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Relevant bibliographies by topics / Alkaline solvolysis

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Journal articles

Academic literature on the topic 'Alkaline solvolysis'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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Journal articles on the topic "Alkaline solvolysis"

1

Kašpárek, František, Kamila Vavčíková, Jiří Mollin, and Aleš Husek. "Steric effects in alkaline solvolysis of diaryl anilidophosphates." Collection of Czechoslovak Chemical Communications 55, no. 7 (1990): 1769–76. http://dx.doi.org/10.1135/cccc19901769.

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Analysis of the products of solvolysis of aryl esters of anilidophosphoric acids in water-2-propanol mixture excludes that the reaction proceeds via E1cB mechanism. Analysis of the reaction products of solvolysis of methyl-substituted compounds made it possible to evaluate the importance of the reported steric hindrance by CH3 group. The dependence of rate constants of the solvolysis on solvent system has been established.

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2

Mollin, Jiří, Pavlína Staňková, and Oldřiška Staňková. "The evidence and applications of equilibria between hydroxide and alkoxide ions in aqueous-alcoholic systems." Collection of Czechoslovak Chemical Communications 55, no. 11 (1990): 2614–23. http://dx.doi.org/10.1135/cccc19902614.

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The composition of solvolysis products of butyl bromide, acetanhydride, and benzoyl chloride has been followed aqueous alcohol in alkaline and (except for butyl bromide) also in neutral regions. The results have been used as a piece of evidence of the existence of equilibrium between hydroxide and alkoxide ions and for evaluation of the possibility of calculation of the concentration ratio of hydroxide and alkoxide ions from the concentration ratios of the products as well as for evaluation of selectivities of the solvolytic reactions for mechanistic purposes.

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3

Bloomfield, Aaron J., Subhajyoti Chaudhuri, Brandon Q. Mercado, Victor S. Batista, and Robert H. Crabtree. "Facile solvolysis of a surprisingly twisted tertiary amide." New Journal of Chemistry 40, no. 3 (2016): 1974–81. http://dx.doi.org/10.1039/c5nj02449h.

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4

O., Sanda, A. Taiwo E., and A. Osinkolu G. "Alkaline Solvolysis of Poly(Ethylene Terephthalate) in Butan–1–ol Media: Kinetics and Optimization Studies." British Journal of Applied Science & Technology 21, no. 5 (2017): 1–12. https://doi.org/10.9734/BJAST/2017/32597.

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This study was carried out to examine the thermo-chemical decomposition of postconsumer poly(ethylene terephthalate) (PET) in alkaline solution of butan-1-ol. The effect of various process parameters such as reactor temperature, time and sodium hydroxide concentration on the degree of PET degradation and products yield were studied and it was found that the decomposition of PET was essentially complete in an hour, with terephthalic acid and ethylene glycol being the main products. A kinetic study of the process showed that the alkaline solvolysis of PET is a second order reaction.

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5

Tondeur, J. J., A. Borghese, and G. Vandendunghen. "Alkaline solvolysis of triphenylsilane, part 3. Activation parameters in water/acetonitrile mixtures." Reaction Kinetics & Catalysis Letters 49, no. 2 (1993): 241–49. http://dx.doi.org/10.1007/bf02067688.

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6

Mollin, Jiří, Zdeněk Pavelek, and František Kašpárek. "Ratio of lyate ions activities in two-components protogenic solvents." Collection of Czechoslovak Chemical Communications 52, no. 5 (1987): 1115–30. http://dx.doi.org/10.1135/cccc19871115.

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Kinetic method for the evaluation of lyate ions activities in two-component protogenic solvents has been discussed. Spectral methods for the measurement of equilibria between alkoxide and hydroxide ions have been compared. A correlation between dissociation constants of water and of weak organic acids in solvent mixtures has been found. By means of this correlation, ratios of lyate ions activities in water-ethanol and water-2-propanol mixtures have been calculated. These activity ratios, together with the known composition of reaction products, have been used to evaluate the selectivity of the

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7

Sanda, O., E. Taiwo, and G. Osinkolu. "Alkaline Solvolysis of Poly(Ethylene Terephthalate) in Butan–1–ol Media: Kinetics and Optimization Studies." British Journal of Applied Science & Technology 21, no. 5 (2017): 1–12. http://dx.doi.org/10.9734/bjast/2017/32597.

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8

Sanda, O., E. Taiwo, M. Akinrinsola, and G. Osinkolu. "A Study of the Alkaline Solvolysis of Postconsumer Polyethylene Terephthalate in Primary C1 – C3 Aliphatic Alcohols." American Chemical Science Journal 16, no. 1 (2016): 1–14. http://dx.doi.org/10.9734/acsj/2016/27697.

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9

Takada, Masatsugu, Yoshiki Tanaka, Eiji Minami, and Shiro Saka. "Comparative study of the topochemistry on delignification of Japanese beech (Fagus crenata) in subcritical phenol and subcritical water." Holzforschung 70, no. 11 (2016): 1047–53. http://dx.doi.org/10.1515/hf-2016-0033.

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Abstract The delignification of Japanese beech (Fagus crenata) has been evaluated under conditions of subcritical phenol (230°C/1.2 MPa) and subcritical water (230°C/2.9 MPa). In the former, more than 90% of the original lignin was decomposed and removed, while in subcritical water, around half of the original lignin was left as insoluble residue. Ultraviolet (UV) microscopic images of the insoluble residues showed that the lignin in the secondary walls is decomposed and removed under both conditions. These images also revealed that the lignin in the compound middle lamella (CML) is resistant

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10

Thiare, Diène Diègane, Abdourakhmane Khonté, Diegane Sarr, et al. "Solvolysis kinetic study and direct spectrofluorimetric analysis of the fungicide benomyl in natural waters." Macedonian Journal of Chemistry and Chemical Engineering 33, no. 2 (2014): 237. http://dx.doi.org/10.20450/mjcce.2014.513.

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<p>A direct spectrofluorimetric method for the quantitative analysis of benomyl in natural waters is described. Benomyl is an instable, fluorescent fungicide that mainly decomposes into carbendazim and n-butyl-isocyanate in organic and aqueous solutions. The kinetics of benomyl solvolysis reactions were investigated in organic solvents (methanol and acetonitrile) and in aqueous solvent systems, including β–cyclodextrin (β-CD), sodium dodecyl sulfate (SDS), dodecyltrimethylammonium chloride (DTAC), cetyltrimethylammonium chloride (CTAC), cetyltrimethylammonium hydroxide (CTAOH), Brij-700,

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