Relevant bibliographies by topics / Amino aniline

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters
  4. Conference papers

Academic literature on the topic 'Amino aniline'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Amino aniline"

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Gorokhov, Valery Yu, and Tatiana V. Makhova. "Para-(aza,thio)xanthenylated anilines in the pereaminination reaction." Butlerov Communications 60, no. 10 (2019): 32–35. http://dx.doi.org/10.37952/roi-jbc-01/19-60-10-32.

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It is known that the biochemical enzymatic reaction of the reversible transfer of an amino group from an amino-acid to a keto-acid is called a transamination reaction. However, the transamination reaction is applicable not only for biochemical enzymatic reactions, but is also often used in organic synthesis to produce aromatic azomethines. As objects of study in the transamination reaction, we selected substituted N-benzylidenanilines (imines, Schiff bases) and anilines, containing a biologically active heterocyclic fragment in the para-position of the aniline ring. We have shown the feasibili
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Shteinberg, Leon. "INFLUENCE OF SUBSTITUTES ON THE RATE OF THE REACTION OF ORTHOSUBSTITUTED BENZOIC ACIDS WTH ANILINE, CATALYZED BY POLYBUTOXYTITANATES." Ukrainian Chemistry Journal 87, no. 3 (2021): 18–40. http://dx.doi.org/10.33609/2708-129x.87.03.2021.18-40.

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The polybutoxytitanates catalysis of aniline acylation by orthosubstituted benzoic acids leads to the production of substituted benzanilides. Catalytic rate constants of the second order reaction (the first with respect to aniline and ortho-substituted benzoic acid; boiling ortho=xylene, 145°C) correlate well according to the Hammett and Bronsted equations with straight line segments with ρ=1.93 and α=0.66, in contrast to the reaction of aniline with meta- and parasubstituted benzoic acids and substituted anilines with benzoic acid. This dependence drops out 2=nitrobenzoic and 1=naphthoic acid
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Yunnikova, Lidiya P., Yuliya E. Likhareva, and Svetlana Yu Balandina. "N-TROPYLATION OF ARYLAMINES." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 62, no. 2 (2019): 79–84. http://dx.doi.org/10.6060/ivkkt.20196202.5751.

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An efficient method for introduction of biogenic tropylium cycle into aromatic amines molecules is offered. Introduction is carried out in the presence of imidazole as a strong base. Interaction between tropylium salts (tetrafluoroborate or perchlorate) and aromatic amines with either nitro- or acetyl groups (meta-nitroaniline, para-nitroaniline, 2-methyl-4-nitroaniline and para-acetylaniline) as electron-acceptor substituents in the benzol ring results in stable products resulting from substitution of the hydrogen atom in the amino group of aromatic amines, namely: 4-nitro-N-(1'-cyclohepta-2'
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Egu, S. A., J. F. Sale, A. O. C. Aliyu, A. Yahaya, and A. Ocheni. "Synthesis of Amino Acid and Aniline Derivatives of Quinolinediones." Journal of Basic and Applied Research International 29, no. 5-6 (2024): 71–75. http://dx.doi.org/10.56557/jobari/2023/v29i5-68569.

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Successful synthesis of amino acid and aniline derivatives of 6,7-dibromo-5,8-quinolinedione is reported. 6,7-Dibromo-5,8-quinolinedione was prepared by nitrosation of 8-hydroxyquinoline, followed by subsequent amination and oxidation of the resulting intermediates. Thereafter, addition of amino acids and anilines supplied the desired products. Effect of solvent on reaction yield and time showed pyridine as the best amongst the studied solvents. Structural elucidation was done using proton NMR and mass spec.
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Abd El-Ghaffar, M. A., K. A. Shaffei, and Nourelhoda Abdelwahab. "Evaluation of Some Conducting Polymers as Novel Antioxidants for Rubber Vulcanizates." International Journal of Polymer Science 2014 (2014): 1–9. http://dx.doi.org/10.1155/2014/893542.

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Natural rubber (NR) and styrene-butadiene rubber (SBR) formulations containing polyaromatic and polyheterocyclic amine homopolymers and copolymers were prepared. The studied homopolymers named polythiophene (PT), poly(o-phenylene diamine) (Po-PDA) and copolymers named poly(aniline-co-m-toluidine) (PAn-co-mT), poly(aniline-co-o-phenylene diamine) (PAn-co-o-PDA), poly(aniline-co-thiophene) (PAn-co-T), poly(aniline-co-2-amino pyridine) (PAn-co-2APy), and poly(2-amino pyridine-co-o-phenylene diamine) (P2APy-co-o-PDA) have been prepared and characterized. The rheological characteristics and physico
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Al-Howsaway, Hamida O. M., Magda F. Fathalla, Ali A. El-Bardan, and Ezzat A. Hamed. "Reaction of 4-Chloro-3,5-Dinitrobenzotrifluoride with Aniline Derivatives. Substituent Effects." Journal of Chemical Research 2007, no. 9 (2007): 509–12. http://dx.doi.org/10.3184/030823407x240926.

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N-(2,6-Dinitro-4-trifluoromethylphenyl)aniline derivatives were prepared by anilino-dechlorination of 4-chloro-3, 5-dinitrobenzotrifluoride. IR, UV and 1H NMR studies suggested an intramolecular hydrogen bond between the amino hydrogen and one o-nitro group. An addition-elimination mechanism was suggested based on the second-order kinetics and the dependence of rates on the nature and the position of the substituent in the aniline ring, as well as the high negative values of ρ(-3.14, −3.16, −3.01). Such values indicate a positive charge on the aniline nitrogen in the transition state and that
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Yateem, Ali Hussain. "Rotational barrier and electron-withdrawing substituent effects: Theoretical study of -conjugation in para-substituted anilines." Mediterranean Journal of Chemistry 10, no. 4 (2020): 319–34. http://dx.doi.org/10.13171/mjc02004161378ahy.

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The rotational barrier RB around C–NH2 bond between the minimum and maximum states of 84 electron-withdrawing groups at para-position in aniline were studied at the density functional wB97X-D/6-31G** level. The rotational barrier was found to correlate strongly with shortening of the C–NH2 bond, increase of flattening of NH2 group, decrease in negative natural charge on amino nitrogen, increase in minimum ionization potential around lone pair of amino nitrogen, increase in maximum (positive) electrostatic potential on amino hydrogens, increase in NH2 stretching frequencies, and increase in sta
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Tijjani, A. U., A. J. Sufyan, S. Ibrahim, et al. "Characterization of Aniline Degradation by A Previously Isolated Molybdenum-reducing Pseudomonas sp." Bioremediation Science and Technology Research 9, no. 2 (2021): 17–20. http://dx.doi.org/10.54987/bstr.v9i2.621.

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Microorganisms play an integral role in detoxification and removal of toxic compounds from the environment. Aniline is the simplest aromatic amine, consisting of a phenyl group attached to an amino group that is used as herbicide to control weeds. Aniline is detrimental to both environment and health. In this research, six previously isolated bacteria (isolate A-F) were screened on Bushnell Hass media for their potential to grow and utilize aniline as a sole carbon source. Isolate A (Pseudomonas sp.) was found to tolerate and grow best with aniline sole source of carbon. Optimum conditions for
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Shteynberg, Leon. "INFLUENCE OF SUBSTITUTES ON THE RATE OF THE REACTION OF META- АND PARASUBSTITUTED BENZOIC ACIDS WTH ANILINE, CATALYZED BY POLYBUTOXYTITANATES". Ukrainian Chemistry Journal 86, № 6 (2020): 108–31. http://dx.doi.org/10.33609/2708-129x.86.6.2020.108-131.

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The polybutoxytitanates catalysis of acylation of anilines by meta- and parasubstituted benzoic acid results in substituted benzanilides. The rate constants of this second-order reaction (the first in terms of aniline and substituted benzoic acid; boiling ortho-xylene, 145 °С) correlates well according to the Hammett equation with two straight lines for individual groups of substituents with ρ = 1.76 (electron donors) and 0.12 (electron acceptors). Oxybenzoic and phthalic acids, that do not react with aniline and inhibit the interaction of the latter with benzoic acid, fall out of this depende
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Lee, Hwa Jin, and Sang Wook Kang. "CO2 Separation with Polymer/Aniline Composite Membranes." Polymers 12, no. 6 (2020): 1363. http://dx.doi.org/10.3390/polym12061363.

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Polymer composite membranes containing aniline were prepared for CO2/N2 separation. Aniline was selected for high separation performance as an additive containing both the benzene ring to interfere with gas transport and an amino group that could induce the accelerated transport of CO2 molecules. As a result, when aniline having both a benzene ring and an amino group was incorporated into polymer membranes, the selectivity was largely enhanced by the role of both gas barriers and CO2 carriers. Selective layers coated on the polysulfone were identified by scanning electron microscopy (SEM) imag
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Dissertations / Theses on the topic "Amino aniline"

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Prevost, Valérie. "Contribution à l'élaboration de matériaux polymères conducteurs électroniques : étude et modélisation de la polymérisation de l'aniline et de sa copolymérisation avec des acides o-amino-phénoxyalcanesulfoniques." Vandoeuvre-les-Nancy, INPL, 1997. http://www.theses.fr/1997INPL046N.

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Dans le cadre du développement de matériaux polymères conducteurs électroniques, ces travaux visent, d'une part, l'élaboration d'un modèle de la polymérisation de l'aniline par couplage chimique oxydant (en milieu acide et en présence de persulfate d'ammonium), et d'autre part, son extension à la copolymérisation de l'aniline avec des acides o-amino-phénoxyalcanesulfoniques. Mise en place pour l'étude de l'influence des conditions opératoires (nature de l'oxydant, acidité du milieu, concentrations des réactifs,), la technique de suivi de l'avancement de la réaction par la mesure du potentiel r
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Naturale, Guillaume. "Approches radicalaires pour la fonctionnalisation directe de quinones à visée anticancereuse." Thesis, Bordeaux 1, 2012. http://www.theses.fr/2012BOR14635/document.

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Dans le cadre d’un programme de recherche dédié à la découverte de petites molécules à visée anticancéreuse, nous avons envisagé de concevoir des composés originaux dérivés de quinones. Notre premier objectif a été d’élaborer des mimes non-peptidiques de la protéine Smac, susceptibles de participer à relancer le phénomène d’apoptose, dont la structure est rigidifiée par des contraintes conformationnelles. Par ailleurs, les kinases et les phosphatases, jouant des rôles complémentaires de phosphorylation / déphosphorylation dans le cadre du contrôle du cycle cellulaire notamment, apparaissent au
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Philippot, Karine. "Evaluation de complexes amido de rhodium en hydroamination catalytique des oléfines." Toulouse 3, 1993. http://www.theses.fr/1993TOU30090.

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Ce memoire decrit une etude exploratoire de la reactivite de complexes amido de rhodium pour l'hydroamination catalytique d'olefines. Jusqu'ici, aucune solution satisfaisante n'a ete mise a jour pour cette reaction qui constituerait, a l'evidence, une alternative tres interessante aux procedes actuels de synthese industrielle d'amines. L'examen des differents cycles catalytiques envisageables a permis d'imaginer un processus original mettant en jeu, comme precurseur catalytique, un complexe amido de rhodium. La reaction de l'anilidure de lithium sur des complexes de rhodium (i) a ete etudiee e
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Lynch, Peter Neil. "An investigation into the reactivity of nitrosobenzenes as carcinogenic metabolites of nitrobenzenes and anilines." Thesis, University of Newcastle Upon Tyne, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.361594.

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HADDAD-FAHED, OMAIMA. "Catalyse micellaire de reactions de substitution nucleophile aromatique comportant des reactifs electriquement charges." Paris 6, 1987. http://www.theses.fr/1987PA066419.

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Cambou, Patrick. "Rôle du twist à l'état fondamental sur l'anomalie de fluorescence double des N, N dialkylanilines para-substituées diluées en solutions liquides et solides : application au dosage des traces d'eau." Grenoble 1, 1987. http://www.theses.fr/1987GRE10045.

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BENNOUR, SADJIA. "Energetique et mecanismes de la formation et de la coupure des gem-amino-ethers derives des n-benzylidene-anilines dans le methanol." Paris 7, 1990. http://www.theses.fr/1990PA077175.

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L'addition du methanol sur les n-benzylidene-anilines substituees sur le groupe anilino a ete etudiee tant sur le plan cinetique que sur celui thermodynamique. La reaction de formation des gem-amino-ethers, analogues a la formation des hemiacetals et a la formation des gem-amino-alcools, est soumise a une catalyse basique par l'ion methylate et a une catalyse acide dans les milieux tampons constitues d'acides carboxyliques et d'ions carboxylates. Les mecanismes des deux processus, ainsi que celui de la voie non catalysee, ont ete examines sur la base des effets de substituant, des effets isoto
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Cheng, Ying. "Part I: the 't-amino effect' in the Vilsmeier formylation of p-substituted tertiary anilines : part II: study of the chemistry of aminochlorocarbenes derived from Vilsmeier reagents by the action of bases." Thesis, University of Sunderland, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297371.

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Monzón, Díaz Gabriel Andrés [Verfasser], and Paul [Akademischer Betreuer] Knochel. "Zincation of heterocycles and aryl nonaflates : directed magnesiation of highly substituted anilines and amino-substituted heterocycles ; synthesis of heterobenzylic zinc compounds ; new generation of iminium salts / Gabriel Andrés Monzón Díaz. Betreuer: Paul Knochel." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2012. http://d-nb.info/1025821947/34.

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Bahri, Hamed. "Thermodynamique dans les milieux diphasés dispersés : cas des solutions micellaires et des microémulsions." Paris 6, 1986. http://www.theses.fr/1986PA066280.

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Déduction de relations théoriques générales liant dans les systèmes liquides diphasés, les grandeurs observables "globales" aux grandeurs "locales" dans les différentes phases. Exposé de définitions et de notions thermodynamiques. Etablissement de relations générales pour les grandeurs molaires partielles. Etudes du cas d'un système réel : bromures d'alkyltrimethylammonium en milieu eau-kcl, qui montre que les solutions micellaires en milieu salin concentré peuvent être considérées comme un système diphasé. Données sur le partage d'un soluté moléculaire aniline en milieu micellaire. Etudes des
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Book chapters on the topic "Amino aniline"

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Panigrahi, Muktikanta, and Basudam Adhikari. "Acrylic Acid (AA) Based Polyaniline Composite for Liquified Petroleum Gas (LPG) Sensors." In Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip2124.

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N-substituted PANI-ES was obtained from N-phenyl-β-alanine (N-substituted aniline). N-phenyl-β-alanine was synthesized chemically from methyl acrylate and aniline precursor. ESI-MS, H1NMR spectroscopy and FTIR spectroscopy are employed to characterise the N-phenyl-β-alanine for structure elucidation. The structure and properties of corresponding polymers were investigated by X-ray diffraction, FTIR, UV-Visible, H1NMR, FESEM, solubility, and DC conductivity. On the basis of experimental results of prepared N-substituted aniline monomer and its corresponding polymer is proposed. At room temperat
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Benkoski, Léa, and Tristan H. Lambert. "Construction of Multiple Stereocenters." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0039.

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Erick M. Carreira at ETH Zürich reported (Science 2013, 340, 1065) the enantiose­lective α-allylation of aldehyde 1 with alcohol 2 to produce 3 using a dual catalytic system involving a chiral iridium complex and amine 5. This stereodivergent method allows access to all of the possible stereoisomers of 3. In a conceptually related proc­ess, John F. Hartwig at the University of California, Berkeley reported (J. Am. Chem. Soc. 2013, 135, 2068) the highly stereoselective allylic alkylation of azlactone 6 with allylic carbonate 7 catalyzed by a combination of Ir(cod)Cl₂, ligand 9, and racemic silv
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"EFFECT OF AMINO NAPHTHALENE SULFONIC ACID NATURE ON THE STRUCTURE AND PHYSICAL PROPERTIES OF THEIR COPOLYMERS WITH ANILINE." In Functional Polymer Blends and Nanocomposites. Apple Academic Press, 2014. http://dx.doi.org/10.1201/b16895-13.

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Lambert, Tristan H. "Synthesis of Heteroaromatics." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0069.

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Peter Wipf at the University of Pittsburgh utilized (J. Org. Chem. 2013, 78, 167) an alkynol-furan Diels-Alder reaction to convert 1 into the hydroxyindole 2. An intramolecular Larock indole synthesis was employed (Angew. Chem. Int. Ed. 2013, 52, 4902) by Yanxing Jia at Peking University for the conversion of aniline 3 to tricyclic indole 4. The reaction of boronodiene 5 with nitrosobenzene to produce pyrrole 6 was reported (Chem. Commun. 2013, 49, 5414) by Bertrand Carboni at CNRS University of Rennes and Andrew Whiting at Durham University. The merger of imine 7 with propargyl amine 8 in the
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Taber, Douglass F. "Substituted Benzenes: The Garg Synthesis of Tubingensin A." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0062.

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John F. Hartwig of the University of California, Berkeley devised (Science 2014, 343, 853) conditions for the regioselective silylation of an arene 1 to give 2. The silyl group can directly be converted, inter alia, to halo, amino, alkyl, or hydroxyl. Jin-Quan Yu of Scripps La Jolla effected (Angew. Chem. Int. Ed. 2014, 53, 2683) regioselective alkenylation of the arene 3 with 4 to give 5. Wei-Liang Duan of the Shanghai Institute of Organic Chemistry described (Org. Lett. 2014, 16, 500) a related alkenyl­ation protocol. Deping Wang of Henyang Normal University developed (Eur. J. Org. Chem. 201
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Taber, Douglass F. "Heteroaromatic Synthesis: The Tokuyama Synthesis of (−)-Rhazinilam." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0066.

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Mei-Huey Lin of the National Changhua University of Education rearranged (J. Org. Chem. 2014, 79, 2751) the initial allene derived from 1 to the γ-chloroenone. Displacement with acetate followed by hydrolysis led to the furan 2. A. Stephen K. Hashmi of Ruprecht-Karls-Universität Heidelberg showed (Angew. Chem. Int. Ed. 2014, 53, 3715) that the Au-catalyzed conversion of the bis alkyne 3, mediated by 4, proceeded selectively to give 5. Tehshik P. Yoon of the University of Wisconsin used (Angew. Chem. Int. Ed. 2014, 53, 793) visible light with a Ru catalyst to rearrange the azide 6 to the pyrrol
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"A Combined Effect of Ultrasound Cavitation on Adsorption Kinetics in Removal of 4-[(4-Dimethyl Amino Phenyl) Phenyl-Methyl]-N, N-Dimethyl Aniline Along With Bio-Adsorbent." In Chemical and Bioprocess Engineering. Apple Academic Press, 2015. http://dx.doi.org/10.1201/b18402-41.

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"Synthetic Methods for Primary Anilines." In Methods and Strategies for C–N Bond Formation Reactions. Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781837672615-00145.

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Aryl amines have received significant interest because these compounds widely exist in the structural backbones of ligands, pharmaceuticals, agrochemicals, natural products, and functional materials. In N-arylation reactions, several types of organic electrophile coupling partners such as (pseudo)halides (Ullmann-type and Buchwald–Hartwig couplings) and boronic acids (Chan–Lam coupling) are popular. The main synthetic methods for the preparation of these compounds involving N-arylation utilize aryl halides. Progress has been made with the coupling of arylating reagents which are less expensive
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Taber, Douglass F. "Enantioselective Preparation of Alcohols and Amines:The Suh Synthesis of (-)-Macrosphelide J." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0035.

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Keiji Maruoka of Kyoto University (J. Am. Chem. Soc. 2009, 131, 3450) and Yujiro Hayashi of the Tokyo University of Science (Chem. Commun. 2009, 3083) independently developed organocatalysts for the enantioselective α-benzoylation of aliphatic aldehydes such as 1. The product 3 can be readily carried on to, inter alia, either enantiomer of the epoxide. Chengjian Zhu of Nanjing University designed (Adv. Synth. Cat. 2009, 351, 920) a chiral salen complex that mediated the enantioselective opening of both cyclohexene oxide (4) and cyclopentene oxide. This reagent combination might also engage jus
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Taber, Douglass. "Substituted Benzenes: The Alvarez-Manzaneda Synthesis of (-)-Taiwaniquinone G." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0065.

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Continuing efforts toward the direct functionalization of aromatic C-H bonds, Nobutaka Fujii and Hiroaki Ohno of Kyoto University described (Chem. Commun. 2009, 3413) a Pd-mediated protocol for the ortho hydroxylation of aryl tetrahydropyrimidines such as 1. To use a boronic acid as an activating/directing group, Michinori Suginome, also of Kyoto University, devised (J. Am. Chem. Soc. 2009, 131, 7502) the pyrazolylpyridyl derivative 3. The product 4 could be returned to the boronic acid or carried on to the borate ester, in each case with recovery of the directing group. Eiichi Nakamura of the
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Conference papers on the topic "Amino aniline"

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Sterczewski, Lukasz A., Jakub Mnich, and Jaroslaw Sotor. "Multi-Octave THz Generation and Detection at MHz Repetition Rates using the Organic Nonlinear Crystal PNPA." In CLEO: Science and Innovations. Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_si.2024.sm2p.5.

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Generation and detection of broadband THz radiation using the PNPA ((E)-4-((4-nitrobenzylidene)amino)-N-phenyl-aniline) crystal at MHz repetition rates is demonstrated. Compatibility with nanojoule pump pulses at telecommunication wavelengths makes this medium attractive for compact THz spectrometers.
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Haskaj, Adelina, Musaj Pacarizi, Sonja Lepitkova, Berat Sinan, Bahri Sinani, and Elida Dreshaj. "THE POTENTIAL COMPLEXING IMPACT OF SOME ORGANIC COMPOUNDS AMINE AND CARBOXYL GROUPS ON TRANSITION METALS." In 24th SGEM International Multidisciplinary Scientific GeoConference 24. STEF92 Technology, 2024. https://doi.org/10.5593/sgem2024/4.1/s18.42.

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Environmental water chemistry is substantially aided by modern electrochemical research. Sensitive voltammetric techniques are much more useful for metal species in natural waters, where complexation with organic molecules predominates. Many environmental electrochemists are still interested in determining the stability constants of metal ion complexes with various ionic species found in natural waterways. The aim of this work is to investigate the possible influence of complexation of amine and carboxyl groups of some organic molecules (with EDTA, NTA and aniline, using differential pulse pol
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Al-Douh, Mohammed Hadi, Hasnah Osman, and Shafida Abd Hamid. "Synthesis, NMR spectroscopy and crystal structures studies of 2-amino-N-(2-hydroxy-3-methoxybenzylidene) aniline." In 2009 International Conference on Instrumentation, Communications, Information Technology, and Biomedical Engineering (ICICI-BME). IEEE, 2009. http://dx.doi.org/10.1109/icici-bme.2009.5417219.

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de Lange, M. C. C., D. Thorn Leeson, A. H. Huizer, and C. A. G. O. Varma. "Features of the Dual Fluorescence of 4-N,N-dialkylaminoalkylbenzoates in Alkanes." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/up.1992.mc34.

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The appearance of a normal band FN and an anomalous band Fx, to the red of the former, in the fluorescence spectrum of solutions of 4-N,N-diethylaminoethylbenzoate in alkanes has been considered as evidence for the existence of a low energy twisted intramolecular charge transfer (TICT) excited state in electron acceptor substituted aniline derivatives [1]. Objections have been raised against this interpretation of the dual fluorescence [2]. Nevertheless, the TICT state seems to be widely accepted as a reasonable explanation of the phenomenon. Here we will present evidence that the long wavelen
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Yan, Shuxin, Teresa Moore, and Lee H. Spangler. "Ring-mediated coupling of NH2 and CH3 modes in para-methylaniline." In OSA Annual Meeting. Optica Publishing Group, 1990. http://dx.doi.org/10.1364/oam.1990.tuy38.

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Jet-cooled fluorescence-excitation spectra of aniline, aniline-ND2, p-methylaniline and p-methylaniline-ND2 will be presented. Two moderately intense peaks in the p-methylaniline spectrum show an unusual multiplet splitting that is not observed in the ring modes. These two transitions also show a large (100 cm−1) deuterium shift in the ND2 molecule and are thus assigned as evenquanta transitions involving the amine inversion and torsion. The corresponding peaks in aniline are not split, indicating that the splitting is due to the interaction of the CH3 torsion with large-amplitude amine motion
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Quattrociocchi, Daniel Garcez Santos, Antonio Rafael de Oliveira, Douglas da Motta Pio, and Vinicius Rangel Campos. "Estudo teórico da formação da isatina e de seus derivados dimetoxilados pelo método Sandmeyer." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020109.

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Isatin has been attracted the researchers attention due the structural versatility and can be used to synthesized other molecules with pharmacological activities. The Sandmeyer method is one of the most common methods for the synthesis of this molecule. Where the reaction with from aniline with chloral hydrate and hydroxyl amine occurs with good yield. When the same reaction is performed with dimethoxylated aniline show low yield or is not observed experimentally. These observations motivate this work and the justification for these facts are given in terms of thermodynamic parameters and by t
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Plaza, P., N. Dai Hung, M. M. Martin, Y. H. Meyer, and W. Rettig. "Investigation of Fast Relaxation Processes in Non-fluorescent Rhodamine Dyes." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/up.1992.fc21.

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Non radiative relaxation of various N-substituted ethyl-ester-Rhodamine dyes (scheme A) was explained by assuming an intramolecular rotational motion towards a low lying non emissive TICT-like state with charge localization [1]. Stationary and time-resolved fluorescence experiments evidenced that fluorescence quenching in those Rhodamines is linked with the rotation of the amino group. On the other hand, if the o-carboxyphenyl group is exchanged for a p-dimethylamino electron donor group (scheme B), the fluorescence quantum yield is very low in neutral ethanol but increases by more than two or
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Sakamoto, Ken, Kohei Sato, Akira Shigenaga, Daisuke Tsuji, Kohji Itoh, and Akira Otaka. "Development of Efficient Synthetic Method for N-Amino Acyl N-Sulfanylethyl Anilide Linkers as Peptide Thioester Equivalent." In The Twenty-Third American and the Sixth International Peptide Symposium. Prompt Scientific Publishing, 2013. http://dx.doi.org/10.17952/23aps.2013.242.

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Kinaci, Emre, Giuseppe Palmese, Joseph Stanzione, and Sarah Salazar. "Evaluation of hybridized bio-based building blocks as coating materials." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/oyjf3899.

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Commercial epoxy resins are often the oligomeric reaction products of bisphenol A (BPA) with epichlorohydrin. BPA is a toxic petrochemical and a well-known endocrine disruptor which can mimic the body’s own hormones and may lead to several negative health effects. The most common curing agents are also the derivatives of toxic amines such as aniline, ethylene di-amine, and ammonia etc. which are under strict regulations and restrictions by TSCA and (REACH) agencies. Therefore; there is a growing demand to develop epoxy and amine systems from non- or less- toxic and annually renewable precurs
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