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Journal articles on the topic 'Anion recognition'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Flood, Amar H. "Creating molecular macrocycles for anion recognition." Beilstein Journal of Organic Chemistry 12 (March 31, 2016): 611–27. http://dx.doi.org/10.3762/bjoc.12.60.

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The creation and functionality of new classes of macrocycles that are shape persistent and can bind anions is described. The genesis of triazolophane macrocycles emerges out of activity surrounding 1,2,3-triazoles made using click chemistry; and the same triazoles are responsible for anion capture. Mistakes made and lessons learnt in anion recognition provide deeper understanding that, together with theory, now provides for computer-aided receptor design. The lessons are acted upon in the creation of two new macrocycles. First, cyanostars are larger and like to capture large anions. Second is

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2

Yan, Liwei, Ankur Saha, Wei Zhao, et al. "Recognition competes with hydration in anion-triggered monolayer formation of cyanostar supra-amphiphiles at aqueous interfaces." Chemical Science 13, no. 15 (2022): 4283–94. http://dx.doi.org/10.1039/d2sc00986b.

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3

Martínez-Aguirre, Mayte A., Diego Martínez Otero, Magali L. Álvarez-Hernández, Teresa Torres-Blancas, Alejandro Dorazco-González, and Anatoly K. Yatsimirsky. "Anion and sugar recognition by 2,6-pyridinedicarboxamide bis-boronic acid derivatives." Heterocyclic Communications 23, no. 3 (2017): 171–80. http://dx.doi.org/10.1515/hc-2017-0054.

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AbstractTwo 2,6-pyridinedicarboxamide derivatives containing arylboronic acid fragments were prepared and fully characterized including X-ray crystal diffraction analysis of a pinacol ester. These compounds are potential bifunctional receptors for sugars and anions. Acid dissociation and stability constants for complexation of both receptors with glucose and fructose were determined by potentiometric titrations in aqueous DMSO. Also, binding of alizarin red S indicator was studied spectrophotometrically and a highly sensitive detection of fructose by an indicator displacement assay was propose

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4

González-Ruiz, Víctor, Ángel Cores, M. Mar Caja, et al. "Fluorescence Sensors Based on Hydroxycarbazole for the Determination of Neurodegeneration-Related Halide Anions." Biosensors 12, no. 3 (2022): 175. http://dx.doi.org/10.3390/bios12030175.

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The environmental presence of anions of natural origin or anthropogenic origin is gradually increasing. As a tool to tackle this problem, carbazole derivatives are an attractive gateway to the development of luminescent chemosensors. Considering the different mechanisms proposed for anion recognition, the fluorescence properties and anion-binding response of several newly synthesised carbazole derivatives were studied. Potential anion sensors were designed so that they combined the native fluorescence of carbazole with the presence of hydrogen bonding donor groups in critical positions for ani

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5

Brown, Asha, and Paul D. Beer. "Halogen bonding anion recognition." Chemical Communications 52, no. 56 (2016): 8645–58. http://dx.doi.org/10.1039/c6cc03638d.

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The development of solution-based anion receptor molecules which exploit halogen bonding interactions is an emerging area of research. This Feature Article reviews recent advances which have been made in this rapidly developing field, surveying the use of iodoperfluoroarene, haloimidazolium and halotriazole/triazolium halogen-bond-donor motifs in anion receptor design and describing the application of mechanically interlocked rotaxane and catenane frameworks as halogen bonding anion host systems.

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6

Rasheed, Safia, Mukhtiar Ahmed, Muhammad Faisal, and Muhammad Moazzam Naseer. "Isatin-3-thiosemicarbazone as Chromogenic Sensor for the Selective Detection of Fluoride Anion." Heterocyclic Communications 26, no. 1 (2020): 123–29. http://dx.doi.org/10.1515/hc-2020-0104.

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AbstractIn this study, we describe the anion recognition ability of isatin-3-thiosemicarbazone 2, which contains two different anion recognition units i.e. isatin NH and the thiourea moiety. Both have the ability to act as proton donors. Most importantly, a significant colour change of 2 was observed (from light yellow to reddish orange) in organic medium only after the addition of the F– anion. No such colour change could be observed for any other anions including Cl–, Br–, I–, ${{\text{H}}_{2}}\text{P}{{\text{O}}_{4}}^{-},$$\text{N}{{\text{O}}_{\text{2}}}^{-},$$\text{P}{{\text{F}}_{4}}^{-}$e

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7

Godoy-Alcántar, Carolina, Ismael León Rivera, and Anatoly K. Yatsimirsky. "Anion recognition by Thiostrepton." Bioorganic & Medicinal Chemistry Letters 11, no. 5 (2001): 651–54. http://dx.doi.org/10.1016/s0960-894x(01)00025-7.

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8

Kubik, Stefan. "Anion recognition in water." Chemical Society Reviews 39, no. 10 (2010): 3648. http://dx.doi.org/10.1039/b926166b.

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9

Keaveney, Claire M., and David A. Leigh. "Shuttling through Anion Recognition." Angewandte Chemie International Edition 43, no. 10 (2004): 1222–24. http://dx.doi.org/10.1002/anie.200353248.

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10

Keaveney, Claire M., and David A. Leigh. "Shuttling through Anion Recognition." Angewandte Chemie 116, no. 10 (2004): 1242–44. http://dx.doi.org/10.1002/ange.200353248.

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11

Deliomeroglu, Murat K., Vincent M. Lynch, and Jonathan L. Sessler. "Conformationally switchable non-cyclic tetrapyrrole receptors: synthesis of tetrakis(1H-pyrrole-2-carbaldehyde) derivatives and their anion binding properties." Chem. Commun. 50, no. 80 (2014): 11863–66. http://dx.doi.org/10.1039/c4cc05903d.

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12

Ke, Ya-Ting, Wei-Tzu Chou, Yi-Fen Chiang, Chang-Chih Hsieh, and Yih-Chern Horng. "Efficient and selective separation of aqueous sulfate through recognition and precipitation." New Journal of Chemistry 41, no. 6 (2017): 2249–54. http://dx.doi.org/10.1039/c6nj03710k.

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13

Sarada, Ganguri, Ahreum Kim, Dongwon Kim, and Ok-Sang Jung. "Diverse anion exchange of pliable [X2@Pd3L4]4+ double cages: a molecular ruler for recognition of polyatomic anions." Dalton Transactions 49, no. 19 (2020): 6183–90. http://dx.doi.org/10.1039/d0dt01027h.

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14

Miyaji, Hidekazu, Wataru Sato, Deqiang an, and Jonathan L. Sessler. "Optical Anion Sensors Based on Alkyne-Linked, Functionalized Calix[4]pyrroles." Collection of Czechoslovak Chemical Communications 69, no. 5 (2004): 1027–49. http://dx.doi.org/10.1135/cccc20041027.

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Linking a calix[4]pyrrole anion recognition subunit to chromophores or fluorophores via an alkynyl spacer attached to a β-pyrrolic position of a calix[4]pyrrole core produces a new class of anion sensor that permits the detection of halide and phosphate anions in organic media via direct, so-called "naked-eye" visualization or fluorescence quenching-based spectroscopic means.

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15

Badekar, Pooja S., and Anupa A. Kumbhar. "Anthracene-based fluorescence turn-on chemodosimeter for the recognition of persulfate anion." New Journal of Chemistry 42, no. 5 (2018): 3917–23. http://dx.doi.org/10.1039/c7nj03425c.

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16

Desfi, Annisa, Muhammad Zaky, Nessa Zarlita, Velly Effendy, Irfan Ananda Ismail, and Munadia Insani. "Anion Recoqnition Reactios." Journal of Global Research Education 2, no. 1 (2024): 22–26. https://doi.org/10.62194/cadrtm68.

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In the recognition of anions there are several anions that are tested so that we can recognize the anions. This praticum aims to be able to analyze various kinds of anions in a sample and write down the reaction. This praticum aims to be able to analyze various kinds of anions in a sample and write down the reaction. Analysis of this anion using the method of organoleptic methods Organoleptic properties are properties that can be measured by the senses, for example, taste, aroma, color, and so on There are several types of anions found in the samples tested. These finding implays indicate the

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17

Liu, Kai, Xiaojun Zhao, Qingxiang Liu, Jianzhong Huo, Bolin Zhu, and Shihua Diao. "Fluoride-driven ‘turn on’ ESPT in the binding with a novel benzimidazole-based sensor." Beilstein Journal of Organic Chemistry 11 (April 24, 2015): 563–67. http://dx.doi.org/10.3762/bjoc.11.61.

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A novel fluorescence sensor (BIP) bearing NH and OH subunits displayed a highly selective and sensitive recognition property for fluoride over other anions. Fluoride-driven ESPT, poorly used in anion recognition and sensing, was suggested to be responsible for the fluorescence enhancement with a blue shift of 35 nm in the emission spectrum.

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18

Qiao, Yan-Hong, Hai Lin, and Hua-Kuan Lin. "The recognition and sensing of anions by a novel phenanthroline-bridged diamide." Canadian Journal of Chemistry 84, no. 9 (2006): 1155–58. http://dx.doi.org/10.1139/v06-138.

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A novel neutral anion recognition receptor 1 with the additional capability of selectively sensing anionic guest species has been synthesized and examined for its anion-binding abilities by UV–vis absorption spectroscopy. The results of nonlinear curve fitting and Job plot indicate that 1 forms 1:1 stoichiometric complexes with fluoride, chloride, bromide, iodide, and acetate, respectively. Their UV–vis absorption spectra in DMSO indicate the presence of anions such as F –, Cl –, Br–, I–, and AcO– with high affinity ability and selectivity toward F –, and also show dramatic colour changes from

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19

Arabahmadi, Raziyeh, Masoumeh Orojloo, and Saeid Amani. "Azo Schiff bases as colorimetric and fluorescent sensors for recognition of F−, Cd2+ and Hg2+ ions." Anal. Methods 6, no. 18 (2014): 7384–93. http://dx.doi.org/10.1039/c4ay01564a.

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The optical and colorimetric sensing properties of H<sub>2</sub>L<sup>1</sup>–H<sub>2</sub>L<sup>3</sup> for anions were investigated by the naked eye and UV-Vis and fluorescence spectroscopy. The spectral change of H<sub>2</sub>L<sup>1</sup>–H<sub>2</sub>L<sup>3</sup> is due to the anion induced deprotonation and hence an increase in charge density and rigidity of the receptor molecule. The anion sensing abilities of the receptors toward halide anions were also monitored by electrochemical techniques.

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20

Kumar, Anjul, and Pramod S. Pandey. "Anion Recognition by 1,2,3-Triazolium Receptors: Application of Click Chemistry in Anion Recognition." Organic Letters 10, no. 2 (2008): 165–68. http://dx.doi.org/10.1021/ol702457w.

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21

Tisovský, Pavol, Miroslav Horváth, Klaudia Csicsai, et al. "Isatin-1,8-Naphthalimide Hydrazones: A Study of Their Sensor and ON/OFF Functionality." Molecules 24, no. 3 (2019): 397. http://dx.doi.org/10.3390/molecules24030397.

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Five novel hydrazones derived from substituted isatins were synthesized as potential anion sensors. Using UV-VIS, FTIR, NMR and fluorescence spectroscopy, these compounds’ tautomeric equilibrium and Z-E photoisomerization were studied in DMF and CHCl3, depending on the hydrazone concentrations, the presence of basic anions and light stimulation. Anion recognition aspects (PF6−, HSO4−, Br−, Cl−, NO3−, F− and CH3COO−) and these receptors’ detection limits were also studied. We also tested the light-stimulated ON-OFF functionality of these compounds in the presence or absence of these anions.

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22

Elmes, Robert B. P., and Katrina A. Jolliffe. "Anion recognition by cyclic peptides." Chemical Communications 51, no. 24 (2015): 4951–68. http://dx.doi.org/10.1039/c4cc10095f.

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Cyclic peptides provide excellent scaffolds for anion recognition and improved binding affinity and selectivity has been achieved through peptide backbone rigidification and the introduction of side chains bearing anion recognition groups.

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23

Rednic, Monica I., Richard A. Varga, Attila Bende та ін. "Supramolecular anion recognition by β-HCH". Chemical Communications 52, № 83 (2016): 12322–25. http://dx.doi.org/10.1039/c6cc06842a.

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24

Yuan, Dan, and Yuan Fang Li. "Carboxyphenyl-terpyridine-based series of gels for procedural visual recognition of multi-anions." Analytical Methods 10, no. 41 (2018): 5032–37. http://dx.doi.org/10.1039/c8ay01679h.

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The gelation of 4-[2,2′:6′,2′′-terpyridine]-4′-ylbenzoic acid (Hcptpy) occurred with various metal ions and specific anions. With the gel formation, corresponding metal ions and anions were recognized. Also, the metal–organic gels (MOGs) possess stimuli response property to anions. A step-by-step anion recognition progress was established based on one Hcptpy ligand and realized the selective identification 12 kinds of anions.

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25

Tanii, Saori. "Anion Recognition Using Chalcogen Bonding." Journal of Synthetic Organic Chemistry, Japan 78, no. 9 (2020): 894–95. http://dx.doi.org/10.5059/yukigoseikyokaishi.78.894.

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26

Busschaert, Nathalie, Claudia Caltagirone, Wim Van Rossom, and Philip A. Gale. "Applications of Supramolecular Anion Recognition." Chemical Reviews 115, no. 15 (2015): 8038–155. http://dx.doi.org/10.1021/acs.chemrev.5b00099.

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27

Amendola, V. "Anion recognition by dimetallic cryptates." Coordination Chemistry Reviews 219-221 (October 2001): 821–37. http://dx.doi.org/10.1016/s0010-8545(01)00368-x.

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28

Lücking, Ulrich, Dmitry M. Rudkevich, and Julius Rebek. "Deep cavitands for anion recognition." Tetrahedron Letters 41, no. 49 (2000): 9547–51. http://dx.doi.org/10.1016/s0040-4039(00)01688-9.

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29

Wenzel, Marco, and Jan J. Weigand. "Recent advances in anion recognition." Journal of Inclusion Phenomena and Macrocyclic Chemistry 89, no. 3-4 (2017): 247–51. http://dx.doi.org/10.1007/s10847-017-0756-y.

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30

Robson, Ryan N., Benjamin P. Hay, and Frederick M. Pfeffer. "Flexible “Arms” and Anion Recognition." ChemistrySelect 2, no. 17 (2017): 4605–8. http://dx.doi.org/10.1002/slct.201701041.

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31

Zaleskaya-Hernik, Marta, Łukasz Dobrzycki, Marcin Karbarz, and Jan Romański. "Fluorescence Recognition of Anions Using a Heteroditopic Receptor: Homogenous and Two-Phase Sensing." International Journal of Molecular Sciences 22, no. 24 (2021): 13396. http://dx.doi.org/10.3390/ijms222413396.

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In contrast to monotopic receptor 3, the anthracene functionalized squaramide dual-host receptor 1 is capable of selectively extracting sulfate salts, as was evidenced unambiguously by DOSY, mass spectrometry, fluorescent and ion chromatography measurements. The receptors were investigated in terms of anion and ion pair binding using the UV–vis and 1H NMR titrations method in acetonitrile. The reference anion receptor 3, lacking a crown ether unit, was found to lose the enhancement in anion binding induced by the presence of cations. Besides the ability to bind anions in an enhanced manner exh

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32

Isaac, Ibanga Okon, Iqra Munir, Mariya al-Rashida, et al. "Novel acridine-based thiosemicarbazones as ‘turn-on' chemosensors for selective recognition of fluoride anion: a spectroscopic and theoretical study." Royal Society Open Science 5, no. 7 (2018): 180646. http://dx.doi.org/10.1098/rsos.180646.

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New thiosemicarbazide-linked acridines 3a–c were prepared and investigated as chemosensors for the detection of biologically and environmentally important anions. The compounds 3a–c were found selective for fluoride (F − ) with no affinity for other anions, i.e. − OAc, Br − , I − , HSO 4 − , SO 4 2− , PO 4 3− , ClO 3 − , ClO 4 − , CN − and SCN − . Further, upon the gradual addition of a fluoride anion (F − ) source (tetrabutylammonium fluoride), a well-defined change in colour of the solution of probes 3a–c was observed. The anion-sensing process was studied in detail via UV–visible absorption

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33

Wang, Zong-Cheng, Ying-Zi Tan, Lin-Li Tang, and Fei Zeng. "Binaphthyl-Based Chiral Macrocyclic Hosts for the Selective Recognition of Iodide Anions." Molecules 28, no. 12 (2023): 4784. http://dx.doi.org/10.3390/molecules28124784.

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In this study, we explorethe synthesis of binaphthyl-based chiral macrocyclic hosts for the first time. They exhibited the selective recognition abilities of iodide anions which can be favored over those of other anions (AcO−, NO3−, ClO4−, HSO4−, Br−, PF6−, H2PO4−, BF4−, and CO3F3S−), as confirmed by UV-vis, HRMS, and 1H NMR spectroscopy experiments, as well as DFT calculations. Neutral aryl C–H···anion interactions play an important role in the formation complexes. The recognition process can be observed by the naked eye.

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34

Gilski, M., and M. Jaskólski. "Molecular recognition motifs in cytidinium and 2'-deoxycytidinium salts with composite anions." Acta Biochimica Polonica 45, no. 4 (1998): 917–28. http://dx.doi.org/10.18388/abp.1998_4350.

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In the crystal structures of N3-protonated cytidinium and 2'-deoxycytidinium salts with composite XYn anions capable of accepting hydrogen bonds through their Y atoms, the dominating motif of cytosinium...anion interactions consists of a pair of hydrogen bonds donated from the N3+ -H protonation site and from the exoamino N4-H41 group cis to N3, and accepted by two Y centers of one anion. This multipoint recognition pattern is stable and robust and thus can be classified as a supramolecular synthon. In a broader group of N3-protonated, N1-substituted cytosinium salts with composite anions it o

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35

Li, Sui Qin, Yan Zhi Liu, Yuan Cheng Zhu, and Ling Ling Lv. "Substituent Group Effete on the Geometric Configurations of the Acyclic Ruthenium Bipyridine Imidazole-Cyanide Anion Recognition Systems." Advanced Materials Research 1088 (February 2015): 322–26. http://dx.doi.org/10.4028/www.scientific.net/amr.1088.322.

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Substituent group effete; Cyanide anion; Anion recognition; Theoretical computationAbstract. In this paper, the cyanide anion recognition of the [Ru2(bpy)4(mbpibH2)]4+ (mbpibH2 is 1, 3-bis([1, 10]-phenanthroline-[5, 6-d]imidazol-2-yl)- benzene) functional molecular material host based on hydrogen bond weak interactions was discussed by using the quantum chemistry theory and method, the density function Becke, three-parameter, Lee-Yang-Parr, DFT/B3LYP/6-31G*//SDD computational level, especially discussed the geometry structure of the recognition system. The results showed that the substituent g

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36

Indrajit, Saha. "Alcoholic-OH in Anion Coordination Chemistry." International Journal for Research in Engineering Application & Management (IJREAM) 08, no. 10 (2023): 23–27. https://doi.org/10.35291/2454-9150.2023.0005.

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Anion Recognition using synthetic receptors is one of the central areas of research in contemporary supramolecular chemistry. To date, numerous receptors have been reported for the recognition and sensing of anionic substrates. Among the several anion-binding moieties, the alcoholic hydroxyl groups C-O-H is an important functional group in molecular recognition. In this mini-review, we cover the use of this group in development of synthetic anion receptors.

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37

Blackburn, Anna L., Naomi C. A. Baker, and Nicholas C. Fletcher. "New insights into dihydrogenphosphate recognition with dirhenium(i) tricarbonyl complexes bridged by a thiourea moiety." RSC Adv. 4, no. 35 (2014): 18442–52. http://dx.doi.org/10.1039/c4ra00912f.

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Three thiourea ligands and their dirhenium(i) complexes are reported that show an unusual cooperative binding to two dihydrogenphosphate anions; this could explain the high selectivity for phosphate in many reported anion receptors.

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38

Hirasawa, Manabu, Akihiro Orita, Tsubasa Mimuro, and Shin-ichi Kondo. "Unlocking the Use of LiCl as an Inexpensive Salt for Lithium-Ion Batteries with a Novel Anion Receptor." Materials 17, no. 13 (2024): 3244. http://dx.doi.org/10.3390/ma17133244.

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Lithium chloride (LiCl) is an inexpensive and environmentally friendly salt abundant in the ocean. However, the insolubility of LiCl in conventional electrolyte solvents prevents the practical use of LiCl for lithium-ion batteries. Here, we report a novel method to increase the solubility of LiCl in a conventional electrolyte. The solubility of LiCl in ethylene carbonate (EC)/dimethyl carbonate (DMC) (1/1, v/v) is about quadrupled by adding a small amount of anion receptor with two urea moieties as recognition sites connecting with an ether chain. Anion receptor is an organic molecule that can

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39

Rashid, Ambreen, Sahidul Mondal, and Pradyut Ghosh. "Development and Application of Ruthenium(II) and Iridium(III) Based Complexes for Anion Sensing." Molecules 28, no. 3 (2023): 1231. http://dx.doi.org/10.3390/molecules28031231.

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Improvements in the design of receptors for the detection and quantification of anions are desirable and ongoing in the field of anion chemistry, and remarkable progress has been made in this direction. In this regard, the development of luminescent chemosensors for sensing anions is an imperative and demanding sub-area in supramolecular chemistry. This decade, in particular, witnessed advancements in chemosensors based on ruthenium and iridium complexes for anion sensing by virtue of their modular synthesis and rich chemical and photophysical properties, such as visible excitation wavelength,

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40

Caballero, Antonio, Fabiola Zapata, Lidia González, Pedro Molina, Ibon Alkorta та José Elguero. "Discovery of anion–π interactions in the recognition mechanism of inorganic anions by 1,2,3-triazolium rings". Chem. Commun. 50, № 36 (2014): 4680–82. http://dx.doi.org/10.1039/c4cc00169a.

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41

Zheng, Wenxu, Ning-Bew Wong, and Anmin Tian. "Anion−Tri-s-triazine Bonding: A Case for Anion Recognition." Journal of Physical Chemistry A 109, no. 9 (2005): 1926–32. http://dx.doi.org/10.1021/jp045827k.

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42

Formica, Mauro, Vieri Fusi, Daniele Paderni, et al. "A Metal-Based Receptor for Selective Coordination and Fluorescent Sensing of Chloride." Molecules 26, no. 8 (2021): 2352. http://dx.doi.org/10.3390/molecules26082352.

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A scorpionate Zn2+ complex, constituted by a macrocyclic pyridinophane core attached to a pendant arm containing a fluorescent pyridyl-oxadiazole-phenyl unit (PyPD), has been shown to selectively recognize chloride anions, giving rise to changes in fluorescence emission that are clearly visible under a 365 nm UV lamp. This recognition event has been studied by means of absorption, fluorescence, and NMR spectroscopy, and it involves the intramolecular displacement of the PyPD unit by chloride anions. Moreover, since the chromophore is not removed from the system after the recognition event, the

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43

Snowden, Timothy S., and Eric V. Anslyn. "Anion recognition: synthetic receptors for anions and their application in sensors." Current Opinion in Chemical Biology 3, no. 6 (1999): 740–46. http://dx.doi.org/10.1016/s1367-5931(99)00034-4.

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44

Fuentes de Arriba, Ángel L., María G. Turiel, Luis Simón, et al. "Sulfonamide carbazole receptors for anion recognition." Organic & Biomolecular Chemistry 9, no. 24 (2011): 8321. http://dx.doi.org/10.1039/c1ob06126g.

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45

Cametti, Massimo, and Kari Rissanen. "Recognition and sensing of fluoride anion." Chemical Communications, no. 20 (2009): 2809. http://dx.doi.org/10.1039/b902069a.

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46

Wagner-Wysiecka, Ewa, and Natalia Łukasik. "Anion recognition by N,N′-diarylalkanediamides." Tetrahedron Letters 53, no. 45 (2012): 6029–34. http://dx.doi.org/10.1016/j.tetlet.2012.08.103.

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47

Shivanyuk, Alexander, Jan C. Friese, and Julius Rebek. "Anion dependent molecular recognition of cations." Tetrahedron 59, no. 35 (2003): 7067–70. http://dx.doi.org/10.1016/s0040-4020(03)00917-7.

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48

Cockroft, Scott L. "Screening Solvent Effects in Anion Recognition." Chem 3, no. 3 (2017): 383–84. http://dx.doi.org/10.1016/j.chempr.2017.08.008.

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49

Lim, Jason Y. C., and Paul D. Beer. "Sigma-Hole Interactions in Anion Recognition." Chem 4, no. 4 (2018): 731–83. http://dx.doi.org/10.1016/j.chempr.2018.02.022.

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50

Brown, Asha, and Paul D. Beer. "Porphyrin-functionalised rotaxanes for anion recognition." Dalton Trans. 41, no. 1 (2012): 118–29. http://dx.doi.org/10.1039/c1dt11372k.

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