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Dissertations / Theses on the topic 'Anion'

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1

Drumright, Ray E. "Radical anion rearrangements. aryl cyclopropyl ketyl anions." Diss., This resource online, 1991. http://scholar.lib.vt.edu/theses/available/etd-07282008-134853/.

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2

Sun, Zhanhu [Verfasser]. "Quinoline-based anion receptors and anion-pi interactions / Zhanhu Sun." Aachen : Hochschulbibliothek der Rheinisch-Westfälischen Technischen Hochschule Aachen, 2013. http://d-nb.info/1042551367/34.

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3

Wang, Zhiming 1958. "Anion Exchange and Competition in Layered Double Hydroxides." Thesis, University of North Texas, 1997. https://digital.library.unt.edu/ark:/67531/metadc332481/.

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Exchange reactions of anions, especially ferrocyanide and carbonate, with layered double hydroxides (LDHs) were investigated in relation to the origin of life on the early Earth. The effect on ferrocyanide exchange of concentration, pH, reaction time and cations are discussed. It was found that there were two different kinds of ferrocyanide species: one was that intercalated into the layered structure, occupying a site of D symmetry within the LDHs, while in the other, the ferrocyanide group retains full O symmetry. In addition, very low concentration, ferrocyanide associated with LDH will cha
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4

Andrews, Django H. "Anion photoelectron spectroscopy." Diss., Connect to online resource, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3239380.

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5

Wietek, Jonas. "Anion Conducting Channelrhodopsins." Doctoral thesis, Humboldt-Universität zu Berlin, 2018. http://dx.doi.org/10.18452/19325.

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Seit mehr als 10 Jahren kann biologische Aktivität durch eine Vielzahl photosensorischer Proteine beeinflusst werden. In diesem als Optogenetik bezeichneten Forschungsgebiet, werden Kationen leitende Kanalrhodopsine (CCRs) als lichtinduzierte neuronale Aktivatoren eingesetzt. Diese Arbeit soll zur Vervollständigung von optogenetischen Werkzeugen durch die Entwicklung Anionen leitender Kanalrhodopsine (ACRs) dienen, um die bestehenden Nachteile mikrobieller lichtgetriebener Ionenpumpen zu überwinden, die bislang zur neuronale Inhibition genutzt wurden. Der Austausch von E90 in C. reinhardtii K
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6

Calin, Nathalie. "Etude thermique de quelques sels d'hétéropolymolybdates : mise en évidence d'interactions anion-anion et anion-cation à l'état solide." Lille 1, 2001. https://pepite-depot.univ-lille.fr/LIBRE/Th_Num/2001/50376-2001-119.pdf.

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Les polyoxométallates et plus particulièrement les hétéropolymolybdates sont des composés très recherchés en catalyse, homogène ou hétérogène. A l'état solide, leur comportement réactif dépend de nombreux paramètres dont la nature des contre-ions présents, le type de molécules de solvatation, le système cristallin et leur evolution thermique. Plusieurs sels (sodium, potassium, alkyl(aryl)ammonium) des ions dodécamolybdophosphate (3-), vanadoundécamolybdophosphate (4-) et de structures apparentées (octadécamolybdophosphate (6-)) ont été préparés. Ils ont été étudiés en solution par polarographi
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7

Ferguson, Richard. "Fluorescent Anion Sensing and Anion Templated Assembly of Interpenetrated Molecular Architectures." Thesis, University of Oxford, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.491446.

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The main aim: of this project is to develop novel acyclic and macrocyclic hosts for the binding and fluorescent sensing of anionic guests in solution. In addition the use of these hosts in anion templated interpenetrated architectures was exploited. Chapter One introduces the field of supramolecular chemistry and gives a brief description of the non-covalent forces employed in supramolecular host design. A description of the areas of anion binding and the more sophisticated discipline of anion sensing is given. The Chapter concludes with a discussion of the phenomenon of selfassembly and in pa
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8

Sekizaki, Shuichi. "Development of conducting cation radical salts with flexible organic anions : tetracyanoallyl anion derivatives." 京都大学 (Kyoto University), 2006. http://hdl.handle.net/2433/144214.

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9

Zain, S. A. M. "Novel inorganic anion exchangers." Thesis, University of Salford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234769.

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10

Swinburne, Adam Neil. "Induced-fit anion sensing." Thesis, Durham University, 2011. http://etheses.dur.ac.uk/579/.

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Anions have many important roles in biological systems, as well as in the environment and as such there is significant interest in their binding and sensing. In induced-fit anion sensing, the binding of an anion causes a shift in the equilibrium of conformers of the molecule, which in turn may lead to a change in a physical property. In this thesis four experimental chapters describe the synthesis and anion sensing properties of a series of induced-fit anion sensors derived from a hexa-substituted triethylbenzene and diphenylacetylene motif. Chapter one provides an introduction to anion recogn
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11

Sergeant, Genevieve. "Applications of Anion Binding." Thesis, The University of Sydney, 2022. https://hdl.handle.net/2123/28497.

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This thesis describes the development and exploration of chemosensing systems for phosphates and their applications to specific biological challenges. Investigation of the sensing abilities of a peptide-based bis-Zn(DPA) chemosensor, is detailed. Building on existing research aimed at developing selective sensors of phosphate species (PPi, ADP and ATP), the properties of this sensor were thoroughly investigated in a variety of buffered aqueous systems. The chemosensor exhibited a large, selective, turn on in emission in the presence of pyrophosphate but this response was modulated by additiv
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12

Gillmore, Jason G. Jr. "Evaluation of 1,1-Dimethyl-5,7-Di-T-Butylspiro[2.5]Octa-4,7-Dien-6-One as a Mechanistic Probe for Single Electron Transfer." Thesis, Virginia Tech, 1998. http://hdl.handle.net/10919/36888.

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<p> Single electron transfer (SET) mechanisms are becoming ubiquitous in modern organic chemistry. However, it is often difficult to distinguish SET mechanisms from polar mechanisms. Kinetics, products and product distributions, and response to perturbation in solvent and substituents are often identical between the two mechanisms. Detection techniques such as EPR, CIDNP, and UV absorption can often detect "blind" pathways and thus cannot provide unambiguous evidence regarding the true mechanism of interest. In recent years mechanistic probes have been developed which can test for si
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13

Busschaert, Nathalie. "Structure-activity relationships in novel small-molecule anion receptors and transmembrane anion transporters." Thesis, University of Southampton, 2014. https://eprints.soton.ac.uk/367100/.

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14

Wells, Debra J. "Extraction of the perrhenate and pertechnetate anions from aqueous solutions using inorganic anion exchangers." Thesis, University of Reading, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.306851.

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15

Brooks, Simon James. "From linear to cyclic anion receptors : high affinity receptors and sensors for oxo-anions." Thesis, University of Southampton, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438694.

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16

Bradbury, Adam John, and babradbury@optusnet com au. "METAL ION ACTIVATED ANION SENSORS." Flinders University. School of Chemistry Physics and Earth Sciences, 2007. http://catalogue.flinders.edu.au./local/adt/public/adt-SFU20080319.125059.

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A series of new, octadentate, fluorescent, macrocyclic ligands have been prepared with a view to using them to study aromatic anion sequestration. The eight-coordinate Cd(II) complexes of the ligands have been shown capable of acting as receptors for a range of aromatic oxoanions. This has been demonstrated by perturbation of both 1H NMR chemical shift values and the anthracene derived fluorescence emission intensity as the potential guest anion and the host are combined. Non-linear least squares regression analysis of the resulting titration curves leads to the determination of binding consta
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17

Atkinson, Paul. "Chemoselective phospho-anion binding studies." Thesis, Durham University, 2005. http://etheses.dur.ac.uk/2804/.

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An investigation has been carried out, studying the interaction of various bioactive anions, particularly phosphorylated species, with well-defined chiral lanthanide complexes. In each ternary anion adduct, proton NMR analysis revealed a distinctive pattern for the most high frequency shifted resonances. Furthermore, the mean chemical shift of these four resonances can be used to identify the anion adducts present in solution and indicate the binding mode exhibited towards the lanthanide(III) centre. Similar differentiation of anion binding modes is also available from luminescence spectroscop
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18

McGinnes, D. F. "Anion exchangers for radioisotope storage." Thesis, University of Salford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381727.

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19

OLIVARI, MARTINA. "Neutral receptors for anion recognition: synthesis, selectivity studies and transport properties." Doctoral thesis, Università degli Studi di Cagliari, 2014. http://hdl.handle.net/11584/266429.

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This thesis reports the synthesis and studies of a new series of compounds containing urea groups that can function as selective anion receptors and efficient anion transmembrane transporters. Two new asymmetric ureidic receptors L1 (1-(1H-indol-7-yl)-3- (quinolin-2-yl)urea) and L2 (1-(quinolin-2-yl)-3-(quinolin-8-yl)urea), shown in Figure 1, have been synthesised and their affinity towards different anions tested in DMSO-d6. L1 adopts both in solution and in the solid state an (E,Z) conformation. A moderate affinity for acetate has been observed with L1 while no interaction has been observed
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20

Spooner, Michael. "Anions and the bilayer : structural and mechanistic studies towards synthetic anion carriers for therapeutic applications." Thesis, University of Southampton, 2017. https://eprints.soton.ac.uk/410302/.

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Synthetic transmembrane anion transporters have attracted a great deal of interest due to their potential as therapeutic agents for the treatment of channelopathies such as cystic fibrosis or in the treatment of cancer. Despite a great deal of progress in the field over recent years, there are currently several hurdles that need to be overcome before anionophores become genuine therapeutic candidates. These include knowledge of how carriers behave in more cell-like bilayer systems, what molecular properties govern the rate determining step of the transport process and issues with solubility an
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21

Jones, Graham K. "Expression and anion transport studies on the human erythrocyte anion exchange protein (AE1, band 3)." Thesis, University of Bristol, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.245676.

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22

Butson, Jeffery M. "Electron Transfer and Other Reactions Using Atomic Metal Anions." Thèse, Université d'Ottawa / University of Ottawa, 2014. http://hdl.handle.net/10393/30561.

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The atomic metal anions Rb-, Cs-, Cu-, Ag- and Fe- have been generated in the gas phase and reacted with various neutral reactants in a triple quadrupole mass spectrometer. The metal anions were formed via electrospray ionization of the metal-oxalate solutions and form in gas phase between the capillary and the first quadrupole. Neutral gas phase reactants investigated include NO, NO2, SO2, C6F5OH, C6F5NH2, C6F6, E-octafluoro-butene and 1,2,3/1,2,4/1,3,5 trifluoro-benzene. When possible, CBS-4M methods were used to suggest the lowest energy products based on relative energy. Observed reactions
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23

Brown, Terence D. "Anion exchange at the interfaces of mixed anion III-V heterostructures grown by molecular beam epitaxy." Diss., Available online, Georgia Institute of Technology, 2003:, 2003. http://etd.gatech.edu/theses/available/etd-11182003-014419/unrestricted/brownterenced200312phd.pdf.

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Thesis (Ph. D.)--Electrical and Computer Engineering, Georgia Institute of Technology, 2004.<br>May, Gary, Committee Chair; Doolittle, William, Committee Member; Brown, April, Committee Member; Wang, Zhong Lin, Committee Member; Ralph, Stephen, Committee Member. Includes bibliography.
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24

Jagessar, Raymond C. "Anion recognition by novel functionalised porphyrins." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363767.

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25

Goulden, Alistair John. "Anion recognition by novel calixarene receptors." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240479.

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26

Parsons, Thomas. "The anion chemistry of manganese perovskites." Thesis, University of Oxford, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.497068.

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27

Lloyd, Gareth Owen. "Anion-tuning of supramolecular gel properties." Thesis, Durham University, 2010. http://etheses.dur.ac.uk/186/.

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Low molecular weight gelators (LMWGs) are a class of compounds that has garnered great interest from material, synthetic, supramolecular and biological chemists. Anion tuning of these supramolecular gels is a burgeoning field of study. Two classes of compounds, chiral bisureas and urea derivatised pyrazoles are studied. The synthesized chiral bisurea compounds act as gelators in a variety of solvents. Addition of anions in the form of tetrabutyl ammonium salts was found to afford break up of the gels. Studies reveal that the rheological characteristics of these materials can be tuned using the
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28

Burns, Barry. "Palladium catalysed cyclisation anion capture process." Thesis, Queen's University Belfast, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334562.

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29

Watson, James David. "Anion and cation binding in proteins." Thesis, University of Glasgow, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252533.

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30

Murray, Ernest Jonathan. "Metalloporphyrins as hosts for anion transport." Thesis, University of Liverpool, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263898.

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31

Nowosielski, Andrzej. "Alternative regimes for anion exchange denitrification." Thesis, Cranfield University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.352928.

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32

Wilson, Thomas Charles. "Coordination chemistry of the pentacyanocyclopentadienide anion." Thesis, University of Cambridge, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.708033.

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33

Sullivan, Eirin Courtney. "Anion manipulation in perovskite-related materials." Thesis, University of Birmingham, 2009. http://etheses.bham.ac.uk//id/eprint/484/.

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Sr\(_2\)Co\(_2\)O\(_5\) with the perovskite-related brownmillerite structure has been synthesised via quenching, with the orthorhombic unit cell parameters \(a\) = 5.4639(3) Å, \(b\) = 15.6486(8) Å and \(c\) = 5.5667(3) Å based on refinement of NPD data collected at 4K. Electron microscopy revealed L R L R intralayer ordering of chain orientations which requires a doubling of the unit cell along the \(c\) parameter, consistent with the assignment of the space group \(Pcmb\). However, on the length scale pertinent to NPD, no long-range order is observed and the disordered space group \(Imma\) a
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34

Hewett, David R. "Mixed anion amides for hydrogen storage." Thesis, University of Birmingham, 2012. http://etheses.bham.ac.uk//id/eprint/3696/.

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Metal hydride materials have attracted much interest for their potential use as hydrogen storage materials. Complex hydrides are amongst the most promising due to their high gravimetric storage capacities and favourable de/rehydrogenation conditions. Here, mixed anion complex hydrides are investigated both through halide doping of LiNH\(_2\) and Li\(_2\)NH, and though a mixed LiNH\(_2\)-LiBH\(_4\) system. The reaction of LiNH\(_2\) and Li\(_2\)NH with lithium or magnesium chloride, bromide and iodide has been shown to form a series of amide- and imide-halide phases. The structures of these pha
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35

Kilo, Martin, and Thomas Bredow. "Modelling of anion transport in YZrON." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-195357.

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36

Wang, Yizhou. "Regulation of guard cell anion channels." Thesis, University of Glasgow, 2013. http://theses.gla.ac.uk/3859/.

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Stomata account for much of the 70% of global water usage associated with agriculture, and have a profound impact on the water and carbon cycles of the world. Anion channels at the plasma membrane of the guard cell are thought to comprise a major pathway for anion efflux essential for driving stomatal closure. The activity of these channels is therefore tightly linked to abscisic acid (ABA)-dependent stomatal movements. Both the inorganic anion Cl- and the organic acid anion malate (Mal) are transported during stomatal movements. The metabolism of organic acids, primarily Mal plays an especial
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37

Paver, Michael A. "Novel p-block metal anion complexes." Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/271941.

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38

Kilo, Martin, and Thomas Bredow. "Modelling of anion transport in YZrON." Diffusion fundamentals 2 (2005) 22, S. 1-2, 2005. https://ul.qucosa.de/id/qucosa%3A14352.

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39

Kafy, Ahmed M. L. A. E. "Interactions between oligoamines and superoxide anion." Thesis, Aston University, 1987. http://publications.aston.ac.uk/12556/.

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1- Oligoamines and EDTA inhibited the reduction of cytochrome-C and nitrobule tetrazolium (NBT) induced by the hypoxanthine/xanthine oxidase superoxide anion generating system in the following order of effectiveness: putrescine > diaminopropane > spermidine > EDTA > spermine > cadaverine. 2- Oligoamines and EDTA did not affect the rate of urate formation from the hypoxanthine/xanthine oxidase system. 3- Oligoamines and EDTA inhibited the reduction of cytochrome-C induced by stimulated PMNL's in the same order of effectiveness as mentioned before. 4- Oligoamines and EDTA inhibited luminol depen
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40

Smyth, Megan Rebecca. "Chiral hosts for enantioselective anion recognition." Thesis, Queen's University Belfast, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.709822.

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This research thesis considers the synthesis of a novel library of symmetrical and unsymmetrical 2,2-bipyridine ligands containing both amide functionality and chirality. These ligands were then used to develop either a labile system containing iron(II) or an inert system comprised of ruthenium(II) complexes. The inclusion of chirality in the bipyridine ligand, from the synthesis with a chiral amine, resulted in a diastereomeric excess in the resulting metal complexes, observable using circular dichroism spectroscopy. Further enhancement of this diastereomeric excess was observed in the presen
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41

Qin, Lei. "Squaramide-based Receptors for Anion Recognition." Thesis, The University of Sydney, 2017. http://hdl.handle.net/2123/17808.

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A series of squaramide based receptors bearing benzene and pyridine linkers was developed, ranging from simple alkyl-substituted mono-squaramides to macrocyclic tri-squaramides by altering the number of squaramide binding sites, adjusting the geometries of compounds and appending different solubilizing groups. These receptors were studied via host-guest 1H NMR titrations with a range of anions in DMSO-d6 and water. In this work, the successful trial of aqueous soluble, macrocyclic squaramide receptors (MSQs) were synthesized that bind sulfate with high affinity and selectivity over other tetra
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42

TOSOLINI, MASSIMO. "Transition Metal Complexes as Anion Carriers." Doctoral thesis, Università degli Studi di Trieste, 2019. http://hdl.handle.net/11368/2962375.

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La regolazione del trasporto del cloruro attraverso le membrane biologiche è un processo fondamentale coinvolto in molte vie metaboliche, il cui squilibrio porta a gravi malattie genetiche come la fibrosi cistica. In Natura, il trasporto del cloruro è regolato da complesse proteine di membrana, tuttavia esistono anche alcuni esempi di piccole molecole che fungono da trasportatori di anioni. I trasportatori di cloruro hanno mostrato attività biologiche interessanti (ad esempio antitumorale ed antibiotica) e ne è stato proposto l’utilizzo nella terapia di sostituzione dei canali del cloruro per
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43

Groenewald, Ferdinand George. "Computational study of anion-anion intermolecular interactions between I3-ions in the gas phase, solution and solid state." Thesis, Stellenbosch : Stellenbosch University, 2012. http://hdl.handle.net/10019.1/71786.

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44

Lane, Jakob. "Dual Hydrogen Bond Donors for Anion Recognition." Thesis, The University of Sydney, 2021. https://hdl.handle.net/2123/27262.

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Anions are important in many biological and chemical processes, therefore the development of receptors for binding, sensing and extraction is necessary for a range of potential applications, including in medicine and the environment. This thesis details both the development of novel dual hydrogen bonding receptors for anions, and work towards anion sensing and extraction using dual hydrogen bonding motifs. Chapter 2 describes the synthesis and anion binding investigations into the dual hydrogen bond donating motifs diaminomethylenemalononitriles and diaminomethyleneindanediones. Two novel ser
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45

Cook, Gabriel Allen. "Structural studies of anion channel forming peptides /." Search for this dissertation online, 2005. http://wwwlib.umi.com/cr/ksu/main.

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46

Crowhurst, Karin Ann. "Refurbishing alamethicin, a path to anion selectivity." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq29222.pdf.

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47

Cormode, David. "Porphyrin and gold surface based anion receptors." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432558.

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48

Tiwari, Laxmikant. "Design and synthesis of novel anion receptors." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312677.

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49

Rutt, Oliver J. "The synthesis of novel mixed anion solids." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442960.

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50

Kingston, Justine E. "Redox-active host molecules for anion recognition." Thesis, University of Oxford, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.320669.

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