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Journal articles on the topic 'Anionic copolymerization'

Author: Grafiati

Published: 18 July 2021

Last updated: 11 February 2022

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1

Vlček, P., D. Doskočilová, and J. Trekoval. "Anionic copolymerization of methacrylates." Journal of Polymer Science: Polymer Symposia 42, no. 1 (March 8, 2007): 231–38. http://dx.doi.org/10.1002/polc.5070420125.

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2

Quirk, Roderic P., and Rajeev Bhatia. "Alkyllithium-Initiated Polymerization of Trans-1,3,5-Hexatriene and Copolymerization with Styrene." Rubber Chemistry and Technology 62, no. 2 (May 1, 1989): 332–42. http://dx.doi.org/10.5254/1.3536248.

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Abstract The results reported herein established the complexity of the alkyllithium-initiated anionic homopolymerization, styrene copolymerization and styrene block copolymerization of 1,3,5-hexatriene in comparison to the controlled, predictable behavior observed with dienes. As a result of 1,6- and 1,2-enchainment, conjugated diene units are formed along the polymer backbone which can react with the living carbanionic centers to produce branched polymers as indicated in Equation (1). The general effect of solvent on microstructure, as indicated by infrared spectral analyses, is analogous to that of dienes in that 1,2-addition is increased in polar versus hydrocarbon solvents. The observation of branching reactions suggests that conjugated trienes may be useful as branching agents for copolymerizations or linking reactions analogous to the behavior of divinylbenzenes.

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3

Wręczycki, Jakub, Dariusz M. Bieliński, Marcin Kozanecki, Paulina Maczugowska, and Grzegorz Mlostoń. "Anionic Copolymerization of Styrene Sulfide with Elemental Sulfur (S8)." Materials 13, no. 11 (June 7, 2020): 2597. http://dx.doi.org/10.3390/ma13112597.

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The superior ability of thiiranes (episulfides) to undergo ring-opening polymerization (ROP) in the presence of anionic initiators allows the preparation of chemically stable polysulfide homopolymers. Incorporation of elemental sulfur (S8) by copolymerization below the floor temperature of S8 permits the placement of a large quantity of sulfur atoms in the polysulfide mainchain. The utility of styrene sulfide (2-phenylthiirane; StS) for copolymerization with elemental sulfur is reported here. A few polysulfides differing depending on the initial ratio of S8 to StS and copolymerization time were synthesized. Various spectroscopic methods (1H NMR, 13C NMR, Raman spectroscopy and FTIR spectroscopy) were applied to characterize the chemical structure of the copolymers. Additionally, the phase structure and thermal stability of the synthesized polysulfides were investigated using DSC and TGA, respectively. The successful anionic copolymerization of styrene sulfide and elemental sulfur has been demonstrated.

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4

Narita, Tadashi, Tokio Hagiwara, Hiroshi Hamana, Koichi Iwaki, Tsuyoshi Uchida, Takashi Yasumura, and Kazuhiko Maeda. "Anionic copolymerization of hexafluoroacetone with epoxides." Journal of Fluorine Chemistry 59, no. 1 (October 1992): 133–39. http://dx.doi.org/10.1016/s0022-1139(00)80211-0.

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5

Bouquey, Michel, and Alain Soum. "Anionic Ring-Opening Copolymerization of Cyclodisilazanes." Macromolecular Chemistry and Physics 202, no. 7 (April 1, 2001): 1232–38. http://dx.doi.org/10.1002/1521-3935(20010401)202:7<1232::aid-macp1232>3.0.co;2-v.

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6

Ying, Shengkang. "Some aspects of anionic butadiene copolymerization." Macromolecular Symposia 85, no. 1 (August 1994): 251–66. http://dx.doi.org/10.1002/masy.19940850119.

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7

Budín, Jan, Jan Roda, Jiří Brožek, and Jaroslav Kříř. "Anionic Copolymerization ofɛ-Caprolactam withω-Laurolactam." Macromolecular Symposia 240, no. 1 (July 2006): 78–82. http://dx.doi.org/10.1002/masy.200650810.

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8

Valter, Bohumír, M. I. Terekhova, E. S. Petrov, Jaroslav Stehlíček, and Jan Šebenda. "The equilibrium acidity of cyclic and linear amides and its effect on the anionic polymerization of lactams." Collection of Czechoslovak Chemical Communications 50, no. 4 (1985): 834–39. http://dx.doi.org/10.1135/cccc19850834.

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The equilibrium acidity of lactams with rings of various size and of linear N-substituted amides was measured in dimethyl sulfoxide by the spectrophotometric method. The pK values of these NH-acids thus determined varied in the range 22-27. The data are used to characterize the acidobasic equilibrium between the amide groups of the monomer, polymer and their N-anions during the anionic polymerization of lactams. The effect of acidity on the anionic copolymerization of lactams is also discussed.

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9

Nishimura, Shin, Akira Nagai, Akio Takahashi, and Tadashi Narita. "Anionic copolymerization of 2,3,4,5,6-pentafluorostyrene and divinylbenzene." Journal of Polymer Science Part A: Polymer Chemistry 31, no. 1 (January 1993): 135–39. http://dx.doi.org/10.1002/pola.1993.080310116.

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10

Mateva, R., R. Filyanova, R. Velichkova, and V. Gancheva. "Anionic copolymerization of hexanelactam with functionalized polyisoprene." Journal of Polymer Science Part A: Polymer Chemistry 41, no. 4 (January 16, 2003): 487–96. http://dx.doi.org/10.1002/pola.10599.

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11

Lapena, A., J. L. Mateo, and R. Sastre. "Anionic copolymerization of acrolein with aldehydes. III." Journal of Polymer Science: Polymer Symposia 42, no. 1 (March 8, 2007): 311–19. http://dx.doi.org/10.1002/polc.5070420133.

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12

Nuyken, Oskar, Volker Burkhardt, and Christian Hübsch. "Anionic homo- and block copolymerization of vinylferrocene." Macromolecular Chemistry and Physics 198, no. 11 (November 1997): 3353–63. http://dx.doi.org/10.1002/macp.1997.021981102.

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13

Roos, Kévin, Elena Dolci, Stéphane Carlotti, and Sylvain Caillol. "Activated anionic ring-opening polymerization for the synthesis of reversibly cross-linkable poly(propylene oxide) based on furan/maleimide chemistry." Polymer Chemistry 7, no. 8 (2016): 1612–22. http://dx.doi.org/10.1039/c5py01778e.

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14

Fuchs, Dominik A. H., Hanna Hübner, Tobias Kraus, Bart-Jan Niebuur, Markus Gallei, Holger Frey, and Axel H. E. Müller. "The effect of THF and the chelating modifier DTHFP on the copolymerisation of β-myrcene and styrene: kinetics, microstructures, morphologies, and mechanical properties." Polymer Chemistry 12, no. 32 (2021): 4632–42. http://dx.doi.org/10.1039/d1py00791b.

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15

Wu, Zhichao, Pei Liu, Yu Liu, Wei Wei, Xinlin Zhang, Ping Wang, Zhenli Xu, and Huiming Xiong. "Regulating sequence distribution of polyethers via ab initio kinetics control in anionic copolymerization." Polymer Chemistry 8, no. 37 (2017): 5673–78. http://dx.doi.org/10.1039/c7py01073g.

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16

Li, Zheng, Jianding Chen, Ling Su, Bin Zou, Pengfei Zhan, Yong Guan, and Anna Zheng. "A controlled synthesis method of polystyrene-b-polyisoprene-b-poly(methyl methacrylate) copolymer via anionic polymerization with trace amounts of THF having potential of a commercial scale." RSC Advances 7, no. 16 (2017): 9933–40. http://dx.doi.org/10.1039/c6ra25155b.

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17

Tausendfreund, I., F. Bandermann, H. W. Siesler, and M. Kleimann. "Anionic dispersion copolymerization of styrene and 1,3-butadiene." Polymer 43, no. 25 (January 2002): 7085–91. http://dx.doi.org/10.1016/s0032-3861(02)00448-2.

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18

Shragin, D. I., V. M. Kopylov, P. V. Ivanov, and I. B. Sokol’skaya. "Anionic copolymerization of α,ω-dihydroxyoligodimethylsiloxane with organocyclosiloxanes." Polymer Science Series A 50, no. 1 (January 2008): 31–36. http://dx.doi.org/10.1134/s0965545x08010069.

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19

NARITA, T., T. HAGIWARA, H. HAMANA, K. IWAKI, T. UCHIDA, T. YASUMURA, and K. MAEDA. "ChemInform Abstract: Anionic Copolymerization of Hexafluoroacetone with Epoxides." ChemInform 24, no. 30 (August 20, 2010): no. http://dx.doi.org/10.1002/chin.199330300.

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20

Mannebach, Gerd, and Axel H. E. Müller. "Anionic Copolymerization of 5-(N,N-Dialkylamino)isoprenes." Macromolecular Chemistry and Physics 205, no. 6 (April 2004): 731–36. http://dx.doi.org/10.1002/macp.200300245.

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21

Zhang, Qilu, and Richard Hoogenboom. "UCST behavior of polyampholytes based on stoichiometric RAFT copolymerization of cationic and anionic monomers." Chemical Communications 51, no. 1 (2015): 70–73. http://dx.doi.org/10.1039/c4cc07930b.

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Polyampholytes with controlled equimolar ratio of charges were synthesized by reversible addition–fragmentation chain transfer (RAFT) copolymerization of cationic and anionic monomers and their UCST behavior is reported.

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22

Sang, Wei, Hongwei Ma, Qiuyun Wang, Xinyu Hao, Yubin Zheng, Yurong Wang, and Yang Li. "Monomer sequence determination in the living anionic copolymerization of styrene and asymmetric bi-functionalized 1,1-diphenylethylene derivatives." Polymer Chemistry 7, no. 1 (2016): 219–34. http://dx.doi.org/10.1039/c5py01562f.

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In-chain functionalized polystyrenes with different sequential arrangements of functional groups are preparedvialiving anionic copolymerization. The sequence structures are determined by time sampling to establish the sequence-determination method.

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23

Müller, S. S., T. Fritz, M. Gimnich, M. Worm, M. Helm, and H. Frey. "Biodegradable hyperbranched polyether-lipids with in-chain pH-sensitive linkages." Polymer Chemistry 7, no. 40 (2016): 6257–68. http://dx.doi.org/10.1039/c6py01308b.

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Hyperbranched polyether-based lipids with cleavable acetal units were obtained via copolymerization of the epoxide inimer 1-(glycidyloxy)ethyl ethylene glycol ether (GEGE) and glycidol, using anionic ring-opening polymerization.

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24

Liang, Siwei, Jingyi Tang, Shun Yao, and Weixia Zhu. "Removal characteristics of two anionic dyes by a polyethylenimine/poly(N,N-dimethylaminoethyl methacrylate) gel." RSC Advances 9, no. 40 (2019): 22907–20. http://dx.doi.org/10.1039/c9ra04641k.

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The highly efficient gel obtained via the copolymerization of polyethylenimine and poly(N,N-dimethylaminoethyl methacrylate) was successfully applied to remove two anionic dyes (amaranth and sunset yellow) from their aqueous solutions.

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25

Grune, Eduard, Jennifer Bareuther, Jan Blankenburg, Michael Appold, Lloyd Shaw, Axel H. E. Müller, George Floudas, Lian R. Hutchings, Markus Gallei, and Holger Frey. "Towards bio-based tapered block copolymers: the behaviour of myrcene in the statistical anionic copolymerisation." Polymer Chemistry 10, no. 10 (2019): 1213–20. http://dx.doi.org/10.1039/c8py01711e.

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The monoterpene myrcene is a bio-based diene monomer. The statistical, living anionic copolymerization with isoprene, styrene and 4-methylstyrene leads to gradient or tapered block copolymers, studied by in-situ NMR, SAXS and TEM.

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26

Gervais, Matthieu, Antoine Forens, Emmanuel Ibarboure, and Stephane Carlotti. "Anionic polymerization of activated oxetane and its copolymerization with ethylene oxide for the synthesis of amphiphilic block copolymers." Polymer Chemistry 9, no. 19 (2018): 2660–68. http://dx.doi.org/10.1039/c8py00307f.

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The anionic polymerization of oxetane in toluene was achieved using a combination of tetraoctylammonium bromide and simple triisobutylaluminum. By its copolymerization with ethylene oxide, di- and triblock copolymers were prepared in one and two steps respectively.

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27

Amri, Hilmi, Mohamed Naceur Belgacem, and Alessandro Gandini. "2-Furyloxirane: 1. Anionic and coordination homo- and copolymerization." Polymer 37, no. 21 (October 1996): 4815–21. http://dx.doi.org/10.1016/s0032-3861(96)00310-2.

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28

Börner, Hans G., and Walter Heitz. "Anionic block copolymerization of vinyl functionalized triphenylphosphines with styrene." Macromolecular Chemistry and Physics 201, no. 6 (March 1, 2000): 740–46. http://dx.doi.org/10.1002/(sici)1521-3935(20000301)201:6<740::aid-macp740>3.0.co;2-d.

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29

Mohammadi, Mohammad, Shervin Ahmadi, Ismail Ghasemi, and Mohammadreza Rahnama. "Anionic copolymerization of nylon 6/12: A comprehensive review." Polymer Engineering & Science 59, no. 8 (July 2019): 1529–43. http://dx.doi.org/10.1002/pen.25171.

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30

Eschwey, Helmut, and Walther Burchard. "Conditions of gelation in the anionic divinylbenzene-styrene copolymerization." Journal of Polymer Science: Polymer Symposia 53, no. 1 (March 8, 2007): 1–9. http://dx.doi.org/10.1002/polc.5070530104.

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31

FLORJANCZYK, ZBIGNIEW, ANNA KOZERA-SZALKOWSKA, EWA ZYGADLO-MONIKOWSKA, and IZABELA LACH. "SO2-catalyzed anionic copolymerization of oxiranes with cyclic anhydrides." Polimery 45, no. 07/08 (July 2000): 475–84. http://dx.doi.org/10.14314/polimery.2000.475.

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32

Arnold, Manfred, Willy Frank, and G�nther Reinhold. "Anionic copolymerization of butadiene and styryl-terminated polystyrene macromonomers." Polymer Bulletin 24, no. 1 (July 1990): 1–7. http://dx.doi.org/10.1007/bf00298314.

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33

Yu, Jian Ming, Dominique Teyssié, Riadh Ben Khalifa, and Sylvie Boileau. "Anionic polymerization and copolymerization of cyclosiloxanes initiated by trimethylsilylmethyllithium." Polymer Bulletin 32, no. 1 (January 1994): 35–40. http://dx.doi.org/10.1007/bf00297411.

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34

Zhdanov, A. A., B. G. Zavin, and O. G. Blokhina. "Graft anionic copolymerization of octamethyl cyclotetrasiloxane with oligostyrene carbocyclosiloxane." Polymer Science U.S.S.R. 28, no. 10 (January 1986): 2428–34. http://dx.doi.org/10.1016/0032-3950(86)90064-x.

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35

Ederle, Y., F. Isel, S. Grutke, and P. J. Lutz. "Anionic polymerization and copolymerization of macromonomers: Kinetics, structure control." Macromolecular Symposia 132, no. 1 (July 1998): 197–206. http://dx.doi.org/10.1002/masy.19981320119.

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36

Takata, Toshikazu, Keunwo Chung, Atsuhito Tadokoro, and Takeshi Endo. "Anionic copolymerization of bicyclic bis(.gamma.-lactones) with epoxides and volume change during the copolymerization." Macromolecules 26, no. 24 (November 1993): 6686–87. http://dx.doi.org/10.1021/ma00076a065.

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37

Höcker, Hartwig, Helmut Keul, Steffen Kühling, Wieland Hovestadt, and Achim Josef Müller. "The anionic ring-opening polymerization and copolymerization of cyclic carbonates." Makromolekulare Chemie. Macromolecular Symposia 44, no. 1 (May 1991): 239–45. http://dx.doi.org/10.1002/masy.19910440124.

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38

Chen, Fei, and Shengkang Ying. "Anionic copolymerization of α-methylstyrene and styrene: Kinetics and mechanism." Makromolekulare Chemie. Macromolecular Symposia 47, no. 1 (July 1991): 211–19. http://dx.doi.org/10.1002/masy.19910470117.

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39

Nikopoulou, Anastasia, Hermis Iatrou, David J. Lohse, and Nikos Hadjichristidis. "Anionic homo- and copolymerization of styrenic triple-tailed polybutadiene macromonomers." Journal of Polymer Science Part A: Polymer Chemistry 45, no. 16 (2007): 3513–23. http://dx.doi.org/10.1002/pola.22098.

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40

Huang, Yi-Ling, Jing Cao, Wei Hu, and Sai Liang. "Homopolymerization and copolymerization ofN-substituted maleimides with chiral anionic initiators." Polymer International 64, no. 4 (November 25, 2014): 563–70. http://dx.doi.org/10.1002/pi.4836.

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41

Creutz, Serge, Philippe Teyssié, and Robert Jérôme. "Living Anionic Homopolymerization and Block Copolymerization of (Dimethylamino)ethyl Methacrylate." Macromolecules 30, no. 1 (January 1997): 6–9. http://dx.doi.org/10.1021/ma961009h.

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42

Mannebach, Gerd, Ruth Bieringer, Roman Morschhäuser, and Reimund Stadler. "The anionic polymerization of dialkylaminoisoprenes-5-copolymerization with 1,3-butadiene." Macromolecular Symposia 132, no. 1 (July 1998): 245–48. http://dx.doi.org/10.1002/masy.19981320123.

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43

Liu, Zonglin, Yanhui Li, Dagin Wong, and Shuxian Hao. "Anionic block copolymerization of cyclotetrasiloxanes initiated byp-bis(dimethyllithiioxysilyl)benzene." Journal of Applied Polymer Science 62, no. 13 (December 26, 1996): 2355–63. http://dx.doi.org/10.1002/(sici)1097-4628(19961226)62:13<2355::aid-app21>3.0.co;2-0.

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44

Novoa-Carballal, Ramon, Sergey Nosov, Sandrine Pfaff, Holger Schmalz, and Axel H. E. Müller. "Hyperbranched and Hyperstar Polybutadienes via Anionic Self-Condensing Vinyl Copolymerization." Macromolecules 54, no. 12 (June 7, 2021): 5774–83. http://dx.doi.org/10.1021/acs.macromol.1c00537.

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45

Lalrempuia, Ralte, Jarl Underhaug, Karl W. Törnroos, and Erwan Le Roux. "Anionic hafnium species: an active catalytic intermediate for the coupling of epoxides with CO2?" Chemical Communications 55, no. 50 (2019): 7227–30. http://dx.doi.org/10.1039/c9cc02695a.

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A series of hafnium complexes were structurally identified showing high activity (up to 500 h⁻¹) in the selective alternated copolymerization of epoxides with CO₂ under low pressure.

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46

Xu, Xiao-Jun, and Fengxi Chen. "Semi-continuous emulsion copolymerization of butyl methacrylate with polymerizable anionic surfactants." Polymer 45, no. 14 (June 2004): 4801–10. http://dx.doi.org/10.1016/j.polymer.2004.04.060.

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47

Kim, Jung Min, Sneha B. Chakrapani, and Bryan S. Beckingham. "Tuning Compositional Drift in the Anionic Copolymerization of Styrene and Isoprene." Macromolecules 53, no. 10 (May 13, 2020): 3814–21. http://dx.doi.org/10.1021/acs.macromol.0c00526.

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48

Kuchanov, Semion, Christiaan Kok, and Gerrit ten Brinke. "Molecular Inhomogeneity and Scattering Properties of Products of “Living” Anionic Copolymerization." Macromolecules 35, no. 20 (September 2002): 7804–14. http://dx.doi.org/10.1021/ma012072w.

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49

Zhang, Cheng-Jian, Jia-Liang Yang, Lan-Fang Hu, and Xing-Hong Zhang. "Anionic Copolymerization of Carbonyl Sulfide with Epoxides via Alkali Metal Alkoxides." Chinese Journal of Chemistry 36, no. 7 (May 15, 2018): 625–29. http://dx.doi.org/10.1002/cjoc.201700810.

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50

Rieger, Elisabeth, Arda Alkan, Angelika Manhart, Manfred Wagner, and Frederik R. Wurm. "Sequence-Controlled Polymers via Simultaneous Living Anionic Copolymerization of Competing Monomers." Macromolecular Rapid Communications 37, no. 10 (April 13, 2016): 833–39. http://dx.doi.org/10.1002/marc.201600092.

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