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Relevant bibliographies by topics / Allyl halides

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Academic literature on the topic 'Allyl halides'

Author: Grafiati

Published: 4 June 2021

Last updated: 14 February 2022

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Journal articles on the topic "Allyl halides"

1

Mei, Tian-Sheng, Yue-Gang Chen, Xue-Tao Xu, Kun Zhang, Yi-Qian Li, Li-Pu Zhang, and Ping Fang. "Transition-Metal-Catalyzed Carboxylation of Organic Halides and Their Surrogates with Carbon Dioxide." Synthesis 50, no. 01 (September 13, 2017): 35–48. http://dx.doi.org/10.1055/s-0036-1590908.

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Carbon dioxide is not only an essential component of ‘greenhouse gases’, but also an abundant, renewable C1 feedstock in organic synthesis. The catalytic incorporation of carbon dioxide into value-added chemicals to produce carboxylic acids has received enormous attention. This review summarizes recent developments in the transition-metal-catalyzed carboxylation of organic halides and their surrogates, such as aryl, vinyl, and alkyl halides and pseudohalides.1 Introduction2 Carboxylation of Aryl Halides and Pseudohalides3 Carboxylation of Vinyl Halides and Pseudohalides4 Carboxylation of Benzyl Halides and Pseudohalides5 Carboxylation of Allyl Halides and Pseudohalides6 Carboxylation of Propargyl Halides and Pseudohalides7 Carboxylation of Alkyl Halides and Pseudohalides8 Direct Carboxylation of C–H Bonds9 Conclusions and Perspectives

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2

Peppe, Clovis, and Liérson Borges de Castro. "On the reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur and selenium) towards organyl halides for the synthesis of organyl phenyl chalcogenides." Canadian Journal of Chemistry 87, no. 5 (May 2009): 678–83. http://dx.doi.org/10.1139/v09-043.

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The reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur, selenium) towards organyl halides (organyl = alkyl, allyl, benzyl, acyl) was examined. A practical one-pot method to prepare organyl phenyl chalcogenides from indium metal and diphenyl dichalcogenide was found. The coupling is fairly broad in scope and generally works better for organyl halides capable to produce stable carbocations.

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Wang, Shao-Fang, and John Warkentin. "Alkylation of tert-butyl lithiohydrazones of aldehydes and ketones." Canadian Journal of Chemistry 66, no. 9 (September 1, 1988): 2256–58. http://dx.doi.org/10.1139/v88-358.

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Treatment of the tert-butylhydrazones of formaldehyde, acetaldehyde, and acetone with butyllithium afforded the corresponding tert-butyl lithiohydrazones, which were alkylated with alkyl, allyl, and benzyl halides. Fourteen new tert-butylazo compounds were prepared in yields ranging from 38 to 86%.

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Khurana, Jitender M., Sanjay Kumar, and Bhaskara Nand. "Facile reductive dehalogenation of organic halides with nickel boride at ambient temperature." Canadian Journal of Chemistry 86, no. 11 (November 1, 2008): 1052–54. http://dx.doi.org/10.1139/v08-156.

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The hydrodehalogenation of a series of aryl, alkyl, allyl, and benzyl chlorides, bromides, and iodides has been carried out efficiently using nickel boride in methanol at ambient temperature, leading to the corresponding products resulting from hydrogen/halogen exchange.Key words: hydrodehalogenation, reduction, organic halides, sodium borohydride, nickel boride.

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5

Huval, Chad C., and Daniel A. Singleton. "Direct free-radical substitutions on allyl and vinyl halides using alkyl halides/hexabutylditin." Tetrahedron Letters 34, no. 19 (May 1993): 3041–42. http://dx.doi.org/10.1016/s0040-4039(00)93373-2.

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6

Verhé, R., N. De Kimpe, L. De Buyck, D. Courtheyn, L. van Caenegem, and N. Schamp. "Reactivity of Electrophilic Allyl Halides." Bulletin des Sociétés Chimiques Belges 92, no. 4 (September 1, 2010): 371–96. http://dx.doi.org/10.1002/bscb.19830920407.

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7

Karabiyikoglu, Sedef, Alexandre V. Brethomé, Thomas Palacin, Robert S. Paton, and Stephen P. Fletcher. "Enantiomerically enriched tetrahydropyridine allyl chlorides." Chemical Science 11, no. 16 (2020): 4125–30. http://dx.doi.org/10.1039/d0sc00377h.

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Enantiomerically enriched allyl halides are rare due to their configurational lability. Stable piperidine-based allyl chloride enantiomers can be produced via kinetic resolution, and undergo highly enantiospecific catalyst-free substitutions.

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Schäfer, Philipp, Mireia Sidera, Thomas Palacin, and Stephen P. Fletcher. "Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides." Chemical Communications 53, no. 93 (2017): 12499–511. http://dx.doi.org/10.1039/c7cc07151e.

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9

Hassan, Mohamed Ezeldin. "Palladium-catalyzed cross-coupling reaction of organostannanes with nucleoside halides." Collection of Czechoslovak Chemical Communications 56, no. 9 (1991): 1944–47. http://dx.doi.org/10.1135/cccc19911944.

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A general reaction is described for the synthesis of C-5 substituted nucleosides through the coupling of organostannanes with nucleoside-palladium intermediate derived in situ from 5-iodouridine (or 5-iodo-2’-deoxyuridine) and [PdCl2(PPh3)2]. The reaction was used for the synthesis of C-5 aryl, heteroaryl, vinyl, allyl and alkyl substituted nucleosides.

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Musalov, Maxim V., Vladimir A. Potapov, and Svetlana V. Amosova. "Efficient Synthesis of a New Family of 2,6-Disulfanyl-9-Selenabicyclo[3.3.1]Nonanes." Molecules 26, no. 10 (May 11, 2021): 2849. http://dx.doi.org/10.3390/molecules26102849.

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The efficient synthesis of a new family of 2,6-disulfanyl-9-selenabicyclo[3.3.1]nonanes in high yields has been developed based on 9-selenabicyclo[3.3.1]nonane-2,6-dithiolate anion generated from bis-isothiouronium salt of 2,6-dibromo-9-selenabicyclo[3.3.1]nonane. The derivatives of 2,6-disulfanyl-9-selenabicyclo[3.3.1]nonane containing alkyl, allyl and benzyl moieties have been prepared in 90–99% yields by nucleophilic substitution of 9-selenabicyclo[3.3.1]nonane-2,6-dithiolate anion with alkyl, allyl and benzyl halides. The reaction of nucleophilic addition of 9-selenabicyclo[3.3.1]nonane-2,6-dithiolate anion to alkyl propiolates afforded 2,6-di(vinylsulfanyl)-9-selenabicyclo[3.3.1]nonanes. The conditions for regio- and stereoselective addition of 9-selenabicyclo[3.3.1]nonane-2,6-dithiolate anion to a triple bond of alkyl propiolates have been found. To date, not a single representative of 2,6-disulfanyl-9-selenabicyclo[3.3.1]nonanes has been described in the literature.

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Dissertations / Theses on the topic "Allyl halides"

1

Argyropoulos, John N. "Single electron transfer in the reactions of aromatic ketones and alkyl halides with enolates and alkoxides." Diss., Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/27690.

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Ridlehuber, Richard Walter. "The mechanism of reaction of alkyl halides with diphenylphosphides." Thesis, Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/26812.

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Pham, Tung Ngoc. "Single electron transfer in reactions involving alkyl halides with nucleophiles." Diss., Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/27353.

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Coleman, David Thornton III. "Involvement of radical intermediates in the reaction of alkyl halides with cuprates, the cannizzaro reaction, and the wittig reaction." Diss., Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/27688.

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Zhou, Jianrong (Jianrong Steve). "Cross-coupling reactions of unactivated alkyl halides." Thesis, Massachusetts Institute of Technology, 2005. http://hdl.handle.net/1721.1/33655.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2005.
Vita.
Includes bibliographical references.
My graduate research at MIT has been focused on the development of palladium- or nickel-catalyzed cross-coupling reactions using unactivated alkyl electrophiles (e.g., halides and sulfonates). Although aryl and alkenyl electrophiles have been commonly used in such processes, the utility of alkyl substrates has been underdeveloped, and merits further exploration. We have developed the first palladium-based catalyst that is effective for Negishi couplings of primary alkyl electrophiles. A single protocol (2%Pd₂(dba)₃/8%P(Cyp)₃/NMI in THF/NMP at 80⁰C) can be applied to a broad spectrum of electrophiles, including chlorides, bromides, iodides, and tosylates. Concerning the scope of the nucleophilic components, an array of alkyl-, alkenyl-, and arylzinc halides can be coupled. The process is tolerant of a variety of functional groups, including esters, amides, imides, nitriles, and heterocycles. Furthermore, geometrically- defined alkenylzinc species, generated from titanium-mediated hydrozincation of internal alkynes, can be directly used in the process. Despite the progress in nickel- and palladium-catalyzed C(sp³)-C(sp³) bond formation, the methods had been limited to primary alkyl electrophiles.
(cont.) No doubt, the ability to use more challenging, secondary ones will further augment the usefulness of these metal- catalyzed processes. To this end, we have determined that Ni(cod)₂/s-Bu-Pybox can catalyze room-temperature Negishi couplings of an array of functionalized alkyl bromides and iodides. To the best of our knowledge, this is the first nickel- or palladium- catalyzed cross-coupling procedure for unactivated, [beta]-hydrogen-containing secondary alkyl halides. In addition, preliminary studies using substrate-based probes suggest that the oxidative addition proceeds through a radical pathway. This may explain the unparalleled reactivity of the nickel catalyst. As an extension of the nickel catalysis, we have established that the combination of Ni(cod)₂ and bathophenanthroline can effect Suzuki reactions of secondary halides and organoboronic acids. These organoboron reagents are particularly widely used in the cross-coupling chemistry, owing to their chemical stability, biological non-toxicity, and commercial availability. Again, mechanistic evidence has been collected to support the involvement of organic radicals during the oxidative addition step.
by Jianrong (Steve) Zhou.
Ph.D.

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6

Kanyi, Charles Wairagu. "Chemistry of the Faujasite zeolites (X, Y) with alkyl halides and other systems and the effects of sodium treatment on this chemistry." Diss., Online access via UMI:, 2007.

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7

Park, Bongjin. "Single electron transfer in reactions involving alkyl halides with lithium alkylamide, lithium alkyl and lithium metal." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/27052.

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8

Collingwood, S. P. "New applications of isoureas in synthesis." Thesis, University of Newcastle Upon Tyne, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.378325.

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9

Whitehead, Thomas William 1951. "Sorption and desorption of volatile alkyl halides in a desert soil." Thesis, The University of Arizona, 1987. http://hdl.handle.net/10150/191936.

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A series of twelve laboratory column experiments were conducted to determine equilibrium partitioning coefficients (K ) and kinetic rate coefficients for sorption of four hydrophobic pollutants on a low organic carbon natural soil. K 's for trichloroethene (ICE), tetrachloroethene (PCE), 1,1,1-trichloroethane (TCA), and 1,1,2,2-tetrachloroethane (PCA), were 0.17, 0.44, 0.06, and 0.05, respectively; about as expected based on empirical carbon-based partitioning equations found in the literature. Tailing of the breakthrough curves could be accounted for with a two-site non-equilibrium solute transport model. Rates were fast compared to pore water velocities normally encountered in an alluvial aquifer, but kinetic effects were observed at pore water velocities likely to be encountered during pumping, such as for site cleanup. Desorption was faster than adsorption, with forward rates of about 10⁻⁴ to 10⁻⁵ s⁻¹ and reverse rates about 10⁻³ to 10⁻⁴ s⁻¹. The two-site model indicated that slower sites constituted roughly half the total number of sites.

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10

Ursinyova, Nina. "Cyclic sulfamidates as pseudo-alkyl halides in Sp3 -based cross-coupling chemistry." Thesis, University of Bristol, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.680108.

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The use of cyclic sulfamidates as pseudo-alkyl halides in Sp3 -based cross-coupling chemistry has been studied and two approaches were explored. The first approach involved a transition metal-mediated cross-coupling of cyclic sulfamidates, including studies into the oxidative addition step of the catalytic cycle. Various transition metal catalysts (palladium, nickel and iron) and nucleophiles (zinc, boron, magnesium and tin reagents) were investigated. After extensive screening, the desired cross-coupling was achieved under palladium-catalysed Suzuki-Miyaura conditions, albeit in a low yield (20%) and with poor mass recovery. The second approach, via enantiomerically pure f3- and y-aminoalkyl boronic esters, required development of efficient conditions for borylation of cyclic sulfamidates. A range of known and novel 1,2- and 1,3-cyclic sulfamidates was synthesised and subjected to the optimised borylation conditions to determine the scope of this transformation. Mechanism of the copper-catalysed borylation process was also explored, together with the utility of boronic esters in sp3 _Sp2 and Sp3 _sp3 cross-coupling reactions. Aminoalkyl boronic esters (from borylation of cyclic sulfamidates) were also assessed as possible substrates for Matteson homologation. After extensive screening, it was found that f3-aminoalkyl boronic esters (from 1,2-cyclic sulfamidates) can be homologated in a 50% yield, while y-aminoalkyl boronic esters are completely unreactive to a range of homologation conditions.

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Books on the topic "Allyl halides"

1

McDonagh, Reman. Solubilisation of arsenic, gallium arsenide and tin by alkyl halides. Leicester: De Montfort University, 1993.

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2

Methods for the oxidation of organic compounds: Alcohols, alcohol derivatives, alkyl halides ... London: Academic Press, 1988.

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3

Haines, Alan H. Methods for the oxidation of organic compounds: Alcohols, alcohol derivatives, alkyl halides, nitroalkanes, alkyl azides, carbonyl compounds, hydroxyarenes and aminoarenes. London: Academic, 1988.

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4

Harris, Nathan. Molecular orbital studies of heterosubstituted allyl and vinyl carbanions. 1991.

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5

White, William. The application of polystyrene bound tin hydride to a continuous flow reactor system for the reduction of alkyl and aryl halides. 1990.

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6

Pike, Philip Willard. Alkyl additions to olefins by Tri-n-butylgermanium hydride reduction of alkyl halides and hydrogen abstraction from triorganotin hydrides by the 5-hexenyl radical. 1987.

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Book chapters on the topic "Allyl halides"

1

Wreford, S. S., R. Pankayatselvan, and K. M. Nicholas. "π-Allyl Metal Complexes by Reaction with the Corresponding Metal Halides." In Inorganic Reactions and Methods, 18–35. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145265.ch2.

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2

Bellama, J. M. "By Hydrogen and Alkyl Halides." In Inorganic Reactions and Methods, 295–97. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch220.

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Bellama, J. M. "By Hydrogen and Alkyl Halides." In Inorganic Reactions and Methods, 302–4. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch223.

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Bellama, J. M. "By Hydrogen and Alkyl Halides." In Inorganic Reactions and Methods, 309–10. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch230.

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Poller, R. C. "By Reaction with Alkyl Halides." In Inorganic Reactions and Methods, 269–72. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch119.

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6

Bellama, J. M. "By Hydrogen, Alkyl and Other Halides." In Inorganic Reactions and Methods, 318–19. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch238.

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7

Davies, A. G. "17.11.1 Radical cations of alkyl halides." In Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2, 566–68. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-87641-0_56.

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8

Page, E. M. "Of Transition-Metal Halides by Oxidative Addition by Alkyl Halides." In Inorganic Reactions and Methods, 185. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch113.

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9

Sarkar, T. K. "From Allyl Halides." In Compounds of Groups 15 (As, Sb, Bi) and Silicon Compounds, 1. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-004-00949.

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Evano, G. "Of Allyl Halides." In Three Carbon-Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-020-00109.

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Conference papers on the topic "Allyl halides"

1

McDonald, J. K., J. A. Merritt, and S. P. McManus. "Laser-induced chemistry of the allyl halides." In AIP Conference Proceedings Volume 146. AIP, 1986. http://dx.doi.org/10.1063/1.35944.

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2

Stepin, S. N., T. A. u. Holmurodov, and O. O. u. Mirzaev. "ОРГАНИЧЕСКИЙ СИНТЕЗ ВЫСОКОМОЛЕКУЛЯРНЫХ СОЕДИНЕНИЙ." In Nauka. Issledovaniia. Praktika: sbornik izbrannyh statei po materialam Mezhdunarodnoi nauchnoi konferencii (Sankt-Peterburg, Fevral` 2020). ГНИИ "Нацразвитие", 2020. http://dx.doi.org/10.37539/srp289.2020.13.60.005.

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в данной работе приводятся результаты исследования реакции алкилирования 2-тиоксо-6-фенилпиримидин-4-она алкилгалогенидами C4-C9. Показано, что в зависимости от условий реакции и соотношения реагентов образуются продукты N-3 алкилированияthis article presents the results of the alkylation reaction of 2-thio-6- phenylpyrimidin-4-one with C4-C9 alkyl halides. The results show that, depending on the reaction conditions and the ratio of reagents, N-3 alkylation products are formed.

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3

Liu, Yu, and Ruben Martin. "Metal-catalyzed direct carboxylation of unactivated alkyl halides with CO2." In 15th Brazilian Meeting on Organic Synthesis. São Paulo: Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201362534256.

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Ghahremani, Amir H., and Thad Druffel. "Intense Pulse Light Annealing for Perovskite Photovoltaics." In ASME 2020 15th International Manufacturing Science and Engineering Conference. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/msec2020-8394.

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Abstract Rapid advancements within photovoltaics realm necessitates swift fabrication of the modules using cheap materials through cost effective manufacturing processes to achieve short cost payback time. Photovoltaics manufacturing includes chemical processing of the materials followed by thermal annealing. Yet, long-term annealing of the materials using high temperature furnaces have remained the prevalent post-processing approach in industry which necessitates alternative methods to achieve high performance modules through rapid and economical processes. Intense pulse light (IPL) has been successfully applied as a promising rapid post-process annealing for various thin film photovoltaics, particularly to process the organic-inorganic perovskite solar cell (PSC) layers. In this paper, several results pertinent to the application of IPL on perovskite and SnO2 electron transport thin films are presented and the role of IPL on rapid thermal annealing (RTA) is explained. We show that swift fabrication of PSCs through IPL can result in efficiencies exceeding 16% when the Perovskite film is annealed with aid of CH2I2 alkyl halide additive in the ambient with 60% relative humidity. In addition, the synergy of IPL-alkyl halide interaction for other perovskite chemistries is introduced. We show that achieving to PSCs exceeding 12% efficiency was possible when the perovskite and SnO2 ETL was annealed sequentially through IPL.

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Montserrat Martínez, M., Marc Snapper, and Zhen You. "SYNTHESIS OF HIGHLY FUNCTIONALIZED NON-RACEMIC CHIRAL ALKYL HALIDES USING KHARASCH ADDITION." In The 13th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00182.

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Pranszke, B. "Steric effects in the chemiluminescent reactions of metastable Ca*(3P) atoms with isomeric alkyl halides." In IV Workshop on Atomic and Molecular Physics, edited by Jozef Heldt. SPIE, 2003. http://dx.doi.org/10.1117/12.544435.

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Nunes, Vanessa Lóren, (PG) Ingryd Cristina de Oliveira, and Olga S. do Rêgo Barros. "Copper(I)-Senelenophene-2-carboxylate Catalyzed Cross- Coupling of Aryl or alkyl Thiols And Aryl Halides." In 14th Brazilian Meeting on Organic Synthesis. São Paulo: Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0177-1.

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Tysoe, Wilfred T. "Understanding the Tribological Chemistry of Chlorine- and Sulfur- and Phosphorus-Containing Additives." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-63361.

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Chlorine- and sulfur- and phosphorus-containing compounds are commonly added to the base fluid to synthesize lubricants used under extreme-pressure (EP) conditions. Analyzing the resulting tribological films on iron reveals that chlorinated hydrocarbons thermally decompose forming a layer that consists of iron chloride (FeCl2) or carbide (Fe3C), and that dialkyldisulfides react to form FeS and Fe3C. Alkyl phosphates thermally decompose on iron oxide to form alkyl and alkoxy, as well as POx species, on the surface. The alkyl and alkoxy species thermally decompose on heating to evolve gas-phase products and deposit carbon onto the surface. The POx species rapidly diffuse into the oxide forming a film that consists of a carbonaceous layer covering a phosphate film. The tribological properties of evaporated and reactively grown thin films have been investigated in ultrahigh vacuum. This strategy eliminates contamination and allows films of known composition and structure to be grown on well-characterized substrates. Three tribological regimes are identified depending on film thickness. In the first regime, an initial rapid decrease in friction is found when a film that is a few nanometers thick (corresponding to a monolayer) covers the surface. The friction coefficient increases once again in the second regime as the film becomes thicker, due to the increased contact area between the film and the rough tribotip, and the behavior is well described by a modified Greenwood-Williamson model. A third regime is found when the film becomes thicker than the interfacial roughness, where the surfaces are completely separated by the film. Finally, measuring the friction coefficients of thin halide films deposited onto various substrates, where the local pressure at the asperity tips depends on the substrate hardness, shows that the shear strength of the “monolayer” films depends on pressure.

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Reports on the topic "Allyl halides"

1

Hanrahan, R. J. Radiation chemistry of hydrocarbon and alkyl halide systems: Final report, August 1, 1984--August 31, 1988 and summary report, 1963--1988. Office of Scientific and Technical Information (OSTI), January 1988. http://dx.doi.org/10.2172/6259817.

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