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Relevant bibliographies by topics / Allylic alcohols

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Academic literature on the topic 'Allylic alcohols'

Author: Grafiati

Published: 4 June 2021

Last updated: 18 February 2022

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Journal articles on the topic "Allylic alcohols"

1

Ficeri, Vlastimír, Peter Kutschy, Milan Dzurilla, and Ján Imrich. "[3,3]- Versus [1,3]-Sigmatropic Rearrangement of O-Substituted Allyl N-Acylmonothiocarbamates." Collection of Czechoslovak Chemical Communications 59, no. 12 (1994): 2650–62. http://dx.doi.org/10.1135/cccc19942650.

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Substituted allylic alcohols (2-buten-1-ol, 1-buten-3-ol, cinnamyl alcohol and 3-methyl-2-buten-1-ol) react with acyl isothiocyanates (4-chlorobenzoyl, 2,6-difluorobenzoyl, 3-phenylpropenoyl, 2-thienocarbonyl, 3-chloro-2-thienocarbonyl and 3-chloro-2-benzo[b]thienocarbonyl isothiocyanate) with the formation of highly reactive O-substituted allyl N-acylmonothiocarbamates, which either spontaneously or by heating in boiling benzene undergo [3,3]-sigmatropic rearrangement to S-substituted allyl N-acylmonothiocarbamates. The structure of S-esters with isomerized allylic group affords the unequivoc

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2

Wang, Jialiang, Wen Huang, Zhengxing Zhang, Xu Xiang, Ruiting Liu, and Xigeng Zhou. "FeCl3·6H2O Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol." Journal of Organic Chemistry 74, no. 9 (May 2009): 3299–304. http://dx.doi.org/10.1021/jo900070q.

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3

Cooper, Matthew A., and A. David Ward. "Hydroxyselenation of allylic alcohols." Tetrahedron Letters 36, no. 13 (March 1995): 2327–30. http://dx.doi.org/10.1016/0040-4039(95)00247-a.

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4

Harada, Kohei, Marina Nogami, Keiichi Hirano, Daisuke Kurauchi, Hisano Kato, Kazunori Miyamoto, Tatsuo Saito, and Masanobu Uchiyama. "Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates." Organic Chemistry Frontiers 3, no. 5 (2016): 565–69. http://dx.doi.org/10.1039/c6qo00009f.

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Chern, Ching-Yuh, Ching-Chun Tseng, Rong-Hong Hsiao, Fung Fuh Wong, and Yueh-Hsiung Kuo. "Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes." Heteroatom Chemistry 2019 (August 18, 2019): 1–8. http://dx.doi.org/10.1155/2019/5053702.

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This work reports an efficient method for the oxidation reaction of aliphatic, aromatic allylic, and benzylic alcohols into aldehydes catalyzed by the cyclopentadienyl ruthenium(II) complex (RuCpCl(PPh3)2) with bubbled O2. Through further optimizing controlled studies, the tendency order of oxidation reactivity was determined as follows: benzylic alcohols > aromatic allylic alcohols >> aliphatic alcohols. In addition, this method has several advantages, including a small amount of catalyst (0.5 mol%) and selective application of high discrimination activity of aliphatic, aromatic ally

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6

Akkarasamiyo, Sunisa, Somsak Ruchirawat, Poonsaksi Ploypradith та Joseph S. M. Samec. "Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols". Synthesis 52, № 05 (7 січня 2020): 645–59. http://dx.doi.org/10.1055/s-0039-1690740.

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The Suzuki–Miyaura reaction is one of the most powerful tools for the formation of carbon–carbon bonds in organic synthesis. The utilization of alcohols in this powerful reaction is a challenging task. This short review covers progress in the transition-metal-catalyzed Suzuki–Miyaura-type cross-coupling reaction of π-activated alcohol, such as aryl, benzylic, allylic, propargylic and allenic alcohols, between 2000 and June 2019.1 Introduction2 Suzuki–Miyaura Cross-Coupling Reactions of Aryl Alcohols2.1 One-Pot Reactions with Pre-activation of the C–O Bond2.1.1 Palladium Catalysis2.1.2 Nickel

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Hamada, Yoko, Rio Matsunaga, Tomoko Kawasaki-Takasuka, and Takashi Yamazaki. "Base-Mediated Claisen Rearrangement of CF3-Containing Bisallyl Ethers." Molecules 26, no. 14 (July 19, 2021): 4365. http://dx.doi.org/10.3390/molecules26144365.

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We have previously clarified that the strongly electron-withdrawing CF3 group nicely affected the base-mediated proton shift of CF3-containing propargylic or allylic alcohols to afford the corresponding α,β-unsaturated or saturated ketones, respectively, which was applied this time to the Claisen rearrangement after O-allylation of the allylic alcohols with a CF3 group, followed by isomerization to the corresponding allyl vinyl ethers via the proton shift, enabling the desired rearrangement in a tandem fashion, or in a stepwise manner, the latter of which was proved to have attained an excelle

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8

Jun, Chul-Ho, and Chang-Hee Lee. "Chelation-Assisted C–H and C–C Bond Activation of Allylic Alcohols by a Rh(I) Catalyst under Microwave Irradiation." Synlett 29, no. 06 (November 16, 2017): 736–41. http://dx.doi.org/10.1055/s-0036-1591697.

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Chelation-assisted Rh(I)-catalyzed ketone synthesis from allylic alcohols and alkenes through C–H and C–C bond activations under microwave irradiation was developed. Aldimine is formed via olefin isomerization of allyl alcohol under Rh(I) catalysis and condensation with 2-amino-3-picoline, followed by continuous C–H and C–C bond activations to produce a dialkyl ketone. The addition of piperidine accelerates the reaction rate by promoting aldimine formation under microwave conditions.

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Emayavaramban, Balakumar, Moumita Roy, and Basker Sundararaju. "Iron-Catalyzed Allylic Amination Directly from Allylic Alcohols." Chemistry - A European Journal 22, no. 12 (February 17, 2016): 3952–55. http://dx.doi.org/10.1002/chem.201505214.

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10

Berger, Anna Lucia, Karsten Donabauer, and Burkhard König. "Photocatalytic Barbier reaction – visible-light induced allylation and benzylation of aldehydes and ketones." Chemical Science 9, no. 36 (2018): 7230–35. http://dx.doi.org/10.1039/c8sc02038h.

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We report a photocatalytic version of the Barbier type reaction using readily available allyl or benzyl bromides and aromatic aldehydes or ketones as starting materials to generate allylic or benzylic alcohols.

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Dissertations / Theses on the topic "Allylic alcohols"

1

Brennan, Meabh B. "Chemo- and stereoselective oxidation of allylic amino alcohols." Thesis, University of Oxford, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.531953.

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Hackett, Simon F. J. "Selective Oxidation of Allylic Alcohols on Palladium Catalysts." Thesis, University of York, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.490272.

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This thesis concerns the selective aerobic oxidation of allylic alcohols over practical and model palladium c~alysts. The goal was to elucidate the nature of the active catalyst site and origin of deactivation, which have hindered industrial implementation of such systems. It is hoped that understanding such fundamental aspects of the catalytic process will help optimise futureÃ‚Â· catalysts exhibiting high turnover frequencies as well as longer lifetimes on-stream. To realise these goals wet-chemical inorganic materials synthesis has been married with Ultra High Vacuum (UHV) single crystal me

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3

Gao, Y. (Yun). "Synthesis and synthetic transformations of allylic alcohols, epoxy alcohols, and 1,2-cyclic sulfates." Thesis, Massachusetts Institute of Technology, 1988. http://hdl.handle.net/1721.1/14588.

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Khan, Afzal. "Synthesis and reactions of epoxides." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.286509.

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Peters, Byron. "Iridium Catalysed Asymmetric Hydrogenation of Olefins and Isomerisation of Allylic Alcohols." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-122419.

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The work described in this thesis is focused on exploring the efficacy of asymmetric iridium catalysis in the hydrogenation of challenging substrates, including precursors to chiral sulfones and chiral cyclohexanes. Furthermore, iridium catalysis was used to isomerise allylic alcohols to aldehydes, and in a formal total synthesis of Aliskiren (a renin inhibitor). A large variety of unsaturated sulfones (cyclic, acyclic, vinylic, allylic and homoallylic) were prepared and screened in the iridium catalysed hydrogenation reaction using a series of previously developed N,P-ligated Ir-catalysts. Th

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Smith, Torben J. N. "Enantioselective deprotonations of three membered rings." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243768.

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Lee, Wai-Man. "Stereocontrolled synthesis of polysubstituted tetrahydropyrans and #delta#-lactones via tandem [2,3]-Wittig-anionic oxy-Cope rearrangement." Thesis, University of Liverpool, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243034.

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Evans, Paul. "The epoxy Ramberg BaÌˆcklund rearrangement (ERBR) and related studies". Thesis, University of York, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265373.

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Otoo, Barnabas. "Conjugate Additions and Transposition of the Allylic Alcohols of Enol Ethers of 1, 2-Cyclohexanedione." Digital Commons @ East Tennessee State University, 2010. https://dc.etsu.edu/etd/1748.

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A variety of protected enolic forms of 1, 2-cyclohexanedione was prepared as substrates for conjugate addition studies using organocopper reagents. The sequence involved the enol ether preparation via the enolate, alkylation with an organometalic reagent, and oxidative rearrangement with pyridinium chlorochromate followed by the conjugate addition reactions. Protection of 1, 2-cyclohexanedione was achieved by reacting with chloro tert-butyldimethyl silane and subjected to alkylation. Steric problems were encountered and so an alternative protective group the methoxymethyl acetal was prepared a

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10

Qiu, Shuai. "Trifluoromethoxylation of Allylic Alcohols via 1,2-Aryl Migration Promoted by Visible Light-Mediated Photoredox Catalysis." Thesis, KTH, Skolan för kemi, bioteknologi och hälsa (CBH), 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-278836.

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Visible light photoredox catalysis has proven to be a powerful tool for promoting transformations in organic synthesis. Hence this project was carried out to develop tools for predicting reactivity patterns of visible light- promoted redox reactions. Fluorination is of immense importance in organic chemistry, and so is trifluoromethoxylation. The fluorination reaction has been studied for a long time and has been accomplished in milder ways, while the generation of a trifluoromethoxy-radical at room temperature and atmospheric pressure remains a challenge. The design of the reaction in this pr

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Books on the topic "Allylic alcohols"

1

Loutchnikov, Andrei. Rhodium-catalyzed coupling reactions of multisubstituted alkenes, arylsubstituted allylic amines, esters and alcohols with arylboronic acids in aqueous media. Ottawa: National Library of Canada, 2003.

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2

Kagaku Busshitsu Hyōka Kenkyū Kikō and Shin Enerugī Sangyō Gijutsu Sōgō Kaihatsu Kikō (Japan), eds. Ariru arukōru: Allyl alcohol. Tōkyō: Seihin Hyōka Gijutsu Kiban Kikō Kagaku Busshitsu Hyōka Kenkyū Kikō, 2009.

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3

Courtin, Helene L. Oxidation of allyl alcohol into glycerol by hydrogen peroxideoverTI-ZSM-5. Manchester: UMIST, 1994.

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4

Loutchinkov, Andrei. Rhodium-catalyzed coupling reactions of multisubstituted alkenes, arylsubstituted allylic amines, esters and alcohols with arylboronic acids in aqueous media. 2003, 2003.

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Book chapters on the topic "Allylic alcohols"

1

Surh, Young-Joon. "Sulfotransferase-Mediated Activation of Some Benzylic and Allylic Alcohols." In Advances in Experimental Medicine and Biology, 339–45. Boston, MA: Springer US, 1996. http://dx.doi.org/10.1007/978-1-4757-9480-9_41.

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2

Johnson, Roy A., and K. Barry Sharpless. "Asymmetric Oxidations and Related Reactions: Catalytic Asymmetric Epoxidation of Allylic Alcohols." In Catalytic Asymmetric Synthesis, 229–80. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0471721506.ch7.

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3

Fu, Ming-Chen. "Efficient Pd-Catalyzed Regio- and Stereoselective Carboxylation of Allylic Alcohols with Formic Acid." In Springer Theses, 77–105. Singapore: Springer Singapore, 2020. http://dx.doi.org/10.1007/978-981-15-7623-2_4.

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4

Hodgson, D. M., and P. G. Humphreys. "Allylic Substitution." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00495.

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Hodgson, D. M., and P. G. Humphreys. "Allylic Rearrangements." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00549.

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6

Eames, J. "Isomerization of Allylic Alcohols." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00341.

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7

Eames, J. "Hydroxylation of Allylic Alcohols." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00346.

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8

Eames, J. "Dihydroxylation of Allylic Alcohols." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00348.

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9

Eames, J. "Epoxidation of Allylic Alcohols." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00349.

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Eames, J. "Cyclopropanation of Allylic Alcohols." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00353.

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Conference papers on the topic "Allylic alcohols"

1

HENRIQUE FREIRE ARAUJO, LUIZ, José Augusto Rosário Rodrigues, FABIO NASARIO, and Paulo José Samenho Moran. "Biocatalytic Redox Reactions with Allylic Alcohols." In XXV Congresso de Iniciação Cientifica da Unicamp. Campinas - SP, Brazil: Galoa, 2017. http://dx.doi.org/10.19146/pibic-2017-78725.

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Lattanzi, Alessandra, Antonio Proto, and Arrigo Scettri. "Titanocenes Catalyzed Diastereoselective Epoxidation of Allylic Alcohols." In The 3rd International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1999. http://dx.doi.org/10.3390/ecsoc-3-01747.

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3

Tabarelli, Greice, Marcelo Godoi, Fábio Z. Galetto, and Antonio Luiz Braga. "Microwave-assisted solvent- and catalyst-free synthesis of allylic thioetheres from allylic alcohols." In 14th Brazilian Meeting on Organic Synthesis. São Paulo: Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0127-1.

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4

Rosário Rodrigues, José Augusto, and NatÁlia Maria Polidoro. "Cascade Redox Reactions with allylic alcohols in biocatalysis." In XXIII Congresso de Iniciação Científica da Unicamp. Campinas - SP, Brazil: Galoá, 2015. http://dx.doi.org/10.19146/pibic-2015-37703.

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Maria Polidoro, NatÁlia, José Augusto Rosário Rodrigues, FABIO NASARIO, and Paulo José Samenho Moran. "Biocatalytic redox reactions of allylic alcohols catalysed by microorgansims." In XXIV Congresso de Iniciação Científica da UNICAMP - 2016. Campinas - SP, Brazil: Galoa, 2016. http://dx.doi.org/10.19146/pibic-2016-51178.

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Oliveira, Caio C., and Carlos Roque D. Correia. "Studies on the Regio- and Enantioselective Heck Arylations of Acyclic Allylic Alcohols." In 15th Brazilian Meeting on Organic Synthesis. São Paulo: Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013913141742.

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Matyushov, V. F., A. L. Tolstov, L. V. Kobryna, P. S. Yaremov, V. G. Ilyin, and E. V. Lebedev. "Facile synthesis of catalytically active porous titanosilicates for liquid-phase epoxidation of allyl alcohol with hydrogen peroxide." In 2016 International Conference on Nanomaterials: Application & Properties (NAP). IEEE, 2016. http://dx.doi.org/10.1109/nap.2016.7757262.

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