Academic literature on the topic 'Aniline absorption'

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Journal articles on the topic "Aniline absorption"

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R., P. Rastogi, and K. Srivastava P. "An optically oscillating ephemeral intermediate in uncatalyzed bromate driven oscillators." Journal of Indian Chemical Society Vol. 81, Nov 2004 (2004): 959–61. https://doi.org/10.5281/zenodo.5833485.

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Department of Chemistry, Lucknow University, Lucknow-226 001, India Department of Applied Chemistry, Birla Institute of Technology, Mesra, Ranchi-835 215, India <em>Manuscript received 21 June 2003, revised 21 June 2004, accepted 22 July 2004</em> An optically oscillating ephemeral intermediate was found in the uncatalyzed bromate driven oscillator, phenol-\(BrO_3^--H_2SO_4\) or aniline-\(BrO_3^--H_2SO_4\) system in a batch reactor. These oscillations were found to be in phase with the redox potential oscillations. The oscillating ephemeral intemediate in phenol system was found to be phenoxy
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KURIAN, ACHAMMA, S. THOMAS LEE, K. P. UNNIKRISHNAN, D. SAJAN GEORGE, V. P. N. NAMPOORI, and C. P. G. VALLABHAN. "STUDIES ON TWO-PHOTON ABSORPTION OF ANILINE USING THERMAL LENS EFFECT." Journal of Nonlinear Optical Physics & Materials 12, no. 01 (2003): 75–80. http://dx.doi.org/10.1142/s0218863503001213.

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Two-photon absorption spectrum of aniline is recorded using thermal lens effect with optical parametric oscillator as the pump source. Studies show that the two-photon absorption spectrum observed corresponds to 1A1 → 1B2 transition of aniline.
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Bayrakçeken, Fuat, and İpek Ş. Karaaslan. "High resolution electronic absorption spectra of aniline, anilino and silicon dioxide." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 59, no. 12 (2003): 2785–89. http://dx.doi.org/10.1016/s1386-1425(03)00061-1.

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Bhattacharya, Sumanta, Sandip K. Nayak, Subrata Chattopadhyay, Manas Banerjee, and Asok K. Mukherjee. "Absorption Spectroscopic Study of the Complexation of C70with Aniline and Substituted Anilines." Journal of Physical Chemistry A 106, no. 29 (2002): 6710–13. http://dx.doi.org/10.1021/jp0204051.

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Tian, Weiguo, Yinan Xue, Jintao Tian, et al. "Colorimetric and fluorometric dual-mode detection of aniline pollutants based on spiropyran derivatives." RSC Advances 6, no. 86 (2016): 83312–20. http://dx.doi.org/10.1039/c6ra17862f.

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The selective UV-vis absorption of spiropyran and the fluorescence quenching of SP-cellulose material induced by aniline were observed and exploited for rapid detection and accurate quantitative determination of aniline pollutants in the environment.
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Qin, Ling, G. N. R. Tripathi, and Robert H. Schüler. "Radiation Chemical Studies of the Oxidation of Aniline in Aqueous Solution." Zeitschrift für Naturforschung A 40, no. 10 (1985): 1026–39. http://dx.doi.org/10.1515/zna-1985-1009.

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Oxidation of aniline in aqueous solution by ·OH radicals proceeds predominantly via addition to the ring followed by elimination of OH- on the microsecond time scale to form the aniline radical cation. Direct oxidation by electron transfer accounts for less than 4% of the ·OH reactions. The different hydroxycyclohexadienyl isomers produced by ·OH addition decay at different rates with this decay catalyzed both by protons and phosphate. In basic solution the resultant radical cation deprotonates to form the anilino radical. The p Ka for the equilibrium between the acidic and basic forms of this
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Zhang, Xuan. "Preparation and Microwave Absorption Properties of Polyaniline and Magnetite Core-Shell-Structured Hybrid." International Journal of Polymer Science 2018 (October 24, 2018): 1–6. http://dx.doi.org/10.1155/2018/3417060.

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In this study, polyaniline and Fe3O4 (PAN@Fe3O4) hybrids are fabricated and their microwave absorption property is studied. PAN@Fe3O4 hybrids are fabricated by the in situ aniline polymerization at spherical of Fe3O4 which is prepared by the solvothermal process. Fourier-transform infrared spectrophotometer (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) are applied to confirm the composition of the fabricated PAN@Fe3O4 hybrids. The morphologies of PAN@Fe3O4 hybrids are studied by scanning electron microscope (SEM) and transmission electron microscopy (TEM). The con
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Mou, Wen-Yu, Bin Xie, Xiao-Long Li, et al. "Tartrate-stabilized titanium–oxo clusters containing sulfonate chromophore ligands: synthesis, crystal structures and photochemical properties." New Journal of Chemistry 45, no. 24 (2021): 10930–39. http://dx.doi.org/10.1039/d1nj01540k.

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Lin, Shu-Yu, Sheng-Lung Chou, Chien-Ming Tseng, and Yu-Jong Wu. "IR absorption spectra of aniline cation, anilino radical, and phenylnitrene isolated in solid argon." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 276 (August 2022): 121233. http://dx.doi.org/10.1016/j.saa.2022.121233.

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Li, Ding Guo, Wen Hua Lu, Cong Chen, Wei Rao, and Yong Hong Xiong. "Synthesis and Microwave Absorption Characteristics of Polyaniline." Applied Mechanics and Materials 327 (June 2013): 53–57. http://dx.doi.org/10.4028/www.scientific.net/amm.327.53.

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This paper aims at reporting the synthesis and microwave absorption characteristics of polyaniline (PANI). The PANI nanoparticles were synthesized by chemical oxidative polymerization method with ammonium persulfate ((NH4)2S2O8, APS) as oxidant and hydrochloric acid (HCl) for protonation of aniline. For APS/aniline mol ratio of 1, HCl concentration of 1 mol/L, reaction temperature of 5°C, the reaction time of 6h, the obtained PANI exhibits the highest value(30.9 S·cm-1)of the electrical conductivity. The structure and morphology of PANI were studied by X-ray diffraction (XRD), scanning electro
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Dissertations / Theses on the topic "Aniline absorption"

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Franzen, Paulo Licênio. "Propriedades ópticas não-lineares de oligômeros de anilina." Universidade de São Paulo, 2002. http://www.teses.usp.br/teses/disponiveis/76/76131/tde-09042008-085704/.

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Apresentamos os resultados do estudo das não-linearidades ópticas de origem eletrônica de duas moléculas da classe dos oligômeros de anilina: o dímero e o tetrâmero. Foram medidas quatro concentrações de tetrâmero, puras e também dopadas em 33 e 100%; uma de dímero pura e outra dopada em 100%. As soluções foram preparadas usando dimetil-sulfóxido (DMSO) como solvente e a dopagem foi realizada com ácido clorídrico. As amostras foram caracterizadas por medidas de absorção linear e fluorescência antes das medidas não-lineares. Obtivemos os valores da primeira hiperpolarizabilidade (?) para todas
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David, Hélène. "Etude de matrices polymères permettant la libération contrôlée d'agents actifs en agriculture : expérimentation et modélisation des transferts de matière." Saint-Etienne, 1989. http://www.theses.fr/1989STET4004.

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L'agent actif considéré a été l'éthoprophos, principe nématicide utilisé en agrochimie, mais dans un premier temps, l'aniline a été utilisé comme agent simulant. Les processus d'absorption et de désorption dans l'eau, ont été modélisés, dans le cas d'un granulé composé d'EVA pur, à l'aide d'une solution analytique de l'équation de Fick. Un modèle mathématique basé sur une méthode numérique a été construit pour décrire les transferts à travers un granulé composé par un noyau et une enveloppe
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Boni, Leonardo de. "Propriedades ópticas de tetrâmeros de anilina em solução." Universidade de São Paulo, 2000. http://www.teses.usp.br/teses/disponiveis/76/76131/tde-12062008-152417/.

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Neste trabalho são estudadas algumas propriedades ópticas de tetrâmeros de anilina em solução, usando o dimetil sulfóxido (DMSO) como solvente. Os espectros de absorção e emissão permitiram uma determinação aproximada dos níveis de energia do tetrâmero. Para a caracterização das propriedades ópticas não lineares foram utilizadas as técnicas de varredura-Z resolvida em freqüência e com trem de pulsos. Com a primeira foram determinados os parâmetros térmicos relacionados ao solvente, enquanto que com a segunda foram caracterizadas as não linearidades eletrônicas associadas aos estados excitados
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Rouyer, Virgile. "Polyaniline : hydratation, mise en oeuvre par voie solvant, et durabilité : approches RMN et méthodes diffusives." Université Joseph Fourier (Grenoble), 1999. http://www.theses.fr/1999GRE10075.

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Ce memoire est consacre a l'hydratation, a la mise en oeuvre par voie solvant, et a la durabilite d'un polymere conducteur electronique intrinseque : la polyaniline (pani). Les coefficients de diffusion de l'eau, ainsi que les mecanismes physico-chimiques associes a l'hydratation de diverses poudres de pani, sont caracterises, en regime transitoire ou stationnaire, par : sorption (isothermes et cinetiques), calorimetrie, permeation, et rmn (relaxation magnetique nucleaire transversale). Nous debattons de l'influence de l'etat de dopage et de la nature du dopant (hci, acs) sur les processus d'i
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Books on the topic "Aniline absorption"

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Panigrahi, Muktikanta, and Arpan Kumar Nayak. Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip212.

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In this research work, we have demonstrated the synthesis, spectroscopic characteristics, thermal behaviour and DC conductivity of a few nanostructured composites, substituted conducting polymers (ICPs) and composites of ICPs. The physical properties of aforementioned composites are significantly changed by the doping with HCl, H2SO4, HNO3, H3PO4, or acrylic acid. The charge transport properties of these polymeric materials have been studied in detail because of their potential application in gas sensors. In the current work, varieties of conducting polymer based materials such as PANI-ES/Cloi
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Book chapters on the topic "Aniline absorption"

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Elegbeleye, Ife, Eric Maluta, Regina Maphanga, Michael Walter, and Oliver Brügner. "Photoanode Applications of Polyene-Diphenylaniline Dyes Molecules Adsorbed on TiO2 Brookite Cluster." In Revolutionizing Energy Conversion - Photoelectrochemical Technologies and Their Role in Sustainability. IntechOpen, 2024. http://dx.doi.org/10.5772/intechopen.1005450.

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TiO2 has excellent photoelectrochemical properties, which makes its suitable for photoanode applications. TiO2 is widely utilized as semiconductor for dye-sensitized photoanode owing to its excellent stability and availability. The brookite polymorph of TiO2 has been suggested to demonstrate better photocatalytic properties. In this work, we studied the adsorption of polyenediphenyl-aniline dyes on (TiO2) n = 8, 68 brookite clusters using density functional theory (DFT). We report our results on the UV–Vis absorption spectra of the dyes and dyes adsorbed on TiO2 clusters, adsorption energies o
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Panigrahi, Muktikanta, and Basudam Adhikari. "DL-Polylactide (DL-PLA) Based Polyaniline Composite for Hydrogen Gas Sensors." In Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip2125.

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Different inorganic acids like HCl, HNO3, H2SO4 and H3PO4-doped based DL-PLA/PANI-ES composites were synthesized by in-situ chemical oxidation polymerization technique using liquid aniline as precursors. The doped composite have observed fibril-like morphology with different average sized diameter (178 nm for HCl doped composite, 162 nm (H2SO4 doped composite), 153 nm (H3PO4 doped composite) and 163 nm (HNO3 doped composite), respectively. Analysis of presence of functional groups and other chemical groups of as prepared composites was done by FTIR experiment in ATR mode. The optical (direct)
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Conference papers on the topic "Aniline absorption"

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"Absorption Properties of TiO2 Coated MWCNT/Fe3O4/Poly aniline Nano Composite in X-Band." In The 9th International Conference on Engineering and Applied Sciences. ICIR Publishing Company, 2019. http://dx.doi.org/10.29088/iceasconf.2019.1005.

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Yudin, I. K., M. A. Anisimov, and I. A. Dmitrieva. "Photon Correlation Spectroscopy of Dark "Non-Transparent" Fluids." In Photon Correlation and Scattering. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/pcs.1992.tub5.

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Photon correlation spectroscopy (PCS) is the most precise and accurate method to measure a size of submicron particles in transparent suspensions. However, interpretation is simple only for single scattering approximation and much more complicated for multiple scattering. For dark "non-transparent" media, such as a crude oil, metal powder suspensions, etc… PCS technigue is practically not usable. In such media the multiple scattering is negligible due to the strong light absorption. Low-optical-path cells are not convenient in practice. We propose modified light scattering geometry for particl
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Larsson, L. J., E. P. Frisch, and I. Bjoörk. "PROPERTIES OF THE COMPLEX BETWEEN ou-MACROGLOBULIN AND THE PROTEINASE BRINASE FROM ASPERGILLUS ORYZAE." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1643039.

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Brinase, a proteinase from Aspergillus oryzae, has previously been shown to have a significant thrombolytic effect in patients suffering from peripheral arterial disease. Brinase is rapidly bound to α1-proteinase inhibitor and α2-macroglobulin (α2M) in plasma. Since binding of a proteinase to α2 M only results in ste-rical blockingof the active siteand not complete inactivation of the enzyme, it has been suggested that brinase in complex with α2M may retain ability to digest fibrin.To test this hypothesis, we have characterized the binding of brinase to α2M and the properties of the complex fo
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