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Journal articles on the topic 'Ancient Pb Slags'

Author: Grafiati
Published: 2 June 2025
Last updated: 31 July 2025

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1

Zubkova, N. V., N. V. Chukanov, I. V. Pekov, et al. "New data on fiedlerite-1A from ancient slags of Lavrion, Greece: crystal structure and H-bonding." Доклады Академии наук 486, no. 1 (2019): 83–87. http://dx.doi.org/10.31857/s0869-5652486183-87.

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The crystal structure (R = 0.0750) of fiedlerite-1A Pb3Cl4F(OH) H2O from ancient slags of Lavrion (Greece) was studied on a single crystal. The mineral is triclinic, a = 8.5741(7), b = 8.0480(5), с = 7.2695(4) Å, (a = 90.087(5), (b = 102.126(6), (g = 103.424(6)) V = 476.37(6) Å3, Z = 2. Pb2+ cations centre bicapped trigonal prisms Pb(1)F(H2O)Cl6, Pb(2)(OH)2FCl5 and Pb(3)(OH)F2Cl5. Additional Pb′site with 10% occupancy was revealed in the structure. There are two basic structure fragments alternating along the a axis: (100) layers formed by Pb(2)- and Pb(3)-centred polyhedra and elongated along
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2

Fernández-Caliani, Juan Carlos, and Juan Aurelio Pérez-Macías. "Tracing Soil Contamination from Pre-Roman Slags at the Monte Romero Archaeological Site, Southwest Spain." Soil Systems 8, no. 3 (2024): 78. http://dx.doi.org/10.3390/soilsystems8030078.

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Soil serves as a repository of human history, preserving artifacts within its horizons. However, the presence of chemically reactive remnants, such as ancient slags, can significantly impact the surrounding soil environment. This paper addresses this scarcely explored issue by focusing on soil contamination arising from pre-Roman slag deposits at the Monte Romero archaeological site in southwest Spain, dating back to the Tartessian period (c. 7th century BC). Through the high-resolution microscopy examination of slag wastes and the trace element analysis of soil samples by ICP-OES, this study
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3

Siidra, O. I., N. V. Chukanov, I. V. Pekov, et al. "Pb2(AsO2OH)Cl2, a new phase from the Lavrion ancient slags, Greece: occurrence and characterization." Mineralogical Magazine 76, no. 3 (2012): 597–602. http://dx.doi.org/10.1180/minmag.2012.076.3.10.

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AbstractTransparent prismatic crystals of Pb2(AsO2OH)Cl2 were collected in black metallurgical slag on the coast in the Punta Zeza area, 3 km south of the town of Lavrion, Greece. Analyses by energy-dispersive X-ray spectrometry (EDS) provided the following chemical composition: PbO 73.04, As2O3 15.97, Cl 11.42, O=Cl –2.58, total 97.85 wt.%. The empirical formula calculated on the basis of As = 1 is HxPb2.03(AsO3)1.00Cl1.995 (x = 0.96). The infrared spectrum of Pb2(AsO2OH)Cl2 has characteristic AsO33– bands at 707 and 594 cm–1, O–H stretching vibrations at 3310 and 2900 cm–1 and a band at 1107
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4

Triantafyllidis, Stavros Savvas, Georgios Anastasakis, Anastasios Papanastasiou, et al. "Provenance of Coastal and Seabed Sediments Relative to Mining and Processing Wastes: The Case of Lavrion, Attiki Peninsula, Greece." Minerals 14, no. 1 (2023): 33. http://dx.doi.org/10.3390/min14010033.

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A detailed textural, mineralogical, and geochemical investigation of beach sands and seabed sediments from Thorikos and Oxygono bays of the eastern coast of Lavrion is performed, with the objective the provenance of the ore types exploited, the processing and beneficiation types employed, and the respective exploitation periods. The Oxygono Bay beach and seabed sands are highly heterogeneous, predominated by lithic clasts originating from surrounding lithologies. Examination of the fine-grained fraction from the seabed core revealed that only the upper 50 cm was affected by recent and ancient
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5

Siidra, Oleg I., Diana O. Nekrasova, Nikita V. Chukanov, et al. "The hydrocerussite-related phase, NaPb5(CO3)4(OH)3, from the ancient slags of Lavrion, Greece." Mineralogical Magazine 82, no. 4 (2018): 809–19. http://dx.doi.org/10.1180/minmag.2017.081.058.

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ABSTRACTThe hydrocerussite-related phase, NaPb5(CO3)4(OH)3, has been found as colourless lamellar crystals in cavities within a pebble of the ancient marine slag collected in the Pacha Limani area of the Lavrion mining district, Attiki, Greece. This phase of anthropogenic origin was characterized by electron microprobe, infrared spectroscopy, powder and single-crystal X-ray diffraction. The unique crystal structure (P63/mmc,a= 5.2533(11),c= 29.425(6) Å,V= 703.3(3) Å3andR1= 0.047) is based upon structurally and chemically different electroneutral blocks. Each of the blocks can be split into sep
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6

Tzankova, Nikoleta. "Trace elements of unbound residual copper in ancient metallurgical slags from the archaeological open-pit mine in the Propadnala Voda deposit, SЕ Bulgaria". Review of the Bulgarian Geological Society 85, № 3 (2024): 333–36. https://doi.org/10.52215/rev.bgs.2024.85.3.333.

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This study presents, for the first time, trace element data obtained through LA-ICP-MS for unbound residual copper found as unextracted drops (or prills) in metallurgical slags from an open-pit mine located in the Propadnala Voda deposit within the Rossen Ore Field in the Burgas ore district. The analysis reveals the following chemical elements in amounts above the sensitivity limits of the equipment: Sc – 307 ppm, Cr – 52633 ppm, Ni – 670 ppm, Ag – 418 ppm, La – 15 ppm, Ce – 33 ppm, Ta – 17 ppm, Pb – 602 ppm, and Bi – 109 ppm. Since the ore source for the copper production, from which these s
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7

Peng, Xi, Bin Quan Jiao, and Dong Wei Li. "Heavy Metal’s Potential Harm for Environment of Ancient Pyrometallurgical Slag." Advanced Materials Research 160-162 (November 2010): 130–34. http://dx.doi.org/10.4028/www.scientific.net/amr.160-162.130.

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The total content of heavy metal in solid waster is usually used to forecast heavy metal’s potential harm for environment.This work was to study the potential harm for environment of ancient pyrometallurgical slag.The heavy metal content in ancient pyrometallurgical slag is high and the average content of heavy metal (zinc plus plumbum) is up to 6.97%.But the leachable quantity of Zn,Pb,Cr and Cd are all very low.It shows that the total content of heavy metal could not represent the harm for environment. Meanwhile,leaching behavior of heavy metal in pyrometallurgical slag was discussed through
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8

LERMİ, Abdurrahman, and Emmanuel Daanoba SUNKARI. "Geochemistry, risk assessment, and Pb isotopic evidence for sources of heavy metals in stream sediments around the Ulukışla Basin, Niğde, southern Turkey." TURKISH JOURNAL OF EARTH SCIENCES 29, no. 7 (2020): 1167–88. http://dx.doi.org/10.3906/yer-2001-9.

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Concentrations of selected elements (Al, Fe, Mn, Mo, As, Cd, Cu, Cr, Ni, Co, Pb, Sb, and Zn) and Pb isotope ratios were determined in 53 sediments from Alihoca, Gümüş, Horoz, and Çakıt streams around the south-central Taurides (Ulukışla Basin), Niğde, which is a known mining province in Turkey. Several pollution and risk assessment indices were used to assess possible heavy metal pollution in the stream sediments and the associated potential ecological risks. Concentrations of As, Cd, Cu, Cr, Ni, Co, Pb, Sb, and Zn were elevated in the streams located near ancient mines, active mines, and slag
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9

Chuvashova, I. S., S. V. Rasskazov, and E. V. Saranina. "207Pb–206Pb age of sources of Late Cenozoic volcanic rocks of the crust-mantle transition in relation to the age of ophiolites and ancient blocks exposed on the surface of the crust: transect Kitoi–Baydrag of the Baikal-Mongolian region." Geology and Environment 2, no. 2 (2022): 61–90. http://dx.doi.org/10.26516/2541-9641.2022.2.61.

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The results of determinations of Pb isotope ratios in Late Cenozoic volcanic rocks of the southwestern part of the Baikal rift system along the Kitoi-Baidrag transect are presented. The obtained 207Pb–206Pb estimates of the restite material incubation time in the springs are in good agreement with the Precambrian dating of ensembles of ancient continental blocks and ophiolite belts exposed on the Earth's surface. The sources are distinguished along the transect: the ancient Gargan block of the Tuva-Mongolian microcontinent (massif) with the Hadean protolith and Archean-Neoproterozoic events; K
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10

Shui, Guo Hong, and Dong Wei Li. "Acute Toxicity Test on Old Smelting Slag." Advanced Materials Research 160-162 (November 2010): 1564–68. http://dx.doi.org/10.4028/www.scientific.net/amr.160-162.1564.

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The total amount of heavy metal in Ming and Qing dynasties smelted residue was analyzed. Also leaching solution’s acute toxicity of heavy metal in waste residue was discussed.The results showed that the residual quantity of heavy metal(zinc and plumbum) in residue was up to 6.97%. After several hundred years of lixiviation by rainwater, heavy metal (zinc and plumbum) which had released to circumstance was more than 1.71%.Heavy metal in ancient leaching has declined and Residue in Zn is only a very small part of the leaching, Pb leaching below the detection limit ,Cr, and Cd there was leachingo
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11

Wang, Gongwen, Shouting Zhang, Changhai Yan, et al. "Resource-environment joint forecasting using big data mining and 3D/4D modeling in Luanchuan mining district, China." Earth sciences and subsoil use 44, no. 3 (2021): 219–42. http://dx.doi.org/10.21285/2686-9993-2021-44-3-219-242.

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The Fourth generation industrial age and 5G + intelligent communication in the "Fourth Paradigm of Science" in the 21st century provide a new opportunity for research on the relationship between mining development and environmental protection. This paper is based on the theory of metallogenic geodynamics background, metallogenic process and quantitative evaluation and chooses the Luanchuan district as a case study, using deep-level artificial intelligence mining and three/four-dimensional (3D/4D) multi-disciplinary, multi-parameter and multi-scale modeling technology platform of geoscience big
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12

Tsaimou, C., P.E. Tsakiridis, and P. Oustadakis. "ANALYTICAL AND TECHNOLOGICAL EVALUATION OF ANCIENT LEAD SLAGS FROM LAVRION, ATTIKA, GREECE." April 4, 2015. https://doi.org/10.5281/zenodo.16605.

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The present research reports the chemical and mineralogical results of various archaeometallurgical lead slags from the Ari site at Lavrion, one of the largest ancient sites of Pb–Ag metallurgical activities in Greece, excavated by the School of Mining and Metallurgical Engineering of Greece, under the directorship of Prof. C. Tsaimou. Dating of the metallurgical slags was carried out using radiocarbon measurements, indicating the earliest phase of the Roman Empire. Chemical analysis, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscop
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13

Zubkova, Natalia V., Nikita V. Chukanov, Igor V. Pekov, et al. "The crystal structure of the compound Pb6Cu+(AsO3)2Cl7 discovered in the ancient slags of Lavrion, Greece." Zeitschrift für Kristallographie - Crystalline Materials 230, no. 3 (2015). http://dx.doi.org/10.1515/zkri-2014-1779.

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AbstractLead and copper(I) chloride arsenite was found in the ancient metallurgic slag from the Vrissaki area, Lavrion district, Attikí Peninsula, Greece. Its chemical composition corresponds to the idealized formula Pb
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14

Singtuen, Vimoltip, Burapha Phajuy, Nucharee Pongsaisri, and Santi Pailoplee. "GEORESOURCE DISTRIBUTION IMPACTS THE PROSPERITY OF THE SUKHOTHAI KINGDOM AND ANTHROPOLOGICAL CIVILIZATION IN THAILAND." May 23, 2024. https://doi.org/10.5281/zenodo.11250791.

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The Sukhothai Kingdom, which emerged in the Yom River valley around the 13th-14th century AD, functioned as a trading post between the Gulf of Martaban and the central Mekong River basin and is now recognized as a UNESCO World Heritage site. The reasons behind the establishment of Sukhothai remain unclear, with limited research on the topic. This study explores significant geological resources within Sukhothai and its surrounding areas using field surveys, macroscopic analysis, geochemical analyses via portable X-ray fluores-cence (pXRF), and Least Cost Path (LCP) analysis to hypothesize the f
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15

Νεραντζής, Νεραντζής, та Στρατής Παπαδόπουλος. "Η μεταλλουργία της Πιστύρου και της περιοχής της κατά τους ιστορικούς χρόνους: η έρευνα και τα πρώτα πορίσματα". EULIMENE, 31 грудня 2019, 1–24. http://dx.doi.org/10.12681/eul.32835.

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The metal production at Pistyros and the surrounding area in the historical period: Reserach and first results. This article focuses on metal production at the Thasian colony of Pistyros in Aegean Thrace during the Classical/Hellenistic periods. Evidence for mining activity in the Lekani Mountains, that was mentioned by ancient authors is also under examination. Mining shafts and galleries, mineral processing areas and slag heaps represent direct evidence for the organization and running of large-scale metal production in this region. With the foundation of Thasian colonies and emporia in the
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