Dissertations / Theses: 'Anisotropi'

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Isachsen, Marit. "Effekt av anisotropi på udrenert skjærstyrke i naturlige skråninger." Thesis, Norges teknisk-naturvitenskapelige universitet, Institutt for bygg, anlegg og transport, 2012. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-18653.

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Anisotropi har stor innvirkning på den udrenerte skjærstyrken i leire. I dag er NGI-ADP modellen implementert i elementmetodeprogrammet Plaxis, men modellen tar kun hensyn til anisotropi på deviatoriske spenninger, og egner seg derfor best under initialt flatt terreng. Denne masteroppgaven tar utgangspunkt i en forenklet variant av ADP-modellen, presentert av Kristoffer Rabstad i hans hovedoppgave våren 2011. Modellen er kalt ADPXX, og tar også hensyn til anisotropi på initiale skjærspenninger, på horisontale og vertikale plan. ADPXX-modellen viste en større effekt av anisotropi på grunn av initiale skjærspenninger enn forventet, hvilket er bakgrunnen for oppgaven.Materialmodellens egenskaper er analysert i ulike initialtilstander. Det har vist seg at det er vanskelig å gi aktiv og passiv styrke som input som funksjon av initial effektiv vertikal overlagring. Styrketakene må relateres til de effektive initiale hovedspenningene uansett hvilken retning disse måtte ha. Endringer i modellen og i programkoden er utført for bedre tilnærming til reell materialoppførsel ved å justere grad av anisotropi ut fra initialspenningen, på en konsistent måte innen rammen av et Mohr Coulomb (MC) flytekriterium. Dette innebærer at graden av anisotropi varierer gjennom materialet. For enkelhets skyld er det antatt at anisotropi på skjærspenninger gir like stort bidrag som anisotropi på deviatoriske spenninger. Modellens egenskaper er demonstrert gjennom eksempler, både på en naturlig skråning og på to fiktive idealskråninger. Modellen oppfører seg som forventet. I tilfeller der spenningene øker proporsjonalt, som i en vanlig stabilitetsanalyse av en naturlig skråning, vil modellen gi samme resultat som MC. I situasjoner der en ytre last fører til spenningsrotasjon, vil den brukerdefinerte modellen gi lavere kapasitet. Forskjellen minker dersom skråningen initialt har lav sikkerhet mot brudd.

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Chen, Xiaoming. "Two-dimensional constrained anisotropic inversion of magnetotelluric data." Phd thesis, Universität Potsdam, 2012. http://opus.kobv.de/ubp/volltexte/2012/6316/.

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Tectonic and geological processes on Earth often result in structural anisotropy of the subsurface, which can be imaged by various geophysical methods. In order to achieve appropriate and realistic Earth models for interpretation, inversion algorithms have to allow for an anisotropic subsurface. Within the framework of this thesis, I analyzed a magnetotelluric (MT) data set taken from the Cape Fold Belt in South Africa. This data set exhibited strong indications for crustal anisotropy, e.g. MT phases out of the expected quadrant, which are beyond of fitting and interpreting with standard isotropic inversion algorithms. To overcome this obstacle, I have developed a two-dimensional inversion method for reconstructing anisotropic electrical conductivity distributions. The MT inverse problem represents in general a non-linear and ill-posed minimization problem with many degrees of freedom: In isotropic case, we have to assign an electrical conductivity value to each cell of a large grid to assimilate the Earth's subsurface, e.g. a grid with 100 x 50 cells results in 5000 unknown model parameters in an isotropic case; in contrast, we have the sixfold in an anisotropic scenario where the single value of electrical conductivity becomes a symmetric, real-valued tensor while the number of the data remains unchanged. In order to successfully invert for anisotropic conductivities and to overcome the non-uniqueness of the solution of the inverse problem it is necessary to use appropriate constraints on the class of allowed models. This becomes even more important as MT data is not equally sensitive to all anisotropic parameters. In this thesis, I have developed an algorithm through which the solution of the anisotropic inversion problem is calculated by minimization of a global penalty functional consisting of three entries: the data misfit, the model roughness constraint and the anisotropy constraint. For comparison, in an isotropic approach only the first two entries are minimized. The newly defined anisotropy term is measured by the sum of the square difference of the principal conductivity values of the model. The basic idea of this constraint is straightforward. If an isotropic model is already adequate to explain the data, there is no need to introduce electrical anisotropy at all. In order to ensure successful inversion, appropriate trade-off parameters, also known as regularization parameters, have to be chosen for the different model constraints. Synthetic tests show that using fixed trade-off parameters usually causes the inversion to end up by either a smooth model with large RMS error or a rough model with small RMS error. Using of a relaxation approach on the regularization parameters after each successful inversion iteration will result in smoother inversion model and a better convergence. This approach seems to be a sophisticated way for the selection of trade-off parameters. In general, the proposed inversion method is adequate for resolving the principal conductivities defined in horizontal plane. Once none of the principal directions of the anisotropic structure is coincided with the predefined strike direction, only the corresponding effective conductivities, which is the projection of the principal conductivities onto the model coordinate axes direction, can be resolved and the information about the rotation angles is lost. In the end the MT data from the Cape Fold Belt in South Africa has been analyzed. The MT data exhibits an area (> 10 km) where MT phases over 90 degrees occur. This part of data cannot be modeled by standard isotropic modeling procedures and hence can not be properly interpreted. The proposed inversion method, however, could not reproduce the anomalous large phases as desired because of losing the information about rotation angles. MT phases outside the first quadrant are usually obtained by different anisotropic anomalies with oblique anisotropy strike. In order to achieve this challenge, the algorithm needs further developments. However, forward modeling studies with the MT data have shown that surface highly conductive heterogeneity in combination with a mid-crustal electrically anisotropic zone are required to fit the data. According to known geological and tectonic information the mid-crustal zone is interpreted as a deep aquifer related to the fractured Table Mountain Group rocks in the Cape Fold Belt.
Tektonische und geologische Prozesse verursachen häufig eine strukturelle Anisotropie des Untergrundes, welche von verschiedenen geophysikalischen Methoden beobachtet werden kann. Zur Erstellung und Interpretation geeigneter, realistischer Modelle der Erde sind Inversionsalgorithmen notwendig, die einen anisotropen Untergrund einbeziehen können. Für die vorliegende Arbeit habe ich einen magnetotellurischen (MT) Datensatz vom Cape Fold Gürtel in Südafrika untersucht. Diese Daten weisen auf eine ausgeprägte Anisotropie der Kruste hin, da z.B. die MT Phasen außerhalb des erwarteten Quadranten liegen und nicht durch standardisierte isotrope Inversionsalgorithmen angepasst und ausgewertet werden können. Um dieses Problem zu beheben, habe ich eine zweidimensionale Inversionsmethode entwickelt, welche eine anisotrope elektrische Leitfähigkeitsverteilungen in den Modellen zulässt. Die MT Inversion ist im allgemeinen ein nichtlineares, schlecht gestelltes Minimierungsproblem mit einer hohen Anzahl an Freiheitsgraden. Im isotropen Fall wird jeder Gitterzelle eines Modells ein elektrischer Leitfähigkeitswert zugewiesen um den Erduntergrund nachzubilden. Ein Modell mit beispielsweise 100 x 50 Zellen besitzt 5000 unbekannte Modellparameter. Im Gegensatz dazu haben wir im anisotropen Fall die sechsfache Anzahl, da hier aus dem einfachen Zahlenwert der elektrischen Leitfähigkeit ein symmetrischer, reellwertiger Tensor wird, wobei die Anzahl der Daten gleich bleibt. Für die erfolgreiche Inversion von anisotropen Leitfähigkeiten und um die Nicht-Eindeutigkeit der Lösung des inversen Problems zu überwinden, ist eine geeignete Einschränkung der möglichen Modelle absolut notwendig. Dies wird umso wichtiger, da die Sensitivität von MT Daten nicht für alle Anisotropieparameter gleich ist. In der vorliegenden Arbeit habe ich einen Algorithmus entwickelt, welcher die Lösung des anisotropen Inversionsproblems unter Minimierung einer globalen Straffunktion berechnet. Diese besteht aus drei Teilen: der Datenanpassung, den Zusatzbedingungen an die Glätte des Modells und die Anisotropie. Im Gegensatz dazu werden beim isotropen Fall nur die ersten zwei Parameter minimiert. Der neu definierte Anisotropieterm wird mit Hilfe der Summe der quadratischen Abweichung der Hauptleitfähigkeitswerte des Modells gemessen. Die grundlegende Idee dieser Zusatzbedingung ist einfach. Falls ein isotropes Modell die Daten ausreichend gut anpassen kann, wird keine elektrische Anisotropie zusätzlich in das Modell eingefügt. Um eine erfolgreiche Inversion zu garantieren müssen geeignete Regularisierungsparameter für die verschiedenen Nebenbedingungen an das Modell gewählt werden. Tests mit synthetischen Modellen zeigen, dass bei festgesetzten Regularisierungsparametern die Inversion meistens entweder in einem glatten Modell mit hohem RMS Fehler oder einem groben Modell mit kleinem RMS Fehler endet. Die Anwendung einer Relaxationsbedingung auf die Regularisierung nach jedem Iterationsschritt resultiert in glatteren Inversionsmodellen und einer höheren Konvergenz und scheint ein ausgereifter Weg zur Wahl der Parameter zu sein. Die vorgestellte Inversionsmethode ist im allgemeinen in der Lage die Hauptleitfähigkeiten in der horizontalen Ebene zu finden. Wenn keine der Hauptrichtungen der Anisotropiestruktur mit der vorgegebenen Streichrichtung übereinstimmt, können nur die dazugehörigen effektiven Leitfähigkeiten, welche die Projektion der Hauptleitfähigkeiten auf die Koordinatenachsen des Modells darstellen, aufgelöst werden. Allerdings gehen die Informationen über die Rotationswinkel verloren. Am Ende meiner Arbeit werden die MT Daten des Cape Fold Gürtels in Südafrika analysiert. Die MT Daten zeigen in einem Abschnitt des Messprofils (> 10 km) Phasen über 90 Grad. Dieser Teil der Daten kann nicht mit herkömmlichen isotropen Modellierungsverfahren angepasst und daher mit diesen auch nicht vollständig ausgewertet werden. Die vorgestellte Inversionsmethode konnte die außergewöhnlich hohen Phasenwerte nicht wie gewünscht im Inversionsergebnis erreichen, was mit dem erwähnten Informationsverlust der Rotationswinkel begründet werden kann. MT Phasen außerhalb des ersten Quadranten können für gewöhnlich bei Anomalien mit geneigter Streichrichtung der Anisotropie gemessen werden. Um diese auch in den Inversionsergebnissen zu erreichen ist eine Weiterentwicklung des Algorithmus notwendig. Vorwärtsmodellierungen des MT Datensatzes haben allerdings gezeigt, dass eine hohe Leitfähigkeitsheterogenität an der Oberfläche in Kombination mit einer Zone elektrischer Anisotropie in der mittleren Kruste notwendig sind um die Daten anzupassen. Aufgrund geologischer und tektonischer Informationen kann diese Zone in der mittleren Kruste als tiefer Aquifer interpretiert werden, der im Zusammenhang mit den zerrütteten Gesteinen der Table Mountain Group des Cape Fold Gürtels steht.

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Taouk, Habib. "Wave propagation in general anisotropic media." Ohio : Ohio University, 1986. http://www.ohiolink.edu/etd/view.cgi?ohiou1183380228.

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Ljungberg, Adam, and Nathalie Schmidt. "Deformationsstrukturer i ett duplext rostfritt stål (SAF 2507)." Thesis, Högskolan Dalarna, Materialteknik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:du-15770.

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För att kunna förbättra processer och användning av det duplexa rostfria stålet SAF 2507 måste dess deformationsegenskaper undersökas och förklaras. Genom EBSD-analyser har deformationsstrukturer och polfgurer tagits fram för att kunna beskriva materialets beteende vid deformation. Även Taylorfaktorer, E-moduler och Poissons tal har tagits fram för att kunna undersöka materialets anisotropi. Experimenten har utförts på prov av SAF 2507 som har deformerats plastiskt till olika töjningar. Det som undersökts är odeformerat prov, prov som dragits enaxligt till 7,7 % och 24,3 % töjning, samt ett prov som är cykliskt belastat till 3 % töjning. Det undersökta stålet tillverkas genom två olika metoder, men i denna rapport har enbart det extruderade stålet undersökts. Genom att jämföra hur stålets olika mekaniska egenskaper beter sig under plastisk deformation har resultatet blivit att stålets ferritfas beter sig anisotropt med en antydan till ökande isotropi vid ökande deformation. Austenitfasen beter sig däremot isotropt och blir varken mer eller mindre isotropt vid ökande deformation. Substrukturerna i ferritfasen ökar tydligt vid ökande deformation, och ses framför allt i austenitfasen efter 24 % deformation.
In order to improve the processes and the use of the duplex stainless steel SAF 2507, its deformation properties has to be investigated and explained. Through EBSD-analysis deformation structures and pole figures have been developed to describe the behavior of the material during deformation. Also Taylor factors, Young’s modules and Poisson's ratio have been developed in order to investigate the material's anisotropy. The experiments have been performed on samples of SAF 2507 which has been plastically deformed at different strains. The strains studied are undeformed sample, samples drawn uniaxial drawn to 7.7 % and 24.3 % elongation, and one sample which is cyclically loaded to 3% elongation. The steel we have investigated is produced by two different methods, but in this report, only the extruded steel is investigated. By comparing how different mechanical properties of the steel behave during plastic deformation, the result shows that the steel’s ferrite phase behaves anisotropically with a hint of increasing isotropy when the deformation is increasing. The austenite phase behaves isotropic and does not become more or less isotropic with increasing deformation. The substructures in the ferrite phase are clearly increasing with increasing deformation, and are seen mainly in the austenite phase after 24 % deformation.

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Vallefuoco, Donato. "Numerical study of unconfined and confined anisotropic turbulence." Thesis, Lyon, 2017. http://www.theses.fr/2017LYSEC053/document.

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Pour les écoulements turbulents d’intérêt pratique, la turbulence interagit avec le confinement et les forces externes, ce qui cause inhomogénéité et anisotropie statistiques. Isoler leur contribution à des statistiques ciblées est indispensable pour comprendre les différents phénomènes physiques. Le but de cette thèse a donc été d’acquérir une meilleure connaissance de l’anisotropie en fonction de la direction et de l’échelle dans un ensemble de contextes idéalisés et réalistes. On a utilisé une caractérisation statistique dans l’espace spectral ainsi que dans l’espace de séparation. La caractérisation dans l’espace spectral concerne les statistiques anisotropes de turbulence sous forme de spectres directionnels d’énergie, polarisation et hélicité. La caractérisation dans l’espace de séparation s’appuie sur les moments des incréments de vitesse à deux points du deuxième et troisième ordre, et sur les corrélations de vitesse à deux points. Tout d’abord, on a étudié l’effet du forçage spectral de grandes échelles. Les schémas de forçage considérés sont le schéma de forçage de type Euler, non hélicitaire et hélicitaire, et le schéma ABC. On a montré que les deux forçages ont un inconvénient, dans le sens que, si le nombre de modes suffisamment excités est petit, de l’anisotropie se produit même aux petites échelles. Dans le cas du forçage Euler, cela dépend de la gamme de nombres d’onde forcés ainsi que de leur hélicité. Le forçage ABC, pour lequel le niveau d’hélicité injectée ne peut pas être contrôlé, n’excite que six modes et donc il produit toujours de l’anisotropie et à toutes les échelles résolues. Ensuite, on a analysé l’anisotropie en fonction de l’échelle et de la direction pour la turbulence homogène en rotation. Chose étonnante, l’anisotropie se produit à toutes les échelles même si la rotation est faible. En particulier, on a identifié deux gammes d’échelles anisotropes qualitativement différentes. Aux grandes échelles, l’anisotropie directionnelle est plus grande et décroît avec le nombre d’onde. Aux petites échelles, elle est beaucoup plus faible—mais encore significative—et croit lentement avec le nombre d’onde jusqu’aux échelles dissipatives. Une autre conclusion intéressante et originale de cette partie du travail concerne le rôle de l’échelle de Zeman et son lien avec l’anisotropie aux différentes échelles de l’écoulement. D’après des travaux précédents, l’échelle de Zeman devrait être l’échelle de longueur caractéristique qui sépare les échelles affectées par la rotation par les échelles isotropes. Après une plus ample investigation, en utilisant simulations à différents paramètres, on a découvert que l’échelle de séparation entre grande et faible anisotropie est plutôt l’échelle de longueur caractéristique pour laquelle les effets de rotation et de dissipation s’équilibrent. Ce résultat, toutefois, n’est pas en contradiction avec l’argument de Zeman sur le rétablissement de l’isotropie dans la limite asymptotique de viscosité nulle, comme l’échelle de séparation s’annule à nombre de Reynolds infini, et donc seulement la gamme d’anisotropie décroissante devrait persister et les échelles beaucoup plus petite que celle de Zeman pourraient récupérer l’isotropie. Enfin, on a considéré l’écoulement de von Kármán entre deux disques équipés de pales en contre-rotation dans une cavité cylindrique. On a répété l’analyse dans l’espace de séparation dans plusieurs petites sous-régions, afin d’enquêter les analogies possibles entre la dynamique de l’écoulement et celle de la turbulence homogène en rotation. On a découvert que, dans les régions du domaine où l’écoulement a un taux de rotation moyen plus grand, les distributions des statistiques dans l’espace de séparation montrent certaines des caractéristiques typiques de la turbulence en rotation
In turbulent flows of practical interest, turbulence interacts with confinement and external forces, leading to statistical inhomogeneity and anisotropy. Isolating their contributions to some targeted statistics is indispensable for understanding the underlying physical phenomena. The aim of this thesis has therefore been to gain further insight into direction- and scale-dependent anisotropy in a set of idealized and realistic contexts. Both spectral space and separation space statistical characterizations have been employed. The spectral characterization concerns the anisotropic statistics of turbulence under the form of directional energy, polarization and helicity spectra. The separation space characterization is built on two-point second- and third-order velocity increment moments, and two-point velocity correlations. First, we studied the effect of large-scale spectral forcing. The considered forcing methods are the non-helical and the helical Euler scheme, and the ABC-scheme. We showed that both forcings have a drawback in that, if the number of sufficiently excited modes is too low, anisotropy is bound to arise even at small scales. In the case of Euler forcing, this depends on both the range of forcing wavenumbers and its helicity contents. The ABC forcing, for which the amount of injected helicity cannot be controlled, excites only six modes and therefore always generates anisotropy at all resolved scales. Our second step was to analyze the scale- and direction-dependent anisotropy of homogeneous rotating turbulence. Surprisingly, anisotropy arises at all scales even at low rotation rate. In particular, we identified two anisotropic ranges with different features. In the large scales, directional anisotropy is larger and decreases with wavenumber. At smaller scales, it is much weaker—although still significant—and slowly increases with wavenumber all the way to the dissipative scales. Another interesting and original conclusion of this part of the work concerns the role of the Zeman scale and its link with the flow scale-dependent anisotropy. The Zeman scale was previously argued to be the characteristic lengthscale separating rotation-affected scales 2 from isotropic ones. Upon closer investigation using several simulations at different parameters, we found that the separating scale between large and weak anisotropy is rather the characteristic lengthscale at which rotation and dissipation effects balance. This result, however, does not contradict Zeman’s argument about isotropy recovery in the asymptotic limit of vanishing viscosity, since the separating scale vanishes at infinite Reynolds number, and therefore only the decreasing anisotropy range should persist and scales much smaller than the Zeman one may recover isotropy. Finally, we considered the von Kármán flow between two counter-rotating bladed disks in a cylindrical cavity. We repeated the separation space analysis in different small sub-regions, in order to question the possible analogies in the flow dynamics with that of homogeneous rotating turbulence. We found that, in the regions of the domain where the mean flow has a larger average rotation rate, the distributions of the statistics in separation space display some of the features typical of rotating turbulence

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Ferraro, Filippo Jacopo. "Magnetic anisotropies and exchange bias in ultrathin cobalt layers for the tunnel anisotropic magnetoresistance." Thesis, Université Grenoble Alpes (ComUE), 2015. http://www.theses.fr/2015GREAY086/document.

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Dans le cadre de l’étude des phénomènes magnétiques et de la spintronique qui sont présents aux échelles nanoscopiques nous avons étudié différents aspects des structures asymétriques de Pt/Co/AlOx. L’un des objectifs de cette thèse est le contrôle de l’oxydation et des propriétés magnétiques de ces multicouches. Nous avons combiné les mesures de structures (réflexion de Rayon-X), transports (Effet Hall anormal), et magnétiques (VSM-SQUID) afin de déterminer les rôles des effets magnétiques et d’interfaces. Un objectif était d’analyser le rôle de quelques monocouches (MCs) de CoO (qui peut se former lors de la sur oxydation de l’Al) sur les propriétés de la multicouche. Nous avons utilisé une technique de déposition avec un gradient d’épaisseur pour contrôler l’oxydation à l’échelle nanométrique. Nous avons établis que quelques monocouches (MCs) de CoO a un impact sur l’anisotropie de a multicouche. Pour approfondir l’effet de la couche de CoO, nous avons construit des bicouches ultrafines de Co(0.6nm)/CoO(0.6nm). Nous avons effectué des mesures refroidi sur champ sur ce système et trouvé un fort effet de couplage d'échange. Ces résultats indiquent que la couche CoO garde une forte anisotropie même en dans la limite des monocouches et permet de réfuter certains modèles sur l’effet d’échange bias et indique que les couches, couramment négligé, de CoO doivent être prises en considération dans le bilan énergétiques du système. Nous avons construits un appareil de mesure perpendiculaire de la magnétorésistance tunnel anisotrope (TAMR) à partir de la structure Pt/Co/AlOx. La TAMR est un effet de spintronique relativement récent dans lequel la rotation d’aimantation dans une électrode magnétique (combiné avec un couplage spin-orbite) peut entrainer un changement de la probabilité de l’effet tunnel, ce qui se manifeste comme un effet de magnétorésistance. Nous avons démontré qu’un contrôle précis de l’état d’oxydation est essentiel pour l’effet TAMR. La forte anisotropie magnétique induite nous permet d’atteindre des valeurs de TAMR plus grande comparée à celle des structures Pt/Co/AlOx
In the context of studying magnetic and spintronics phenomena occurring at the nanoscale, we investigated several aspects of Pt/Co/AlOx asymmetric structures. One of the objectives of this thesis was the control of the oxidation and the tailoring of the magnetic properties of these multilayers. We combined structural (X-Ray Reflectivity), transport (Anomalous Hall Effect) and magnetic measurements (VSM-SQUID), to study the interplay of magnetic and interfacial effects. One objective was to analyze the role that few monolayers (MLs) of CoO (which can form when overoxidizing the Al layer), could have on the properties of the stack. We used a wedge deposition techniques to control the oxidation on a subnanometer scale. We established that few MLs of CoO largely affect the total anisotropy of the stack. To further investigate the impact of the CoO, we engineered ultrathin Co(0.6nm)/CoO(0.6nm) bilayers. We performed field cooled measurements on this system and we found a large exchange bias anisotropy. These results indicate that the CoO keeps a large anisotropy even in the ML regime, help to rule out some of the models proposed to explain the exchange bias effect and imply that the usually neglected CoO presence must be considered in the energy balance of the system. We build perpendicular Tunneling Anisotropic MagnetoResistance (TAMR) devices based on the Pt/Co/AlOx structure. The TAMR is a relatively new spintronics effect in which the rotation of the magnetization in a single magnetic electrode (combined with the Spin-Orbit Coupling) can cause a change of the tunnel probability, which manifests as a magnetoresistance effect. We demonstrated that a careful control of the interface oxidation is crucial for the TAMR effect. The large induced magnetic anisotropy allowed us to achieve enhanced TAMR values compared to similar Pt/Co/AlOx structures

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Quarta, Francesco. "Implementazione numerica di modelli algebrici espliciti per il flusso termico e il tensore degli sforzi di Reynolds in moti turbolenti anisotropi stazionari." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2019.

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In questo lavoro di tesi si è implementato un modello anisotropo per la turbolenza nel codice di calcolo agli elementi finiti FEMuS, in modo da sopperire alle mancanze derivanti dall'assunzione di Boussinesq per quanto riguarda il tensore degli sforzi di Reynolds e del flusso termico turbolento. Entrambe queste grandezze sono state implementate attraverso modelli algebrici espliciti e il codice così sviluppato è stato utilizzato per simulare il moto turbolento oltre un gradino con parete riscaldata per una corrente di sodio liquido. La bontà dei risultati è stata validata attraverso il confronto con diverse simulazioni DNS e sperimentali per la medesima configurazione.

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Edström, Alexander. "Theoretical and Computational Studies on the Physics of Applied Magnetism : Magnetocrystalline Anisotropy of Transition Metal Magnets and Magnetic Effects in Elastic Electron Scattering." Doctoral thesis, Uppsala universitet, Materialteori, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-304666.

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In this thesis, two selected topics in magnetism are studied using theoretical modelling and computational methods. The first of these is the magnetocrystalline anisotropy energy (MAE) of transition metal based magnets. In particular, ways of finding 3d transition metal based materials with large MAE are considered. This is motivated by the need for new permanent magnet materials, not containing rare-earth elements, but is also of interest for other technological applications, where the MAE is a key quantity. The mechanisms of the MAE in the relevant materials are reviewed and approaches to increasing this quantity are discussed. Computational methods, largely based on density functional theory (DFT), are applied to guide the search for relevant materials. The computational work suggests that the MAE of Fe1-xCox alloys can be significantly enhanced by introducing a tetragonality with interstitial B or C impurities. This is also experimentally corroborated. Alloying is considered as a method of tuning the electronic structure around the Fermi energy and thus also the MAE, for example in the tetragonal compound (Fe1-xCox)2B. Additionally, it is shown that small amounts (2.5-5 at.%) of various 5d dopants on the Fe/Co-site can enhance the MAE of this material with as much as 70%. The magnetic properties of several technologically interesting, chemically ordered, L10 structured binary compounds, tetragonal Fe5Si1-xPxB2 and Hexagonal Laves phase Fe2Ta1-xWx are also investigated. The second topic studied is that of magnetic effects on the elastic scattering of fast electrons, in the context of transmission electron microscopy (TEM). A multislice solution is implemented for a paraxial version of the Pauli equation. Simulations require the magnetic fields in the sample as input. A realistic description of magnetism in a solid, for this purpose, is derived in a scheme starting from a DFT calculation of the spin density or density matrix. Calculations are performed for electron vortex beams passing through magnetic solids and a magnetic signal, defined as a difference in intensity for opposite orbital angular momentum beams, integrated over a disk in the diffraction plane, is observed. For nanometer sized electron vortex beams carrying orbital angular momentum of a few tens of ħ, a relative magnetic signal of order 10-3 is found. This is considered realistic to be observed in experiments. In addition to electron vortex beams, spin polarised and phase aberrated electron beams are considered and also for these a magnetic signal, albeit weaker than that of the vortex beams, can be obtained.

Felaktigt ISBN i den tryckta versionen: 9789155497149

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Azevedo, Carlos Alberto Cabral de. "Formulação alternativa para análise de domínios não-homogêneos e inclusões anisotrópicas via MEC." Universidade de São Paulo, 2007. http://www.teses.usp.br/teses/disponiveis/18/18134/tde-18102007-110753/.

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Este trabalho trata da análise de problemas planos de chapa compostos por materiais anisotrópicos, definidas em uma região ou no domínio por completo, utilizando-se o método dos elementos de contorno. As soluções fundamentais para problemas anisotrópicos, embora existentes, mostram-se difíceis de serem utilizadas devido à complexidade de sua formulação matemática ou da necessidade de se encontrar partes da solução numericamente. Nesse sentido, a formulação alternativa mostrada nesse trabalho permite o estudo de meios anisotrópicos utilizando-se as soluções fundamentais para meios isotrópicos nas representações integrais de problemas planos com campo de tensões iniciais. A região do domínio com propriedades anisotrópicas ou diferentes das propriedades elásticas de um meio isotrópico usado como referência é discretizada em células triangulares, enquanto que o contorno do problema é discretizado em elementos lineares. As componentes do tensor de tensões iniciais da região anisotrópica são definidas como uma correção das tensões elásticas do material isotrópico de referência através de uma matriz de penalização. Essa matriz, por sua vez, é obtida através de relações envolvendo as constantes elásticas de rigidez do meio desejado e os coeficientes elásticos de flexibilidade do meio isotrópico de referência. Essa técnica é particularmente adequada para a análise de inclusões anisotrópicas onde há a necessidade de discretizar apenas uma parte pequena do domínio, aumentando, portanto, pouco o número de graus de liberdade do sistema. Os resultados obtidos com a formulação proposta são comparados com os resultados numéricos existentes na literatura.
This work deals with elastic 2D problems characterized by the presence of zones with different materials and anisotropic inclusions using the boundary element method. The anisotropy can be assumed either over the whole domain or defined only over some particular inclusions, which is the most usual case. Fundamental solutions for anisotropic domains, although well-known, lead to more complex formulations and may introduce difficulties when the analysis requires more complex material models as for instance plastic behavior, finite deformations, etc. The alternative formulation proposed in this work can be applied to anisotropic bodies using the classical fundamental solutions for 2D elastic isotropic domains plus correction given by an initial stress field. The domain region with anisotropic properties or only with different isotropic elastic parameters has to be discretized into cells to allow the required corrections, while the complementary part of the body requires only boundary discretization. The initial stress tensor to be applied to the anisiotropic region is defined as the isotropic material elastic stress tensor correction by introducing a local penalty matrix. This matrix is obtained by the difference between the elastic parameters between the reference values and the anisotropic material. This technique is particularly appropriate for anisotropic inclusion analysis, in which the domain discretization is required only over a small region, therefore increasing very little the number of degrees of freedom of the final algebraic system. The numerical results obtained by using the proposed formulation have demonstrated to be very accurate in comparison with either analytical solutions or the other numerical values.

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Koabaz, Mahmoud. "Contribution à l’étude des ondes de LAMB dans une plaque anisotrope : théorie et expérience." Thesis, Bordeaux 1, 2010. http://www.theses.fr/2010BOR14071/document.

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Le rayonnement d'une source ultrasonore située sur l'une des interfaces d'une plaque anisotrope est étudié. Le calcul du tenseur de Green est effectué dans le cas général d'un problème 3D. Une décomposition en multiples réflexions /réfractions, constituant une série de rayons au sein de la plaque, est utilisée pour une comparaison théorie-expérience dans le cas d'un mono cristal de Cuivre. La vitesse de phase et la vitesse d'énergie sont mesurées en fonction de la fréquence ou de la direction d'observation, pour une plaque de carbone-époxy unidirectionnels, et comparées avec la théorie
The ultrasonic radiation from a source located on one of the interfaces of an anisotropic plateis studied. The calculation of the Green tensor is performed in the general case of a 3Dproblem. Decomposition into multiple reflections /refractions, as a series of rays in the plate,is used for comparison between theory and experiment in the case of a single crystal of copper. The phase velocity and energy velocity are measured in terms of frequency ordirection of observation, for a plate of unidirectional carbon-epoxy, and compared withtheory

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Riedel, Marko. "Efficient computation of seismic traveltimes in anisotropic media and the application in pre-stack depth migration." Doctoral thesis, Technische Universitaet Bergakademie Freiberg Universitaetsbibliothek "Georgius Agricola", 2016. http://nbn-resolving.de/urn:nbn:de:bsz:105-qucosa-204044.

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This study is concerned with the computation of seismic first-arrival traveltimes in anisotropic media using finite difference eikonal methods. For this purpose, different numerical schemes that directly solve the eikonal equation are implemented and assessed numerically. Subsequently, they are used for pre-stack depth migration on synthetic and field data. The thesis starts with a detailed examination of different finite difference methods that have gained popularity in scientific literature for computing seismic traveltimes in isotropic media. The most appropriate for an extension towards anisotropic media are found to be the so-called Fast Marching/Sweeping methods. Both schemes rely on different iteration strategies, but incorporate the same upwind finite difference Godunov schemes that are implemented up to the second order. As a result, the derived methods exhibit high numerical accuracy and perform robustly even in highly contrasted velocity models. Subsequently, the methods are adapted for transversely isotropic media with vertical (VTI) and tilted (TTI) symmetry axes, respectively. Therefore, two different formulations for approximating the anisotropic phase velocities are tested, which are the weakly-anisotropic and the pseudo-acoustic approximation. As expected, the pseudo-acoustic formulation shows superior accuracy especially for strongly anisotropic media. Moreover, it turns out that the tested eikonal schemes are generally more accurate than anisotropic ray tracing approaches, since they do not require an approximation of the group velocity. Numerical experiments are carried out on homogeneous models with varying strengths of anisotropy and the industrial BP 2007 benchmark model. They show that the computed eikonal traveltimes are in good agreement with independent results from finite difference modelling of the isotropic and anisotropic elastic wave equations, and traveltimes estimated by ray-based wavefront construction, respectively. The computational performance of the TI eikonal schemes is largely increased compared to their original isotropic implementations, which is due to the algebraic complexity of the anisotropic phase velocity formulations. At this point, the Fast Marching Method is found to be more efficient on models containing up to 50 million grid points. For larger models, the anisotropic Fast Sweeping implementation gradually becomes advantageous. Here, both techniques perform independently well of the structural complexity of the underlying velocity model. The final step of this thesis is the application of the developed eikonal schemes in pre-stack depth migration. A synthetic experiment over a VTI/TTI layer-cake model demonstrates that the traveltime computation leads to accurate imaging results including a tilted, strongly anisotropic shale layer. The experiment shows further that the estimation of anisotropic velocity models solely from surface reflection data is highly ambiguous. In a second example, the eikonal solvers are applied for depth imaging of two-dimensional field data that were acquired for geothermal exploration in southern Tuscany, Italy. The developed methods also produce clear imaging results in this setting, which illustrates their general applicability for pre-stack depth imaging, particularly in challenging environments.

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Belijar, Guillaume. "Anisotropic composite elaboration and modeling : toward materials adapted to systems." Thesis, Toulouse 3, 2016. http://www.theses.fr/2016TOU30353/document.

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L'objectif de ces travaux de thèse a été de démontrer la possibilité, en se basant sur une approche prédictive, de contrôler avec précision la fonctionnalisation d'un matériau composite, d'isotrope à anisotrope, sous l'application d'un champ électrique. Ces derniers matériaux présentent en effet un fort potentiel pour des applications futures telles que des condensateurs intégrés ou bien encore des composites conducteurs thermiques. Une première approche théorique des différentes forces et mécanismes entrant en jeux lors de l'élaboration de composites anisotropes par chaînage a permis d'identifier les paramètres impactant le procédé d'élaboration. A la suite de cette étude théorique, un modèle de formation de chaînes de particules sous champ électrique a été développé afin de prédire la dynamique de chaînage. Le modèle choisi (méthode moment dipolaire effectif) a permis la simulation de plus de 4500 particules. Les paramètres ayant au préalable été identifiés ont ensuite été mesurés. Pour la permittivité des particules, une méthode de mesure diélectrophorétique a été développée, ce qui est une première dans le cas de particules céramiques. L'élaboration des composites anisotropes a été couplé avec un suivi novateur, en temps réel, d'un marqueur (permittivité) de la formation de chaînes, permettant d'obtenir la dynamique de structuration des particules. Afin de valider l'aspect prédictif du modèle numérique, une comparaison a été effectuée entre la dynamique mesurée et simulée. Les résultats obtenus ont démontré une très bonne fiabilité des prédictions du modèle, même si des progrès sont encore réalisables aux faibles taux de chargement. Dans un dernier temps, une preuve de concept a été démontrée, de la réalisation de composites anisotropes dont les particules sont alignées perpendiculairement au champ électrique
This study was aimed to demonstrate the possibility, based on a predictive approach, to tailor the structure of a composite from isotropic to anisotropic when applying an electric field. This composites have great potential for future applications such as embed capacitors or thermally conductive composites. A theoretical approach of the forces and mechanisms acting in the elaboration of anisotropic composites by chaining allowed identifying the key parameters. Based on this approach a model of particle chaining under electric field was established to predict the structuration dynamics. This model (effective dipole moment) allowed simulating more than 4500 particles. The parameters previously identified were then measured, and for the particle permittivity, a dielectrophoretic measurement method was developed, which was a first for ceramic particles. The elaboration of anisotropic composites was coupled to a novel on-line monitoring of a chaining marker (permittivity), allowing to obtain the structuration dynamics. To validate the predictive aspect of the model, experimental and numerical dynamics were compared showing the robustness and accuracy of the model, even if improvement is still possible at low filler content. In the last part, a proof of concept was demonstrated of the elaboration of anisotropic composites with fillers oriented normally to the direction of the electric field

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Poulain, Arthur. "RANS & WMLES Simulations of Compressor Corner Separation." Thesis, KTH, Mekanik, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-279819.

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In axial compressor, corner separation phenomenon can occur between the blade surface and the hub. This leads to high total pressure losses, blockage and may worsen to surge. Various studies on NACA65-009 blade were previously performed experimentally and numerically to predict the corner separation. The LMFA showed that RANS simulations tend to overestimate it while the Wall-Resolved LES (WRLES) was able to well capture it. The conclusions drawn on RANS are validated here with another solver software. An extensive parametric study is performed on RANS which highlights the good performance of two non-linear turbulence models k − ω Wilcox QCR and EARSM k − kl for for predicting the topology and the intensity of corner separation. They are however very dependent on the mesh and the numerics. A Wall-Modeled LES (WMLES) is then computed. It reproduces well the topology of the separation given by the experiments and predicts similar anisotropy to the WRLES. Nevertheless it shows high sensitivity to the level of turbulence close to the endwall and the boundary layer profile of the upstream flow. Finally, this confirms that the WMLES is a promising alternative to the WRLES in order to study the corner separation on more costly geometries (several blades for instance).
I axiell kompressor kan hörnseparationsfenomen uppstå mellan bladytan och navet. Konsekvenserna är stora totala tryckförluster och kompressor blockering. Olika studier på NACA65-009 bladet utfördes tidigare experimentellt och numeriskt för att förutsäga hörnseparationen. LMFA visade att RANS simuleringar tenderar att överskatta den hörnseparationen medan Vägg-Löst LES (WRLES på engelska) kunde fånga bra den. Slutsatserna som dras om RANS valideras här med en annan lösningsprogramvara. En omfattande parametrisk studie utförs på RANS som belyserde goda prestandan för två icke-linjära turbulensmodeller k − ω Wilcox QCRoch EARSM k − kl för att förutsäga topologin och intensiteten för hörnseparation. Dock är de mycket beroende av nät och numerik. En Vägg-Modell LES (WMLES på engelska) beräknas sedan. Det reproducerar väl topologin för separationen som ges av experimenten och förutsäger liknande anisotropi som WRLES. Dock visar det hög känslighet för turbulensnivån nära ändväggen och gränsskiktsprofilen för uppströmsflödet. Slutligen bekräftar detta att WMLES är ett lovande alternativ till WRLES för att studera hörnseparationen på dyrare geometrier (till exempelflera blad).

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El-Khatib, Fatima. "Synthèse, caractérisation et études magnétiques de complexes de Co(II) et de Ni(II) avec des ligands de type cryptands." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLS018/document.

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Les molécules-aimants sont une classe d’objets aux propriétés très singulières, et dont les applications envisagées, certes sans doute lointaines, sont multiples. Dans le cadre du stockage de l’information, la principale propriété de ces molécules est le blocage de leur aimantation qui leur confère les propriétés de mémoire au niveau de la molécule unique. Théoriquement l’existence d’une aimantation spontanée au niveau d’une molécule de spin S ne peut exister que s’il y a une levée de dégénérescence à champ nul (ZFS) qui sépare les états de spin ±mS. Dans ce contexte, les molécules-aimants peuvent être divisées en deux classes : (i) les complexes mononucléaires dont la majorité comprennent, en général, des ions paramagnétiques présentant une forte anisotropie axiale qui à leurs tours sont responsables de la relaxation lente de l’aimantation dans le système, et (ii) les complexes polynucléaires, où les ions métalliques (métaux de transition et/ou lanthanides) communiquent entre eux par une interaction d’échange J ou par interaction dipolaire. Ce type de complexes peut à son tour diviser en deux parties : HomoBinucléaires et HétéroBinucléaires. Différents complexes de Co (II) et de Ni (II) sont synthétisés et étudiés chimiquement et magnétiquement avec ce type de ligand qui est capable d’accepter deux métaux dans deux sites de coordination liés par des différents ligands pontants (Cl-, Br-, NO3-, N3-, imidazole, etc..). Les mesures de susceptibilité magnétique de certains complexes montrent une interaction antiferromagnétique avec une anisotropie axiale de type Ising (D < 0) et autre de type planaire (D > 0). Cela est dû de la nature des ions métalliques et les géométries des complexes pentacoordinés (bipyramide trigonale et pyramide à base carrée)
For molecular magnetic materials to be used in applications, they must retain their magnetization at reasonable temperatures, which can be achieved with high-energy barriers for magnetization reversal and slow relaxation of the magnetization. In the field of Single-Molecule Magnets (SMMs), over the last decade, the main focus has shifted from large spin complexes to highly anisotropic systems which have displayed high energy barriers.1 Here, we used a cryptand ligand that forces a trigonal bipyramidal arrangement to obtain a large (in absolute value) negative zero field splitting parameter D.2 In order to use these molecules as models for entangled quantum bits (qbits), the cryptand ligand was chosen to have two coordination sites allowing the design of chemically stable binuclear complexes with tunable antiferromagnetic coupling. We prepared pentacoordinate complexes of Co(II) and Ni(II) with different bridging ligands (Cl-, Br-, NO3-, N3-, Im-, etc.). Magnetic measurements indicated an Ising type anisotropy and weak antiferromagnetic coupling as expected from the nature of the bridging ligands (N3- and Im-) and the trigonal bipyramidal geometry around the metal ions

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Xia, Chao [Verfasser], and Guofang [Akademischer Betreuer] Wang. "On a class of anisotropic problems = Über eine Klasse von anisotropen Problemen." Freiburg : Universität, 2012. http://d-nb.info/1123470936/34.

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Parra, Martinez Juan Pablo. "On multilayered system dynamics and waves in anisotropic poroelastic media." Doctoral thesis, KTH, VinnExcellence Center for ECO2 Vehicle design, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-195801.

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The mechanical and acoustic anisotropy of media is a governing factor in the behaviour of multilayered systems including such media. The understanding of the mechanisms conditioning the dynamic behaviour of multilayered systems is of paramount importance. In particular, the intrinsic anisotropy of poroelastic media presents a potential for the optimal design of systems for multifunctional performances. Indeed, these multilayered systems are bound by stiffness, thermal and acoustic performance constraints in simultaneously. A plane wave method is presented to study the influence of material orientation in the dynamic behaviour of multilayered systems composed of anisotropic poroelastic media. The method is applied to a system composed of an anisotropic open-celled melamine foam core in between two metal sheets. This particular multilayered configuration allows to shed light on phenomena intrinsic to layers composed of anisotropic poroelastic materials, such as the frequency shift of the fundamental resonance of the panel, or the compression-shear coupling effects taking place in the poroelastic core layers. The latter phenomena is of particular importance, as it is evidenced on the unconventional polarisation of waves in anisotropic poroelastic media. Finally, the method is adapted to the optimisation of multilayered systems for acoustic performance. the design variables are consequently the core material orientations with respect to the global coordinate system. The solutions to the optimisation problem are analysed in terms of dynamic behaviour, thus allowing to correlate acoustic performance of the overall structure, and the response of each individual layer.

QC 20161110

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Ballot, Noémie. "Matériaux nanométriques à base de métaux 3d (Fe, Co, Ni) : Nouvelles voies de synthèse et caractérisations." Thesis, Paris 13, 2014. http://www.theses.fr/2014PA132065/document.

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L’intérêt grandissant envers les nanomatériaux a base des métaux de transition 3d comme le cobalt, le nickel et le fer trouve son origine dans les propriétés intrinsèques de ces éléments (forte aimantation du fer et constante magnétocristalline élevée du cobalt) combinées aux propriétés particulières offertes par la taille nanométrique et l’anisotropie de ces alliages. Parmi les nombreuses voies de synthèse dites de chimie douce, le procède polyol permet l’élaboration de plusieurs classes de matériaux inorganiques a l’état finement divises (oxydes, hydroxydes et métaux) grâce aux réactions de réduction et d’hydrolyse qui peuvent être conduites et contrôlées dans les milieux polyols. Le premier axe de ce travail a consisté à tirer profit de l’état finement divise des oxydes et hydroxydes élabores en milieu polyol pour l’obtention de métaux et alliages correspondants, au moyen d’une réduction ménagée a l’état solide sous flux d’hydrogène. Il a alors été possible d’aboutir a des particules de CoFe2, CoFe, NiFe, Ni3Fe et Fe ferromagnétiques avec une température de blocage supérieure a 300 K. Le deuxième axe de travail a trait a l’élaboration d’objets anisotropes. Pour ce faire, une nouvelle approche est proposée : la synthèse en milieu polyol assistée par l’application d’un champ magnétique. Ce type de synthèse mené a des nanofils d’akaganeite β-FeOOH et a des nanoparticules d’oxydes spinelles. Une réduction relativement douce (300 °C) des nanofils d’akaganeite permet de l’obtention de phases spinelles de même morphologie et avec des propriétés magnétiques en accord avec la composition chimique et le caractère nanométrique des particules (comportement superparamagnétique avec une température de blocage proche de 300 K, Ms élevée et Hc dépendant de la nature de l’élément M se trouvant dans le spinelle MFe2O4 : élevé dans le cas du cobalt et faible dans le cas du fer et du nickel)
The growing interest in nanomaterials based on 3d transition metals such as cobalt, iron and nickel finds its origin in the intrinsic properties of these elements (high magnetization of iron and high magnetocristalline constant of cobalt) combined with particular property due to nanometric size and anisotropy of these alloys. Among the numerous synthetic routes, the polyol method which belongs to the chimie douce routes allows the elaboration of several finely divided inorganic materials (oxides, hydroxides, metals) by means of reduction or forced hydrolysis reactions conducted in polyol medium. The main first contribution of this work was to take advantage of these finely divided oxides and hydroxides elaborated in polyol medium to obtain metals and alloys, through a controlled reduction in solid form under hydrogen flow. Ferromagnetic particles of CoFe2, CoFe, NiFe, Ni3Fe and Fe with a blocking temperature above 300 K were obtained. The second main contribution of this work relates elaboration of anisotropic objects. Further, a new approach is proposed: forced hydrolysis in polyol medium assisted by applying a magnetic field. This type of synthesis leads to akaganeite β7&eOOH nanowires and spinel oxides nanoparticles. A relative mild reduction (300 °C) of akaganeite nanowires allows to obtain spinels phase with same morphology and magnetic properties in agreement with the chemical composition and the particles nanoscale (superparamagnetic behavior with blocking temperaturenear 300 K, high Ms and Hc dependent on the nature of the M element in the spinel MFe2O4, high in the case of cobalt and low for nickel and iron)

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Yu, Cheng-Han. "Anisotropic mechanical behaviors and microstructural evolution of thin-walled additively manufactured metals." Licentiate thesis, Linköpings universitet, Konstruktionsmaterial, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-169054.

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Additive manufacturing (AM), also known as 3D printing, is a concept and method of a manufacturing process that builds a three-dimensional object layer-by-layer. Opposite to the conventional subtractive manufacturing, it conquers various limitations on component design freedom and raises interest in various fields, including aerospace, automotive and medical applications. This thesis studies the mechanical behavior of thin-walled component manufactured by a common AM technique, laser powder bed fusion (LPBF). The studied material is Hastelloy X, which is a Ni-based superalloy, and it is in connection to a component repair application in gas turbines. The influence of microstructure on the deformation mechanisms at elevated temperatures is systematically investigated. This study aims for a fundamental and universal study that can apply to different material grades with FCC crystallographic structure. It is common to find elongated grain and subgrain structure caused by the directional laser energy input in the LPBF process, which is related to the different printing parameters and brands of equipment. This thesis will start with the study of scan rotation effect on stainless steel 316L in an EOS M290 equipment. The statistic texture analysis by using neutron diffraction reveals a clear transition when different level of scan rotation is applied. Scan rotation of 67° is a standard printing parameter with intention to lower anisotropy, yet, the elongated grain and cell structure is still found in the as-built microstructure. Therefore, the anisotropic mechanical behavior study is carried out on the sample printed with scan rotation of 67° in this thesis. Thin-walled effects in LPBF are investigated by studying a group of plate-like HX specimens, with different nominal thicknesses from 4mm down to 1mm, and a reference group of rod-like sample with a diameter of 18mm. A texture similar to Goss texture is found in rod-like sample, and it becomes <011>//BD fiber texture in the 4mm specimen, then it turns to be <001> fiber texture along the transverse direction (TD) in the 1mm specimen. Tensile tests with the strain rate of 10−3 s−1 have been applied to the plate-like specimens from room temperature up to 700 ℃. A degradation of strength is shown when the sample becomes thinner, which is assumed to be due to the overestimated load bearing cross-section since the as-built surface is rough. A cross-section calibration method is proposed by reducing the surface roughness, and a selection of proper roughness parameters is demonstrated with the consideration of the calculated Taylor’s factor and the residual stress. The large thermal gradient during the LPBF process induces high dislocation density and strengthens the material, hence, the LPBF HX exhibits better yield strength than conventionally manufactured, wrought HX, but the work hardening capacity and ductility are sacrificed at the same time. Two types of loading condition reveal the anisotropic mechanical behavior, where the vertical and horizontal tests refer to the loading direction being on the BD and TD respectively. The vertical tests exhibit lower strength but better ductility that is related to the larger lattice rotation observed from the samples with different deformation level. Meanwhile, the elongated grain structure and grain boundary embrittlement are responsible for the low horizontal ductility. A ductile to brittle transition is traced at 700 ℃, so a further study with two different slow strain rates, 10−5 s−1 and 10−6 s−1, are carried out at 700 ℃. Creep damage is shown in the slow strain rates testing. Deformation twinning is found only in the vertical tests where it forms mostly in the twin favorable <111> oriented grain along the LD. The large lattice rotation and the deformation twinning make the vertical ductility remain high level under the slow strain rates. The slow strain rate tensile testing lightens the understanding of creep behavior in LPBF Ni-based superalloys. In summary, this thesis uncovers the tensile behavior of LPBF HX with different variations, including geometry-dependence, temperature-dependence, crystallographic texture-dependence and strain rate-dependence. The generated knowledge will be beneficial to the future study of different mechanical behavior such as fatigue and creep, and it will also enable a more robust design for LPBF applications.
Additiv tillverkning, eller 3D-utskrifter, är tillverkningsmetoder där man skapar ett tredimensionellt objekt genom att tillföra material lager for lager. Till skillnad från konventionella avverkande tillverkningsmetoder elimineras många geometriska begränsningar vilket ger större designfrihet och metoderna har därför väckt stort intresse inom en rad olika områden, inklusive flyg-, fordons- och medicinska tillämpningar. I denna avhandling studeras mekaniska egenskaper hos tunnväggiga komponenter tillverkade med en vanligt förekommande laserbaserad pulverbädds-teknik, laser powder bed fusion (LPBF). Det studerade materialet är Hastelloy X, en Ni-baserad superlegering som är vanligt förekommande for både nytillverkning och reparation av komponenter för gasturbiner. Inverkan av mikrostruktur på deformationsmekanismerna vid förhöjda temperaturer undersöks systematiskt. Detta arbete syftar till att ge grundläggande och generisk kunskap som kan tillämpas på olika materialtyper med en kubiskt tätpackad (FCC) kristallstruktur. Det är vanligt att man hittar en utdragen kornstruktur orsakad av den riktade tillförseln av laserenergi i LPBF-processen, vilket kan relateras till olika processparametrar och kan variera mellan utrustningar frän olika leverantörer. Denna avhandling inleds med studien av effekten av scanningsstrategi vid tillverkning av rostfritt stål 316L i en EOS M290-utrustning. En statistisk texturanalys med hjälp av neutrondiffraktion påvisar en tydlig övergång mellan olika mikrostrukturer när olika scanningsstrategier tillämpas. En scanningsrotation på 67 mellan varje lager är en typisk standardinställning med avsikt att sanka anisotropin i materialet, dock finns den utdragna kornstrukturen oftast kvar. I denna avhandling studeras därför de anisotropa egenskaperna hos material tillverkade med 67 scanningsrotation. Effekten av tunnväggiga strukturer i LPBF undersöks genom att studera en uppsättning platta HX-prover, med olika nominella tjocklekar från 4 mm ner till 1 mm, samt en referensgrupp med cylindriska prov med en diameter på 18 mm. Kristallografisk textur som liknar den av Goss-typ återfinns i de cylindriska proverna vilket gradvis övergår från en fibertextur med <011> i byggriktningen for 4mm-proven till en fibertextur med <001> i tvärriktningen for 1mm-proven. Dragprovning med en töjningshastighet på 10−3 s−1 har utförts på de platta provstavarna från rumstemperatur upp till 700 ℃. En sänkning av styrkan uppvisas när proven blir tunnare, vilket kan antas bero på att det lastbarande tvärsnittet överskattas på grund av den grova ytan. En metod för tvärsnittskalibrering föreslås genom att kompensera for ytråheten, och valet av lämplig ytfinhetsparameter motiveras med hänsyn till den beräknade Taylor-faktorn och förekomsten av restspänningar. Den stora termiska gradienten som uppstår for LPBF-processen inducerar en hög dislokationstäthet vilket höjer materialets styrka och följaktligen uppvisar LPBF HX högre sträckgräns an konventionellt tillverkad, smidda HX, men förmågan till deformationshårdnande samt duktiliteten i materialet sänks samtidigt. Tester utförda i två olika belastningsriktningar, vertikalt respektive horisontellt mot byggriktningen, demonstrerar det anisotropiska mekaniska beteendet. De vertikala testerna uppvisar lägre hållfasthet men bättre duktilitet vilket kan relateras till en större benägenhet for kristallstukturen att rotera när deformationsgraden ökar. Samtidigt är den utdragna kronstukturen ansvarig for den lägre duktiliteten for de horisontella proverna. En övergång från ett duktilt till ett mer sprött beteende noterades vid 700 ℃, och därför initierades ytterligare en studie där tester med två lägre töjningshastigheter, 10−5 s−1 och 10−6 s−1, utfördes vid 700 ℃. Det kan noteras att krypskador återfinns i tester med en långsam deformationshastighet och deformationstvillingar uppstår endast i de vertikala provstavarna där det främst bildas tvillingar i korn orienterade med <111> riktningen längs belastningsriktningen. Den stora förmågan till rotation i kristallstrukturen och deformationstvillingarna bidrar till att den vertikala duktiliteten förblir hög även i testerna med en låg deformationshastighet. Testerna med en långsam draghastighet bidrar därför till en bättre förståelse av krypbeteendet i LPBF Nibaserade superlegeringar. Sammanfattningsvis så bidrar denna avhandling till bättre förståelse av de mekaniska egenskaperna hos LPBF HX i olika utföranden och förhållanden, inklusive geometriberoende, temperaturberoende, deformationshastighetsberoende samt inverkan av kristallografisk textur. Den genererade kunskapen kommer att vara till stor nytta vid fortsatta studier av olika mekaniska egenskaper som utmattning och kryp, samt bidrar till att möjliggöra en mer robust design for LPBF-tillämpningar.

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19

Bjork, Andreas. "Characterizing magnetic susceptibility and remanent magnetization of magnetite and hematite rich drill-core samples at Blötberget." Thesis, Uppsala universitet, Geofysik, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-347975.

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Laboratory magnetic measurements are used to develop a methodology to characterize the Kiruna-type Rare Earth Elements (REE) bearing apatite iron-oxide deposits at Blötberget in central Sweden. This high-grade ore deposit is known to have sharp boundaries between lens shaped main ore bodies of magnetite-rich ore, and a complex hematite-rich ore associated with pegmatites and skarn formation. The thesis covers laboratory magnetic measurements of 37 samples originating from eight drill cores and reference samples from previously mined area. It focuses on on-covering how the samples relate in terms of magnetic susceptibility, further its dependency on temperature, frequency, field and the orientation. The results are correlated with petrographic analysis previously performed on accompanying thin sections. The measurements show that magnetite with strong susceptibility contribution overshadow the hematite contribution in the samples. Transition changes in susceptibility are noticeable when crossing the Verwey temperature; -153°C, Curie temperature; 580°C and Néel temperature; 680°C. The Morin temperature appears at -60°C, or is missing. Linear relationships are identified between the magnitude difference in susceptibilities across transitions at high temperature and wt% magnetite and hematite have been identified. The Blötberget skarn and hematite-rich ore samples have a higher degree of susceptibility anisotropy than the other ore-types. Blötberget samples are dominated by multidomain characteristics in remanence, saturation and coercivity. High temperature measurements have shown that the magnetite is close to pure. The low temperature measurements suggest hematite is impure or bears a petrological footprint. The study also shows that rich iron ore samples sometimes can be at risk of being overlooked with standard methods of measuring susceptibility
Laboratorietekniska metoder kan användas som ett komplement till malmgeologi och geofysisk prospektering. I denna metodstudie karaktäriseras apatitjärnmalm från Blötberget, nära Grängesberg. En fyndighet bestående av linsformade malmkroppar rika på magnetit och ofta avskilda men komplexa hematitrika stråk. Studien är gjord 37 prover från totalt 8 borrkärnor, och lokaler som tillhörde produktion från gruvverksamhet under 1900-talet. Mätmetoderna fokuserar på att kartlägga malmens magnetiska egenskaper, och hur temperatur, frekvens, fältstyrka samt riktning påverkar dessa. Resultaten jämfördes med tidigare petrografisk studie av tillhörande tunnslip Resultaten visar att magnetit står för merparten av susceptibiliteten i proverna, men att även hematit kan urskiljas och kvantifieras. Temperaturberoende har påvisats vid övergångar för Verwey-temperatur; -153°C, Curie-temperatur; 580 °C, och Néeltemperatur; 680 °C. Den förväntade Morin-temperaturen vid -14°C, påträffades vid -60 °C eller saknas helt för flera av de hematitrika proverna. Magnetiskt anisotropa prover återfinns bland prover som identifierats som skarn eller hematitrika. Magnetisk granulometri visar karaktär av multidomäntyp med låg magnetisk coercivitet och hög satureringsförmåga. Högtemperaturmätningar av susceptibilitet visar på ren magnetit för prover från Blötberget. Samtidigt visar lågtemperaturemätningar att hematit sannolikt har inblandning av titanium eller bär på ett mer komplext förflutet. Studien visar också att det finns en risk i att enbart förlita sig på bulksusceptibilitet för prover rika på malm.

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20

Rosa, Diego Saldanha da. "Estudo de exchange bias via magnetorresistência anisotrópica." Universidade Federal de Santa Maria, 2013. http://repositorio.ufsm.br/handle/1/9237.

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Anisotropic magnetoresistance (AMR) corresponds to the change of R in an ferromagnetic material with the angle between electric current and magnetization. Sensors using this effect are suited to detect both angular and linear displacements. In this work, structural, magnetic and electric characterization were performed in order to study the exchange interaction between antiferromagnetic IrMn and ferromagnetic NiFe, in a bilayer and a multilayer. Simulations of the AMR measurements were performed and showed good agreement with the experimental data. Different anisotropy field values were observed. The difference between the anisotropy field and the exchange field values is responsible for the different AMR data sets extracted from each sample. The model takes into account the, anisotropy (uniaxial), Zeeman, and exchange-bias (unidirectional) energies was used to explain the observed behavior.
Magnetorresistência anisotrópica (AMR) consiste na variação da resistência de um material ferromagnético em função do ângulo entre a corrente elétrica e a magnetização do material, o que faz com que sensores que utilizam este efeito sejam promissores para medidas de posição tanto angulares quanto lineares. Neste trabalho, caracterização estrutural, magnética e elétrica foram realizadas para estudar a interação de troca entre camadas antiferromagnética de IrMn e ferromagnética de NiFe em uma bicamada e uma multicamada. Simulações das medidas de AMR foram realizadas e boa concordância entre os dados experimentais e os simulados foi obtida. Diferentes valores de campos de anisotropias foram observados. A diferença entre o campo de anisotropia unidirecional e o campo de exchange é responsável pela diferença entre as medidas de AMR obtidas. Um modelo que considera as energias de anisotropia (uniaxial), Zeeman e de exchangebias (unidirecional) foi usado para explicar o comportamento observado.

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21

Misra, Pranob. "Optical polarization anisotrop in nonpolar GaN thin films due to crystal symmetry and anisotropic strain." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=978811909.

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Misra, Pranob. "Optical polarization anisotrop in nonpolar GaN thin films due to crystal symmetry and anisotropic strain." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2006. http://dx.doi.org/10.18452/15425.

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Diese Arbeit befasst sich mit den optischen Eigenschaften von dünnen GaN-Schichten gewachsen in verschiedenen Orientierungen. Hierbei werden die optischen Eigenschaften von verspannten M- und A-plane sowie unverspannten C-plane GaN-Schichten untersucht und die Ergebnisse im Rahmen von Bandstrukturberechnungen diskutiert. Im Rahmen dieser Arbeit werden die Bandstrukturverschiebungen theoretisch mittels eines k.p-Näherungsansatzes untersucht. Diese Bandverschiebungen beeinflussen sowohl die Übergangsenergien als auch die Oszillatorstärken. Man findet, dass die C-plane Schicht im Falle einer isotropen Verspannung in der Filmebene keine Anisotropie der optischen Polarisation zeigt. In beiden Fällen zeigen die drei Übergänge von den drei oberen Valenzbändern in das untere Leitungsband andere Polarisationseigenschaften als die entsprechenden Übergänge in C-plane GaN-Schichten. Es wird beobachtet, dass für einen bestimmten Wertebereich der Verspannung in der Filmebene diese Übergänge nahezu vollständig x-,z- bzw. y-artig polarisiert sind. Die verwendeten Schichten wurden auch mittels Transmissionspektroskopie untersucht. Im Falle der M-plane GaN-Schichten können zwei fundamentale Übergänge identifiziert werden, wobei der elektrische Feldvektor E des einfallenden Lichtes einmal parallel (z-Polarisation) und einmal senkrecht (x-Polarisation) auf der c-Achse steht. Die M-plane GaN-Schicht besitzt unterschiedliche Dielektrizitätskonstanten für z-Polarisation und x-Polarisation, welche zu zusätzlichem Dichroismus und Doppelbrechung führen. Als Resultat findet eine Filterung der Polarisation für einfallendes, linear polarisiertes Licht statt. Die elektrische Feldkomponente mit x-Polarisation wird stärker absorbiert als die Komponente mit z-Polarisation. Diese Polarisationsfilterung äußert sich für schmalbandiges Licht in Form einer Drehung der Polarisationsebene in Richtung der c-Achse, wobei ein maximaler Rotationswinkel von 40 Grad gefunden wurde.
In this work, we focus on the optical response of GaN thin films grown along various orientations. The optical properties of strained M- and A- and unstrained C-plane GaN thin films are investigated, and the results are explained with help of band-structure calculations. We calculate the strain-induced band-structure modification using the k.p perturbation approach. The valence-band (VB) states are modified affecting both the transition energies as well as the oscillator strengths. We observe that C-plane GaN does not show any in-plane polarization anisotropy, when an isotropic in-plane strain is applied. For the case of M- and A-plane GaN, one expects to see an in-plane polarization anisotropy even for the unstrained case. Additionally, the in-plane strain significantly changes the band structure and the symmetry of the VB states. The three transitions, involving electrons in the conduction band (CB) and holes in the top three VBs, will exhibit a very different polarization characteristic than the ones for C-plane GaN. These transitions are predominantly x, z, and y polarized, respectively, for a certain range of in-plane strain values, present in our samples. For M-plane GaN thin films, two fundamental transitions can be identified, which occur when the electric field vector E is perpendicular (x-polarization) and parallel c (z-polarization). These transitions give rise to a transmittance spectrum separated by 50 meV at room temperature with respect to each other. This result in a polarization filtering of an incident linearly polarized light beam after transmission, because the electric field component with x-polarization is more strongly absorbed than with z-polarization. This filtering manifests as a rotation of the polarization vector toward the c axis and can be as large as 40 degrees for an initial angle of 60 degrees, for our samples.

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Geslain, Alan. "Anisotropie naturelle et induite des matériaux poreux : étude expérimentale et modélisation." Phd thesis, Université du Maine, 2011. http://tel.archives-ouvertes.fr/tel-00718301.

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Ce travail de thèse a pour objectif de caractériser le comportement anisotrope des mousses acoustiques. Ces matériaux, couramment employés pour lutter contre les nuisances sonores et vibratoireset sont modélisés à l'aide du modèle de Biot. Celui-ci est basé sur le formalisme de lamécanique des milieux continus à deux champs couplés, l'un associé au solide et l'autre au fluidesaturant. Nous nous intéresserons plus particulièrement dans ce travail aux paramètres du solideet aux matériaux présentant une anisotropie (c'est-à-dire des propriétés qui varient suivant lesdirections) du squelette solide. Ici, deux types d'anisotropie sont distingués, l'anisotropie naturelledu matériau et celle induite par une action extérieure, cette dernière ayant pour principale cause lacompression statique des échantillons. Par ailleurs, trois types de symétries naturelles sont considérés : isotropie, isotropie transverse avec et sans rotation de direction principale. Celles-ci sont leplus couramment rencontrées.L'analyse expérimentale du type de symétrie des mousses se fait au moyen d'un dispositif, appelé rigidimètre, qui permet de déterminer la raideur mécanique d'échantillons cubiques de moussesous hypothèse quasi-statique. Celui-ci est couplé à une mesure au vibromètre laser à balayage, permettantde mesurer le déplacement normal des faces des cubes. Des lignes de niveaux des champsde déplacements normaux surfaciques sont ainsi obtenues. Il est alors possible de classer les différentstypes d'anisotropie en analysant ces courbes de niveaux. Ainsi, avec ces a-priori, une méthodea été élaborée pour déterminer les coefficients de Poisson à l'aide de techniques de minimisationà partir des autres constantes élastiques préalablement déterminées. Ce problème est construit àpartir d'indicateurs expérimentaux et d'indicateurs provenant d'un modèle éléments finis.L'influence de la compression statique sur les modules élastiques est ensuite étudiée. Toutd'abord, la variation du module d'Young en fonction du taux de compression est caractérisée àpartir de mesures au rigidimètre. Ensuite, la variation du module de cisaillement en fonction de lacompression statique est caractérisée par une méthode d'ondes guidées (en collaboration avec laKULeuven). Il a été montré que les variations de modules élastiques pouvaient être importantespuisqu'elles peuvent atteindre 50 %. A partir de ces déterminations expérimentales, quatre zones decomportement de la mousse ont été mises en évidence. Ces quatre zones correspondent respectivementà des effets de compression, de flambement, de densification et de réarrangement des cellules.Un modèle éléments-finis microstructural, dans lequel la cellule élémentaire est modélisée par untétrakaidécaèdre de Kelvin, est enfin proposé. Celui-ci permet de modéliser les trois premièreszones, qui correspondent aux compressions statiques usuelles dans les applications acoustiques.

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Cuxac, Pascal. "Propagation et atténuation des ondes ultrasoniques dans des roches fissurées et anisotropes." Vandoeuvre-les-Nancy, INPL, 1991. http://docnum.univ-lorraine.fr/public/INPL_T_1991_CUXAC_P.pdf.

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Les recherches présentées dans ce mémoire concernent l'application de la propagation d'ondes ultrasoniques à l'étude de roches fissurées et/ou anisotropes. Ce travail peut être décomposé en quatre grandes parties : la première étape est basée sur l'étude des célérités des ondes compressionnelles et cisaillantes. Celles-ci permettent la détermination des anisotropies des roches aboutissant à une classification selon le degré de symétrie. Cette symétrie impose les directions de propagation et de polarisation nécessaires à la détermination des modules élastiques dynamiques. Un montage dans une cellule triaxiale nous a permis d'étudier l'influence de la contrainte. Celle-ci se traduit par une augmentation des vitesses du fait de la fermeture de fissures. Cependant l'étude complète de l'évolution des paramètres élastiques avec la pression reste impossible dans le cas de roches anisotropes. La deuxième partie aborde la détermination de l'atténuation d'une onde compressionnelle à partir de la méthode du rapport de spectres. Ces mesures réalisées sur roches fortement anisotropes montrent la nécessité de travailler en milieu confiné afin d'avoir un signal de bonne qualité. Le calcul d'atténuation est ensuite appliqué à la caractérisation d'un milieu isotrope fissuré. Un calcul de densité de fissuration relative est tout d'abord proposé à partir des célérités des ondes. Ensuite, à partir de nos essais, nous discutons des diverses théories existantes. Il apparait que nos résultats font intervenir un grand nombre de mécanismes qui ne peuvent être pris en considération par les différents modèles. En milieu anisotrope, ces mesures sont rendues très difficiles par l'apparition de fissures dans le plan d'anisotropie rendant la roche beaucoup trop atténuante. Enfin, l'étude de la propagation d'ultrasons durant un essai de traction directe permet de constater un endommagement précoce du grès étudié. Le calcul des modules élastiques statiques à partir d'essais de compression constitue la troisième partie. L'influence de la pression de confinement et de l'orientation de l'anisotropie est mise en évidence. Dans la dernière partie, nous comparons les modules élastiques obtenus par les deux méthodes. On constate une bonne corrélation des paramètres sauf lorsque la présence de fissures influe sur la mesure ; les modules dynamiques apparaissent alors supérieures aux modules statiques

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25

Le, Laurent Ludovic. "Etude théorique de l'anisotropie magnétique dans des systèmes hybrides pour la spintronique moléculaire." Thesis, université Paris-Saclay, 2020. http://www.theses.fr/2020UPASP071.

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L'anisotropie magnétique est une propriété de grande importance aussi bien pour les applications (stockage magnétiques, ...) que pour son intérêt fondamental. Dans ce manuscrit, nous nous intéressons plus précisément au calcul de l'énergie d'anisotropie magnéto-cristalline (MCA) qui est issue du couplage spin-orbite. C'est une grandeur délicate à déterminer pour plusieurs raisons : elle est en général très faible (de l'ordre du meV par atome au maximum) et elle dépend crucialement de nombreux paramètres physiques et numériques. Elle est notamment fortement dépendante des symétries du système, du réseau cristallin, mais aussi de la nature des matériaux, ici des métaux de transition 3d. Nous nous intéressons plus particulièrement à des couches minces magnétiques pour lesquelles la MCA est calculée comme étant la différence d'énergie du système entre une aimantation parallèle à la surface du matériau et une aimantation orthogonale à celle-ci. Nous utilisons en particulier des codes basés sur théorie de la fonctionnelle densité (DFT, Quantum ESPRESSO et Quantum ATK) et un code de liaisons fortes (TB). La MCA étant obtenue comme une différence d'énergie entre deux orientations de spin en utilisant le théorème de force. L'objectif de cette thèse de doctorat est de comprendre et de décrire en détails le comportement de la MCA dans des films minces magnétiques et les différentes manières de modifier de manière contrôlée (ou non) cette grandeur. Grâce à nos outils de calcul, nous avons extrait des grandes tendances et mis en évidence les paramètres essentiels qui permettent de piloter l'anisotropie. L'une d'entre elles retient particulièrement notre attention, l'hybridation d'orbitales entre un métal de transition 3d et un atome de carbone non-magnétique, donnant lieu d'importantes variations d'anisotropie. De tels systèmes sont dits hybrides, et nous renseignent sur les capacités de transmission du magnétisme (polarisation, anisotropie) entre atomes voisins
Magnetic anisotropy is a property of great importance both for applications (magnetic storage, ...) and for its fundamental interest. In this manuscript, we are more precisely interested in the computation of the magneto-crystalline anisotropy energy (MCA) that results from spin-orbit coupling. It is a delicate quantity to determine for several reasons : it is generally very small (of the order of meV per atom at most) and depends crucially on many physical and numerical parameters. In particular, it is strongly dependent on the symmetries of the system, the crystal lattice, but also on the nature of the materials, in this case the transition metals 3d. We are more particularly interested in magnetic thin films for which the MCA is calculated as the difference in system energy between a magnetization parallel to the surface of the material and a magnetization orthogonal to it. In particular, we use codes based on density functional theory (DFT, Quantum ESPRESSO and Quantum ATK) and a tight-binding code (TB). The MCA being obtained as an energy difference between two spin orientations using the force theorem. The objective of this PhD thesis is to understand and describe in detail the behavior of the MCA in magnetic thin films and the different ways to tune and modify (controllably or not) its magnitude. Thanks to our computational tools, we have extracted the main trends and highlighted the essential parameters that allow us to control the anisotropy. One of them is of particular interest, the hybridization of orbitals between a 3d transition metal and non-magnetic carbon atom, giving rise to important variations in anisotropy. Such systems are called hybrid-systems, and give us information on the transmission of magnetic properties (polarization, anisotropy) between neighboring atoms

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Valadés, Cruz César Augusto. "Polarized super-resolution fluorescence microscopy." Thesis, Aix-Marseille, 2014. http://www.theses.fr/2014AIXM4333.

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Alors que la microscopie super-résolue a apporté une amélioration considérable en imagerie des assemblages moléculaires dans les milieux biologiques à l'échelle nanométrique, son extension à l'imagerie de l'orientation moléculaire, utilisant l'anisotropie de fluorescence, n'a pas encore été complètement explorée. Apporter une information sur l'orientation moléculaire à l'échelle nanométrique aurait un intérêt considérable pour la compréhension des fonctions biologiques. Dans cette thèse, nous proposons une technique de microscopie super-résolution résolue en polarisation, capable d'imager les comportements d'orientation moléculaire dans des environnements statiques et dynamiques, dans le but de rapporter une information structurale à l'échelle de la molécule unique et à des échelles spatiales nanométriques. En utilisant la microscopie par reconstruction stochastique (dSTORM) en combinaison avec une détection polarisée, des images d'anisotropie de fluorescence sont reconstruites avec une résolution spatiale de quelques dizaines de nanomètres. Nous analysons numériquement le principe de la méthode en combinaison avec des modèles des mécanismes d'orientation moléculaire. Enfin, nous proposons une technique alternative basée sur l'émission de molécules uniques en fluctuations stochastiques: l'imagerie super-résolue polarisée par fluctuations (polar-SOFI), et comparons cette approche avec la précédente. Nous illustrons les deux techniques pour l'imagerie de l'ordre moléculaire dans des fibres de stress d'actine et de tubuline dans des cellules fixées, des fibres d'ADN et des fibrilles d'amyloïde à base d'insuline
While super-resolution microscopy has brought a significant improvement in nanoscale imaging of molecular assemblies in biological media, its extension to imaging molecular orientation using fluorescence anisotropy has not yet been fully explored. Providing orientational order information at the nanoscale would be of considerable interest for the understanding of biological functions since they are intrinsically related to structural fundamental processes such as in protein clustering in cell membranes, supra-molecular polymerization or aggregation. In this thesis, we propose a super-resolution polarization-resolved microscopy technique able to image molecular orientation behaviors in static and dynamic environments, in order to report structural information at the single molecule level and at nanometric spatial scale. Using direct Stochastic Optical Reconstruction Microscopy (dSTORM) in combination with polarized detection, fluorescence anisotropy images are reconstructed at a spatial resolution of a few tens of nanometers. We analyze numerically the principle of the method in combination with models for orientational order mechanisms, and provide conditions for which this information can be retrieved with high precision in biological samples based on fibrillar structures. Finally, we propose an alternative technique based on stochastic fluctuations of single molecules: polarized super-resolution optical fluctuation imaging (polar-SOFI), and compare this approach with the previous one. We illustrate both techniques on molecular order imaging in actin stress fibers and tubulin fibers in fixed cells, DNA fibers and insulin amyloid fibrils

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Rubert, José Benaque. "Grandes deformações e anisotropia por tensores de mapeamento aplicados a problemas de materiais compostos e na conformação de metais." Universidade de São Paulo, 1997. http://www.teses.usp.br/teses/disponiveis/18/18134/tde-21032018-092739/.

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Este trabalho tem por objetivo demonstrar a viabilidade do emprego da teoria de interação de substâncias no contínuo para a análise de compostos multifásicos, sendo possível considerar-se substâncias anisótropas através de sua representação via uma formulação isótropa equivalente. No campo teórico, referente à anisotropia via formulação isótropa equivalente, deduzem-se tensores de mapeamento de tensões e deformações para o espaço fictício na configuração deformada, adequados às análises com grandes deformações. Os modelos de materiais compostos e de anisotropia propostos, foram implementados no âmbito de um código de cálculo para análise dinâmica explícita com grandes deformações. Entre as aplicações do programa destacam-se o estudo de problemas de conformação de lâminas metálicas e de compostos multifásicos e a possibilidade de analisar compostos de matriz frágil reforçada por fibras curtas, considerando-se uma função simples de dano elasto-plástico. Os exemplos executados mostram boa concordância dos resultados obtidos neste trabalho com aqueles obtidos por outros autores e com alguns resultados experimentais existentes.
The aim of this work is to valuate the performance of the theory of interacting substances in the continuum (role of mixtures) applied to composites including anisotropic substances which are modeled by an isotropic equivalent formulation. In the theoretical field, with respect to the anisotropy consideration by an equivalent isotropic formulation on the deformed configuration, convenient mapping tensors for stresses and strains in the fictitious space are deduced and applied to large deformation problems. The proposed models of anisotropy and composites were implemented in an explicit code for dynamic analysis with large deformations. The code is applied to the solution of sheet metal forming processes and multiphase composites including an analysis of a brittle matrix composite reinforced by short fibers by a simple elastoplastic damage model. The numerical results of the chosen examples are in good agreement with those suggested in some references or with some reported experiments.

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Alves, Jozismar Rodrigues. "Difusão rotacional em membrana e anisotropia de fluorescência." Universidade de São Paulo, 2012. http://www.teses.usp.br/teses/disponiveis/43/43134/tde-27032013-121603/.

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Propriedades estruturais de membranas modelo, tais como as vesículas lipídicas, podem ser investigadas através da adição de sondas fluorescentes. Após sua incorporação aos sistemas biomoleculares, as moléculas fluorescentes são excitadas por luz linearmente polarizada e a emissão de fluorescência é despolarizada, devido à difusão translacional e também à difusão rotacional do fluoróforo, durante o tempo de vida do estado excitado. O monitoramento da luz emitida é feito através da técnica de fluorescência resolvida no tempo, em que são acompanhadas, por um lado, a intensidade da luz emitida, que fornece o tempo de decaimento da fluorescência, dependente do meio, e, por outro, o decaimento da anisotropia nas componentes da luz emitida, cujos tempos de correlação rotacional informam sobre a fluidez do meio. Uma molécula muito usada como sonda fluorescente é o DPH. Este fluoróforo, bastante hidrofóbico, possui simetria molecular uniaxial, e seus momentos de transição de absorção e emissão são colineares. Um dos usos desta sonda é no acompanhamentos da fluidez da bicamada lipídica ao longo da transição de fase das cadeias. A interpretação de dados experimentais requer modelos para a localização das moléculas fluorescentes, bem como para as possíveis restrições a seu movimento. Neste estudo, apresentamos três modelos para a difusão de moléculas fluorescentes uniaxiais, como o DPH, sugeridos em diversos artigos da literatura. O primeiro modelo consiste de um dipolo com rotação livre aleatória em solução homogênea, e serve como base para os modelos de difusão em meios anisotrópicos. No segundo modelo, consideramos rotações aleatórias dos dipolos reemissores no interior de cones distribuídos com seus eixos perpendiculares à vesícula esférica, geometria que pode refletir o movimento da sonda com eixo em media paralelo às cadeias lipídicas, restrito por elas. No terceiro modelo, o dipolo rotacional no plano da bicamada de geometria esférica, movimento que poderia ocorrer entre as monocamadas que constituem a bicamada. Para cada um dos modelos propostos analisamos a difusão rotacional da sonda através de dois métodos: (i) resolvemos a equação de difusão, para uma única molécula, levando em conta as condições de contorno impostas pelos modelos e determinamos a probabilidade da molécula ser encontrada com uma dada configuração em um tempo t. considerando a distribuição de moléculas na geometria proposta, obtemos a expressão analítica para a anisotropia de fluorescência. No caso da geometria do cone, a solução é obtida numericamente; (ii) realizamos simulações numéricas do passeio aleatório rotacional restrito, nas geometrias correspondentes, método muito útil no caso de geometrias de baixa simetria ou de composição de geometrias. Realizamos um estudo exploratório dos dados experimentais para DPH em membrana modelo, à luz dos resultados para os dois modelos propostos para este meio anisotrópico.
Structural properties of model membranes, such as lipid vesicles, may be investigated through the addition of fluorescent probes. After incorporation into the biomolecular system, the fluorescent molecules are excited with linearly polarized light and the fluorescence emission is depolarized due to translational as well as rotational diffusion during the life-time of the excited state. The monitoring of emitted light emitted informs on fluorescence decay times, and the decay of the components of the emitted light yield rotational correlation times which inform on the fluidity of the medium. The fluorescent molecule DPH, of uniaxial symmetry, is rather hydrophobic and has collinear transition and emission moments. It has been used frequently as a probe for the monitoring of the fluidity of the lipid bilayer along the phase transition of the chains. The interpretation of experimental data requires models for localization of fluorescent molecules as well as for possible restrictions on their movement. In this study, we develop calculations for three models for uniaxial diffusion of fluorescent molecules, such as DPH, suggested in several articles in the literature. The first model consists of a free randomly rotating dipole in a homogeneous solution, and serves as the basis for the study of the diffusion of models in anisotropic media. In the second model, we consider random rotations of emitting dipoles distributed within cones with their axes perpendicular to the vesicle spherical geometry: this could mimic the movement of the probe axis parallel to an average lipid chain. In the third model, the dipole rotates in the plane of the bilayer spherical geometry, within a movement that might occur between the monolayers forming the bilayer. For each of the models proposed, two methods are used by us in order to analyse the rotational diffusion: (1) solution of the corresponding rotational diffusion equation for a single molecule, taking into account the boundary conditions imposed by the models, for the probability of the fluorescent molecule to be found with a given configuration at time t. considering the distribution of molecules in the geometry proposed, we obtain the analytical expression for the fluorescence anisotropy, except for the cone geometry, for which the solution is obtained numerically; (11) numerical simulations of a rotational random walk restricted in geometries corresponding method very useful in case of low-symmetry geometries or geometries of composition. In this study, we have reproduced existing calculations, in some cases, extended calculations developed previously by other authors, in others, or, still, developed new calculations. As an application of our methodology for analysis of diffusional rotations, we have conducted an exploratory study of the experimental data for DPH in lipid bilayers, in the light of the results for the two models proposed for anisotropic media.

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Simas, Emanuelle Reis. "Fotoquímica de polímeros conjugados contendo centros de transferência de carga e migração de energia." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/75/75131/tde-24032011-093724/.

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Neste trabalho foram estudados os processos de migração e transferência de energia em derivados de polifluoreno, de estrutura totalmente conjugada e de conjugação confinada. A dinâmica de estado excitado dos derivados PF-BNI, PFOPPV e PFPPV foi estudada em solução diluída de diferentes solventes através de espectroscopia eletrônica de alta resolução temporal. O derivado PF-BNI, contendo N-(2-benzotiazol)-1,8-naftalimida (BNI) como terminador da cadeia de poli(9,9\'dioctilfluoreno), foi sintetizado pela rota de Yamamoto. O material apresenta alto rendimento quântico de fluorescência e suas propriedades de emissão são moduladas pela polaridade do solvente. As medidas de fluorescência resolvida no tempo mostraram a migração do exciton singlete ao longo da cadeia polimérica e a formação de um estado excitado de transferência de carga intracadeia (ICCT). Os derivados PFOPPV e PFPPV são copolímeros de fluoreno contendo unidades fluoreno-vinileno-fenileno no segmento cromofórico. No PFOPPV o segmento cromofórico é confinado entre segmentos alifáticos (-(CH2)8-) flexíveis, no PFPPV a cadeia principal é totalmente conjugada. A dinâmica de estado excitado dos derivados, PFOPPV e PFPPV, é caracterizada pela presença de segmentos cromofóricos contendo isômeros cis e trans. No PFOPPV, a sua estrutura segmentada permite a transferência de energia entre os segmentos cromofóricos, via interações dipolo-dipolo. A transferência acarreta a depolarização da emissão de fluorescência. No caso do PFPPV a migração de energia ocorre em menos de 20 ps e o decaimento de fluorescência decorre da emissão de segmentos contendo isômeros cis e trans, já na condição estacionária.
This work reports the study of energy transfer and migration processes in fully conjugated and segmented polyfluorene derivatives. The excited-state dynamics of the derivatives, PF-BNI, PFOPPV and PFPPV was studied in diluted solution of different solvents by means of ultrafast time-resolved spectroscopy. Poly(9,9\'-dioctylfluorene) end-capped with N-(2-benzothiazole)-1,8-naphthalimide, named PF-BNI, was prepared via Yamamoto-coupling reaction. This derivative is a highly fluorescence material with emission modulated by solvent polarity. Time-resolved fluorescence measurements showed the singlet exciton migration through the polymer backbone and the formation of an intrachain charge transfer excited-state (ICCT). PFOPPV and PFPPV are both fluorene copolymers containing fluorene-vinylene-phenylene moieties in the backbone. Whereas the PFPPV backbone is fully conjugated, the chromophore segment in PFOPPV backbone is confined between aliphatic (-(CH2)8-) flexible segments. The excited-state dynamics of both copolymers is characterized by the presence of conjugated moieties containing cis and trans isomers. The segmented structure of PFOPPV allows the resonant energy transfer between the chromophores, which is provided by dipole-dipole interactions. The energy transfer process leads to the depolarization of PFOPPV fluorescence emission. For PFPPV the energy migration occurs in less than 20 ps and the fluorescence decay is ascribed to the emission of chromophore segments containing cis and trans, already in a photostationary condition.

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Martins, Alessandro. "Desenvolvimento do processo de produção e estudo estrutural e magnético de filmes finos ordenados de FePt." Universidade de São Paulo, 2004. http://www.teses.usp.br/teses/disponiveis/43/43134/tde-24022014-153235/.

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Filmes de ligas FePt com uma estrutura quimicamente ordenada Tetragonal de Face Centrada FCT (tipo L1 IND.0) e textura [001] apresentam anisotropia magnética perpendicular, alta coercividade e grande efeito Kerr polar magnetoóptico. Entretanto, filmes completamente ordenados são normalmente obtidos através de um processo de \"sputtering\" com deposições em altas temperaturas do substrato(T IND. S > OU =600 ºC) ou por pós-tratamento térmico em temperaturas maiores que 500 ºC. As pesquisas atualmente em desenvolvimento visam a obtenção dessa estrutura ordenada a temperaturas mais baixas, o que seria mais adequado para aplicações práticas dos filmes. Neste trabalho, procuramos as melhores condições para a preparação de filmes de FePt com a fase ordenada FCT(001) em reduzidas temperaturas. Investigamos a influência do método de deposição, temperatura do substrato, espessura do filme e tipo de substrato sobre o grau de ordem química e textura dos filmes de FePt e, consequentemente, sobre suas propriedades magnéticas. Os filmes finos de ligas Fe IND.xPt IND. x-1(com x = 50 at%) foram preparados por \"Sputtering Magnetron DC\", através de dois diferentes métodos de deposição: pelo usual de codeposição e pelo método de deposiçãO alternada monocamadas atômicas (DAM). Os filmes foram crescidos sobre substratos de SiO IND.2/ Si(100), Si(100) e MgO(100), com e sem uma camada \"buffer\" de Pt ( com espessuras de 50 1 766 nm), sob T IND. s variando de temperatura ambiente a 600 ºC. O \"buffer\" de Pt foi usado para permitir melhores condições para a indução de um crescimento \"epitaxial\" da ordenada fase FCT(001) nos filmes de FePt. Os resultados da caracterização estrutural e magnética realizados através das técnicas de Difração de RAios-X (XRD) e Magnetometria de Amostra Vibrante (VSM) mostram que os substratos de MgO São adequados para induzir um crescimento \"epitaxial\" de filmes de FePt ) com uma estrutura FCT e textura [001]. Entretanto, com o uso de um \"buffer\" de Pt otimizado (com predominante fase FCC(100)), pré-depositado sobre MgO, foram obtifos melhores resultados em termos de \"epitaxia\" conveniente para o ordenamento da estrutura cristalina, para os filmes de FePt preparados por ambos os métodos de deposição. Os resultados mostram também que o efeito de um crescimento \"epitaxial\" induzido varia com a espessura do filme. Em relação ao método de deposição, os resultados revelam a maior eficiência de método DAM em comparação com o métodos de codeposição para a preparação de filmes de FePt com a fase FCT(001), em temperaturas reduzidas (T IND.s < OU = 400ºC). Com o uso do método DAM, foi possível a obtenção da fase ordenanda FCT(001) em filmes de FePt crescidos diretamente sobre o MgO em T IND. s = 400ºC. Para filmes de FePt crescidos sobre Pt/MgO, a formação da fase FCT(001) foi verificada em T IND.s = 200ºC e um alto grau de ordenamento químico (S = 0,88) em T IND. s = 400ºC. Estudos de Espectroscopia de Absorção de Rios-X (XAS) também foram realizados.
FePt alloy films, with a chemically ordered face-centered-tetragonal FCT (type LI IND.0) structure and [001] texture, present perpendicular magnetic anisotropy, high coactivity and large polar magneto-optical Kerr effect. However, completely ordered films are usually obtained either by sputtering process at high substrate temperatures (T IND.s MAIOR IGUAL A 600°C) or by postanneling treatment at temperatures higher than 500°C. For technological purposes the preparation temperatures has to be as low as possible. In this work we have searched the more adequate conditions to preparation of FePt films with ordered FCT(001) phase at reduced temperatures. We have investigated the influence of deposition methods, substrate temperature, thickness of film, and type of substrate on the degree of the chemical ordering and preferred texture of FePt films and, consequently, on their magnetic properties. The Fe IND.xPt IND.1-x alloy thin films (with x SEMELHANTE A 50 at%) were prepared by DC Magnetron Sputtering, via two different deposition methods: a conventional code position method and an alternate monatomic layer (DAM) deposition method. The films were grown on SiO IND.2/Si (100), Si (100) and MgO (100) substrates, with and without a Pt buffer layer (thickness ranging from 50 to 76 nm), at T IND.s varying from room temperature to 600°C. The Pt buffer layer was used for obtaining better conditions to the induction of an epitaxial grown of FePt films with the ordered FCT(001) phase. The results of structural and magnetic characterization performed by X-ray diffraction (XRD) and vibrating sample magnetometry (VSM) show that the MgO substrates are adequate to induce an epitaxial growth of FePt films with a FCT structure and [001] texture. However, with the use of an optimized Pt FCC(100) buffer layer pre-deposited on MgO, the best conditions to an epitaxial induced growth were obtained, by both deposition methods. The results show also that the quality of the epitaxial induced growth depends on the thickness of the film. In relation to the deposition method in comparison to the code position method for preparation of FePt FCT(001) films, at reduced temperatures (T IND.s MENOR IGUAL A 400°C). With the use of the DAM method it was possible to obtain the ordered FCT(001) phase in the FePt film grown directly on MgO, at T IND.s = 400°C. For FePt film grown on Pt/MgO, the formation of the FCT(001) phase was verified at T IND.s = 200°C, and high degree of chemical order (S=0,88) was obtained at T IND.s = 400°C. X-ray Absorption Spectroscopy (XAS) studies also were done.

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31

Bicalho, Elton da Silva [UNESP]. "Estrutura de variabilidade espacial e temporal da emissão de CO2 e atributos do solo caracterizada por dimensão fractal em área de cana-de-açúcar." Universidade Estadual Paulista (UNESP), 2012. http://hdl.handle.net/11449/96815.

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A emissão de CO2 do solo (FCO2) é influenciada por processos físicos, químicos e biológicos que afetam a produção de CO2 no interior do solo e o seu transporte para a atmosfera, variando no tempo e no espaço em função das condições ambientais e do manejo agrícola da área. O objetivo deste estudo foi investigar a correlação existente entre os padrões de estrutura de variabilidade espacial e temporal de FCO2 e atributos do solo, em área de cana-de-açúcar sob sistema de manejo cana crua, por meio de dimensão fractal (DF), derivada a partir de variogramas isotrópicos e anisotrópicos em diferentes escalas espaciais. A área experimental constituiu-se de uma malha regular de 60 × 60 m contendo 141 pontos espaçados em distâncias mínimas que variaram de 0,5 a 10 m. A emissão de CO2, temperatura e umidade do solo foram avaliadas durante 7 dias, sendo determinados os atributos físico e químicos do solo em amostragem na profundidade de 0,0 a 0,1 m. A média de FCO2 variou de 1,26 a 1,77 μmol m-2 s-1 ao longo dos dias, com dependência temporal na média e longa escalas, em alcances superiores a 20 m. Apesar do comportamento isotrópico observado para FCO2, seus valores de DF, calculados para diferentes direções, evidenciaram maior variabilidade temporal na direção paralela à linha de plantio, indicando influência das práticas de manejo adotadas na área. A variabilidade espacial de FCO2 foi mais bem evidenciada na média (20 a 30 m) e longa (40 a 60 m) escalas, com sua estrutura de variabilidade, caracterizada pelo fractograma, correlacionando-se significativamente com a maioria dos atributos do solo e apresentando comportamento similar à observada para a temperatura do solo e volume total de poros. Além disso, os fractogramas permitiram observar o comportamento da dependência espacial e temporal de FCO2 e...
Soil CO2 emission (FCO2) is influenced by physical, chemical and biological factors that affect the production of CO2 in the soil and its transport to the atmosphere, varying in time and space as a function of environmental conditions and agricultural management. The aim of this study was to investigate the correlation between spatial and temporal variability patterns of FCO2 and soil properties in sugarcane area under green management by using fractal dimension (DF), derived from isotropic and anisotropic variogram at different spatial scales. The experimental area consisted of a regular grid of 60 × 60 m containing 141 points spaced at minimum distances ranging from 0.5 to 10 m. Soil CO2 emission, soil temperature and soil moisture were evaluated over a period of 7 days, and soil physical and chemical properties were determined by sampling at a depth of 0.0 to 0.1 m. The average of FCO2 ranged from 1.26 to 1.77 mol m-2 s-1 throughout the days, with temporal dependence in the medium and large scales, at ranges of more than 20 m. Despite the isotropic behavior observed for FCO2, their DF values, calculated for different directions, showed greater temporal variability in the direction parallel to the row, indicating the influence of area management. Spatial variability of FCO2 was better evidenced in the medium (20 to 30 m) and long (40 to 60 m) scales, with its variability structure, characterized by fractogram, significantly correlated with most soil properties and similar behaving to that observed for the soil temperature and total pore volume. In addition, fractograms allowed to observe the behavior of the spatial and temporal dependence... (Complete abstract click electronic access below)

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32

Beres, Jan. "Caractérisation de l'anisotropie d'une plate-forme carbonatée karsifiée : approche méthodologique conjointe sismique et électrique." Phd thesis, Université Paris Sud - Paris XI, 2013. http://tel.archives-ouvertes.fr/tel-00880759.

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Les résultats présentés dans ce document portent sur les anisotropies sismique et électrique d'un massif calcaire fracturé dans des galeries parallèles souterraines. Les fractures étant orientées verticalement, leurs propriétés sont approximées par isotropie transverse horizontale (HTI). Plusieurs méthodes d'inversion ont été étudié pour traiter les données sismiques (temps d'arrivée des ondes P et S); et pour traiter les données de résistivité électrique mesuré dans une configuration pôle-pôle (valeur de potentiel mesuré).Pour traiter les données sismiques (quatre campagnes), les méthodes étudiées dans ce document sont: une tomographie isotrope, une approximation de cosinus, une inversion anisotrope basée sur l'algorithme Monte-Carlo pour les paramètres de la matrice de rigidité (de l'isotropie transverse horizontale) et une tomographie anisotrope pour un milieu avec une isotropie transverse inclinée. Toutes les méthodes conduisent à la conclusion qu'il y a effectivement une anisotropie présente dans le massif rocheux et confirment la direction de la vélocité maximale parallèle à la direction de la fracturation. Une forte anisotropie de 15 % est présente dans la zone étudiée.Pour traiter les données électriques (deux campagnes), les méthodes étudiées sont une approximation de cosinus et une inversion anisotrope basée sur l'algorithme Monte-Carlo pour les paramètres de résistivité transversale ρT, de résistivité longitudinale ρL et de l'angle d'orientation du modèle par rapport au système de référence. La présence à 180° de deux maxima de résistivité apparente par rapport à l'azimut de mesure ne peuvent être modélisés par des approches conventionnelles. Une modélisation conceptuelle d'un maillage des fils conducteurs dans un milieu non conducteur a été développé et montre des résultats prometteurs, avec le succès de la modélisation des deux maxima.Des mesures répétées montrent de légères variations de résistivité apparentes et des variations des ondes P. Les variations des ondes S ne sont pas prononcés, ce qui reflète un changement de la saturation en eau. La porosité de 10-15% est estimé à partir des mesures sismiques.

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33

Ponce, Escudero Carlos. "Structural analysis of tectonic lozenges in anisotropic rocks: fied analysis and experimental modelling." Doctoral thesis, Universitat Autònoma de Barcelona, 2014. http://hdl.handle.net/10803/283937.

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34

Merabtine, Skander. "Etude expérimentale de la multifissuration et de la décohésion de films minces et nanostructures magnétiques sur substrats flexibles : effet sur l'anisotropie magnétique." Thesis, Sorbonne Paris Cité, 2017. http://www.theses.fr/2017USPCD058/document.

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Les systèmes magnétiques flexibles et étirables sont d’intérêt croissant pour le développement de dispositifs électromagnétiques conformables aux surfaces non planes. Dans ce contexte, l’objectif de cette thèse est d’identifier des relations entre phénomènes mécaniques irréversibles (fissuration et délamination) aux grandes déformations et propriétés magnétiques de films minces d’épaisseurs nanométriques (alliages de CoFeB et NiFe) élaborés sur substrat polymère (Kapton®) par pulvérisation magnétron. Dans un premier temps, des essais de traction couplés in situ à la microscopie à forces atomiques ou des mesures de résistance électrique ont permis d’étudier la multifissuration des films minces et les décollements localisés (cloques) subséquents. Ces mesures ont permis de mettre en évidence des domaines de déformations macroscopiques pour lesquels chaque mécanisme était prépondérant. De plus l’énergie d’adhésion a pu être discutée et estimée à partir du suivi des cloques sous déformation. Dans un second temps, des mesures par résonance ferromagnétique effectuées ex situ ont permis de relier les domaines des déformations identifiés précédemment aux évolutions de l’anisotropie magnétique des films minces. De plus, une corrélation entre hétérogénéités de déformations et coefficient d’amortissement de Gilbert a été trouvée. Enfin, les propriétés magnétomécaniques de réseaux de nanolignes de NiFe ont permis de mettre en évidence l’intérêt de la nanostructuration pour ces systèmes magnétiques déformables
Flexible and stretchable magnetic systems are of increasing interest for the development of electromagnetic devices conformable to non-planar surfaces. In this context, the objective of this thesis is to identify the relationships between irreversible mechanical phenomena (cracking and delamination) at large strains and magnetic properties of thin films of nanometric thicknesses (CoFeB and NiFe alloys) deposited on polymer substrate (Kapton®) by magnetron sputtering. In a first time, tensile tests coupled in situ with atomic force microscopy or electrical resistance measurements were used to study thin film multifissuration and subsequent localized debonding (buckles). These measurements made it possible to highlight areas of macroscopic strains for which each mechanism was predominant. In addition, the adhesion energy could be discussed and estimated from the monitoring of the buckles under applied strain. In a second step, ferromagnetic resonance measurements carried out ex situ made it possible to link the previously identified areas of strains to the evolutions of the magnetic anisotropy of thin films. In addition, a correlation between strain heterogeneities and Gilbert damping coefficient was found. Finally, the magnetomechanical properties of NiFe nanowires arrays have made it possible to highlight the advantage of nanopatterning for these deformable magnetic systems

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Loussert, Charles. "Mise en forme topologique : lumière et cristaux liquides." Thesis, Bordeaux, 2014. http://www.theses.fr/2014BORD0325/document.

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Ce travail de thèse consiste en l’étude de la mise en forme topologique de la lumière et de la matière et s’articule autour de deux axes de recherche. Le premier concerne la mise en forme topologique de la lumière à partir d’interfaces spin-orbite à base de cristaux liquides. En l’occurrence, nous montrons dans ce manuscrit que différents systèmes de défauts topologiques naturels permettent de générer des vortex optiques par interaction spin-orbite de la lumière, de manière efficace, accordable en longueur d’onde et reconfigurable en temps réel et donnant accès à des charges topologiques diverses. Tout ceci nous a permis de travailler à des échelles microscopiques et de manière spatialement contrôlée. Ces avancées ouvrent la voie au contrôle de l’état orbital de la lumière sur une large bande spectrale.Le second axe concerne la mise en forme topologique d’un film de cristal liquide cholestérique dans le cadre du stockage de l’information de nature topologique. Nous avons démontré la possibilité de générer une grande diversité de défauts topologiques métastables, de manière contrôlée et reconfigurable, à la fois dans le temps et dans l’espace. Nous avons développé une approche permettant de réduire drastiquement le coût énergétique d’écriture de ces défauts. Nous avons également montré qu’il était possible d’obtenir un nouveau type de mémoire réinscriptible contrôlé par le degré de liberté «spin» du photon
The enclosed work deals with the study of the topological shaping of light and matter and will bedivided into two categories of research. The first focuses on the topological shaping of light from liquid-crystal based spin-orbit interfaces. In particular, we show in this manuscript, that different systems based on the use of natural topological defects behave as highly efficient natural optical spin-orbit encoders, for distinct topological charges, at the micron scale and with spatial control.The operating wave length and operation mode of such interfaces can be tuned in real-time using low voltage electric fields. This breakthrough opens the path to the ultra-broadband control of the light’sorbital state. The second category concerns the topological shaping of a cholesteric liquid crystal film in context of mass data storage. We show the potential to generate metastable topological mi-crostructures in a controlled and reconfigurable way, both in time and space and with a low energy cost. We also demonstrated a new, unique type of rewritable memory, controlled by the«spin»ofthe laser-generated incident photon

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Labalette, Vincent. "Structure and rheology of anisotropic colloids." Thesis, Toulouse, INPT, 2020. http://www.theses.fr/2020INPT0068.

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Les argiles colloïdalles sont des phillosilicates d’hydrure de magnésium (ou d’aluminium) pouvant, de part des substitutions isomorphiques, acquérir une charge négative structurale compensée par la présence de cations au niveau de l’espace interfoliaire ou en surface même du colloïde. Ces nanoparticules ont une forme de palet avec un rapport de forme pouvant varier entre 20 et 100. Lors de leur mise en suspension, les colloïdes s’hydratent provoquant ainsi leur gonflement et le relargage des cations. Les groupements hydroxyles présents en bordure des argiles sont extrêmement dépendants du pH et peuvent ainsi générer une charge de bord positive à bas pH, ou négative à pH élevé. Ainsi les argiles colloïdales en suspension présentent à la fois une anisotropie de forme et de charge. Ces caractéristiques confèrent aux dispersions d’argile des propriétés optiques (argiles ocreuses), mécaniques (fabrication de tuile, enduit) ou même nettoyantes (pouvoir dégraissant) intéressantes. Bien qu’étudié depuis de nombreuses années, le comportement des argiles en suspension reste controversé. C’est dans ce contexte que s’inscrit cette thèse dont l’objectif est de proposer un modèle de simulation « gros-grains » de particules présentant une anisotropie à la fois structurale et de charge et ainsi d’étudier le comportement à l’équilibre et hors équilibre d’une suspension de particules anisotropes. Contrairement au modèle Monte-Carlo habituellement utilisé pour modéliser le comportement à l’équilibre d’une suspension de particules anisotropes, le modèle présenté ici tient compte des interactions hydrodynamiques et permet ainsi d’étudier la dynamique du système, que ce soit lors de la formation de structures à l’équilibre ou suite à l’application de force de cisaillement. Les particules sont modélisées à l’aide d’agrégats de sphères liées entre elles par des ressorts, ou contraintes à un mouvement de corps rigide via les équations de la mécanique du solide. La dynamique des agrégats est étudiée à l’aide du code de simulations de type Accelerated Stokesian Dynamics (ASD) et les interactions électrostatiques modélisées suivant le principe d’additivité de paires avec un potentiel de Yukawa. L’implémentation du modèle à « gros-grain » de particules anisotropes dans le code ASD a ainsi permis d’étudier les structures à l’équilibre et sous écoulement de particules présentant des caractéristiques communes avec la Laponite, une smectite de type 2:1 largement étudiée expérimentalement et numériquement dans la littérature. Dans ce manuscrit, des études concernant ces particules anisotropes sont présentées pour différentes fraction volumique et portées d’interactions électrostatiques. La dynamique de formation des structures au repos (Wigner glass, gel, overlapping coin...) ainsi que leurs évolutions sont discutées. Enfin, la réponse rhéologique de ces structures lors de l’application d’un écoulement cisaillant est étudiée, mettant en lumière l’importance du ratio entre les forces électrostatiques et hydrodynamiques au sein de la dynamique du système. Pour des structures initialement percolées, la réponse du stress à la déformation du système dépend de la microstructure initiale aux temps courts, et possède un comportement rhéofluidifiant ainsi qu’une viscosité finale indépendants de la microstructure initiale
Colloidal clays are hydrous magnesium phyllosilicates (sometimes aluminum), usually bearing a negative structural charge coming from isomorphic substitution compensated by the presence of cations in the basal spacing or on the surface of the colloid. These nanoparticles have a platelet shape with an aspect ratio going from 20 to 100. When immersed in water, clays hydrate and swell, leading to the release of the cations. The hydroxyl group presents on the edge of the particles are sensitive to the pH (titrable sites) resulting in an amphoteric edge charge. At low pH the rim is positively charged and becomes neutral or negative at pH 11. Therefore, suspensions of colloidal clays have both charge and shape anisotropies. Thanks to these features, clay dispersions exhibit interesting optical properties (ochreous clays), mechanical properties (tile manufacturing, surface coating) and even cleaning properties (grease-removing). Although studied for decades, the behavior of colloidal clays remains controversial. In this manuscript, we propose a coarse-grained model to simulate particles with both structural and charge anisotropy. This model allows studying the behavior of colloidal suspensions at equilibrium and under shear flow. Contrary to the Monte-Carlo method usually employed to model the equilibrium behavior of anisotropic particles, the model presented in this thesis takes into account hydrodynamic interactions, allowing the dynamics of the system to be studied. The particles are coarse-grained as clusters of spheres bound by springs or constrained to a rigid body motion thanks to solid mechanics equations. The dynamics of the particles are computed using the Accelerated Stokesian Dynamics code (ASD), and the electrostatic interactions are computed in a pairwise additive fashion with a Yukawa potential. The implementation of this coarse-grained model in the ASD method allows studying the microstructure of anisotropic particles presenting similar features than Laponite, a 2:1 synthetic smectite clay widely studied experimentally and numerically in the literature. Several studies are presented here while varying the volume fraction and the range of electrostatic interactions. The dynamics of formation of the observed structures (Wigner glass, gel, overlapping coin, etc.) and their structural evolution behavior are then discussed. Finally, the rheological response of the different structures to a start-up shear has been studied, highlighting the importance of the ratio between the electrostatic and the hydrodynamic forces. For initially percolated systems, it has been shown that the stress response on the applied strain depends on the initial microstructure at short times, and exhibits shear-thinning and final viscous response independent of the initial structure

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37

Agélas, Léo. "Schémas volumes finis multipoints pour grilles non orthogonales." Thesis, Paris Est, 2009. http://www.theses.fr/2009PEST1048/document.

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Un des ingrédients principaux pour la simulation numérique des écoulements des fluides (hydrocarbures, gaz naturel) en milieux poreux est la discrétisation des termes elliptiques anisotropes et hétérogènes. Dans l’industrie pétrolière, la nécessité d’améliorer la précision des simulations dans les régions proches des puits a suscité l’utilisation de maillages non structurés généraux et des tenseurs de perméabilité pleins. Notre défi a été de trouver des discrétisations consistantes et robustes des termes elliptiques anisotropes, hétérogènes sur maillages généraux. Notre recherche s’est focalisée sur des méthodes volumes finis qui soient consistantes, stables sur maillages polyédriques généraux, robustes par rapport à l’anisotropie et l’hétérogénéité du tenseur de perméabilité, qui mènent à des systèmes linéaires bien conditionnés pour lesquels des stratégies de préconditionnement optimales peuvent être conçues et qui donnent un stencil compact pour réduire les communications dans les implémentations parallèles. Pour répondre à cette recherche, nous avons proposé plusieurs schémas tels que MPFA O généralisé, G scheme, CG method, VFSYM, DIOPTRE. Nous avons prouvé également que toutes ces méthodes convergent sous des hypothèses adéquates à la fois sur le tenseur de perméabilité et le maillage
One of the key ingredients for the numerical simulation of Darcy flow in heterogeneous porous media is the discretization of anisotropic heterogeneous elliptic terms. In the oil industry, the need to improve accuracy in near wellbore regions has prompted the use of general unstructured meshes and full permeability tensors. Our effort has therefore been devoted to find consistent and robust finite volume discretizations of anisotropic, heterogeneous elliptic terms on general meshes. Our research was focused on finite volume methods which are consistent and coercive on general polyhedral meshes as well as robust with respect to the anisotropy and heterogeneity of the permeability tensor ; yield well-conditioned linear systems for which optimal preconditioning strategies can be devised ; have a narrow stencil to reduce the communications in parallel implementations. To answer to this search, we have proposed several scemes such that generalized MPFA O, G scheme, CG method, VFSYM, DIOPTRE. We proved also the convergence of all these methods under suitable assumptions on both the permeability tensor and the mesh

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Müller, Sascha, Sebastian Iwan, Marcel Meyer, and Lothar Kroll. "Integrative Prozess- und Bauteilsimulation für kurzfaserverstärkte Spritzgießbauteile." Universitätsbibliothek Chemnitz, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-226118.

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Thermoplastische Kunststoffe werden zur Steigerung der mechanischen Eigenschaften häufig mit Kurzfasern verstärkt, wodurch sich jedoch eine anisotrope Eigenschaftscharakteristik einstellt. Dies führt oftmals zu ungewohntem Werkstoff- und Bauteilverhalten. Die Fertigungsparameter und -randbedingungen im Spritzgießprozess besitzen einen großen Einfluss auf lokale Faserorientierungen, wovon auch die globalen Bauteileigenschaften abhängen. Für eine werkstoffgerechte Auslegung von derartigen Bauteilen sind tiefgreifende Verständnisse über die mechanischen, thermischen und rheologischen Eigenschaften sowie die Kopplung von Spritzgieß- und Bauteilsimulation unerlässlich. Diese sogenannte integrative Simulation wird am Beispiel eines Strukturbauteiles aufgezeigt.

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Polisano, Kévin. "Modélisation de textures anisotropes par la transformée en ondelettes monogéniques." Thesis, Université Grenoble Alpes (ComUE), 2017. http://www.theses.fr/2017GREAM090/document.

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L’analyse de texture est une composante du traitement d’image qui suscite beaucoup d’intérêt tant les applications qu’elle recouvre sont diverses. En imagerie médicale, les signaux enregistrés sous forme d’images telles que les radiographies de l’os ou les mammographies, présentent une micro-architecture fortement irrégulière qui invite à considérer la formation de ces textures comme la réalisation d’un champ aléatoire. Suite aux travaux précurseurs de Benoit Mandelbrot, de nombreux modèles dérivés du champ brownien fractionnaire ont été proposés pour caractériser l’aspect fractal des images et synthétiser des textures à rugosité prescrite. Ainsi l’estimation des paramètres de ces modèles, a notamment permis de relier la dimension fractale des images à la détection de modifications de la structure osseuse telle qu’on l’observe en cas d’ostéoporose. Plus récemment, d’autres modèles de champs aléatoires, dits anisotropes, ont été utilisés pour décrire des phénomènes présentant des directions privilégiées, et détecter par exemple des anomalies dans les tissus mammaires.Cette thèse porte sur l’élaboration de nouveaux modèles de champs anisotropes, permettant de contrôler localement l’anisotropie des textures. Une première contribution a consisté à définir un champ brownien fractionnaire anisotrope généralisé (GAFBF), et un second modèle basé sur une déformation de champs élémentaires (WAFBF), permettant tous deux de prescrire l’orientation locale de la texture. L’étude de la structure locale de ces champs est menée à l’aide du formalisme des champs tangents. Des procédures de simulation sont mises en oeuvres pour en observer concrètement le comportement, et servir de benchmark à la validation d’outils de détection de l’anisotropie. En effet l’étude de l’orientation locale et de l’anisotropie dans le cadre des textures soulève encore de nombreux problèmes mathématiques, à commencer par la définition rigoureuse de cette orientation. Notre seconde contribution s’inscrit dans cette perspective. En transposant les méthodes de détection de l’orientation basées sur la transformée en ondelettes monogéniques, nous avons été en mesure, pour une vaste classe de champs aléatoires, de définir une notion d’orientation intrinsèque. En particulier l’étude des deux nouveaux modèles de champs anisotropes introduits précédemment, a permis de relier formellement cette notion d’orientation aux paramètres d’anisotropie de ces modèles. Des connexions avec les statistiques directionnelles sont également établies, de façon à caractériser la loi de probabilité des estimateurs d’orientation.Enfin une troisième partie de la thèse est consacrée au problème de la détection de lignes dans les images. Le modèle sous jacent est celui d’une superposition de lignes diffractées (c-a-d convoluées par un noyau de flou) et bruitées, dont il s’agit de retrouver les paramètres de position et d’intensité avec une précision sub-pixel. Nous avons développé dans cet objectif une méthode basée sur le paradigme de la super-résolution. La reformulation du problème en termes d’atomes 1-D a permis de dégager un problème d’optimisation sous contraintes, et de reconstruire ces lignes en atteignant cette précision. Les algorithmes employés pour effectuer la minimisation appartiennent à la famille des algorithmes dits proximaux. La formalisation de ce problème inverse et sa résolution, constituent une preuve de concept ouvrant des perspectives à l’élaboration d’une transformée de Hough revisitée pour la détection ‘continue’ de lignes dans les images
Texture analysis is a component of image processing which hold the interest in the various applications it covers. In medical imaging, the images recorded such as bone X-rays or mammograms show a highly irregular micro-architecture, which invites to consider these textures formation as a realization of a random field. Following Benoit Mandelbrot’s pioneer work, many models derived from the fractional Brownian field have been proposed to characterize the fractal behavior of images and to synthesize textures with prescribed roughness. Thus, the parameters estimation of these models has made possible to link the fractal dimension of these images to the detection of bone structure alteration as it is observed in the case of osteoporosis. More recently, other models known as anisotropic random fields have been used to describe phenomena with preferred directions, for example for detecting abnormalities in the mammary tissues.This thesis deals with the development of new models of anisotropic fields, allowing to locally control the anisotropy of the textures. A first contribution was to define a generalized anisotropic fractional Brownian field (GAFBF), and a second model based on an elementary field deformation (WAFBF), both allowing to prescribe the local orientation of the texture. The study of the local structure of these fields is carried out using the tangent fields formalism. Simulation procedures are implemented to concretely observe the behavior, and serve as a benchmark for the validation of anisotropy detection tools. Indeed, the investigation of local orientation and anisotropy in the context of textures still raises many mathematical problems, starting with the rigorous definition of this orientation. Our second contribution is in this perspective. By transposing the orientation detection methods based on the monogenic wavelet transform, we have been able, for a wide class of random fields, to define an intrinsic notion of orientation. In particular, the study of the two new models of anisotropic fields introduced previously allowed to formally link this notion of orientation with the anisotropy parameters of these models. Connections with directional statistics are also established, in order to characterize the probability distribution of orientation estimators.Finally, a third part of this thesis was devoted to the problem of the lines detection in images. The underlying model is that of a superposition of diffracted lines (i.e, convoluted by a blur kernel) with presence of noise, whose position and intensity parameters must be recovered with sub-pixel precision. We have developed a method based on the super-resolution paradigm. The reformulation of the problem in the framework of 1-D atoms lead to an optimization problem under constraints, and enables to reconstruct these lines by reaching this precision. The algorithms used to perform the minimization belong to the family of algorithms known as proximal algorithms. The modelization and the resolution of this inverse problem, provides a proof of concept opening perspectives to the development of a revised Hough transform for the continuous detection of lines in images

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Dinh, Quoc Dan. "Brazilian test on anisotropic rocks." Doctoral thesis, Technische Universitaet Bergakademie Freiberg Universitaetsbibliothek "Georgius Agricola", 2011. http://nbn-resolving.de/urn:nbn:de:bsz:105-qucosa-76331.

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The present work describes investigations on the anisotropic strength behavior of rocks in the splitting tensile test (Brazilian test). Three transversely isotropic rocks (gneiss, slate and sandstone) were studied in the Lab. A total of more than 550 indirect tensile strength tests were conducted, with emphasis was placed on the investigation of the influence of the spatial position of anisotropic weakness plane to the direction of the load on the fracture strength and fracture or fracture mode. In parallel, analytical solutions were evaluated for stress distribution and developed 3D numerical models to study the stress distribution and the fracture mode at the transversely isotropic disc. There were new findings on the fracture mode of crack propagation, the influence of the disc thickness, the influence of the applying loading angle and angle of the loading-foliation for transversely isotropic material
Inhalt der Arbeit sind Untersuchungen zum anisotropen Festigkeitsverhalten von Gesteinen beim Spaltzugversuch (Brazilian Test). Laborativ wurden drei transversalisotrope Gesteine (Granit, Schiefer und Sandstein) untersucht. Insgesamt wurden mehr als 550 Spaltzugversuche durchgeführt, wobei der Schwerpunkt auf die Untersuchung des Einflusses der räumlichen Lage der Anisotropieebene zur Richtung des Lasteintrages auf die Bruchfestigkeit und das Bruchbild bzw. den Bruchmodus gelegt wurde. Parallel dazu wurden analytische Lösungen zur Spannungsverteilung ausgewertet sowie numerische 3D-Modelle entwickelt, um die Spannungsverteilung sowie den Bruchmodus bei einer transversalisotropen Scheibe zu untersuchen. Es wurden neue Erkenntnisse zum Bruchmodus, der Rissausbreitung, des Einflusses der Scheibendicke, dem Einfluss des Lasteinleitungswinkel sowie des Winkels Lasteintrag - Anisotropieebene für transversalisotropes Material gewonnen

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Leão, Marcio Fernandes. "Análise tensão deformação de uma barragem de concreto em solo residual preponderantemente anisotrópico." Universidade do Estado do Rio de Janeiro, 2015. http://www.bdtd.uerj.br/tde_busca/arquivo.php?codArquivo=9394.

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Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro
Estudos de fundações de obras de arte, como barragens de concreto-gravidade e barragens de terra, devem contemplar todos os esforços atuantes no maciço de fundação, principalmente as tensões e as deformações esperadas durante todo o processo construtivo e no período pós-construtivo. Quando essas estruturas são apoiadas sobre rochas de boa sanidade, a escolha do barramento geralmente favorece a implantação de barragens de concreto. Entretanto, quando os maciços de fundação são formados por solos, a opção técnica geralmente mais bem aceita é quanto à utilização de barragens de terra. Em ambos os casos, as análises de estabilidade e de deformação são desenvolvidas por métodos analíticos bem consolidados na prática. Nas condições mais adversas de fundação, seja em rochas ou em solos com marcante anisotropia e estruturas reliquiares herdadas da rocha-mãe, a utilização de modelos constitutivos anisotrópicos em análises por elementos finitos propicia simulações mais realistas dessas feições estruturais, contribuindo para o seu melhor conhecimento. O presente trabalho teve por objetivo demonstrar a utilização de um modelo constitutivo anisotrópico no estudo da fundação da Barragem San Juan, localizada na República Dominicana, que foi concebida como uma estrutura tipo concreto-gravidade apoiada sobre solos residuais jovens altamente anisotrópicos. Nessa obra, apesar de sua pequena altura, a presença marcante de descontinuidades ensejou um estudo mais detalhado do comportamento tensão-deformação da fundação, levando em conta o levantamento detalhado da atitude das descontinuidades presentes no maciço e os resultados de ensaios de resistência em planos paralelos e normais às descontinuidades. Para a estimativa de deformações, os respectivos módulos de Young (Es) foram estimados com base em correlações com a resistência à penetração SPT desenvolvidas nesta dissertação, a partir de um estudo estatístico baseado em várias publicações disponíveis na literatura. As análises numéricas por elementos finitos foram desenvolvidas através do programa Plaxis 2D, utilizando-se como modelo constitutivo aquele denominado The Jointed Rock Model, que é particularmente recomendado para análises de estabilidade e deformação de materiais anisotrópicos. Os resultados das análises numéricas foram comparados com as análises de equilíbrio limite elaboradas para o projeto executivo da referida barragem, pelo programa Slope, utilizando o método rigoroso de Morgenstern e Price, que se mostrou conservador. Os resultados das análises numéricas mostraram sua inequívoca versatilidade para a escolha de opções de reforço da fundação, através de dentes que objetivavam o aumento das condições de estabilidade da barragem.

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Nicolas, Elias Antonio. "Estudo de criterios de resistencia de materiais anisotropicos aplicados a madeira." [s.n.], 2006. http://repositorio.unicamp.br/jspui/handle/REPOSIP/257999.

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Orientador: Nilson Tadeu Mascia
Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Civil, Arquitetura e Urbanismo
Made available in DSpace on 2018-08-07T08:37:01Z (GMT). No. of bitstreams: 1 Nicolas_EliasAntonio_D.pdf: 5212612 bytes, checksum: 6374b5ff3649878b30250be16c1a8e76 (MD5) Previous issue date: 2006
Resumo: Esta pesquisa refere-se ao estudo de critérios de resistência de materiais anisotrópicos, especialmente o critério tensorial de resistência de TSAI- WU, com aplicações teóricas e experimentais para a madeira. Neste sentido foi realizada uma revisão teórica dos principais temas relacionados à presente pesquisa, como: critérios gerais de resistência, fórmula de hankinson, critério de TSAIWU, modos de ruptura da madeira, fatores que influenciam na resistência da madeira,equipamentos e corpos-de-prova para realização de ensaios uniaxiais e biaxiais, prescrições de cálculo das normas de estruturas de madeira. O objetivo principal deste trabalho foi determinar os parâmetros de resistência do critério tensorial de TSAI-WU, com a finalidade de definir uma superfície de ruptura, para a espécie de madeira estudada, cupiúba (Goupia glabra), e comparar os dados dos ensaios com as estimativas do critério. No estudo experimental foram realizados os seguintes ensaios: tração e compressão, uniaxiais, com ângulos das fibras inclinados em relação ao carregamento (0°, 15°, 30°, 45°, 60°, 75° e 90°); ensaios de cisalhamento paralelo às fibras e ensaios de compressão biaxial. As estimativas do critério de TSAI- WU ficaram próximas das estimativas da fórmula de Hankinson e também dos dados dos ensaios uniaxiais de tração e compressão. Por outro lado, para ensaios biaxiais, o critério de TSAI-WU sofre grande influência do coeficiente de interação.De um modo geral, o critério de TSAI-WU apresenta bons resultados, facilidade de utilização se comparado a outros critérios, devido especialmente a seu caráter tensorial, podendo ser aplicado na avaliação de resistência da madeira e de outros materiais anisotrópicos
Abstract: This research deals with the study of anisotropic material failure criteria, specifically TSAI- WU tensor failure criteria, and theoretical and experimental applications for wood. Thus it was carried out a theoretical revision of the principal themes related to this research: general failure criteria, Hankinson's formula, TSAI-WU tensor criterion, failure modes of wood, factors that affect wood strength, equipaments and specimens for development of uniaxial and biaxial tests and rules of design codes of wood structures. The main objective of this work was to determine the TSAI-WU tensor failure criterion parameters, with the purpose of defining the failure surface, for the wood specie Cupiúba (Goupia Glabra) and of comparing the test results and criterion estimates as well. In the experimental development it was performed the following axial tests: tension and compression, with inclined grain angles in related to the load (0°, 15°, 30°, 45°, 60°, 75° and 90°); shear tests and biaxial compression. The estimates of TSAI-WU criterion were close of Hankinson's formula and the tension and compression tests results too. On the other hand, for biaxial compressive test, TSAI- WU criterion influence ofthe interaction coefficient (F12). In general, TSAI- WU criterion can be applied to evaluate wood strength and other anisotropic materials too, by presenting good results and facility in utilizing especially when comparing to other criteria due to its tensor form
Doutorado
Estruturas
Doutor em Engenharia Civil

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43

Preza, Sérgio Leandro Espindola. "Localização e dinâmica de sondas fluorescentes em modelos de membranas: estudos por dinâmica molecular e anisotropia de fluorescência resolvida no tempo." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/59/59135/tde-01042014-112145/.

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As moléculas AHBA (2-Amino-N-hexadecil-benzamida) e DPH (1,6-Difenil-1,3,5- hexatrieno) são sondas fluorescentes com características particulares, comumente utilizadas para monitorar diferentes regiões das bicamadas lipídicas, no entanto, pouco se sabe sobre a mobilidade e dinâmica destas sondas em membranas e quais os principais fatores que influenciam as suas interações com solventes polares e apolares. Esta tese teve por objetivo estudar essas sondas em diferentes ambientes, para ampliar o entendimento de suas estruturas, mobilidade e dinâmicas rotacionais em diferentes solventes e em bicamadas lipídicas. Utilizou-se a técnica de Dinâmica Molecular (DM) para obter as trajetórias das sondas em caixas com diferentes proporções de água e 1,4-dioxano e também nas membranas de POPC (1-palmitoil-2-oleoil-sn-glicerol-3-fosfocolina) e DMPC (1,2-dimiristoil-sn-glicerol-3-fosfocolina). Com as trajetórias geradas, foram analisadas a estrutura, a solvatação e a dinâmica rotacional das sondas em misturas de solventes e membranas modelo. Para as DM em solventes, os resultados indicaram um comportamento atípico das duas moléculas, com a diminuição da interação com a água a medida que diminuía-se a proporção de 1,4-dioxano na caixa. Em membranas, a localização e mobilidade da sonda AHBA apresentaram comportamento semelhante em POPC e DMPC, com os tempos obtidos a partir da curva de autocorrelação rotacional do seu dipolo comparáveis aos medidos pelo experimento de anisotropia de fluorescência resolvida no tempo. Já para o DPH, os resultados em POPC indicaram que a sonda alinha-se paralelamente à superfície da membrana e apresenta muito mais liberdade para se movimentar quando comparada às aos resultados de DM em DMPC, onde a sonda se alinhou paralelamente às caudas dos fosfolipídios e teve uma restrição bem maior para seus movimentos. Os tempos de correlação rotacional do seu dipolo em POPC apresentaram boa concordância com os obtidos experimentalmente. Em contrapartida, os resultados em DMPC mostraram que é preciso mais tempo de DM para comparação entre a correlação rotacional teórica e a experimental, por ser um sistema mais compactado. De qualquer forma, os resultados indicam que a DM é uma técnica promissora para modelagem da dinâmica rotacional de moléculas em membranas.
AHBA (2-Amino-N-hexadecyl benzamide) and DPH (1,6-diphenyl-1,3,5-hexatriene) molecules are fluorescent probes with particular characteristics commonly used to monitor different regions of the lipid bilayers, however, little is known about the mobility and dynamics of these probes in membranes and the main factors that influence their interactions with polar and non-polar solvents. This thesis aimed to study these probes in different environments, to extend the understanding of their structures, mobility and rotational dynamics in different solvents and in lipid bilayers. It was used the Molecular Dynamic (MD) technique to obtain the trajectories of the probes in boxes with different proportions of water and 1,4-dioxane, and also in membranes of POPC (1-palmitoyl-2- oleoy l-sn-glycerol-3 -phosphocholine) and DMPC (1,2-dimyristoyl-sn-glycerol-3-phosphocholine). With the trajectories generated, the structure, solvation and rotational dynamics of the probes were analyzed in solvent mixtures and model membranes. For simulations in solvents, the results indicate an atypical behavior of the two molecules with the decrease of the interaction with water, when decreased the proportion of 1,4-dioxane in the box. In membranes, the location and mobility of AHBA showed similar behavior for on DMPC and POPC, with the decay times obtained from the dipole rotational autocorrelation curve comparable to experimental time-resolved fluorescence anisotropy data. For the DPH in POPC, the results indicated that the probe is aligned parallel to the membrane surface and is much more free to move when compared to simulations in DMPC, where the probe is aligned parallel to the tails of the phospholipids, and had a greater restriction for their movement. The rotational correlation times of their dipole in POPC showed good agreement with those obtained experimentally. On the other hand, the results in DMPC, showed that it needs more time of simulation for comparison between the theoretical and experimental rotational correlation, because it a more compressed system. In any way, the results indicate that MD is a promising technique for modeling the rotational dynamics of molecules in membranes.

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Macêdo, Jorge Andrey da Silva. "Formalismo FDTD para a modelagem de meios dispersivos apresentando anisotropia biaxial." Universidade de São Paulo, 2008. http://www.teses.usp.br/teses/disponiveis/18/18155/tde-15102008-135510/.

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Este trabalho apresenta um novo formalismo bi-dimensional em diferenças finitas no domínio do tempo (2D-FDTD) para a simulação de estruturas baseadas em metamateriais. A natureza dispersiva destes meios é levada em consideração de forma precisa pela inclusão dos modelos materiais de Drude para os tensores permissividade elétrica e permeabilidade magnética. Todos os elementos dos tensores são considerados neste formalismo, o que o torna muito atraente para a modelagem de uma classe geral de estruturas eletromagnéticas. Dois efeitos de enorme impacto são analisados em detalhes, sendo eles a cobertura de invisibilidade e o rotacionamento de campo. Ambos os efeitos requerem a utilização de técnicas de transformação de coordenadas a qual deve ser aplicada apenas na região onde os campos eletromagnéticos precisam ser manipulados, tirando vantagem da invariância das equações de Maxwell quanto a estas operações. Esta técnica redefine localmente os parâmetros de permissividade e permeabilidade do meio transformado. O formalismo implementado apresentou grande estabilidade e precisão, uma conseqüência direta da natureza dispersiva dos modelos materiais de Drude, o que o caracteriza como uma boa contribuição para uma completa compreensão da fenomenologia por trás destes efeitos fascinantes. Os resultados numéricos apresentaram boa concordância com os disponíveis na literatura. Foi também observado que ambas estruturas são muito sensíveis a variações de freqüência do campo de excitação.
This work introduces an extended two-dimensional finite difference time domain method (2D-FDTD) for the simulation of metamaterial based structures. The dispersive nature of these media is accurately taken into account through the inclusion of the Drude material models for the permittivity and permeability tensors. All tensor elements are properly accounted for, making the formalism quite attractive for the modeling of a general class of electromagnetic structures. Two striking effects are investigated with the proposed model, namely, the invisibility cloaking and the field rotation effects. Both effects require the utilization of a coordinate transformation technique which must be applied only in the region where the electromagnetic field needs to be manipulated, taking advantage of the invariance of Maxwell\'s equations with respect to these operations. This technique locally redefines the permittivity and permeability parameters of the transformed media. The implemented formalism has proved to be quite stable and accurate, a direct consequence of the dispersive nature of the Drude material model, which characterizes it as a good contribution to fully understand the phenomenology behind these fascinating effects. The numerical results are in good agreement with those available in the literature. It was also verified that both structures are very sensitive to frequency variations of the excitation field.

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Bicalho, Elton da Silva. "Estrutura de variabilidade espacial e temporal da emissão de CO2 e atributos do solo caracterizada por dimensão fractal em área de cana-de-açúcar /." Jaboticabal : [s.n.], 2012. http://hdl.handle.net/11449/96815.

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Orientador: Newton La Scala Júnior
Coorientador: Alan Rodrigo Panosso
Coorientador: Gener Tadeu Pereira
Banca: José Garcia Vivas Miranda
Banca: Zigomar Menezes de Souza
Resumo: A emissão de CO2 do solo (FCO2) é influenciada por processos físicos, químicos e biológicos que afetam a produção de CO2 no interior do solo e o seu transporte para a atmosfera, variando no tempo e no espaço em função das condições ambientais e do manejo agrícola da área. O objetivo deste estudo foi investigar a correlação existente entre os padrões de estrutura de variabilidade espacial e temporal de FCO2 e atributos do solo, em área de cana-de-açúcar sob sistema de manejo cana crua, por meio de dimensão fractal (DF), derivada a partir de variogramas isotrópicos e anisotrópicos em diferentes escalas espaciais. A área experimental constituiu-se de uma malha regular de 60 × 60 m contendo 141 pontos espaçados em distâncias mínimas que variaram de 0,5 a 10 m. A emissão de CO2, temperatura e umidade do solo foram avaliadas durante 7 dias, sendo determinados os atributos físico e químicos do solo em amostragem na profundidade de 0,0 a 0,1 m. A média de FCO2 variou de 1,26 a 1,77 μmol m-2 s-1 ao longo dos dias, com dependência temporal na média e longa escalas, em alcances superiores a 20 m. Apesar do comportamento isotrópico observado para FCO2, seus valores de DF, calculados para diferentes direções, evidenciaram maior variabilidade temporal na direção paralela à linha de plantio, indicando influência das práticas de manejo adotadas na área. A variabilidade espacial de FCO2 foi mais bem evidenciada na média (20 a 30 m) e longa (40 a 60 m) escalas, com sua estrutura de variabilidade, caracterizada pelo fractograma, correlacionando-se significativamente com a maioria dos atributos do solo e apresentando comportamento similar à observada para a temperatura do solo e volume total de poros. Além disso, os fractogramas permitiram observar o comportamento da dependência espacial e temporal de FCO2 e... (Resumo completo, clicar acesso eletrônico abaixo)
Abstract: Soil CO2 emission (FCO2) is influenced by physical, chemical and biological factors that affect the production of CO2 in the soil and its transport to the atmosphere, varying in time and space as a function of environmental conditions and agricultural management. The aim of this study was to investigate the correlation between spatial and temporal variability patterns of FCO2 and soil properties in sugarcane area under green management by using fractal dimension (DF), derived from isotropic and anisotropic variogram at different spatial scales. The experimental area consisted of a regular grid of 60 × 60 m containing 141 points spaced at minimum distances ranging from 0.5 to 10 m. Soil CO2 emission, soil temperature and soil moisture were evaluated over a period of 7 days, and soil physical and chemical properties were determined by sampling at a depth of 0.0 to 0.1 m. The average of FCO2 ranged from 1.26 to 1.77 mol m-2 s-1 throughout the days, with temporal dependence in the medium and large scales, at ranges of more than 20 m. Despite the isotropic behavior observed for FCO2, their DF values, calculated for different directions, showed greater temporal variability in the direction parallel to the row, indicating the influence of area management. Spatial variability of FCO2 was better evidenced in the medium (20 to 30 m) and long (40 to 60 m) scales, with its variability structure, characterized by fractogram, significantly correlated with most soil properties and similar behaving to that observed for the soil temperature and total pore volume. In addition, fractograms allowed to observe the behavior of the spatial and temporal dependence... (Complete abstract click electronic access below)
Mestre

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46

Croix, Patrick. "Endommagement et rupture des métaux anisotropes pour la dynamique et le crash de véhicules." Valenciennes, 2002. https://ged.uphf.fr/nuxeo/site/esupversions/35d379a9-0ce7-47e2-b08f-5ae639026583.

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La forme et l'orientation des microcavités sont prises en compte dans le modèle éléments finis développé pour améliorer la prédiction d'apparition et de propagation de fissures. La loi d'évolution de porosité due à la nucléation est modifiée pour répondre au problème de la non évolution de l'endommagement en cisaillement pur. Une procédure d'identification par méthode inverse des paramètres d'endommagement est mise au point. Cette méthode est basée sur la corrélation des résultats expérimentaux et numériques, d'essais de traction et d'essais de type Arcan. L'identification a été réalisée pour le cas d'un matériau anisotrope en aluminium. Pour obtenir une indépendance à la taille du maillage, deux stratégies sont proposées : par remaillage basé sur un critère d'endommagement et/ou par détermination des paramètres d'endommagement en fonction de la taille du maillage. Ces différents travaux sont illustrés par plusieurs comparaisons expérimentales numériques d'essais sur longeron en aluminium
The shape and orientation of the microvoids are taken into account in the finite element model developed to improve the prediction of cracks occurrence. The evolution law of porosity due to nucleation is modified to solve the problem of the non-evolution of damage in pure shearing. An identification procedure of damage parameters by the inverse method is developed. This method is based on the correlation of experimental and numerical results, obtained from tensile and Arcan tests. The identification was carried out in the case of an anisotropic aluminium material. To obtain an independence with the mesh size, two strategies are used : by an adaptive meshing based on a damage criterion and/or by the determination of the damage parameters according to the size of the mesh. This work is illustrated by several confrontations of experimental/numerical tests carried out on an extruded aluminium tube

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47

Martin, Rautenberg. "Étude Macro et Microscopique du Comportement Viscoplastique d'Alliages de Zirconium Sollicités Thermo-mécaniquement entre 300°C et 420°C." Thesis, Toulouse, INPT, 2012. http://www.theses.fr/2012INPT0042.

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Dans l'industrie nucléaire, les composants en alliages de zirconium (Zr) sont utilisés comme éléments de structure dans les assemblages combustibles. La fabrication de ces éléments, leur utilisation en Réacteur à Eau Pressurisée (REP) et leur stockage avant retraitement induisent, entre autres, des sollicitations thermo-mécaniques complexes. Ce travail, grâce à une approche expérimentale multi-échelles, propose de mieux préciser les mécanismes de déformation qui sont à considérer. Pour cela, nous avons mené, sur des échantillons prélevés sur des composants en alliage de Zr destinés à être utilisés en REP, des essais mécaniques (fluage, traction, relaxation) et, d'autre part, des caractérisations microstructurales. Des essais de fluage multiaxial ont ainsi permis de mettre en évidence une anisotropie de comportement, dont l'origine physique a été montrée au moyen d'analyses en diffraction des électrons rétrodiffusés (EBSD) et d'observations en Microscopie Electronique en Transmission (MET). Par une démarche similaire, nous avons aussi identifié la nature des mécanismes accommodant la déformation à l'échelle du grain et à celle du polycristal. Ainsi, les incompatibilités de déformation intergranulaires et les cinétiques d'écoulement viscoplastiques identifiées expérimentalement s'expliquent par l'intervention de processus de traînage d'espèces en solutions par les dislocations, ainsi que l'activation locale de vieillissement dynamique. Enfin, nous avons esquissé des pistes pour l'utilisation de ces résultats dans des modélisations numériques
In the nuclear industry, zirconium (Zr) based alloys are used as core structural materials in Pressurized Water Reactors (PWRs). The manufacturing of those components, and their environment during or after their use in PWRs induce complex thermo-mechanical loadings. This work, through a multi-scale experimental approach, proposes to focus on the deformation mechanisms that occur during those loadings. Using samples taken from Zr alloy components, we carried out different mechanicals tests (creep tests, tensile tests, relaxation tests) and microstructural characterizations. Results of multiaxial creep tests were correlated to Transmission Electron Microscope (TEM) observations and Electron BackScattered Diffraction (EBSD) analyses. Therefore, the macroscopic creep anisotropy was related to the physical mechanisms observed at the dislocation scale and during mesoscopic measurements. Our conclusions also show that the viscoplastic properties obtained experimentally match a control of dislocation mobility by solute species dragging processes. Further, the intergranular strain incompatibilities that we observed could be explained by local activations of dynamic strain ageing mechanisms. Finally, we used our results to suggest improvements on physically-based modelling techniques

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48

Carlioz, Thomas. "Nucléation et propagation de fissures en conditions anisotropes." Thesis, Paris Est, 2017. http://www.theses.fr/2017PESC1247/document.

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En partant d'une problématique industrielle correspondant à la naissance de fissures lors de l'excavation d'un tunnel dans un matériau argileux, nous proposons de nous intéresser à un sujet plus large qui est celui de la nucléation d'une fissure de dimension macroscopique. Ainsi, des résultats généraux et théoriques sont établis tout au long de ce mémoire. Ces derniers sont toutefois utilisés pour proposer une interprétation aux faciès de fissuration observés lors de l'excavation de galeries de stockage à grandeur profondeur. Dans un premier temps, un modèle géométrique idéalisé pour des fissures est justifié. Cette étude préalable permet à la fois d'acter la nature fermée des fissures susceptibles de nucléer ainsi que d'utiliser le critère mixte en statuant sur le bienfondé d'une étude bidimensionnelle équivalente. En précisant la notion de longueur de nucléation stable et en s'inspirant des outils classiques de la mécanique linéaire de la rupture, nous établissons dans un second temps notre propre critère de nucléation. Pour ce faire, nous proposons, grâce à des modélisations micromécaniques, de revisiter l'approche thermodynamique usuelle dans un cadre adiabatique afin d'être davantage en accord avec la brutalité du phénomène étudié. Par la suite, nous mettons aux points différentes méthodes permettant d'utiliser le critère suggéré. Enfin, le critère est mis en œuvre dans le cadre de la problématique industrielle initiale pour essayer de donner une justification à l'anisotropie des géométries des fissures observées, et ce, en prenant en compte les différentes directions de forage de l'ouvrage. Dans un deuxième temps, nous proposons de nous intéresser, de manière plus prospective, aux problématiques liées aux modèles locaux d'endommagement. Une attention particulière est accordée à la notion de stabilité des états d'équilibre. Ainsi, une adaptation du critère de Hill est proposée et des différences quantitatives sont soulignées lorsqu'un cadre adiabatique, nous paraissant plus justifié, est pris en compte. Enfin, le problème de la localisation de l'endommagement dans un problème unidimensionnel est abordé
Starting from an industrial issue that is cracks onset when excavating a tunnel, this work aims at giving new insights into a more general problematic which is the initiation of macroscopic cracks. Thus, general and theoretical results are established. Nevertheless, they are applied in order to give some explanations to the excavation-induced fractures observed around the deep geological repository. To begin with, an idealised geometrical model is detailed and justified. Thanks to this preliminary work, we establish that the cracks that should be taken into account are closed ones. In addition we show that it's possible for small cracks length to work on an equivalent bidimensionnal problem. This last result allows us to apply the mixed criteria. After giving the definition of a stable crack initiation length we define our own criteria to predict cracks onset. In order to do so and in order to be more in adequacy with the caracter brutal of a crack initiation, we offer through a micromecanic modelisation to deploy the usual thermodynamic approach in an adiabatic context. Different methods to compute the key quantity which is the incremental energy released rate are then built. Finally, the criteria is applied to give some justifications to the anisotropic geometry of the excavation-induced fractures. In a second part of this work, we focuse on the problematics tied to the local damage models. For instance, the notion of stability for an equilibrium state is discussed. Hill's stability critera is adapted to damage problems. Once again, it seems that an adiabatic context is more suited and the differences implied are emphasized. To conclude, we offer to investigate the localisation issue in one dimensionnal problems

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49

Hucht, Alfred. "Temperaturabhängigkeit magnetischer Anisotropien in ultradünnen Filmen - Temperature dependence of magnetic anisotropies in ultra-thin films." Gerhard-Mercator-Universitaet Duisburg, 2001. http://www.ub.uni-duisburg.de/ETD-db/theses/available/duett-09132001-105033/.

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Anisotropies essentially affect magnetism in thin ferromagnetic films of few atomic layers. On the one hand they can stabilize long range order in these systems, on the other hand they strongly influence the orientation of magnetization. The intrinsic causes of anisotropies in these systems are the spin-orbit coupling of the electrons and the long-range magnetic dipole interaction. While the dipole interaction always favors an orientation of magnetization in the plane of the film, spin-orbit coupling can favor different orientations of magnetization on the surface and in the inner layers of the film. This can lead to a competition between anisotropies, which in turn leads to a spin reorientation transition with varying film thickness. This transition can be of varying order, i. e. be continuous or discontinuous. Experiments also find a spin reorientation transition with varying temperature, which until now was not well understood. In the framework of a classical Heisenberg model this transition is investigate d by means of different theoretical methods in the course of this thesis. At zero temperature the system can be dealt with analytically and criteria for the spin reorientation transition and its order are found. Furthermore it is investigated whether the long-range dipole interaction results in a domain ground state. These investigations are extended to finite temperatures by means of a molecular field theory and results are compared to Monte Carlo simulations. It is shown that in contrast to other works the temperature driven spin reorientation transition in the monolayer is discontinuous also in the simulations, whereas in general it is continuous for the bilayer. Consequently the molecular field theory and the Monte Carlo simulations agree qualitatively. Exemplary for thicker films the influence of an external magnetic field is investigated in the bilayer, furthermore the effective anisotropies Kn(T) of the phenomenological Landau theory are calculated numerically for the microscopic model. Analytic expres sions for the dependence of the anisotropies Kn(T) on the parameters of the model are obtained by the means of perturbation theory, which lead to a deeper understanding of the spin reorientation transition. Accordingly to this the origin for the spin reorientation transition lies in the differing temperature dependence of the dipolar and spin-orbit parts of the Kn(T). Additionally the magnetization in the surface of the film decreases more rapidly with increasing temperature. As a consequence the influence of the surface anisotropy decreases with increasing temperature. This effects a similar result as increasing the film thickness and leads to the transition. Finally the model is extended to continuous film thicknesses, since in experiment the spin reorientation transition depends crucially on film thickness. The results of this extended model are compared to experiment and give good agreement.

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50

Terceño, Izaga Mikel. "Papel del diffusion tensor imaging en la resonancia magnética cerebral como marcador predictivo del estado motor y evolución funcional en pacientes con hemorragia intracerebral." Doctoral thesis, Universitat de Girona, 2018. http://hdl.handle.net/10803/565633.

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The present thesis, aims to study whether the evaluation of the CT through DTI and tractography sequences in the first 12 hours from the ICH onset, is able to predict the motor and functional outcome at 3 months. The results of this thesis allow us to affirm that the fractional anisotropy (FA) valours of the CT, evaluated in the first 12 hours since the ICH onset, is an excellent independent and early predictor of motor function and functional prognosis at 3 months in patients with HIC. In addition, the study with the same sequences at 30 days, does not demonstrate better results. Therefore, the inclusion of MRI sequences such as DTI in the study of ICH in the acute phase, would allow the identification of those patients who could benefit from intensive medical and rehabilitative therapies from the first hours, as well as providing information regarding the prognosis to patients and relatives
La presente tesis doctoral, pretende estudiar si la evaluación del TCE mediante secuencias de DTI y tractografía en las primeras 12 horas desde el inicio de la HIC, es capaz de predecir el déficit motor y el estado funcional a los 3 meses. Los resultados de esta tesis permiten afirmar que la anisotropía fraccionada (FA) del TCE, evaluada en las primeras 12 horas desde el inicio de la HIC es un excelente predictor independiente y precoz de la función motora y del pronóstico funcional a los 3 meses en pacientes que sufren una HIC. Además, el estudio mediante la misma técnica a los 30 días, no ofrece mejores resultados. Por tanto, la inclusión de secuencias de RM como el DTI en el estudio de la HIC en la fase aguda, permitiría identificar aquellos pacientes que pudieran beneficiarse de un tratamiento médico y rehabilitador intensivos desde las primeras horas, así como facilitar la información en cuanto al pronóstico a pacientes y familiares

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