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Relevant bibliographies by topics / Alkali metals

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Academic literature on the topic 'Alkali metals'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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Journal articles on the topic "Alkali metals"

1

Chen, Yan-bo, Yong Deng, Ran Liu, Li-da Chen, and Xing-min Guo. "Optimization of alkali metals discharge performance of blast furnace slag and its extreme value model." High Temperature Materials and Processes 41, no. 1 (2022): 306–14. http://dx.doi.org/10.1515/htmp-2022-0013.

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Abstract In order to improve the alkali metals discharge capacity of slag, the gas-slag balance method was used to carry out the slag alkali metals discharge experiments, the effect of slag composition on alkali metals discharge performance of slag was studied, some suggestions were put forward to optimize the alkali metals discharge performance of slag and the extreme value model was established. The results show that the alkali metals discharge ratio of slag decreased with the increase in the binary basicity and mass fraction of TiO2, and increased with the increase in the mass fraction of M

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2

Li, Fang Yong, Jing Hui Song, and Zhi Gang Zhan. "Effect of the Alkali Metals’ Existing Form on its Emission Characteristics during Biomass Combustion Process." Advanced Materials Research 550-553 (July 2012): 544–49. http://dx.doi.org/10.4028/www.scientific.net/amr.550-553.544.

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As one kind of renewable energy, bio-energy attracts more and more scholars’ attention due to its good ignition, combustion characteristics and zero CO2 release during bio-energy combustion process, alkali metals’ emission could cause fouling, slagging, high temperature corrosion and ultra-fine particulate matter emission, which hazard equipment safety and human healthy. In this paper, the release characteristics of alkali metals during the combustion process of rice straw (RS) and sawdust (SD) was studied by the chemical desperation disposal method and in a vertical thermal balance furnace. A

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3

Hensel, Friedrich, and Georg-Friedrich Hohl. "Expanded Fluid Alkali Metals." REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY 3, no. 2 (1994): 163–79. http://dx.doi.org/10.4131/jshpreview.3.163.

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Koplík, Jan, Tomáš Solný, Lukáš Kalina, and Jiří Másilko. "Immobilization of Sr²⁺, Bi³⁺ and Zn²⁺ in Alkali-Activated Materials Based on Blast Furnace Slag and Fly Ash." Key Engineering Materials 761 (January 2018): 15–18. http://dx.doi.org/10.4028/www.scientific.net/kem.761.15.

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It is well known, that alkali-activated materials (AAMs) are suitable for immobilization of heavy metals and other hazardous materials. This study is focused on the characterization of inhibition of three metals – Sr2+, Bi3+and Zn2+in alkali-activated matrices. Two type of matrices were prepared – alkali-activated blast furnace slag (BFS) and alkali-activated fly ash (FA). Sodium water glass was used as alkaline activator. The ability of these matrices to fix the metals were proved by leaching tests. Compressive strength was measured to characterize mechanical properties of the matrices. Scann

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5

Linnarsson, Margareta K., Sethu Saveda Suvanam, Lasse Vines, and Anders Hallén. "Alkali Metal Re-Distribution after Oxidation of 4H-SiC." Materials Science Forum 858 (May 2016): 677–80. http://dx.doi.org/10.4028/www.scientific.net/msf.858.677.

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Relocation of alkali metals sodium, potassium and cesium during oxidation of 4H-SiC has been studied by secondary ion mass spectrometry. The alkali metal source has been introduced by ion implantation before oxidation into n-and p-type 4H-SiC samples. Dry oxidation of SiC has been performed at 1150 oC during 4, 8 and 16 h. In the formed oxide, the main part of the alkali metals diffuses out via the SiO2 surface. Close to the moving SiO2/SiC interface, a minor amount of alkali metals is retained. In the SiC material, the main amount of implanted alkali atoms is not redistributed during the oxid

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6

Dye, James L. "The alkali metals: 200 years of surprises." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 373, no. 2037 (2015): 20140174. http://dx.doi.org/10.1098/rsta.2014.0174.

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Alkali metal compounds have been known since antiquity. In 1807, Sir Humphry Davy surprised everyone by electrolytically preparing (and naming) potassium and sodium metals. In 1808, he noted their interaction with ammonia, which, 100 years later, was attributed to solvated electrons. After 1960, pulse radiolysis of nearly any solvent produced solvated electrons, which became one of the most studied species in chemistry. In 1968, alkali metal solutions in amines and ethers were shown to contain alkali metal anions in addition to solvated electrons. The advent of crown ethers and cryptands as co

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7

Yang, Tian Hua, Wan Li Xing, Xing Ping Kai, Run Dong Li, and Ye Guang He. "The Influence of Chlorine on the Migration Behavior of Alkali Metal during Biomass and Coal Co-Combustion." Applied Mechanics and Materials 40-41 (November 2010): 335–38. http://dx.doi.org/10.4028/www.scientific.net/amm.40-41.335.

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Rice straw and Tiefa coal were used as experimental materials. Under the conditions of different temperatures and Cl/K molar ratio, the experiment was performed by using co-firing devices and ion measure instruments (flame photometer and a visible spectrophotometer). The results reveal that the majority of alkali metals and chlorine are released to gas phase by the precipitation of alkali chloride and HCl(g) above 700°C. Alkali metals release increase with the raising of chlorine content in raw materials. Alkali metals release related to sulfur, silicon and aluminum etc.

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Gärtner, Stefanie. "Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides." Crystals 10, no. 11 (2020): 1013. http://dx.doi.org/10.3390/cryst10111013.

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Alkali metal thallides go back to the investigative works of Eduard Zintl about base metals in negative oxidation states. In 1932, he described the crystal structure of NaTl as the first representative for this class of compounds. Since then, a bunch of versatile crystal structures has been reported for thallium as electronegative element in intermetallic solid state compounds. For combinations of thallium with alkali metals as electropositive counterparts, a broad range of different unique structure types has been observed. Interestingly, various thallium substructures at the same or very sim

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Bai, Kaifei, Zhen Cui, Enling Li, et al. "Adsorption of alkali metals on graphitic carbon nitride: A first-principles study." Modern Physics Letters B 34, no. 32 (2020): 2050361. http://dx.doi.org/10.1142/s0217984920503613.

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The electronic and optical properties of the adsorption of alkali metals (Li, Na, K, Rb, Cs) on graphitic carbon nitride (g-C3N[Formula: see text] were calculated and studied based on the first principles of density functional theory. The results investigate that alkali metals adsorbed g-C3N4 has metallic properties, while intrinsic g-C3N4 was semiconducting. Importantly, the charge density differential investigated the charge transfer discovered between the alkali metal and the g-C3N4 monolayer. Meanwhile, the charges (electrons) transfer from the alkali metals to the g-C3N4 system leading to

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Lin, Tao, and Amir Seraj. "Evolving Machine Learning Methods for Density Estimation of Liquid Alkali Metals over the Wide Ranges." International Journal of Chemical Engineering 2022 (May 12, 2022): 1–11. http://dx.doi.org/10.1155/2022/7633865.

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Alkali metals are widely used as industrial materials in products such as electrochemical cells because of their properties that make them suited to high temperatures. In this study, three computational approaches including gene expression programming (GEP), least squares support vector machine (LSSVM), and adaptive neuro fuzzy inference system (ANFIS) have been suggested to estimate density of different liquid alkali metals in extensive ranges of pressure and temperature. An experimental databank involving 595 experimental alkali metals’ densities has been gathered to prepare and test the mod

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Dissertations / Theses on the topic "Alkali metals"

1

Weston, David. "The interaction of propene with the alkali metals." Thesis, University of Nottingham, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338491.

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Comb, Anthony Lloyd. "Controlled reduction of organic substrates by alkali metals." Thesis, University of Nottingham, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293654.

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Lobb, William S. "Collision studies in the spectra of alkali metals." Thesis, University of Newcastle Upon Tyne, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328148.

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Matranca, Guillermo. "New Jellium Model for Alkali Metals and its Future Applications to Metal Clusters." FIU Digital Commons, 2012. http://digitalcommons.fiu.edu/etd/657.

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This research develops a new method for understanding the properties of materials. The new method was applied to alkali metals to examine how well it can predict the Wigner-Seitz radius, rs. Pseudo-potentials for the individual atoms were generated and utilized to obtain the interaction energy within these metals. The system involves 4 coulombic charges; two of them are the result of the neutral atom (one valence electron and one positive core charge for alkali atoms) and the other two are background charges of equal and opposite amount. This coulombic interaction will behave differently depen

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Cao, Yu. "Mass spectrometric study of alkali metal containing ions." Diss., Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/27890.

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Sonwane, Pavankumar Bajrang. "Speciation of alkali metals in biomass combustion and gasification." Birmingham, Ala. : University of Alabama at Birmingham, 2006. http://www.mhsl.uab.edu/dt/2006m/sonwane.pdf.

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Kernoghan, Ann A. "Positron scattering by atomic hydrogen and the alkali metals." Thesis, Queen's University Belfast, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318773.

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Liddle, Stephen Taylor. "Donor functionalised amide and alkoxide complexes of alkali metals." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324941.

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Saddawi, Abha. "The role of alkali metals in biomass thermochemical conversion." Thesis, University of Leeds, 2011. http://etheses.whiterose.ac.uk/21119/.

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Environmental preservation concerns, coupled with those of energy supply security, are leading to a push for alternative fuels that are both green and sustainable. Therefore, biomass, which is a renewable low carbon energy source, is being increasingly utilized worldwide. The use of biomass in thermochemical conversion is not without problems, some of which are related to the inherent alkali metal content present in these types of fuels. The work conducted for this thesis mainly deals with topics related to thermal degradation kinetics of biomass and the influence of alkali metals on these kin

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Djegli, Abdellah. "The interaction of 1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne with transition metals and alkali metals." Case Western Reserve University School of Graduate Studies / OhioLINK, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=case1055520104.

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Books on the topic "Alkali metals"

1

Halka, Monica. Alkali and alkaline earth metals. Facts on File, 2010.

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2

Brian, Nordstrom, ed. Alkali and alkaline earth metals. Facts on File, 2010.

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3

Drit͡s, M. E. Splavy shchelochnykh i shchelochnozemelʹnykh metallov: Spravochnik. "Metallurgii͡a", 1986.

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4

W, Ohse Roland, and International Union of Pure and Applied Chemistry., eds. Handbook of thermodynamic and transport properties of alkali metals. Blackwell Scientific, 1985.

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W, Ohse Roland, and International Union of Pure and Applied Chemistry., eds. Handbook of thermodynamic and transport properties of alkali metals. Blackwell Scientific, 1985.

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6

Jitka, Eysseltová, Dirkse T. P. 1915-, Makovic̆ka Jiřı́, and Salomon Mark, eds. Alkali metal orthophosphates. Pergamon, 1988.

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7

Borgstedt, H. U. Applied chemistry of the alkali metals. Plenum Press, 1987.

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8

Pittner, Jiří. Ab initio study of optical properties of neutral and charged pure and mixed alkali metal clusters. VMF Verlag für Wissenschaft und Forschung, 1997.

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9

Slobodin, B. V. Vanadaty s-ėlementov. Rossiĭskai︠a︡ akademii︠a︡ nauk, Uralʹskoe otdelenie, Institut khimii tverdogo tela, 2008.

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10

G, Walthall Frank, Philpotts John A, and Geological Survey (U.S.), eds. Abundances of Li, Rb, and Sr in W-2, BCR-1, and AC-E determined by isotope dilution mass spectroscopy. U.S. Dept. of the Interior, Geological Survey, 1993.

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Book chapters on the topic "Alkali metals"

1

Arevalo, Ricardo. "Alkali and Alkaline Earth Metals." In Encyclopedia of Earth Sciences Series. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-39193-9_211-1.

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2

Arevalo, Ricardo. "Alkali and Alkaline Earth Metals." In Encyclopedia of Earth Sciences Series. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-39312-4_211.

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3

Roundhill, D. Max. "Alkali and Alkaline Earth Metals." In Extraction of Metals from Soils and Waters. Springer US, 2001. http://dx.doi.org/10.1007/978-1-4757-5204-5_11.

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4

Borgstedt, Hans Ulrich. "With Alkali Metals." In U Uranium. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-662-05671-4_1.

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5

Turova, Nataliya. "Alkali Metals, Francium." In Inorganic Chemistry in Tables. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-20487-6_31.

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6

Breunig, H. J. "Of Alkali Metals." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch186.

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7

Huber, F., and K. Grätz. "With Alkali Metals." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145258.ch63.

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8

Akitt, J. W. "The Alkali and Alkaline Earth Metals." In Multinuclear NMR. Springer US, 1987. http://dx.doi.org/10.1007/978-1-4613-1783-8_7.

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9

Watts, G. R. "Alloys with Alkali Metals." In Rh Rhodium. Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-06411-5_11.

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10

Tyagi, Adish, Rohit Singh Chauhan, and A. K. Tyagi. "Biochemistry of Alkali and Alkaline Earth Metals." In Metal Ions in Biology. CRC Press, 2025. https://doi.org/10.1201/9781003432333-3.

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Conference papers on the topic "Alkali metals"

1

McNallan, M. J., and Y. S. Park. "High Temperature Corrosion of Alloys and Ceramics by Alkali Chlorides." In CORROSION 1996. NACE International, 1996. https://doi.org/10.5006/c1996-96441.

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Abstract Alkali chlorides are well known to cause accelerated corrosion. At elevated temperatures, the presence of alkali chlorides as vapors or molten deposits can cause accelerated attack of either high temperature metal alloys or ceramics. The mechanism of attack is different in the two cases, however, with the chlorine component being most aggressive for corrosion of metals and the alkali being most aggressive for corrosion of ceramics. The reaction of the alkali chloride with the oxide scale on metals releases chlorine which causes accelerated corrosion. The corrosion rate can be reduced

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2

Mäkipää, M., Th Malkow, and D. J. Baxter. "The Effect of Salt Composition on the Chlorine Corrosion of Low Alloy Steels." In CORROSION 2001. NACE International, 2001. https://doi.org/10.5006/c2001-01186.

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Abstract Material wastage of superheater tubes made of low alloy steels is greatly accelerated under normal operating conditions if alkali chlorides are stable in the deposits. The effect of salt composition on the corrosion behavior especially that of the alkali cation, Na or K was investigated using crucible tests in a thermobalance under a flowing N2-O2-CO2-atmosphere, followed by SEM/EDS analyses and thermodynamic calculations. For both salts, rapid corrosion occurred due to the known mechanism of active oxidation. In the case of sodium chloride, a major part of the metal loss was caused b

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Sharp, W. B. A. (Sandy), Douglas L. Singbeil, and James R. Keiser. "Superheater Corrosion Produced by Biomass Fuels." In CORROSION 2012. NACE International, 2012. https://doi.org/10.5006/c2012-01308.

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Abstract About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler’s steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr2O3. However, this Cr2O3 can be fluxed awa

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Yin, Yvette L. "Making the Transition from Metals to FRP – A Case History." In CORROSION 2005. NACE International, 2005. https://doi.org/10.5006/c2005-05508.

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Abstract Whenever a project, such as a chemical plant expansion, requires vessels and tanks, the specifying engineer's first thought is generally of metals. However, on a major chlor-alkali plant expansion project overseas, the metals that will stand up to the aggressive service, e.g. Titanium and Nickel 200, are very costly. In this plant, nearly half of the new equipment and piping was fabricated of non-metallic materials; predominantly fiber reinforced plastic (FRP) and dual laminates. This paper will give those unfamiliar with FRP pointers that will enable them to have a successful project

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Eshelman, Donald M., and Stephen Drake. "Use of Poly Dicyclopentadiene for the Chlor-Alkali and Chlorate Industries." In CORROSION 2000. NACE International, 2000. https://doi.org/10.5006/c2000-00557.

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Abstract The process streams found in chlor-alkali and chlorate plants require unique materials of construction to provide corrosion resistance to these aggressive environments which typically operate in the temperature range of 80-100°C. The poly dicyclopentadiene has exceptional corrosion resistance and offers a cost effective alternative to premium metals, perfluorinated materials, and dual laminates currently used in these plants. This material also provides the temperature stability necessary to operate in these process streams. Included is a discussion on the corrosion resistance and phy

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Appleby, A. J. "Corrosion in Low and High Temperature Fuel Cells - an Overview." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86079.

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Abstract Fuel cell anodes operate in a reducing atmosphere, whereas cathodes operate under strongly oxidizing conditions in difficult electrolytic environments. Electrochemical corrosion can limit the working cathode potential, hence fuel cell operating efficiency, as well as fuel cell lifetime. The four principal classes of electrolyte are aqueous alkali, aqueous acid, and two high-temperature CO2-rejecting systems: molten alkali carbonates (ca. 650°C) and solid oxide ionic conductors (1000°C). For the aqueous electrolytes, thermodynamically stable cathode materials include some of the noble

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Talus, Annika, Rikard Norling, and Alice Moya Núñez. "Influence of Pb and Cl in Waste Wood Fuel on Furnace Wall Corrosion of Low Alloyed Steel and Alloy 625." In CONFERENCE 2024. AMPP, 2024. https://doi.org/10.5006/c2024-21033.

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Abstract Firing waste wood in thermal power plants can lead to furnace wall corrosion due to corrosive elements such as chlorine, heavy metals, and alkali metals present in the fuel. This study investigates the influence of lead and chlorine on furnace wall corrosion of a low alloyed steel (16Mo3) and a nickel-based alloy (Alloy 625) during two field exposures using an air-cooled probe. Two two-week long test campaigns firing two different waste wood fuels (higher and lower lead and chlorine content) were carried out, exposing samples having metal temperatures in the interval 350-400 °C. The c

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Lai, G. Y. "A New NI-CO-CR-FE-SI Alloy for High Temperature, Hostile Environments." In CORROSION 1989. NACE International, 1989. https://doi.org/10.5006/c1989-89209.

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Abstract A new sulfidation-resistant alloy based on the Ni-Co-Cr-Fe-Si system was recently developed at Haynes International, Inc. The alloy utilizes both Cr and Si to form a very protective oxide scale in resisting sulfidation attack. This oxide scale is particularly resistant to ash/salt deposit corrosion attack which has been frequently encountered in industrial combustion environments contaminated with corrosive species, such as alkali metals, sulfur, chlorine, zinc and others. Recent field tests have indicated that this alloy performs extremely well in waste incinerators, cement kilns and

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Agarwal, D. C., and U. Brill. "NiCr27FeSiRE: a New Alloy for Waste Incineration." In CORROSION 1993. NACE International, 1993. https://doi.org/10.5006/c1993-93209.

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Abstract Controlled high temperature incineration is playing an increasingly important role in proper and safe management of both municipal and industrial waste products. Depending on the chemical make-up of the waste stream and combustion conditions, a multitude of aggressive and corrosive high temperature environments are produced. These could be either sulfudizing, carburizing, halogenizing, nitriding, reducing, and oxidizing in nature, or a combination thereof. Other harmfull species are also generated due to presence of alkali metals (Na, K) and heavy metals (Pb, Zn), all of which could a

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Li, Yuanshi, Yan Niu, and Weitao Wu. "Accelerated Corrosion of Pure Fe, Cr, Ni and Several Fe-based Alloys Induced by ZnCl2-KCl at 450 °C in Pure O2." In CORROSION 2001. NACE International, 2001. https://doi.org/10.5006/c2001-01158.

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Abstract Corrosion problems in waste incinerators are usually very severe, also due to the presence of low-melting point heavy and alkali metal chlorides. In this paper, the corrosion behavior of several Fe-based alloys with different Cr content, as well as three pure metals Fe, Cr, and Ni, was studied at 450°C beneath ZnCl2-KCl deposits in flowing pure oxygen. All the materials suffered from accelerated corrosion, characterized by an important separation and spallation of the oxide scales. The Cr-containing alloys did not exhibit better corrosion resistance to this environment due to the poor

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Reports on the topic "Alkali metals"

1

Natesan, K., D. L. Rink, and R. Haglund. Chemical compatibility of structural materials in alkali metals. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/115713.

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Burgess Jr, Donald R. Melting Points and Boiling Points for the Alkali Metals. National Institute of Standards and Technology, 2023. http://dx.doi.org/10.6028/nist.tn.2277.

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Burgess Jr., Donald R. Melting Points and Boiling Points for the Alkali Metals. National Institute of Standards and Technology, 2023. http://dx.doi.org/10.6028/nist.tn.2273.

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Natesan, K., D. L. Rink, R. Haglund, and R. W. Clark. Subtask 12E1: Compatibility of structural materials in liquid alkali metals. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/415183.

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Natesan, K., and D. L. Rink. Fabrication of aluminum nitride and its stability in liquid alkali metals. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/115712.

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Kim, Hojong, Supathorn Phongikaroon, and James L. Willit. Fundamental Electrochemical Properties of Liquid Metals in LiCl-KCl for Separation of Alkali/Alkaline-Earths (Cs, Sr, and Ba). Office of Scientific and Technical Information (OSTI), 2018. http://dx.doi.org/10.2172/1490212.

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Wang, K., G. S. Chottiner, P. Herrera-Fierro, and D. A. Scherson. Ex-situ and in-situ spectroscopic studies of the passive film on alkali and alkaline earth metals in nonaqueous solvents. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/7254901.

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King, William, Daniel McCabe, Seth Hunter, and Sean Noble. Evaluations of the Fates of Alkali Metals, Actinides, Mercury, and Iodine During DWPF Recycle Diversion. Office of Scientific and Technical Information (OSTI), 2021. http://dx.doi.org/10.2172/1807895.

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Wang, K., G. S. Chottiner, P. Herrera-Fierro, and D. A. Scherson. Ex-situ and in-situ spectroscopic studies of the passive film on alkali and alkaline earth metals in nonaqueous solvents. Final report. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10180284.

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Scherson, D., G. Chottiner, P. Herrara-Fierro, and Xuekun Xing. Spectroscopic studies of the passive film on alkali and alkaline earth metals in non-aqueous solvents: A surface science approach: Final report. Office of Scientific and Technical Information (OSTI), 1987. http://dx.doi.org/10.2172/5554162.

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