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1
Watson, Ken, Lawrence C. Rowan, Timothy L. Bowers, Carmen Anton‐Pacheco, Pablo Gumiel, and Susanne H. Miller. "Lithologic analysis from multispectral thermal infrared data of the alkalic rock complex at Iron Hill, Colorado." GEOPHYSICS 61, no. 3 (May 1996): 706–21. http://dx.doi.org/10.1190/1.1443998.
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Airborne thermal‐infrared multispectral scanner (TIMS) data of the Iron Hill carbonatite‐alkalic igneous rock complex in south‐central Colorado are analyzed using a new spectral emissivity ratio algorithm and confirmed by field examination using existing 1:24 000‐scale geologic maps and petrographic studies. Color composite images show that the alkalic rocks could be clearly identified and that differences existed among alkalic rocks in several parts of the complex. An unsupervised classification algorithm defines four alkalic rock classes within the complex: biotitic pyroxenite, uncompahgrite, augitic pyroxenite, and fenite + nepheline syenite. Felsic rock classes defined in the surrounding country rock are an extensive class consisting of tuff, granite, and felsite, a less extensive class of granite and felsite, and quartzite. The general composition of the classes can be determined from comparisons of the TIMS spectra with laboratory spectra. Carbonatite rocks are not classified, and we attribute that to the fact that dolomite, the predominant carbonate mineral in the complex, has a spectral feature that falls between TIMS channels 5 and 6. Mineralogical variability in the fenitized granite contributed to the nonuniform pattern of the fenite‐nepheline syenite class. The biotitic pyroxenite, which resulted from alteration of the pyroxenite, is spatially associated and appears to be related to narrow carbonatite dikes and sills. Results from a linear unmixing algorithm suggest that the detected spatial extent of the two mixed felsic rock classes was sensitive to the amount of vegetation cover. These results illustrate that spectral thermal infrared data can be processed to yield compositional information that can be a cost‐effective tool to target mineral exploration, particularly in igneous terranes.
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Hakim, Fahmi, Yanuardi Satrio Nugroho, Cendi Diar Permata Dana, and Anastasia Dewi Titisari. "Geology and Petrogenesis of Igneous Rocks from Batur Paleovolcano, Gunungkidul, Yogyakarta: Evidence from their Textures, Mineralogy, and Major Elements Geochemistry." Journal of Applied Geology 4, no. 1 (August 14, 2019): 32. http://dx.doi.org/10.22146/jag.48739.
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Batur paleovolcano is located in Wediombo Beach area, Gunungkidul Regency, Yogyakarta and is being part of Wuni Formation. Several volcanic products including lava flow, autoclastic breccia and volcanic breccia can be found associated with diorite intrusions. This research is aimed to characterize geological, mineralogical andgeochemical variations of igneous rocks from Batur paleovolcano to understand its petrogenesis. Detailed geological mapping with scale of 1:12,500 is conducted to identify geological aspects and delineate igneous rocks distributions. Igneous rocks and selected wall rocks samples were prepared for laboratory analysis including 8 samples for petrography and 5 samples for ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry) analysis. Several geochemical data from previous study are also added to investigate the geochemical variations. Geological condition of the research area consists of four rock units including colluvial deposit, limestone, andesite lava and diorite intrusion. Geological structures found are normal fault and shear joint where the main stress direction is north–south. Petrography analysis showed that igneous rocks in this research area consist of diorite intrusion and andesite lava with phorphyritic texture. Plagioclase become the most abundant minerals found both as phenocryst phase and groundmass. Hornblende only occur as phenocryst phase in minor amounts as accesory mineral. Major elementsgeochemistry analysis showed the rocks are characterized by intermediate silica with low alkali content. They are can be categorized as calc-alkaline series. However, some samples are fall into tholeiitic series. Major elements variation and textural study also indicate the magma is experienced differentiation process by fractional crystallization mechanism. This study suggests that igneous rocks from Batur paleovolcano is formed by two phases of formation. Earlier phase is the formation of andesite lava in island arc tholeiitic tectonic setting then at the later phase is formation of diorite intrusion in the calc-alkaline basalts tectonic setting.
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Fitton, J. G., and B. G. J. Upton. "Alkaline igneous rocks: a review symposium." Journal of the Geological Society 142, no. 4 (July 1985): 697–708. http://dx.doi.org/10.1144/gsjgs.142.4.0697.
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Hurai, Vratislav, Monika Huraiová, and Patrik Konečný. "REE Minerals as Geochemical Proxies of Late-Tertiary Alkalic Silicate ± Carbonatite Intrusions Beneath Carpathian Back-Arc Basin." Minerals 11, no. 4 (March 31, 2021): 369. http://dx.doi.org/10.3390/min11040369.
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The accessory mineral assemblage (AMA) of igneous cumulate xenoliths in volcanoclastic deposits and lava flows in the Carpathian back-arc basin testifies to the composition of intrusive complexes sampled by Upper Miocene-Pliocene basalt volcanoes. The magmatic reservoir beneath Pinciná maar is composed of gabbro, moderately alkalic to alkali-calcic syenite, and calcic orthopyroxene granite (pincinite). The intrusive complex beneath the wider area around Fiľakovo and Hajnáčka maars contains mafic cumulates, alkalic syenite, carbonatite, and calc-alkalic granite. Both reservoirs originated during the basaltic magma underplating, differentiation, and interaction with the surrounding mantle and crust. The AMA of syenites is characterized by yttrialite-Y, britholite-Y, britholite-Ce, chevkinite-Ce, monazite-Ce, and rhabdophane(?). Baddeleyite and REE-zirconolite are typical of alkalic syenite associated with carbonatite. Pyrochlore, columbite-Mn, and Ca-niobates occur in calc-alkalic granites with strong peralkalic affinity. Nb-rutile, niobian ilmenite, and fergusonite-Y are crystallized from mildly alkalic syenite and calc-alkalic granite. Zircons with increased Hf/Zr and Th/U ratios occur in all felsic-to-intermediate rock-types. If rock fragments are absent in the volcanic ejecta, the composition of the sub-volcanic reservoir can be reconstructed from the specific AMA and zircon xenocrysts–xenolith relics disintegrated during the basaltic magma fragmentation and explosion.
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Nelson, Demian A., John M. Cottle, and Blair Schoene. "Butcher Ridge igneous complex: A glassy layered silicic magma distribution center in the Ferrar large igneous province, Antarctica." GSA Bulletin 132, no. 5-6 (October 26, 2019): 1201–16. http://dx.doi.org/10.1130/b35340.1.
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Abstract The Butcher Ridge igneous complex, Antarctica, is an ∼6000 km3 hypabyssal silicic intrusion containing rhythmically layered glassy rocks. Baddeleyite U-Pb geochronologic analysis on a sample of the Butcher Ridge igneous complex yielded an age of ca. 182.4 Ma, which confirms that it was emplaced synchronously with the Ferrar large igneous province. Rocks of the Butcher Ridge igneous complex vary from basaltic andesite to rhyolite, and so the inferred volume of the Butcher Ridge igneous complex makes it the most voluminous silicic component of the Ferrar large igneous province. Major-element, trace-element, and isotopic data combined with binary mixing, assimilation-fractional crystallization (AFC), and energy-constrained AFC models are consistent with formation of Butcher Ridge igneous complex silicic rocks by contamination of mafic Ferrar parental magma(s) with local Paleozoic plutonic basement rocks. Field and petrographic observations and evidence for alkali ion exchange suggest that the kilometer-long, meter-thick enigmatic rhythmic layering formed as a result of secondary hydration and devitrification of volcanic glass along parallel fracture networks. The regularity and scale of fracturing/layering imply a thermally driven process that occurred during shallow emplacement and supercooling of the intrusion in the upper crust. We suggest that layering observed in the Butcher Ridge igneous complex is analogous to that reported from terrestrial and Martian cryptodomes, and therefore it is an ideal locality at which to study layering processes in igneous bodies.
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Noble, S. R., R. D. Tucker, and T. C. Pharaoh. "Lower Palaeozoic and Precambrian igneous rocks from eastern England, and their bearing on late Ordovician closure of the Tornquist Sea: constraints from U-Pb and Nd isotopes." Geological Magazine 130, no. 6 (November 1993): 835–46. http://dx.doi.org/10.1017/s0016756800023190.
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AbstractThe U-Pb isotope ages and Nd isotope characteristics of asuite of igneous rocks from the basement of eastern England show that Ordovician calc-alkaline igneous rocks are tectonically interleaved with late Precambrian volcanic rocks distinct from Precambrian rocks exposed in southern Britain. New U-Pb ages for the North Creake tuff (zircon, 449±13 Ma), Moorby Microgranite (zircon, 457 ± 20 Ma), and the Nuneaton lamprophyre (zircon and baddeleyite, 442 ± 3 Ma) confirm the presence ofan Ordovician magmatic arc. Tectonically interleaved Precambrian volcanic rocks within this arc are verified by new U-Pb zircon ages for tuffs at Glinton (612 ± 21 Ma) and Orton (616 ± 6 Ma). Initial εNd values for these basement rocks range from +4 to - 6, consistent with generation of both c. 615 Ma and c. 450 Ma groups of rocksin continental arc settings. The U-Pb and Sm-Nd isotope data support arguments for an Ordovician fold/thrust belt extending from England to Belgium, and that the Ordovician calc-alkaline rocks formed in response to subductionof Tornquist Sea oceanic crust beneath Avalonia.
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Pivarunas, Anthony F., and Joseph G. Meert. "Protracted magmatism and magnetization around the McClure Mountain alkaline igneous complex." Lithosphere 11, no. 5 (June 27, 2019): 590–602. http://dx.doi.org/10.1130/l1062.1.
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Abstract The McClure Mountain–Iron Mountain igneous complex is an alkalic intrusive center in the northern Wet Mountains of southern Colorado. It was emplaced in early Cambrian time into gneissic/granitic 1.75–1.45 Ga Proterozoic host rocks. Numerous dikes are associated with the complex, primarily along the western side. Although the main intrusive nepheline-syenite body is well dated, the ages of the surrounding dikes are poorly known. Crosscutting relationships and poorly defined K-Ar dates suggest that the dikes are younger than the main intrusion. Paleomagnetic samples were collected from dikes associated with the McClure Mountain igneous complex. Geochronologic samples were also collected from two dikes sampled for their paleomagnetism. We obtained U-Pb zircon ages of 526 ± 8 Ma for a lamprophyric extracomplex dike and 483 ± 2 Ma for a trachytic extracomplex dike. These ages suggest either multistage or protracted dike intrusion around the ca. 524 Ma McClure Mountain complex. Our paleomagnetic data are consistent with previously published results. Dikes of the complex primarily exhibit southeast and shallow paleomagnetic directions, with variable declinations. Results from several baked contact tests indicate that the magnetizations are secondary. A steeply inclined magnetization is pervasive and was acquired over a protracted interval from late Laramide time to the present day.
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Mollai, Habib, Georgia Pe-Piper, and Rahim Dabiri. "Genetic relationships between skarn ore deposits and magmatic activity in the Ahar region, Western Alborz, NW Iran." Geologica Carpathica 65, no. 3 (June 1, 2014): 209–27. http://dx.doi.org/10.2478/geoca-2014-0015.
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Abstract Paleocene to Oligocene tectonic processes in northwest Iran resulted in extensive I-type calc-alkaline and alkaline magmatic activity in the Ahar region. Numerous skarn deposits formed in the contact between Upper Cretaceous impure carbonate rocks and Oligocene-Miocene plutonic rocks. This study presents new field observations of skarns in the western Alborz range and is based on geochemistry of igneous rocks, mineralogy of the important skarn deposits, and electron microprobe analyses of skarn minerals. These data are used to interpret the metasomatism during sequential skarn formation and the geotectonic setting of the skarn ore deposit related igneous rocks. The skarns were classified into exoskarn, endoskarn and ore skarn. Andraditic garnet is the main skarn mineral; the pyroxene belongs to the diopside-hedenbergite series. The skarnification started with pluton emplacement and metamorphism of carbonate rocks followed by prograde metasomatism and the formation of anhydrous minerals like garnet and pyroxene. The next stage resulted in retro gradation of anhydrous minerals along with the formation of oxide minerals (magnetite and hematite) followed by the formation of hydrosilicate minerals like epidote, actinolite, chlorite, quartz, sericite and sulfide mineralization. In addition to Fe, Si and Mg, substantial amounts of Cu, along with volatile components such as H2S and CO2 were added to the skarn system. Skarn mineralogy and geochemistry of the igneous rocks indicate an island arc or subduction-related origin of the Fe-Cu skarn deposit.
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Lykhin, D. A., V. V. Yarmolyuk, and A. A. Vorontsov. "Age, composition and sources of rocks and ores of the Okunevskoe fluorite-leucophanite deposit, Western Sayan: assessment of the contribution of magmatism to ore mineralization." Геология рудных месторождений 61, no. 5 (November 18, 2019): 37–61. http://dx.doi.org/10.31857/s0016-777061537-61.
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The paper presents data on the structure of the Okunevskoe fluorite-Leucophanite deposit, located within the Early Paleozoic rare-metal East Sayan rare metal metallogenic zone. The deposit is controlled by alkali granitoids, with ore mineralization concentrated at the contact of granitoids and host carbonates. It is represented by leucophanite-fluorite and pyroxene-fluorite ore types. The Ar-Ar age of granitoids is established at ~485Ma. Geochemical characteristics of igneous rocks, ores, and host carbonates are determined. It is shown that in geochemical parameters leucophanite-fluorite ores are close to alkaline granites, while pyroxene-fluorite ores are close to alkaline syenites. The characteristics of the Nd isotop composition in rocks and ores of the deposit are given. Igneous rocks (granitoids and basite dikes) are characterized byNd (t) values from +4 to +5.5. TheNd (t) values in ores range from +1.2 to+4.2, in skarns itis +4.8. The host carbonates have abruptly contrasting valuesNd (t) = 4.2. Based on these data, which demonstrate a high compositional similarity between granitoids and ores, aconclusion is drawn about the leading contribution from magmatic processes to the ore mineralization of the Okunevskoe deposit.
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Phillips, E. R., R. P. Barnes, R. J. Merriman, and J. D. Floyd. "The tectonic significance of Ordovician basic igneous rocks in the Southern Uplands, southwest Scotland." Geological Magazine 132, no. 5 (September 1995): 549–56. http://dx.doi.org/10.1017/s001675680002121x.
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AbstractIn the northern part of the Southern Uplands, restricted volumes of basic igneous rocks occur at or near the base of the Ordovician sedimentary strata. These rocks have previously been interpreted as ocean-floor tholeiites representative of the subducted Iapetus oceanic plate, preserved as tectonic slivers in a fore-arc accretionary prism. The alternative, back-arc basin model proposed for the Southern Uplands on sedimentological evidence raises questions over the origin of these rocks. New geochemical data and previously published data clearly indicate that the volcanic material does not have a simple single source. The oldest (Arenig) volcanic rocks from the Moffat Shale Group associated with the Leadhills Fault include alkaline within-plate basalts and tholeiitic lavas which possibly display geochemical characteristics of midocean ridge basalts. In the northernmost occurrence, alkaline and tholeiitic basalts contained within the Caradoc Marchburn Formation are both of within-plate ocean island affinity. To the south, in the Gabsnout Burn area, the Moffat Shale Group contains lenticular bodies of dolerite and basalt which have characteristics of island-arc to transitional basalts. This complex association of basaltic volcanic rocks is, at the present time, difficult to reconcile with either a simple fore-arc or back-arc setting for the Southern Uplands. However, the increasing arc-related chemical influence on basic rock geochemistry towards the southeast may tentatively be used in support of a southern arc-terrane, and as a result, a back-arc situation for the Southern Uplands basin. An alternative is that these volcanic rocks may represent the local basement to the basin and include remnants of an arc precursor to the Southern Uplands basin.
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Roberts, R. J., F. Corfu, T. H. Torsvik, C. J. Hetherington, and L. D. Ashwal. "Age of alkaline rocks in the Seiland Igneous Province, Northern Norway." Journal of the Geological Society 167, no. 1 (January 2010): 71–81. http://dx.doi.org/10.1144/0016-76492009-014.
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Emeleus, C. H. "The Tertiary lavas and sediments of northwest Rhum, Inner Hebrides." Geological Magazine 122, no. 5 (September 1985): 419–37. http://dx.doi.org/10.1017/s0016756800035342.
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AbstractSeveral small outliers of Tertiary lavas and sediments rest with strong unconformity on a buried landscape eroded from Torridonian sediments and Tertiary granophyre. Erosion continued during the period of sediment and lava accumulation. Four formations are recognized; these are, in order of increasing age, the Orval Formation (hawaiite and basaltic hawaiite lavas), the Guirdil Formation (icelandite lavas, interbedded conglomerates), the Upper Fionchra Formation (tholeiitic basaltic andesite lavas, hyaloclastite deposits, basal conglomerate) and the Lower Fionchra Formation (alkali and transitional basalt, basaltic hawaiite and hawaiite lava flows, basal conglomerate); each is separated by an erosional interval. Clasts in the conglomerates reveal a history of erosion of a terrain exposing gneisses, Torridonian sediments, igneous rocks derived from the Rhum Tertiary Central Complex (including allivalites), and Tertiary lavas of local origin but also including, in the oldest conglomerates, tholeiitic basalts not now preserved on or near Rhum. Prior to and during lava and sediment accumulation, erosion on Rhum had cut down to a level similar to that of the present day, although not to the extent that high-grade thermally altered rocks, which are a marked feature of the Central Complex, were being eroded in any quantity. A sequence of east–west trending valleys, possibly initiated on the line of the earlier Main Ring Fault, drained the area of the Central Complex which then, as now, must have been high ground. Small lakes occasionally formed in the valleys allowing the accumulation of fine-grained sediment with plant remains, and promoting the formation of hyaloclastite deposits when buried by later flows. No source for any of the lava formations is preserved on Rhum; they are thought to have come from feeders north of Rhum, possibly near Canna, and to have ponded against the hills and valleys near and in the Central Complex.The oldest tholeiitic lavas, not now found in situ, were followed by alkali and transitional flows compositionally similar to the Skye Main Lava Series but characteristically feldsparphyric; the most mafic also contain phenocrysts of magnesian olivine (with included Cr-Al-rich spinels) and aluminous spinel. Both the early alkalic/transitional basalts and the youngest hawaiites and basaltic hawaiites equilibrated at pressures < 9 kb; the tholeiitic basaltic andesites and icelandites equilibrated at relatively shallows depths.Apart from a few N–S to NW–SE-trending basalt dykes, the lava formations represent the youngest Tertiary igneous event on Rhum.
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Young, Davis. "Origin of the American Quantitative Igneous Rock Classification: Part 4." Earth Sciences History 30, no. 1 (December 1, 2011): 1–38. http://dx.doi.org/10.17704/eshi.30.1.65q0ng14n572846u.
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After several failed attempts to construct a new chemico-mineralogical igneous rock classification on the basis of three or more factors, C. Whitman Cross, Joseph P. Iddings, Louis V. Pirsson, and Henry S. Washington decided to establish a practical and logically consistent scheme on the basis of only two factors, namely, two primary groups consisting of hypothetical minerals with ideal chemical compositions, the amounts of which were to be calculated from the chemical compositions of igneous rocks. One primary group consisted mainly of alkali alumina silicates and quartz (salic minerals), whereas the other consisted mainly of calcic ferromagnesian minerals (femic). A list of the amounts of these calculated standard minerals within an igneous rock was termed the norm, and the list of the proportions of actual minerals in a rock was termed its mode.In the Fall of 1901 the quartet decided to publish a preliminary paper that presented the major themes of their two-factor classification scheme. Iddings was charged with writing a draft of the scheme, and Washington was assigned the task of producing an essay on nomenclature to be published later. The team continually refined the definitions of specific subdivisions of the scheme proposed by Iddings as well as the corresponding nomenclature proposed by Washington. They also refined the norm calculation algorithm and developed methods for calculating the norm from the mode of rocks containing aluminous ferromagnesian minerals such as hornblende and biotite.After a few months of evaluating and revising a succession of drafts, the team eventually determined to publish their work of classification and nomenclature all at once by combining the refined drafts into one large comprehensive manuscript in three parts: Part I on classification, Part II on nomenclature, and Part III on methods of calculation. Iddings coordinated and edited the various criticisms and drafts contributed by team members into one large manuscript and shepherded the project to final publication in late October 1902 in Journal of Geology. The massive 139-page article entitled ‘A quantitative chemico-mineralogical classification and nomenclature of igneous rocks’ was preceded in earlier issues of the same journal by a two-part series authored by Cross on the historical development of systematic petrography. In early 1903, both of Cross's papers and the CIPW article were combined and published as a book, Quantitative Classification of Igneous Rocks.
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Pharaoh, T. C., T. S. Brewer, and P. C. Webb. "Subduction-related magmatism of late Ordovician age in eastern England." Geological Magazine 130, no. 5 (September 1993): 647–56. http://dx.doi.org/10.1017/s0016756800020951.
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AbstractDeep boreholes show that plutonic and volcanic igneous rocks comprise an important component of the Caledonian basement in eastern England. The isotopic compositions of these rocks reveal that many of them are of late Ordovician age (440–460 Ma), and their geochemical compositions suggest calc–alkaline affinities. The intermediate (diorite-tonalite) plutonic rocks are associated with a prominent northwest–southeast trending belt of aeromagnetic anomalies extending from Derby to St Ives, Hunts., which is interpreted to work the plutonic core of a calc-alkaline magmatic arc. It is inferred that this arc was generated by the subduction of oceanic lithosphere, possibly from the Tornquist Sea, in a south or southwest direction beneath the Midlands Microcraton in late Ordovician times. The age and geochemical composition of concealed Ordovician volcanic rocks in eastern England, and hypabyssal intrusions of the Midlands Minor Intrusive Suite in central England, is compatible with such a hypothesis.
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Liu, Guichun, Guangyan Chen, M. Santosh, Xin Qian, Zaibo Sun, Jian-Wei Zi, Tianyu Zhao, Qinglai Feng, and Shen Ma. "Tracking Prototethyan assembly felsic magmatic suites in southern Yunnan (SW China): evidence for an Early Ordovician–Early Silurian arc–back-arc system." Journal of the Geological Society 178, no. 4 (March 2, 2021): jgs2020–221. http://dx.doi.org/10.1144/jgs2020-221.
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Early Paleozoic trondhjemites, gneissic granites and alkali granites in southern Yunnan preserve important records of the tectonic evolution of the Prototethyan Ocean and regional correlations. Zircon ages suggest that these granitoids were emplaced from 476 to 436 Ma. The trondhjemites are characterized by high Na2O and low K2O contents, with εNd(t) values of −1.9 to −3.5 and εHf(t) values of −2.8 to +3.9. The trondhjemites were derived from an amphibolite source with a juvenile mafic component. The gneissic granites belong to the metaluminous low-K calc-alkaline series with an εNd(t) value of −6.2 and εHf(t) values of −5.0 to −0.4. The alkali granites belong to the high-K calc-alkaline series and yield εNd(t) values of −10.1 to −10.7 and εHf(t) values of −7.9 to −2.3. The gneissic granites were derived from an ‘ancient' lower mafic crust, whereas the alkali granites were derived from a meta-sedimentary source. These granitoids were formed during the subduction of the Prototethyan Ocean beneath the Simao Block and can be compared with similar igneous rocks from the Truong Son and Tam Ky-Phuoc Son zones in southern Laos. Our study, along with Early Paleozoic igneous suites from southern Laos, central Vietnam and the Malay Peninsula, suggests an arc–back-arc system along the northern margin of Gondwana.Supplementary material: Tables of zircon U–Pb and in-situ Hf and geochemical data are available at https://doi.org/10.6084/m9.figshare.c.5322386
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Holm, Paul Martin. "Radiometric age determinations in the Kærven area, Kangerdlugssuaq, Bast Greenland Tertiary igneous Province: 40Ar/39 Ar, Kl Ar and Rb/Sr isotopic results." Bulletin of the Geological Society of Denmark 38 (February 18, 1991): 183–201. http://dx.doi.org/10.37570/bgsd-1990-38-18.
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The Kærven syenite complex was emplaced as part of the magmatic activity related to continental rifling in the Paleogene. Radiometric age determinations have been carried out on samples from selected parts of the complex, which consists of more !han 10 significant units. Five amphiboles and two alkali feldspar have been analysed by the 40Arl'9Ar method with stepwise heating, five amphiboles and one biotite K/Ar analyses are presented together with Rb/Sr isotope analysis of 6 amphiboles, 2 biotites, 3 alkali feldspars and 32 whole rocks. The results reveal that a Iate, probably 36 Ma, thermal event caused Ar-loss in the alkali feldspars and excess 40Ar-gain in variable amounts in the analysed minerals. Also the Sr isotopes were disturbed by the secondary heating. Crystallisation ages for parts of the Kærven complex can be established as 58 ± 1 Ma, while other units have younger ages of 56.1 ± 0.8 Ma and 50.4 ± 0.8 Ma. The age for the early Kærven rocks is significantly older than other recorded syenites in the Kangerdlugssuaq area and is comparable only to the estimated age of the initiation of basaltic volcanism along the East Greenland coast at 57 Ma. An Rb/Sr isochron for four nordmarkite whole rocks and a 40Ar/39 Ar age plateau of an amphibole from one nordmarkite date the part of the Kangerdlugssuaq alkaline intrusion adjacent to the Kærven complex as 54.6 ± 2.4 Ma. This is older than other parts of the Kangerdlugssuaq intrusion, and indicate that this intrusion was multiple and emplaced over several million years
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SU, YUPING, JIANPING ZHENG, LILI LIANG, HONGKUN DAI, JUNHONG ZHAO, MING CHEN, XIANQUAN PING, ZIQI LIU, and JIAN WANG. "Derivation of A1-type granites by partial melting of newly underplated rocks related with the Tarim mantle plume." Geological Magazine 156, no. 3 (November 20, 2017): 409–29. http://dx.doi.org/10.1017/s0016756817000838.
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AbstractThe granitic rocks of the Tarim large igneous province (LIP) are temporally and spatially related to mafic intrusions. However, their tectonic setting and genetic relationship are debated. Here, we report geochemical, and zircon U–Pb–Hf isotopic results for three alkali feldspar granitic plutons in the Halajun area, western margin of the Tarim Block. Zircon U–Pb ages suggest these plutons were emplaced at 268–275 Ma, coeval with the neighbouring mafic–ultramafic complexes and syenitic rocks. These granitic rocks have high contents of SiO2, alkalis, Rb, Th, Zr and REE (except Eu), and high ratios of FeO*/MgO and Ga/Al, and show strong depletions in Ba, Sr, Eu, which are commonly observed in the A1-type granites. Zircon Hf isotopes reveal a limited range ofεHf(t) values from −1.0 to +3.5 for different samples from three granitic plutons, obviously higher than those (mostly <0) of the mafic rocks. This distinct difference, along with a Daly gap and small volume of mafic rocks, argues against extreme fractionation of mafic magma as the main origin of the A1-type granites. Instead the A1-type granites were most likely derived from partial melting of newly underplated rocks triggered by the upwelling asthenosphere, followed by extensive fractionation. These A1-type granites were emplaced within an anorogenic setting during the late stage of the Tarim LIP, which possibly lasts for more than 30 Ma. The Piqiang mafic–ultramafic complex directly stemmed from asthenospheric mantle and Halajun A1-type granites represent two manners of vertical crustal growth.
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Li, Yan, Feng-Jun Nie, and Zhao-Bin Yan. "Age and Geochemistry of Late Jurassic Mafic Volcanic Rocks in the Northwestern Erguna Block, Northeast China." Minerals 11, no. 9 (September 17, 2021): 1010. http://dx.doi.org/10.3390/min11091010.
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The northwestern Erguna Block, where a wide range of volcanic rocks are present, provides one of the foremost locations to investigate Mesozoic Paleo-Pacific and Mongol-Okhotsk subduction. The identification and study of Late Jurassic mafic volcanic rocks in the Badaguan area of northwestern Erguna is of particular significance for the investigation of volcanic magma sources and their compositional evolution. Detailed petrological, geochemical, and zircon U-Pb dating suggests that the Late Jurassic mafic volcanic rocks formed at 157–161 Ma. Furthermore, the geochemical signatures of these mafic volcanic rocks indicate that they are calc-alkaline or transitional series with weak peraluminous characteristics. The rocks have a strong MgO, Al2O3, and total alkali content, and a SiO2 content of 53.55–63.68 wt %; they are enriched in Rb, Th, U, K, and light rare-earth elements (LREE), and depleted in high-field-strength elements (HFSE), similar to igneous rocks in subduction zones. These characteristics indicate that the Late Jurassic mafic volcanic rocks in the Badaguan area may be derived from the partial melting of the lithospheric mantle as it was metasomatized by subduction-related fluid and the possible incorporation of some subducting sediments. Subsequently, the fractional crystallization of Fe and Ti oxides occurred during magmatic evolution. Combined with the regional geological data, it is inferred that the studied mafic volcanic rocks were formed by lithospheric extension after the closure of the Mongol-Okhotsk Ocean.
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Barr, S. M., C. E. White, N. G. Culshaw, and J. WF Ketchum. "Geology and tectonic setting of Paleoproterozoic granitoid suites in the Island Harbour Bay area, Makkovik Province, Labrador." Canadian Journal of Earth Sciences 38, no. 3 (March 1, 2001): 441–63. http://dx.doi.org/10.1139/e00-086.
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Paleoproterozoic granitoid rocks in the Island Harbour Bay area (Kaipokok domain, Makkovik Province, Labrador) are divided into four separate suites on the basis of field relations, petrology, and age. The redefined Island Harbour Bay plutonic suite consists of ca. 18951870 Ma dioritic to granitic (mainly granodioritic and granitic) units. The rocks are variably foliated as a result of emplacement under amphibolite-facies conditions in a dextral transpressive regime during Andean-type subduction. The dominant mafic mineral is biotite, and accessory epidote, allanite, and titanite are abundant. The suite is calc-alkalic, but with rare-earth element patterns similar to those of Archean tonalitictrondhjemiticgranodioritic suites. It is interpreted to have formed deep in an Andean-type magmatic arc at the margin of the Nain continent. In contrast, the younger Hares Islands and Drunken Harbour granites (emplaced at ca. 1805 and 1790 Ma, respectively) were part of widespread late-orogenic magmatic activity in the Makkovik Province. In contrast to the Island Harbour Bay plutonic suite, these units retain igneous textures and are either unfoliated or display magmatic foliation, locally modified by emplacement in active shear zones. The ca. 1716 Ma Blacklers Bight granite varies from porphyritic to equigranular, is fluorite-bearing, and has chemical features approaching those of continental A-type granites. Similar granite occurs farther south in the Makkovik Province, reflecting widespread anorogenic magmatic activity at that time, perhaps related to mafic magma underplating. Variable interaction with Archean (Nain Province) crust by granitic magmas of all three ages is evidenced by εNd values ranging from 7.2 to 2.5.
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Bevins, R. E., G. J. Lees, and R. A. Roacht. "Petrogenesis of Ordovician igneous rocks in the southern part of the Welsh Basin." Geological Magazine 129, no. 5 (September 1992): 615–24. http://dx.doi.org/10.1017/s0016756800021786.
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AbstractDuring early Ordovician times volcanic and high-level intrusive activity occurred at numerous centres across North Pembrokeshire. Previous work suggested a geochemical transition in this activity from calcalkaline through to tholeiitic with time. However, new data indicate more extensive calc-alkaline magmatism and that both magma types were coeval. The origin of the calcalkaline magmas remains equivocal, but the tholeiitic magmas appear to have been derived from a source similar to N-type MORB, variably modified by supra-subduction zone fluids, combined with some fractionation during ascent. These data are consistent with emplacement in a supra-subduction zone marginal basin.
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GRENNE, T., R. B. PEDERSEN, T. BJERKGÅRD, A. BRAATHEN, M. G. SELASSIE, and T. WORKU. "Neoproterozoic evolution of Western Ethiopia: igneous geochemistry, isotope systematics and U–Pb ages." Geological Magazine 140, no. 4 (July 2003): 373–95. http://dx.doi.org/10.1017/s001675680300801x.
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New geochemical, isotopic and age data from igneous rocks complement earlier models of a long-lived and complex accretionary history for East African Orogen lithologies north of the Blue Nile in western Ethiopia, but throw doubt on the paradigm that ultramafic complexes of the region represent ophiolites and suture zones. Early magmatism is represented by a metavolcanic sequence dominated by pyroclastic deposits of predominantly basaltic andesite composition, which give a Rb–Sr whole-rock errorchron of 873±82 Ma. Steep REE patterns and strong enrichments of highly incompatible trace elements are similar to Andean-type, high-K to medium-K calc-alkaline rocks; εNd values between 4.0 and 6.8 reflect a young, thin continental edge. Interlayered basaltic flows are transitional to MORB and compare with mafic rocks formed in extensional, back-arc or inter-arc regimes. The data point to the significance of continental margin magmatism already at the earliest stages of plate convergence, in contrast with previous models for the East African Orogen. The metavolcanites overlap compositionally with the Kilaj intrusive complex dated at 866±20 Ma (U–Pb zircon) and a related suite of dykes that intrude thick carbonate-psammite sequences of supposedly pre-arc, continental shelf origin. Ultramafic complexes are akin to the Kilaj intrusion and the sediment-hosted dykes, and probably represent solitary intrusions formed in response to arc extension. Synkinematic composite plutons give crystallization ages of 699±2 Ma (Duksi, U–Pb zircon) and 651±5 Ma (Dogi, U–Pb titanite) and testify to a prolonged period of major (D1) contractional deformation during continental collision and closure of the ‘Mozambique Ocean’. The plutons are characterized by moderately peraluminous granodiorites and granites with εNd values of 1.0–2.0. They were coeval with shoshonitic, latitic, trachytic and rare trachybasaltic intrusions with very strong enrichments of highly incompatible trace elements and εNd of 0.4–8.0. The mafic end-member is ascribed to partial melting of enriched sub-continental mantle that carried a subduction component inherited from pre-collision subduction. Contemporaneous granodiorite and granite formation was related to crustal underplating of the mafic magmas and consequent melting of lower crustal material derived from the previously accreted, juvenile arc terranes of the East African Orogen.
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Wahlgren, Carl-Henric, and Michael B. Stephens. "Chapter 7 Småland lithotectonic unit dominated by Paleoproterozoic (1.8 Ga) syn-orogenic magmatism, Svecokarelian orogen." Geological Society, London, Memoirs 50, no. 1 (2020): 207–35. http://dx.doi.org/10.1144/m50-2017-19.
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AbstractThe Småland lithotectonic unit in the 2.0−1.8 Ga Svecokarelian orogen, southeastern Sweden, is dominated by a c. 1.81−1.77 Ga alkali–calcic magmatic suite (the Transscandinavian Igneous Belt or TIB-1). At least in its central part, the TIB-1 suite was deposited on, or emplaced into, c. 1.83–1.82 Ga calc-alkaline magmatic rocks with base metal sulphide mineralization and siliciclastic sedimentary rocks (the Oskarshamn–Jönköping Belt). Ductile deformation and metamorphism under low- to medium-grade conditions affected the Oskarshamn–Jönköping Belt prior to c. 1.81 Ga. Both suites were subsequently affected by low-grade ductile deformation, mainly along steeply dipping, east–west to NW–SE shear zones with dip-slip and dextral strike-slip displacement. Sinistral strike-slip NE–SW zones are also present. In the northern part of the lithotectonic unit, 1.9 Ga magmatic rocks, c. 1.87–1.81 Ga siliciclastic sedimentary rocks and basalt, and c. 1.86–1.85 Ga granite show fabric development, folding along steep NW–SE axial surfaces and medium- or high-grade metamorphism prior to c. 1.81 Ga and, at least partly, at c. 1.86–1.85 Ga; base metal sulphide, Fe oxide and U or U–REE mineralizations also occur. Magmatism and siliciclastic sedimentation along an active continental margin associated with subduction-related, accretionary tectonic processes is inferred over about 100 million years.
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Szopa, Krzysztof, Roman Włodyka, and David Chew. "LA-ICP-MS U-Pb apatite dating of Lower Cretaceous rocks from teschenite-picrite association in the Silesian Unit (southern Poland)." Geologica Carpathica 65, no. 4 (August 1, 2014): 273–84. http://dx.doi.org/10.2478/geoca-2014-0018.
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Abstract The main products of volcanic activity in the teschenite-picrite association (TPA) are shallow, sub-volcanic intrusions, which predominate over extrusive volcanic rocks. They comprise a wide range of intrusive rocks which fall into two main groups: alkaline (teschenite, picrite, syenite, lamprophyre) and subalkaline (dolerite). Previous 40Ar/39Ar and 40K/40Ar dating of these rocks in the Polish Outer Western Carpathians, performed on kaersutite, sub-silicic diopside, phlogopite/biotite as well as on whole rock samples has yielded Early Cretaceous ages. Fluorapatite crystals were dated by the U-Pb LA-ICP-MS method to obtain the age of selected magmatic rocks (teschenite, lamprophyre) from the Cieszyn igneous province. Apatite-bearing samples from Boguszowice, Puńców and Lipowa yield U-Pb ages of 103± 20 Ma, 119.6 ± 3.2 Ma and 126.5 ± 8.8 Ma, respectively. The weighted average age for all three samples is 117.8 ± 7.3 Ma (MSWD = 2.7). The considerably smaller dispersion in the apatite ages compared to the published amphibole and biotite ages is probably caused by the U-Pb system in apatite being less susceptible to the effects of hydrothermal alternation than the 40Ar/39Ar or 40K/40Ar system in amphibole and/or biotite. Available data suggest that volcanic activity in the Silesian Basin took place from 128 to 103 Ma with the the main magmatic phase constrained to 128-120 Ma.
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Milner, Simon C., Anton P. Le Roex, and Ronald T. Watkins. "Rb-Sr age determinations of rocks from the Okenyenya igneous complex, northwestern Namibia." Geological Magazine 130, no. 3 (May 1993): 335–43. http://dx.doi.org/10.1017/s001675680002001x.
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AbstractThe Okenyenya igneous complex is one of a suite of intrusions which define a prominent northeast-trending linear feature in Damaraland, northwestern Namibia. Precise Rb–Sr internal isochron ages range from 128.6 ± 1 to 123.4 ± 1.4 Ma for the major phases of intrusion identified within the complex. The tholeiitic gabbros forming the outer rings of the complex, and the later alkali gabbros which form the central hills, cannot be distinguished in terms of Rb–Sr ages, although field relations clearly indicate the younger age of the latter. The intrusionsof nepheline-syenite and essexite comprising the mountain of Okenyenya Bergon the northern edge of the complex give ages of 123.4 ± 1.4 and 126.3 ± 1 Ma, respectively, and form the final major phase of intrusion. The ages obtained for early and late intrusive phases define a minimum magmatic ‘life-span’ of approximately 5 Ma for the complex. The determined age of the Okenyenya igneous complex (129–123 Ma), when taken together with the few reliable published ages for other Damaraland complexes (130–134 Ma), suggests that these sub-volcanic complexes were emplaced contemporaneously with the widespread Etendeka volcanics (˜ 130 Ma), and relate to magmatism associated with the breakup of southern Africa and South America with the opening of the South Atlantic Ocean. The linear distributionof intrusions in Damaraland is interpreted to be due to magmatism resultingfrom the upwelling Tristan plume being focused along a structural discontinuity between the Pan-African, Damaran terrain to the south, and Proterozoiccratonic basement to the north.
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Jing, Jia-Hao, Hao Yang, Wen-Chun Ge, Yu Dong, Zheng Ji, Yan Jing, Jun-Hui Bi, and Hong-Ying Zhou. "Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China." Geological Magazine 158, no. 9 (March 24, 2021): 1617–38. http://dx.doi.org/10.1017/s0016756821000170.
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AbstractLate Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.
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Mbissik, Aaron, Abdellatif Elghali, Muhammad Ouabid, Otmane Raji, Jean-Louis Bodinier, and Hicham El Messbahi. "Alkali-Hydrothermal Treatment of K-Rich Igneous Rocks for Their Direct Use as Potassic Fertilizers." Minerals 11, no. 2 (January 30, 2021): 140. http://dx.doi.org/10.3390/min11020140.
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Due to the increasing demand for conventional sources of potassium (K) and their inaccessibility by African countries, K-rich igneous rocks are increasingly studied as potential alternative sources. In this study, six potassic igneous rocks (syenites and trachytes) from the Tamazeght, Jbel Boho, Ait Saoun, and El Glo’a regions (Morocco) were sampled and characterized. Then they were hydrothermally treated to enhance their K release for potential use as potassic fertilizers. The raw materials are mainly formed by microcline (up to 74%), orthoclase (20–68%), albite (36–57%), biotite-muscovite (15–23%), and titanite, calcite, hematite, and apatite as accessory minerals. These samples were crushed and milled to reach a particle size <150 µm and mixed with 4 N NaOH solution in an autoclave. The liquid/solid (L/S) ratio was about 44 mL/50 g. The powders were allowed to react with the solution at 170 °C for 7 h. For all tests, NaOH reacted completely with the powders and no liquid was observed after the treatment. X-ray diffraction (XRD), thermal gravimetric analysis (TGA), infrared spectroscopy (IRTF), and scanning electron microscopy (SEM-EDS) were carried out on treated samples to characterize the mineralogical and structural changes due to the alkali-hydrothermal treatment. Indeed, the treated samples revealed the presence of sodic neoformed phases such as thermonatrite, sodalite, analcime, and cancrinite. The treated material was leached for a week using deionized water and the elements released were measured using inductively coupled plasma–atomic emission spectroscopy (ICP-AES). The hydrothermal process showed a strong effect on structure breakdown as well as on the release of K and other nutrients such as P, Fe, Si, Mg, and Ca. Therefore, the alkali-hydrothermal treatment allowed the release of 50.5 wt% K. Moreover, the release of Mg, Ca, Fe, P, K, and Si were significantly increased. Mg, Ca, Fe, P, K, and Si release within raw materials was about (0.5–3.6), (3.5–31.4), (0.01–0.4), (0.01–0.3), (20–55), and (4.6–8) mg/kg, respectively, whereas treated samples showed a higher release of these elements. Quantitatively, Mg, Ca, Fe, P, K, and Si releases were about (10–11.8), (60–70), (7–20), (1.2–15), (218–1278), and (1119–2759) mg/kg, respectively. Consequently, the treated igneous rocks (syenite and trachyte) could be directly used as potassic fertilizers that would also be a source of other nutrients.
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Ripa, Magnus, and Michael B. Stephens. "Chapter 9 Continental magmatic arc and siliciclastic sedimentation in the far-field part of a 1.7 Ga accretionary orogen." Geological Society, London, Memoirs 50, no. 1 (2020): 253–68. http://dx.doi.org/10.1144/m50-2017-3.
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AbstractTrachyandesitic to trachybasaltic lavas, interlayered siliciclastic sedimentary rocks and subaerial ignimbrites with a rhyolitic to trachydacitic composition lie unconformably above metamorphic rocks in west-central Sweden. These volcanic rocks erupted at 1711 + 7/−6 to 1691 ± 5 Ma and belong to a high-K, calc-alkaline to shoshonitic suite deposited in a continental arc setting. Positive ɛNd values and Nb/Yb ratios in the trachyandesitic to trachybasaltic rocks indicate an enriched mantle source. Coeval, 1710 ± 11 to 1681 ± 16 Ma plutonic and subvolcanic rocks are mainly granitic or quartz syenitic in composition. Subordinate components include quartz monzonite, quartz monzodiorite and monzogabbro or gabbro. ɛNd values in the range −1.0 to + 1.1 overlap with those in the inferred 1.9–1.8 Ga source rocks. All these rocks belong to the youngest phase of the lithodemic unit referred to as the Transscandinavian Igneous Belt. This magmatic province extends in a roughly NNW direction for at least 900 km, variably deformed and metamorphosed equivalents occurring inside and beneath younger orogenic belts to the south (Sveconorwegian) and north (Caledonian). The part of the province in west-central Sweden addressed here represents a far-field and shallow crustal component in this 1.7 Ga accretionary orogenic system.
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Lopes, Rosana Peporine, and Mabel Norma Costas Ulbrich. "Geochemistry of the alkaline volcanicsubvolcanic rocks of the Fernando de Noronha Archipelago, southern Atlantic Ocean." Brazilian Journal of Geology 45, no. 2 (June 2015): 307–33. http://dx.doi.org/10.1590/23174889201500020009.
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<p>The Fernando de Noronha Archipelago presents, on its main island, a centrally-located stratigraphic unit, the Remédios Formation (age around 8 - 12 Ma) constituted by basal pyroclastic rocks intruded by dikes, plugs and domes of varied igneous rocks, capped by flows and pyroclastics of mafic to ultramafic rocks of the Quixaba Formation (age around 1 - 3 Ma), which is limited from the underlying unit by an extensive irregular erosion surface. A predominant sodic Remédios series (basanites, tephrites, tephriphonolites, essexite, phonolites) can be separated from a moderately potassic Remédios sequence (alkali basalts, trachyandesites, trachytes), both alkaline series showing mostly continuous geochemical trends in variation diagrams for major as well as trace elements, indicating evolution by crystal fractionation (mainly, separation of mafic minerals, including apatites and titanites). There are textural and mineralogical evidences pointing to hybrid origin of some intermediate rocks (e.g., resorbed pyroxene phenocrysts in basaltic trachyandesites, and in some lamprophyres). The primitive Quixaba rocks are mostly melanephelinites and basanites, primitive undersaturated sodic types. Geology (erosion surface), stratigraphy (two distinct units separated by a large time interval), petrography (varied Remédios Formation, more uniform Quixaba unit) and geochemistry indicate that the islands represent the activity of a protracted volcanic episode, fueled by intermittent melting of an enriched mantle, not related to asthenospheric plume activity.</p>
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Pourkhorsandi, Hamed, Hassan Mirnejad, Davoud Raiesi, and Jamshid Hassanzadeh. "Crystal size and shape distribution systematics of plagioclase and the determination of crystal residence times in the micromonzogabbros of Qisir Dagh, SE of Sabalan volcano (NW Iran)." Geologica Carpathica 66, no. 4 (August 1, 2015): 257–68. http://dx.doi.org/10.1515/geoca-2015-0024.
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AbstractThe Qisir Dagh igneous complex occurs as a combination of volcanic and intrusive rocks to the south-east of the Sabalan volcano, north-western Iran. Micromonzogabbroic rocks in the region consist of plagioclase, alkaline feldspar and clinopyroxene as the major mineral phases and orthopyroxene, olivine, apatite and opaque minerals as the accessory minerals. Microgranular and microporphyritic textures are well developed in these rocks. Considering the importance of plagioclase in reconstructing magma cooling processes, the size and shape distribution and chemical composition of this mineral were investigated. Based on microscopic studies, it is shown that the 2-dimensional size average of plagioclase in the micromonzogabbros is 538 micrometers and its 3-dimensional shape varies between tabular to prolate. Crystal size distribution diagrams point to the presence of at least two populations of plagioclase, indicating the occurrence of magma mixing and/or fractional crystallization during magma cooling. The chemical composition of plagioclase shows a wide variation in abundances of Anorthite-Albite-Orthoclase (An=0.31–64.58, Ab=29.26–72.13, Or=0.9–66.97), suggesting a complex process during the crystal growth. This is also supported by the formation of antiperthite lamellae, which formed as the result of alkali feldspar exsolution in plagioclase. The calculated residence time of magma in Qisir Dagh, based on 3D crystal size distribution data, and using growth rate G=10−10mm/s, varies between 457 and 685 years, which indicates a shallow depth (near surface) magma crystallization and subvolcanic nature of the studied samples.
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Cuney, Michel. "Felsic magmatism and uranium deposits." Bulletin de la Société Géologique de France 185, no. 2 (February 1, 2014): 75–92. http://dx.doi.org/10.2113/gssgfbull.185.2.75.
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Abstract The strongly incompatible behaviour of uranium in silicate magmas results in its concentration in the most felsic melts and a prevalence of granites and rhyolites as primary U sources for the formation of U deposits. Despite its incompatible behavior, U deposits resulting directly from magmatic processes are quite rare. In most deposits, U is mobilized by hydrothermal fluids or ground water well after the emplacement of the igneous rocks. Of the broad range of granite types, only a few have U contents and physico-chemical properties that permit the crystallization of accessory minerals from which uranium can be leached for the formation of U deposits. The first granites on Earth, which crystallized uraninite, dated at 3.1 Ga, are the potassic granites from the Kaapval craton (South Africa) which were also the source of the detrital uraninite for the Dominion Reef and Witwatersrand quartz pebble conglomerate deposits. Four types of granites or rhyolites can be sufficiently enriched in U to represent a significant source for the genesis of U deposits: peralkaline, high-K metaluminous calc-alkaline, L-type peraluminous and anatectic pegmatoids. L-type peraluminous plutonic rocks in which U is dominantly hosted in uraninite or in the glass of their volcanic equivalents represent the best U source. Peralkaline granites or syenites are associated with the only magmatic U-deposits formed by extreme fractional crystallization. The refractory character of the U-bearing minerals does not permit their extraction under the present economic conditions and make them unfavorable U sources for other deposit types. By contrast, felsic peralkaline volcanic rocks, in which U is dominantly hosted in the glassy matrix, represent an excellent source for many deposit types. High-K calc-alkaline plutonic rocks only represent a significant U source when the U-bearing accessory minerals (U-thorite, allanite, Nb oxides) become metamict. The volcanic rocks of the same geochemistry may be also a favorable uranium source if a large part of the U is hosted in the glassy matrix. The largest U deposit in the world, Olympic Dam in South Australia is hosted by highly fractionated high-K plutonic and volcanic rocks, but the origin of the U mineralization is still unclear. Anatectic pegmatoids containing disseminated uraninite which results from the partial melting of uranium-rich metasediments and/or metavolcanic felsic rocks, host large low grade U deposits such as the Rössing and Husab deposits in Namibia. The evaluation of the potentiality for igneous rocks to represent an efficient U source represents a critical step to consider during the early stages of exploration for most U deposit types. In particular a wider use of the magmatic inclusions to determine the parent magma chemistry and its U content is of utmost interest to evaluate the U source potential of sedimentary basins that contain felsic volcanic acidic tuffs.
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Lynas, B. D. T., C. C. Rundle, and R. W. Sanderson. "A note on the age and pyroxene chemistry of the igneous rocks of the Shelve Inlier, Welsh Borderland." Geological Magazine 122, no. 6 (November 1985): 641–47. http://dx.doi.org/10.1017/s0016756800032040.
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AbstractGeological survey, electron microprobe analyses of clinopyroxenes and isotopic age determinations have revealed that the intrusive dolerites and basic–intermediate lavas of the Shelve Ordovician Inlier are part of a co-magmatic suite which show transitional affinities between tholeiites and alkali basalts. The ages of most of the intrusives are shown to be mid-Ordovician.
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PE-PIPER, GEORGIA, and DAVID J. W. PIPER. "Late Cenozoic, post-collisional Aegean igneous rocks: Nd, Pb and Sr isotopic constraints on petrogenetic and tectonic models." Geological Magazine 138, no. 6 (November 2001): 653–68. http://dx.doi.org/10.1017/s0016756801005957.
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Nd isotopic composition has been determined for 16 igneous rocks, representing the wide geochemical, spatial and temporal range of post-collisional, late Cenozoic magmas in the Aegean area. Nd isotopes are used to further interpret previously published Pb and Sr isotope data. The overall pattern of late Cenozoic volcanism resulted from rapid extension, with thermal effects causing melting of hydrated, enriched, subcontinental lithosphere to produce widespread K-rich magmas. Slab break-off and intrusion of hot asthenosphere caused partial melting of rift-related continental margin basalts at the detachment point to generate adakitic magmas. Further outboard, mafic magma from enriched lithospheric mantle melted thickened lower crust to produce the granitoid plutons of the Cyclades. Nd isotopic variation in these varied rock types correlates with pre-Cenozoic palaeo-geography. Proterozoic subduction-related enrichment in Th and U, together with other large-ion lithophile elements, produced distinctive Pb isotope composition. This was later modified where Mesozoic subduction of terrigenous sediment was important, whereas subduction of oceanic carbonate sediments produced enrichment in radiogenic Sr and low Ce/Sr ratios. Late Cenozoic magmas sourced in eastern Pelagonian zone sub-continental lithospheric mantle have Nd model ages of about 1.0 Ga, and generally high 87Sr/86Sr and high 207Pb/204Pb (∼ 15.68) and 208Pb/204Pb (∼ 39.0) for low 206Pb/204Pb (∼ 18.6), but rocks to the west have more radiogenic Pb and higher Ce/Sr as a result of greater subduction of terrigenous sediment from the northern Pindos ocean. Magmas sourced from sub-continental lithosphere beneath the Apulian continental block were strongly influenced by subduction of oceanic crust and sediments north of the passive margin of north Africa. Subduction of Nile-derived terrigenous sediment in the east resulted in Nd model ages of 0.7 to 0.8 Ga and radiogenic Pb isotopes. Greater subduction of oceanic carbonate in the west resulted in magmas with higher 87Sr/86Sr and lower Ce/Sr. The strongly negative εNd for adakites in the central Aegean rules out a source from subducted oceanic basalt, and the adakite magma was probably derived from melting of hydrated Triassic sub-alkaline basalt of continental origin. Where trachytic rocks are succeeded by nepheline-normative basalts (e.g. Samos), Nd isotope data imply that early partial melting of the enriched subcontinental lithospheric mantle involved hydrous amphibole and phlogopite, but once these minerals were consumed, younger magmas were produced by partial melting dominated by olivine and orthopyroxene.
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Snachev, Vladimir I., Aleksandr V. Snachev, and Boris A. Puzhakov. "Geology, physical-chemical and geodynamic conditions for the formation of Sokolovsk and Krasnokamensk granitoid massifs (South Ural)." Georesursy 23, no. 1 (March 30, 2021): 85–93. http://dx.doi.org/10.18599/grs.2021.1.9.
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The article describes the geological structure of the Sokolovsk and Krasnokamensk massifs located in the central part of the Western subzone of the Chelyabinsk-Adamovka zone of the Southern Urals. They are of Lower Carboniferous age and break through the volcanogenic-sedimentary deposits of the Krasnokamensk (D3kr) and Bulatovo (S1-D1bl) strata. It was found that these intrusions belong to the gabbro-syenite complex and are composed of gabbroids (phase I) and syenites, quartz monzonites, less often monzodiorites (phase II). The rocks of the second phase predominate (90–95%). Gabbros belong to the normal alkaline series of the sodium series and are close to tholeiitic mafic rocks, the formation of which is associated with riftogenic structures; syenites correspond to moderately alkaline series with K-Na type of alkalinity. It has been proved that in terms of their petrographic, petrochemical, geochemical, and metallogenic features (content of TiO2, K2O, Na2O, Rb, Sr, distribution of REE, the presence of skarn-magnetic mineralization), the rocks of the massifs under consideration undoubtedly belong to the gabbro-granite formation. Crystallization of the Sokolovsk and Krasnokamensk intrusions occurred at a temperature of 880–930 °С in the mesoabyssal zone at a depth of about 7–8 km (P = 2.2–2.4 kbar). At the postmagmatic stage, the transformation parameters of the initially igneous rocks were, respectively, T = 730–770 °C, P = 4.0–4.2 kbar. The fact that these massifs belong to the gabbro-granite formation makes it possible to include them, together with Bolshakovsk, Klyuchevsky, Kurtmaksky and Kambulatovo, into the Chelyabinsk-Adamovka segment of the South Ural Early Carboniferous rift system.
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Zhong, Yuting, Roland Mundil, Jun Chen, Dongxun Yuan, Steven W. Denyszyn, Adam B. Jost, Jonathan L. Payne, Bin He, Shuzhong Shen, and Yigang Xu. "Geochemical, biostratigraphic, and high-resolution geochronological constraints on the waning stage of Emeishan Large Igneous Province." GSA Bulletin 132, no. 9-10 (February 3, 2020): 1969–86. http://dx.doi.org/10.1130/b35464.1.
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Abstract The initiation and peak magmatic periods of the Emeishan Large Igneous Province (LIP) are well constrained by both biostratigraphic and radioisotopic dating methods; however, the age of cessation of volcanism is poorly constrained and continues to be debated. Marine carbonates interbedded with volcanic ashes across the Guadalupian–Lopingian boundary (GLB) are widespread in south China, and these ashes provide an opportunity to study its timing, origin, and potential relationship with the Emeishan LIP. Here we present biostratigraphic constraints, mineralogical and geochemical characteristics, and high-resolution geochronology of ash layers from the Maoershan and Chaotian sections. Stratigraphic correlation, especially conodont biostratigraphy, confines these ashes to the early Wuchiapingian. Those altered ashes are geochemically akin to alkali tonsteins from the coal seams of the lower Xuanwei/Lungtan Formation in southwest China. The ashes postdating the GLB yield a coherent cluster of zircon U-Pb ages with weighted mean 206Pb/238U ages of 258.82 ± 0.61 Ma to 257.39 ± 0.68 Ma, in agreement with the ages of intrusive rocks (259.6 ± 0.5 Ma to 257.6 ± 0.5 Ma) in the central Emeishan LIP. Moreover, the ɛHf(t) values of zircons from the ashes vary from +2.5 to +10.6, a range consistent with that of the Emeishan LIP. The results collectively suggest that the early Wuchiapingian volcanic ashes are a product of extrusive alkaline magmatism and most likely mark the waning stage of the Emeishan volcanism, which may have continued until ca. 257.4 Ma in the early Wuchiapingian.
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Brueckner, Stefanie M., Gregory Johnson, Stephanie Wafforn, Harold Gibson, Ross Sherlock, Christina Anstey, and Ken McNaughton. "Potential for Volcanogenic Massive Sulfide Mineralization at the A6 Anomaly, North-West British Columbia, Canada: Stratigraphy, Lithogeochemistry, and Alteration Mineralogy and Chemistry." Minerals 11, no. 8 (August 11, 2021): 867. http://dx.doi.org/10.3390/min11080867.
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The Middle Jurassic A6 Anomaly is located 30 km southeast of Eskay Creek, north-central British Columbia and consists of thick, altered felsic igneous rocks overlain by a mafic volcano-sedimentary package. Lithogeochemistry on igneous rocks, X-ray diffraction on altered felsic units, and electron probe microanalysis and secondary ion mass spectrometry on illite and quartz were applied to explore the volcanogenic massive sulfide (VMS) potential, characterize alteration, and determine fluid conditions at the A6 Anomaly. Lithogeochemistry revealed calc-alkaline rhyodacite to trachyte of predominantly FII type, tholeiitic basalts with Nb/Yb < 1.6 (i.e., Group A), and transitional to calc-alkaline basalts and andesites with Nb/Yb > 2.2 (i.e., Group B). The felsic units showed weakly to moderately phyllic alteration (quartz–illite with minor orthoclase and trace chlorite–pyrite–calcite–barite–rutile). Illite ranged in composition from illite/smectite (K = 0.5–0.69 apfu) to almost endmember illite (K = 0.69–0.8 apfu), and formed from feldspar destruction by mildly acidic, relatively low temperature, oxidized hydrothermal fluids. The average δ18O composition was 10.7 ± 3.0‰ and 13.4 ± 1.3‰ relative to Vienna Standard Mean Ocean Water for illite and quartz, respectively. Geothermometry involving illite composition and oxygen isotope composition on illite and quartz yielded average fluid temperatures of predominantly 200–250 °C. Lithogeochemical results showed that the A6 Anomaly occurred in a late-Early to Middle Jurassic evolving back-arc basin, further east then previously recognized and in which transitional to calc-alkaline units formed by crustal assimilation to enriched Mid-Ocean Ridge Basalt (EMORB) (i.e., felsic units, Group B), followed by thinning of the crust resulting in tholeiitic normalized MORB basalts (i.e., Group A) with a minor crustal component. The alteration assemblage is representative of distal footwall alteration, and metal transport in this zone was limited despite favorable temperature, pH, and redox state, indicating a metal depleted source (i.e., felsic units).
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Breemen, O. van, and K. L. Currie. "Geology and UPb geochronology of the Kipawa Syenite Complex a thrust related alkaline pluton and adjacent rocks in the Grenville Province of western Quebec." Canadian Journal of Earth Sciences 41, no. 4 (April 1, 2004): 431–55. http://dx.doi.org/10.1139/e04-010.
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The Kipawa Syenite Complex, a thin, folded sheet of amphibole syenite, quartz syenite and minor nepheline syenite, lies along a west-vergent thrust separating a lower slice comprising the Kikwissi granodiorite and biotite tonalite dated at 2717 +1511 Ma, and unconformably overlying metasedimentary rocks from an overlying slice containing the Red Pine Chute orthogneiss, an alkali granite gneiss, and the Mattawa Quartzite. The syenite complex, dated at 1033 ± 3 Ma, lies within the lower slice but has metasomatically altered the overlying slice. Texturally guided UPb spot analyses on partially metasomatised zircons from the alkali granite gneiss yield a cluster of 207Pb/206Pb ages at 1389 ± 8 Ma, interpreted as the time of igneous crystallization and four ages overlapping the time of syenite emplacement, interpreted as in situ, metasomatic growth. The highest structural slice comprises garnet amphibolite separated from lower slices by the Allochthon Boundary Thrust. Metamorphic grade increases upward from greenschist grade in the biotite tonalite to amphibolite grade (690 °C, 9 kbar (1 kbar = 100 MPa)) at the lower boundary of the alkali granite. Emplacement of the Kipawa Syenite Complex took place after assembly of the thrust stack had begun and after emplacement of the allochthon or hot slab responsible for the inverted metamorphic gradient. Origin of the syenite is tentatively ascribed to anatexis of material metasomatized by flow of alkaline solutions along a major shear surface. Crystallization of new zircon in the margins of the syenite shows that metasomatism continued from ca. 1035 to 990 Ma, redistributing alkalies, fluorine, rare-earth elements and zirconium.
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DRUGUET, ELENA, ANTONIO CASTRO, MARTIM CHICHORRO, M. FRANCISCO PEREIRA, and CARLOS FERNÁNDEZ. "Zircon geochronology of intrusive rocks from Cap de Creus, Eastern Pyrenees." Geological Magazine 151, no. 6 (March 11, 2014): 1095–114. http://dx.doi.org/10.1017/s0016756814000041.
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AbstractNew petrological and U–Pb zircon geochronological information has been obtained from intrusive plutonic rocks and migmatites from the Cap de Creus massif (Eastern Pyrenees) in order to constrain the timing of the thermal and tectonic evolution of this northeasternmost segment of Iberia during late Palaeozoic time. Zircons from a deformed syntectonic quartz diorite from the northern Cap de Creus Tudela migmatitic complex yield a mean age of 298.8±3.8 Ma. A syntectonic granodiorite from the Roses pluton in the southern area of lowest metamorphic grade of the massif has been dated at 290.8±2.9 Ma. All the analysed zircons from two samples of migmatitic rocks yield inherited ages from the Precambrian metasedimentary protolith (with two main age clusters at c. 730–542 Ma and c. 2.9–2.2 Ga). However, field structural relationships indicate that migmatization occurred synchronously with the emplacement of the quartz dioritic magmas at c. 299 Ma. Thus, the results of this study suggest that subduction-related calc-alkaline magmatic activity in the Cap de Creus was coeval and coupled with D2 dextral transpression involving NNW–SSE crustal shortening during Late Carboniferous – Early Permian time (c. 299–291 Ma). Since these age determinations are within the range of those obtained for undeformed (or slightly deformed) calc-alkaline igneous rocks from NE Iberia, it follows that the Cap de Creus massif would represent a zone of intense localization of D2 transpression and subsequent D3 ductile wrenching that extended into the Lower Permian during a transitional stage between the Variscan and Cimmerian cycles.
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HAJIALIOGHLI, ROBAB, MOHSSEN MOAZZEN, AHMAD JAHANGIRI, ROLAND OBERHÄNSLI, BEATE MOCEK, and UWE ALTENBERGER. "Petrogenesis and tectonic evolution of metaluminous sub-alkaline granitoids from the Takab Complex, NW Iran." Geological Magazine 148, no. 2 (September 1, 2010): 250–68. http://dx.doi.org/10.1017/s0016756810000683.
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AbstractThe Takab complex is composed of a variety of metamorphic rocks including amphibolites, metapelites, mafic granulites, migmatites and meta-ultramafics, which are intruded by the granitoid. The granitoid magmatic activity occurred in relation to the subduction of the Neo-Tethys oceanic crust beneath the Iranian crust during Tertiary times. The granitoids are mainly granodiorite, quartz monzodiorite, monzonite and quartz diorite. Chemically, the magmatic rocks are characterized by ASI<1.04, AI<0.87 and high contents of CaO (up to ~14.5 wt%), which are consistent with the I-type magmatic series. Low FeOt/(FeOt+MgO) values (<0.75) as well as low Nb, Y and K2O contents of the investigated rocks resemble the calc-alkaline series. Low SiO2, K2O/Na2O and Al2O3 accompanied by high CaO and FeO contents indicate melting of metabasites as an appropriate source for the intrusions. Negative Ti and Nb anomalies verify a metaluminous crustal origin for the protoliths of the investigated igneous rocks. These are comparable with compositions of the associated mafic migmatites, in the Takab metamorphic complex, which originated from the partial melting of amphibolites. Therefore, crustal melting and a collision-related origin for the Takab calc-alkaline intrusions are proposed here on the basis of mineralogy and geochemical characteristics. The P–T evolution during magmatic crystallization and subsolidus cooling stages is determined by the study of mineral chemistry of the granodiorite and the quartz diorite. Magmatic crystallization pressure and temperature for the quartz-diorite and the granodiorite are estimated to be P~7.8±2.5 kbar, T~760±75°C and P~5±1 kbar, T~700°C, respectively. Subsolidus conditions are consistent with temperatures of ~620°C and ~600°C, and pressures of ~5 kbar and ~3.5 kbar for the quartz-diorite and the granodiorite, respectively.
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LI, WU-XIAN, XIAN-HUA LI, and ZHENG-XIANG LI. "Middle Neoproterozoic syn-rifting volcanic rocks in Guangfeng, South China: petrogenesis and tectonic significance." Geological Magazine 145, no. 4 (April 8, 2008): 475–89. http://dx.doi.org/10.1017/s0016756808004561.
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AbstractMiddle Neoproterozoic igneous rocks are widespread in South China, but their petrogenesis and tectonic implications are still highly controversial. The Guangfeng middle Neoproterozoic volcano-sedimentary succession was developed on a rare Sibaoan metamorphic basement (the Tianli Schists) in the southeastern Yangtze Block, South China. This paper reports geochronological, geochemical and Nd isotopic data for the volcanic rocks in this succession. The volcanic rocks consist of alkaline basalts, andesites and peraluminous rhyolites. SHRIMP U–Pb zircon age determinations indicate that they were erupted at 827±14 Ma, coeval with a widespread episode of anorogenic magmatism in South China. Despite showing Nb–Ta depletion relative to La and Th, the alkaline basalts are characterized by highly positive ɛNd(T) values (+3.1 to +6.0), relatively high TiO2and Nb contents and high Zr/Y and super-chondritic Nb/Ta ratios, suggesting their derivation from a slab melt-metasomatized subcontinental lithospheric mantle source in an intracontinental rifting setting. The andesites have significantly negative ɛNd(T) values (−9.3 to −11.1) and a wide range of SiO2contents (57.6–65.6%). They were likely generated by the mixing of fractionated basaltic melts with felsic melts derived from the Archaean metasedimentary rocks in the middle to lower crust. The rhyolites are highly siliceous and peraluminous. They are characterized by depletion in Nb, Ta, Sr, P and Ti and relatively high ɛNd(T) values (−3.0 to −4.8), broadly similar to those of the adjacentc.820 Ma peraluminous granitoids derived from the Mesoproterozoic to earliest Neoproterozoic sedimentary source at relatively shallow levels. We conclude that the Guangfeng volcanic suite is a magmatic response of variant levels of continental lithosphere (including lithospheric mantle and the lower-middle to upper crust) to the middle Neoproterozoic intracontinental rifting possibly caused by mantle plume activity.
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Putiš, Marián, Peter Ivan, Milan Kohút, Ján Spišiak, Pavol Siman, Martin Radvanec, Pavel Uher, et al. "Meta-igneous rocks of the West-Carpathian basement, Slovakia: indicators of Early Paleozoic extension and shortening events." Bulletin de la Société Géologique de France 180, no. 6 (October 1, 2009): 461–71. http://dx.doi.org/10.2113/gssgfbull.180.6.461.
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Abstract The paper reviews the main West-Carpathian Early Paleozoic metamorphosed originally sedimentary-magmatic complexes, dated by SHRIMP on zircons, as indicators of crustal extension and shortening events. Igneous precursors of a Layered Amphibolite Complex (LAC) – fractionated upper mantle gabbros to diorites, dated at 503 ± 4 and 492 ± 4 Ma from the North-Veporic, or 480 ± 5 and 450 ± 6 Ma from the Tatric basement are contemporaneous with subaluminous to metaluminous I-type (507 ± 4 Ma, the South-Veporic basement), peraluminous S-type (497 ± 4 Ma, the South-Veporic basement; 516 ± 7, 485 ± 6 and 462 ± 6 Ma, the North-Veporic basement; 497 ± 6, 472 ± 6 and 450 ± 6 Ma, the Tatric basement), alkaline A-type (511 ± 6 Ma, South-Veporic basement) granitic orthogneisses and calcalkaline rhyolitic (482 ± 6 Ma) and dacitic (476 ± 7 Ma) metavolcanics (Gemeric basement), indicating a magmatic immature back arc setting. The ages point to Middle/Late Cambrian, Early and Late Ordovician magmatic phases, coeval with the extension in the northern Gondwana margin. Separation of an inferred Avalonian and/or Galatian terranes distal continental ribbon corresponds with the opening of a Medio-European Basin. A 430-390 Ma dated MP/HP metamorphic event, recorded in the LAC and associated orthogneisses, occurred in the area of thinned immature back arc basin crust due to closure of the Medio-European Basin. Thus a distal Gondwana continental ribbon north of this basin could be an eastward lateral pendant of Armorica, derived from Galatian terrane. Metaophiolites of the Pernek Group (a metagabbrodolerite dated at 371 ± 4 Ma) in the Tatric basement, analogous to island-arc tholeiites and back-arc basin basalts, indicate a back-arc basin setting north of a 430-390 Ma old northward dipping subduction/collision zone, dividing the northward drifting western Galatian terrane microplate from the Gondwana margin. Some metabasites of the Gemeric basement might indicate Late Devonian to Mississippian opening of a peri-Gondwanan Paleotethyan oceanic basin: a 383 ± 3 Ma old remelted metagabbro (482 ± 9 Ma) from the Klátov gneiss-amphibolite complex, ca. 385 Ma old porphyritic metabasite of the Zlatník ophiolite complex, as well as a 350 ± 5 Ma old HP metabasite as tectonic fragment within the Rakovec Group. The closure of Devonian-Mississippian basins, accompanied by medium-pressure (the Pernek Group) to high-pressure (blueschist to eclogitic tectonic fragments in greenschist facies rocks of the Rakovec Group) metamorphism, occurred in late Carboniferous to early Permian, when Paleotethyan realm complexes accreted to a Galatian terrane microplate, the latter represented by the older and the higher-grade Tatric and Veporic basement complexes.
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Sheraton, John W., Robert J. Tingey, Lance P. Black, and Robin L. Oliver. "Geology of the Bunger Hills area, Antarctica: implications for Gondwana correlations." Antarctic Science 5, no. 1 (March 1993): 85–102. http://dx.doi.org/10.1017/s0954102093000112.
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The Bunger Hills area of the East Antarctic Shield consists of granulite-facies felsic orthogneiss, with subordinate paragneiss and mafic granulite. The igneous precursors of granodioritic orthogneiss were emplaced 1500-1700 Ma ago, and late Archaean (2640 Ma) tonalitic orthogneiss occurs in the nearby Obruchev Hills. Peak metamorphism (M1) (at about 750-800°C and 5-6kb) occurred 1190 ±15 Ma ago (U-Pb zircon age), and was accompanied by the first of three ductile deformations (D1). Emplacement of voluminous, mainly mantle-derived plutonic rocks, ranging from gabbro, through quartz monzogabbro and quartz monzodiorite, to granite, followed between 1170 (during D3) and 1150 Ma. Intrusion of abundant dolerite dykes of four chemically distinct suites at about 1140 Ma was associated with shear zone formation, indicating at least limited uplift; all subsequent deformation was of brittle-ductile type. Alkaline mafic dykes were emplaced 500 Ma ago. Marked geochronological similarities with the Albany Mobile Belt of Western Australia suggest that high-grade metamorphism occurred during collision between the Archaean Yilgarn Craton of Australia and the East Antarctic Shield about 1200 Ma ago.
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Wu, Mingqian, Iain M. Samson, Kunfeng Qiu, and Dehui Zhang. "Concentration Mechanisms of Rare Earth Element-Nb-Zr-Be Mineralization in the Baerzhe Deposit, Northeast China: Insights from Textural and Chemical Features of Amphibole and Rare Metal Minerals." Economic Geology 116, no. 3 (May 1, 2021): 651–79. http://dx.doi.org/10.5382/econgeo.4789.
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Abstract The Early Cretaceous Baerzhe deposit in Inner Mongolia, Northeast China, hosts a world-class resource of rare earth elements (REEs), niobium, zirconium, and beryllium. In contrast to previous interpretations of the deposit as a multiphase, miaskitic alkaline granite, our observations of the relationships of various rock phases, the textural features and chemical evolution of amphibole, and the distribution of primary and secondary mineral assemblages suggest that the igneous phases evolved from a hypersolvus porphyritic granite, through a variably altered transsolvus granite, both of which are miaskitic, to a strongly altered, agpaitic, transsolvus granite that contained primary elpidite. All of these phases share a common igneous lineage. The Baerzhe deposit is characterized by five stages of rare metal mineralization, starting with the magmatic crystallization of elpidite (stage I). Elpidite was subsequently hydrothermally replaced by zircon and quartz to form pseudomorphs in stage II. Stage II is also characterized by Na metasomatism (albite and aegirine alteration of alkali feldspar and amphibole, respectively) and by snowball quartz that contains inclusions of albite, aegirine, and zircon. Sodium metasomatism, Zr mineralization, and snowball quartz are restricted to the agpaitic rocks. REEs, Nb, and Be occur as a variety of minerals that are disseminated through all the altered rocks and were precipitated in three sequential stages (stages III-V), with the formation of heavy REE-dominant phases generally preceding light REE-dominant phases. Moderate to pervasive hematization, which altered much of the transsolvus miaskitic granite and all the agpaitic granite, initiated late in stage II and accompanied most of the REE-Nb-Be mineralization in stage III. The stage-III mineralization, represented by hingganite-(Y), hingganite-(Ce), aeschynite-(Y), and columbite-(Fe), developed in two substages, with hingganite-(Y) preceding hingganite-(Ce); these REE-Nb-Be minerals are mainly contained in quartz-rich pseudomorphs (REE-Nb-Be–rich pseudomorphs) but also occur as partial replacement of earlier minerals. Stages IV and V represent a transition from F-absent assemblages that are characterized by euxenite-group minerals and monazite-(Ce) in stage IV-A, to light REE and F-rich minerals: bastnäsite-(Ce) in stage IV-B and fluocerite-(Ce) and synchysite-(Ce) in stage V. The low REE, Nb, and Be concentrations in amphibole and the fact that REE-Nb-Be assemblages never contain zircon as a constituent preclude leaching of preexisting amphibole or zirconosilicates as significant sources of REEs, Nb, or Be. Rather, these elements may have inherently been present in magmatic-hydrothermal fluids or have been leached from crystallized fluoride melts.
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Smith, I. E. M., A. J. R. White, B. W. Chappell, and R. A. Eggleton. "Fractionation in a zoned monzonite pluton: Mount Dromedary, southeastern Australia." Geological Magazine 125, no. 3 (May 1988): 273–84. http://dx.doi.org/10.1017/s0016756800010219.
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AbstractMount Dromedary pluton is one of several predominantly monzonite plutons and smaller intrusive bodies which constitute the Dromedary igneous complex in southeastern New South Wales. The pluton exhibits a striking arrangement of petrographically, but not always chemically, distinct zones ranging from mafic monzonite at the outside to quartz monzonite in the centre. The rocks display a mineralogical and geochemical integrity which indicates a consanguineous relationship. Minor compositional discontinuities between zones, together with observed and inferred minor intrusive zone boundaries, suggest that each zone has to some extent evolved independently. Negative Eu anomalies in REE abundance patterns show that some of the zones have been affected by fractionation of feldspar, but complementary accumulates are not found at the present levels of exposure. The pattern of zoning can be explained by a process of shallow fractional crystallization in which variations within zones are the result of lateral accretion of alkali feldspar as well as settling and/or lateral accretion of mafic phases at lower levels in the intrusion and upward displacement of fractionated magma. The parental magma of the pluton probaby originated by partial melting of an alkali basalt composition with an amphibolite mineralogy at the base of the crust.
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de Wit, M., and M. Bamford. "Fossil wood from the Upper Cretaceous crater sediments of the Salpeterkop volcano, North West Province, South Africa." South African Journal of Geology 124, no. 3 (September 1, 2021): 751–60. http://dx.doi.org/10.25131/sajg.124.0028.
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Abstract The Salpeterkop volcano forms part of what has been referred to as the Upper Cretaceous Sutherland Suite of alkaline rocks, an igneous province composed of olivine melilitites, carbonatites, trachytes and ultramafic lamprophyres. Salpeterkop is a remnant of the summit tuff ring structure that surrounds a crater which is almost 1 km in diameter and is filled with epiclastic strata. Five pieces of silicified wood were collected from the crater filled sediments, sectioned and identified as a new species of Cupressinoxylon, C. widdringtonioides. This is the first example of the fossil genus in South Africa. Only one member of the Cupressaceae s.l. occurs in southern Africa today. From the wide and indistinct growth rings in the fossil wood it can be deduced that the local climate was warm and humid with little or no seasonality, in support of global records of a warm Late Cretaceous. The preservation of the crater further signifies the low level of erosion the region has experienced since its emplacement.
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Trop, Jeffrey M., Jeffrey A. Benowitz, Donald Q. Koepp, David Sunderlin, Matthew E. Brueseke, Paul W. Layer, and Paul G. Fitzgerald. "Stitch in the ditch: Nutzotin Mountains (Alaska) fluvial strata and a dike record ca. 117–114 Ma accretion of Wrangellia with western North America and initiation of the Totschunda fault." Geosphere 16, no. 1 (November 21, 2019): 82–110. http://dx.doi.org/10.1130/ges02127.1.
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Abstract The Nutzotin basin of eastern Alaska consists of Upper Jurassic through Lower Cretaceous siliciclastic sedimentary and volcanic rocks that depositionally overlie the inboard margin of Wrangellia, an accreted oceanic plateau. We present igneous geochronologic data from volcanic rocks and detrital geochronologic and paleontological data from nonmarine sedimentary strata that provide constraints on the timing of deposition and sediment provenance. We also report geochronologic data from a dike injected into the Totschunda fault zone, which provides constraints on the timing of intra–suture zone basinal deformation. The Beaver Lake formation is an important sedimentary succession in the northwestern Cordillera because it provides an exceptionally rare stratigraphic record of the transition from marine to nonmarine depositional conditions along the inboard margin of the Insular terranes during mid-Cretaceous time. Conglomerate, volcanic-lithic sandstone, and carbonaceous mudstone/shale accumulated in fluvial channel-bar complexes and vegetated overbank areas, as evidenced by lithofacies data, the terrestrial nature of recovered kerogen and palynomorph assemblages, and terrestrial macrofossil remains of ferns and conifers. Sediment was eroded mainly from proximal sources of upper Jurassic to lower Cretaceous igneous rocks, given the dominance of detrital zircon and amphibole grains of that age, plus conglomerate with chiefly volcanic and plutonic clasts. Deposition was occurring by ca. 117 Ma and ceased by ca. 98 Ma, judging from palynomorphs, the youngest detrital ages, and ages of crosscutting intrusions and underlying lavas of the Chisana Formation. Following deposition, the basin fill was deformed, partly eroded, and displaced laterally by dextral displacement along the Totschunda fault, which bisects the Nutzotin basin. The Totschunda fault initiated by ca. 114 Ma, as constrained by the injection of an alkali feldspar syenite dike into the Totschunda fault zone. These results support previous interpretations that upper Jurassic to lower Cretaceous strata in the Nutzotin basin accumulated along the inboard margin of Wrangellia in a marine basin that was deformed during mid-Cretaceous time. The shift to terrestrial sedimentation overlapped with crustal-scale intrabasinal deformation of Wrangellia, based on previous studies along the Lost Creek fault and our new data from the Totschunda fault. Together, the geologic evidence for shortening and terrestrial deposition is interpreted to reflect accretion/suturing of the Insular terranes against inboard terranes. Our results also constrain the age of previously reported dinosaur footprints to ca. 117 Ma to ca. 98 Ma, which represent the only dinosaur fossils reported from eastern Alaska.
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Bellon, Hervé, René C. Maury, Sutanto, Rubini Soeria-Atmadja, Joseph Cotten, and Mireille Polvé. "65 m.y.-long magmatic activity in Sumatra (Indonesia), from Paleocene to Present." Bulletin de la Société Géologique de France 175, no. 1 (January 1, 2004): 61–72. http://dx.doi.org/10.2113/175.1.61.
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Abstract Sumatra is the largest volcanic island of the Indonesian archipelago. The oblique subduction of the Indian Ocean lithosphere below the Sundaland margin is responsible for the development of a NW-SE trending volcanic arc, the location of which coincides approximately with the Great Sumatran Fault Zone (GSFZ). We present in this paper ca. 80 new 40K-40Ar ages measured on Cenozoic calc-alkaline to shoshonitic magmatic rocks sampled all along this arc from Aceh to Lampung. The results show that magmatic activity started during the Paleocene (ca. 63 Ma) all along the arc, and was more or less permanent until Present. However, its spatial distribution increased at ca. 20 Ma, a feature possibly connected to the development of the Great Sumatran Fault. The position of Plio-Quaternary magmatic rocks is shifted away from the trench by a few tens of kilometres with respect to that of Paleocene to Miocene ones, a feature consistent with a significant tectonic erosion of the Sundaland margin during the Cenozoic. The studied samples display typical subduction-related geochemical signatures. However, we have been unable to identify clear geochemical trends, either spatial or temporal. We suggest that the lack of such regular variations reflects a complex igneous petrogenesis during which the contribution of the Sundaland continental crust overprinted those of the mantle wedge and the subducted slab.
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Kornprobst, Jacques, Michel Piboule, and Abdelhalim Tabit. "Diversite des clinopyroxenites a grenat associees aux massifs ultramafiques orogeniques; eclogites, ariegites, griquaites et grospydites; une discussion." Bulletin de la Société Géologique de France III, no. 2 (March 1, 1987): 345–51. http://dx.doi.org/10.2113/gssgfbull.iii.2.345.
Full textAbstract:
Abstract Chemical composition of rocks belonging to the garnet clinopyroxenite clan (eclogites, griquaites, grospydites) are plotted in the Al <sub>2</sub> O <sub>3</sub> -FeO-MgO diagram. Compositions of eclogites from metamorphic series define a trend corresponding to liquids resulting from the low-pressure cotectic precipitation of ol+cpx+pl. These data support the igneous nature of the material and suggest that the original rocks experienced crystallization of the crust. Garnet clinopyroxenite inclusions from kimberlites and alkali basalts as well as garnet clinopyroxenite lenses from high temperature peridotite bodies define a different trend that can be interpreted as resulting from cpx+gt precipitation from a basic melt. The unusual position of these latter rocks justify that the term "griquaite" be applied to them. Corundum and/or kyanite bearing eclogites from metamorphic series as well as "grospydites" included in kimberlites or alkali basalts, or found as lenses in ultramafic bodies), plot toward the Al-rich apex of the Al-F-M diagram, but show different SiO <sub>2</sub> /Al <sub>2</sub> O <sub>3</sub> : the term "grospydite" appears fully justified to describe the latter, and distinguish them from the former (metamorphic) ones. The origin of grospydites is still in debate: they may be the products of high pressure crystallization of basic liquids. or of metasomatic crystallization of gabbros recycled within the mantle. The coexistence within the Beni Bousera massif in northern Morocco of griquaites and grospydites indicates the large heterogeneity of this upper mantle fragment. This heterogeneity can only be explained by a complex geodynamic evolution characterized by either 1) the succession of two distinct episodes of basic melt production; or 2) a cyclical mechanism implying the subduction in the mantle of a lithospheric fragment followed by the adiabatic ascension of this fragment towards the surface.
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Oyarzún, Jorge, Roberto Oyarzun, Javier Lillo, Pablo Higueras, Hugo Maturana, and Ricardo Oyarzún. "Distribution of chemical elements in calc-alkaline igneous rocks, soils, sediments and tailings deposits in northern central Chile." Journal of South American Earth Sciences 69 (August 2016): 25–42. http://dx.doi.org/10.1016/j.jsames.2016.03.004.
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Gwalani, L. G., N. M. S. Rock, W. J. Chang, S. Fernandez, C. J. All�gre, and A. Prinzhofer. "Alkaline rocks and carbonatites of Amba Dongar and adjacent areas, Deccan Igneous Province, Gujarat, India: 1. Geology, petrography and petrochemistry." Mineralogy and Petrology 47, no. 2-4 (1992): 219–53. http://dx.doi.org/10.1007/bf01161569.
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Mugnier, Jean-Louis, Sebastien Cannic, and Henriette Lapierre. "The tholeiites of the Valaisan domain (Versoyen, western Alps): a Carboniferous magma emplaced in a small oceanic basin." Bulletin de la Société Géologique de France 179, no. 4 (July 1, 2008): 357–68. http://dx.doi.org/10.2113/gssgfbull.179.4.357.
Full textAbstract:
Abstract The mafic-ultramafic assemblages of the Versoyen complex exposed in the Valaisan domain is close to the boundary between the Internal and the External domains of the western Alps. Zircons extracted from the Versoyen complex suggest an emplacement during Paleozoic times, and probably during the Visean (~337 Ma). The base of the Versoyen complex is formed of laccoliths and sills associated with black shales, while pillow basalts and tuffs predominate at the uppermost levels. Locally, basaltic dikelets intruded leucocratic gneiss. Ultramafic-mafic cumulates form the bottom of the thickest intrusions while diabases are present along the chilled margins. All these rocks have been affected by a polyphased metamorphism under eclogitic to blueschist and greenschist facies conditions. Magmatic textures have been destroyed and the igneous mineralogy is seldom preserved. The mafic rocks of the Versoyen complex show tholeiitic to alkali-transitional affinities. The pillow basalts and the sill cores have flat REE patterns characteristic of N-MORB and T-MORB. Their εNd (assuming an age of 337 Ma) ratios range from + 5.7 to + 9 which suggest a mixing of N-MORB and OIB sources. The sill margins show Th, U and LREE-enrichments and negative εNd ratios. These features are likely related to contamination when hot mafic magmas intruded unconsolidated sediments rich in water. The high Th, U, LREE abundances and low εNd ratio of the basaltic dikelet are probably related to crustal contamination occurring during magma ascent. The geochemical characteristics of the Versoyen rocks are compatible with a tholeiitic magma emplaced into a small oceanic basin in the vicinity of a continent. The importance of pre-Mesozoic crustal thinning evidenced in one segment of the boundary between the Internal and External zones of the Alps suggests that the Pennine Front is an Alpine mega-thrust inherited from a Variscan suture.