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Journal articles on the topic 'All-Copper Redox Flow Battery'

Author: Grafiati

Published: 2 June 2025

Last updated: 31 July 2025

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1

Schaltin, Stijn, Yun Li, Neil R. Brooks, et al. "Towards an all-copper redox flow battery based on a copper-containing ionic liquid." Chemical Communications 52, no. 2 (2016): 414–17. http://dx.doi.org/10.1039/c5cc06774j.

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2

Peljo, Pekka, David Lloyd, Nguyet Doan, Marko Majaneva, and Kyösti Kontturi. "Towards a thermally regenerative all-copper redox flow battery." Physical Chemistry Chemical Physics 16, no. 7 (2014): 2831. http://dx.doi.org/10.1039/c3cp54585g.

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3

Cross, Nicholas R., Renaldo E. Springer, Matthew J. Rau, et al. "Membrane Transport and Performance in the All-Aqueous Copper Thermally Regenerative Battery." ECS Meeting Abstracts MA2022-02, no. 1 (2022): 8. http://dx.doi.org/10.1149/ma2022-0218mtgabs.

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Redox flow batteries are emerging as a promising method to provide grid-scale power and long-duration energy storage safely and economically. The thermally regenerative ammonia battery (TRAB) is a new redox flow battery category that can be recharged using low-grade waste heat rather than electric energy, adding further flexibility to the applicability of flow battery systems. Recently, a new TRAB with all-aqueous electroactive species (referred to as the Cuaq-TRAB), as opposed to deposition-dissolution reactions, was found to have superior energy and power densities relative to competing TRAB

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4

D'Adamo, Mirko, Wouter Badenhorst, Lasse Murtomäki, et al. "Modeling an All-Copper Redox Flow Battery for Microgrid Applications: Impact of Current and Flow Rate on Capacity Fading and Deposition." Energies 18, no. 8 (2025): 2084. https://doi.org/10.3390/en18082084.

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The copper redox flow battery (CuRFB) stands out as a promising hybrid redox flow battery technology, offering significant advantages in electrolyte stability. Within the CuBER H-2020 project framework, this study addresses critical phenomena such as electrodeposition at the negative electrode during charging and copper crossover through the membrane, which influence capacity fading. A comprehensive two-dimensional physicochemical model of the CuRFB cell was developed using COMSOL Multiphysics, providing insights into the distribution of electroactive materials over time. The model was validat

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5

D’Adamo, Mirko, Wouter Badenhorst, Lasse Murtomäki, et al. "Modeling an All-Copper Redox Flow Battery for Microgrid Applications: Impact of Current and Flow Rate on Capacity Fading and Deposition." Energies 18, no. 8 (2025): 2084. https://doi.org/10.3390/en18082084.

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The copper redox flow battery (CuRFB) stands out as a promising hybrid redox flow battery technology, offering significant advantages in electrolyte stability. Within the CuBER H-2020 project framework, this study addresses critical phenomena such as electrodeposition at the negative electrode during charging and copper crossover through the membrane, which influence capacity fading. A comprehensive two-dimensional physicochemical model of the CuRFB cell was developed using COMSOL Multiphysics, providing insights into the distribution of electroactive materials over time. The model was validat

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6

Sanz, Laura, David Lloyd, Eva Magdalena, Jesús Palma, and Kyösti Kontturi. "Description and performance of a novel aqueous all-copper redox flow battery." Journal of Power Sources 268 (December 2014): 121–28. http://dx.doi.org/10.1016/j.jpowsour.2014.06.008.

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7

Zhang, Jing, Gaopeng Jiang, Pan Xu, et al. "An all-aqueous redox flow battery with unprecedented energy density." Energy & Environmental Science 11, no. 8 (2018): 2010–15. http://dx.doi.org/10.1039/c8ee00686e.

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8

Gong, Ke, Fei Xu, Jonathan B. Grunewald, et al. "All-Soluble All-Iron Aqueous Redox-Flow Battery." ACS Energy Letters 1, no. 1 (2016): 89–93. http://dx.doi.org/10.1021/acsenergylett.6b00049.

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9

Badenhorst, Wouter Dirk, Kuldeep, Laura Sanz, Catia Arbizzani, and Lasse Murtomäki. "Performance improvements for the all-copper redox flow battery: Membranes, electrodes, and electrolytes." Energy Reports 8 (November 2022): 8690–700. http://dx.doi.org/10.1016/j.egyr.2022.06.075.

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10

Li, Yun, Jeroen Sniekers, João Malaquias, et al. "A non-aqueous all-copper redox flow battery with highly soluble active species." Electrochimica Acta 236 (May 2017): 116–21. http://dx.doi.org/10.1016/j.electacta.2017.03.039.

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11

Badenhorst, Wouter, Christian M. Jensen, Uffe Jakobsen, Zahra Esfahani, and Lasse Murtomäki. "Control-Oriented Electrochemical Model and Parameter Estimation for an All-Copper Redox Flow Battery." Batteries 9, no. 5 (2023): 272. http://dx.doi.org/10.3390/batteries9050272.

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Redox flow batteries are an emergent technology in the field of energy storage for power grids with high renewable generator penetration. The copper redox flow battery (CuRFB) could play a significant role in the future of electrochemical energy storage systems due to the numerous advantages of its all-copper chemistry. Furthermore, like the more mature vanadium RFB technology, CuRFBs have the ability to independently scale power and capacity while displaying very fast response times that make the technology attractive for a variety of grid-supporting applications. As with most batteries, the

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12

Lloyd, David, Eva Magdalena, Laura Sanz, Lasse Murtomäki, and Kyösti Kontturi. "Preparation of a cost-effective, scalable and energy efficient all-copper redox flow battery." Journal of Power Sources 292 (October 2015): 87–94. http://dx.doi.org/10.1016/j.jpowsour.2015.04.176.

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13

Lloyd, David, Tuomas Vainikka, and Kyösti Kontturi. "The development of an all copper hybrid redox flow battery using deep eutectic solvents." Electrochimica Acta 100 (June 2013): 18–23. http://dx.doi.org/10.1016/j.electacta.2013.03.130.

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14

Jia, Chuankun, Feng Pan, Yun Guang Zhu, Qizhao Huang, Li Lu, and Qing Wang. "High–energy density nonaqueous all redox flow lithium battery enabled with a polymeric membrane." Science Advances 1, no. 10 (2015): e1500886. http://dx.doi.org/10.1126/sciadv.1500886.

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Redox flow batteries (RFBs) are considered one of the most promising large-scale energy storage technologies. However, conventional RFBs suffer from low energy density due to the low solubility of the active materials in electrolyte. On the basis of the redox targeting reactions of battery materials, the redox flow lithium battery (RFLB) demonstrated in this report presents a disruptive approach to drastically enhancing the energy density of flow batteries. With LiFePO4 and TiO2 as the cathodic and anodic Li storage materials, respectively, the tank energy density of RFLB could reach ~500 watt

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15

Li, Heyao, Zhuqian Zhang, Haojie Zhang, and Yuchen Zhou. "Exploring the Flow and Mass Transfer Characteristics of an All-Iron Semi-Solid Redox Flow Battery." Batteries 11, no. 4 (2025): 166. https://doi.org/10.3390/batteries11040166.

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To improve the flow mass transfer inside the electrodes and the efficiency of an all-iron redox flow battery, a semi-solid all-iron redox flow battery is presented experimentally. A slurry electrode is designed to replace the traditional porous electrode. Moreover, the effects of an additional external magnetic field are further investigated in the semi-solid battery experiment. The results show that the mass transfer of the slurry in the battery flow channel and the prolonged discharge time are significantly affected by the additional external magnetic fields. In addition, a three-dimensional

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16

Morais, William Gomes, Emanuele Maria Groiss, Valentina La Valle, and Edoardo Gino Macchi. "Electrochemical Characterization of Stable Cu(II)/Cu(I) Electrolytes for Redox Flow Battery." ECS Meeting Abstracts MA2023-02, no. 8 (2023): 3338. http://dx.doi.org/10.1149/ma2023-0283338mtgabs.

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The path to reach carbon neutrality cannot be paved without further development of long life and low-cost batteries, considering also cyclability, calendar life, and round-trip efficiency. In this context, Redox Flow Batteries (RFB) have gathered researchers’ attention as possible candidates to play a major role in the incoming of the next generation batteries. Their unique capability to decouple power and energy makes possible of have flexible modular design and operation, along with outstanding scalability, plus moderate maintenance costs and long-life cycling. [1] Although vanadium based re

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17

Gerber, Fischer, Pinkwart, and Tübke. "Segmented Printed Circuit Board Electrode for Locally-resolved Current Density Measurements in All-Vanadium Redox Flow Batteries." Batteries 5, no. 2 (2019): 38. http://dx.doi.org/10.3390/batteries5020038.

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One of the most important parameters for the design of redox flow batteries is a uniform distribution of the electrolyte solution over the complete electrode area. The performance of redox flow batteries is usually investigated by general measurements of the cell in systematic experimental studies such as galvanostatic charge-discharge cycling. Local inhomogeneity within the electrode cannot be locally-resolved. In this study a printed circuit board (PCB) with a segmented current collector was integrated into a 40 cm2 all-vanadium redox flow battery to analyze the locally-resolved current dens

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18

Zhang, Shu Di, and Yu Chun Zhai. "Study on the Stability of all Vanadium Redox Flow Battery Electrolyte." Applied Mechanics and Materials 281 (January 2013): 461–64. http://dx.doi.org/10.4028/www.scientific.net/amm.281.461.

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In order to study on several additives to Vanadium battery electrolyte stability, different additives were added in the electrolyte of vanadium battery electrolyte at different temperatures, precipitation time were observed, cyclic voltammetry curves were tested and ultraviolet quantitative analysis to precipitated supernatant , The results show that after adding the different additives, at 40 °C temperature, 1.8 mol / L concentration can stably exist in the electrolyte of the vanadium battery. The added amount of sodium oxalate, ammonium oxalate is equivalent 3% of the amount V4+ solution, th

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19

Lee, Chi-Yuan, Chin-Lung Hsieh, Chia-Hung Chen, Yen-Pu Huang, Chong-An Jiang, and Pei-Chi Wu. "A Flexible 5-In-1 Microsensor for Internal Microscopic Diagnosis of Vanadium Redox Flow Battery Charging Process." Sensors 19, no. 5 (2019): 1030. http://dx.doi.org/10.3390/s19051030.

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Multiple important physical parameters in the vanadium redox flow battery are difficult to measure accurately, and the multiple important physical parameters (e.g., temperature, flow, voltage, current, pressure, and electrolyte concentration) are correlated with each other; all of them have a critical influence on the performance and life of vanadium redox flow battery. In terms of the feed of fuel to vanadium redox flow battery, the pump conveys electrolytes from the outside to inside for reaction. As the performance of vanadium redox flow battery can be tested only by an external machine—aft

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20

Bae*, Chulheung, Edward Pelham Lindfield Roberts, Mohammed Harun Chakrabarti, and Muhammad Saleem. "All-Chromium Redox Flow Battery for Renewable Energy Storage." International Journal of Green Energy 8, no. 2 (2011): 248–64. http://dx.doi.org/10.1080/15435075.2010.549598.

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21

Rychcik, M., and M. Skyllas-Kazacos. "Characteristics of a new all-vanadium redox flow battery." Journal of Power Sources 22, no. 1 (1988): 59–67. http://dx.doi.org/10.1016/0378-7753(88)80005-3.

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22

Park, Dong-Jun, Kwang-Sun Jeon, Cheol-Hwi Ryu, and Gab-Jin Hwang. "Performance of the all-vanadium redox flow battery stack." Journal of Industrial and Engineering Chemistry 45 (January 2017): 387–90. http://dx.doi.org/10.1016/j.jiec.2016.10.007.

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23

Chen, Jin Qing, Bao Guo Wang, and Hong Ling Lv. "Numerical Simulation and Experiment on the Electrolyte Flow Distribution for All Vanadium Redox Flow Battery." Advanced Materials Research 236-238 (May 2011): 604–7. http://dx.doi.org/10.4028/www.scientific.net/amr.236-238.604.

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The electrolyte flow states of all vanadium redox flow battery (VRB) have a direct effect on the battery performance and life. To reveal the electrolyte distribution in the battery, the computation fluid dynamics (CFD) method was used to simulate a parallel flow field. A hydraulics experiment and a battery performance experiment were carried out to confirm the simulated results. The results show that the predicted information agreed well with the experimental results. The electrolyte has a concentrated distribution in the central region of the parallel flow field and the disturbed flow and the

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24

Zhong, Longchun, and Fengming Chu. "A Novel Biomimetic Lung-Shaped Flow Field for All-Vanadium Redox Flow Battery." Sustainability 15, no. 18 (2023): 13613. http://dx.doi.org/10.3390/su151813613.

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The all-vanadium redox flow battery (VRFB) was regarded as one of the most potential technologies for large-scale energy storage due to its environmentally friendliness, safety and design flexibility. The flow field design and mass transfer performance in the porous electrodes were some of the main factors to influence the battery performance. A novel biomimetic lung-shaped flow field was designed, and the battery performance was compared with the serpentine flow field by numerical simulation analysis. The results showed that the charging voltage of the VRFB was reduced by about 5.34% when SOC

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25

Huo, Yongjie, Xueqi Xing, Cuijuan Zhang, Xiang Wang, and Yongdan Li. "An all organic redox flow battery with high cell voltage." RSC Advances 9, no. 23 (2019): 13128–32. http://dx.doi.org/10.1039/c9ra01514k.

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26

Sanz, Laura, David Lloyd, Eva Magdalena, Jesús Palma, Marc Anderson, and Kyösti Kontturi. "Study and characterization of positive electrolytes for application in the aqueous all-copper redox flow battery." Journal of Power Sources 278 (March 2015): 175–82. http://dx.doi.org/10.1016/j.jpowsour.2014.12.034.

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27

Chai, Jingchao, Amir Lashgari, Xiao Wang, Caroline K. Williams, and Jianbing “Jimmy” Jiang. "All-PEGylated redox-active metal-free organic molecules in non-aqueous redox flow battery." Journal of Materials Chemistry A 8, no. 31 (2020): 15715–24. http://dx.doi.org/10.1039/d0ta02303e.

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A non-aqueous redox flow battery based on all-PEGylated, metal-free compounds is presented. The PEGylation enhances the stability of the redox-active materials, alleviating crossover by increasing the anolyte and catholyte species’ molecular sizes.

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28

Roberts, Edward, Mohammad Rahimi, Asghar Molaei Dehkordi, Fatemeh ShakeriHosseinabad, Maedeh Pahlevaninezhad, and Ashutosh Kumar Singh. "(Invited) Redox Flow Battery Innovation." ECS Meeting Abstracts MA2022-01, no. 3 (2022): 483. http://dx.doi.org/10.1149/ma2022-013483mtgabs.

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Flow battery innovations should offer significant improvements in performance, without compromising the durability / lifetime, and be cost-effective and scalable. The presentation will review some of the progress that has been made to enhance flow battery performance, and will discuss a number of recent innovations that aim to deliver these characteristics. These will include: Magnetic flowable electrodes applied in a polysulfide-iodide flow battery. Using flow through the current feeder to enhance mass transport and enable dendrite free zinc deposition in the zinc-iodide flow battery. Graphen

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29

Zhang, Ye-Qi, Guang-Xu Wang, Ru-Yi Liu, and Tian-Hu Wang. "Operational Parameter Analysis and Performance Optimization of Zinc–Bromine Redox Flow Battery." Energies 16, no. 7 (2023): 3043. http://dx.doi.org/10.3390/en16073043.

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Zinc–bromine redox flow battery (ZBFB) is one of the most promising candidates for large-scale energy storage due to its high energy density, low cost, and long cycle life. However, numerical simulation studies on ZBFB are limited. The effects of operational parameters on battery performance and battery design strategy remain unclear. Herein, a 2D transient model of ZBFB is developed to reveal the effects of electrolyte flow rate, electrode thickness, and electrode porosity on battery performance. The results show that higher positive electrolyte flow rates can improve battery performance; how

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30

Pahlevaninezhad, Maedeh, Ashutosh Kumar Singh, Thomas Storwick, et al. "An Advanced Composite Membrane for the All-Vanadium Redox Flow Battery." ECS Meeting Abstracts MA2022-01, no. 3 (2022): 466. http://dx.doi.org/10.1149/ma2022-013466mtgabs.

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Redox flow batteries (RFBs) are a promising technology for grid scale stationary energy storage to complement renewable energy systems. These batteries have a relatively low energy density; however, they offer important advantages, including: long life-time; decoupled energy (arbitrarily large electrolyte volume) and power (electrode area); high round-trip efficiency; scalability and design flexibility; fast response; and low environmental impacts. These advantages make them superior to many energy storage technologies for stationary applications [1-4]. Among the various types of RFBs, vanadiu

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31

Hendriana, Dena, Mochamad Hamdan Aziz, Yohanes Acep Nanang Kardana, Muhamad Lutfi Rachmat, Gembong Baskoro, and Henry Nasution. "Self-Discharging and Corrosion Problems in Vanadium Redox Flow Battery." Reaktor 22, no. 3 (2023): 77–85. http://dx.doi.org/10.14710/reaktor.22.3.77-85.

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Vanadium redox flow battery (VRFB) has a potential for large energy storage system due to its independence of energy capacity and power generation. VRFB is known to have challenges of high price, corrosion problem and lower energy efficiency. In this work, VRFB prototype with all components from existing parts sold in the market has been assembled and tested. Estimated electrochemical reactions are discussed for initial charging process with Vanadium Pentoxide powder as initial state to obtain fully charged battery state with V2+ ion in anolyte and VO2 + ion in catholyte. Material corrosion te

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32

Yesilyurt, Muhammed Samil, and Huseyin Ayhan Yavasoglu. "An All-Vanadium Redox Flow Battery: A Comprehensive Equivalent Circuit Model." Energies 16, no. 4 (2023): 2040. http://dx.doi.org/10.3390/en16042040.

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In this paper, we propose a sophisticated battery model for vanadium redox flow batteries (VRFBs), which are a promising energy storage technology due to their design flexibility, low manufacturing costs on a large scale, indefinite lifetime, and recyclable electrolytes. Primarily, fluid distribution is analysed using computational fluid dynamics (CFD) considering only half-cells. Based on the analysis results, a novel model is developed in the MATLAB Simulink environment which is capable of identifying both the steady-state and dynamic characteristics of VRFBs. Unlike the majority of publishe

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33

Bao, Jie, Yunxiang Chen, Peiyuan Gao, et al. "Semi-Analytical Model for Hybrid and Redox Targeting Flow Battery Systems." ECS Meeting Abstracts MA2024-01, no. 3 (2024): 552. http://dx.doi.org/10.1149/ma2024-013552mtgabs.

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Redox flow battery represents an economically viable energy storage technology that can integrate intermittent renewable energies from solar and wind power into existing electric grids. Besides the conventional all-liquid redox flow battery, there are two different architectures of flow batteries: hybrid and redox targeting flow batteries. Because the reactive solid phase is involved in the system, the energy storage density increases significantly. Therefore, they are considered as ones of the potential solutions for the future large-scale deployment of long-duration energy storage systems (L

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34

Peljo, Pekka, Heron Vrubel, Véronique Amstutz, et al. "All-vanadium dual circuit redox flow battery for renewable hydrogen generation and desulfurisation." Green Chemistry 18, no. 6 (2016): 1785–97. http://dx.doi.org/10.1039/c5gc02196k.

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35

Dong-Yang, LIU, CHENG Jie, PAN Jun-Qing, WEN Yue-Hua, CAO Gao-Ping, and YANG Yu-Sheng. "All-Lead Redox Flow Battery in a Fluoroboric Acid Electrolyte." Acta Physico-Chimica Sinica 27, no. 11 (2011): 2571–76. http://dx.doi.org/10.3866/pku.whxb20111105.

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36

Alkhayri, Fahad, and C. Adam Dyker. "A Bispyridinylidene Anolyte for an All-Organic Redox Flow Battery." ECS Meeting Abstracts MA2020-01, no. 1 (2020): 112. http://dx.doi.org/10.1149/ma2020-011112mtgabs.

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37

Zhen, Yihan, Cuijuan Zhang, Jiashu Yuan, Yicheng Zhao, and Yongdan Li. "A high-performance all-iron non-aqueous redox flow battery." Journal of Power Sources 445 (January 2020): 227331. http://dx.doi.org/10.1016/j.jpowsour.2019.227331.

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38

Luo, Tao, Oana David, Youri Gendel, and Matthias Wessling. "Porous poly(benzimidazole) membrane for all vanadium redox flow battery." Journal of Power Sources 312 (April 2016): 45–54. http://dx.doi.org/10.1016/j.jpowsour.2016.02.042.

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39

Anwar, M. Shariq, and Arindam Sarkar. "A Low Voltage, High Current All-Tungsten Redox Flow Battery." ECS Meeting Abstracts MA2022-02, no. 2 (2022): 140. http://dx.doi.org/10.1149/ma2022-022140mtgabs.

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With the exponential growth of electricity generation using intermittent renewable power sources, there is a need for affordable energy storage. For grid level storage in past years, redox flow batteries (RFB) have drawn considerable attention. Most successful RFBs till now are all-vanadium RFB and all-iron RFB. But these RFBs have a few drawbacks associated with them like; First RFB developed by NASA[1], Iron-chromium RFB, had problems of ions crossing over; all-iron RFB [2] have a problem of hydrogen evolution reaction (HER) at the negative electrode which causes capacity decay; and the comm

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40

Al-Fetlawi, H., A. A. Shah, and F. C. Walsh. "Non-isothermal modelling of the all-vanadium redox flow battery." Electrochimica Acta 55, no. 1 (2009): 78–89. http://dx.doi.org/10.1016/j.electacta.2009.08.009.

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41

Brushett, Fikile R., John T. Vaughey, and Andrew N. Jansen. "An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery." Advanced Energy Materials 2, no. 11 (2012): 1390–96. http://dx.doi.org/10.1002/aenm.201200322.

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42

Kabtamu, Daniel Manaye, Guan-Yi Lin, Yu-Chung Chang, et al. "The effect of adding Bi3+ on the performance of a newly developed iron–copper redox flow battery." RSC Advances 8, no. 16 (2018): 8537–43. http://dx.doi.org/10.1039/c7ra12926b.

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In this paper, we propose a new, abundant, cost-effective, non-toxic, and environmentally benign iron–copper redox flow battery (Fe/Cu RFB), which employs Fe<sup>2+</sup>/Fe<sup>3+</sup> and Cu<sup>+</sup>/Cu<sup>0</sup> as the positive and negative electrolytes, respectively.

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43

Ibanez, Santiago Enrique, Paula Navalpotro, Ignacio Almonacid, Eduardo Pedraza, and Rebeca Marcilla. "Close Contact without Mixing: All-Aqueous Membrane-Free Flow Battery." ECS Meeting Abstracts MA2022-01, no. 48 (2022): 1996. http://dx.doi.org/10.1149/ma2022-01481996mtgabs.

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The accumulation of energy produced by renewable sources to be used when demand is high is a key aspect of a truly decarbonized grid. Among all energy accumulation technologies, Redox Flow Batteries (RFBs) are specially promising due to its safety, flexibility of design and the ability to decouple capacity and power of the system. In a standard configuration, both redox electrolytes that are stored in external tanks are pumped in the electrochemical reactor separated only by an ion-selective membrane. This membrane is a critical part of the battery as it allows the selective pass of certain io

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44

Er, Süleyman, Changwon Suh, Michael P. Marshak, and Alán Aspuru-Guzik. "Computational design of molecules for an all-quinone redox flow battery." Chemical Science 6, no. 2 (2015): 885–93. http://dx.doi.org/10.1039/c4sc03030c.

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45

Cross, Nicholas R., Matthew J. Rau, Serguei N. Lvov, Christopher A. Gorski, Bruce E. Logan, and Derek M. Hall. "The Impacts of Electrolyte Composition on Key Performance Metrics of the All-Aqueous Copper Thermally Regenerative Ammonia Battery." ECS Meeting Abstracts MA2022-01, no. 1 (2022): 98. http://dx.doi.org/10.1149/ma2022-01198mtgabs.

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A significant amount of the potential energy that is generated during energy harvesting worldwide is discarded as waste heat because of inefficient power generation cycles. Much of this wasted power source goes unused because it is trapped as low-grade thermal energy (< 100 °C), which traditional power cycles cannot viably harness. With the advent of electrochemical power systems such as redox flow batteries and fuel cells, researchers are investigating new methods of providing usable electric power from these unused low-grade thermal energy sources. The thermally regenerative ammonia batte

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46

Rohan, James F., Declan P. Casey, Giampaolo Lacarbonara, et al. "(Digital Presentation) Electrolyte Optimisation for Copper Deposition and Dissolution in Redox Flow Batteries." ECS Meeting Abstracts MA2022-01, no. 3 (2022): 511. http://dx.doi.org/10.1149/ma2022-013511mtgabs.

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Aqueous copper redox flow batteries (CuRFB) based systems offer an alternative, more sustainable, redox flow battery to those based on vanadium for stationary renewable energy storage. Copper is an abundant material (~20 million tonnes/ year), that can be easily recycled and is significantly lower cost (6.5 € kg -1), by comparison with vanadium technology (20 € kg-1)[i]. CuRFBs can also be operated without perfluorinated membranes required in the vanadium redox flow batteries (VRFB). The CuRFB system takes advantage of the three stable oxidation states of copper Cu(0)-Cu(I)–Cu(II) in which the

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47

Düerkop, Dennis, Hartmut Widdecke, Carsten Schilde, Ulrich Kunz, and Achim Schmiemann. "Polymer Membranes for All-Vanadium Redox Flow Batteries: A Review." Membranes 11, no. 3 (2021): 214. http://dx.doi.org/10.3390/membranes11030214.

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Redox flow batteries such as the all-vanadium redox flow battery (VRFB) are a technical solution for storing fluctuating renewable energies on a large scale. The optimization of cells regarding performance, cycle stability as well as cost reduction are the main areas of research which aim to enable more environmentally friendly energy conversion, especially for stationary applications. As a critical component of the electrochemical cell, the membrane influences battery performance, cycle stability, initial investment and maintenance costs. This review provides an overview about flow-battery ta

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Kortekaas, Luuk, Sebastian Fricke, Aleksandr Korshunov, Isidora Cekic-Laskovic, Martin Winter, and Mariano Grünebaum. "Building Bridges: Unifying Design and Development Aspects for Advancing Non-Aqueous Redox-Flow Batteries." Batteries 9, no. 1 (2022): 4. http://dx.doi.org/10.3390/batteries9010004.

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Abstract:

Renewable energy sources have been a topic of ever-increasing interest, not least due to escalating environmental changes. The significant rise of research into energy harvesting and storage over the years has yielded a plethora of approaches and methodologies, and associated reviews of individual aspects thereof. Here, we aim at highlighting a rather new avenue within the field of batteries, the (noaqueous) all-organic redox-flow battery, albeit seeking to provide a comprehensive and wide-ranging overview of the subject matter that covers all associated aspects. This way, subject matter on a

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Sreenath, Sooraj, Nitish Kumar Sharma, and Rajaram K. Nagarale. "Alkaline all iron redox flow battery with a polyethylene/poly(styrene-co-divinylbenzene) interpolymer cation-exchange membrane." RSC Advances 10, no. 73 (2020): 44824–33. http://dx.doi.org/10.1039/d0ra08316j.

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Ding, Yu, Yu Zhao, Yutao Li, John B. Goodenough, and Guihua Yu. "A high-performance all-metallocene-based, non-aqueous redox flow battery." Energy & Environmental Science 10, no. 2 (2017): 491–97. http://dx.doi.org/10.1039/c6ee02057g.

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Abstract:

An all-metallocene based redox flow battery was constructed using ferrocene catholyte and cobaltocene anolyte with a working potential of ∼1.7 V. The potential can be lifted to 2.1 V via rational functionalization of metallocenes, showing the promise of metallocenes as electroactive materials for stationary energy storage.

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