Academic literature on the topic 'Alkyl anilines'

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Journal articles on the topic "Alkyl anilines"

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Ajeetha, N., and V. G. K. M. Pisipati. "The Influence of the Position of Oxygen on the Phase Behaviour of Benzylidene Anilines." Zeitschrift für Naturforschung A 58, no. 12 (2003): 735–37. http://dx.doi.org/10.1515/zna-2003-1209.

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Synthesis and Characterization of N (p-n-alkyl benzylidene)-p-n-alkoxy anilines (n.Om), N (p-nalkoxy benzylidene)-p-n-alkoxy anilines (nO.Om) and N (p-n-alkyl benzylidene)-p-n-alkyl anilines (n.m), where n = m = either 4 or 5, has been carried out using thermal microscopy (TM) and differential scanning calorimetry (DSC). The results are discussed in the light of other experimental observations on N (p-n-alkoxy benzylidene)-p-n alkyl anilines (nO.m). It has been observed that the position of oxygen on either side of the rigid core of the benzylidene moiety plays an important role in the manifes
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Ohnishi, Atsushi, Tohru Shibata, Tatsuya Imase, Satoshi Shinkura, and Kanji Nagai. "Achiral Molecular Recognition of Substituted Aniline Position Isomers by Crown Ether Type Chiral Stationary Phase." Molecules 26, no. 2 (2021): 493. http://dx.doi.org/10.3390/molecules26020493.

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To understand the selectivity of the crown ether type chiral stationary phase (CSP), the retention selectivity for aniline and the positional isomers of substituted anilines were studied. In various substituted isomers, except nitroaniline, a remarkable decrease of retention due to steric hindrance was observed for the 2-substituted isomer. To determine the detailed molecular recognition mechanism, quantum chemical calculations were performed for the aggregates between the crown ether and the anilines. The results suggested that the 20-Crown-6, which includes a phenyl-substituted 1,1′-binaphth
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Gohar, Gamal A., and Moustafa M. Habeeb. "Proton transfer equilibria, temperature and substituent effects on hydrogen bonded complexes between chloranilic acid and anilines." Spectroscopy 14, no. 3 (2000): 99–107. http://dx.doi.org/10.1155/2000/831496.

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The proton transfer equilibrium constants (KPT) for 1 : 1 complex formation between Chloranilic Acid (CA) and a series ofp- andm‒substituted anilines have been measured in 1,4-dioxane spectrophotometrically. The results supported the concept of amine-solvent hydrogen bond formation (short range solvation effect). Beside, this effect, theKPTvalues were apparently affected by the electron donation power of the aniline ring substituent, which was transmitted to the interaction center via resonance and inductive effects. Linear relationships betweenKPTand σ-Hammett substituent constants, or pKvalu
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Górecki, Sebastian, and Agnieszka Kudelko. "Synthesis and Characterization of Novel 2-Alkyl-1,3,4-Oxadiazoles Containing a Phenylazo Group." Molecules 29, no. 18 (2024): 4316. http://dx.doi.org/10.3390/molecules29184316.

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An efficient method for the synthesis of novel phenylazo-containing moieties is described. The derivatives of 5-(4-(phenyldiazenyl)phenyl)-1,3,4-oxadiazole, substituted at position 2 of the heterocyclic scaffold with alkyl groups of different chain lengths, were prepared. The titled compounds were obtained using the appropriate 4-(5-alkyl-1,3,4-oxadiazol-2-yl)anilines, which were directed to diazotization and subsequently coupled to phenol, resorcinol, and N,N-dimethylaniline. Additionally, we report a mild and effective procedure for the preparation of 4-(5-alkyl-1,3,4-oxadiazol-2-yl)anilines
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Canesi, Sylvain. "Rapid Formation of Advanced Scaffolds from Phenols and Anilines." Synlett 30, no. 06 (2018): 647–64. http://dx.doi.org/10.1055/s-0037-1610340.

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This article is an account of our efforts over the last decade to functionalize phenols and anilines at any position and to use these compounds to generate substituted aromatic systems and advanced unsaturated cyclohexanone moieties, enabling the rapid formation of complex structures. Total syntheses of numerous natural products involving such intermediates were achieved.1 Introduction2 ortho-Functionalization of Phenols and Aniline Derivatives Mediated by Iodanes (III) and Synthesis of Panacene2.1 Cross-Coupling with Aniline Derivatives2.2 Dearomative Cycloaddition of Arenes and Heteroarenes2
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Wiseman, Paul, Murray Heggie, and Ramamurthy Palepu. "Viscosities and thermodynamics of viscous flow of binary liquid mixtures of 2-(2-butoxyethoxy)ethanol with aniline and N-alkyl anilines." Canadian Journal of Chemistry 70, no. 10 (1992): 2645–49. http://dx.doi.org/10.1139/v92-333.

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Viscosities and densities of binary mixtures containing 2-(2-butoxyethoxy)ethanol with aniline and N-alkyl-substituted anilines have been determined at five different temperatures over the complete concentration range. Excess volumes, viscosities, and excess molar free energy of activation of flow were calculated and the departure from ideal behavior is explained on the basis of specific interactions between the components in these mixtures. McAllister's approach correlates the viscosity data with a significantly high degree of accuracy for all these systems.
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Wei, Yen, Ramakrishnan Hariharan, and Sandeep A. Patel. "Chemical and electrochemical copolymerization of aniline with alkyl ring-substituted anilines." Macromolecules 23, no. 3 (1990): 758–64. http://dx.doi.org/10.1021/ma00205a011.

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Tian, Ze-Yu, and Cheng-Pan Zhang. "Ullmann-type N-arylation of anilines with alkyl(aryl)sulfonium salts." Chemical Communications 55, no. 79 (2019): 11936–39. http://dx.doi.org/10.1039/c9cc06535k.

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Vo, Huyen Thanh, Shin Hye Cho, Ung Lee, Jungho Jae, Honggon Kim, and Hyunjoo Lee. "Reversible absorption of SO2 with alkyl-anilines: The effects of alkyl group on aniline and water." Journal of Industrial and Engineering Chemistry 69 (January 2019): 338–44. http://dx.doi.org/10.1016/j.jiec.2018.09.033.

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Wu, Qiao-Lei, Jing Guo, Gong-Bin Huang, Albert S. C. Chan, Jiang Weng, and Gui Lu. "Visible-light-promoted radical cross-coupling of para-quinone methides with N-substituted anilines: an efficient approach to 2,2-diarylethylamines." Organic & Biomolecular Chemistry 18, no. 5 (2020): 860–64. http://dx.doi.org/10.1039/c9ob02600b.

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Dissertations / Theses on the topic "Alkyl anilines"

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Zingales, Nicholas C. "Investigation of the Steric and Electronic Properties of 3-Iminophosphine Ligands in Chelated Palladium Allyl Complexes for Use in the Regioselective Hydroamination of Allenes." University of Toledo / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1356544579.

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Bahri, Hamed. "Thermodynamique dans les milieux diphasés dispersés : cas des solutions micellaires et des microémulsions." Paris 6, 1986. http://www.theses.fr/1986PA066280.

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Déduction de relations théoriques générales liant dans les systèmes liquides diphasés, les grandeurs observables "globales" aux grandeurs "locales" dans les différentes phases. Exposé de définitions et de notions thermodynamiques. Etablissement de relations générales pour les grandeurs molaires partielles. Etudes du cas d'un système réel : bromures d'alkyltrimethylammonium en milieu eau-kcl, qui montre que les solutions micellaires en milieu salin concentré peuvent être considérées comme un système diphasé. Données sur le partage d'un soluté moléculaire aniline en milieu micellaire. Etudes des
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Wu, Kuan-Ying, and 吳冠瑩. "Studies on the structure and properties of soluble poly(N-alkyl aniline)." Thesis, 1995. http://ndltd.ncl.edu.tw/handle/30950418637306517663.

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Lee, Tsung-Han, and 李崇漢. "Studies on Syntheses, Structure, and Physical properties of Organic Solvent Soluble Polyanilines: Poly[N-(alkyl ketone)aniline]s." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/66958905979159685568.

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碩士<br>長庚大學<br>化工與材料工程研究所<br>94<br>Abstract The purpose of this study is to modify the polyaniline (PAn) by incorporation with four compounds of normal aldehydes of different chain lengths: butyraldehyde, heptanal, octanal, and decanal. The four kinds of N-keto-alkylated polyanilines, which were poly[(N-butyl ketone)aniline], poly[(N-heptyl ketone)aniline], poly[(N-octyl ketone)aniline], and poly[(N-decyl ketone)aniline] were successfully synthesized. By the NMR, IR, and XPS spectra, we confirmed that the derivatives have keto- and normal alkyl-groups. For UV-Vis spectra and true soluti
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Chung, Wen Hung, and 鐘文宏. "Palladium-Catalyzed Synthesis of 5- and 5,7- Substituted Indoles and Allylation of Anilines by Direct Use of Allyl Alcohols." Thesis, 1998. http://ndltd.ncl.edu.tw/handle/43009120655655106838.

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碩士<br>高雄醫學院<br>藥學研究所<br>86<br>The indole nucleus is common to a large number and a wide variety of biologically active natural and unnatural compounds. Many procedures are known for preparing indoles; the availability of the starting materials and its compatibility with the reaction conditions generally dictate the method of choice for synthesizing a target molecule. Among them are unavailability of some patterns of indole substitution using classic methods and the search for efficient ways
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Halířová, Martina. "Deriváty 5-alkylpyrazin-2-karboxylové kyseliny jako potenciální antiinfektiva." Master's thesis, 2017. http://www.nusl.cz/ntk/nusl-356264.

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DERIVATIVES OF 5-ALKYLPYRAZINE-2-CARBOXYLIC ACID AS POTENTIAL ANTI-INFECTIVES HALÍŘOVÁ MARTINA Department of Pharmaceutical Chemistry and Drug Analysis, Faculty of Pharmacy in Hradec Králové, Charles University, Czech Republic In our previous study, we have demonstrated that 5-alkylamino-N- phenylpyrazine-2-carboxamides with longer alkyl chain (C5-C8) exerted micromolar growth inhibition activity against M. tuberculosis H37Rv. We speculated that the long alkylamino chain could facilitate the penetration of lipophilic mycobacterial cell envelope. To test this hypothesis, we performed the amino
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Book chapters on the topic "Alkyl anilines"

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Johnson, Adam R., Christopher C. Cummins, and Sandro Gambarotta. "N-Tert -Alkyl-anilides as Bulky Anciliary Ligands." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132630.ch20.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of monomeric titanium(III) alkyl complex stabilized by anilide ligation." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_24.

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Wong, Y. S. "Alkenylation of -Alkyl-Substituted Anilines." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00389.

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Wong, Y. S. "Hydroxylation of -Alkyl-Substituted Anilines (Synthesis of -Quinol Imines)." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00390.

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Taber, Douglass F. "Best Synthetic Methods: Functional Group Transformations." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0003.

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Vinyl glycine 2 is a useful precursor to a variety of amino acids. Timothy E. Long of the University of Georgia found (Tetrahedron Lett. 2009, 50, 5067) that the o-nitrophenyl sulfoxide 1 eliminated smoothly in refluxing toluene. Alicia Boto and Rosendo Hernández of IPNA La Laguna observed (Tetrahedron Lett. 2009, 50, 3974) that a related selenoxide elimination proceeded to give the single regioisomer 4. Avelino Corma of the Universidad Politécnica de Valencia developed ( Chemical Commun. 2009, 4947) a gold catalyst for the selective hydroboration of alkynes over alkenes. Eiji Shirakawa and Ta
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Wong, Y. S. "Alkylation of -Alkyl-Substituted Aniline Derivatives." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00386.

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Taber, Douglass F. "Substituted Benzenes: The Piers/Lau Synthesis of Hamigeran B." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0064.

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Govindasamy Sekar of the Indian Institute of Technology, Madras, developed ( Chem. Commun. 2011, 47, 5076) an environmentally friendly procedure for the amination of 1 to 2. Jens-Uwe Peters of Hoffmann-La Roche, Basel, showed (Tetrahedron Lett. 2011, 52, 749) that the Udenfriend protocol could be used to convert drugs such as 3 to their hydroxylated metabolites. Suman L. Jain and Anil K. Sinha of the Indian Institute of Petroleum reported (Chem. Commun. 2011, 47, 1610) complementary conditions for arene hydroxylation. Dimethyl aniline has been used, inter alia, as a nucleophile in enantioselec
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Wong, Y. S. "Acyloxylation of -Alkyl-Substituted Aniline Derivatives (Synthesis of -Quinol Imide Acetates)." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00391.

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Wong, Y. S. "Amidation of -Alkyl-Substituted Aniline Derivatives (Synthesis of -Quinol Imide Amides)." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00394.

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Ulrich, H. "From Alkyl [(3-Phenyl-2-propynoyl)anilino]acetates and Aryl Isothiocyanates." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00189.

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Conference papers on the topic "Alkyl anilines"

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Śliwiński, Jakub Stefan, Bartłomiej Kobiałka, Wojciech Szymański, Krzysztof Urbanek, and Rafał Banasiuk. "New Coatings Based on PANI-hexacyanoferrate-nano-TiO2 Composites to Improve Their Anticorrosive Resistance." In CORROSION 2018. NACE International, 2018. https://doi.org/10.5006/c2018-11135.

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Abstract New corrosion protective coatings were proposed and long term corrosion tests were performed. These coatings, based on modified polyaniline, showed that hexacyanoferrate improved their anticorrosion properties. Our recent research gives some information about the increasing oxygen diffusivity barrier when nano-TiO2 is added. The goal of this paper was to check if there is a synergy effect between these two compounds. The polyaniline-hexacyanoferrate-nano-TiO2 composites were prepared by in situ oxidative polymerization of aniline in solutions of two different inorganic acids. The corr
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Kon, Yoshihiro. "Selective monoallylation of anilines to form fine chemicals using allyl alcohol derived from glycerol." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/mjrr3569.

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Glycerol is an important starting material for the production of value-added chemicals such as electronic materials and pharmaceuticals. We herein present a selective allylation reaction using allyl alcohol which is given from glycerol. First, we show the rhenium catalyzed high-yielding synthesis of allyl alcohol from glycerol through deoxydehydration reaction. Next, the selective N-allyl aniline synthesis from allyl alcohol with aniline is performed. The well-dispersed tungsten oxide supported on zirconium oxide can catalyze the reaction to produce the corresponding mono-allyl compound over
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Wiggins, J., B. Morasch, O. Durán, and B. Barea-López. "Cure Path Dependency on Meta-Alkyl Substituted Aniline Based Polybenzoxazine Thermosets." In SAMPE 2022. NA SAMPE, 2022. http://dx.doi.org/10.33599/nasampe/s.22.0758.

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