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1

Whelan, M., K. Barton, J. Cassidy, J. Colreavy, and B. Duffy. "Corrosion inhibitors for anodised aluminium." Surface and Coatings Technology 227 (July 2013): 75–83. http://dx.doi.org/10.1016/j.surfcoat.2013.02.029.

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2

Sharma, Manish Kumar, Anil Kumar Sharma, and S. P. Mathur. "Solanum surrattence as Potential Corrosion Inhibitor." ISRN Corrosion 2012 (August 28, 2012): 1–5. http://dx.doi.org/10.5402/2012/907676.

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Developping chip and ecofriendlly corrosion inhibitors can replace toxic chemicals which are currently used in industries. Plant extract of Solanum surrattence in acetone, petroleum ether, and methanol has been tasted using mass loss and thermometric measurements for corrosion of aluminium in acid solutions. The plant extract of Solanum surrattence is a good corrosion inhibitor for aluminium. The inhibition efficiency depends upon the concentration of inhibitors, it inhibits the metal of 97.60% at its maximum value. This inhibitor shows efficiency at 25°C. At higher temperature the inhibition efficiency decreases. These types of inhibitors can be used to replace the toxic chemicals which are currently used in industries. We find out cheap and ecofriendlly corrosion inhibitors which can be used by acid, petrochemical, and chemical industries.
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3

Jha, Saurabh Kumar. "Self-Healing Coating on Aluminium Alloy (AA2014) using a Sol - Gel Process." International Journal for Research in Applied Science and Engineering Technology 9, no. VI (June 10, 2021): 293–300. http://dx.doi.org/10.22214/ijraset.2021.34968.

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In this paper, a new doping concept has been improved which shows self-healing properties by sustained release of corrosion inhibitors in a carrier system. The anti-corrosive properties of (AA2014) aluminium alloy was tested by electrochemical impedance spectroscopy. The sol-gel coating doped with both inorganic and organic inhibitors gives a satisfying result. Releasing the event of inhibitor depends on the pH value of the corrosion environment. The barrier properties of the best coating divulge by high pore resistance with having high impedance value at low frequency. The immersion test confirmed that double doping concept is valuable also for long immersion test.
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4

Wulandari, Pramesti A. D., and M. Noer Ilman. "Corrosion rate of AA 7050 in 3.5% NaCl environment with sodium chromate (Na2CrO4) inhibitor variation." MATEC Web of Conferences 197 (2018): 12002. http://dx.doi.org/10.1051/matecconf/201819712002.

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Aluminium alloy 7050 is widely used for aerospace applications due to its excellent mechanical properties. However, when the airplane is operated and exposed by the corrosive environment, alumina layer of aluminium is not thick enough to provide protection. Therefore, corrosion protection method in the airplane needs to be improved. In the recent experiments, corrosion process in the airplane could be inhibited by corrosion inhibitors that are mixed with a protective coating. In this current study, the effect of sodium chromate inhibitor on the corrosion rate of aluminium alloy AA 7050 has been investigated. The 7050 aluminium alloys in this experiment were machined into specimens for the tensile test, hardness test, corrosion test and metallographic examination. The corrosion test was performed in 3.5% NaCl solution containing 0.1%, 0.3%, 0.5%, 0.7% sodium chromate inhibitor and the results have been compared with the corrosion rate in 3.5% NaCl solution as reference. The tensile test results showed that the ultimate and yield strength were 527.36 MPa and 481.42 MPa. Hardness test results were 175.36 VHN on the short transverse plane, 164.43 VHN on the long transverse plane, and 164.23 VHN on the longitudinal plane. This experimental study can be concluded that the corrosion rate of material decreases with increasing of Na2CrO4 concentration in the solution.
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5

Niyi, Olowoyo D., Fadairo Ekaette Akpan, and Aziza Andrew Ejiro. "Concentration Dependent Effects of Green Inhibitors on Gravimetric Indices of Corrosion Linked Metal Integrity." Current World Environment 16, no. 1 (April 28, 2021): 134–42. http://dx.doi.org/10.12944/cwe.16.1.13.

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The use of plant phytochemicals as anti-corrosion agents is gaining widespread acceptance. This study was designed to evaluate the concentration dependent effects of green inhibitors from Pennisetum purpureum (elephant grass) Mangifera indica (mango leaves) and Heveabrasiliensis (rubber leaves) on some gravimetric indicators of corrosion linked metal stability. The material strength, weight loss, corrosion rate of the metal coupons and the inhibition efficiency of the green inhibitors were determined after 3 days. Our findings revealed a slight increase (p=0.05) in material strength (MS) of Pennisetum purpureum inhibitor treated - iron and steel at 100% inhibitor relative to their controls (minus Pennisetum purpureum -iron and steel coupons) and also relative to the (+Mangifera indica inhibitor and + Heveabrasiliensis -treated iron and steel coupons at 50% concentration. The material strength for P. purpureum-treated aluminium was slightly increased (p>0.05). There was also a slight decrease (p>0.05) in the weight loss of P. purpureum exposed iron coupon at a 100% inhibitor when compared to the controls, 50% P. purpureum exposed iron coupon and at 50 and 100% H. brasiliensis and M. indica-treated iron coupon in 15% acid medium. Pre-treatment of test metals with the combined green inhibitors at 50 and 100% concentration caused a significant (p≤0.05) decreases in weight loss and increases in material strength of all three test metals when compared to their respective inhibitor-free controls, and when treatment was done with a single green inhibitor. There was a slight decrease in the corrosion rate of iron, aluminium and steel coupons in acid medium treated with 50% P. purpureum inhibitor when compared to the same parameter of other green inhibitors evaluated in this study, albeit, the reduction was not significant (p>0.05). There was a further decreases (p≤0.05) in the corrosion rate of iron and steel when the combined green inhibitors at 100% concentration(+All green inhibitors (PAGI) at 100%) were used relative to when treatment was done using individual green inhibitors separately. The inhibition efficiency of the combined green inhibitors at 50% concentration on aluminium, iron and steel was 86% 57% and 60% respectively. While the treatment of the same coupons with combined inhibitors (+PAGI at100% concentration) increased the inhibition efficiency to 88% 75% and 74% for aluminium, iron and steel respectively. Overall, the study revealed the possible anti-corrosion effects of the extracts of H. brasiliensis, P. purpureum and M. indica on aluminium, iron and steel coupons and the synergism in anti-corrosion characteristics of these green inhibitors when combined. This study establishes the anticorrosion effects of H. brasiliensis, P. purpureum and M. indica extracts.
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6

Müller, Bodo. "Polymeric corrosion inhibitors for aluminium pigment." Reactive and Functional Polymers 39, no. 2 (February 1999): 165–77. http://dx.doi.org/10.1016/s1381-5148(97)00179-x.

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7

ZAVERACH, YE M., and O. I. STREMETSKYI. "CORROSION INHIBITORS FOR ALUMINIUM IN ALKALINE MEDIUM." HERALD of Khmelnytskyi national university 271, no. 2 (March 2019): 44–48. http://dx.doi.org/10.31891/2307-5732-2019-271-2-44-48.

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8

Jayalakshmi,, M., and V. S. Muralidharan,. "Inhibitors for Aluminium Corrosion in Aqueous Media." Corrosion Reviews 15, no. 3-4 (December 1997): 315–40. http://dx.doi.org/10.1515/corrrev.1997.15.3-4.315.

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9

Forsyth, Maria, Marianne Seter, Bruce Hinton, Glen Deacon, and Peter Junk. "New 'Green' Corrosion Inhibitors Based on Rare Earth Compounds." Australian Journal of Chemistry 64, no. 6 (2011): 812. http://dx.doi.org/10.1071/ch11092.

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A series of rare earth organic compounds pioneered by our group have been shown to provide a viable alternative to the use of chromates as corrosion inhibitors for some steel and aluminium applications. For example we have shown that the lanthanum 4-hydroxy cinnamate offers excellent corrosion mitigation for mild steel in aqueous environments while rare earth diphenyl phosphates offer the best protection in the case of aluminium alloys. In both cases the protection appears to be related to the formation of a nanometre thick interphase occurring on the surface that reduces the electrochemical processes leading to metal loss or pitting. Very recent work has indicated that we may even be able to address the challenging issue of stress corrosion cracking of high strength steels. Furthermore, filiform corrosion can be suppressed when selected rare earth inhibitor compounds are added as pigments to a polymer coating. There is little doubt from the work thus far that a synergy exists between the rare earth and organic inhibitor components in these novel compounds. This paper reviews some of the published research conducted by the senior author and colleagues over the past 10 years in this developing field of green corrosion inhibitors.
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10

Patil, D. B., and A. R. Sharma. "Inhibition of Corrosion of Aluminium in Potassium Hydroxide Solution by Pyridine Derivatives." ISRN Materials Science 2014 (January 19, 2014): 1–5. http://dx.doi.org/10.1155/2014/154285.

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The influence of 3-methylpyridine and 3-nitropyridine on the corrosion rate of aluminium in 1 mol L−1 potassium hydroxide solution was investigated using weight loss method. It was observed that both investigated derivatives behave as inhibitors. It was found that the inhibition efficiency increases with increasing inhibitor concentration. The inhibition mechanism is discussed on the basis of adsorption of inhibitor molecules on the metal surface. The inhibitors were adsorbed on the surface according to the Frumkin adsorption isotherm. The effect of temperature on the corrosion inhibition of Al was studied and thermodynamic functions for the dissolution and adsorption processes in the absence and in the presence of the inhibitors were computed and discussed.
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11

Bazzi, L., R. Salghi, E. Zine, S. El Issami, S. Kertit, and B. Hammouti. "Inhibition de la corrosion de l'alliage d'aluminium 6063 au moyen de composés inorganiques dans une solution de chlorure de sodium à 3 %." Canadian Journal of Chemistry 80, no. 1 (January 1, 2002): 106–12. http://dx.doi.org/10.1139/v01-189.

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Some inorganic compounds have been tested as corrosion inhibitors for 6063 aluminium alloy in 3% NaCl by electrochemical and metalographic methods. The compounds were MoO42–, CrO42–, NO2– oxo-anions and Li+ and Mg2+ metallic cations. Results obtained show that these compounds inhibited corrosion of 6063 aluminium alloy, and that the Li+ cations were the best inhibitors. The difference between pitting potential and corrosion potential increase by increasing the concentration of Li+. The maximum inhibition efficiency (E% = 85%) was attained at 5 × 10–3 M. Increasing temperature from 25 to 55°C improve corrosion resistance of 6063 aluminium alloy in the absence of Li+. However, in the presence of these cations, E% decreased at elevated temperature.Key words: corrosion, inhibition, inorganic compounds, 6063 aluminium alloy, 3% NaCl.
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12

Xhanari, Klodian, Matjaž Finšgar, Maša Knez Hrnčič, Uroš Maver, Željko Knez, and Bujar Seiti. "Green corrosion inhibitors for aluminium and its alloys: a review." RSC Advances 7, no. 44 (2017): 27299–330. http://dx.doi.org/10.1039/c7ra03944a.

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13

MUNIANDY, M. T., A. ABDUL RAHIM, H. OSMAN, A. MOHD SHAH, S. YAHYA, and P. BOTHI RAJA. "INVESTIGATION OF SOME SCHIFF BASES AS CORROSION INHIBITORS FOR ALUMINIUM ALLOY IN 0.5 M HYDROCHLORIC ACID SOLUTIONS." Surface Review and Letters 18, no. 03n04 (June 2011): 127–33. http://dx.doi.org/10.1142/s0218625x11014564.

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The inhibitory effect of some Schiff bases viz. N,N′-bis(2-hydroxybenzylidene)-1,3-diaminobenzene (SB1), N,N′-bis(4-bromobenzylidene)-1,3-diaminobenzene (SB2) and N,N′-bis(2-hydroxy-5-bromobenzylidene)-1,3-diaminobenzene (SB3) on the corrosion of aluminium alloy in 0.5 M HCl acid have been studied using weight loss measurements, potentiodynamic polarization and Scanning Electron Microscopy (SEM). The experimental results showed that these Schiff bases SB1, SB2 and SB3 efficiently inhibit the corrosion of aluminium alloy in 0.5 M HCl medium and found to follow almost similar corrosion inhibition pattern. The potentiodynamic polarization curves revealed that, all the studied Schiff bases are mixed type inhibitors with a predominantly cathodic action and their inhibition efficiencies increased with increasing inhibitor concentration. The adsorption of Schiff bases was found to follow Langmuir adsorption isotherm. SEM study revealed that these compounds protect the metal corrosion by adsorption on its surface to form a protective layer. The inhibition performance depends strongly on the type of functional groups substituted on the benzene ring.
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14

Khramov, A. N., V. N. Balbyshev, and R. A. Mantz. "Protection of Aluminium Alloys via Hybrid Sol-Gel Coatings with Encapsulated Organic Corrosion Inhibitors." Materials Science Forum 519-521 (July 2006): 661–66. http://dx.doi.org/10.4028/www.scientific.net/msf.519-521.661.

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Several heterocyclic organic corrosion inhibitors that contain ionazible functional group were encapsulated into nano-structural hybrid organo-silicate coating to improve its corrosion protection performance on aluminum alloy 2024-T3 substrate. When the coating is formed on the substrate surface, it serves simultaneously as protective barrier and as a reservoir for leachable corrosion inhibitor that is stored and released through the mechanism of reversible ionic interaction with the matrix material. The efficiency of active corrosion protection for these coating systems was examined by electrochemical methods including potentiodynamic polarization (PDS) and electrochemical impedance spectroscopy (EIS). The effects of chemical structure and the loading concentration of the inhibitor within the coating were determined.
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15

Müller, Bodo, and Sonja Kubitzki. "Heterocyclic corrosion inhibitors for aluminium and zinc pigments." Pigment & Resin Technology 29, no. 5 (October 2000): 268–72. http://dx.doi.org/10.1108/03699420010353519.

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16

Müller, B., M. Schubert, and D. Triantafillidis. "Epoxy esters as corrosion inhibitors for aluminium pigment." Surface Coatings International Part B: Coatings Transactions 84, no. 2 (April 2001): 157–60. http://dx.doi.org/10.1007/bf02699778.

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17

Abdallah, M. "Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solution." Corrosion Science 46, no. 8 (August 2004): 1981–96. http://dx.doi.org/10.1016/j.corsci.2003.09.031.

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18

Zin, Ivan M., Vasyl I. Pokhmurskii, Sergiy A. Korniy, Olena V. Karpenko, Stuart B. Lyon, Olha P. Khlopyk, and Mariana B. Tymus. "Corrosion inhibition of aluminium alloy by rhamnolipid biosurfactant derived from pseudomonas sp. PS-17." Anti-Corrosion Methods and Materials 65, no. 6 (November 5, 2018): 517–27. http://dx.doi.org/10.1108/acmm-03-2017-1775.

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Purpose The purpose of this paper is to study the influence of rhamnolipid biosurfactant complex on the corrosion and the repassivation of a freshly cut Al-Cu-Mg aluminium alloy surface. Design/methodology/approach The electrochemical methods, supported by quantum-chemical calculations and scanning electron microscopy data, were used. Findings It was established that the rhamnolipid biosurfactant effectively inhibits corrosion of the alloy in synthetic acid rainwater. The efficiency of inhibition becomes stronger with the increase of biosurfactant concentration; however, above the critical micelle concentration, the further improvement in inhibition is minor. It is believed that the mechanism of corrosion inhibition is related to the adsorption of the biosurfactant molecule on the aluminium alloy surface and the formation of a barrier film; however, the formation of a complex compound (salt film) between aluminium ions and rhamnolipid on anodic sites of the alloy is not ruled out. In case of surface mechanical activation of the alloy, the biosurfactant molecule effectively prevents corrosion. Furthermore, addition of the biosurfactant to the corrosion environment increases the repassivation kinetics of the alloy by two to four times as compared with an uninhibited environment. Practical implications The commercial impact of the study consists in the possibility of obtaining of environmentally safe corrosion inhibitors of aluminium alloys by biosynthesis from renewable agricultural raw materials. Originality/value The originality of this paper is to study the effectiveness of “green” corrosion inhibitor based on biogenic product on freshly generated surface of aluminium alloy.
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19

Berković, K., S. Kovač, and J. Vorkapić-Furač. "Natural compounds as environmentally friendly corrosion inhibitors of aluminium." Acta Alimentaria 33, no. 3 (September 2004): 237–47. http://dx.doi.org/10.1556/aalim.33.2004.3.4.

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20

Lamaka, S. V., M. L. Zheludkevich, K. A. Yasakau, M. F. Montemor, and M. G. S. Ferreira. "High effective organic corrosion inhibitors for 2024 aluminium alloy." Electrochimica Acta 52, no. 25 (September 2007): 7231–47. http://dx.doi.org/10.1016/j.electacta.2007.05.058.

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21

Elewady, G. Y., and H. A. Mostafa. "Ketonic secondary Mannich bases as corrosion inhibitors for aluminium." Desalination 247, no. 1-3 (October 2009): 573–82. http://dx.doi.org/10.1016/j.desal.2008.08.006.

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22

Madkour, Loutfy H., R. M. Issa, and I. M. El-Ghrabawy. "Kinetics of Substituted Bis- and Mono-azo Dyes as Corrosion Inhibitors for Aluminium in Hydrochloric Acid and Sodium Hydroxide Solutions." Journal of Chemical Research 23, no. 7 (July 1999): 408–9. http://dx.doi.org/10.1177/174751989902300702.

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This investigation is designed to apply an advanced kinetic–thermodynamic model on the data obtained from acidic and alkaline corrosion of aluminium using bis- and mono-azo dyes as corrosion inhibitors.
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23

Xhanari, Klodian, and Matjaž Finšgar. "Organic corrosion inhibitors for aluminium and its alloys in acid solutions: a review." RSC Advances 6, no. 67 (2016): 62833–57. http://dx.doi.org/10.1039/c6ra11818f.

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24

Allal, Hamza, Youghourta Belhocine, and Emna Zouaoui. "Computational study of some thiophene derivatives as aluminium corrosion inhibitors." Journal of Molecular Liquids 265 (September 2018): 668–78. http://dx.doi.org/10.1016/j.molliq.2018.05.099.

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25

Obot, I. B., N. O. Obi-Egbedi, and S. A. Umoren. "Antifungal drugs as corrosion inhibitors for aluminium in 0.1M HCl." Corrosion Science 51, no. 8 (August 2009): 1868–75. http://dx.doi.org/10.1016/j.corsci.2009.05.017.

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26

Joseph, Olufunmilayo O., and Olakunle O. Joseph. "Corrosion Inhibition of Aluminium Alloy by Chemical Inhibitors: An Overview." IOP Conference Series: Materials Science and Engineering 1107, no. 1 (April 1, 2021): 012170. http://dx.doi.org/10.1088/1757-899x/1107/1/012170.

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27

Gayathri, V. S., K. Yamuna, D. Gnana Prakash, R. Kameshwari, R. Supraja, Ramesh Munusamy, and Thiruvalan Venkatesan. "Green Inhibitors: Anti Corrosive Propensity of Garcinia mangostana for Aluminum 1100." Solid State Phenomena 185 (February 2012): 109–12. http://dx.doi.org/10.4028/www.scientific.net/ssp.185.109.

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Corrosion is one of the key concerns during construction of a chemical plant.Mangosteen (Garcinia mangostana), a tropical purple fruit contains as many as 40 varieties of xanthones and exhibits good amount of anti oxidant property. The objective of this paper was to study the anti-corrosive property of Mangosteen on aluminium 1100. The study was designed to screen the inhibition efficiency of Mangosteen at various concentrations at pH 1. The Mangosteen extract was obtained by Soxhlet extraction from its dry hard pericarp and analyzed by UV methods.
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28

Madram, A. R., F. Shokri, M. R. Sovizi, and H. Kalhor. "Aromatic Carboxylic Acids as Corrosion Inhibitors for Aluminium in Alkaline Solution." Portugaliae Electrochimica Acta 34, no. 6 (2016): 395–405. http://dx.doi.org/10.4152/pea.201606395.

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29

Lomakina, S. V., T. S. Shatova, and L. P. Kazansky. "Heteropoly anions as corrosion inhibitors for aluminium in high temperature water." Corrosion Science 36, no. 9 (September 1994): 1645–51. http://dx.doi.org/10.1016/0010-938x(94)90059-0.

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30

Müller, B., and S. Fischer. "Epoxy ester resins as corrosion inhibitors for aluminium and zinc pigments." Corrosion Science 48, no. 9 (September 2006): 2406–16. http://dx.doi.org/10.1016/j.corsci.2005.10.002.

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31

Zheludkevich, M. L., K. A. Yasakau, S. K. Poznyak, and M. G. S. Ferreira. "Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy." Corrosion Science 47, no. 12 (December 2005): 3368–83. http://dx.doi.org/10.1016/j.corsci.2005.05.040.

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32

Gomma, Gamal K., and Mostafa H. Wahdan. "Schiff bases as corrosion inhibitors for aluminium in hydrochloric acid solution." Materials Chemistry and Physics 39, no. 3 (January 1995): 209–13. http://dx.doi.org/10.1016/0254-0584(94)01436-k.

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33

Hori, Y., J. Takao, and H. Shomon. "Improvements of anode properties of aluminium alloys for aluminium primary cell: heat treatment and corrosion inhibitors." Electrochimica Acta 31, no. 5 (May 1986): 555–59. http://dx.doi.org/10.1016/0013-4686(86)85032-0.

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34

müller, B., G. Kubitzki, and G. Kinet. "Aromatic 2-Hydroxy-Oximes as corrosion inhibitors for aluminium and zinc pigments." Corrosion Science 40, no. 9 (September 1998): 1469–77. http://dx.doi.org/10.1016/s0010-938x(98)00058-4.

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35

Bethencourt, M., F. J. Botana, J. J. Calvino, M. Marcos, and M. A. RodrÍguez-Chacón. "Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review." Corrosion Science 40, no. 11 (November 1998): 1803–19. http://dx.doi.org/10.1016/s0010-938x(98)00077-8.

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36

Moussa, M. N., M. M. El‐Tagoury, A. A. Radi, and S. M. Hassan. "Carboxylic acids as corrosion inhibitors for aluminium in acidic and alkaline solutions." Anti-Corrosion Methods and Materials 37, no. 3 (March 1990): 4–8. http://dx.doi.org/10.1108/eb007262.

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37

Müller, Bodo. "Amino and polyamino acids as corrosion inhibitors for aluminium and zinc pigments." Pigment & Resin Technology 31, no. 2 (April 2002): 84–87. http://dx.doi.org/10.1108/03699420210420369.

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38

KHAIROU, K. S., A. A. ALFI, and E. M. MABROUK. "Natural polymers as corrosion inhibitors for aluminium and tin in acidic media." Material Science Research India 4, no. 2 (December 25, 2007): 279–90. http://dx.doi.org/10.13005/msri/040207.

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39

Wysocka, Joanna, Mateusz Cieslik, Stefan Krakowiak, and Jacek Ryl. "Carboxylic acids as efficient corrosion inhibitors of aluminium alloys in alkaline media." Electrochimica Acta 289 (November 2018): 175–92. http://dx.doi.org/10.1016/j.electacta.2018.08.070.

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40

Fouda, Abd El-Aziz S., Hanem A. Mostafa, and Hamed M. Abu-Elnader. "Phenyl semicarbazide derivatives as corrosion inhibitors for aluminium in hydrochloric acid solution." Monatshefte f�r Chemie Chemical Monthly 120, no. 6-7 (1989): 501–7. http://dx.doi.org/10.1007/bf00810836.

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41

Eugene, Uwiringiyimana, P. Sylvester O rsquo Donnell, V. Joseph Ifeoma, and V. Adams Feyisayo. "The effect of corrosion inhibitors on stainless steels and aluminium alloys: A review." African Journal of Pure and Applied Chemistry 10, no. 2 (March 31, 2016): 23–32. http://dx.doi.org/10.5897/ajpac2016.0676.

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42

Srinivasan, P. Bala, W. Dietzel, R. Zettler, J. F. dos Santos, and V. Sivan. "Effects of inhibitors on corrosion behaviour of dissimilar aluminium alloy friction stir weldment." Corrosion Engineering, Science and Technology 42, no. 2 (June 2007): 161–67. http://dx.doi.org/10.1179/174327807x159916.

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43

Hassan, S. M., M. N. Moussa, M. M. El‐Tagoury, and A. A. Radi. "Aromatic acid derivatives as corrosion inhibitors for aluminium in acidic and alkaline solutions." Anti-Corrosion Methods and Materials 37, no. 2 (February 1990): 8–11. http://dx.doi.org/10.1108/eb007261.

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44

Branzoi, V., Florentina Golgovici, and Florina Branzoi. "Aluminium corrosion in hydrochloric acid solutions and the effect of some organic inhibitors." Materials Chemistry and Physics 78, no. 1 (February 2003): 122–31. http://dx.doi.org/10.1016/s0254-0584(02)00222-5.

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45

Umoren, S. A., O. Ogbobe, P. C. Okafor, and E. E. Ebenso. "Polyethylene glycol and polyvinyl alcohol as corrosion inhibitors for aluminium in acidic medium." Journal of Applied Polymer Science 105, no. 6 (2007): 3363–70. http://dx.doi.org/10.1002/app.26530.

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46

Sangeetha, M., S. Rajendran, J. Sathiyabama, and A. Krishnaveni. "Inhibition of Corrosion of Aluminium and its Alloys by Extracts of Green Inhibitors." Portugaliae Electrochimica Acta 31, no. 1 (2013): 41–52. http://dx.doi.org/10.4152/pea.201301041.

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47

Matienzo, L. J., D. K. Shaffer, W. C. Moshier, and G. D. Davis. "Environmental and adhesive durability of aluminium-polymer systems protected with organic corrosion inhibitors." Journal of Materials Science 21, no. 5 (May 1986): 1601–8. http://dx.doi.org/10.1007/bf01114714.

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48

Subramanyam, N. C., B. S. Sheshadri, and S. M. Mayanna. "Thiourea and substituted thioureas as corrosion inhibitors for aluminium in sodium nitrite solution." Corrosion Science 34, no. 4 (April 1993): 563–71. http://dx.doi.org/10.1016/0010-938x(93)90272-i.

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Müller, B., and T. Schmelich. "High-molecular weight styrene-maleic acid copolymers as corrosion inhibitors for aluminium pigments." Corrosion Science 37, no. 6 (June 1995): 877–83. http://dx.doi.org/10.1016/0010-938x(94)00171-2.

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50

del Olmo, Rubén, Marta Mohedano, Beatriz Mingo, Raúl Arrabal, and Endzhe Matykina. "LDH Post-Treatment of Flash PEO Coatings." Coatings 9, no. 6 (May 30, 2019): 354. http://dx.doi.org/10.3390/coatings9060354.

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Abstract:
This work investigates environmentally friendly alternatives to toxic and carcinogenic Cr (VI)-based surface treatments for aluminium alloys. It is focused on multifunctional thin or flash plasma electrolytic oxidation (PEO)-layered double hydroxides (LDH) coatings. Three PEO coatings developed under a current-controlled mode based on aluminate, silicate and phosphate were selected from 31 processes (with different combinations of electrolytes, electrical conditions and time) according to corrosive behavior and energy consumption. In situ Zn-Al LDH was optimized in terms of chemical composition and exposure time on the bulk material, then applied to the selected PEO coatings. The structure, morphology and composition of PEO coatings with and without Zn-Al-LDH were characterized using XRD, SEM and EDS. Thicker and more porous PEO coatings revealed higher amounts of LDH flakes on their surfaces. The corrosive behavior of the coatings was studied by electrochemical impedance spectroscopy (EIS). The corrosion resistance was enhanced considerably after the PEO coatings formation in comparison with bulk material. Corrosion resistance was not affected after the LDH treatment, which can be considered as a first step in achieving active protection systems by posterior incorporation of green corrosion inhibitors.
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