and the l-α-hydroxyacid dehydrogenase family. Most of these enzymes catalyze the oxidations of hydroxyl groups, yielding carbonyl moieties. Over the years, carbanion, hydride transfer, and radical mechanisms have been discussed for these enzymes, and the main experimental evidences supporting these mechanisms are presented here. Regardless of the chemical nature of the organic substrate (i.e., activated and

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Deeksha, Yajurvedi, Baghmar Manju, and K. Sharma Pradeep. "Correlation analysis of reactivity in the oxidation of substituted benzyl alcohols by 2,2' -bipyridinium chlorochromate." Journal of Indian Chemical Society Vol. 85, May 2008 (2008): 496–501. https://doi.org/10.5281/zenodo.5816421.

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Department of Chemistry, J. N. V. University. Jodhpur-342 005, Rajasthan, India <em>E-mail :</em> drpkvs27@yahoo.com <em>Manuscript received 20 June 2007, revised 4 February 2008, accepted 13 February 2008</em> Oxidation of benzyl alcohol and some <em>ortho-</em>, <em>meta-</em> and <em>para</em>-monosubstituted ones by 2,2' -bipyridinium chlorochromate (BPCC) in DMSO leads to the formation of corresponding benzaldehydes. The reaction is first order in both BPCC and the alcohol. The reaction is promoted by hydrogen ions; the hydrogen-ion dependence has the form : <em>k</em><sub>obs</sub> =

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Zhou, Zhanxiang, Xiuhua Sun, and Y. James Kang. "Metallothionein Protection against Alcoholic Liver Injury through Inhibition of Oxidative Stress." Experimental Biology and Medicine 227, no. 3 (2002): 214–22. http://dx.doi.org/10.1177/153537020222700310.

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Antioxidants are likely potential pharmaceutical agents for the treatment of alcoholic liver disease. Metallothionein (MT) is a cysteine-rich protein and functions as an antioxidant. This study was designed to determine whether MT confers resistance to acute alcohol-induced hepatotoxicity and to explore the mechanistic link between oxidative stress and alcoholic liver injury. MT-overexpressing transgenic and wild-type mice were administrated three gastric doses of alcohol at 5 g/kg. Liver injury, oxidative stress, and ethanol metabolism-associated changes were determined. Acute ethanol adminis

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Zhang, Wenhui, Ran Liu, Xueyan Lv, et al. "Oxidant-Free Electrochemical Direct Oxidative Benzyl Alcohols to Benzyl Aldehydes Using Three-Dimensional Printing PPAR Polyoxometalate." Molecules 28, no. 18 (2023): 6460. http://dx.doi.org/10.3390/molecules28186460.

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The oxidation of benzyl alcohols is an important reaction in organic synthesis. Traditional methods for benzyl alcohol oxidation have not been widely utilized due to the use of significant amounts of precious metals and environmentally unfriendly reagents. In recent years, electrocatalytic oxidation has gained significant attention, particularly electrochemical anodic oxidation, which offers a sustainable alternative for oxidation without the need for external oxidants or reducing agents. Here, a copper monosubstituted phosphotungstate-based polyacrylate resins (Cu-LPOMs@PPAR) catalyst has bee

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ANUPAMA, BOHRA, K. SHARMA PRADEEP, and K. BANERJI KALYAN. "Kinetics and Mechanism of the Oxidation of Secondary Alcohols by Hexamethyl-enetetramine-Bromine." Journal of Indian Chemical Society Vol. 75, Oct-Dec 1998 (1998): 784–87. https://doi.org/10.5281/zenodo.5923088.

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Department of Chemistry, J. N. V. University, Jodhpur-342 005 <em>Manuscript received 11 September 1998</em> Oxidation of secondary alcohols by hexamethylenetetramine-bromine (HABR) in acetic acid leads to the formation of the corresponding ketones. The reaction is first order with respect to HABR. Michaelis-Menten type kinetics were observed with respect to alcohols. The oxidation of benzhydrol-α-d exhibited a substantial kinetic isotope effect <em>(k<sub>H</sub>/k<sub>D</sub> </em>= 3.16 at 298 K). The reaction was subjected to both polar and steric effects of the substituent

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Sheikhi, Ehsan, Mehdi Adib, Morteza Karajabad, and Seyed Gohari. "Sulfuric Acid-Promoted Oxidation of Benzylic Alcohols to Aromatic Aldehydes in Dimethyl Sulfoxide: An Efficient Metal-Free Oxidation Approach." Synlett 29, no. 07 (2018): 974–78. http://dx.doi.org/10.1055/s-0037-1609149.

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An efficient metal-free oxidation of benzylic alcohols to aromatic aldehydes is described. Heating a solution of the benzylic alcohol in DMSO in the presence of H2SO4 afforded the corresponding aldehyde in excellent yield. This oxidation reaction, which proceeds with a short reaction time and no side products, is akin to the Pfitzner–Moffatt oxidation, but without the need for N,N′-dicyclohexylcarbodiimide.

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Bourbonnais, R., and M. G. Paice. "Veratryl alcohol oxidases from the lignin-degrading basidiomycete Pleurotus sajor-caju." Biochemical Journal 255, no. 2 (1988): 445–50. http://dx.doi.org/10.1042/bj2550445.

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The basidiomycete Pleurotus sajor-caju mineralizes ring-14C-labelled lignin (dehydrogenative polymer) when grown in mycological broth. Under these conditions, two veratryl alcohol oxidase (VAO) enzymes were found in the culture medium. They oxidized a number of aromatic alcohols to aldehydes and reduced O2 to H2O2. The enzymes were purified by ion-exchange and gel-permeation chromatography. The final step of purification on Mono Q resolved the activity into two peaks (VAO I and VAO II). Both enzymes had the same Mr, approx. 71,000, but their isoelectric points differed slightly, 3.8 for VAO I

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H., N. Sheikh, Sharma Madhu, and L. Kalsotra B. "Kinetics and mechanism of oxidation of alcohols by piperidinium chlorochromate." Journal of Indian Chemical Society Vol. 82, Oct 2005 (2005): 913–16. https://doi.org/10.5281/zenodo.5827046.

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Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu-180 006, India <em>E-mail </em>: hnsheikh@rediffmail.com <em>Manuscript received 19 May 2005, accepted 14 July 2005</em> Piperidinium chlorochromate is an efficient oxidizing agent for oxidation of primary alcohols to aldehydes. Kinetics of oxidation of alcohols to the corresponding carbonyl compounds have been studied in aqueous-acetic acid medium in presence of perchloric acid. The reaction shows first order kinetics each in [PipCC] and [H<sup>+</sup>]. Michaelis-Menten type kinetics have been observed with respect

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Wang, Yuehong, Zizhuo Li, Yu Zhang, et al. "Targeting Pin1 Protects Mouse Cardiomyocytes from High-Dose Alcohol-Induced Apoptosis." Oxidative Medicine and Cellular Longevity 2016 (2016): 1–11. http://dx.doi.org/10.1155/2016/4528906.

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Long-term heavy alcohol consumption is considered to be one of the main causes of left ventricular dysfunction in alcoholic cardiomyopathy (ACM). As previously suggested, high-dose alcohol induces oxidation stress and apoptosis of cardiomyocytes. However, the underlying mechanisms are yet to be elucidated. In this study, we found that high-dose alcohol treatment stimulated expression and activity of Pin1 in mouse primary cardiomyocytes. While siRNA-mediated knockdown of Pin1 suppressed alcohol-induced mouse cardiomyocyte apoptosis, overexpression of Pin1 further upregulated the numbers of apop

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Stone, C. L., T. K. Li, and W. F. Bosron. "Stereospecific Oxidation of Secondary Alcohols by Human Alcohol Dehydrogenases." Journal of Biological Chemistry 264, no. 19 (1989): 11112–16. http://dx.doi.org/10.1016/s0021-9258(18)60436-3.

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Ferre, E., G. Gil, M. Barre, M. Bertrand та J. Le Petit. "Oxidation of α-allenic alcohols by yeast alcohol dehydrogenase". Enzyme and Microbial Technology 8, № 5 (1986): 297–99. http://dx.doi.org/10.1016/0141-0229(86)90025-6.

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Radosavljevic, Tatjana, Dusan Mladenovic, and Danijela Vucevic. "The role of oxidative stress in alcoholic liver injury." Medical review 62, no. 11-12 (2009): 547–53. http://dx.doi.org/10.2298/mpns0912547r.

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Introduction. Oxidative stress plays an important role in pathogenesis of alcoholic liver injury. The main source of free oxygen species is cytochrome P450-dependent monooxygenase, which can be induced by ethanol. Role of cytochrome P4502E1 in ethanol-induced oxidative stress. Reactive oxygen species produced by this enzyme are more important in intracellular oxidative damage compared to species derived from activated phagocytes. Free radicals lead to lipid peroxidation, enzymatic inactivation and protein oxidation. Role of mitochondria in alcohol-induced oxidative stress. Production of mitoch

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