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Dissertations / Theses on the topic 'Alkane And Alkene'

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1

Peter, Sebastian. "Oxyfunctionalization of alkanes, alkenes and alkynes by unspecific peroxygenase (EC 1.11.2.1)." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2013. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-113321.

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Unspecific peroxygenase (EC 1.11.2.1) represents a group of secreted hemethiolate proteins that are capable of catalyzing the selective mono-oxygenation of diverse organic compounds using only H2O2 as a cosubstrate. In this study, the peroxygenase from Agrocybe aegerita (AaeUPO) was found to catalyze the hydroxylation of various linear (e.g n-hexane), branched (e.g. 2,3-dimethylbutane) and cyclic alkanes (e.g. cyclohexane). The size of n-alkane substrates converted by AaeUPO ranged from gaseous propane (C3) to n-hexadecane (C16). They were mono-hydroxylated mainly at the C2 and C3 position, ra
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2

Ly, Mai Anh. "Evaluation of components for the heterologous expression of Mycobacterium chubuense NBB4 monooxygenases." Thesis, The University of Sydney, 2014. http://hdl.handle.net/2123/11638.

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Bacterial monooxygenases have important roles in the biogeochemical cycling of carbon and nitrogen, as well as potential applications in biocatalysis of pharmaceutically important epoxides, and bioremediation of chlorinated pollutants. However, use of monooxygenases for biotechnology requires understanding of microbial physiology and the catalytic properties (e.g. substrate range and kinetic parameters) of monooxygenases themselves. Heterologous expression of monooxygenases is one way to advance our fundamental knowledge of MO functions, and also to enable future applications. This project f
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3

Yip, Wing-ping, and 葉永平. "Alkane C-H bond oxidations and alkene dihydroxylations by oxorutheniumcomplexes of chelating tertiary amine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31246254.

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4

Wagener, Alex [Verfasser], and Stefan [Akademischer Betreuer] Ernst. "Adsorptive Trennung von Gemischen kurzkettiger Alkane und Alkene an nanostrukturierten porösen Adsorbentien / Alex Wagener. Betreuer: Stefan Ernst." Kaiserslautern : Universitätsbibliothek Kaiserslautern, 2012. http://d-nb.info/1021529036/34.

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5

Prat, Casellas Irene. "Bioinspired non-heme iron catalysts for challenging oxidative transformations: mechanistic studies and catalytic applications on selective alkane hydroxylation and alkene cis-dihydroxilation." Doctoral thesis, Universitat de Girona, 2013. http://hdl.handle.net/10803/117778.

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The functionalization of hydrocarbons in a sustainable manner is one of the main challenges for chemists. Their abundance in nature as natural gas or crude oil makes them the most convenient chemical feedstock. The oxidation of hydrocarbons is one of the most interesting reactions, because the introduction of an oxygen atom introduces functionality in these molecules, increasing their value as reagents for further chemical transformation. However, these reactions are fundamentally difficult due to the low reactivity of alkyl C-H bonds. Current available methodologies involve highly reactive-ox
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6

Haak, Edgar. "Titankatalysatoren für die intermolekulare Hydroaminierung von Alkinen und Alkenen." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=964517639.

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7

Groaz, Elisabetta. "Alkene and alkyne metathesis reactions using ruthenium initiators." Thesis, King's College London (University of London), 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.440449.

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8

Mehta, Brinda Mayank. "Green Resins based on Alkene- and Alkyne-containing Triglycerides." University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1468795161.

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9

Pongtavornpinyo, Ruti. "Indium Carbenes Alkenes and Alkanes." Thesis, Imperial College London, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.508494.

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10

Edwards, Andrew R. "Polyfluorinated alkenes and alkynes." Thesis, Durham University, 1997. http://etheses.dur.ac.uk/4772/.

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The research described within this thesis may be divided into four main subject areas: 1) The use of (Z)-2H-heptafluorobut-2-ene (10) as a synthon for hexafluorobut- 2-yne (4) in Diels-Alder reactions was investigated. Novel 'one-pot' routes to a variety of bis(trifluoromethyl) substituted furan and arene derivatives were discovered, along with the synthesis of the novel diene, bis(trifluoromethyl)cyclopentadiene (46), from cyclopentadiene.2) A variety of nucleophiles were successfully reacted with (10), the products of which were identical to those that have been, or would be expected to be,
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11

Pimm, Austen David. "The application of #alpha#-metallated heterosubstituted alkenes to trisubstituted alkene synthesis." Thesis, University of Southampton, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332548.

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12

Mahelová, Zora. "Charakterizace chemického složení dehtu po zplyňování biomasy." Master's thesis, Vysoké učení technické v Brně. Fakulta chemická, 2016. http://www.nusl.cz/ntk/nusl-240964.

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Biomass is a renewable source of energy and represents an acceptable alternative to fosil fuels. Usable methods of energetic use of biomass are combustion and gasification. Main interest is focused on gasification in last years. Gasification is based on conversion of organic material to usable gaseous product called syngas, which can be used as a fuel for energy production. Large amount of tar is formed as a by-product of incineration and gasification of biomass. Tar is composed by various mixture of organic substances, has a negative effect on operating conditions and is a potential threat to
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13

Greenhalgh, Mark David. "Iron-catalysed hydrofunctionalisation of alkenes and alkynes." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/17624.

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The iron-catalysed hydrofunctionalisation of alkenes and alkynes has been developed to give a range of functionalised products with control of regio-, chemo- and stereochemistry. Using a bench-stable iron(II) pre-catalyst, the hydrosilylation, hydroboration, hydrogermylation and hydromagnesiation of alkenes and alkynes has been achieved. Iron-catalysed hydrosilylation, hydroboration and hydrogermylation of terminal, 1,1- and 1,2-disubstituted alkyl and aryl alkenes and alkynes was developed, in which the active iron catalyst was generated in situ (Scheme A1). Alkyl and vinyl silanes and pinaco
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14

Shoai, Shiva. "Regioselective rhodium-catalyzed alkyne hydrothiolation with alkane thiols : substrate scope and mechanistic investigations." Thesis, University of British Columbia, 2010. http://hdl.handle.net/2429/27028.

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The optimization and substrate scope of ClRh(PPh₃)₃-catalyzed alkyne hydrothiolation with alkane thiols producing E-linear vinyl sulfides is presented. The reactions generally proceed in good yields with good selectivities for a variety of alkane thiols and alkynes. Bulky aliphatic alkynes result in the best selectivity, while aryl alkynes with para-substituted electron donating groups give the best yields. The presence of coordinating functional groups in either the substrate or solvent negatively affects the reaction both in yield and selectivity. Deuterium-labeling studies indicate that the
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15

Sorigue, Damien. "Biosynthèse d'hydrocarbures dérivés des acides gras chez les microalgues." Thesis, Aix-Marseille, 2016. http://www.theses.fr/2016AIXM4084.

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Les alcanes et les alcènes sont des hydrocarbures non cycliques important dans l’industrie. Ils sont synthétisés à partir d'acides gras par une grande variété d’organismes mais les connaissances à ce sujet sont très limitées chez les microalgues. Le but de ces travaux était donc de rechercher la présence d’alcanes ou d’alcènes dans diverses microalgues modèles, et d’essayer d’identifier la ou les enzymes responsables de la synthèse de ces composés. Nous avons mis en évidence la présence d’hydrocarbures linéaires en C15-C17 chez les microalgues Chlorella et Chlamydomonas. Ces composés étaient s
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16

Naohisa, Nakagawa. "Selective Synthesis of Alkynes and Alkenes Using Iron-Catalyzed Cross-Coupling and Organometallic Addition Reactions." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/200444.

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17

Hobbs, Paul Michael. "Computational sorption studies of alkanes and alkenes in zeolites." Thesis, University of Reading, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.320085.

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18

Guo, Zijian. "Developing unstrained alkenes and alkynes for bioorthogonal chemistry." Thesis, University of Cambridge, 2019. https://www.repository.cam.ac.uk/handle/1810/289423.

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Bioorthogonal reactions, due to its excellent selectivity and time-efficiency, have emerged as a popular tool for protein and cell probing. Among all the bioorthogonal reactions, the inverse electron-demand Diels-Alder reaction (IEDDA) reaction has its advantage of bearing the fastest kinetics. Although the IEDDA reaction drew considerable attention in chemical biology in the last decade, challenges lie in finding the suitable dienophiles. Strained dienophiles, for example, trans-cyclooctene derivatives, can undergo ultrafast IEDDA reactions and therefore have been extensively developed. Unstr
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19

STADERINI, Samuele. "Photoinduced hydrothiolation and hydrophosphonylation of alkenes and alkynes." Doctoral thesis, Università degli studi di Ferrara, 2014. http://hdl.handle.net/11392/2389036.

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Hydrofunctionalization of terminal double or triple bonds have become classical ligation tools for facile assembly of building blocks into larger molecules especially because comply Sharpless’ prerequisite to be considered “click-chemistry” reactions. In particular the free-metal photoinduced radical thiol-ene (TEC) and thiol-yne (TYC) couplings are well-known to be atom economy, high-efficient, catalyzed only by light and completely regioselective. If both TEC and TYC have already been studied on simple substrates as linear terminal alkenes or alkynes, only few researches have been carried ou
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20

Hoenigman, Rebecca Lee. "Theoretical and experimental investigations of diradicals, pyramidalized alkenes, and bent alkynes /." Thesis, Connect to this title online; UW restricted, 2002. http://hdl.handle.net/1773/8580.

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21

Hunt, Ashley D. "Intramolecular Cope-type Hydroamination of Alkenes and Alkynes Using Hydrazides." Thèse, Université d'Ottawa / University of Ottawa, 2011. http://hdl.handle.net/10393/19881.

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Nitrogen-containing molecules are ubiquitous in both natural products and pharmaceutical drugs, thus an efficient method for the formation of these motifs is of great importance. Hydroamination, that is the addition of an N-H bond across an unsaturated carbon-carbon bond of an alkene or alkyne, stands out as a potential approach to obtain such molecules. To date, most research in this area relies on transition-metal catalysis to enable such reactivity. In efforts directed towards metal-free alternatives, we have developed a simple, metal-free hydroamination of alkenes using hydrazides. Fur
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22

Zhang, Yaming. "Electron spin resonance studies of organic radical cations : theoretical and experimental approach." Thesis, Liverpool John Moores University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.313090.

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23

Peter, Sebastian [Verfasser], Martin [Akademischer Betreuer] Hofrichter, John T. [Akademischer Betreuer] Groves, and Katrin [Akademischer Betreuer] Scheibner. "Oxyfunctionalization of alkanes, alkenes and alkynes by unspecific peroxygenase (EC 1.11.2.1) / Sebastian Peter. Gutachter: Martin Hofrichter ; John T. Groves ; Katrin Scheibner. Betreuer: Martin Hofrichter." Dresden : Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2013. http://d-nb.info/1068152370/34.

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24

Kleinschmidt, Olaf. "Photokatalytische Oxidation von Alkenen und Alkanen mit Sauerstoff an belichtetem Titandioxid." [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=962781142.

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25

Ingle, R. "Selective oxidation of alkanes and alkenes by polyoxometalates using green oxidants." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2008. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2631.

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26

ZHENG, TAO. "MOLECULAR SIMULATION OF DIFFUSION AND SORPTION OF ALKANES AND ALKANE MIXTURES IN POLY[1-(TRIMETHYLSILYL)-1-PROPYNE]." University of Cincinnati / OhioLINK, 2000. http://rave.ohiolink.edu/etdc/view?acc_num=ucin973701057.

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27

Régent, Damien [Verfasser], and Bernhard [Akademischer Betreuer] Breit. "Rhodium-catalyzed intra- and intermolecular alkene hydroacylation = Rhodium-katalisierte Intra- und Intermolecular Alken Hydroacylation." Freiburg : Universität, 2014. http://d-nb.info/1115813811/34.

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28

Fröhling, Bettina. "Reaktionen elektrophiler und nucleophiler Schwefeldonoren mit cyclischen Alkenen und Alkinen." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=964453169.

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29

Janson, Pär. "Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-103064.

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This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is directed at selectively introducing trifluoromethyl groups into compounds containing double or triple bonds. All reactions proceed under mild conditions and can in most cases be performed on the bench-top. We have developed three different procedures for transformations of activated alkenes and alkynes as well as quinones. In paper I the selective introduction of a trifluoromethyl group together with an oxygen functionality to double and triple bonds is demonstrated. Paper II is focused on the relat
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30

Okada, Takumi. "Studies on Ruthenium Complex-Catalyzed Functionalization of Alkenes and Alkynes." 京都大学 (Kyoto University), 2002. http://hdl.handle.net/2433/149811.

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31

Garba, Mustapha Danlami. "Valorisation of alkanes and alkynes by transhydrogenation in petrochemical processes." Thesis, University of Glasgow, 2017. http://theses.gla.ac.uk/8719/.

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The production of high premium fuel is an issue of priority to every refinery. The trans-hydrogenation process was devised to convert two low value refinery cracked products to premium products; the conversion processes involve the combination of dehydrogenation and hydrogenation reactions as a single step process. The low value refinery products (i.e. alkanes and alkynes or alkadienes) have been converted to alkenes (olefins) by trans-hydrogenation using catalysts system based on VOx, CrOx and Pt all supported on alumina. Although trans-hydrogenation has been disclosed in many patents over de
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32

Szuromi, Endre. "Alkene-oxo and alkene-alkene coupling on Pt(II)." Diss., Columbia, Mo. : University of Missouri-Columbia, 2005. http://hdl.handle.net/10355/4156.

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Thesis (Ph. D.)--University of Missouri-Columbia, 2005.<br>The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file viewed on (November 14, 2006) Vita. Includes bibliographical references.
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33

Chan, Wing-kei. "Oxidation of alkenes and alkynes catalyzed by a cyclodextrin-modified ketoester and metalloporphyrins." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B36709591.

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34

Kluwer, Alexander Marco. "Palladium-catalyzed stereoselective hydrogenation of alkynes to (Z)-alkenes in common solvents and supercritical CO2." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2004. http://dare.uva.nl/document/75435.

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35

Fosu, Stacy C. "Functionalization of Arenes, Amines, Alkenes, and Alkynes Mediated by Radical Pathways." The Ohio State University, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=osu1555514456659022.

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36

Rode, Katharina. "Studies Toward Selenium-pi-Acid Catalyzed Oxidative Functionalizations of Olefinic and Acetylenic Multiple Bonds." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://hdl.handle.net/21.11130/00-1735-0000-0005-1491-0.

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37

Elser, Iris [Verfasser], and Michael R. [Akademischer Betreuer] Buchmeiser. "(Pre-)ionic and/or chiral alkene and alkyne metathesis catalysts of group 6 / Iris Elser ; Betreuer: Michael R. Buchmeiser." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2018. http://d-nb.info/1183678274/34.

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38

Tóth, Krisztián [Verfasser], and Klaus T. [Akademischer Betreuer] Wanner. "Synthesis and biological evaluation of novel N-substituted nipecotic acid derivatives with an alkyne, trans-alkene or cis-alkene spacer as GABA uptake inhibitors / Krisztián Tóth ; Betreuer: Klaus T. Wanner." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2018. http://d-nb.info/1177682087/34.

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39

Daini, Masaki. "Catalytic Carboboration of Alkynes and Alkenes via Activation of Boron-Chlorine Bond." 京都大学 (Kyoto University), 2012. http://hdl.handle.net/2433/159405.

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40

Yada, Akira. "Nickel/Lewis Acid Dual Catalysis for Carbocyanation Reactions of Alkynes and Alkenes." 京都大学 (Kyoto University), 2010. http://hdl.handle.net/2433/120818.

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41

Yeo, Benjamin Roy. "Alkanes, alkenes and aromatics : the oxidative dehydrogenation of n-octane using iron molybdate catalysts." Thesis, Cardiff University, 2014. http://orca.cf.ac.uk/76035/.

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The oxidative dehydrogenation (ODH) of n-octane to produce octene at atmospheric pressure has been studied using an industrially supplied iron molybdate catalyst from Johnson Matthey (JM). In situ X-ray diffraction studies revealed at temperatures ≥450 °C the catalyst undergoes a reductive phase transition when reacted with noctane at 450 °C where the phase changes from Fe2(MoO4)3-MoO3 to FeMoO4-MoO2-Mo4O11. As a result, if the temperature is taken back below this point the catalyst does not revert to the original phase and therefore the same activity and selectivity cannot be achieved.
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42

Chan, Wing-kei, and 陳永基. "Oxidation of alkenes and alkynes catalyzed by a cyclodextrin-modified ketoester and metalloporphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B36709591.

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43

Gómez, Martín Laura. "Bioinspired iron and manganese catalysts for the effective and selective oxidation of alkanes and alkenes." Doctoral thesis, Universitat de Girona, 2010. http://hdl.handle.net/10803/8056.

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La gran eficiència, selectivitat i les condicions suaus exhibides per les reaccions que tenen lloc al centre actiu de les metal·looxigenases són la font d'inspiració per la present dissertació. Amb l'objectiu de dissenyar catalitzadors d'oxidació eficients hem fet ús de dues estratègies: la primera consisteix en el disseny de complexos amb baix pes molecular inspirats en aspectes estructurals de la primera esfera de coordinació del centre metàl·lic d'enzims de ferro i de manganès. Aquests complexos s'han estudiat com a catalitzadors en l'oxidació selectiva d'alcans i d'alquens fent servir oxid
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44

Wilkinson, Jon N. "Regioselective reactions at a diruthenium centre." Thesis, University of Bristol, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266954.

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45

Correia, Leslie Daniel Camara. "Oxygen transfer in hydrocarbon-aqueous dispersions and its applicability to alkane-based bioprocesses." Thesis, Link to the online version, 2007. http://hdl.handle.net/10019/999.

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46

Criswell, Leah. "Neutron diffraction and quasielastic neutron scattering studies of films of N-alkanes and a branched alkane absorbed on graphite." Diss., Columbia, Mo. : University of Missouri-Columbia, 2007. http://hdl.handle.net/10355/6010.

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Thesis (Ph. D.)--University of Missouri-Columbia, 2007.<br>The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on March 11, 2008) Includes bibliographical references.
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47

Wassermann, Tobias N. "Umgebungseinflüsse auf die C-C- und C-O-Torsionsdynamik in Molekülen und Molekülaggregaten Schwingungsspektroskopie bei tiefen Temperaturen." Berlin Logos, 2009. http://d-nb.info/1000809706/04.

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48

de, Orbe Izquierdo María Elena. "Gold-Catalyzed Intermolecular Reactions of Alkynes with Alkenes: Novel Reactivities and Global Mechanistic Picture." Doctoral thesis, Universitat Rovira i Virgili, 2018. http://hdl.handle.net/10803/663302.

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La catàlisi amb or es una ferramenta poderosa per la construcció d’enllaços C-C i la creació de complexitat molecular mitjançant l’activació selectiva d’alquins. Malgrat els avanços en reaccions intramoleculars d’alquins amb alquens, la versió intermolecular es encara desafiant, ja que els productes finals son també alquens que competeixen amb els substrats donant oligomeritzacions. En aquesta Tesi Doctoral, explorem reaccions intermoleculars d’un ampli rang d’alquins amb alquens i investiguem els mecanismes experimentalment i mitjançant càlculs DFT. El nostre grup va desenvolupar la cicloadi
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49

Lippincott, Daniel John. "Allenes, Alkenes & Alkynes| My Piece of the pi ...in Water at Room Temperature." Thesis, University of California, Santa Barbara, 2019. http://pqdtopen.proquest.com/#viewpdf?dispub=10982306.

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<p> I. An environmentally responsible, mild method for the synthesis of functionalized 1,3-butadienes is presented. It utilizes allenic esters of varying substitution patterns, as well as a wide range of boron-based nucleophiles under palladium catalysis, generating sp&ndash;sp<sup>2</sup>, sp<sup>2</sup>&ndash;sp<sup> 2</sup>, and sp<sup>2</sup>&ndash;sp<sup>3</sup> bonds. Functional group tolerance measured via robustness screening, along with room temperature and aqueous reaction conditions highlight the methodology&rsquo;s breadth and potential utility in synthesis. </p><p> II. A mild me
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50

Banerjee, S. "Conversion of alkanes and alkenes over Ga-modified ZSM-5 type zeolites and metal oxide catalyst." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2001. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2314.

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