Academic literature on the topic 'Alkaline Ferricyanide'

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Journal articles on the topic "Alkaline Ferricyanide"

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(Miss), MANIBALA, S. SINGH H., KRISHNA B., and K. TANDON P. "lridium(lll) Chloride Catalysed Oxidation of Propan-2-one by Hexacyanoferrate(III) in Aqueous Alkaline Medium." Journal of Indian Chemical Society Vol. 62, Jun 1985 (1985): 434–37. https://doi.org/10.5281/zenodo.6319445.

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Chemical Laboratories, University of Allahabad, Allahabad-211 002 <em>Manuscript received 15 January 1983, revised 7 March 1984, accepted 8 June 1985</em> The kinetic data show direct proportionality with respect to ferrkyanide concentra&shy;tions. The reaction rate is directly proportional to the substrate, OH<sup>-</sup> ions and iridium(III) at lower concentrations, but at higher concentrations the rate becomes independent of the substrate, alkali and the catalyst concentrations. These data suggest the formation of an activated complex between the substrate and iridium(III). Toffs complex w
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2

Pandita, Sangeeta, and Saral Baweja. "Qualitative carbohydrate analysis using alkaline potassium ferricyanide." Resonance 21, no. 3 (2016): 285–88. http://dx.doi.org/10.1007/s12045-016-0323-7.

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SITANSU, SEKHAR BHATTACHARYYA, and ROY ANSUMAN. "Oxidation of Hydroxyl Ion by Potassium Ferricyanide." Journal of Indian Chemical Society Vol. 63, Jul 1986 (1986): 677–79. https://doi.org/10.5281/zenodo.6273182.

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Department of Chemical Technology, University College of Science &amp; Technology, 92 Acharya Prafulla Chandra Road, Calcutta-700 009 <em>Manuscript received 22 July 1985, accepted 7 June 1986</em> The oxidation of hydroxyl ion by potassium ferricyanide in solution has been studied. Under standard condition, the reaction is endoenergic. Application of poten&shy;tial drives the reaction electrochemically rather than merely generate local concentra&shy;tion of hydroxyl ion at anode to produce both oxygen and ferrocyanide in the vicinity of the same electrode, as suggested earlier. With high hydr
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Kaziro, RW, and JK Beattie. "The pH Dependence of the Ruthenium-Catalyzed Ferricyanide Oxidation of Cyclohexanol." Australian Journal of Chemistry 42, no. 8 (1989): 1273. http://dx.doi.org/10.1071/ch9891273.

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The oxidation of cyclohexanol to cyclohexanone by ferricyanide in alkaline aqueous solutions is catalysed by the addition of chlororuthenium compounds. In solutions of pH less than 11 the progress of the reaction is limited by the decomposition of the catalyst in its reduced state. The catalyst lifetime can be lengthened by an increase in the concentration of the ferricyanide oxidant. In solutions of pH 11.3-11.9 either of the oxidation or the reduction steps of the catalytic cycle can be made rate determining, by adjustment of the relative concentrations of cyclohexanol and ferricyanide . The
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Böhm, Stanislav, Hanuš Slavík, and Josef Kuthan. "Ferricyanide oxidation of 1-substituted pentaphenylpyridinium salts. A novel route to 1-substituted 2,3,4,5-tetraphenylpyrroles." Collection of Czechoslovak Chemical Communications 54, no. 1 (1989): 200–205. http://dx.doi.org/10.1135/cccc19890200.

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Oxidation of 1-substituted 2,3,4,5,6-pentaphenylpyridinium salts Ia-Ij by potassium ferricyanide in an alkaline medium yields the corresponding 1-substituted 2,3,4,5-tetraphenylpyrroles in 68 to 76% yields. The selectivity of the reaction is discussed.
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Bolognese, Adele, Marina Buonanno, Antonio Cantilena, Giovanni Musci, and Angelo Alberti. "The oxidation of ortho-anisidine in alkaline medium. A product characterization and an EPR study." Canadian Journal of Chemistry 72, no. 5 (1994): 1351–56. http://dx.doi.org/10.1139/v94-168.

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Alkaline oxidation of ortho-anisidine by potassium ferricyanide in alkaline aqueous solution was examined. Azo compounds, a diamine, and para-iminoquinones were isolated from the highly coloured reaction mixture. The reaction was also carried out within the cavity of an EPR spectrometer and two radical species have been detected. Following these product results and EPR studies, a radical mechanism is proposed for the process.
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Fell, Eric M., Diana De Porcellinis, Yan Jing, et al. "Long-Term Stability of Ferri/Ferrocyanide As an Electroactive Component for Redox Flow Battery Applications: On the Origin of Apparent Capacity Fade." ECS Meeting Abstracts MA2022-02, no. 46 (2022): 1726. http://dx.doi.org/10.1149/ma2022-02461726mtgabs.

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The attraction of aqueous organic redox flow batteries (AORFBs) lies in the potential for low mass-production cost and long lifetime of the organic molecules. To reach cell potentials &gt;1.0 V, several AORFBs have employed the ferri/ferrocyanide redox couple as posolyte in alkaline conditions. Recent works have reported significant amounts of capacity fade of this redox couple at high pH, attributed either to chemical decomposition associated with cyanide ligand dissociation and irreversible hydroxylation of the iron complex [1,2], or due to cell unbalancing associated with electrochemical ox
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Hoshyargar, Faegheh, Husnaa Khan, Kourosh Kalantar-zadeh, and Anthony P. O'Mullane. "Generation of catalytically active materials from a liquid metal precursor." Chemical Communications 51, no. 74 (2015): 14026–29. http://dx.doi.org/10.1039/c5cc05246g.

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A facile route to prepare catalytically active materials from a liquid metal alloy is introduced. Sonication of liquid galinstan (GaInSn) in alkaline solution or treating it with reducing agents generates In : Sn rich microspheres that are catalytically active for electron transfer reactions such as potassium ferricyanide and 4-nitrophenol reduction.
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Jezek, Jan, Barry G. D. Haggett, Anne Atkinson, and David M. Rawson. "Determination of Glucosinolates Using Their Alkaline Degradation and Reaction with Ferricyanide." Journal of Agricultural and Food Chemistry 47, no. 11 (1999): 4669–74. http://dx.doi.org/10.1021/jf9906026.

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Kubík, Richard, and Josef Kuthan. "Sterically Crowded Heterocycles. V. Incorporation of Melamine and Adenine Moieties into Imidazo[1,2]heteroaromatic Molecules." Collection of Czechoslovak Chemical Communications 61, no. 5 (1996): 770–73. http://dx.doi.org/10.1135/cccc19960770.

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Melamine and adenine react with 2,4,6-triphenylpyrylium perchlorate to corresponding quaternary pyridinium salts 1 and 2, respectively. Ferricyanide oxidation of salt 1 in alkaline medium gave (Z)-3-(2,4-diamino-7-phenylimidazo[1,2-a][1,3,5]triazin-6-yl]-1,3-diphenylprop-2-en-1-one (3). Analogous oxidation of perchlorate 2 afforded (Z)-3-(8-phenylimidazo[1,2-f]-4H-purin-7-yl)-1,3-diphenylprop-2-en-1-one (5).
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Conference papers on the topic "Alkaline Ferricyanide"

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Moake, J. L., M. A. Harris, C. E. Whitley, and C. P. Alfrey. "RAPID, SENSITIVE N0N-RADI0ACTIVE QUANTIFICATION AND ANALYSIS OF PLASMA VON WILLEBRAND FACTOR (vWF) MULTIMERS." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1644085.

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Assessment of plasma vWF abnormalities by clinical coagulation laboratories is difficult because the available test systems for vWF antigen quantification and multimer analysis are expensive, laborious, and require days, radioactive anti-vWF antibodies and autoradiographic methods. We have devised simple, rapid, sensitive alternative techniques for vWF quantification and multimer analysis that can be readily installed in clinical laboratories. Plasma vWF antigen quantification is by a 2 hour enzyme immunoassay that accurately detects levels as low as 0.23% of normal. Plasma vWF to be quantifie
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