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1

Chang, Fei, Yeqin Guan, Xinghua Chang, et al. "Alkali and Alkaline Earth Hydrides-Driven N2 Activation and Transformation over Mn Nitride Catalyst." Journal of the American Chemical Society 140, no. 44 (2018): 14799–806. http://dx.doi.org/10.1021/jacs.8b08334.

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2

BRESE, N. E. "ChemInform Abstract: Alkaline Earth Nitrides and Hydrides." ChemInform 23, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.199203280.

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3

Garcia, Lucia, Mary F. Mahon, and Michael S. Hill. "Multimetallic Alkaline-Earth Hydride Cations." Organometallics 38, no. 19 (2019): 3778–85. http://dx.doi.org/10.1021/acs.organomet.9b00493.

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4

Monge, M. A., R. Pareja, Roberto González, and Yi Chen. "Positronium Hydride Defects in Thermochemically Reduced Alkaline-Earth Oxides." Materials Science Forum 239-241 (January 1997): 47–50. http://dx.doi.org/10.4028/www.scientific.net/msf.239-241.47.

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5

Abe, Osami. "Sintering of silicon nitride with alkaline-earth nitrides." Ceramics International 16, no. 1 (1990): 53–60. http://dx.doi.org/10.1016/0272-8842(90)90063-l.

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6

Gingl, F., A. Hewat, and K. Yvon. "Orthorhombic Ba6Mg7H26: a new fluoride-related ternary alkaline earth hydride." Journal of Alloys and Compounds 253-254 (May 1997): 17–20. http://dx.doi.org/10.1016/s0925-8388(96)03005-8.

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7

Yoshida, M., K. Yvon, and P. Fischer. "LiSr2PdH5, the first mixed alkali-alkaline earth transition metal hydride." Journal of Alloys and Compounds 194, no. 1 (1993): L11—L13. http://dx.doi.org/10.1016/0925-8388(93)90635-z.

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8

Gingl, F., F. Bonhomme, K. Yvon, and P. Fischer. "Tetracalcium Trimagnesium Tetradekahydride, Ca4Mg3H14: The First Ternary Alkaline Earth Hydride*." Zeitschrift für Physikalische Chemie 1, no. 1 (1992): 339–40. http://dx.doi.org/10.1524/zpch.1992.1.1.339.

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9

Gingl, F., F. Bonhomme, K. Yvon, and P. Fischer. "Tetracalcium trimagnesium tetradecahydride, Ca4Mg3H14: the first ternary alkaline earth hydride." Journal of Alloys and Compounds 185, no. 2 (1992): 273–78. http://dx.doi.org/10.1016/0925-8388(92)90475-o.

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10

Gingl, F., K. Yvon, and P. Fischer. "Strontium magnesium tetrahydride (SrMgH4): a new ternary alkaline earth hydride." Journal of Alloys and Compounds 187, no. 1 (1992): 105–11. http://dx.doi.org/10.1016/0925-8388(92)90526-f.

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11

Rowberg, Andrew J. E., Leigh Weston, and Chris G. Van de Walle. "Ion-Transport Engineering of Alkaline-Earth Hydrides for Hydride Electrolyte Applications." Chemistry of Materials 30, no. 17 (2018): 5878–85. http://dx.doi.org/10.1021/acs.chemmater.8b01593.

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12

Zhang, Yu, Keiji Shimoda, Hiroki Miyaoka, Takayuki Ichikawa, and Yoshitsugu Kojima. "Thermal decomposition of alkaline-earth metal hydride and ammonia borane composites." International Journal of Hydrogen Energy 35, no. 22 (2010): 12405–9. http://dx.doi.org/10.1016/j.ijhydene.2010.08.018.

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13

Steinbrenner, U., and A. Simon. "Ba3N - a New Binary Nitride of an Alkaline Earth Metal." Zeitschrift für anorganische und allgemeine Chemie 624, no. 2 (1998): 228–32. http://dx.doi.org/10.1002/(sici)1521-3749(199802)624:2<228::aid-zaac228>3.0.co;2-8.

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14

Wiesinger, Michael, Brant Maitland, Christian Färber, et al. "Simple Access to the Heaviest Alkaline Earth Metal Hydride: A Strongly Reducing Hydrocarbon-Soluble Barium Hydride Cluster." Angewandte Chemie International Edition 56, no. 52 (2017): 16654–59. http://dx.doi.org/10.1002/anie.201709771.

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15

Wiesinger, Michael, Brant Maitland, Christian Färber, et al. "Simple Access to the Heaviest Alkaline Earth Metal Hydride: A Strongly Reducing Hydrocarbon-Soluble Barium Hydride Cluster." Angewandte Chemie 129, no. 52 (2017): 16881–86. http://dx.doi.org/10.1002/ange.201709771.

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16

YOSHIDA, M., K. YVON, and P. FISCHER. "ChemInform Abstract: LiSr2PdH5, the First Mixed Alkali-Alkaline Earth Transition Metal Hydride." ChemInform 24, no. 24 (2010): no. http://dx.doi.org/10.1002/chin.199324032.

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17

GINGL, F., F. BONHOMME, K. YVON, and P. FISCHER. "ChemInform Abstract: Tetracalcium Trimagnesium Tetradecahydride, Ca4Mg3H14: The First Ternary Alkaline Earth Hydride." ChemInform 23, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199239004.

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18

GINGL, F., K. YVON, and P. FISCHER. "ChemInform Abstract: Strontium Magnesium Tetrahydride (SrMgH4): A New Ternary Alkaline Earth Hydride." ChemInform 23, no. 48 (2010): no. http://dx.doi.org/10.1002/chin.199248006.

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19

Mirsaidov, U. M., M. Yu Akramov, I. U. Mirsaidov, and O. A. Azizov. "Modeling of Synthesis of Aluminum Hydride via Binary Hydrides of Alkaline Earth Metals." Journal of Applied Solution Chemistry and Modeling 7 (May 10, 2018): 9–13. http://dx.doi.org/10.6000/1929-5030.2018.07.02.

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20

Gonzalez-Silveira, M., R. Gremaud, H. Schreuders, et al. "In-Situ Deposition of Alkali and Alkaline Earth Hydride Thin Films To Investigate the Formation of Reactive Hydride Composites." Journal of Physical Chemistry C 114, no. 32 (2010): 13895–901. http://dx.doi.org/10.1021/jp101704m.

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21

Matveev, Andrei T., Konstantin L. Firestein, Alexander E. Steinman, et al. "Synthesis of boron nitride nanostructures from borates of alkali and alkaline earth metals." Journal of Materials Chemistry A 3, no. 41 (2015): 20749–57. http://dx.doi.org/10.1039/c5ta05831g.

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22

STEINBRENNER, U., and A. SIMON. "ChemInform Abstract: Ba3N - A New Binary Nitride of an Alkaline Earth Metal." ChemInform 29, no. 17 (2010): no. http://dx.doi.org/10.1002/chin.199817004.

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23

Beheshtian, Javad, Mohammad T. Baei, Zargham Bagheri, and Ali Ahmadi Peyghan. "Carbon nitride nanotube as a sensor for alkali and alkaline earth cations." Applied Surface Science 264 (January 2013): 699–706. http://dx.doi.org/10.1016/j.apsusc.2012.10.100.

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24

BOCQUILLON, G., C. LORIERS-SUSSE, and J. LORIERS. "ChemInform Abstract: Effect of Several Additives in Cubic Boron Nitride Synthesis Using Alkaline or Alkaline Earth Nitrides." ChemInform 24, no. 2 (2010): no. http://dx.doi.org/10.1002/chin.199302030.

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25

Aymar, Mireille, and Olivier Dulieu. "The electronic structure of the alkaline-earth-atom (Ca, Sr, Ba) hydride molecular ions." Journal of Physics B: Atomic, Molecular and Optical Physics 45, no. 21 (2012): 215103. http://dx.doi.org/10.1088/0953-4075/45/21/215103.

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26

Muhammad, Rafique, Yong Shuai, and He-Ping Tan. "A first-principles study on alkaline earth metal atom substituted monolayer boron nitride (BN)." Journal of Materials Chemistry C 5, no. 32 (2017): 8112–27. http://dx.doi.org/10.1039/c7tc02894f.

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This paper presents first-principles density functional theory (DFT) calculations for the structural, electronic, magnetic and optical properties of monolayer boron nitride (BN) doped with different alkaline earth metal (AEM) atoms.
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27

SCHULTZ-COULON, V., and W. SCHNICK. "ChemInform Abstract: CaMg2N2. A Mixed Alkaline-Earth Metal Nitride with anti-La2O3 Structure." ChemInform 26, no. 32 (2010): no. http://dx.doi.org/10.1002/chin.199532008.

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28

Çamurlu, Hasan Erdem, Yavuz Topkaya, and Naci Sevinç. "Catalytic effect of alkaline earth oxides on carbothermic formation of hexagonal boron nitride." Ceramics International 35, no. 6 (2009): 2271–75. http://dx.doi.org/10.1016/j.ceramint.2008.12.005.

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29

Zhang, Qing-An, Yumiko Nakamura, Ken-ich Oikawa, Takashi Kamiyama, and Etsuo Akiba. "Synthesis and Crystal Structure of Sr2AlH7: A New Structural Type of Alkaline Earth Aluminum Hydride." Inorganic Chemistry 41, no. 25 (2002): 6547–49. http://dx.doi.org/10.1021/ic020450n.

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30

Reckeweg, O., and F. J. DiSalvo. "Alkaline Earth Metal-Hydride-Iodide Compounds: Syntheses and Crystal Structures of Sr2H3I and Ba5H2I3.9(2)O2." Zeitschrift für Naturforschung B 66 (2011): 0021. http://dx.doi.org/10.5560/znb.2011.66b0021.

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31

Zhang, Qing-An, Yumiko Nakamura, Ken-ich Oikawa, Takashi Kamiyama, and Etsuo Akiba. "Synthesis and Crystal Structure of Sr2AlH7: A New Structural Type of Alkaline Earth A luminum Hydride." Inorganic Chemistry 42, no. 9 (2003): 3152. http://dx.doi.org/10.1021/ic0300363.

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32

Morris, Louis J., Nasir A. Rajabi, Mary F. Mahon, Ian Manners, Claire L. McMullin, and Michael S. Hill. "Synthesis and reactivity of alkaline-earth stannanide complexes by hydride-mediated distannane metathesis and organostannane dehydrogenation." Dalton Transactions 49, no. 30 (2020): 10523–34. http://dx.doi.org/10.1039/d0dt02406f.

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33

Li, Y. Q., G. de With, and H. T. Hintzen. "Luminescence properties of Ce3+-activated alkaline earth silicon nitride M2Si5N8 (M=Ca, Sr, Ba) materials." Journal of Luminescence 116, no. 1-2 (2006): 107–16. http://dx.doi.org/10.1016/j.jlumin.2005.03.014.

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34

Xu, Dongdong, Chunhui Shan, Yingzi Li та ін. "Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study". Inorganic Chemistry Frontiers 4, № 11 (2017): 1813–20. http://dx.doi.org/10.1039/c7qi00459a.

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35

Zhang, Qing-An, Yumiko Nakamura, Ken-ich Oikawa, Takashi Kamiyama, and Etsuo Akiba. "New Alkaline Earth Aluminum Hydride with One-Dimensional Zigzag Chains of [AlH6]: Synthesis and Crystal Structure of BaAlH5." Inorganic Chemistry 41, no. 26 (2002): 6941–43. http://dx.doi.org/10.1021/ic020388u.

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36

Reckeweg, Olaf, and Francis J. DiSalvo. "ChemInform Abstract: Alkaline Earth Metal-Hydride-Iodide Compounds: Syntheses and Crystal Structures of Sr2H3I and Ba5H2I3.9(2)O2." ChemInform 42, no. 14 (2011): no. http://dx.doi.org/10.1002/chin.201114015.

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37

Rudolph, Daniel, Thomas Wylezich, Atul D. Sontakke, et al. "Synthesis and optical properties of the Eu2+-doped alkaline-earth metal hydride chlorides AE7H12Cl2 (AE = Ca and Sr)." Journal of Luminescence 209 (May 2019): 150–55. http://dx.doi.org/10.1016/j.jlumin.2019.01.033.

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38

Rafique, Muhammad, Mukhtiar A. Unar, Irfan Ahmed, Ali R. Chachar, and Yong Shuai. "Ab-initio investigations on physisorption of alkaline earth metal atoms on monolayer hexagonal boron nitride (h-BN)." Journal of Physics and Chemistry of Solids 118 (July 2018): 114–25. http://dx.doi.org/10.1016/j.jpcs.2018.03.007.

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39

Guo, W., H. A. Ma, and X. Jia. "The etching process of boron nitride by alkali and alkaline earth fluorides under high pressure and high temperature." Materials Research Bulletin 51 (March 2014): 258–62. http://dx.doi.org/10.1016/j.materresbull.2013.12.027.

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40

Reckeweg, Olaf, and Francis J. DiSalvo. "Alkaline earth metal nitride compounds with the composition M2NX (M=Ca, Sr, Ba; X=□, H, Cl or Br)." Solid State Sciences 4, no. 5 (2002): 575–84. http://dx.doi.org/10.1016/s1293-2558(02)01300-6.

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41

Ito, Y., and T. Nishikiori. "Novel electrochemical reactions related to electrodeposition and electrochemical synthesis." Journal of Mining and Metallurgy, Section B: Metallurgy 39, no. 1-2 (2003): 233–49. http://dx.doi.org/10.2298/jmmb0302233i.

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Novel electrochemical reactions in molten salts related to electrodeposition and electrochemical synthesis are reviewed to show their usefulness and possibilities in producing functional materials. Surface nitriding of various metals and stainless steels is possible by the use of anodic reaction of nitride ion (N3-) in LiCl-KCl-Li3N melts. Electrochemical hydrogen absorption/desorption reaction occurs in molten salts containing hydride ion (H-). Electrochemical implantation and displantation can be applied to form transition metal-rare earth metal alloys in LiCl-KCl melts containing rare earth
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42

Black, Ashley P., Kristin A. Denault, Judith Oró-Solé, Alejandro R. Goñi та Amparo Fuertes. "Red luminescence and ferromagnetism in europium oxynitridosilicates with a β-K2SO4 structure". Chemical Communications 51, № 11 (2015): 2166–69. http://dx.doi.org/10.1039/c4cc08548e.

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LaSrSiO<sub>3</sub>N and LaBaSiO<sub>3</sub>N are the first examples of nitride-based alkaline earth orthosilicates with β-K<sub>2</sub>SO<sub>4</sub> structure, and they show red-orange luminescence after activation with Eu<sup>2+</sup>. The analogous compound LaEuSiO<sub>3</sub>N is, in addition to a red phosphor material, a soft ferromagnet with a Curie temperature of 3 K.
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43

Mukherjee, Debabrata, Thomas Höllerhage, Valeri Leich, et al. "The Nature of the Heavy Alkaline Earth Metal–Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster." Journal of the American Chemical Society 140, no. 9 (2018): 3403–11. http://dx.doi.org/10.1021/jacs.7b13796.

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44

Schultz-Coulon, Verena, and Wolfgang Schnick. "CaMg2N2 – ein gemischtes Erdalkalimetallnitrid mit anti-La2O3-Struktur / CaMg2N2 – a Mixed Alkaline-Earth Metal Nitride with anti-La2O3 Structure." Zeitschrift für Naturforschung B 50, no. 4 (1995): 619–22. http://dx.doi.org/10.1515/znb-1995-0425.

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CaMg2N2 (trigonal, P3̄ m 1 (Nr. 164); a = 354.046(1), c = 609.079(2) pm; Z = 1) is isotypic to the anti-La2O3 structure with octahedral and tetrahedral coordination for Ca2+ and Mg2+ ions, respectively. The compound has been prepared by the reaction o f the binary nitrides Ca3N2 and Mg3N2 (molar ratio 1:2) in a tungsten crucible under a pure nitrogen atmosphere at 1050 °C. The formation of the solid CaMg2N2 may be interpreted in analogy to reactions o f related oxides as an acid-base reaction between the binary nitrides with different coordination tendencies of Ca2+ and Mg2+ ions. An analysis
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45

Milanese, Chiara, Sebastiano Garroni, Fabiana Gennari, et al. "Solid State Hydrogen Storage in Alanates and Alanate-Based Compounds: A Review." Metals 8, no. 8 (2018): 567. http://dx.doi.org/10.3390/met8080567.

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The safest way to store hydrogen is in solid form, physically entrapped in molecular form in highly porous materials, or chemically bound in atomic form in hydrides. Among the different families of these compounds, alkaline and alkaline earth metals alumino-hydrides (alanates) have been regarded as promising storing media and have been extensively studied since 1997, when Bogdanovic and Schwickardi reported that Ti-doped sodium alanate could be reversibly dehydrogenated under moderate conditions. In this review, the preparative methods; the crystal structure; the physico-chemical and hydrogen
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46

Duan, C. J., X. J. Wang, W. M. Otten, A. C. A. Delsing, J. T. Zhao, and H. T. Hintzen. "Preparation, Electronic Structure, and Photoluminescence Properties of Eu2+- and Ce3+/Li+-Activated Alkaline Earth Silicon Nitride MSiN2(M = Sr, Ba)." Chemistry of Materials 20, no. 4 (2008): 1597–605. http://dx.doi.org/10.1021/cm701875e.

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47

Baker, Charles F., Marten G. Barker, Claire Wilson, and Duncan H. Gregory. "New mixed alkaline-earth nitridomolybdate(vi) nitride oxides with anion-ordered sub-structuresDedicated to Dr Marten G. Barker in memoriam." Dalton Transactions, no. 9 (2004): 1298. http://dx.doi.org/10.1039/b316558b.

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48

DYMOVA, T. N. "ChemInform Abstract: Some Aspects of the Evolution of the Chemistry of Aluminum Hydride and the Hydroaluminates of Alkali- and Alkaline-Earth Metals." ChemInform 28, no. 43 (2010): no. http://dx.doi.org/10.1002/chin.199743290.

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49

Werwein, Anton, Christopher Benndorf, Marko Bertmer, Alexandra Franz, Oliver Oeckler, and Holger Kohlmann. "Hydrogenation Properties of LnAl2 (Ln = La, Eu, Yb), LaGa2, LaSi2 and the Crystal Structure of LaGa2H0.71(2)." Crystals 9, no. 4 (2019): 193. http://dx.doi.org/10.3390/cryst9040193.

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Many Zintl phases take up hydrogen and form hydrides. Hydrogen atoms occupy interstitial sites formed by alkali or alkaline earth metals and / or bind covalently to the polyanions. The latter is the case for polyanionic hydrides like SrTr2H2 (Tr = Al, Ga) with slightly puckered honeycomb-like polyanions decorated with hydrogen atoms. This study addresses the hydrogenation behavior of LnTr2, where the lanthanide metals Ln introduce one additional valence electron. Hydrogenation reactions were performed in autoclaves and followed by thermal analysis up to 5.0 MPa hydrogen gas pressure. Products
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50

Reckeweg, Olaf, Jay C. Molstad, Scott Levy, and Francis J. DiSalvo. "Syntheses and Crystal Structures of the New Ternary Barium Halide Hydrides Ba2H3X (X = Cl or Br)." Zeitschrift für Naturforschung B 62, no. 1 (2007): 23–27. http://dx.doi.org/10.1515/znb-2007-0104.

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Single crystals of the isotypic hydrides Ba2H3X (X = Cl or Br) were obtained by solid-state reactions of Ba, NaCl, NaNH2 and metallic Na, or Ba, NH4Br and Na, respectively, in sealed, silicajacketed stainless-steel ampoules. The crystal structures of the new compounds were determined by means of single crystal X-ray diffraction. Ba2H3Cl and Ba2H3Br crystallize in a stuffed anti CdI2 structure and adopt the space group P3̄m1 (No. 164) with the lattice parameters a = 443.00(6), c = 723.00(14) pm and a = 444.92(4), c = 754.48(14) pm, respectively. The hydride positions are derived by crystallogra
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