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Journal articles on the topic 'Alkali metals'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Chen, Yan-bo, Yong Deng, Ran Liu, Li-da Chen, and Xing-min Guo. "Optimization of alkali metals discharge performance of blast furnace slag and its extreme value model." High Temperature Materials and Processes 41, no. 1 (2022): 306–14. http://dx.doi.org/10.1515/htmp-2022-0013.

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Abstract In order to improve the alkali metals discharge capacity of slag, the gas-slag balance method was used to carry out the slag alkali metals discharge experiments, the effect of slag composition on alkali metals discharge performance of slag was studied, some suggestions were put forward to optimize the alkali metals discharge performance of slag and the extreme value model was established. The results show that the alkali metals discharge ratio of slag decreased with the increase in the binary basicity and mass fraction of TiO2, and increased with the increase in the mass fraction of M

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2

Li, Fang Yong, Jing Hui Song, and Zhi Gang Zhan. "Effect of the Alkali Metals’ Existing Form on its Emission Characteristics during Biomass Combustion Process." Advanced Materials Research 550-553 (July 2012): 544–49. http://dx.doi.org/10.4028/www.scientific.net/amr.550-553.544.

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As one kind of renewable energy, bio-energy attracts more and more scholars’ attention due to its good ignition, combustion characteristics and zero CO2 release during bio-energy combustion process, alkali metals’ emission could cause fouling, slagging, high temperature corrosion and ultra-fine particulate matter emission, which hazard equipment safety and human healthy. In this paper, the release characteristics of alkali metals during the combustion process of rice straw (RS) and sawdust (SD) was studied by the chemical desperation disposal method and in a vertical thermal balance furnace. A

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3

Hensel, Friedrich, and Georg-Friedrich Hohl. "Expanded Fluid Alkali Metals." REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY 3, no. 2 (1994): 163–79. http://dx.doi.org/10.4131/jshpreview.3.163.

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4

Koplík, Jan, Tomáš Solný, Lukáš Kalina, and Jiří Másilko. "Immobilization of Sr²⁺, Bi³⁺ and Zn²⁺ in Alkali-Activated Materials Based on Blast Furnace Slag and Fly Ash." Key Engineering Materials 761 (January 2018): 15–18. http://dx.doi.org/10.4028/www.scientific.net/kem.761.15.

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It is well known, that alkali-activated materials (AAMs) are suitable for immobilization of heavy metals and other hazardous materials. This study is focused on the characterization of inhibition of three metals – Sr2+, Bi3+and Zn2+in alkali-activated matrices. Two type of matrices were prepared – alkali-activated blast furnace slag (BFS) and alkali-activated fly ash (FA). Sodium water glass was used as alkaline activator. The ability of these matrices to fix the metals were proved by leaching tests. Compressive strength was measured to characterize mechanical properties of the matrices. Scann

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5

Linnarsson, Margareta K., Sethu Saveda Suvanam, Lasse Vines, and Anders Hallén. "Alkali Metal Re-Distribution after Oxidation of 4H-SiC." Materials Science Forum 858 (May 2016): 677–80. http://dx.doi.org/10.4028/www.scientific.net/msf.858.677.

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Relocation of alkali metals sodium, potassium and cesium during oxidation of 4H-SiC has been studied by secondary ion mass spectrometry. The alkali metal source has been introduced by ion implantation before oxidation into n-and p-type 4H-SiC samples. Dry oxidation of SiC has been performed at 1150 oC during 4, 8 and 16 h. In the formed oxide, the main part of the alkali metals diffuses out via the SiO2 surface. Close to the moving SiO2/SiC interface, a minor amount of alkali metals is retained. In the SiC material, the main amount of implanted alkali atoms is not redistributed during the oxid

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6

Dye, James L. "The alkali metals: 200 years of surprises." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 373, no. 2037 (2015): 20140174. http://dx.doi.org/10.1098/rsta.2014.0174.

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Alkali metal compounds have been known since antiquity. In 1807, Sir Humphry Davy surprised everyone by electrolytically preparing (and naming) potassium and sodium metals. In 1808, he noted their interaction with ammonia, which, 100 years later, was attributed to solvated electrons. After 1960, pulse radiolysis of nearly any solvent produced solvated electrons, which became one of the most studied species in chemistry. In 1968, alkali metal solutions in amines and ethers were shown to contain alkali metal anions in addition to solvated electrons. The advent of crown ethers and cryptands as co

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7

Yang, Tian Hua, Wan Li Xing, Xing Ping Kai, Run Dong Li, and Ye Guang He. "The Influence of Chlorine on the Migration Behavior of Alkali Metal during Biomass and Coal Co-Combustion." Applied Mechanics and Materials 40-41 (November 2010): 335–38. http://dx.doi.org/10.4028/www.scientific.net/amm.40-41.335.

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Rice straw and Tiefa coal were used as experimental materials. Under the conditions of different temperatures and Cl/K molar ratio, the experiment was performed by using co-firing devices and ion measure instruments (flame photometer and a visible spectrophotometer). The results reveal that the majority of alkali metals and chlorine are released to gas phase by the precipitation of alkali chloride and HCl(g) above 700°C. Alkali metals release increase with the raising of chlorine content in raw materials. Alkali metals release related to sulfur, silicon and aluminum etc.

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8

Gärtner, Stefanie. "Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides." Crystals 10, no. 11 (2020): 1013. http://dx.doi.org/10.3390/cryst10111013.

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Alkali metal thallides go back to the investigative works of Eduard Zintl about base metals in negative oxidation states. In 1932, he described the crystal structure of NaTl as the first representative for this class of compounds. Since then, a bunch of versatile crystal structures has been reported for thallium as electronegative element in intermetallic solid state compounds. For combinations of thallium with alkali metals as electropositive counterparts, a broad range of different unique structure types has been observed. Interestingly, various thallium substructures at the same or very sim

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9

Bai, Kaifei, Zhen Cui, Enling Li, et al. "Adsorption of alkali metals on graphitic carbon nitride: A first-principles study." Modern Physics Letters B 34, no. 32 (2020): 2050361. http://dx.doi.org/10.1142/s0217984920503613.

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The electronic and optical properties of the adsorption of alkali metals (Li, Na, K, Rb, Cs) on graphitic carbon nitride (g-C3N[Formula: see text] were calculated and studied based on the first principles of density functional theory. The results investigate that alkali metals adsorbed g-C3N4 has metallic properties, while intrinsic g-C3N4 was semiconducting. Importantly, the charge density differential investigated the charge transfer discovered between the alkali metal and the g-C3N4 monolayer. Meanwhile, the charges (electrons) transfer from the alkali metals to the g-C3N4 system leading to

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10

Lin, Tao, and Amir Seraj. "Evolving Machine Learning Methods for Density Estimation of Liquid Alkali Metals over the Wide Ranges." International Journal of Chemical Engineering 2022 (May 12, 2022): 1–11. http://dx.doi.org/10.1155/2022/7633865.

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Alkali metals are widely used as industrial materials in products such as electrochemical cells because of their properties that make them suited to high temperatures. In this study, three computational approaches including gene expression programming (GEP), least squares support vector machine (LSSVM), and adaptive neuro fuzzy inference system (ANFIS) have been suggested to estimate density of different liquid alkali metals in extensive ranges of pressure and temperature. An experimental databank involving 595 experimental alkali metals’ densities has been gathered to prepare and test the mod

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11

Degtyareva, Valentina. "Core ionization in compressed alkali and alkali earth metals." Acta Crystallographica Section A Foundations of Crystallography 65, a1 (2009): s344. http://dx.doi.org/10.1107/s0108767309092666.

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12

Liu, Yanquan, Leming Cheng, Yonggang Zhao, et al. "Transformation behavior of alkali metals in high-alkali coals." Fuel Processing Technology 169 (January 2018): 288–94. http://dx.doi.org/10.1016/j.fuproc.2017.09.013.

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13

Liang, Shuai, Shengguang Cao, Changrong Liu, Shah Zeb, Yu Cui, and Guoxin Sun. "Heavy metal adsorption using structurally preorganized adsorbent." RSC Advances 10, no. 12 (2020): 7259–64. http://dx.doi.org/10.1039/d0ra00125b.

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14

Prut, V. V. "Gruneisen function of alkali metals." Izvestiya vysshikh uchebnykh zavedenii. Fizika 65, no. 2 (2022): 131–39. http://dx.doi.org/10.17223/00213411/65/2/131.

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15

Hopkins, Alexander D. "Alkali and alkaline-earth metals." Annual Reports Section "A" (Inorganic Chemistry) 102 (2006): 46. http://dx.doi.org/10.1039/b508351f.

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16

Hill, Michael S. "Alkali and alkaline-earth metals." Annual Reports Section "A" (Inorganic Chemistry) 105 (2009): 55. http://dx.doi.org/10.1039/b818133k.

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17

Ranganathan, S., and K. N. Pathak. "Diffusion in liquid alkali metals." Journal of Physics: Condensed Matter 6, no. 7 (1994): 1309–18. http://dx.doi.org/10.1088/0953-8984/6/7/004.

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18

Edwards, Peter P., Paul A. Anderson, and John Meurig Thomas. "Dissolved Alkali Metals in Zeolites." Accounts of Chemical Research 29, no. 1 (1996): 23–29. http://dx.doi.org/10.1021/ar950152c.

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19

Dass, Narsingh. "Melting maximum in alkali metals." Physical Review B 52, no. 5 (1995): 3023–25. http://dx.doi.org/10.1103/physrevb.52.3023.

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20

Hoshino, Kozo. "Structure of Liquid Alkali Metals." REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY 1, no. 4 (1992): 280–87. http://dx.doi.org/10.4131/jshpreview.1.280.

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21

Hill, Michael S. "Alkali and alkaline-earth metals." Annual Reports Section "A" (Inorganic Chemistry) 103 (2007): 39. http://dx.doi.org/10.1039/b612595f.

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22

Schilling, J. S. "Superconductivity in the alkali metals." High Pressure Research 26, no. 3 (2006): 145–63. http://dx.doi.org/10.1080/08957950600864401.

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23

Hill, Michael S. "Alkali and alkaline earth metals." Annual Reports Section "A" (Inorganic Chemistry) 104 (2008): 64. http://dx.doi.org/10.1039/b716559p.

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24

Wallace, Duane C. "Anharmonic entropy of alkali metals." Physical Review B 46, no. 9 (1992): 5242–45. http://dx.doi.org/10.1103/physrevb.46.5242.

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25

Aruga, T. "Alkali-metal adsorption on metals." Progress in Surface Science 31, no. 1-2 (1989): 61–130. http://dx.doi.org/10.1016/0079-6816(89)90013-0.

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26

Afyon, Semih, Peter Höhn, Marc Armbrüster, et al. "Azidoaurates of the Alkali Metals." Zeitschrift für anorganische und allgemeine Chemie 632, no. 10-11 (2006): 1671–80. http://dx.doi.org/10.1002/zaac.200600062.

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27

Balasubramanian, R. "Superheating of Liquid Alkali Metals." International Journal of Thermophysics 27, no. 5 (2006): 1494–500. http://dx.doi.org/10.1007/s10765-006-0098-2.

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28

Mishra, S. K., and T. N. Singh. "Lattice Dynamics of Alkali Metals." physica status solidi (b) 158, no. 1 (1990): 153–63. http://dx.doi.org/10.1002/pssb.2221580114.

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29

Liu, Renmin, Congmei Chen, Wei Chu, and Wenjing Sun. "Unveiling the Origin of Alkali Metal (Na, K, Rb, and Cs) Promotion in CO2 Dissociation over Mo2C Catalysts." Materials 15, no. 11 (2022): 3775. http://dx.doi.org/10.3390/ma15113775.

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Molybdenum carbide (Mo2C) is a promising and low-cost catalyst for the reverse water−gas shift (RWGS) reaction. Doping the Mo2C surface with alkali metals can improve the activity of CO2 conversion, but the effect of these metals on CO2 conversion to CO remains poorly understood. In this study, the energies of CO2 dissociation and CO desorption on the Mo2C surface in the presence of different alkali metals (Na, K, Rb, and Cs) are calculated using density functional theory (DFT). Alkali metal doping results in increasing electron density on the Mo atoms and promotes the adsorption and activatio

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30

Linnarsson, Margareta K., and Anders Hallén. "Diffusion of Alkali Metals in SiC." Materials Science Forum 778-780 (February 2014): 297–300. http://dx.doi.org/10.4028/www.scientific.net/msf.778-780.297.

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Diffusion of lithium, sodium and potassium in SiC has been studied by secondary ion mass spectrometry. The alkali metal diffusion sources have been introduced by ion implantation. Subsequent anneals have been carried out in vacuum or in Ar atmosphere in the temperature range 700 °C - 1500 °C for 5 min to 16 h. The bombardment-induced defects in the vicinity of the ion implanted profile are readily decorated by the implanted . In the bulk, the diffusing alkali metals are most likely trapped and detrapped at boron and/or other defects during diffusion. The diffusivity of the studied alkali metal

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31

Tumidajski, Peter J. "Thermodynamic investigation of the ternary K–Pb–Sn and Rb–Pb–Sn alloys." Canadian Journal of Chemistry 69, no. 3 (1991): 458–61. http://dx.doi.org/10.1139/v91-068.

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Activity coefficients for alkali metals in the K–Pb–Sn and Rb–Pb–Sn alloys were measured at 606 °C (879 K) for compositions generally less than about 10 at.% alkali metal. An alkali metal concentration cell with a potassium or rubidium substituted β-Al2O3 solid electrolyte was used to perform the experiments. A coulometric titration technique was used to electrochemically generate the alkali metal in the Pb–Sn alloys. The results indicated that, for both potassium and rubidium alloys, as solvent composition is varied from pure tin to pure lead the liquid becomes more associated, suggesting the

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32

Sukhachev, R. A., M. V. Mamonova, P. V. Prudnikov, and A. V. Lavrenov. "Carbon Defects Applied to Alkali-Ion Batteries: A Density Functional Theory Study." Russian Journal of Physical Chemistry A 99, no. 6 (2025): 1335–41. https://doi.org/10.1134/s0036024425700694.

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Abstract The study investigates the adsorption properties of alkali metals (Li, Na, K) on defective carbon surfaces using density functional theory. Various types of defects are considered, including single vacancies and nitrogen doping. The results demonstrate that the presence of defects significantly enhances the adsorption energy, with nitrogen doping in particular intensifying the interaction with alkali metals. This effect could potentially improve the performance of alkali-ion batteries, enabling higher capacity.

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33

Fohlmeister, Lea, and Andreas Stasch. "Alkali Metal Hydride Complexes: Well-Defined Molecular Species of Saline Hydrides." Australian Journal of Chemistry 68, no. 8 (2015): 1190. http://dx.doi.org/10.1071/ch15206.

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The first examples of well-defined alkali metal hydride complexes have been synthesised and characterised in recent years, and their properties and underlying principles for their generation and stabilisation are emerging. This article gives an account of the hydrides of the alkali metals (Group 1 metals) and selected ‘-ate’ complexes containing hydrides and alkali metals, and reviews the chemistry of well-defined alkali metal hydride complexes including their syntheses, structures, and characteristics. The properties of the alkali metal hydrides LiH, NaH, KH, RbH, and CsH are dominated by the

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34

Lugt, W. van der, and W. Geertsma. "Electron transport in liquid metals and alloys." Canadian Journal of Physics 65, no. 3 (1987): 326–47. http://dx.doi.org/10.1139/p87-039.

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This paper deals with a number of selected topics from the field of electric transport properties in liquid metals and alloys. First, some nearly free electron systems are considered; it appears that some problems associated with the properties of liquid Na–Cs alloys and of amalgams are still unsolved. Then, systems exhibiting strong compound formation, particularly alkali–nonalkali alloys with a large electronegativity difference between the components, are reviewed. A qualitative interpretation in terms of chemical-valence rules, based upon our knowledge of the solid state, is given. Next, r

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35

Bacariza, M. Carmen, Cláudia Grilo, Paula Teixeira, José M. Lopes, and Carlos Henriques. "Alkali and Alkali-Earth Metals Incorporation to Ni/USY Catalysts for CO2 Methanation: The Effect of the Metal Nature." Processes 9, no. 10 (2021): 1846. http://dx.doi.org/10.3390/pr9101846.

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CO2 methanation is typically carried out using Ni-supported catalysts containing promoters such as alkali or alkali-earth metals to improve their properties. In this work, bimetallic Ni-based USY zeolite catalysts containing alkali (Li, K and Cs) and alkali-earth (Mg, Ca) metal compounds were prepared using the same conditions (15 wt% of metals; co-impregnation), characterized by N2 sorption, XRD, TGA, CO2 adsorption–desorption, DRS UV-Vis and H2-TPR, and finally applied in CO2 methanation reaction (86,100 mL h−1 g−1, PCO2 = 0.16 bar, H2:CO2 = 4:1). For each group, the effects of the second me

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36

Maercker, Adalbert. "Ether Cleavage with Organo-Alkali-Metal Compounds and Alkali Metals." Angewandte Chemie International Edition in English 26, no. 10 (1987): 972–89. http://dx.doi.org/10.1002/anie.198709721.

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37

Kilic, H. H., S. Pietzko, and R. W. Schmutzler. "Thermodynamic activity of alkali metals in alkali metal-gold alloys." Journal of Non-Crystalline Solids 117-118 (February 1990): 521–24. http://dx.doi.org/10.1016/0022-3093(90)90583-8.

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38

Siringo, Fabio, Renato Pucci, and Giuseppe G. N. Angilella. "Are light alkali metals still metals under high pressure?" High Pressure Research 15, no. 4 (1997): 255–64. http://dx.doi.org/10.1080/08957959708244246.

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39

Sonvane, Yogeshkumar A., Pankajsinh B. Thakor, P. N. Gajjar, and Ashvin R. Jani. "Temperature Dependent Surface Properties of Liquid Alkali Metals." Solid State Phenomena 209 (November 2013): 44–47. http://dx.doi.org/10.4028/www.scientific.net/ssp.209.44.

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Temperature dependent surface properties like surface tension (γ) and surface entropy (SV) of liquid alkali metals are studied in the present paper. Our newly constructed parameter free model potential is used to describe the electron-ion interaction. To see the influence of local field correction function on surface properties of liquid alkali metal, we have used Sarkar et al local field correction function. The present results are found in good agreement with available experimental data as well as other theoretical data. Lastly we conclude that our model potential is capable to explain surfa

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40

Yin, Jun, Ying Hu, and Juyoung Yoon. "Fluorescent probes and bioimaging: alkali metals, alkaline earth metals and pH." Chemical Society Reviews 44, no. 14 (2015): 4619–44. http://dx.doi.org/10.1039/c4cs00275j.

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This review highlights the recent advances that have been made in the design and bioimaging applications of fluorescent probes for alkali metals, alkaline earth metal cations and for pH determination within biological systems.

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41

Koplík, Jan, Miroslava Smolková, and Jakub Tkacz. "The Leachability of Heavy Metals from Alkali-Activated Fly Ash and Blast Furnace Slag Matrices." Materials Science Forum 851 (April 2016): 141–46. http://dx.doi.org/10.4028/www.scientific.net/msf.851.141.

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The ability of alkali-activated materials (AAMs) to fix and immobilize heavy metals was investigated. Two raw materials were used to prepare alkali-activated matrices – high-temperature fly ash and blast furnace slag (BFS). NaOH served as an alkaline activator. Two heavy metals (Mn, Ni) were added in different amounts to find out the influence of dosage of heavy metal on the mechanical properties of the matrices and the leachability. Leachability was measured as concentration of heavy metals in leachates (ČSN EN 12457-4) by inductively coupled plasma/optical emission spectrometry (ICP/OES). St

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42

Gup, Ramazan, H. Korkmaz Alpoguz, and A. Dincer Beduk. "Synthesis and Extraction Properties of 1,2-Bis(amidoxime) Derivatives." Collection of Czechoslovak Chemical Communications 67, no. 2 (2002): 209–18. http://dx.doi.org/10.1135/cccc20020209.

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Four 1,2-bis(amidoxime)s bearing benzoate groups were synthesized. Their complexing properties were studied by the liquid-liquid extraction of selected alkali (Na+ and K+) and transition metals (Hg2+, Cu2+, Pb2+ and Ni2+). It has been observed that all ligands show a high affinity to Cu2+ and Hg2+ ions, whereas almost no affinity to alkali metals.

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43

Popov, A. V., A. V. Kazakov, D. V. Bukhtoyarov, and R. A. Emelyanov. "Combustion and Extinguishing of Alkali Metals." Occupational Safety in Industry, no. 3 (March 2022): 78–83. http://dx.doi.org/10.24000/0409-2961-2022-3-78-83.

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Research was conducted on studying the features of combustion and extinguishing of the alkali metals. As experiments showed, during combustion in the air, in addition to oxygen, only lithium from the entire series of alkali metals additionally uses nitrogen as an oxidizing agent. Sodium was chosen as the combustible load for the experiments on the determination of the extinguishing efficiency. When conducting fire tests according to the previously developed methodology, the extinguishing ability was evaluated by the mass of the fire extinguishing agent, after which the sodium combustion did no

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44

Artamonova, I. V., L. A. Lesnova, S. M. Rusakova, and E. B. Godunov. "Evaluation of alkali metals salts solubility." Izvestiya MGTU MAMI 7, no. 1-3 (2013): 5–8. http://dx.doi.org/10.17816/2074-0530-67744.

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Calculation of alkali metals salts solubility is made using two approaches: thermodynamic (or power) and on values of charge and ionic radius sizes. The estimation of salts and oxyhydroxides solubility for elements of 1А subgroups of periodic table is given.

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45

Thakor, Gajjar, and Jani. "THERMODYNAMIC PROPERTIES OF LIQUID ALKALI METALS." Condensed Matter Physics 4, no. 3 (2001): 473. http://dx.doi.org/10.5488/cmp.4.3.473.

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46

Gorrell, I. B. "2 Alkali and alkaline-earth metals." Annual Reports Section "A" (Inorganic Chemistry) 96 (2000): 5–22. http://dx.doi.org/10.1039/b002946g.

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47

Frisch, G., and C. Röhr. "New oxoferrates of the alkali metals." Acta Crystallographica Section A Foundations of Crystallography 61, a1 (2005): c383. http://dx.doi.org/10.1107/s0108767305083741.

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48

Gorrell, I. B. "2 Alkali and alkaline-earth metals." Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 98 (2002): 3–22. http://dx.doi.org/10.1039/b109552h.

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49

Gorrell, I. B. "2 Alkali and alkaline-earth metals." Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 99 (2003): 3–19. http://dx.doi.org/10.1039/b211501h.

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50

Leonova, L. S., A. V. Levchenko, E. I. Moskvina, et al. "Tungsten oxide bronzes with alkali metals." Russian Journal of Electrochemistry 45, no. 5 (2009): 593–601. http://dx.doi.org/10.1134/s1023193509050188.

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