Academic literature on the topic 'Alpha-arylation au palladium'

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Journal articles on the topic "Alpha-arylation au palladium"

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Nilsson, Kristina, and Anders Hallberg. "Regioselective palladium-catalyzed tandem .alpha.-arylation/isomerization of cyclic enamides." Journal of Organic Chemistry 55, no. 8 (1990): 2464–70. http://dx.doi.org/10.1021/jo00295a041.

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Cabri, Walter, Ilaria Candiani, Angelo Bedeschi, Sergio Penco, and Roberto Santi. ".alpha.-Regioselectivity in palladium-catalyzed arylation of acyclic enol ethers." Journal of Organic Chemistry 57, no. 5 (1992): 1481–86. http://dx.doi.org/10.1021/jo00031a029.

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Cabri, Walter, Ilaria Candiani, Angelo Bedeschi, and Roberto Santi. "Ligand-controlled .alpha.-regioselectivity in palladium-catalyzed arylation of butyl vinyl ether." Journal of Organic Chemistry 55, no. 11 (1990): 3654–55. http://dx.doi.org/10.1021/jo00298a050.

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Andersson, Carl Magnus, Anders Hallberg, and G. Doyle Daves. "Regiochemistry of palladium-catalyzed arylation reactions of enol ethers. Electronic control of selection for .alpha.- or .beta.-arylation." Journal of Organic Chemistry 52, no. 16 (1987): 3529–36. http://dx.doi.org/10.1021/jo00392a007.

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Yin, Bo, Yu-Feng Du, Yan-Zuo Chen, Xiaohuan Li, Dong-Mei Fang, and Feng Gao. "Palladium-catalyzed direct deprotonative arylation of 2-pyridylacetonitriles: Facile synthesis of alpha-aryl-2-pyridylacetonitrile." Tetrahedron Letters 61, no. 47 (2020): 152534. http://dx.doi.org/10.1016/j.tetlet.2020.152534.

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JEFFERY, T. "ChemInform Abstract: Palladium-Catalyzed Arylation of Allylic Alcohols: Highly Selective Synthesis of β-Aromatic Carbonyl Compounds or β-Aromatic . alpha.,β-Unsaturated Alcohols." ChemInform 23, № 7 (2010): no. http://dx.doi.org/10.1002/chin.199207101.

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Mitsudo, Takeaki, Mamoru Kadokura, and Yoshihisa Watanabe. "Novel synthesis of .alpha.,.beta.-unsaturated ketones by the palladium-catalyzed arylation of ketenes with aroyl chlorides or the decarbonylative cross-condensation of acyl halides." Journal of Organic Chemistry 52, no. 15 (1987): 3186–92. http://dx.doi.org/10.1021/jo00391a002.

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Wu, Xin-Xing, Hao Ye, Ming Li, Jianing Qian, Hong Dai, and Yujun Shi. "Selective synthesis of acylated caprolactam via sequential Michael addition/palladium-catalyzed alpha-arylation of ketones." Organic Chemistry Frontiers, 2021. http://dx.doi.org/10.1039/d0qo01323d.

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Dissertations / Theses on the topic "Alpha-arylation au palladium"

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Gatland, Alice Elizabeth. "Palladium-catalysed enolate arylation in the synthesis of isoquinolines." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:f106760d-2375-4d56-81b2-faa6ee96cabc.

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<strong>Chapter 1. Introduction</strong> Scientific background on the development of homogeneous palladium-catalysed cross coupling reactions, focusing on the &alpha;-arylation reaction of enolates and its application to the synthesis of heteroaromatic compounds. The classical syntheses of isoquinolines are discussed, followed by an account of modern methods for their synthesis, including the recent &alpha;-arylation-based methodology developed by the Donohoe group. <strong>Chapter 2. Results and Discussion</strong> 2.1 Studies towards the development of a palladium-catalysed, C–H activation-b
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Pilgrim, Ben Samuel. "Novel palladium-catalysed routes to aromatic heterocycles." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:d143b5bf-1738-48ce-be75-4a25249acb9d.

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A brief summary of the use of palladium as a catalyst, the characteristic reactivity of palladium complexes and the commonly used palladium-catalysed cross coupling reactions is given, with a special focus on the palladium-catalysed α-arylation of enolates and its application to the synthesis of aromatic heterocycles. The synthesis of aromatic heterocycles via both traditional methods and more recent metal-catalysed approaches is discussed in the context of isoquinolines. The palladium-catalysed oxidation of dihydrofurans bearing an ortho-bromophenyl group at the 2-position to the correspondin
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Gauthier, Delphine. "Vers la synthèse de nouveaux analogues du TMC-95A : formation régiosélective d'oxindoles substitués." Paris 11, 2008. http://www.theses.fr/2008PA112039.

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Les travaux décrits dans cette thèse concernent l’approche vers la synthèse de nouveaux analogues du TMC-95A, molécule naturelle qui agit en tant qu’inhibiteur du protéasome. Ses propriétés cytotoxiques et sa structure macrocyclique originale, avec un noyau tryptophane hautement oxydé, confèrent un grand intérêt à la synthèse totale ou d’analogues du TMC-95A. Dans le contexte d’une étude de relations structure/activité, la préparation de dérivés possédant un noyau tryptophane diversement substitué a constitué le cœur du projet scientifique. Différentes stratégies ont été développées pour obten
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Zine, Khalid. "Synthèse régio- et stéréosélective du 4,4,4-trifluorobut-2-énoate d'éthyle porteur d'un groupement tributylstannyl en position alpha ou bêta : réactivité cupro-catalysée des vinylétains en l'absence de complexes du palladium." Thesis, Tours, 2011. http://www.theses.fr/2011TOUR4044/document.

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Vu l’importance des molécules fluorées dans différents domaines et vu la réactivité engendrée par le 4,4,4-trifluorobut-2-ynoate d’éthyle 1 lors des travaux antérieurs réalisés au laboratoire, nous avons décidé d’étudier le comportement de dérivé fluoré 1 vis-à-vis d’hydrure tributylétain sans l’emploi de catalyseurs ou d’additifs. Le but est d’accéder à de nouveaux synthons fluorés par voies originales.Après une étude préliminaire pour effectuer cette réaction d’hydrostannation dans les meilleures conditions, nous avons réalisé pour la première fois la synthèse totalement régio- et stéréoséle
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