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Journal articles on the topic 'Alicyclic ketones'

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1

Manikyamba, Prerepa. "Structural effects in the oxidation of ketones by acid iodate." Collection of Czechoslovak Chemical Communications 56, no. 6 (1991): 1279–86. http://dx.doi.org/10.1135/cccc19911279.

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The kinetics of oxidation of aliphatic, alicyclic and aryl alkyl ketones by acid iodate has been studied in aqueous methanol medium. The reaction exhibits first order dependence each on [iodate] and [ketone]. The reaction is acid catalysed and a medium of low dielectric constant is favourable for the oxidation process. The oxidation rates are slower than the enolisation rates of the ketones. The mechanism proposed involves rate limiting attack of IO+2 on the enol form of the ketone leading to the formation of an intermediate carbonium ion which undergoes solvolysis, ultimately leading to the f
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2

Shao, You-Dong, Dan-Dan Han, Wen-Yue Ma, and Dao-Juan Cheng. "Chiral phosphoric acid catalyzed atroposelective and diastereoselective synthesis of 9-aryltetrahydroacridines." Organic Chemistry Frontiers 7, no. 16 (2020): 2255–62. http://dx.doi.org/10.1039/d0qo00534g.

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A chiral phosphoric acid catalyzed atroposelective annulation between 2-aminoaryl ketones and alicyclic ketones has been developed to access a new library of enantioenriched axially chiral 9-aryltetrahydroacridines.
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3

Švec, Petr. "Chlorination of 2,4,6-trichlorophenol in acidic aqueous medium." Collection of Czechoslovak Chemical Communications 50, no. 8 (1985): 1842–51. http://dx.doi.org/10.1135/cccc19851842.

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The course of chlorination of 2,4,6-trichlorophenol (I) in water and approximately 20% sulfuric and hydrochloric acids has been investigated. In all these media the reaction gives primarily 2,4,6,6-tetrachloro-2,4-cyclohexadienone (II) which is subsequently chlorinated under formation of polychlorinated alicyclic ketones or isomerized to give the more stable 2,4,6,6-tetrachloro-2,5-cyclohexadienone (III), the precursor of further arising chlorinated 1,4-benzoquinones. The ratio of the arising polychlorinated alicyclic ketones to chlorinated 1,4-benzoquinones is significantly influenced by conc
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4

Radhasyam, Panda, and Kumar Acharya Prabhat. "Peroxomonosulfuric acid oxidations : kinetics and mechanism of oxidation of cyclic ketones." Journal of Indian Chemical Society Vol. 82, Jan 2005 (2005): 31–35. https://doi.org/10.5281/zenodo.5823807.

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Department of Chemistry, Khallikote College (Autonomous), Berhampur-760 001, India <em>E-mail</em> : rspanda50@hotmail.com <em>Manuscript received 25 November 2003, revised 27 May 2004, accepted 16 July 2004</em> The kinetics of oxidation of cyclic ketones by peroxomonosulfuric acid (PMSA) have been studied in the pH range 0-9.65. The reaction follows second-order kinetics- first-order each in [PMSA] and [ketone] at constant pH. The observed pH-rate profile has been rationalised invoking HSO<sup>-</sup><sub>5</sub>, SO<sup>2-</sup><sub>5</sub>, the protonated and unprotonated forms of cyclic k
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5

Yakabe, Shigetaka, Masao Hirano, and Takashi Morimoto. "Alumina-assisted reduction of carbonyl compounds with sodium borohydride in hexane." Canadian Journal of Chemistry 76, no. 12 (1998): 1916–21. http://dx.doi.org/10.1139/v98-204.

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A broad range of aliphatic, alicyclic, and aromatic ketones and aldehydes underwent smooth reduction with a combination of common, inexpensive laboratory reagents, sodium borohydride and chromatographic neutral alumina, in hexane to afford the corresponding alcohols in a selective and high-yielding manner under mild and neutral conditions. The NaBH4-based biphasic system can also successfully be used for the reduction of unsaturated substrates as well as steroidal and highly hindered ketones.
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6

Yoshizako, Fumiki, Atsuo Nishimura, and Mitsuo Chubachi. "Identification of algal transformation products from alicyclic ketones." Journal of Fermentation and Bioengineering 77, no. 2 (1994): 144–47. http://dx.doi.org/10.1016/0922-338x(94)90313-1.

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7

Mączka, Wanda Krystyna, and Agnieszka Mironowicz. "Biotransformation of Isoprenoids and Shikimic Acid Derivatives by a Vegetable Enzymatic System." Zeitschrift für Naturforschung C 59, no. 3-4 (2004): 201–4. http://dx.doi.org/10.1515/znc-2004-3-413.

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In biotransformations carried out under similar conditions enzymatic systems from carrot (Daucus carota L.), celeriac (Apium graveolens L. var. rapaceum) and horse-radish (Armoracia lapathifolia Gilib.) hydrolyzed the ester bonds of acetates of phenols or alicyclic alcohols. Nevertheless, methyl esters of aromatic acids did not undergo hydrolysis. Alcohols were oxidized to ketones in a reversible reaction.
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8

Stamhuis, Eize J., Henk Maatman, and Geert E. H. Joosten. "Reactions of alicyclic ketones in carbon tetrachloride. II. Kinetics of the chlorination of 2-chlorocyclopentanone and 2-chlorocyclohexanone, catalyzed by hydrogen chloride." Canadian Journal of Chemistry 64, no. 9 (1986): 1690–96. http://dx.doi.org/10.1139/v86-278.

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The kinetics of the direct chlorination of 2-chlorocyclopentanone (2-mccp) and 2-chlorocyclohexanone (2-mcch) in carbon tetrachloride, catalyzed by hydrogen chloride, were studied. Reaction products are all the possible 2,2-, 2,5-, and 2,6-dichloro compounds. The ratios depend on the concentrations of the monochloro compound and hydrogen chloride. Surprisingly, even at conversions of the monochloro compound as low as 2%, 2,2,5-trichlorocyclopentanone and 2,2,6-trichlorocyclohexanone, respectively, are also formed. The chlorination reaction of both monochloro ketones shows zero order in chlorin
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9

Ali Bawa, Ramadan, and Aya Ramadan Swairi. "Synthesis of Some Alicyclic Oximes and Study of the Expected Conformational Isomerism." Academic Journal of Life Sciences, no. 512 (December 5, 2019): 116–20. http://dx.doi.org/10.32861/ajls.512.116.120.

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Five alicyclic oximes 1 – 5 have been readily synthesized in moderate to good yields. These oximes were obtained through a reaction between the hydroxylamine hydrochloride and a number of alicyclic ketones (cylobutanone, cyclopentanone, cyclohexanone, cycloheptanone and cyclooctanone) under mild reaction conditions. The spectroscopic data confirmed the formation of the first four oximes 1 – 4 as single conformational isomers. However, the cyclooctanone oxime 5 was obtained as a mixture of two conformational isomers with 81% for the major and only 19% for the minor isomer. Such finding could be
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10

Verner, Jiri, and Milan Potacek. "Criss-cross Cycloadditions on Ketazines Derived from Alicyclic Ketones." Molecules 11, no. 1 (2006): 34–42. http://dx.doi.org/10.3390/11010034.

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11

Armstrong, Roly J., Wasim M. Akhtar, James R. Frost, Kirsten E. Christensen, Neil G. Stevenson, and Timothy J. Donohoe. "Stereoselective synthesis of alicyclic ketones: A hydrogen borrowing approach." Tetrahedron 75, no. 48 (2019): 130680. http://dx.doi.org/10.1016/j.tet.2019.130680.

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12

Stamhuis, Eize J., Henk Maatman, Henk Stinissen, and Geert E. H. Joosten. "Reactions of alicyclic ketones in carbon tetrachloride. I, The kinetics of the chlorination of cyclopentanone and cyclohexanone catalyzed by hydrogen chloride." Canadian Journal of Chemistry 64, no. 9 (1986): 1681–89. http://dx.doi.org/10.1139/v86-277.

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The kinetics of the direct chlorination of cyclopentanone (cp) and cyclohexanone (ch) in carbon tetrachloride, catalyzed by hydrogen chloride, was studied. The rate of chlorination, measured by flow and stopped-flow techniques, is zero order in chlorine; the order in cp and ch increases from 1 at [cp] and [ch] of 0.01 M concentration to 2 at concentrations of 1 M. This is explained by self-association of the ketones in carbon tetrachloride solutions. The order in hydrogen chloride is 1. Since this compound is one of the products, the reaction is autocatalytic. Deuterium isotope effects and the
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13

Vaishnav, Dinesh D., Robert S. Boethling, and Leo Babeu. "Quantitative structure — Biodegradability relationships for alchols, ketones and alicyclic compounds." Chemosphere 16, no. 4 (1987): 695–703. http://dx.doi.org/10.1016/0045-6535(87)90005-1.

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14

Majerski, Zdenko, and Vladimir Vinković. "A New, One-Pot Preparation of Alicyclic Ketones via WoIff Rearrangement." Synthesis 1989, no. 07 (1989): 559–60. http://dx.doi.org/10.1055/s-1989-27319.

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15

Wan, Yu, Shu-Ying Huang, Gui-Xiang Liu, et al. "A Catalyst-free Synthesis of Pyrazolopyridines Derived from Alicyclic Mono-ketones." Journal of Heterocyclic Chemistry 53, no. 6 (2016): 1715–20. http://dx.doi.org/10.1002/jhet.2171.

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16

Alrubaie, Leaqaa A., Raheem J. Muhasin та Mazin N. Mousa. "Synthesis, characterization and evaluation of antiinflammatory properties of novel α, β-unsaturated ketones". Tropical Journal of Pharmaceutical Research 19, № 1 (2020): 147–54. http://dx.doi.org/10.4314/tjpr.v19i1.22.

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Purpose: To prepare and characterize alicyclic aromatic chalcone derivatives, and study their antibiotic and anti-inflammatory properties.Methods: Claisen-Schmidt (aldol condensation) base-catalyzed condensation was used for preparation of chalcone derivatives (compounds I - IV), and the products were characterized using ultraviolet-visible spectroscopy (UV), FT-IR spectroscopy, proton nuclear magnetic resonance (1H-NMR), carbone 13CNMR and mass spectroscopy (MS). The antibacterial effect of the compounds was determined against Baci. cereus, Staph. Aureus, E. coli, and Pseudomonas Aeruginosa.
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17

Satam, Vijay, Ravi K. Bandi, Ajaya K. Behera, et al. "Design, Synthesis, and Cytotoxicity of Novel 3-Arylidenones Derived from Alicyclic Ketones." Chemical Biology & Drug Design 78, no. 4 (2011): 700–708. http://dx.doi.org/10.1111/j.1747-0285.2011.01176.x.

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18

Wan, Yu, Rui Yuan, Hua-hong Xu, Chao Wang, Jin-long Qi, and Hui Wu. "A Regioselective Biginelli-like Reaction Controlled by the Size of Alicyclic Mono-ketones." Journal of Heterocyclic Chemistry 51, S1 (2014): E123—E128. http://dx.doi.org/10.1002/jhet.1893.

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19

DIMMOCK, J. R., M. CHAMANKHAH, A. SENIUK, T. M. ALLEN, G. Y. KAO, and S. HALLERAN. "ChemInform Abstract: Synthesis and Cytotoxic Evaluation of Some Mannich Bases of Alicyclic Ketones." ChemInform 27, no. 7 (2010): no. http://dx.doi.org/10.1002/chin.199607108.

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20

Iloukhani, Hossein, K. Dayananda Reddy, and M. V. Prabhakara Rao. "Excess Volumes of Trichloroethylene with Some Aliphatic and Alicyclic Ketones at 303.15K and 313.15K." Physics and Chemistry of Liquids 14, no. 3 (1985): 181–88. http://dx.doi.org/10.1080/00319108508080981.

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21

Rosowsky, Andre, Andrew T. Papoulis, and Sherry F. Queener. "One-step synthesis of novel 2,4-diaminopyrimidine antifolates from bridged alicyclic ketones and cyanoguanidine." Journal of Heterocyclic Chemistry 36, no. 3 (1999): 723–28. http://dx.doi.org/10.1002/jhet.5570360324.

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22

Cremlyn, Richard J., Martin J. Frearson, and Stephen Graham. "THE SYNTHESIS AND CHLOROSULFONATION OF SOME DIARYLIDENE AND HETEROARYLIDENE KETONES WITH VARYING ALICYCLIC RING SIZE." Phosphorus, Sulfur, and Silicon and the Related Elements 107, no. 1-4 (1995): 205–17. http://dx.doi.org/10.1080/10426509508027936.

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23

Iloukheni, Hossein, K. Dayananda Reddy, and M. V. Prabhakara Rao. "Excess volumes of tetrachloroethylene with some aliphatic and alicyclic ketones at 303.15 and 313.15 K." Journal of Chemical & Engineering Data 30, no. 3 (1985): 306–8. http://dx.doi.org/10.1021/je00041a021.

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24

Wan, Yu, Rui Yuan, Hua-hong Xu, Chao Wang, Jin-long Qi, and Hui Wu. "ChemInform Abstract: A Regioselective Biginelli-Like Reaction Controlled by the Size of Alicyclic Mono-ketones." ChemInform 46, no. 9 (2015): no. http://dx.doi.org/10.1002/chin.201509225.

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25

Alimardanov, Hafiz M., Makhaddin F. Abbasov, and Nahida A. Jafarova. "Catalytic liquid-phase oxidation of alicyclic ketones and their derivatives into lactones by hydrogen peroxide." Processes of Petrochemistry and Oil Refining, no. 02 (2025): 418. https://doi.org/10.62972/1726-4685.2025.2.418.

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26

Velíšek, J., and K. Cejpek. "Biosynthesis of food constituents: Lipids. 1. Fatty acids and derivated compounds – a review." Czech Journal of Food Sciences 24, No. 5 (2011): 193–216. http://dx.doi.org/10.17221/3317-cjfs.

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This review article gives a survey of the principal biosynthetic pathways that lead to the most important common fatty acids and their derivatives occurring in foods and feeds. Fatty acids are further subdivided to saturated fatty acids and unsaturated fatty acids. This review is focused on the less common fatty acids including geometrical and positional isomers of unsaturated fatty acids, acetylenic fatty acids, branched-chain fatty acids, alicyclic fatty acids, epoxy fatty acids, hydroxy fatty acids, and oxo fatty acids. A survey is further given on the biosynthesis of the aliphatic very-lon
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27

Romankevich, E. A., A. A. Vetrov, and A. S. Ulyantsev. "Organic Matter in the Ocean: Indicators of Biogeochemical Processes." Oceanology 63, S1 (2023): S131—S142. http://dx.doi.org/10.1134/s0001437023070159.

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Abstract The article presents informative organogeochemical indicators used in oceanology to characterize biogeochemical processes. A classification based on data on suspended particulate matter, plankton, benthos, bottom sediments, and sea, river, and pore water has been developed. Clusters have been identified that include the elemental and isotopic composition of organic matter (OM), the group composition of lipids, aliphatic and alicyclic hydrocarbons, higher alcohols, macromolecular acids and ketones, isoprenoids, lignin and its structural monomers, and PAHs. The most informative indices
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28

Matysiak, J., M. Gorzel, and A. Skrzypek. "Synthetic musk odorants in cosmetic products." Archives of Physiotherapy and Global Researches 25, no. 1 (2021): 43–51. https://doi.org/10.5604/01.3001.0054.0160.

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Musk has its place among the most important classes of odorants used in the perfume industry as itimparts sensuality, volume and diffusion to fragrance compositions. Synthetic musk odorants have beenin use for over 130 years and are found in almost all fragrant consumer products including cosmetics andlaundry detergents. The first group of synthetic musks comprised nitro musks. These are nitro derivatives ofalkylbenzenes which, however, have been banned or their use has been limited to a significant extent. Theywere replaced by polycyclic and macrocyclic musks. Among the polycyclic musks, gala
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29

Rosowsky, Andre, Andrew T. Papoulis, and Sherry F. Queener. "ChemInform Abstract: One-Step Synthesis of Novel 2,4-Diaminopyrimidine Antifolates from Bridged Alicyclic Ketones and Cyanoguanidine." ChemInform 30, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199944160.

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30

Zhao, Xueqi. "Chemical Constitutions of Natural Musk and Research Progress of Synthetic Musk." Highlights in Science, Engineering and Technology 55 (July 9, 2023): 199–204. http://dx.doi.org/10.54097/hset.v55i.9958.

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Natural musk, which is released by adult male musk deer, has vital use in medicine, cosmetics, detergents, and other fields. This paper has mentioned that as a result of its predominant composition of macrocyclic ketones, pyridine, alcohols, fatty acids, polypeptides (PEP-tides), proteins, and other desired but uncommon substances, synthetic musk was created. The synthetic musk has been divided into four groups based on its chemical composition: nitrogen-containing musks (NMs), polycyclic musks (PMs), macrocyclic musks (MMs), and alicyclic musk or linear musk (AMs). The history of the creation
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31

Abouabdellah, Ahmed, Corinne Aubert, Jean-Pierre Bégué, Danièle Bonnet-Delpon та Jean Guilhem. "Lewis acid-induced ene-cyclization of ω-olefinic trifluoromethyl ketones: access to alicyclic compounds bearing a CF3group". J. Chem. Soc., Perkin Trans. 1, № 6 (1991): 1397–403. http://dx.doi.org/10.1039/p19910001397.

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32

Hernández-Laguna, A., R. Alguacil, J. L. M. Abboud, and Y. G. Smeyers. "MNDO-PM3 and AM1 studies of heats of formation of aliphatic and alicyclic aldehydes, ketones and nitriles." Journal of Molecular Structure: THEOCHEM 282, no. 1-2 (1993): 33–41. http://dx.doi.org/10.1016/0166-1280(93)85031-s.

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33

Iloukhani, Hossein, and M. V. Prabhakara Rao. "Ultrasonic Studies of Binary Mixtures of Trichloroethylene and Tetrachloroethylene with some Aliphatic and Alicyclic Ketones at 303.15 K." Physics and Chemistry of Liquids 15, no. 1 (1985): 11–18. http://dx.doi.org/10.1080/00319108508080999.

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34

Simoni, Daniele, Francesco Paolo Invidiata, Stefano Manfredini, et al. "Facile synthesis of 2-nitroalkanols by tetramethylguanidine (TMG)-catalyzed addition of primary nitroalkanes to aldehydes and alicyclic ketones." Tetrahedron Letters 38, no. 15 (1997): 2749–52. http://dx.doi.org/10.1016/s0040-4039(97)00461-9.

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35

Fäh, Christoph, Roland Mathys, Leo A. Hardegger, Solange Meyer, Daniel Bur та François Diederich. "Enantiomerically Pure and Highly Substituted Alicyclic α,α-Difluoro Ketones: Potential Inhibitors for Malarial Aspartic Proteases, the Plasmepsins". European Journal of Organic Chemistry 2010, № 24 (2010): 4617–29. http://dx.doi.org/10.1002/ejoc.201000712.

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36

Panda, Markandeswar, and Subas C. Pati. "Ruthenium (VIII) mediated oxidation of some aliphatic and alicyclic ketones by periodate-ruthenium (III) system in aqueous HClO4 medium." International Journal of Chemical Kinetics 28, no. 6 (1996): 453–60. http://dx.doi.org/10.1002/(sici)1097-4601(1996)28:6<453::aid-kin7>3.0.co;2-u.

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37

Tokmadzhyan, G. G. "Acid hydrolysis of amides obtained by Beckmann rearrangement of methyl ketones oximes of unsaturated γ-lactone, aromatic, and alicyclic series". Russian Journal of Organic Chemistry 47, № 11 (2011): 1746–49. http://dx.doi.org/10.1134/s1070428011110170.

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38

Tamura, Rui, Masahiro Sato, and Daihei Oda. "Facile synthesis of allylic nitro compounds by N,N-dimethylethylenediamine-catalyzed condensation of aliphatic and alicyclic ketones with primary nitroalkanes." Journal of Organic Chemistry 51, no. 23 (1986): 4368–75. http://dx.doi.org/10.1021/jo00373a007.

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39

SIMONI, D., F. P. INVIDIATA, S. MANFREDINI, et al. "ChemInform Abstract: Facile Synthesis of 2-Nitroalkanols by Tetramethylguanidine (TMG)- Catalyzed Addition of Primary Nitroalkanes to Aldehydes and Alicyclic Ketones." ChemInform 28, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199731089.

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40

Hirano, Masao, Yosimitsu Ueno, and Takashi Morimoto. "Some Observations on Baeyer-Villiger Oxidation of Alicyclic Ketones with Magnesium Monoperoxyphthalte in Aprotic Solvent in the Presence of Bentonite Clay." Synthetic Communications 25, no. 23 (1995): 3765–75. http://dx.doi.org/10.1080/00397919508011450.

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41

Hirano, Masao, Masaki Oose, and Takashi Morimoto. "A Novel Synthesis of Lactones by the Oxidation of Alicyclic Ketones with Oxone in Aprotic Solvent in the Presence of “Wet-Alumina”." Chemistry Letters 20, no. 2 (1991): 331–32. http://dx.doi.org/10.1246/cl.1991.331.

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42

Meyer, Walter L., Michael J. Brannon, Celmira da G. Burgos, Thomas E. Goodwin, and Ralph W. Howard. "Annulation of .alpha.-formyl .alpha.,.beta.-unsaturated ketones by a Michael addition-cyclization sequence. A versatile synthesis of alicyclic six-membered rings." Journal of Organic Chemistry 50, no. 4 (1985): 438–47. http://dx.doi.org/10.1021/jo00204a003.

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43

Bastida, Rosa M., Enrique Brillas та José M. Costa. "Electrohydrodimerization of α,β‐Unsaturated Alicyclic and Aliphatic Ketones in Hydroethanolic Solutions on a Mercury Electrode: I . Reduction of 2‐Cyclopenten‐1‐One". Journal of The Electrochemical Society 138, № 8 (1991): 2289–96. http://dx.doi.org/10.1149/1.2085963.

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44

Bastida, Rosa M., Enrique Brillas та José M. Costa. "Electrohydrodimerization of α,β‐Unsaturated Alicyclic and Aliphatic Ketones in Hydroethanolic Solutions on a Mercury Electrode: II . Reduction of 3‐Buten‐2‐One". Journal of The Electrochemical Society 138, № 8 (1991): 2296–303. http://dx.doi.org/10.1149/1.2085964.

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45

GLEBOV, L. "Mechanism of gas-phase hydrogenation of alicyclic ketones on iron catalyst: Effective experimental method on the basis of reaction gas chromatography/mass spectrometry." Journal of Catalysis 93, no. 1 (1985): 75–82. http://dx.doi.org/10.1016/0021-9517(85)90152-6.

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46

HIRANO, M., Y. UENO, and T. MORIMOTO. "ChemInform Abstract: Some Observations on Baeyer-Villiger Oxidation of Alicyclic Ketones with Magnesium Monoperoxyphthalate in Aprotic Solvent in the Presence of Bentonite Clay." ChemInform 27, no. 7 (2010): no. http://dx.doi.org/10.1002/chin.199607079.

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47

HIRANO, M., M. OOSE, and T. MORIMOTO. "ChemInform Abstract: A Novel Synthesis of Lactones by the Oxidation of Alicyclic Ketones with Oxone in Aprotic Solvent in the Presence of “Wet-Alumina”." ChemInform 23, no. 42 (2010): no. http://dx.doi.org/10.1002/chin.199242193.

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48

Lagercrantz, Carl. "gem-Dinitro and gem-nitronitroso dianion radicals formed in the reaction between sodium nitrite–ascorbate and carbonyl compounds such as aldehydes, alicyclic ketones, lactams and peptides. An EPR study." J. Chem. Soc., Perkin Trans. 2, no. 1 (1996): 101–5. http://dx.doi.org/10.1039/p29960000101.

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49

Furuya, M., and H. Nakajima. "Preparation of alicyclic ketone condensates." Zeolites 11, no. 2 (1991): 196. http://dx.doi.org/10.1016/0144-2449(91)80429-4.

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50

Bishop, R., and GH Lee. "Detection of Non-Conjugative Interactions in Rigid Cyclic Molecules by Using Carbon-13 N.M.R. Shift Values." Australian Journal of Chemistry 40, no. 2 (1987): 249. http://dx.doi.org/10.1071/ch9870249.

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In previous work, interaction between formally unconjugated unsaturated groups was detected by comparing the 13C n.m.r. shift values of the sp2 atoms of difunctional compounds with those of the corresponding monofunctional compounds. This procedure has now been used to investigate possible interactive effects in a range of rigid alicyclic systems where steric and conformational factors cannot be involved, namely, the 2,6-disubstituted adamantane (6), 4,8-disubstituted 2-thiaadamantane (7), 2,6-disubstituted noradamantane (8), and 2,5-disubstituted norbornane (9) systems. In each case interacti
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