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Dissertations / Theses on the topic 'Anion binding'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Sergeant, Genevieve. "Applications of Anion Binding." Thesis, The University of Sydney, 2022. https://hdl.handle.net/2123/28497.

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This thesis describes the development and exploration of chemosensing systems for phosphates and their applications to specific biological challenges. Investigation of the sensing abilities of a peptide-based bis-Zn(DPA) chemosensor, is detailed. Building on existing research aimed at developing selective sensors of phosphate species (PPi, ADP and ATP), the properties of this sensor were thoroughly investigated in a variety of buffered aqueous systems. The chemosensor exhibited a large, selective, turn on in emission in the presence of pyrophosphate but this response was modulated by additiv

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2

Atkinson, Paul. "Chemoselective phospho-anion binding studies." Thesis, Durham University, 2005. http://etheses.dur.ac.uk/2804/.

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An investigation has been carried out, studying the interaction of various bioactive anions, particularly phosphorylated species, with well-defined chiral lanthanide complexes. In each ternary anion adduct, proton NMR analysis revealed a distinctive pattern for the most high frequency shifted resonances. Furthermore, the mean chemical shift of these four resonances can be used to identify the anion adducts present in solution and indicate the binding mode exhibited towards the lanthanide(III) centre. Similar differentiation of anion binding modes is also available from luminescence spectroscop

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3

Watson, James David. "Anion and cation binding in proteins." Thesis, University of Glasgow, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252533.

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4

Murray, Ben. "Anion binding studies with responsive lanthanide complexes." Thesis, Durham University, 2008. http://etheses.dur.ac.uk/2237/.

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The binding of a range of biologically prevalent anions to several novel lanthanide(III) complexes has been studied by emission spectroscopy, (^1)H-NMR and mass spectrometry. In each case, the resultant solution adduct and the mode of anion binding was characterised through analysis of spectral response. Following the first chapter, in which relevant background work and literature reports are discussed, the novel lanthanide(III) complexes described herein are separated into three chapters. Chapter 2 describes a range of complexes bearing a pendant azaxanthone or aza-thioxanthone derived chromo

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5

Hussain, Sabir. "Polycyclic receptors for anion binding and transport." Thesis, University of Bristol, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.547832.

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6

Seijo, Bibiana Campos. "Supramolecular complexes for cation and anion binding." Thesis, Manchester Metropolitan University, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405678.

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7

Edwards, Sophie Jane. "Preorganised receptors for anion binding and transport." Thesis, University of Bristol, 2015. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.685437.

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This thesis is concerned with the synthesis of new anion receptors and describes the anion binding and anion transport properties of these compounds Ten squaramide receptors (A) based on a steroidal cholapod backbone have been synthesised. Association constants for the squaramide receptors with chloride anions were assessed in chloroform and were found to be exceptionally high, up to 1.2 x 1014 M-1 , and in most cases were higher than that of all chloride receptors previously published by the A. P. Davis group. The introduction of electron withdrawing aromatic groups led to increased associati

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8

Qin, Lei. "Squaramide-based Receptors for Anion Recognition." Thesis, The University of Sydney, 2017. http://hdl.handle.net/2123/17808.

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A series of squaramide based receptors bearing benzene and pyridine linkers was developed, ranging from simple alkyl-substituted mono-squaramides to macrocyclic tri-squaramides by altering the number of squaramide binding sites, adjusting the geometries of compounds and appending different solubilizing groups. These receptors were studied via host-guest 1H NMR titrations with a range of anions in DMSO-d6 and water. In this work, the successful trial of aqueous soluble, macrocyclic squaramide receptors (MSQs) were synthesized that bind sulfate with high affinity and selectivity over other tetra

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9

Zwicker, Eddie Vincent. "Development and Applications of Novel Anion Receptors." Thesis, The University of Sydney, 2019. http://hdl.handle.net/2123/20962.

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The construction of novel anion receptors is crucial for applications in biological, medicinal and environmental studies. This thesis describes a number of advances in the development and application of anion receptors. The focus lies on both the synthesis and application of these novel receptors. Chapter two describes the syntheses and anion binding studies of the croconamides and deltamides, two novel dual hydrogen bond donating motifs. Important anion binding trends are highlighted and the binding properties of these scaffolds are compared to those of commonly used urea and squaramide bindi

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10

Cooper, James Arthur. "Novel cyclohexane-based receptors for anion binding and transport." Thesis, University of Bristol, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.683940.

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This thesis describes a series of novel anionophores and details their synthesis, anion binding and anion transport capabilities. These novel anionophores are based on a cyclohexane scaffold CA, Figure 1), and are simpler to synthesise than the cholapod and decal ins CB and C in Figure 1 respectively) previously reported by the Davis group. Association constants for chloride were evaluated for the new cyclohexane-based receptors in DMSO-d6/0.S% H20 and, where solubility permitted, in water-saturated chloroform. For the novel cyclohexane systems A, higher association constants were obtained whe

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11

Zieleniuk, Candace A. "Anion binding and catalytic studies of metal salen complexes." [Gainesville, Fla.] : University of Florida, 2009. http://purl.fcla.edu/fcla/etd/UFE0024865.

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12

Cooper, James B. "Multi-site calix[4]arenes anion and cation recognition." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312555.

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13

Knight, Joanne L. "Crown ether and catechol receptors for metal and anion complexation." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301241.

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14

Schumacher, Amy Lea. "Oxoporphyrinogens: Electrochemistry, anion binding, and light induced electron transfer studies." Diss., Wichita State University, 2007. http://hdl.handle.net/10057/1496.

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The research presented in this dissertation deals with the electrochemical, anion binding and photochemical studies of various oxoporphyrinogen systems. The first chapter provides a brief introduction to the material discussed in subsequent chapters. The second chapter discusses the electrochemical, spectroelectrochemical, computational (ab inito), and structural characterization of an extended family of N-substituted oxoporphyrinogens. The effect of increasing N-substitution on the electrochemical and spectroelectrochemical properties was systematically investigated. Chapter three focuses on

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15

Graydon, Andrew R. "An investigation of anion binding by acyclic metal-centred receptors." Thesis, University of Oxford, 1995. http://ora.ox.ac.uk/objects/uuid:352c26dc-6d31-4417-9185-dcb75b18af77.

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This thesis reflects two main aims. Firstly, the synthesis and characterisation of a number of potential anion receptors was undertaken and their anion binding properties were assessed. In so doing, a second aim was fulfilled, namely a comparison of the various methods of detecting the bound anion, and quantifying the binding strength. Four techniques appear in this thesis; <sup>1</sup>H nuclear magnetic resonance, UV-visible spectroscopy, electrochemistry and luminescent emission. Quantitative titrations were performed and, where possible, stability constants estimated. Chapter One provides a

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16

Lenthall, Joseph T. "Anion and platinum group metal binding of bis(thioureido) ligands." Thesis, Durham University, 2007. http://etheses.dur.ac.uk/2854/.

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A series of bis(thioureido) ligands have been synthesised, which show anion binding in acetone-d(_6). Their structures have been determined by X-ray crystallography and some exhibit hydrogen bonding interactions with the π-electrons of the the thiocarbonyl bond. This hydrogen bonding interaction has been investigated for the general thiocarbonyl and carbonyl bond using the CSD, and a marked difference in the interaction of hydrogen bond donors with the π-electrons of carbonyl and thiocarbonyl bonds has been shown. The bis(thioureido) ligands have been coordinated to platinum group metals and t

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17

Duckmanton, Paul Andrew. "Anion-binding ureaphosphine ligands and their late transition metal complexes." Thesis, University of Nottingham, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438264.

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18

Zhang, Hu. "Engaging Chiral Cationic Intermediates by Anion-Binding in Asymmetric Catalysis." Thesis, Harvard University, 2016. http://nrs.harvard.edu/urn-3:HUL.InstRepos:26718738.

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Anion-binding catalysis by dual hydrogen-bond donors such as ureas and squaramides has been demonstrated as a powerful strategy for the development of highly enantioselective transformations involving prochiral cationic intermediates, such as iminium ions, oxocarbenium ions, carbenium ions, and episulfonium ions. The research described in this dissertation explores the ability of dual H-bond donor catalysts to engage chiral cationic intermediates and to induce enantioselectivity in transformations involving such intermediates. In Chapters 1, we provide an overview of the progress and challenge

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19

Schumacher, Amy Lea D'Souza Francis. "Oxoporphyrinogens: Electrochemistry, anion binding, and light induced electron transfer studies /." Diss., A link to full text of this thesis in SOAR, 2007. http://hdl.handle.net/10057/1496.

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20

Davis, Julian Murray. "Sapphyrins aggregation and anion binding behavior in polar, protic media /." Access restricted to users with UT Austin EID UMI Company copy, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3036590.

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21

Dickson, Sara-Jane. "Flexible podand and metal-based hosts for anion binding and sensing." Thesis, Durham University, 2008. http://etheses.dur.ac.uk/2263/.

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A series of amino-pyridyl and aminomethyl-pyridyl ligands, all with both pyridyl and secondary amine functionalities have been synthesised. A new series of organic and metal- based derivatives of these ligands have been prepared, along with the preparation of an organic viologen host, with previously reported urea arms,(^1) and the properties of these new compounds, and in particular their anion binding behaviour have been studied. The 3-aminomethyl-pyridyl ligands interact with transition metals and anions, in both solution and the solid state. They showed a particular affinity for copper(II)

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22

Filby, Maria ? "Anion binding host systems based on calix[4]arenes and nanoparticles." Thesis, Durham University, 2007. http://etheses.dur.ac.uk/2399/.

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A range of novel host molecules with various degrees of pre-organisation for the supramolecular complexation of anionic guest species have been synthesized. Both organic core and nanoparticle-based derivatives of the ligands have been prepared and the properties of the new host ligands studied with particular reference to their anion binding behaviour. Two types of calix[4]arene derived cationic hosts for anions with, respectively, 1,3-altemate and cone conformations have been prepared. The affinity of the tetrasubstituted calix[4]arene hosts for a variety of anions has been probed with Ή NMR

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23

Salgado, Chayanika. "Synthesis of novel acyclic and macrocyclic receptors for anion binding and templation." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.491981.

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This thesis is concerned with the design and synthesis ofnew acyclic and macrocyclic receptors for anion binding and templation. ' Chapter One: Provides an introduction to the field of supramolecular chemistry and the nature of non-covalent interactions. A discussion of host-guest chemistry, in particular that of anions together with underlying principles of molecular recognition is given. Self assembly and anion templated interlocked molecular architectures are also reviewed. Chapter Two: Describes the design and synthesis of new Schiff base and amine pyridyl containing acyclic transition met

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24

Mason, Laura. "Synthesis, anion binding studies and applications of mono- and bimetallic lanthanide complexes." Thesis, University of Oxford, 2017. http://ora.ox.ac.uk/objects/uuid:285c82eb-c3c7-4ce4-a1eb-c72151b2ce15.

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This work describes the preparation and study of lanthanide complexes derived from heptadentate DO3A and DO3AM ligands. The work described encompasses a range of synthetic studies using conventional Click chemistry, novel gold catalysed couplings to prepare mono- and bi- metallic complexes and synthesis of DO3AM derivatives. These complexes have been used in a variety of studies to explore proton and anion binding events, and to develop catalysts for fluorination in protic solvents. Chapter one describes the fundamental properties of the lanthanides with a focus on their luminescent behaviour,

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25

Currie, Richild Alecia. "Spectroscopic, electrochemical and mass spectrometric investigation of anion binding by tripodal molecular receptors." FIU Digital Commons, 2005. http://digitalcommons.fiu.edu/etd/2698.

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The synthesis and anion binding properties of a fluorescent tripodal n-dansylamide (2) and a redox active tripodal quinone-based (3) receptor derived from 1,3,5-tris-(aminomethyl)-2,4,6-triethylbenzene. Herein the investigation of anion binding by these receptors via 1H-NMR, FT-IR, UV-Visible, and (APCI-MS) is reported. Fluorescence and electrochemical studies determined the ability of these receptors to sense anions. The downfield chemical shift changes in the 1H-NMR spectra and the low energy shifts of the νN-H stretching frequency in the FT-IR spectra indicated anion binding via hydrogen bo

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26

Devoille, Aline M. J. "New cofacial binuclear complexes for the oxygen reduction reaction and selective anion binding." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/9963.

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This thesis describes the design, synthesis and reactivity of bimetallic complexes of doubly-pillared Schiff-base calixpyrrole ligands. Chapter One introduces the oxygen reduction reaction in light of the global energy scenario at present and in the future. Compounds and materials known to catalyse this reaction are discussed, with particular focus on transition metal complexes of pyrrole-containing macrocycles and the ability of these compounds to act as catalysts in redox reactions. Chapter Two describes the design and synthesis of several of the macrocyclic ligands developed during this pro

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27

Shraberg, Joshua. "A Computational Study of Procyanidin Binding to Histatin 5 and Thermodynamic Properties of Hofmeister-Anion Binding to a Hydrophobic Cavitand." ScholarWorks@UNO, 2014. http://scholarworks.uno.edu/td/1944.

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Various studies suggest tannins act as antioxidants, anticarcinogens, cardio-protectants, anti-inflammatory agents, and antimicrobials. However, more investigation is needed to examine the bioavailability of tannins. Tannins bind to salivary peptides by hydrophilic and hydrophobic mechanisms. Electrospray Ionization Mass Spectrometry (ESI-MS) has been used to assess both hydrophilic and hydrophobic components of protein complexes. ESI-MS could potentially be an effective tool for screening the bioavailability of tannins. Weaker binding tannins are predicted to be more highly absorbed by the bo

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28

Turner, David Roger. "Anion binding properties and solid-state studies of novel urea-containing ligands and derivatives." Thesis, King's College London (University of London), 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.415507.

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29

El, Drubi Vega Ismael. "Synthesis and characterization of new supermolecular receptors and study of their anion binding properties." Thesis, University of Southampton, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438661.

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30

Fischer, Theresa [Verfasser], and Mancheño Olga [Akademischer Betreuer] García. "Enantioselective Nucleophilic Dearomatization of Heteroarenes by Anion-Binding-Catalysis / Theresa Fischer ; Betreuer: Olga García Mancheño." Regensburg : Universitätsbibliothek Regensburg, 2019. http://d-nb.info/1180719484/34.

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31

Schafer, Andrew Gerard. "Silanediols As Hydrogen Bond Donor Catalysts." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1396442513.

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32

Engle, Keary Mark. "Ligand-accelerated catalysis in palladium(II)-mediated C-H functionalisation ; Hydrogen bonding effects on the reactivity of fluoride anion." Thesis, University of Oxford, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.711664.

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33

Abbas, Ismail Ibrahim. "Anion and cation binding studies of calix[4]pyrrole receptors : detailed thermodynamic studies and environmental applications." Thesis, University of Surrey, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.441863.

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34

Hart, John Stewart. "Capsules, secondary interactions and unusual multi-metallic complexes." Thesis, University of Edinburgh, 2012. http://hdl.handle.net/1842/9923.

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Research into inorganic supramolecular chemistry is burgeoning, in particular that which focuses on the formation of capsular molecules and the effects that these unique environments have on catalytic reactions. With the aim of producing new ligand designs that could not only support reactive metals, but also partake in supramolecular aggregation to provide a capsular microenvironment, new tripodal ligands and wide span imines and amines have been synthesised. Furthermore, the exploitation of hydrogen-bonding motifs formed through pyrrole-imine tautomerisation upon metallation of these ligands

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35

Visco, Michael David. "Chiral Silanediols Designed for Enantioselective Heterocycle Functionalization." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1492438099945523.

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36

Lin, Song. "Elucidation of the Cation−π Interaction in Small-Molecule Asymmetric Catalysis." Thesis, Harvard University, 2013. http://dissertations.umi.com/gsas.harvard:11132.

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The cation–π interaction has been long-established to play an important role in molecular recognition, supramolecular chemistry, and molecular biology. In contrast, its potential application in small-molecule catalysis, especially as a selectivity-determining factor in asymmetric synthesis has been overlooked until very recently. This dissertation begins with an extensive literature review on the state-of-the-art research on the application of cation–π interactions in non-enzymatic catalysis of organic and organometallic transformations. The research in this field has been

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37

Kuchelmeister, Hannes [Verfasser], Carsten [Akademischer Betreuer] Schmuck, and Shirley [Akademischer Betreuer] Knauer. "Molecular Recognition of Biologically Relevant Targets : From Anion Binding Motifs to Application in Cell Biology / Hannes Kuchelmeister. Gutachter: Shirley Knauer. Betreuer: Carsten Schmuck." Duisburg, 2011. http://d-nb.info/1017289697/34.

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38

Copey, Laurent. "Synthèses et applications de nouveaux ligands pyrroliques et méthodologies de synthèse de phosphines P-chirogéniques." Thesis, Lyon 1, 2014. http://www.theses.fr/2014LYO10259/document.

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Deux thématiques principales ont été étudiées au cours de cette thèse. La première partie porte sur la synthèse de complexes de manganèse dérivés de porphyrines et de salens. L'activité catalytique de ces complexes a été évaluée dans l'époxydation d'alcènes non-Fonctionnalisés. Suite à cette étude, les propriétés électroniques des ligands ont été étudiées, notamment par le biais de la complexation d'anions. Dans une deuxième étape, nous nous sommes intéressés à la synthèse de phosphines P-Chirogéniques. Afin de trouver un substitut à l'éphédrine, couramment utilisée dans ces synthèses, des dér

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39

Birrell, James Andrew. "I. Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis II. Development of a Practical Method for the Synthesis of Highly Enantioenriched Trans-1,2-Amino Alcohols." Thesis, Harvard University, 2013. http://dissertations.umi.com/gsas.harvard:11037.

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A highly enantioselective acylation of silyl ketene acetals with acyl fluorides was developed to generate useful α,α-disubstituted butyrolactone products in high yield and excellent enantioselectivities. This transformation is promoted by an arylpyrrolidino thiourea catalyst and 4-pyrrolidinopyridine and represents the first example of enantioselective thiourea anion-binding catalysis with fluoride. Mechanistic investigations revealed both catalysts to be necessary for reaction to occur, suggesting the thiourea aids in the generation of the key N-acylpyridinium/fluoride ion pair. The outstandi

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40

Petri, Niclas. "Involvement of Membrane Transport Proteins in Intestinal Absorption and Hepatic Disposition of Drugs Using Fexofenadine as a Model Drug." Doctoral thesis, Uppsala University, Department of Pharmacy, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-5808.

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<p>The aims of this thesis were to study the in vivo relevance of membrane transporters for intestinal absorption and the hepatic disposition of drugs in humans and preclinical models. Fexofenadine is a substrate for ABCB1 (P-glycoprotein) and members of the organic anion transporting polypeptide (OATP/SLCO) family. It is marginally metabolised in humans. </p><p>The influence of known inhibitors of ABCB1 and OATPs on the membrane transport and pharmacokinetics of fexofenadine was investigated in Caco-2 and porcine models and in humans. The permeability of fexofenadine remained low, even when s

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41

Sperandio, Céline. "Développement de nouvelles plateformes polyols halogénés et étude de leurs propriétés supramoléculaires." Electronic Thesis or Diss., Aix-Marseille, 2019. http://www.theses.fr/2019AIXM0556.

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Dans un monde où les préoccupations environnementales sont de plus en plus présentes, il paraît primordial de mettre en place de nouvelles méthodologies de synthèse plus éco-compatibles. Cela constitue un moteur fondamental pour la conception de nouveaux objets moléculaires possédant des propriétés innovantes, conduisant à la conception de nouveaux matériaux, médicaments ou procédés chimiques. Dans la Nature, les polyols se révèlent comme étant des motifs essentiels pour expliquer l’activité biologique de nombreux produits naturels ou médicaments. Durant cette thèse, nous nous sommes attachés

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42

Hiscock, Jennifer R. "Binding anions using simple neutral molecules." Thesis, University of Southampton, 2010. https://eprints.soton.ac.uk/171157/.

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This thesis reports a number of novel neutral, hydrogen bond donating anion receptors and describes their anion coordination properties in both the solution and solid states. A set of ten urea/thiourea linked indole/carbazole groups were found to have high affinities for a variety of oxo-anions in highly competitive DMSO solutions. Of these receptors, the diindolylurea motif was found to be excellent for the binding of dihydrogen phosphate. This group of receptors were found to form 1:1 complexes in solution with various anions but more complex 2:1 and 3:1 receptor:anion complexes were observe

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43

Wenzel, Marco. "Tripodale Azaliganden - Ambivalente Rezeptoren für Kationen und Anionen." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2008. http://nbn-resolving.de/urn:nbn:de:bsz:14-ds-1210087455514-66575.

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Das Ziel der vorliegenden Arbeit bestand in der Synthese von neuen funktionalisierten tripodalen Azaliganden auf Basis von Tris(2-aminoethyl)amin (Tren) und ihrer Charakterisierung als Rezeptoren und Extraktionsmittel für Kationen, Anionen sowie Salze. Die Komplexbildungs- und Phasentransfereigenschaften gegenüber den Kationen Ag(I), Co(II), Ni(II), Cu(II), Zn(II) und Cd(II) sowie den Anionen Cl-, Br-, I-, H2PO4-, SO42- und HCrO4- wurden durch Flüssig-Flüssig-Extraktion und Flüssigmembrantransport, 1H-NMR-Spektroskopie sowie Silberpotentiometrie untersucht; Struktur-Wirkungsbeziehungen für die

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44

Todd, Adam Mitchell. "Binding and detection of anions using tripodal hosts." Thesis, Durham University, 2010. http://etheses.dur.ac.uk/329/.

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The aim of this project was to investigate the anion-binding properties of a range of different receptor compounds. For the most part, the receptors reported here were tripodal in nature, wherein three hydrogen-bonding receptor groups, including amines, amides and ureas, are linked around a common structural core. In this study, a range of different cores were chosen, such as simple and flexible organic frameworks based on the tris(2-aminoethyl)amine (tren) precursor, conformationally-restricted and brightly coloured aromatic species based on the dye pararosaniline, and triply-ligated metal co

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45

Camiolo, Salvatore. "Anions in supramolecular chemistry : binding, sensing and assembly." Thesis, University of Southampton, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252044.

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46

Hsuan, J. J. "Study of the oxidation of transferrin by periodate anions." Thesis, University of Bristol, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372042.

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47

Ayling, Alan J. "Steroidal electroneutral receptors for anions : synthesis and evaluation." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367663.

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48

Ilioudis, Christos. "Binding of inorganic anions by polyaza-macrocycles and macrobicycles." Thesis, King's College London (University of London), 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.410052.

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49

Grauwels, Glenn. "Physico-Chemical Characterisation of Chloride Transmembrane Transport using Calix[6]arene-based Receptors." Doctoral thesis, Universite Libre de Bruxelles, 2020. https://dipot.ulb.ac.be/dspace/bitstream/2013/311902/5/contratGG.pdf.

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The development of synthetic molecular receptors that can selectively bind anions, translocate them through a lipidic bilayer membrane and release them on the other side is a very topical and emerging field of supramolecular chemistry, warranted by the biological importance of transmembrane anion transport.The first part of this thesis is devoted to the study of the transmembrane transport of chloride and of the organic ion pair propylammonium chloride with calix[6]arene receptors functionalized with three (thio)urea arms on their small rim. The transport of chloride across the lipid bilayer o

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50

Wallace, Karl Jonathan. "Synthesis and binding studies of molecular podands for the recognition of anions." Thesis, King's College London (University of London), 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.406226.

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