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Journal articles on the topic 'Alkaline Earth Metal hydrides'

Author: Grafiati

Published: 24 August 2024

Last updated: 31 July 2025

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1

Yang, Wen-Hua, Wen-Cai Lu, Shan-Dong Li, et al. "Superconductivity in alkaline earth metal doped boron hydrides." Physica B: Condensed Matter 611 (June 2021): 412795. http://dx.doi.org/10.1016/j.physb.2020.412795.

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2

Shi, Xianghui, Zhizhou Liu, and Jianhua Cheng. "Research Progress of Molecular Alkaline-Earth Metal Hydrides." Chinese Journal of Organic Chemistry 39, no. 6 (2019): 1557. http://dx.doi.org/10.6023/cjoc201903043.

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3

Reckeweg, Olaf, Jay C. Molstad, Scott Levy, and Francis J. DiSalvo. "Syntheses and Crystal Structures of the New Ternary Barium Halide Hydrides Ba2H3X (X = Cl or Br)." Zeitschrift für Naturforschung B 62, no. 1 (2007): 23–27. http://dx.doi.org/10.1515/znb-2007-0104.

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Single crystals of the isotypic hydrides Ba2H3X (X = Cl or Br) were obtained by solid-state reactions of Ba, NaCl, NaNH2 and metallic Na, or Ba, NH4Br and Na, respectively, in sealed, silicajacketed stainless-steel ampoules. The crystal structures of the new compounds were determined by means of single crystal X-ray diffraction. Ba2H3Cl and Ba2H3Br crystallize in a stuffed anti CdI2 structure and adopt the space group P3̄m1 (No. 164) with the lattice parameters a = 443.00(6), c = 723.00(14) pm and a = 444.92(4), c = 754.48(14) pm, respectively. The hydride positions are derived by crystallogra

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4

Kunkel, Nathalie, Holger Kohlmann, Adlane Sayede, and Michael Springborg. "Alkaline-Earth Metal Hydrides as Novel Host Lattices for EuIILuminescence." Inorganic Chemistry 50, no. 13 (2011): 5873–75. http://dx.doi.org/10.1021/ic200801x.

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5

Yvon, Klaus, and Bernard Bertheville. "Magnesium based ternary metal hydrides containing alkali and alkaline-earth elements." Journal of Alloys and Compounds 425, no. 1-2 (2006): 101–8. http://dx.doi.org/10.1016/j.jallcom.2006.01.049.

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6

Zhang, Song, Lu Wang, Yun-Long Tai, et al. "Metal carbonates-induced solution-free dehydrogenation of alkaline earth metal hydrides at room temperature." Journal of Solid State Chemistry 289 (September 2020): 121485. http://dx.doi.org/10.1016/j.jssc.2020.121485.

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7

Gebreyohannes, Muez Gebregiorgis, Chernet Amente Geffe, and Pooran Singh. "Computational study of pressurized tetragonal magnesium hydride (MgH4) as a potential candidate for high-temperature superconducting material." Materials Research Express 9, no. 3 (2022): 036001. http://dx.doi.org/10.1088/2053-1591/ac5e22.

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Abstract The dream of realizing room temperature superconductivity is one of the most challenging problems in condensed matter physics. Currently, materials with dense hydrogen contents at high pressures hold great promise for realizing room temperature superconductivity. In particular, pressurized alkaline earth metal hydrides received particular attention following the recently predicted sodalite-like calcium hydride (CaH6) with predicted Tc about 261 K above a pressure of 150 GPa; and magnesium hydride (MgH6) with predicted Tc about 270 K above 300 GPa. In this paper, we studied magnesium h

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8

Danlami, Abdullahi, Sadiq Garba Abdu, Alhassan Shuaibu, and Ismail Magaji. "First principles study of structural stability, electronic and mechanical properties of lithium doped calcium hydrides as superconductors." Science World Journal 20, no. 1 (2025): 9–16. https://doi.org/10.4314/swj.v20i1.2.

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Alkaline earth metal with Hydrogen-rich compounds hold promise as high-temperature superconductors under high pressures. Recent theoretical hydride structures on achieving high-pressure superconductivity are composed mainly of H2 fragments. Through a systematic investigation of Ca hydrides with different hydrogen contents within both theoretical and experimental methods has become a major research area. In this work we used Density functional theory (DFT) coupled with some Quantum and classical theories to investigate the structural, Mechanical, electronic and superconducting properties of sin

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9

IVANOVIĆ, NENAD, NIKOLA NOVAKOVIĆ, DANIELE COLOGNESI, IVANA RADISAVLJEVIĆ, and STANKO OSTOJIĆ. "ELECTRONIC PRINCIPLES OF SOME TRENDS IN PROPERTIES OF METALLIC HYDRIDES." International Journal of Modern Physics B 24, no. 06n07 (2010): 703–10. http://dx.doi.org/10.1142/s0217979210064320.

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Due to their extensive present, important and versatile potential applications, metal hydrides (MH) are among the most investigated solid-state systems. Theoretical, numerical and experimental studies have provided a considerable knowledge about their structure and properties, but in spite of that, the basic electronic principles of various interactions present in MH have not yet been completely resolved. Even in the simplest MH, i.e. alkali hydrides (Alk-H), some trends in physical properties, and especially their deviations, are not well understood. Similar doubts exist for the alkaline-eart

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10

Kunkel, Nathalie, Holger Kohlmann, Adlane Sayede, and Michael Springborg. "ChemInform Abstract: Alkaline-Earth Metal Hydrides as Novel Host Lattices for EuII Luminescence." ChemInform 42, no. 35 (2011): no. http://dx.doi.org/10.1002/chin.201135009.

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11

Stavila, Vitalie. "Structural features of metal dodecahydro-closo-dodecaborates." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1026. http://dx.doi.org/10.1107/s2053273314089736.

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Metal dodecahydro-closo-dodecaborates have been recently explored as materials for hydrogen storage and as promising ionic conductors. However, their utility as hydrogen storage media is impeded by their high thermal stability, kinetic limitations, and side reactions. The high thermal and chemical stability of these materials makes them interesting for solid battery membrane applications, however more work is needed to understand the complicated phase transitions which occur in many metal dodecahydro-closo-dodecaborates. Recent literature suggests that dodecahydro-closo-dodecaborate species ar

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12

Hrenar, Tomica, Hans-Joachim Werner, and Guntram Rauhut. "Towards accurate ab initio calculations on the vibrational modes of the alkaline earth metal hydrides." Physical Chemistry Chemical Physics 7, no. 17 (2005): 3123. http://dx.doi.org/10.1039/b508779a.

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13

Sundqvist, Bertil. "Pressure-Temperature Phase Relations in Complex Hydrides." Solid State Phenomena 150 (January 2009): 175–95. http://dx.doi.org/10.4028/www.scientific.net/ssp.150.175.

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Interest in hydrogen as a future energy carrier in mobile applications has led to a strong increase in research on the structural properties of complex alkali metal and alkaline earth hydrides, with the aim to find structural phases with higher hydrogen densities. This contribution reviews recent work on the structural properties and phase diagrams of these complex hydrides under elevated pressures, an area where rapid progress has been made over the last few years. The materials discussed in greatest detail are LiAlH4, NaAlH4, Li3AlH6, Na3AlH6, LiBH4, NaBH4, and KBH4. All of these have been s

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14

Ali, Sharafat. "Elastic Properties and Hardness of Mixed Alkaline Earth Silicate Oxynitride Glasses." Materials 15, no. 14 (2022): 5022. http://dx.doi.org/10.3390/ma15145022.

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The incorporation of nitrogen as a second anion species into oxide glasses offers unique opportunities for modifying glass properties via changes in glass polymerization and structure. In this work, the compositional dependence of elastic properties and the nanoindentation hardness of mixed alkaline-earth silicate oxynitride glasses containing a high amount of nitrogen (>15 at.%, c.a. 35 e/o) were investigated. Three series of silicon oxynitride glass compositions AE–Ca–Si–O–N glasses (where AE = Mg, Sr, and Ba) having varying amounts of modifiers were prepared using a new glass synthesis r

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15

Yoshida, M., K. Yvon, and P. Fischer. "LiSr2PdH5, the first mixed alkali-alkaline earth transition metal hydride." Journal of Alloys and Compounds 194, no. 1 (1993): L11—L13. http://dx.doi.org/10.1016/0925-8388(93)90635-z.

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16

Pistidda, C., A. Santoru, S. Garroni, et al. "First Direct Study of the Ammonolysis Reaction in the Most Common Alkaline and Alkaline Earth Metal Hydrides by in Situ SR-PXD." Journal of Physical Chemistry C 119, no. 2 (2015): 934–43. http://dx.doi.org/10.1021/jp510720x.

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17

Zhao, Juan, Yin-Fan Wei, Yue-Ling Cai, et al. "Highly Selective and Efficient Reduction of CO2 to Methane by Activated Alkaline Earth Metal Hydrides without a Catalyst." ACS Sustainable Chemistry & Engineering 7, no. 5 (2019): 4831–41. http://dx.doi.org/10.1021/acssuschemeng.8b05177.

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18

Shi, Xianghui, Guorui Qin, Yang Wang, Lanxiao Zhao, Zhizhou Liu, and Jianhua Cheng. "Super‐Bulky Penta‐arylcyclopentadienyl Ligands: Isolation of the Full Range of Half‐Sandwich Heavy Alkaline‐Earth Metal Hydrides." Angewandte Chemie 131, no. 13 (2019): 4400–4404. http://dx.doi.org/10.1002/ange.201814733.

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19

Shi, Xianghui, Guorui Qin, Yang Wang, Lanxiao Zhao, Zhizhou Liu, and Jianhua Cheng. "Super‐Bulky Penta‐arylcyclopentadienyl Ligands: Isolation of the Full Range of Half‐Sandwich Heavy Alkaline‐Earth Metal Hydrides." Angewandte Chemie International Edition 58, no. 13 (2019): 4356–60. http://dx.doi.org/10.1002/anie.201814733.

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20

Zhang, Yu, Keiji Shimoda, Hiroki Miyaoka, Takayuki Ichikawa, and Yoshitsugu Kojima. "Thermal decomposition of alkaline-earth metal hydride and ammonia borane composites." International Journal of Hydrogen Energy 35, no. 22 (2010): 12405–9. http://dx.doi.org/10.1016/j.ijhydene.2010.08.018.

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21

Colognesi, D., G. Barrera, A. J. Ramirez-Cuesta, and M. Zoppi. "Hydrogen self-dynamics in orthorhombic alkaline earth hydrides through incoherent inelastic neutron scattering." Journal of Alloys and Compounds 427, no. 1-2 (2007): 18–24. http://dx.doi.org/10.1016/j.jallcom.2006.03.031.

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22

YOSHIDA, M., K. YVON, and P. FISCHER. "ChemInform Abstract: LiSr2PdH5, the First Mixed Alkali-Alkaline Earth Transition Metal Hydride." ChemInform 24, no. 24 (2010): no. http://dx.doi.org/10.1002/chin.199324032.

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23

Xu, Dongdong, Chunhui Shan, Yingzi Li та ін. "Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study". Inorganic Chemistry Frontiers 4, № 11 (2017): 1813–20. http://dx.doi.org/10.1039/c7qi00459a.

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24

Kan, Hong Min, Ning Zhang, Xiao Yang Wang, and Hong Sun. "Recent Advances in Hydrogen Storage Materials." Advanced Materials Research 512-515 (May 2012): 1438–41. http://dx.doi.org/10.4028/www.scientific.net/amr.512-515.1438.

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An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based di

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25

Madern, Nicolas, Véronique Charbonnier, Judith Monnier, Junxian Zhang, Valérie Paul-Boncour, and Michel Latroche. "Investigation of H Sorption and Corrosion Properties of Sm2MnxNi7−x (0 ≤ x < 0.5) Intermetallic Compounds Forming Reversible Hydrides." Energies 13, no. 13 (2020): 3470. http://dx.doi.org/10.3390/en13133470.

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Intermetallic compounds are key materials for energy transition as they form reversible hydrides that can be used for solid state hydrogen storage or as anodes in batteries. ABy compounds (A = Rare Earth (RE); B = transition metal; 2 < y < 5) are good candidates to fulfill the required properties for practical applications. They can be described as stacking of [AB5] and [AB2] sub-units along the c crystallographic axis. The latter sub-unit brings a larger capacity, while the former one provides a better cycling stability. However, ABy binaries do not show good enough properties for appli

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26

Mukherjee, Debabrata, Danny Schuhknecht, and Jun Okuda. "Hydrido Complexes of Calcium: A New Family of Molecular Alkaline-Earth-Metal Compounds." Angewandte Chemie International Edition 57, no. 31 (2018): 9590–602. http://dx.doi.org/10.1002/anie.201801869.

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27

Kritikos, M., and D. Nore´us. "Synthesis and characterization of ternary alkaline-earth transition-metal hydrides containing octahedral [Ru(II)H6]4− and [Os(II)H6]4− complexes." Journal of Solid State Chemistry 93, no. 1 (1991): 256–62. http://dx.doi.org/10.1016/0022-4596(91)90297-u.

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28

Li, Yongtao, Fang Fang, Yun Song, et al. "Hydrogen storage of a novel combined system of LiNH2–NaMgH3: synergistic effects of in situ formed alkali and alkaline-earth metal hydrides." Dalton Trans. 42, no. 5 (2013): 1810–19. http://dx.doi.org/10.1039/c2dt31923c.

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29

Wiesinger, Michael, Brant Maitland, Christian Färber, et al. "Simple Access to the Heaviest Alkaline Earth Metal Hydride: A Strongly Reducing Hydrocarbon-Soluble Barium Hydride Cluster." Angewandte Chemie 129, no. 52 (2017): 16881–86. http://dx.doi.org/10.1002/ange.201709771.

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30

Wiesinger, Michael, Brant Maitland, Christian Färber, et al. "Simple Access to the Heaviest Alkaline Earth Metal Hydride: A Strongly Reducing Hydrocarbon-Soluble Barium Hydride Cluster." Angewandte Chemie International Edition 56, no. 52 (2017): 16654–59. http://dx.doi.org/10.1002/anie.201709771.

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31

Li, Qian, Bing Xu, Tengfei Huang, Wenjie Yu, and Xuefeng Wang. "Activation of CO2 by Alkaline-Earth Metal Hydrides: Matrix Infrared Spectra and DFT Calculations of HM(O2CH) and (MH2)(HCOOH) Complexes (M = Sr, Ba)." Inorganic Chemistry 60, no. 15 (2021): 11466–73. http://dx.doi.org/10.1021/acs.inorgchem.1c01477.

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32

Reckeweg, O., and F. J. DiSalvo. "Alkaline Earth Metal-Hydride-Iodide Compounds: Syntheses and Crystal Structures of Sr2H3I and Ba5H2I3.9(2)O2." Zeitschrift für Naturforschung B 66 (2011): 0021. http://dx.doi.org/10.5560/znb.2011.66b0021.

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33

Rudolph, Daniel, Thomas Wylezich, Atul D. Sontakke, et al. "Synthesis and optical properties of the Eu2+-doped alkaline-earth metal hydride chlorides AE7H12Cl2 (AE = Ca and Sr)." Journal of Luminescence 209 (May 2019): 150–55. http://dx.doi.org/10.1016/j.jlumin.2019.01.033.

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34

Reckeweg, Olaf, and Francis J. DiSalvo. "ChemInform Abstract: Alkaline Earth Metal-Hydride-Iodide Compounds: Syntheses and Crystal Structures of Sr2H3I and Ba5H2I3.9(2)O2." ChemInform 42, no. 14 (2011): no. http://dx.doi.org/10.1002/chin.201114015.

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35

Yudomustafa, Fakhruddin, Eni Febriana, Wahyu Mayangsari, et al. "Study on Leaching Lanthanum From Ferronickel Slag With Pretreatment Alkaline Fusion." Metalurgi 39, no. 2 (2025): 89. https://doi.org/10.55981/metalurgi.2024.764.

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Ferronickel slag is a byproduct of nickel ore smelting. Several efforts have been made to find alternative applications for ferronickel slag, such as the production of construction materials, cement, or geopolymers. It is reported that 38% is used for road construction, 48% is used for industrial cement mixtures, and the rest is used for fertilizers, geopolymers, and hydraulic techniques. Ferronickel slag still contains some valuable minerals such as silica, magnesium, nickel, iron, and several REEs (rare earth elements). One of the REEs, namely lanthanum, has many applications, including Ni-M

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36

Mukherjee, Debabrata, Thomas Höllerhage, Valeri Leich, et al. "The Nature of the Heavy Alkaline Earth Metal–Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster." Journal of the American Chemical Society 140, no. 9 (2018): 3403–11. http://dx.doi.org/10.1021/jacs.7b13796.

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37

Gilson, Denis F. R., and Ralph O. Moyer. "Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6 (A = Alkali Metal, Alkaline Earth, and Lanthanides; M = Ir, Fe, Ru, Os, Pt, Mn)." Inorganic Chemistry 51, no. 3 (2012): 1231–32. http://dx.doi.org/10.1021/ic202534p.

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38

Gilson, Denis F. R., and Ralph O. Jr Moyer. "ChemInform Abstract: Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6(A: Alkali Metal, Alkaline Earth, and Lanthanides; M: Ir, Fe, Ru, Os, Pt, Mn)." ChemInform 43, no. 16 (2012): no. http://dx.doi.org/10.1002/chin.201216006.

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39

BRESE, N. E. "ChemInform Abstract: Alkaline Earth Nitrides and Hydrides." ChemInform 23, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.199203280.

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40

Okuda, Jun. "Cationic rare-earth metal hydrides." Coordination Chemistry Reviews 340 (June 2017): 2–9. http://dx.doi.org/10.1016/j.ccr.2016.09.009.

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41

Gingl, F., A. Hewat, and K. Yvon. "Orthorhombic Ba6Mg7H26: a new fluoride-related ternary alkaline earth hydride." Journal of Alloys and Compounds 253-254 (May 1997): 17–20. http://dx.doi.org/10.1016/s0925-8388(96)03005-8.

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42

Gingl, F., K. Yvon, and P. Fischer. "Strontium magnesium tetrahydride (SrMgH4): a new ternary alkaline earth hydride." Journal of Alloys and Compounds 187, no. 1 (1992): 105–11. http://dx.doi.org/10.1016/0925-8388(92)90526-f.

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43

Fuentealba, P., O. Reyes, H. Stoll, and H. Preuss. "Ground state properties of alkali and alkaline–earth hydrides." Journal of Chemical Physics 87, no. 9 (1987): 5338–45. http://dx.doi.org/10.1063/1.453653.

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44

Nafezarefi, F., H. Schreuders, B. Dam, and S. Cornelius. "Photochromism of rare-earth metal-oxy-hydrides." Applied Physics Letters 111, no. 10 (2017): 103903. http://dx.doi.org/10.1063/1.4995081.

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45

Chapple, Peter M., Julien Cartron, Ghanem Hamdoun, et al. "Metal–metal bonded alkaline-earth distannyls." Chemical Science 12, no. 20 (2021): 7098–114. http://dx.doi.org/10.1039/d1sc00436k.

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The complete series of heterobimetallic alkaline-earth distannyls [Ae{SnR<sub>3</sub>}<sub>2</sub>·(thf)<sub>x</sub>] (Ae = Ca, Sr, Ba) have been prepared for R = Ph and SiMe<sub>3</sub>, and their bonding and electronic properties have been comprehensively investigated.

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46

Pedersen, A. S. "Magnesium (Beryllium) and Alkaline Earth (Calcium, Strontium and Barium) Hydrides." Solid State Phenomena 49-50 (January 1996): 35–70. http://dx.doi.org/10.4028/www.scientific.net/ssp.49-50.35.

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47

Zhang, Chao, Xiao-Jia Chen, Rui-Qin Zhang, and Hai-Qing Lin. "Chemical Trend of Pressure-Induced Metallization in Alkaline Earth Hydrides." Journal of Physical Chemistry C 114, no. 34 (2010): 14614–17. http://dx.doi.org/10.1021/jp103968c.

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48

Gupta, M. "Electronic Structure of Hydrides Containing Alkali and Alkaline-earth Elements*." Zeitschrift für Physikalische Chemie 1, no. 1 (1992): 543–52. http://dx.doi.org/10.1524/zpch.1992.1.1.543.

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49

Gupta, M. "Electronic Structure of Hydrides Containing Alkali and Alkaline-earth Elements*." Zeitschrift für Physikalische Chemie 181, Part_1_2 (1993): 9–18. http://dx.doi.org/10.1524/zpch.1993.181.part_1_2.009.

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50

Zurek, Eva. "Hydrides of the Alkali Metals and Alkaline Earth Metals Under Pressure." Comments on Inorganic Chemistry 37, no. 2 (2016): 78–98. http://dx.doi.org/10.1080/02603594.2016.1196679.

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