Academic literature on the topic 'Alkaline earth nitride hydride'

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Journal articles on the topic "Alkaline earth nitride hydride"

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Chang, Fei, Yeqin Guan, Xinghua Chang, Jianping Guo, Peikun Wang, Wenbo Gao, Guotao Wu, Jie Zheng, Xingguo Li, and Ping Chen. "Alkali and Alkaline Earth Hydrides-Driven N2 Activation and Transformation over Mn Nitride Catalyst." Journal of the American Chemical Society 140, no. 44 (October 16, 2018): 14799–806. http://dx.doi.org/10.1021/jacs.8b08334.

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BRESE, N. E. "ChemInform Abstract: Alkaline Earth Nitrides and Hydrides." ChemInform 23, no. 3 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199203280.

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Garcia, Lucia, Mary F. Mahon, and Michael S. Hill. "Multimetallic Alkaline-Earth Hydride Cations." Organometallics 38, no. 19 (September 9, 2019): 3778–85. http://dx.doi.org/10.1021/acs.organomet.9b00493.

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Monge, M. A., R. Pareja, Roberto González, and Yi Chen. "Positronium Hydride Defects in Thermochemically Reduced Alkaline-Earth Oxides." Materials Science Forum 239-241 (January 1997): 47–50. http://dx.doi.org/10.4028/www.scientific.net/msf.239-241.47.

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Abe, Osami. "Sintering of silicon nitride with alkaline-earth nitrides." Ceramics International 16, no. 1 (January 1990): 53–60. http://dx.doi.org/10.1016/0272-8842(90)90063-l.

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Gingl, F., A. Hewat, and K. Yvon. "Orthorhombic Ba6Mg7H26: a new fluoride-related ternary alkaline earth hydride." Journal of Alloys and Compounds 253-254 (May 1997): 17–20. http://dx.doi.org/10.1016/s0925-8388(96)03005-8.

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Yoshida, M., K. Yvon, and P. Fischer. "LiSr2PdH5, the first mixed alkali-alkaline earth transition metal hydride." Journal of Alloys and Compounds 194, no. 1 (April 1993): L11—L13. http://dx.doi.org/10.1016/0925-8388(93)90635-z.

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Gingl, F., F. Bonhomme, K. Yvon, and P. Fischer. "Tetracalcium Trimagnesium Tetradekahydride, Ca4Mg3H14: The First Ternary Alkaline Earth Hydride*." Zeitschrift für Physikalische Chemie 1, no. 1 (January 1992): 339–40. http://dx.doi.org/10.1524/zpch.1992.1.1.339.

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Gingl, F., F. Bonhomme, K. Yvon, and P. Fischer. "Tetracalcium trimagnesium tetradecahydride, Ca4Mg3H14: the first ternary alkaline earth hydride." Journal of Alloys and Compounds 185, no. 2 (July 1992): 273–78. http://dx.doi.org/10.1016/0925-8388(92)90475-o.

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Gingl, F., K. Yvon, and P. Fischer. "Strontium magnesium tetrahydride (SrMgH4): a new ternary alkaline earth hydride." Journal of Alloys and Compounds 187, no. 1 (August 1992): 105–11. http://dx.doi.org/10.1016/0925-8388(92)90526-f.

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Dissertations / Theses on the topic "Alkaline earth nitride hydride"

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Verbraeken, Maarten Christiaan. "Doped alkaline earth (nitride) hydrides." Thesis, St Andrews, 2009. http://hdl.handle.net/10023/714.

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Tulyapitak, Tulyapong. "CURE AND MECHANICAL PROPERTIES OF CARBOXYLATED NITRILE RUBBER (XNBR) VULCANIZED BY ALKALINE EARTH METAL COMPOUNDS." University of Akron / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=akron1158067153.

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Ovchinnikov, Alexander. "Nitridomanganates of alkaline-earth metals." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-215891.

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The main goal of the present work was the synthesis of alkaline-earth nitridomanganates (AExMnyNz) with extended anionic structures and the characterization of their electronic and magnetic properties. Up to now, only compounds with isolated nitridomanganate anions have been reported in the discussed ternary systems. A systematic exploratory synthesis, employing high-temperature treatment of AE nitrides and Mn under controlled N2 pressure, yielded more than ten new nitridomanganates. Their crystal structures contain anionic building blocks of different dimensionalities, ranging from isolated species to three-dimensional frameworks. In general, the formation of Mn-rich compositions was found to be driven by the emergence of Mn-Mn interactions, which creates a link between nitridometalates and transition-metal-rich binary nitrides. The obtained nitridomanganates display a plethora of interesting phenomena, such as large spin-orbit coupling, magnetic frustration, quenching of magnetism due to Mn-Mn interactions, and metal-insulator transition.
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Santoru, Antonio [Verfasser]. "Insights into the structure and reaction mechanism of alkali and alkaline-earth metal amide-metal hydride composite systems for hydrogen storage / Antonio Santoru." Hamburg : Helmut-Schmidt-Universität, Bibliothek, 2018. http://d-nb.info/1162510706/34.

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Marchuk, Alexey [Verfasser], and Wolfgang [Akademischer Betreuer] Schnick. "Mineralizer-assisted high-pressure high-temperature synthesis and characterization of novel phosphorus nitride imides and luminescent alkaline earth metal (oxo)nitridophosphates / Alexey Marchuk. Betreuer: Wolfgang Schnick." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2016. http://d-nb.info/1098130766/34.

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Chih-HungChu and 朱智鴻. "Effects of rare-earth and alkaline earth oxides additives on the sintering properties of aluminum nitride ceramics." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/77728947464238916075.

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博士
國立成功大學
資源工程學系碩博士班
98
Aluminum nitride (AlN) ceramics, prepared with additives of CaO plus three different rare-earth oxides (Y, Sm, and Gd, separately), have been densified in an Al2O3 crucible at temperatures of up to 1650°C and 1700°C using a conventional MoSi2 heating element furnace. The advantage of using the particular experimental system and sintering condition is considered to be amenable to lower production cost and enhance the feasibility of mass production. The results of density measurements show that the atomic weight of the rare-earth element may substantially affect the apparent density of the sintered AlN specimen due to the kinetics of atomic diffusion during sintering. Dense AlN ceramics with higher thermal conductivity of 106-147 Wm-1K-1 were successfully obtained by using sintering additives of CaO plus separate rare-earth oxides of Gd, Sm, and Y at 1700°C with 3 h soaking time. The results of this study show that relative densities in excess of 99% of theoretical and a relatively highest thermal conductivity of 147 W/m-1K-1 have been achieved for feedstock materials prepared with combined addition of 1 wt.% Y2O3 and 1 wt.% CaO. Moreover, it is noted that fabrication of AlN samples having separately additives in the coupling of (1) Y2O3-CaO and (2) Yb2O3-CaO with the flow of nitrogen atmosphere is significantly related to the densification of AlN, namely the enhancement of densities from 80% to 87%. Results of residual carbon content analysis show that the protective agent as carbon black does not diffuse into sintered bodies in this processing method, seemingly, it seems to be ignored that the trace amount of residual carbon is thus shown to be harmful to properties for AlN ceramics. In addition, it is noted from Taguchi method that the control factors as sintering temperature and soaking time, are main notable factors for the densification of sintered AlN, and the contribution ratios are 50.4% and 29.3%, respectively. Noted that the relative densities of samples having 0.215 and 0.43 mole% Y2O3 increase with increasing CaO addition; whereas, the relative densities of samples with 0.86 mole% Y2O3 steeply increase first and then, starting at 1.29 mole%, to decrease with increasing CaO addition. Results of XRD profiles show that the formation of secondary phases was given to transform form single Al5Y3O12 phase to the presence of Al5Y3O12, CaYAl3O7 and CaAl4O7 multiple phases due to the mixture of various amount of Y2O3 and CaO addition. Moreover, results shown that the relative density in excess of 96% of theoretical was obtained for AlN sample fired at 1600oC for 8 h, indicating that the employment of micro hot-pressed sintering has been shown to be helpful for augmenting the densification of AlN ceramics. The thermal conductivities up to 130 Wm-1K-1 has greatly related to the merely Al5Y3O12 as secondary phases, the purification of the AlN lattice, and the grain boundary phases isolated distribution. The thermal conductivities of 65-110 Wm-1K-1 were obtained for test samples sintered at 1650 and 1700oC for 3 h, giving that the influence of the secondary phase distribution enriched at the grain boundaries for each sintered AlN. For the compacts sintered at 1650oC and 1700oC for 3 h, the dielectric constant and loss factors range form 8.98 to 10.6 and 0.02 to14.6 x10-3 at 1 MHz, respectively. Additionally, higher Vicker's hardness of 1124 kgmm-2 and fracture toughness of approaching 3.5 MPa‧m1/2 were obtained for the series of test runs. Critical temperature for AlN densification to obtain the highest density is around1650°C.
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Book chapters on the topic "Alkaline earth nitride hydride"

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Scerri, Eric. "More Chemistry." In The Periodic Table. Oxford University Press, 2019. http://dx.doi.org/10.1093/oso/9780190914363.003.0019.

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The trends within rows and columns of the periodic table are quite well known and are not repeated here. Instead, I concentrate on a number of other chemical trends, some of which challenge the form of reductionism that attempts to provide explanations based on electronic configurations alone. In the case of one particular trend described here, the knight’s move, the chemical behavior defies any theoretical understanding whatsoever, at least at the present time. As is well known to students of inorganic chemistry, a small number of elements display what is termed diagonal behavior where, in apparent violation of group trends, two elements from adjacent groups show greater similarity than is observed between these elements and the members of their own respective groups. Of these three classic examples of diagonal behavior, let us concentrate on the first one to the left in the periodic table, that between lithium and magnesium. The similarities between these two elements are as follows:1. Whereas the alkali metals form peroxides and superoxides, lithium behaves like a typical alkaline earth in forming only a normal oxide with formula Li2O. 2.Unlike the other alkali metals, lithium forms a nitride, Li3N, as do the alkaline earths. 3.Although the salts of most alkali metals are soluble, the carbonate, sulfate, and fluorides of lithium are insoluble, as in the case of the alkaline earth elements. 4.Lithium and magnesium both form organometallic compounds that act as useful reagents in organic chemistry. Lithium typically forms such compounds as Li(CH3)3, while magnesium forms such compounds as CH3MgBr, a typical Grignard reagent that is used in nucleophilic addition reactions. Organolithium and organomagnesium compounds are very strong bases that react with water to form alkanes. 5.Lithium salts display considerable covalent character, unlike their alkali metal homologues but in common with many alkaline earth salts. 6.Whereas the carbonates of the alkali metals do not decompose on heating, that of lithium behaves like the carbonates of the alkaline earths in forming the oxide and carbon dioxide gas. 7.Lithium is a considerably harder metal than other alkali metals and similar in hardness to the alkaline earths.
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Lambert, Tristan H. "New Methods for C–N Ring Construction." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0055.

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The reduction of pyridines offers an attractive approach to piperidine synthesis, and now Toshimichi Ohmura and Michinori Suginome of Kyoto University have developed (J. Am. Chem. Soc. 2012, 134, 3699) a rhodium-catalyzed hydroboration of pyridines, including the reaction of 1 to produce 3. Timothy J. Donohoe at the University of Oxford has found (Org. Lett. 2011, 13, 2074) that pyridinium silanes 4 undergo intramolecular hydride transfer by treatment with TBAF to produce dihydropyridones (e.g., 5) with good diastereoselectivity. Enantioselective amination of allylic alcohols has proven challenging, but Ross A. Widenhoefer at Duke University has reported (Angew. Chem. Int. Ed. 2012, 51, 1405) that a chiral gold catalyst can effect such intramolecular cyclizations with good enantioselectivity, as in the synthesis of 7 from 6. Alternatively, Masato Kitamura at Nagoya University has developed (Org. Lett. 2012, 14, 608) a ruthenium catalyst that operates at as low as 0.05 mol% loading for the conversion of substrates such as 8 to 9. Efforts to replace transition metal catalysts with alkaline earth metal-based alternatives have been gaining increasing attention, and Kai C. Hultzsch at Rutgers University has found (Angew. Chem. Int. Ed. 2012, 51, 394) that the magnesium complex 12 is capable of catalyzing intramolecular hydroamination (e.g., 10 to 11) with high enantioselectivity. Meanwhile, a stereoselective Wacker-type oxidation of tert-butanesulfinamides such as 13 to produce pyrrolidine derivatives 14 has been disclosed (Org. Lett. 2012, 14, 1242) by Shannon S. Stahl at the University of Wisconsin at Madison. Though highly desirable, Heck reactions have rarely proven feasible with alkyl halides due to competitive β-hydride elimination of the alkyl palladium intermediates. Sherry R. Chemler at the State University of New York at Buffalo has demonstrated (J. Am. Chem. Soc. 2012, 134, 2020) a copper-catalyzed enantioselective amination Heck-type cascade (e.g., 15 and 16 to 17) that is thought to proceed via radical intermediates. David L. Van Vranken at the University of California at Irvine has reported (Org. Lett. 2012, 14, 3233) the carbenylative amination of N-tosylhydrazones, which proceeds through η3-allyl Pd intermediates constructed via carbene insertion. This chemistry was applied to the two-step synthesis of caulophyllumine B from vinyl iodide 18 and N-tosylhydrazone 19.
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