Dissertations / Theses on the topic 'Anaerob rötning'
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Gregeby, Erik. "Optimeringsunderlag för anaerob rötning av flytgödsel från nötkreatur." Thesis, Växjö University, School of Technology and Design, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:vxu:diva-5519.
Full textProduktions- och optimeringspotentialen vid anaerob rötning av flytgödsel från nötkreatur granskades. Detta genom att, i laboratoriemiljö, undersöka förändringar i processtabilitet, gasproduktion och metanhalt vid tillsats av kycklinggödsel och pH-buffert med flytgödsel från nötkreatur som grundsubstrat. Tillsatsen av pH-buffert underlättade tillväxtfasen för mikroorganismerna, snabbare ökning i metanhalt och den totala metangasproduktionen ökade. Skillnaden var som störst under tillväxtfasen och avtog från stationärfas och framåt. Tillsats av kycklinggödsel har i detta fall inhiberat processen, möjligtvis på grund av ammoniakinhibering vid tillsats av det kväverika substratet som kycklinggödsel är.
Production potential and basis for optimization of anaerobic digestion with cattle manure was reviewed by examining process stability, gas production and methane content in a laboratory environment via addition of pH buffer and chicken manure with slurry from cattle manure as basic feedstock. Addition of pH buffer facilitated the growth of microorganisms by more rapid increase in methane content and greater quantities of produced methane gas. The effects were high during the growth stage but decreased, during and after, the stationary phase. Addition of chicken manure caused inhibition of the process, probably caused by ammonia inhibition from high nitrogen content in chicken manure.
Montelius, Josefine. "Förbehandling av skogsindustriellt slam för ett ökat metanutbyte vid rötning : En kombination av termisk och kemisk förbehandling." Thesis, Karlstads universitet, Institutionen för ingenjörs- och kemivetenskaper, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-31178.
Full textIn the pulp and paper process 505 million tons of water are polluted annually, which has to be purified before it is returned to the surrounding lakes. When the water is treated bigger particles are first separated to form sludge, then dewatered and finally incinerated. The excess water is further treated were a type of sludge bio sludge is formed. The bio sludge contains high concentration of intracellular water, why it is expensive and energy demanding to dewater. It is also forbidden to dump organic waste since 2005, why a more economically attractive treatment of the water is anaerobic digestion. In the digestion organic compounds is converted into methane and carbon dioxide where the methane is the desired gas. The bio sludge also contains fiber residues and microorganisms with complex structure and is nutrient-poor, which makes it hard to digest. Some kind of disintegrating pretreatment is needed and co-digestion with a more nutrient-rich sludge to facilitate the digestion process. In this project thermal pretreatment in combination with chemical pretreatment was examined on bio sludge from Stora Enso Skoghalls bruk at Hammarö. The anaerobe digestion was done by two rounds whereof the first round thermal pretreated at 70C and the second at 140C. The chemical pretreatment was done by additive of sodium hydroxide, calcium hydroxide and phosphoric acid at pH 9 and 11 for the bases and pH 2 and 4 for the acid. Also neutral samples (no chemical pretreatment) and a reference sample (no pretreatment) were done. The bio sludge were co-digested with municipal sludge from Fiskartorpets reningsverk in Kristinehamn which has a mesophilic bacterial culture. The anaerobic digestion lasted for 19 days per round at a temperature of 35C and were done batch wise in E-flasks provided with a small bag for gas collection. Totally 42 samples were made per round which consisted of seven measurement points and six replicates each for a good statistical basis. The results gave an indication of the highest methane production for the samples treated with calcium hydroxide at 140C and the neutral sample treated at 140C. The sample treated with calcium hydroxide at pH 9 and 70C gave the lowest production of methane followed by the reference sample. The samples treated with sodium hydroxide gave a lower methane production at 140C than at 70C while the acid treated samples had almost the same production at the two different temperatures. All the samples had in common a higher proportion of methane in the biogas when treated at 140C than at 70C. The results should be taken with caution since the distribution amongst the samples within the same pretreatment method sometimes is very high.
Gregeby, Erik. "Design och uppbyggnad av satsvisa och kontinuerliga reaktorsystem för anaerob teströtning." Thesis, Linnaeus University, School of Engineering, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-8374.
Full textDetta arbete innefattar planering, uppbyggnad och inkörning av teströtningsanläggning för biogasproduktion, bestående av batch- och tankreaktorsystem. Arbetet inbegriper även utförandet av experiment, på batchreaktorsystem, som syftar till att ge en första inblick och vägledning för vidare studier kring optimering av processen med inriktning på tillsats av kolkälla och justering av kvoten mellan kol och kväve. Utifrån de resultat som erhållits vid försök på batchreaktorsystemet observerades en positiv effekt, gällande ökad nedbrytning av VFA, vid tillsats av glukos till systemet. Igångkörning av tankreaktorsystemet gav erfarenheter gällande handhavandet av anläggningen samt driftsäkerheten, vad gäller t.ex. återstart efter strömavbrott, loggning av gasflödesdata, pålitlig substratdosering och substratuttag utan syreläckage in i systemet.
Fokkema, Maaike. "Spårämnestillsatsers påverkan på biogasproduktionen vid anaerob rötning av avloppsslam : Behovet av spårämnen vid slamrötning på Karlstads reningsverk." Thesis, Karlstads universitet, Institutionen för miljö- och livsvetenskaper (from 2013), 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-68462.
Full textThe Swedish government has set a national goal to have no vehicles running on fossil fuels in year 2030. One of the fuels that can replace the fossil fuels of today is biogas. The biggest wastewater treatment plant in Karlstad, called Sjöstadsverket, is already producing biogas and is expanding to receive more sludge in the future. Because of this, Sjöstadsverket wants to investigate the possibility of a more effective biogas production. A common way to improve biogas production is trace element additives. Therefor the addition of cobalt, nickel, iron and magnesium has been investigated through small scale thermophilic anaerobic digestion trials in batch reactors. The trace elements have also been added in combination with EDTA to investigate the bioavailability of the trace elements. In addition to these experiments a correlation analysis was performed where different factors that might influence the biogas production were investigated for year 2017. The results from the digestion trials prove that no addition of iron, magnesium, cobalt or nickel will increase the biogas production. Instead, the biogas production was inhibited during two out of three experiments. These results indicate that the organisms in the digester at Sjöstadsverket already have a sufficient amount of trace elements. The addition of EDTA did not increase the biogas production either which indicates that the trace elements also are bioavailable to a sufficient extent. The results from the digestion trials are validated by the correlation analysis because no correlation could be found between the biogas production and the investigated trace elements. The results from the correlation analysis show that the pH-level affects the biogas production negatively. The results indicate that the pH-level is to high, something that was also observed during the digestion trials. A higher flow rate into the digesters could lower the pH-levels according to further correlation studies. This has also been observed during the digestion trials where a shorter retention time lowered the pH-levels. Because Sjöstadsverket bases their retention time on a stable volume in the digesters, it could be possible for them to increase the biogas production by increasing the flow rates, which will happen when they start receiving more sludge. Because these conclusions are mainly based on correlations, further studies of the influence of pH-levels and retention times on the biogas production at Sjöstadsverket are recommended.
Larsson, Henric, and Madeleine Sjödal. "Undersökning av biogaspotential i rötat avloppsslam." Thesis, Linnéuniversitetet, Institutionen för teknik, TEK, 2011. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-12617.
Full textThe municipal waste treatment plant Sundet in Växjö currently has a digestion plant producing biogas. The facility consists of two digesters and a machine that dewaters the sludge after the reactors. The substrate that is used in the reactors consists of sewage sludge from Växjö. There are plans to expand the process with a third reactor in which the digested sludge will be digested a second time in order to extract more biogas. The digested sludge from reactor 1 and 2 is planned to undergo three pretreatment steps in the shape of phase separation, decomposition and sanitation before it reaches reactor 3. In the thesis a digestion process is carried out with digested sludge from Sundet in batch reactors that represents the planned third reactor. The purpose is to analyze how much extra biogas that can be extracted with a second digestion process. Calculations of how much energy that is necessary for the pretreatment stages and how much extra energy that can be extracted in the shape of biogas from the digestion process was made in the thesis. The results from the experiments shows that it is possible extract more methane rich gas from the sludge and that the pre treatment stages phase separation and decomposition use small amounts of energy compared to how much energy the extra gas gives. The sanitation process is estimated to cost quite a lot of energy compared to the energy extracted through biogas.
Moberg, Emma. "Utvärdering av jetomrörning : En studie gällande utvärdering av omrörningssystem vid Ekeby reningsverk." Thesis, Mälardalens högskola, Akademin för ekonomi, samhälle och teknik, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:mdh:diva-27880.
Full textJonsson, Maria. "Återvinning av fällningskemikalier ur kemslam från pappers- och massabruk genom acidogenes." Thesis, Karlstads universitet, Institutionen för ingenjörs- och kemivetenskaper, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-62511.
Full textMortensson, Sanna. "Potential för biogasproduktion och användning av rötrester vid anaerob rötning av slam från olika avloppsreningsverk : Val av substrat till biogasproduktionen vid Karlstads reningsverk." Thesis, Karlstads universitet, Fakulteten för hälsa, natur- och teknikvetenskap (from 2013), 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-73140.
Full textSylla, Ibrahima. "high loaded anaerobic mesophilic digestion of sewage sludge : An evaluation of the critical organic loading rate and hydraulic retention time for the anaerobic digestion process at Käppala Wastewater Treatment Plant (WWTP)." Thesis, Mälardalens högskola, Framtidens energi, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:mdh:diva-52406.
Full textGärdeklint, Sylla Ibrahima Sory. "HIGH LOADED ANAEROBIC MESOPHILIC DIGESTION OF SEWAGE SLUDGE : An evaluation of the critical organic loading rate and hydraulic retention time for the anaerobic digestion process at Käppala Wastewater Treatment Plant (WWTP)." Thesis, Mälardalens högskola, Akademin för ekonomi, samhälle och teknik, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:mdh:diva-52283.
Full textNordell, Erik. "Effekter av Zeoliter i Biogasproduktion." Thesis, Linköping University, Biotechnology, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-16761.
Full textBiogas är benämningen för metangas (CH4) som är producerad via anaerob (syrefri) rötning av biologiskt material. I Linköping finns en av Sveriges största biogasanläggningar. Anläggningen drivs av Svensk Biogas AB som ägs av Tekniska Verken i Linköping AB (publ.). I anläggningen rötas stora mängder proteinrikt substrat vilket leder till höga halter av ammoniak (NH3) och ammonium (NH4+) i rötkammaren. Ammoniak (NH3) är toxiskt för de metanbildare som i en välmående process står för den största delen av metangasproduktionen. Höga halter av ammoniak (NH3) och ammonium (NH4+) kan inhibera dessa metanbildare vilket leder till minskad gasproduktion.
Detta examensarbete syftar främst till att genom ett kontinuerligt rötkammarexperiment utreda om zeoliter är ett lämpligt hjälpmedel för att reducera ammonium (NH4+) i en anaerob process. Vid sänkta halter ammonium (NH4+) är hypotesen att de mikroorganismer som är aktiva i den mest effektiva metanbildningsvägen återetableras. Arbetet syftar även till att experimentellt utreda vilka effekter zeoliter i sin helhet har på den anaeroba processen. Zeoliters effekt vid låga zeolitkoncentrationer utreds i en serie utrötningsexperiment i batch. Dessutom har en materialstudie kring zeoliternas kapacitet i olika miljöer genomförts.
Materialstudien visade att den valda zeoliten som studerades, clinoptilolite, hade en maximal katjonbytarkapacitet på ≈ 19 mg NH4+/g zeolit. Vidare konstaterades att zeoliter med mindre diameter än 1 mm har avsevärt bättre kapacitet än zeoliter med större diameter. I det kontinuerliga rötkammarexperimentet konstaterades att clinoptilolite kan användas i en rötkammare för att reducera ammoniumhalten (NH4+). Detta utan att några allvarliga processtörningar uppstår. Cirka 175 g zeolit/l krävdes för att reducera ammoniumhalten (NH4+) från 5300 mg NH4+/l till 3200 mg NH4+/l. Det är inte realistisktatt använda så stora mängder zeoliter i en fullskalig anläggning. Mikrobiologiskt sett observerades ingen förändring av de metanbildarna som dominerar den effektivaste metanbildningsvägen.
Resultaten från utrötningsförsöket i batch visade att zeolittillsatser av 5 g/l respektive 10 g/l hade en klart positiv effekt på metanbildningen jämfört utan zeolittillsats. I de batcher med 1-10 g zeolit/l startade metangasproduktionen ≈ 14 dagar tidigare än batcherna med 0 g zeolit/l. 16 dagar efter att experimentet startade hade batcherna med 5-10 g zeolit/l producerat ≈ 500 ml metangas (CH4) jämfört med serien utan zeoliter som vid samma tidpunkt producerat ≈ 75 ml metangas (CH4). Utrötningsgraden ökade i samtliga serier med zeolittillsats jämfört med serien utan zeoliter. Tillsatsen av 5 g zeolit/l ökade den specifika metangasproduktionen med ≈ 19 % jämfört med utan zeolittillsatser. Slutsatsen är att clinoptilolite i små koncentrationer, mellan 5-10 g/l, påverkar så väl kinetiken som utrötningsgraden för den anaeroba processen på ett positivt sett. Den optimala koncentrationen av clinoptilolite i en mesofil anaerob process bör ligga mellan 5-10 g zeolit/l.
Methane (CH4) is formed by anaerobic (oxygen-free) digestion of biological materials. One of Sweden's largest biogas plants is placed in Linköping. The plant is operated by Svensk Biogas AB, which is owned by Tekniska Verken i Linköping AB (publ.). In their biogas plant a large amount of protein rich material is handled. High amounts of protein leads to high levels of ammonia (NH3) and ammonium (NH4+) in the digestion chamber. High levels of ammonia (NH3) are toxic to the most dominant methane forming microorganism. High concentrations of ammonia (NH3) and ammonium (NH4+) can inhibit these methane forming microorganisms which may lead to a reduction in gas production.
This aim with this master thesis was to reduce high ammonium levels by adding zeolites to a lab scale continuous digestion chamber. The hypothesis is that at reduced levels of ammonium (NH4+) the most effective methane forming microorganism will reestablish. This thesis also aims to experimentally investigate all types of effects that zeolites may have in an anaerobic digestion process. Which effect zeolites at low concentration have in a digestion chamber will be investigated by using lab scale batch digestion chambers. In addition, a material study on the capacity of the zeolites in different environments will be investigated.
The material study showed that the selected zeolite, clinoptilolite, had a cat ion exchange capacity around 19 mg NH4+/g zeolite. It was also found that the zeolites with a diameter less than 1 mm had significantly better capacity than zeolites with larger diameter. In the continuous digestion experiment it was found that clinoptilolite can be used in a digestion chamber to reduce high levels of ammonium (NH4+). This without any serious disorder on the process. Around 175 g zeolite/l was needed to reduce ammonium levels (NH4+) from 5300 mg NH4+/l to 3200 mg NH4+/l. However, it is not realistic to use such large amounts of zeolites in a full-scale digestion chamber. No changes in the culture of methane forming microorganisms were found.
The results of the batch experiment showed that concentrations of 5 g zeolite/l and 10 g zeolite/l had a positive effect on the methanogenesis compared to batches without additives. In the batches with 1-10 g zeolite/l the forming of methane began about 14 days earlier than in the batches without any zeolites. After 16 days, batches with 5-10 g zeolite/l had produced about 500 ml of methane (CH4), compared with series without additives, which at the same time had produced about 75 ml of methane (CH4). The methane yield increased in all series which included zeolites compared to the batches without zeolites. Addition of 5 g zeolite/l increased the specific methane production by approximately 19 % compared to no additives. The conclusion is that clinoptilolite in small concentrations; 5-10 g/l have a positive effect on as well the kinetics as on the methane yield for the anaerobic process. The best concentration of zeolites in a mesophile anaerobic digestion chamber appears to be between 5-10 g zeolite/l.
Abrahamsson, Louise. "Improving methane production using hydrodynamic cavitation as pre-treatment." Thesis, Linköpings universitet, Tema Miljöförändring, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-128783.
Full textDet behövs innovativa lösningar för att utveckla anaerob rötning i syfte att öka metangasutbytet från biogassubstrat. Beroende på substratets egenskaper, kan förbehandling möjliggöra sönderdelning av bakterieflockar, uppbrytning av cellväggar, elimination av inhiberande ämnen och frigörelse av intracellulära organiska ämnen, som alla kan leda till en förbättring av den biologiska nedbrytningen i rötningen. För att uppnå detta har den lågenergikrävande förebehandlingsmetoden hydrodynamisk kavitation prövats på biologiskt slam, matavfall, makroalger respektive gräs, i jämförelse med ångexplosion. Effekten på substraten av dessa två förbehandlingar har uppmäts genom att undersöka distribution av partikelstorlek, löst organiskt kol (sCOD), biometan potential (BMP) och nedbrytningshastigheten. Efter 2 minuters hydrodynamisk kavitation (8 bar) minskade partikelstorleken från 489- 1344 nm till 277- 281 nm (≤77 % reduktion) för de olika biomassorna. Liknande påverkan observerades efter tio minuters ångexplosion (210 °C, 30 bar) med en partikelstorlekreducering mellan 40 och 70 % för alla behandlade substrat. Efter behandling med hydrodynamisk kavitation, i jämförelse med obehandlad biomassa, ökade metanproduktionens hastighetskonstant (K) för matavfall (+65%), makroalgen S. latissima (+3%), gräs (+16 %) samtidigt som den minskade för A. nodosum (-17 %). Förbehandlingen med ångexplosion ökade hastighetskonstanten för S. latissima (+50 %) och A. nodosum (+65 %) medan den minskade för gräs (-37 %), i jämförelse med obehandlad biomassa. Vad gäller BMP värden, orsakade hydrodynamisk kavitation små variationer där endast A. nodosum visade en ökning efter behandling (+44 %) i jämförelse med obehandlad biomassa. Biomassa förbehandlade med ångexplosion visade en ökning för A .nodosum (+86 %), gräs (14 %) och S. latissima (4 %). Sammantaget visar hydrodynamisk kavitation potential som en effektiv behandling före rötning och kapabel att konkurrera med den traditionella ångexplosionen gällande kinetik och energibalans (+14%) samt metanutbytet för A. nodosum.
Filipsson, Ingela. "Latrin som substrat vid rötning : utvärdering av biogaspotential och reduktion av läkemedelsrester." Thesis, Institutionen för energi och teknik, SLU, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-263077.
Full textWastewater contains nutrients such as nitrogen and phosphorous which can cause eutrophi-cation in lakes and streams. Meanwhile, large quantities of nutrients are used in agriculture in order to produce food. One way to utilize nutrients in wastewater and return them to agriculture could be source separation of sewage. This way, nutrients are collected in smallvolumes and are not mixed with bathing, washing, and cleaning water. This thesis aimed at investigating anaerobic digestion as a treatment method and technology to make use of the energy in latrine. In anaerobic digestion, microorganisms degrade organic material and produce energy rich biogas that can be used for heating, electricity, or vehicle fuel. The residue remaining after digestion contains nutrients but also pollutants. The study examined the content of heavy metals and drug residues in latrine, and to what extent the digestion process affected the pharmaceutical content. To evaluate the anaerobic digestion as treatment of latrines, 44 batch experiments wereperformed at laboratory scale. Latrine was taken from a collection basin in Norrtälje. Inoculum from two active anaerobic digestion plants were mixed with latrine in sealed glass bottles and put on shaking tables for approximately 60 days. Some bottles contained an addition of eight drugs dissolved in methanol. Two parallel experiments were performed one at mesophilic temperature (37ºC) and one at thermophilic temperature (52ºC). The volume of gas produced and methane content was measured for calculation of the biogas potential. After completion of the digestion period, the liquid and solids were separated and frozen pending analysis of drug residues. The biogas produced was a little over 250 Nml CH4/gVS after 60 days being comparable to production from pig and chicken manure. The bottles containing added substances showed no inhibition of the biogas process since the gas production was slightly greater in these. The nitrogen content of latrine was 3.7 g/L, the phosphorus content 1.0 g/L and potassium content of 1.0 g/L. The cadmium-phosphorus ratio was 25 mg Cd/kg P, same as the average of Revaq certified sewage sludge. The heavy metal concentrations were below the limits allowed for sewage fractions applied on arable land as proposed by the Swedish Environ-mental Protection Agency. The latrine could be used as fertilizer with current and proposed regulations. Several things indicate that the latrine used contained a higher feces-urine ratio than expected and therefore does not fully represent a complete blackwater. Analyses on drug concentrations were preformed on the liquid phase of the material before and after various periods of anaerobic digestion. Anaerobic digestion proved not to be an effective method to reduce pharmaceuticals in latrine. There were more cases where the concentration of the drug increased rather than decreased during digestion. The increase could be due to changes in adsorption properties of the material during digestion, making them more observable in the analysis. The presence of pharmaceuticals in the environment is relatively well known but more understanding is needed on the hazards of pharmaceutical residues in aquatic and especially agricultural environment.
Mustafa, Riham, and Omnia Bakhiet. "Biogas Produktion i Abu Dhabi – En Utvärdering baserad på Energi och Ekonomi (Jämförelse av två teknologier)." Thesis, KTH, Fastigheter och byggande, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-170577.
Full textAndersson, Johanna. "Optimering av driftstemperatur vid mesofil rötning av slam : - funktionskontroll vid Uppsalas reningsverk." Thesis, Uppsala universitet, Institutionen för geovetenskaper, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-381615.
Full textEnergy efficient processes and the use of fossil free fuels play an important role in order to reduce the impact of climate change. Anaerobic digestion is a common way for stabilizing sewage sludge at wastewater treatment plants (WWTP). One of the benefits with anaerobic digestion is that it also produces biogas, a fossil free fuel with low greenhouse gas emissions. An operational temperature within the mesophilic range has proven to give a stable process with an unfluctuating production of gas. The mesophilic temperature range between 25-40°C but most processes are operated between 35-40°C. This study investigates the opportunity to lower the temperature within the mesophilic range in order to reduce energy consumption. It is important to maintain the production of biogas with a lower temperature. Therefore, the reduction in VS-content (VS-volatile solids), methane yield and time for degradation was determined by a BMP-experiment (BMP-Biochemical Methane Potential) in three different temperatures (32, 34.5 and 37.5°C). In order to quantify the reduction in heat consumption with lower operational temperatures the change in heat balance for a full-scale WWTP in Uppsala was calculated. A major part of the operational cost is dewatering of sludge and it is therefore important that it does not deteriorate with a lower temperature. The effect on the dewaterability at different temperatures was examined by a filterability test measuring CST (capillary suction time). The results from the study showed no significant difference in methane yield between 37.5°C and 34.5°C. The methane yield at 32°C was 11 % lower compared to 37.5°C but the degradation kinetic was not affected by a temperature change. The reduction in heat consumption was 14 % when the temperature was reduced to 34.5°C and 27 % when it was reduced to 32°C. The filterability test did not show a deterioration with lower temperatures. The study showed that it is possible to reduce the operational temperature for anaerobic digestion at the WWTP in Uppsala in order to reduce the energy consumption. To confirm these results a continuously experiment should be done, but this study shows that it is possible to get a successful degradation in a lower mesophilic temperature. This leads the way for further investigations within the mesophilic range and could lead to optimizing anaerobic digestion and the opportunity to get an energy efficient production of biogas.
Jakobsson, Åhs Ann-Charlotte. "Rötning av matavfall – en studie av metanutbytet hos matavfall förbehandlat med skruvkrossteknik samt vid samrötning med bioslam från pappersbruk." Thesis, Karlstads universitet, Institutionen för ingenjörs- och kemivetenskaper, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-32816.
Full textNilsson, Erik. "Anaerobic digestion trials with HTC process water." Thesis, Uppsala universitet, Institutionen för geovetenskaper, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-325289.
Full textBorgström, Ylva. "Pretreatment technologies to increase the methane yields by anaerobic digestion in relation to cost efficiency of substrate transportation." Thesis, Linköpings universitet, Tema vatten i natur och samhälle, 2011. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-69755.
Full textThe world needs new energy sources that are durable for long time and which not affect the environment negatively. Biogas fulfills those demands. The biogas process is however not completely optimized. Several of the substrates used today for biogas production are slowly degraded and only partly digested in the process. Other substrates consist of unnecessarily much water which makes transportation costly. To optimize the process and make the biogas process more profitable, several pretreatment techniques are evaluated by direction of E.ON in this report: steam explosion, extrusion, lime treatment and dewatering. The hope is that one of those could increase the profitability and hopefully also enable substrates that not are working today like feathers and straw. To compare and evaluate the different pretreatment batch digester, experiments were carried out during 31-44 days for untreated and pretreated substrates. Most pretreated substrates were faster degraded than untreated and some also gave a higher methane yield. Chicken waste feathers and wheat straw, which had low methane yields untreated, were affected most by pretreatment. Steam exploded feathers gave after 44 days of digestion 141% higher methane yield and extruded straw gave 22% higher methane yield than untreated samples of the same substrate. A reference plant with a substrate mixture of 12500 tonnes of maize silage and 11500 tons of horsemanure annually was used to make economical calculations. Additionally, chicken waste feathers waste could be included. Obtainable for the reference plant were also chicken waste feathers. Steam explosion appeared to be too expensive for a plant in the size of the reference plant. Its large capacity could probably make it profitable for a much larger biogas plant running on a lot of hard digestible substrates. An extruder could be a profitable investment for the reference plant if the plant gets horse manure with straw as bedding material. To just use the extruder to pretreat maize silage could not make the investment profitable. Dewatering of manure gave significantly lower methane yield per dry weight but significantly higher methane yield per wet weight. The increase in methane yield per wet weight makes the substrate better for transportation. The dewatering equipment from Splitvision tried in this study had too high operational costs and was too expensive to make dewatering particularly profitable. Only when the farm was situated farther away than 40km from the biogas plant it was cheaper to dewater the manure before transport than to transport the manure without any pretreatment. Other dewatering equipments evaluated in this study had much lower operational costs and among those an equipment that makes dewatering profitable might therefore be found. The world needs new energy sources that are durable for long time and which not affect the environment negatively. Biogas fulfills those demands. The biogas process is however not completely optimized. Several of the substrates used today for biogas production are slowly degraded and only partly digested in the process. Other substrates consist of unnecessarily much water which makes transportation costly. To optimize the process and make the biogas process more profitable, several pretreatment techniques are evaluated by direction of E.ON in this report: steam explosion, extrusion, lime treatment and dewatering. The hope is that one of those could increase the profitability and hopefully also enable substrates that not are working today like feathers and straw. To compare and evaluate the different pretreatment batch digester, experiments were carried out during 31-44 days for untreated and pretreated substrates. Most pretreated substrates were faster degraded than untreated and some also gave a higher methane yield. Chicken waste feathers and wheat straw, which had low methane yields untreated, were affected most by pretreatment. Steam exploded feathers gave after 44 days of digestion 141% higher methane yield and extruded straw gave 22% higher methane yield than untreated samples of the same substrate. A reference plant with a substrate mixture of 12500 tonnes of maize silage and 11500 tons of horsemanure annually was used to make economical calculations. Additionally, chicken waste feathers waste could be included. Obtainable for the reference plant were also chicken waste feathers. Steam explosion appeared to be too expensive for a plant in the size of the reference plant. Its large capacity could probably make it profitable for a much larger biogas plant running on a lot of hard digestible substrates. An extruder could be a profitable investment for the reference plant if the plant gets horse manure with straw as bedding material. To just use the extruder to pretreat maize silage could not make the investment profitable. Dewatering of manure gave significantly lower methane yield per dry weight but significantly higher methane yield per wet weight. The increase in methane yield per wet weight makes the substrate better for transportation. The dewatering equipment from Splitvision tried in this study had too high operational costs and was too expensive to make dewatering particularly profitable. Only when the farm was situated farther away than 40km from the biogas plant it was cheaper to dewater the manure before transport than to transport the manure without any pretreatment. Other dewatering equipments evaluated in this study had much lower operational costs and among those an equipment that makes dewatering profitable might therefore be found.
Lundwall, Ted. "Thermophilic anaerobic digestion of municipal wastewater sludges: A pilot scale evaluation with model assistance." Thesis, KTH, Kemiteknik, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-301609.
Full textAs cities grow, the load on the municipal wastewater treatment plants increases. The Käppala Association predicts that the number of population equivalents connected to the Käppala Wastewater Treatment Plant will increase by over 160 % in the coming three decades. An increased load leads to a larger amount of sludge that must be treated. This is done today with stabilization through mesophilic anaerobic digestion and subsequent dewatering and hygienization. At the same time, there is a need for sustainable energy sources in society, to which wastewater treatment plants contribute by providing energy-rich biogas as a by-product from the anaerobic digestion. The degree of digestion is dependent on the retention time of the sludge in the digester and the retention time will become shorter as the load increases. Thermophilic anaerobic digestion has been identified as a possible alternative to the investment of additional digester volume as the method has been reported to provide a faster stabilization and thus an equivalent result with a shorter retention time. In addition, there are indications that thermophilic anaerobic digestion is able to produce a larger amount of biogas per unit of organic material in comparison with mesophilic anaerobic digestion. To evaluate whether the Käppala Association can enjoy these benefits, a thermophilic anaerobic digestion experiment has been conducted on a pilot scale. The pilot plant included a 5 m³ digester which was fed semi-continuously with 65 mass% primary sludge and 35 mass% waste activated sludge. The experiment began with a temperature transition from a mesophilic inoculum to thermophilic conditions, followed by allowing the process to acclimatize. The process was operated thereafter for three retention times with a length of 18 days each. All process parameters were derived as far as possible from the full-scale sludge treatment at Käppala Wastewater Treatment Plant. The experimental results were compared with simulation results based on the mathematical model Anaerobic Digestion Model No. 1. The temperature transition and acclimatization was performed successfully. At reference load, the degree of digestion was 54.4 % and specific methane production was 0.221 Nm3 CH4/kgVS, which was not enough to overcome the mesophilic full-scale process. Indications pointed towards proteins being more easily digested in a thermophilic process. Furthermore, deteriorating process stability and dewaterability of the digestate was observed.
Cardell, Lina. "Anaerobic digestion of pre-treated biological sludge from pulp and paper industry using heat, alkali and electroporation." Thesis, Linköpings universitet, Tema vatten i natur och samhälle, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-57496.
Full textBioslam, som bildas vid vattenreningen på pappers- och massabruk, utgör en kostnad attomhänderta på grund av avvattningssvårigheter. Kvittblivning sker oftast genom förbränningeller användning som jordförbättringsmedel. Genom rötning kan slammet bli merlättavvattnat och tack vare att det bildas biogas minskar slamvolymen samtidigt som energikan utvinnas från metanet. Produktionen av biogas kan ökas genom att förbehandla slammetinnan rötning, vilket skulle innebära ekonomiska fördelar. Denna studie har undersökt effekten av förbehandling för elva bioslam från sex svenskapappers- och massabruk, valda att representera olika typer och storlekar på svenska bruk.Behandlingen gjordes med alkali (NaOH, pH12), värme (80˚C, 1 h) och elektroporering(2000 pulser, 10 kV/cm). Effekten av förbehandling på initial metanproduktionshastighet ochmetanpotential undersöktes med hjälp av satsvis utrötning (batch) av alla slam. Enkombination av två slam från samma burk utvärderades i ett semi-kontinuerligt rötningsförsökefter förbehandling med värme och alkali. Resultatet från utrötningsförsöket visade att den alkaliska förbehandlingen hade störst positivinverkan på metanproduktionen. Värmebehandlingen presterade näst bäst, medanelektroporeringen visade sig ha liten eller ingen effekt. Generellt sett ökade den initialametanproduktionshastigheten till följd av förbehandling, medan metanpotentialen förblevoförändrad. Värmebehandling gav ingen effekt på biogasproduktionen i det semikontinuerligarötningsförsöket jämfört med kontroll, medan alkalisk förbehandling inhiberadebiogasproduktionen och orsakade höga koncentrationer av ackumulerat acetat. Det kunde inteavgöras huruvida det var natrium- eller hydroxidjoner, som orsakade inhiberingen. För attkunna utvärdera möjligheten att röta slam, som förbehandlats med NaOH, rekommenderasvidare analys av dess påverkan på flockstruktur, toxicitet och biotillgänglighet.
Hadin, Åsa. "Anaerobic digestion of horse manure : renewable energy and plant nutrients in a systems perspective." Licentiate thesis, Högskolan i Gävle, Miljöteknik, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:hig:diva-22716.
Full textVid hästhållning alstras hästgödsel som kan användas som växtnäring eller anses vara ett avfall. Hästgödsel utgör både en växtnäringsresurs och en energi resurs. Dessutom styr uppsatta energimål mot att förnybar energi ska ersätta fossila bränslen. Intresset för att öka resursutnyttjandet av hästgödsel ökar på grund av olika incitament för förnybara drivmedel, lagstiftning om gödselhantering och miljöpåverkan från dagens hantering av hästgödsel. I den här avhandlingen beskrivs hästgödselhantering i ett livscykelperspektiv genom att (1) identifiera olika faktorer vid hästhållningen som påverkar möjligheten att utvinna biogas ur hästgödsel och återföra näringen till jordbruksmark, (2) analysera faktorer i biogasprocessen som påverkar den specifika metanmängden och innehållet av växtnäring i gödseln och (3) jämföra olika gödselhanteringsmetoders miljöpåverkan. Metoderna i avhandlingen har varit litteraturstudier, systematisk kombination av teori och empiri samt simulering. Resultaten visar att utfodringen, om och hur hästarna hålls inomhus och utomhus och hur hästgödsel lagras påverkar mängden hästgödsel och dess egenskaper, och därmed också hur den fungerar som ett biogassubstrat. Transporterna har betydelse för hur mycket gödsel som kan samlas in och spridas, medan gödselspridningen påverkar näringsförluster och närings återföring. Resultaten från simuleringarna indikerar högst metanutbyte och bäst energibalans från papper som strömaterial, medan halm och torv gav högre växtnäringsinnehåll i biogödseln. De högsta resultaten på specifik metanmängd nåddes med låg andel strö, vilket också var positivt för växtnäringsinnehållet vid scenarierna med spån och papper. Samtidigt indikerar resultaten att en hög andel strömaterial ger den bästa energibalansen. Miljöpåverkansbedömningen indikerar att potentialen för klimatpåverkan minskar om hästgödsel behandlas i en biogasprocess jämfört med förbränning eller kompostering.
Duong, Sutina. "Systematic Assessment of Straw as Potential Biogas Substrate in Co-digestion with Manure." Thesis, Linköpings universitet, Industriell miljöteknik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-111438.
Full textDetta examensarbete har utförts i samarbete med Biogas Research Center (BRC) och företaget Biogas i Vadstena. Målet med examensarbetet var att systematiskt utvärdera nya substrat för biogasproduktion. Specifikt för det här fallet var att undersöka potentialen för halm i samrötning med gödsel och flyt från svin, höns och nöt. Halm är intressant att utvärdera då det tillhör andra generationens biomassa och finns tillgängligt i stor mängd. Även rötning av gödsel är givande då den spontana metanemissionen uteblir och det ger en bättre gödselhantering. Det har satts upp mål inom såväl EU som i Sverige att mer förnybart bränsle bör produceras för att minska växthusgasutsläppen från fossila bränslen. Metodiken som använts har framarbetats av BRC. Det innebär att substrat granskas utifrån ett flertal nyckelområden, såsom beskrivning och mängd biomassa, gasutbyte, synergieffekter, teknik, ekonomi, miljöpåverkan och energisystem, konkurrerande intressen och institutionella faktorer. Dessa har utvärderats genom litteraturstudier och studie av fallet Biogas i Vadstena. Utifrån resultatet görs en övergripande bedömning av substratet. Resultatet visar att halm inte är lämpligt att röta enskilt på grund av högt TS-värde, högt kolinnehåll och att den är näringsfattig. Halm består även till stor del av lignocellosa-strukturer som är svåra att bryta ned, i synnerhet lignin. Mekaniska, termiska, kemiska och bioglogiska förbehandlingar kan öka tillgängligheten och nedbrytbarheten av halm. Det kan även öka metanpotentialen i vissa fall. Däremot fungerar halm bra som ett komplement i samrötning med gödsel som är ett kväverikt substrat. Det finns teknik för rötning av halm för hela biogasprocessen, från transport, förbehandling och rötning till uppgradering. Dock finns utrymme för tekniken att utvecklas ytterligare. De ekonomiska beräkningarna visar att det är lönsamt att använda halm tillsammans med gödsel i en jordbruksbaserad biogasanläggning för fordonsgasproduktion. Vidare visar beräkningar för energisystemet att biogasproduktion är energieffektiv med energi input/output-kvot på 18-23%. Förutom fordonsgas produceras även biogödsel som är ett miljövänligt alternativ till konstgjord gödsel. Sammanfattningsvis, det är möjligt att producera biogas av halm tillsammans med gödsel och det är fördelaktigt ur en såväl miljömässigt som ekonomiskt perspektiv.
Gillgren, Maria. "Inom vilka områden behövs framtida biogassatsningar? : Future support to biogas production in Sweden." Thesis, Uppsala University, Department of Earth Sciences, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-126773.
Full textEnergimyndigheten har från Regeringen blivit tilldelad 100 miljoner kronor att fördela som investeringsstöd för att främja en effektiv och utökad produktion, distribution samt användning av förnybara gaser såsom biogas. Myndigheten har samtidigt fått i uppdrag att utveckla en sektorsövergripande biogasstrategi och föreslå åtgärder som på kort och lång sikt kan bidra till ökad användning av biogas. Denna strategi ska också tjäna som ett underlag för fördelning av olika former av stöd inom sektorn.
Syftet med detta examensarbete är att sammanställa information som kan bidra som underlag vid upprättandet av den sektorsövergripande biogasstrategin. Ett annat syfte är att bidra med underlag för Energimyndighetens bedömning av var ett investeringsstöd kan ge störst effekt för den fortsatta utvecklingen inom biogasområdet. Detta stöd avser den senaste, ovan nämnda, utlysning som Energimyndigheten gjort inom området. Examensrapporten innehåller bland annat en sammanställning av gjorda insatser inom forskningsområdet biogas de senaste åren, finansierat av framför allt Energimyndigheten, men även en inblick i vilka biogassatsningar som är gjorda av andra nationella aktörer. Ett antal personer från bland annat branschorganisationer har intervjuats för att ta del av deras syn på den framtida biogasmarknaden, vilka satsningar som bör göras och vilka hinder som har störst inverkan. Organisationerna är valda utifrån kriteriet att de ska representera olika delar av biogasbranschen och att olika synvinklar därigenom ska framkomma. Rapporten innehåller slutsatser som dragits av tidigare biogassatsningar hos Energimyndigheten och identifiering av biogasområden där det föreligger stort behov av framtida satsningar för utökad produktion, distribution och användning.
Ett område som i detta examensarbete har identifierats ha stort behov av framtida biogassatsningar är bland annat framtagande av alternativa rötningssubstrat, eftersom mängden tillgängligt substrat nuläget inte är tillräcklig. Detta utgör idag en begränsning för biogasproduktionen. Det bör även satsas mer på förbehandling av substrat innan rötning, vilket ökar gasproduktionen och förbättrar substratutnyttjandet i större utsträckning. Mer satsningar behövs också kring hur biogasprocessens slutprodukt, rötresten, kan bli en mer attraktiv produkt så att återcirkulering av växtnäring kan ske i större grad genom rötrestspridning på åkermark. Detta är av stor vikt eftersom en ökad volym rötningssubstrat ger upphov till större mängd rötrester som ska hanteras. Andra områden som är i behov av framtida stöd är utveckling av befintliga anläggningar för att öka och effektivisera produktionen. För att optimera processerna bör framför allt mer medel satsas på kunskapsuppbyggnad och spridning av den vetenskap som finns tillgänglig. Att länka samman universitet, högskolor och naturbruksgymnasium med anläggningar i drift kan vara det mest effektiva sättet att nå ut med relevant information och kunskap. Ur ett samhällsekonomiskt perspektiv bör mer medel läggas på att öka gödselrötning då detta minskar metanläckage.
Swedish Energy Agency has been allocated SEK 100 million from the government to distribute as investment grant to promote efficient and expanded production, distribution and use of renewable gases such as biogas. The Agency has also been given the task to develop a multidisciplinary strategy for biogas and propose measures which can contribute to increased use of biogas in the short and long term. This strategy will also serve as a basis for the allocation of various forms of support in the biogas sector.
The purpose of this study is to compile information which can be used as input for the establishment of the multidisciplinary strategy for biogas. Another purpose is to provide information to support the Swedish Energy Agency in the assessment of which areas an investment grant will have the greatest impact for the future development of biogas. This grant refers to the latest call of Swedish Energy Agency in the sector. This report includes a summary of what areas grants have been given for research of biogas in recent years, mainly financed by the Swedish Energy Agency, but also an insight into efforts made by other national operators. A number of people from professional biogas organizations have been interviewed to share their views on the future biogas market. Which efforts should be made and the main obstacles to be overcome are other questions discussed. The report contains conclusions from the experience of previous support from the Swedish Energy Agency as well as identification of areas in which there is great need for future efforts in order to expand the production, distribution and use of biogas.
Some areas which have been identified in this thesis for need of future efforts in the biogas sector is for example the development of alternative substrates for anaerobic digestion, because the amount of available substrate is at present not sufficient. This is currently a limitation for the biogas production. There is also a need to further develop the pre-treatment of the substrate before digestion, in order to increase the gas production and improve substrate utilization to a greater extent. More focus are also needed on how the end product from the biogas process, the digestion residues, can become a more attractive product to the recycling of plant nutrients by use as a bio fertilizer on farmland. This is of great importance because larger volume of digestion will result in greater volume of digestion residues to be managed. Other areas in need of future investments are the development of existing facilities to increase and optimize the production. In order to optimize the production processes, more resources should be devoted to capacity building and dissemination of the available knowledge. Linking universities and colleges together with operating biogas plants could be the most effective way to reach out with relevant information and knowledge. From a socioeconomic perspective more resources should be spent on increasing the volume of manure digestion then it is today, which also will result in reduced methane leaks.
Meyer, Ruth. "Matavfallsinsamling - vad tycker Danderydsborna?" Thesis, KTH, Industriell ekologi, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-58629.
Full textThe municipality of Danderyd is one of the smallest municipalities in Sweden in terms of area it covers. There are about 30 000 inhabitants distributed on 12 710 households. Each inhabitant in Danderyd generates about 220 kg of household waste per year. An analysis of the content of the waste bags was performed in 2009. The conclusion was that the household waste contains about 50 % of food waste and almost 25 % of packaging waste that are included in the recycle scheme for packaging in Sweden; hence there is plenty of material that potentially could be recycled in each waste bag in Danderyd. The waste management plan of the municipality of Danderyd contains different goals that should be fulfilled by the year 2020, there are also some sub targets that should be met by the years 2012 and 2016. One of the sub targets is that the recycling of recyclable material should increase by 40 % compared to the level 2009, including biological treatment of organic waste. One possible measure to reach this sub target is to implement collection of food waste from the households. In order to introduce a possible collection of organic waste, it is important to investigate the attitude towards such a scheme of the inhabitants in Danderyd. Therefore, this study has been performed as a master thesis on the request of the city municipal of the municipality of Danderyd. A questionnaire was distributed to 1000 households in Danderyd, 600 to single family house and 400 to households in multiple dwellings. A literature review was also performed in order to find out if anaerobic digestion is a suitable method to treat the collected organic waste in Danderyd in an economical and environmental perspective. Furthermore, different collection systems for organic waste, differentiated environmental waste collection fees, experience from municipalities that already have a collection of organic waste and factors for successful recycling of recyclable materials were also studied in the literature review. There was no unequivocal result that fermentation of organic waste is the most suitable treatment method of food waste. There are advantages such as; the closure of the material loop, nutrients are recycled back to soil, production of biogas that is a renewable fuel and could replace fossil fuel, biogas is also a scare commodity in the area of Stockholm and the separation and recycling of organic waste could increase the interest of environmental issues and also increase the recycling of other recyclable packaging materials. The questionnaire was returned by 60 % of the households but only 39 % of the questionnaire from single family households and 30 % of the households in multiple dwellings were completed correctly. Furthermore, the result showed that there was a large interest for an introduction of collection of organic waste, almost 70 % of the household in villas and about 60 % of households in multiple dwellings said that they were very interested or interested in participating in a collection scheme of organic waste. Of the household 90 % answered that they were prepared to make a large effort or some effort to separate their food waste if an introduction of a recycling scheme of food waste was made. There was also a large interest in environmental issues and 60 % of the households answered that they thought their life style affected the environment and that they were prepared to change their life style to the benefit of the environment. Regarding the recycling of other recyclable materials, the respondents answered that the largest problem was the availability of recycling stations and that collection of packaging waste at the property was requested as the largest motivation measure that the municipality could offer in order to increase recycling. Based on the condition in Danderyd, the existing organization of waste management and in order to reach the environmental sub targets that are defined in the waste management plan, is an introduction of a collection scheme of food waste for anaerobic digestion suggested. The organic waste should be gathered in paper bags and placed in a separate ventilated garbage bin for single family households. The conditions of the refuse chamber differ for multiple dwellings; therefore the possibility to separate organic waste should be organized for each property. The municipality should establish an open communication with each estate manager in order to facilitate the affiliation to the food waste collection scheme. Furthermore, the affiliation to the food waste collection scheme should be optional in order to achieve good quality of the food waste. To motivate the inhabitants to join the collection scheme, a differentiated environmental waste fee is suggested. The municipality should also provide suitable equipment for the collection of food waste.