Relevant bibliographies by topics / Ambidentate

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  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters

Academic literature on the topic 'Ambidentate'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Ambidentate"

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Ghosh, Pokhraj, Manuel Quiroz, Randara Pulukkody, Nattamai Bhuvanesh, and Marcetta Y. Darensbourg. "Bridging cyanides from cyanoiron metalloligands to redox-active dinitrosyl iron units." Dalton Transactions 47, no. 34 (2018): 11812–19. http://dx.doi.org/10.1039/c8dt01761a.

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Valyaev, Dmitry A., Marina A. Uvarova, Alina A. Grineva, Vincent César, Sergei N. Nefedov, and Noël Lugan. "Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMesCO2−ligand." Dalton Transactions 45, no. 30 (2016): 11953–57. http://dx.doi.org/10.1039/c6dt02060g.

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The C4-carboxylation of the archetypal IMes ligand was achieved directly on its complexed form for the first time, and the resulting ambidentate IMes<sup>CO2−</sup>ligand was exploited for the formation of heteropolymetallic complexes.
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Melle, Philipp, Nathalie Ségaud, and Martin Albrecht. "Ambidentate bonding and electrochemical implications of pincer-type pyridylidene amide ligands in complexes of nickel, cobalt and zinc." Dalton Transactions 49, no. 36 (2020): 12662–73. http://dx.doi.org/10.1039/d0dt02482a.

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Pincer-type tridentate pyridyl bis(pyridylidene amide) (pyPYA<sub>2</sub>) ligand systems were coordinated to the Earth-abundant first row transition metals nickel, cobalt and zinc, revealing ambidentate N,N,N and O,N,O coordination behavior.
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Karsch, H. H. "Ambidentate, Anionic Phosphine Ligands in Organoelement Chemistry." Phosphorus, Sulfur, and Silicon and the Related Elements 77, no. 1-4 (1993): 41–44. http://dx.doi.org/10.1080/10426509308045614.

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Burmeister, J. "Ambidentate ligands, the schizophrenics of coordination chemistry." Coordination Chemistry Reviews 105, no. 1 (1990): 77–133. http://dx.doi.org/10.1016/0010-8545(90)80019-p.

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Graham, AJ, PC Healy, JD Kildea, and AH White. "Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLVI. Synthesis and Conformational Systematics of Some Novel Polymeric Adducts of Pyridine-4-carbonitrile With Copper(I) Halides." Australian Journal of Chemistry 42, no. 1 (1989): 177. http://dx.doi.org/10.1071/ch9890177.

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The isolation and structural characterization of 1 : 1 adducts of copper(1) chloride (1) and bromide (2) with pyridine-4-carbonitrile (L) is described; crystals of the two complexes are isomorphous (monoclinic, P21/c, a ≈ 3.9, b ≈ 14.7, c ≈ 13.0 � , β ≈ 96°, Z 4; R0.047, 0.063 for No 630, 707 'observed' reflections respectively). Unlike the 1 : 1 adducts with the parent pyridine and benzonitrile ligands which are 'stair' polymers, these complexes comprise 'split-stair' strands woven into a two-dimensional sheet by crosslinking ambidentate ligands. Cu-N ( nitrile ) (1.942(9), 1.96(1) � ) are ap
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Kunze, Udo, Andreas Bruns, and Hussain Jawad. "Phosphinothioformamides - A Class of Versatile Ambidentate Complex Ligands." Phosphorous and Sulfur and the Related Elements 30, no. 1-2 (1987): 177–80. http://dx.doi.org/10.1080/03086648708080551.

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Abbasi, Alireza, Mikhail Yu Skripkin, Lars Eriksson, and Natallia Torapava. "Ambidentate coordination of dimethyl sulfoxide in rhodium(iii) complexes." Dalton Trans. 40, no. 5 (2011): 1111–18. http://dx.doi.org/10.1039/c0dt01026j.

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Vasil’chenko, I. S., T. E. Shestakova, V. N. Ikorskii, et al. "1-amino-2-thiobenzimidazoleimines as novel ambidentate ligand systems." Russian Journal of Coordination Chemistry 33, no. 3 (2007): 176–83. http://dx.doi.org/10.1134/s1070328407030049.

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Hsieh, Chung-Hung, Scott M. Brothers, Joseph H. Reibenspies, Michael B. Hall, Codrina V. Popescu, and Marcetta Y. Darensbourg. "Ambidentate Thiocyanate and Cyanate Ligands in Dinitrosyl Iron Complexes." Inorganic Chemistry 52, no. 4 (2013): 2119–24. http://dx.doi.org/10.1021/ic3025149.

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Dissertations / Theses on the topic "Ambidentate"

1

Farazi, Vida. "Ambidentate ligands : the preparation and study of phosphine crown systems." Virtual Press, 1987. http://liblink.bsu.edu/uhtbin/catkey/505399.

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The aza crown, sym-1,2-benzo-aza-17-crown-5, was synthesized from 6-aza-3,9-dioxa-1,11-undecanediol, and , -dibromo-o-xylene in the presence of potassium tert-butoxide. This new crown ether was reacted with 4-bromobenzyl bromide and chloroacetyl chloride to form the N-substituted 4-bromobenzyl and chloroacetyl derivatives, respectively. The aza crown and its derivatives were identified with spectroscopic data. The bidentate phosphine amine, Ph2P(CH2)3NH2, was prepared via reduction of 3-(diphenylphosphino)propionitrile by lithium tetrahydroaluminate. Schiff-base reactions between the amine gro
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Krummenacher, Ivo. "Ambidente Ligandensysteme basierend auf Pyrazolylverbindungen der Gruppe 14 /." Zürich : ETH, 2008. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=17624.

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Tchernook, Ivan. "Strategies for Computational Investigation of Reaction Mechanisms in Organic and Polymer Chemistry Using Static Quantum Mechanics." Doctoral thesis, Universitätsbibliothek Chemnitz, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-198756.

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This thesis presents computational studies of problems in the organic and polymer chemistry. The state-of-the art quantum chemical methods are used to gain further insight into the origin and the nature of the reactions in three different organic and polymer systems. The research questions are conceptually approached by identifying the key aspects. Then an appropriate strategy for the quantum chemical modeling is developed. In the scope of the polymer chemistry, the novel synthesis technique of nanostructured materials, the so-called twin polymerization, is investigated. Using three model sys
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Book chapters on the topic "Ambidentate"

1

Mingos, D. M. P. "Redox reactions." In Essentials of Inorganic Chemistry 2. Oxford University Press, 1998. http://dx.doi.org/10.1093/hesc/9780198559184.003.0010.

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This chapter analyses redox reactions. It explains that the oxidation–reduction reactions of transition metal complexes proceed via two primary mechanistic pathways: outer and inner sphere reactions. An outer sphere mechanism occurs when an electron is transferred between two coordination complexes in solution, both of the coordination spheres remain intact, and no ligand is transferred between them. The chapter notes that it is only possible to establish such a mechanism unambiguously when both of the coordination complexes are substitutionally inert. Finally, the chapter describes the inner
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2

Iwamoto, Toschitake. "Inclusion compounds of multi-dimensional cyanometal complex hosts." In Inclusion Compounds. Oxford University PressOxford, 1991. http://dx.doi.org/10.1093/oso/9780198552932.003.0006.

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Abstract The cyanide group, CN-, is able to build up one- (1D), two- (2D), or three-dimensional (3D) frameworks by alternately linking one metal atom M to another metal atom M’. The M’—CN—M linkage is usually colinear; in some cases the M'—C—N or M—N—C bond, or both, bends to a certain extent. The deviation from colinearity is, however, not appreciable in comparison with the case of another ambidentate pseudohalogen group SCN-: the M’—SCN—M linkage is generally bent at the sulphur atom with an approximately tetrahedral angle. The sp hybridization character of the —C=N triple bond may contribut
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Pratim Das, Partha. "SYNTHESIS OF CROWN ETHERS WITH ADDITIONAL AZOMETHINE/SCHIFF-BASE FUNCTIONALITY AND THEIR METAL COMPLEXES." In Futuristic Trends in Chemical Material Sciences & Nano Technology Volume 3 Book 3. Iterative International Publishers, Selfypage Developers Pvt Ltd, 2024. http://dx.doi.org/10.58532/v3becm3ch2.

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The most investigated macromolecules are crown ethers, which are distinguished by their varied host-guest chemistry. Because of their wide-ranging significance, modifying simple crown ethers is of relevance to scientists everywhere. The confluence of two or more distinct kinds of functionalities in one molecular framework leads to ambidentate chelating complexes. Off late Schiff base appended oxa-crown ether systems and their metal complexes have been extensively studied. Schiff bases and their metal complexes have been studied even before crown ethers were synthesized. Numerous research oppor
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