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Dissertations / Theses on the topic 'Amine-functionalization'

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Published: 4 June 2021

Last updated: 1 February 2022

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1

Onomura, Osamu. "Studies on Anodic Selective Functionalization of Cyclic Amine Derivatives." Kyoto University, 1988. http://hdl.handle.net/2433/74738.

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2

Li, Fuyue. "Amine-functionalized polymeric hollow fiber sorbents for post-combustion CO2 capture." Diss., Georgia Institute of Technology, 2014. http://hdl.handle.net/1853/52991.

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Polymeric hollow fiber sorbents were functionalized with amine moieties for improving the carbon dioxide sorption capacity from flue gas to reduce the greenhouse gas emissions from coal-fired power plants. Three different experimental pathways were studied to form the amine-functionalized hollow fiber sorbents. Aminosilane functionalized cellulose acetate (CA) fibers, polyethyleneimine (PEI) functionalized polyamide-imide (PAI, Torlon®) fibers and PEI post-infused and functionalized Torlon®-silica fibers were formed. CO2 equilibrium sorption capacity data were collected by using the pressure d

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3

Chan, Jessica Zee. "Stereoselective Functionalization of Carbonyl Compounds and N-Alkylamines Promoted by Cooperative Catalysts:." Thesis, Boston College, 2020. http://hdl.handle.net/2345/bc-ir:108940.

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Thesis advisor: Masayuki Wasa<br>This dissertation describes the development of cooperative catalyst systems for the functionalization of monocarbonyl compounds and stereoselective transformations of alpha-C–H bonds of N-alkylamines, inspired by the concepts of frustrated Lewis pairs (FLPs). Prior to this dissertation research, practical and broadly applicable C–C and C–heteroatom bond forming reactions involving the FLP complexes that provide synthetically desirable products with high enantioselectivity remained to be developed. Chapter 1 of this dissertation describes the recent advances in

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4

Li, Fuyue. "Amine-functionalized polymeric hollow fiber sorbents for post-combustion CO₂ capture." Diss., Georgia Institute of Technology, 2014. http://hdl.handle.net/1853/53119.

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Polymeric hollow fiber sorbents were functionalized with amine moieties for improving the carbon dioxide sorption capacity from flue gas to reduce the greenhouse gas emissions from coal-fired power plants. Three different experimental pathways were studied to form the amine-functionalized hollow fiber sorbents. Aminosilane functionalized cellulose acetate (CA) fibers, polyethyleneimine (PEI) functionalized polyamide-imide (PAI, Torlon® fibers and PEI post-infused and functionalized Torlon®-silica fibers were formed. CO₂ equilibrium sorption capacity data were collected by using the pressure de

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5

Xu, Jingjing Ph D. Massachusetts Institute of Technology. "Amine functionalization by initiated chemical vapor deposition (iCVD) for interfacial adhesion and film cohesion." Thesis, Massachusetts Institute of Technology, 2011. http://hdl.handle.net/1721.1/65769.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 2011.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Amine functional polymer thin films provide a versatile platform for subsequent functionalization because of their diverse reactivity. Initiated chemical vapor deposition (iCVD) is a polymer chemical vapor deposition technique that utilizes the delivery of vaporphase monomers to form chemically well-defined polymer films with tunable conformality and property. In this thesis work, amine functional iCVD poly(4-aminostyre

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6

Oxby, Keith. "Compatibilization of poly(styrene-acrylonitrile) (SAN) / poly(ethylene) blends via amine functionalization of SAN chain ends." Thesis, McGill University, 2013. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=117225.

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Styrene/acrylonitrile (SAN) copolymers with excellent chain-end fidelity and low polydispersity Mw/Mn (1.10 – 1.30) were synthesized by nitroxide mediated polymerization (NMP) in dimethylformamide (DMF) solution with a succinimidyl ester (NHS) terminal group from the so-called SG1 nitroxide residue. These copolymers were thermally stabilized by removing the N-tert-butyl-N-[1-diethylphosphono-(2,2-dimethylpropyl) nitroxide] (SG1), and then modified to form primary amine end-functional SAN (SAN-NH2). Homogeneous coupling reactions and Fourier-transform infrared spectroscopy (FTIR) indicated th

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7

Kamisetty, Nagendra Kumar. "Development of advanced DNA microarray system by high density amine functionalization of solid surface and functional design of DNA probes." Kyoto University, 2007. http://hdl.handle.net/2433/135562.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(エネルギー科学)<br>甲第12717号<br>エネ博第145号<br>新制||エネ||35(附属図書館)<br>UT51-2007-C253<br>京都大学大学院エネルギー科学研究科エネルギー社会・環境科学専攻<br>(主査)教授牧野圭祐, 教授尾形幸生, 助教授小瀧努<br>学位規則第4条第1項該当

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8

Lee, Dustin. "DEVELOPMENT OF ZEOLITIC IMIDAZOLATE FRAMEWORKS FOR ENHANCING POST-COMBUSTION CO2 CAPTURE." DigitalCommons@CalPoly, 2020. https://digitalcommons.calpoly.edu/theses/2238.

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Post-combustion CO2 capture is a promising approach for complementing other strategies to mitigate climate change. Liquid absorption is currently used to capture CO2 from post-combustion flue gases. However, the high energy cost required to regenerate the liquid absorbents is a major drawback for this process. As a result, solid sorbents have been investigated extensively in recent years as alternative media to capture CO2 from flue gases. For example, metal organic frameworks (MOFs) are nanoporous materials that have high surface areas, large pore volumes, and flexible designs. A large number

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9

Barbosa, Marcela Nascimento. "Estudo de materiais mesoporosos funcionalizados com diferentes aminas para captura do di?xido de carbono atrav?s do processo de adsor??o." Universidade Federal do Rio Grande do Norte, 2013. http://repositorio.ufrn.br:8080/jspui/handle/123456789/17790.

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Made available in DSpace on 2014-12-17T15:42:29Z (GMT). No. of bitstreams: 1 MarcelaNB_TESE.pdf: 4650032 bytes, checksum: 4b8ec547749f785718e5f099093fa925 (MD5) Previous issue date: 2013-09-30<br>Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico<br>Intensive use of machinery and engines burning fuel dumps into the atmosphere huge amounts of carbon dioxide (CO2), causing the intensification of the greenhouse effect. Climate changes that are occurring in the world are directly related to emissions of greenhouse gases, mainly CO2, gases, mainly due to the excessive use of fossil fue

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10

Mulay, Prajakatta. "Synthesis of Folate-Targeted Poly(Ethylene Glycol)-Based Conjugates And Their Precursors." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1574442562023675.

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11

Zhan, Xin. "EFFICIENT ELECTROCHEMICAL FUNCTIONALIZATION OF CARBON NANOTUBES AND CARBON NANOTUBE MEMBRANES FOR ENERGY, DRUG DELIVERY AND POTENTIAL CATALYSIS APPLICATIONS." UKnowledge, 2013. http://uknowledge.uky.edu/chemistry_etds/15.

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Electrochemical diazonium grafting offers versatile functionalization of chemically inert graphite under mild condition, which is particularly suitable for CNT composite modification. Tetrafluorinated carboxylphenyl diazonium grafting provides the most controllable functionalization chemistry allowing near monolayer levels of functionality on carbon nanotubes. The functional density was successfully quantified by anion selective dye-assay and X-ray photoelectron spectroscopy (XPS) of thiol-Au self-assembled monolayers (SAM) as a calibration reference. This technique enables monolayer functiona

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12

Nguyen, Khac Minh Huy. "Activation de liaisons C-H au moyen d’un système catalytique bio-inspiré pour la synthèse d’hétérocycles d’intérêt pharmacologique." Thesis, Sorbonne Paris Cité, 2016. http://www.theses.fr/2016USPCB023.

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Les métalloenzymes d’origine naturelle constituent une riche source d’inspiration pour la conception de catalyseurs synthétiques en raison de leur capacité à réaliser des réactions d’oxydation sélective dans des conditions douces. Parmi ces métalloenzymes, les amine-oxydases à cuivre (CuAOs) permettent l’oxydation sélective des amines primaires grâce à la coopération d’un catalyseur organique quinonique (topaquinone) et d’un ion cuivrique. Récemment, un regain d’intérêt s’est manifesté pour le développement de catalyseurs biomimétiques permettant l’oxydation des amines en imines à l’air ambian

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13

Ashley, Melissa Ann. "Photoredox-Catalyzed Site-Selective Functionalization of Primary Amine Derivatives." Thesis, 2021. https://doi.org/10.7916/d8-nz4d-fj65.

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Given the prevalence of primary amines in biologically active molecules, an important area of research is devoted to creating methods to site-selectively functionalize their C(sp³)-H bonds. For simple aliphatic primary amines, many of these C-H bonds are chemically indistinguishable due to their similar electronics and sometimes, steric environments. Through strategic choice of activating group, site-selective functionalization at both α- and ẟ- positions is achieved. Exploiting inductive effect allows for a photoredox-catalyzed α-C(sp³)-H alkylation of trifluoromethanesulfonamides. In the cas

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14

LIAO, CHI-WEI, and 廖紀維. "Facilitated Hydrogen Release Kinetics from Amine Borane Functionalization on Metal-Organic Frameworks." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/ukx9ek.

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碩士<br>逢甲大學<br>材料科學與工程學系<br>106<br>For the first time, we functionalized the gate-opening metal-organic framework (GO-MOF) of MIL-53(Al) with ammonia borane (AB, NH3BH3) via post-synthesis method. In this report, unusual structural breathing and dehydrogenation behaviors of AB doped MOF (MIL-53-AB) were discovered. Surface coating triggered the GO-MOF breathing phenomenon and opened the structure, and gate was closed after dehydrogenation. The dehydrogenation peak temperature was greatly reduced by 30°C compared to that of pristine AB with suppressed byproduct like ammonia. The absorption peak

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15

Hsieh, Yu-ching, and 謝雨靜. "Synthesis of Poly(3-hexylthiophene) (P3HT) and Its Functionalization with Thiol and Amine." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/26244429891975875414.

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碩士<br>逢甲大學<br>化學工程學所<br>95<br>Electrically conducting polymers bring a new era of novel devices and applications emerging gradually in the market. Decades of revolutionary research has not only discovered exciting science but also led to plastic electronics. Due to its high electrical conductivities, poly (3-hexyl thiophene) or P3HT behaves like semiconductors. It is normally used as the hole transport layer (HTL) in an electroluminescent device, and the conductive components in coatings and plastic composites. P3HT films have a wider light absorption band and a more orderly packing in polymer

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16

Manavalan, Gopinathan, and 郭納登. "Oxygen and amine functionalization of screen printed carbon electrode for the electrochemical sensing applications." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/5jkcba.

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博士<br>國立中興大學<br>化學系所<br>106<br>This thesis describes the oxygen, dicyandiamide functionalization of screen printed carbon electrode (SPCE) and use of these functional moieties for versatile sensor applications. In-situ generated different oxygen functionalities on the surface of the SPCE along with edge/defect sites of preanodized SPCE (SPCE*) is used for metal free oxidation of isoniazid (INZ). Oxygen functionalities/edge sites generated on SPCE along with the role of chloride-containing supporting electrolyte in acidic medium has been found to be crucial for effective adsorption of DCD throu

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17

Huang, Yu-Hua, and 黃鈺華. "Catalytic Evaluation of a Nickel Complex Containing an Amido Phosphine Ligand with a Pendant Amine Arm on Benzene C-H Functionalization and Olefin Isomerization." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/sf56rm.

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碩士<br>國立中山大學<br>化學系研究所<br>107<br>It has been known that benzene C-H activation by [PNN]NiH in the past study, but [PNN]NiH can’t be purified, so we can only do catalytic experiments in situ. In this experiment, [PNN]NiCl was added to Ph2SiH2 to synthesize [PNN]NiH. It is expected that the benzene C-H functionalization with Ar-X (X= Cl, Br, I) can be carried out by [PNN]NiH. 10 mol% [PNN]NiCl, one equivalent of Ph2SiH2 and one equivalent of Ar-X (X= Cl, Br, I) were added to benzene to control the heating temperature and time. The experimental results showed that the target product was the main

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18

Al, Otaibi Mona S. "Post-Synthesis Functionalization of Porous Organic Polymers for CO2 Capture." Thesis, 2014. http://hdl.handle.net/10754/324902.

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Solid porous materials are network materials that contain space void. Porous Organic Polymers (POPs) are porous materials, which are constructed from organic building blocks and exhibit large surface area with low densities. Due to these characteristics, POPs have attracted attentions because of their potential use in application such as gas storage and chemical separation. This thesis presents a study of the synthesis of novel POP being a network based on 2,5- dibromobenzaldehyde and 1,3,5-triethynylbenzene linked together via Sonogashira- Hagihara (SH) coupling. This network showed a relativ

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