Academic literature on the topic 'Aniline'

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Journal articles on the topic "Aniline"

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Kumbhare, Nayan, and Varsha Dhurvey. "Studies of Aniline and it’s Derivatives on Various Organ Systems: A Mini Review." International Journal of Scientific Research in Biological Sciences 12, no. 2 (2025): 21–31. https://doi.org/10.26438/ijsrbs.v12i2.672.

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Certain chemical pollutants in the environment can change a variety of biological processes. Anilines are widely used in the manufacturing of plants, colours, medications, pesticides, and herbicides. This review aims to highlight the destructive, dangerous and altering effects of aniline on various organisms. We believe that this study will provide helpful information regarding aniline's toxicological research, which will help in the formulation of acceptable guidelines for aniline usage.
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Lewis, Frederick D., Jill M. Wagner-Brennan, and Alan M. Miller. "Article." Canadian Journal of Chemistry 77, no. 5-6 (1999): 595–604. http://dx.doi.org/10.1139/v98-229.

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The photophysical and photochemical behavior of several aniline spacer - styrene molecules in which the spacer is a short polymethylene chain has been investigated. Long wavelength excitation selectively excites the aniline chromophore which undergoes intramolecular quenching by the styrene to yield an intramolecular exciplex. Exciplex fluorescence is observed for both of the tertiary anilines investigated and for one of the three secondary anilines. More rapid exciplex formation in nonpolar vs. polar solvents is attributed to the necessity of desolvating the polar aniline singlet in polar sol
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Gorokhov, Valery Yu, and Tatiana V. Makhova. "Para-(aza,thio)xanthenylated anilines in the pereaminination reaction." Butlerov Communications 60, no. 10 (2019): 32–35. http://dx.doi.org/10.37952/roi-jbc-01/19-60-10-32.

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It is known that the biochemical enzymatic reaction of the reversible transfer of an amino group from an amino-acid to a keto-acid is called a transamination reaction. However, the transamination reaction is applicable not only for biochemical enzymatic reactions, but is also often used in organic synthesis to produce aromatic azomethines. As objects of study in the transamination reaction, we selected substituted N-benzylidenanilines (imines, Schiff bases) and anilines, containing a biologically active heterocyclic fragment in the para-position of the aniline ring. We have shown the feasibili
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Shteinberg, Leon. "INFLUENCE OF SUBSTITUTES ON THE RATE OF THE REACTION OF ORTHOSUBSTITUTED BENZOIC ACIDS WTH ANILINE, CATALYZED BY POLYBUTOXYTITANATES." Ukrainian Chemistry Journal 87, no. 3 (2021): 18–40. http://dx.doi.org/10.33609/2708-129x.87.03.2021.18-40.

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The polybutoxytitanates catalysis of aniline acylation by orthosubstituted benzoic acids leads to the production of substituted benzanilides. Catalytic rate constants of the second order reaction (the first with respect to aniline and ortho-substituted benzoic acid; boiling ortho=xylene, 145°C) correlate well according to the Hammett and Bronsted equations with straight line segments with ρ=1.93 and α=0.66, in contrast to the reaction of aniline with meta- and parasubstituted benzoic acids and substituted anilines with benzoic acid. This dependence drops out 2=nitrobenzoic and 1=naphthoic acid
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Dada, Memane Archana. "Aim: Poly (Aniline Co- M- Nitro Aniline) Synthesis and Characterization Doped with Inorganic Acids." International Journal of Science and Social Science Research 1, no. 4 (2024): 161–64. https://doi.org/10.5281/zenodo.13367174.

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The current study describes the synthesis and characterization of poly (anilineco-metanitroaniline) using different mineral acids. Poly (aniline co-meta nitro aniline) was created at room temperature using the chemical oxidative polymerization of monomer aniline and co-monomer meta nitro aniline. As a dopant, hydrochloric acid, sulfuric acid, and perchloric acid were utilized, coupled with acrylic acid as a soft templet. Analytical techniques such as FTIR, UV- DRS, and XRD were used to analyze the synthesized Poly (aniline co - Meta nitro aniline). 
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Crampton, Michael R., Lynsey C. Rabbitt, and François Terrier. "Electrophilic aromatic substitution in substituted anilines; kinetics of the reaction with 4,6-dinitrobenzofuroxan." Canadian Journal of Chemistry 77, no. 5-6 (1999): 639–46. http://dx.doi.org/10.1139/v99-033.

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Kinetic results are reported for reaction of aniline and six of its N- and ring-substituted derivatives with 4,6-dinitrobenzofuroxan (DNBF) in water - dimethyl sulfoxide mixtures. In acidic solution σ-adducts, the result of electrophilic substitution in the anilines, are formed with bonding between a ring-carbon atom of the anilines and the 7-position of DNBF. Reaction normally occurs at the 4-position of the aniline unless this carries a substituent, when reaction occurs at the 2-position. A value of 2.0 for kH/kD, the kinetic isotope effect, indicates that in the reaction with aniline bond f
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Rasmussen, Seth C. "Early history of polyaniline -- revisited: Russian contributions of Fritzsche and Zinin." Bulletin for the History of Chemistry 44, no. 2 (2019): 123–33. https://doi.org/10.70359/bhc2019v044p123.

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Although the history of polyaniline has been traced back to the 1834 contributions of F. F. Runge in Germany, Carl Fritzsche independently discovered an organic base via the decomposition of indigo in 1840. Fritzsche named the base anilin after the Spanish name of indigo, a name which has been retained into the present. Following his isolation of aniline, Fritzsche went on to study its oxidation products, the results of which are consistent with our modern understanding of polyaniline species. Two years after Fritzsche's isolation of aniline, Nikolay Zinin reduced nitrobenzene to give a specie
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Wiberg, Kenneth B. "Substituent Effects on the Acidity of Weak Acids. 4. Anilinium Ions." Collection of Czechoslovak Chemical Communications 69, no. 12 (2004): 2183–92. http://dx.doi.org/10.1135/cccc20042183.

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The gas phase acidity of anilinium ions has been calculated at a number of theoretical levels from B3LYP/6-311++G** to MP2 and CCSD/6-311++G(2dp,2pd). The highest level calculations find anilinium ion and p-protonated aniline to have essentially the same energy, in agreement with experimental studies. They also give a proton affinity for aniline that is in very good agreement with the experimental value. The B3LYP and MP2 calculations are less successful, with B3LYP favoring p-protonation and MP2 favoring N-protonation for aniline. Despite this difficulty, the calculated effect of substituents
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Plater, M. John, and Andrea Raab. "Who Made Mauveine First: Runge, Fritsche, Beissenhirtz or Perkin?" Journal of Chemical Research 40, no. 12 (2016): 758–62. http://dx.doi.org/10.3184/174751916x14792902529027.

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The oxidation of aniline or a mixture of aniline with o-toluidine and p-toluidine following Runge's original method as carefully as possible, using chloride of lime [Ca(OCl)2], produces a coloured solution from which small amounts of mauveine were purified, isolated and analysed by LC-MS. The oxidation of aniline by the method of Fritsche and Beissenhirtz, using potassium dichromate and sulfuric acid, similar to W.H. Perkin's patented method, also gave small quantities of mauveine. The composition of the anilines are suggested depending upon their sources and Kekulé's comments on these early c
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Hurtova, Martina, Daniela Brdová, Bára Křížkovská, et al. "Nitrogen-Containing Flavonoids-Preparation and Biological Activity." Acs Omega 9, no. 32 (2024): 34938–50. https://doi.org/10.1021/acsomega.4c04627.

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In this work, we report the application of Buchwald-Hartwig amination for the preparation of new derivatives of quercetin and luteolin. Our investigation delves into the impact of aniline moiety on antioxidant, and anti-inflammatory activity, cytotoxicity, and the ability of flavonoids to modulate drug-resistance mechanisms in bacteria. The anti-inflammatory activity disappeared after the introduction of aniline into the flavonoids and the cytotoxicity remained low. Although the ability of quercetin and luteolin to modulate bacterial resistance to antibiotics has already been published, this i
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Dissertations / Theses on the topic "Aniline"

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Xie, Xiaoman [Verfasser]. "Anaerobic degradation of phenol and aniline by the sulfate-reducing bacterium Desulfatiglans anilini / Xiaoman Xie." Konstanz : KOPS Universität Konstanz, 2019. http://d-nb.info/123320338X/34.

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Seulen, Sarah [Verfasser]. "Massenspektrometrische Fragmentierungsreaktionen alkylsubstituierter Aniline / Sarah Seulen." Kiel : Universitätsbibliothek Kiel, 2018. http://d-nb.info/1159900515/34.

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Wallace, Emma Naomi Kathleen. "Poly(aniline) composites as bioelectrochemical sensors." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242655.

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Martinez-Bonastre, Alejandro. "Poly(aniline) microelectrodes for ascorbate measurements." Thesis, University of Southampton, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442858.

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Levent, Fulya. "Microwave Initiated Polymerization Of Trihalophenyleneoxide And Aniline." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12612941/index.pdf.

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The aim of the study is to synthesize poly(dibromophenyleneoxide) and polyaniline separately applying different microwave energies (90-900 watt), water amounts (1-5 ml) and time intervals (2-10 min) and investigate the effects of these parameters on the percent conversion of the polymers. The synthesis of poly(dibromophenyleneoxide) (P), radical ion polymer (RIP) and crosslinked polymer (CLP) were achieved by using tribromophenol (TBP) and Ca(OH)2 via microwave energy in a very short time interval. P and RIP were characterized by ATR-FTIR, 1H-NMR, 13C-NMR, TGA-FTIR, ESR, GPC, UV-VIS, DLS and
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Tatchell, Thomas. "Coordination chemistry of pendant aniline aza-macrocycles." Thesis, Cardiff University, 2005. http://orca.cf.ac.uk/56099/.

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The selective functionalisation of triazamacrocycles is investigated herein, with the focus on 1, 4, 7-triazacyclononane (tacn) The ligands tris (5-fluoro, 2- aminophenyl) 1, 4, 7-triazacyclononane (L1), tris (4-fluoro, 2-aminophenyl) 1,4, 7- triazacyclononane (L") and tris (3-fluoro, 2-ammophenyl) 1, 4, 7-triazacyclononane (L ) were studied. X-Ray crystal data was obtained for (L,)M (C104)2.x:MeCN where M=Mn,,/FeII/Ni"/CuII/Znn/CdII/Hgn, (L2)M (C104)2 xMeCN where M=Mn1I/Fe,I/NiII/CuII/ZnII/Cdn and (L3)M (C104)2 xMeCN where M=Mn,1/NiI,/Cun/Zn,I/Cd,,/Pb11 complexes. The (L,)Cu (C104)2 complex e
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Santos, Isabela Ferreira Sodré dos. "Investigação da correlação morfologia/estrutura nos produtos da polimerização da anilina com persulfato de amônio." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-22102013-104923/.

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É verificado que materiais nano/micro estruturado, com morfologia definida possui propriedades melhoradas em relação às formas macro. Essa constatação justifica o crescente número de rotas diferentes para se sintetizar polianilina numa ampla gama de morfologias diferentes e tamanhos definidos, através de variações na síntese padrão de polianilina. Utilizando uma dessas rotas que leva a produto com morfologia esférica, em estudo anterior do nosso grupo foi mostrado que o produto principal é adutos de anilinas constituídos por adutos tipo 1,4-Michael entre anilina e benzoquinona monoimina e segm
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Thomas, James Owain. "Molecular-level studies of oligo (aniline) thin films." Thesis, University of Bristol, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.702307.

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The performance of devices based on small molecules depends on their molecular architecture and their two- and three-dimensional organisation into thin films. In this thesis scanning probe microscopy and density functional theory calculations are used to elucidate packing of poly(aniline) oligomers, oligo(aniline)s, into films formed by vacuum thermal evaporation and solution-processing. Thermal deposition of oligo(aniline)s under ultra-high vacuum conditions and subsequent study by scanning tunneling microscopy at various temperatures highlights two key issues with the preparation of oligo(an
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Hu, Yaoyang. "Functional 3D architectures based on oligo(aniline)s." Thesis, University of Bristol, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.707734.

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Rannou, Patrice. "Poly(aniline) : synthèse, mise en oeuvre et vieillissement." Université Joseph Fourier (Grenoble ; 1971-2015), 1998. http://www.theses.fr/1998GRE10080.

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Ce travail est consacré à la synthèse, la mise en œuvre et le vieillissement d'un polymère conducteur (pc) : la polyaniline (pani). Deux morphologies ont été étudiées : des poudres divisées de pani dopee par l'acide chlorhydrique (pani-hci) et des films de pani dopee par l'acide camphre sulfonique (csa) obtenus par l'évaporation de solutions dans le m-cresol. Dans une première partie, nous présentons la synthèse chimique basse température par voie oxydante de la pani. Le contrôle des paramètres de synthèse a permis de préciser le mécanisme de polymérisation et d'obtenir des polymères de masse
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Books on the topic "Aniline"

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Canada, Canada Environment Canada, and Canada Health Canada, eds. Aniline. Environment Canada, 1994.

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I, Boeckhout C., Netherlands. Directoraat-Generaal van de Arbeid., and TAUW Infra Consult bv, eds. Werkterreinanalyse van aniline. Directoraat-Generaal van de Arbeid van het Ministerie van Sociale Zaken en Werkgelegenheid, 1991.

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Zok, Sabine. Metabolismus substituierter Aniline beim Zebrabärbling. [s.n.], 1991.

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Zvi, Rappoport, ed. The chemistry of anilines. Wiley, 2007.

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Great Britain. Health and Safety Executive., ed. Aniline: Risk assessment document EH72/8. HSE Books, 1997.

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United States. Agency for Toxic Substances and Disease Registry. and Research Triangle Institute, eds. Toxicological profile for methylenedianiline. U.S. Dept. of Health and Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry, 1998.

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Syracuse Research Corporation. Center for Chemical Hazard Assessment. Monograph on human exposure to chemicals in the workplace : aniline: Final report. National Cancer Institute, Division of Cancer Etiology, 1985.

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National Institute for Occupational Safety and Health, ed. Morton International Chemical Company, Patterson [i.e. Paterson], New Jersey. U.S. Dept. of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, 1994.

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Crofton, G. D. A study of the implementation of total quality management at the Clayton Aniline company. UMIST, 1993.

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Simard, Robert D. An EPR study of the intermediates formed in the reaction between aluminium atoms and aniline. Laurentian University, 2005.

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Book chapters on the topic "Aniline"

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Lide, David R. "Aniline." In Handbook of Organic Solvents. CRC Press, 2024. http://dx.doi.org/10.1201/9781003575191-18.

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Gooch, Jan W. "Aniline." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_644.

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Patnaik, Pradyot. "Aniline." In Handbook of Environmental Analysis. CRC Press, 2017. http://dx.doi.org/10.1201/9781315151946-69.

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Gooch, Jan W. "Aniline Dye." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_646.

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Gooch, Jan W. "Aniline Ink." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_649.

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Gooch, Jan W. "Aniline Number." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_650.

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Gooch, Jan W. "Aniline Pigments." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_651.

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Gooch, Jan W. "Aniline Point." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_652.

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Gooch, Jan W. "Aniline Printing." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_653.

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Kontou, Tatiana, Victoria Mills, and Richard Menke. "Aniline dye." In Victorian Material Culture. Routledge, 2022. http://dx.doi.org/10.4324/9781315400303-64.

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Conference papers on the topic "Aniline"

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Haskaj, Adelina, Musaj Pacarizi, Sonja Lepitkova, Berat Sinan, Bahri Sinani, and Elida Dreshaj. "THE POTENTIAL COMPLEXING IMPACT OF SOME ORGANIC COMPOUNDS AMINE AND CARBOXYL GROUPS ON TRANSITION METALS." In 24th SGEM International Multidisciplinary Scientific GeoConference 24. STEF92 Technology, 2024. https://doi.org/10.5593/sgem2024/4.1/s18.42.

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Environmental water chemistry is substantially aided by modern electrochemical research. Sensitive voltammetric techniques are much more useful for metal species in natural waters, where complexation with organic molecules predominates. Many environmental electrochemists are still interested in determining the stability constants of metal ion complexes with various ionic species found in natural waterways. The aim of this work is to investigate the possible influence of complexation of amine and carboxyl groups of some organic molecules (with EDTA, NTA and aniline, using differential pulse pol
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Sterczewski, Lukasz A., Jakub Mnich, and Jaroslaw Sotor. "Multi-Octave THz Generation and Detection at MHz Repetition Rates using the Organic Nonlinear Crystal PNPA." In CLEO: Science and Innovations. Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_si.2024.sm2p.5.

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Generation and detection of broadband THz radiation using the PNPA ((E)-4-((4-nitrobenzylidene)amino)-N-phenyl-aniline) crystal at MHz repetition rates is demonstrated. Compatibility with nanojoule pump pulses at telecommunication wavelengths makes this medium attractive for compact THz spectrometers.
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Jauhari, Smita, and Bhupendra Mistry. "“Study of the Inhibitive Effect of Novel Quinoline Schiff Base on Corrosion of Mild Steel in HCl Solution”." In CORROSION 2013. NACE International, 2013. https://doi.org/10.5006/c2013-02326.

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Abstract Schiff base 4-Chloro-N-[(2-chloroquinolin-3-yl)methylene]aniline was synthesized, and its inhibitive effect for mild steel in 1M HCl solution was investigated by weight loss measurement and electrochemical tests.From the weight loss measurements and electrochemical tests, it was observed that the inhibition efficiency increases with the increase in the Schiff base concentration and reaches a maximum at the optimum concentration. This is further confirmed by the decrease in corrosion rate. It is found that the system follows Langmuir adsorption isotherm.
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Jauhari, Smita, and Bhupendra Mistry. "Study of the Inhibitive Effect of Novel Schiff Base on Corrosion of HCL on Mild Steel." In CORROSION 2012. NACE International, 2012. https://doi.org/10.5006/c2012-01478.

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Abstract Schiff base (E)-3-chloro-N-((2-chloroquinolin-3-yl)methylene)aniline (CQA) was synthesized, and its inhibitive effect for mild steel in 1M HCl solution was investigated by weight loss measurement and electrochemical tests. From the weight loss measurements and electrochemical tests, it was observed that the inhibition efficiency increases with the increase in the Schiff base concentration and reaches a maximum at the optimum concentration. This is further confirmed by the decrease in corrosion rate. It is found that the system follows Langmuir adsorption isotherm.
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Omotosho, Olugbenga Adeshola, Joshua Olusegun Okeniyi, and Abimbola Patricia Idowu Popoola. "Corrosion Inhibition of Stainless Steel in 0.5 M HCl by C6H5NH2." In CORROSION 2018. NACE International, 2018. https://doi.org/10.5006/c2018-10807.

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Abstract In this study, different concentrations of C6H5NH2 (Aniline) were employed for investigating its corrosion inhibition of stainless steel in 0.5 M HCl. Corrosion rate measurements at 28°C, 45°C and 60°C were obtained from a linear sweep voltametry instrument and analyzed for inhibition efficiency and apparent activation energy in the presence and absence of C6H5NH2. Results showed that C6H5NH2 generally exhibited excellent inhibition effects on stainless steel corrosion at the higher temperatures, i.e. the 45°C and 60°C, at which the self-protectiveness of the stainless steel metal app
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Li, Jie, Boya Zhang, Xuanjie Zhang, Yixuan Li, Xiao Yuan, and Xingwen Li. "Effect of Large Linking Groups on the Electrical and Thermal Properties of Aniline Cured Epoxy Resins." In 2024 3rd International Conference on Power Systems and Electrical Technology (PSET). IEEE, 2024. https://doi.org/10.1109/pset62496.2024.10808806.

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Fonseca, A., E. Almanza, W. Rozo, and E. Vera. "Effect of N-Furfuryil-Aniline and N-Furyl-C-Phenyl-Nitrone on Corrosion Inhibition of Low Carbon Steel in 3% NaCl." In CONFERENCE 2022. AMPP, 2022. https://doi.org/10.5006/c2022-18167.

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ABSTRACT Carbon steel is one of the most commonly used metals in the oil, gas, and hydrocarbons transport industry, given its mechanical properties and low production cost; however, its low corrosion resistance to different aggressive environments has been considerably reported. Worldwide, there is an interest in mitigating corrosion and minimizing the associated cost. Inhibitors have become one of the best practical methods to avoid internal corrosion damage, especially in hydrocarbons transport lines. This investigation aims to develop and evaluate the molecules n-furfuryil-aniline (NFA) and
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Kon, Yoshihiro. "Selective monoallylation of anilines to form fine chemicals using allyl alcohol derived from glycerol." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/mjrr3569.

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Glycerol is an important starting material for the production of value-added chemicals such as electronic materials and pharmaceuticals. We herein present a selective allylation reaction using allyl alcohol which is given from glycerol. First, we show the rhenium catalyzed high-yielding synthesis of allyl alcohol from glycerol through deoxydehydration reaction. Next, the selective N-allyl aniline synthesis from allyl alcohol with aniline is performed. The well-dispersed tungsten oxide supported on zirconium oxide can catalyze the reaction to produce the corresponding mono-allyl compound over
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Catargiu, Ana-Maria, and Mircea Grigoras. "Polyaniline/poly (aniline-N-propansulfonic acid) composites by template polymerization of aniline." In Advanced Topics in Optoelectronics, Microelectronics, and Nanotechnologies 2012, edited by Paul Schiopu and Razvan Tamas. SPIE, 2012. http://dx.doi.org/10.1117/12.974919.

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Gao, Ling, Shouxin Ren, and Huizhen Zhang. "Simultaneous Spectrophotometric Determination of O-nitro-aniline, M-nitro-aniline and P-nitro-aniline Using a Wavelet-based Generalized Regression Neural Network." In 2008 International Workshop on Modelling, Simulation and Optimization (WMSO). IEEE, 2008. http://dx.doi.org/10.1109/wmso.2008.47.

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Reports on the topic "Aniline"

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Zhou, H. C., and R. S. Duran. The Effect of Surface Pressure on Langmuir-Blodgett Polymerization of 2- Pentadecyl Aniline. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada250993.

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Bernstein, E. R., M. F. Hineman, S. K. Kim, and D. F. Kelley. Vibrational Dynamics of Aniline (N2)1 Clusters in Their First Excited Singlet State. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada245812.

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Huang, S. X., J. L. Gland, and D. A. Fischer. Aniline hydrogenolysis on the Pt(111) single crystal surface: Mechanisms for C-N bond activation. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10117539.

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Essington, M. E., J. M. Bowen, R. A. Wills, and B. K. Hart. Adsorption of aniline and toluidines on montmorillonite: Implications for the disposal of shale oil production wastes. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/6745527.

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Essington, M. E., J. M. Bowen, R. A. Wills, and B. K. Hart. Adsorption of aniline and toluidines on montmorillonite: Implications for the disposal of shale oil production wastes. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10133217.

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Ruangpornvisuti, Vithaya. Basicity investigation and structure optimization of polyaza-Calixarenes and stabilities of their complexes with metal cations. Chulalongkorn University, 2000. https://doi.org/10.58837/chula.res.2000.26.

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Abstract:
The structure of 25, 26, 27, 28-tetra(2-ethoxyaniline)calix[4]arene of cone (cL) and partial cone (pcL) conformations were optimized by PM3 of quantum chemical method. It has been found that cL structure is more stable than pcL conformation. The stabilization energies of protonation on four aniline-nitrogen atoms of both conformations of the ligand at 6-31G energy level, were obtained. The protonations process on the cL and pcL being 7 and 24 possible pathways, respectively, were evaluated. The basicity constants of partial cone conformation of 25, 26, 27, 28-tetra(2- ethoxyaniline)calix[4]are
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Feng, J., W. Zhang, A. G. MacDiarmid, and A. J. Epstein. Synthesis and Characterization of Oligomeric Anilines. Defense Technical Information Center, 1997. http://dx.doi.org/10.21236/ada330138.

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NIOSH skin notation (SK) profile: aniline [CAS No. 62-53-3]. U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, 2015. http://dx.doi.org/10.26616/nioshpub2015192.

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Request for assistance in preventing bladder cancer from exposure to o-toluidine and aniline. U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health, 1990. http://dx.doi.org/10.26616/nioshpub90116.

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