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Dissertations / Theses on the topic 'Anthracene'

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1

Davis, Nicola Kathleen Sybille. "Anthracene-fused porphyrins." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:86b0efea-d33a-42e2-9304-82d94e8f895a.

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This thesis describes the synthesis of a novel family of porphyrins fused to anthracenes, together with investigations into their optical and electrochemical properties, as well as exploring their potential for application in dye-sensitised solar cells. Chapter 1 gives an overview of the structure-property relationships of large planar pi- systems for organic electronic applications. Porphyrins are introduced as suitable building blocks for such systems, and approaches for extending the pi-conjugation of these macrocycles are presented. A literature review of porphyrins fused to aromatic units
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2

Destecroix, Harry. "Anthracene based synthetic lectins." Thesis, University of Bristol, 2015. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.682557.

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Over the past 40 years there has been substantial interest in continuous glucose monitors (CGMs) for diabetes management. Much of the work has focused on the use of enzymes, lectins (carbohydrate binding proteins) or boronic acids as the sensing element, but instability and biocompatibility has hindered development. This has presented an 0pp0l1unity for supramolecular chemists to make synthetic lectins for glucose that respond in real time to glucose in the blood. However, carbohydrate recognition in water presents a challenge due to the hydromimetic nature of the substrate. Moreover, subtle s
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3

Najah, Zaid. "Asymmetric synthesis using anthracene auxiliaries." Thesis, University of Sheffield, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.555128.

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Diels-Alder reaction conditions of the chiral anthracene auxiliary, 9-(l-methoxyethyl) anthracene and 2-cyclopenten-I-one were optimised using the microwave irradiation to give three regioisomers in 80: 12:8 ratio. Flash chromatography purification afforded the desired adduct in 45% yield. Subsequent asymmetric transformations on the major cycloadduct were performed in good yield with excellent levels of diastereoselectivity. Alkylation-reduction reactions sequence on the ketone cycloadduct furnished the desired ketones in 65-75% yield and up to 92:8 diastereoselectivity. Corresponding alcohol
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4

Moran, Nina. "Novel anthracene-tagged DNA sensors." Thesis, University of Exeter, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425489.

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5

Duprey, Jean-Louis Henry Alan. "Studies on Anthracene Tagged Oligonucleotides." Thesis, University of Birmingham, 2011. http://etheses.bham.ac.uk//id/eprint/1286/.

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This thesis describes the synthesis, characterization and study of a range of oligonucleotides that were modified by the inclusion of a non-nucleosidic anthracene unit. This involved the synthesis of different stereoisomers of a non-nucleosidic backbone attached to DNA via a carbon chain linker. These monomers were then coupled to short (15-mer) oligonucleotide chains using solid state DNA synthesis and purified using RP-HPLC. Two systems were studied: a duplex with anthracene functioning as a non-bonding base opposite of a natural nucleobase and a wedge type system. The probes were then exami
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6

Dujols, Virginie Elisabeth. "Rhodamine & anthracene-based chemosensors /." The Ohio State University, 1996. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487941504294111.

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7

Wandtke, Sebastian. "Anthracene Based Colorimetric Molecular Sensors." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0022-5DBE-D.

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8

Jiménez, Isaac Ojea. "Asymmetric transformations of chiral anthracene derivatives." Thesis, University of Sheffield, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420699.

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9

Bullen, Gemma Anne. "Anthracene tagged biomolecules for DNA binding." Thesis, University of Birmingham, 2015. http://etheses.bham.ac.uk//id/eprint/6369/.

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Within this thesis, the use of anthracene to perform various applications within biomolecules is assessed. Anthracene displays two interesting photo properties which make it an appealing molecule for incorporation; fluorescence and photodimerisation. The former is utilised to develop a single nucleotide polymorphism detection assay which is shown to allow for determination of the base present in a complementary strand of DNA. In addition to this, the photodimerisation properties of anthracene are used within a protein for the first time. This is utilised to develop a photoswitched binding prot
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10

Mashau, Sharon Ntevheleni. "The preparation of pitches from anthracene oil." Pretoria : [S.n.], 2007. http://upetd.up.ac.za/thesis/available/etd-06242008-075035/.

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11

Gupta, Bindu 1963. "Solubility of anthracene in complex solvent system." Thesis, The University of Arizona, 1989. http://hdl.handle.net/10150/276989.

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The solubility of anthracene was measured in binary and ternary co-solvent-water systems. The binary systems consisted of water and a completely miscible organic solvent (CMOS); while the ternary system incorporated a partially miscible organic solvent (PMOS) into the binary systems. The data were used to test the following model:(UNFORMATTED TABLE OR EQUATION FOLLOWS) log Sᵃ(c,p,w) = log Sᵃ(w) + f(c) σᵃ(c) + [(Sᴾ(w) 10 (f(c) σᴾ(c))/D(p)] σᵃ(p). (TABLE/EQUATION ENDS) The terms on the right of the equality sign are the aqueous solubility of anthracene, the solubility of anthracene in CMOS-water
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12

Pijeat, Joffrey. "Anthracenylporphyrin based building blocks for the bottom-up fabrication of nitrogen-doped graphene nanostructures." Thesis, Université Paris-Saclay (ComUE), 2019. http://www.theses.fr/2019SACLS346/document.

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La synthèse de graphène par approche « bottom-up » fait l’objet de nombreux travaux de recherche ayant pour but de contrôler les propriétés électroniques et optiques de ce matériau par la fabrication de nanostructures avec une précision atomique. D’autre part, le contrôle de dopant dans le graphène permettant d’en moduler les propriétés suscite un grand intérêt et dans ce contexte l’utilisation de porphyrines avec un taux d’azote contrôlé est attrayante. Par leurs ressemblances structurelles, les porphyrines π-étendues peuvent être considérées comme des nanoparticules de graphène dopées à l’az
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13

Atherton, Jonathan Charles Christian. "Novel photoactivated chiral auxiliaries." Thesis, University of Newcastle Upon Tyne, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.273482.

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14

Abood, Norman Anthony. "Synthesis, physico-chemical and biological properties of 5- and 6-fluoro-1,2,3,4-tetrahydro- 7,12-dimethylbenz(a)anthracene /." The Ohio State University, 1987. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487326511713964.

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15

Chen, Peng. "Effects of surfactants on microbial growth on anthracene." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape8/PQDD_0019/MQ47015.pdf.

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16

Bawa, Ramadan Ali. "Electron-rich and electron-deficient anthracene chiral auxiliaries." Thesis, University of Sheffield, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420777.

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17

Rowe, Jennifer Maria. "Luminescent Properties of Anthracene-based Metal-Organic Frameworks." Thesis, Virginia Tech, 2016. http://hdl.handle.net/10919/71684.

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Metal-organic frameworks (MOFs) are crystalline materials composed of metal clusters and organic ligands. MOFs that exhibit photoluminescence are promising materials for a broad range of applications. Due to their structural tunability and crystalline nature, luminescent MOFs also provide an excellent platform for studying structure–property relationships of materials. The photophysical properties of three anthracene-dicarboxylic acids – 1,4-anthracene dicarboxylic acid (1,4-ADCA), 2,6-anthracene dicarboxylic acid (2,6-ADCA) and 9,10-anthracene dicarboxylic acid (9,10-ADCA) – were studied i
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18

Bierly, Pierre-Charles 1952. "Electronic absorption of anthracene in supercritical carbon dioxide." Thesis, The University of Arizona, 1991. http://hdl.handle.net/10150/277852.

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There has been much interest in the last five or ten years in supercritical fluid extraction. In addition to the fact that some supercritical fluids may be less harmful to the environment than traditional extraction solvents, claims have been made for the superior extraction capabilities of supercritical fluids. In a few cases concentrations from absorbance measurements in the supercritical have been calculated with absorptivities derived from studies in liquid systems. This study suggests that the molar absorptivity in the supercritical may be quite different from that in a liquid system. The
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19

Neumann, Anthony. "Bacterial interactions with anthracene in a model soil system." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/mq22647.pdf.

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20

Manchester, Jack Nathaniel. "Photochromic control of nucleic acid systems through anthracene photodimerisation." Thesis, University of Birmingham, 2014. http://etheses.bham.ac.uk//id/eprint/4964/.

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The focus of this project has involved the incorporation of non-nucleosidic anthracene phosphoramidites into oligonucleotide sequences for the purpose of studying anthracene photodimerisation and its effect on DNA structure and function. The primary aim of the research was to use this technique as a method of disrupting hybridisation between complementary oligonucleotides. By introducing two anthracene tags into the same oligonucleotide sequence it is possible to initiate a reversible, light-induced reaction involving the intramolecular dimerisation of the appended anthracene groups. The resul
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21

Vorona, Mikhail. "Anthracene-Based Molecules for Organic Thin-Film Transistor Integration." Thesis, Université d'Ottawa / University of Ottawa, 2020. http://hdl.handle.net/10393/41536.

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Organic electronics are devices based on semiconductors derived from carbon based molecules and polymers. These devices can be made flexible, lightweight and potentially inexpensive with the development of economies of scale. Specific examples of organic electronics include organic thin-film transistors (OTFTs), organic light-emitting diodes (OLEDs) and organic photovoltaic (OPVs). Anthracene-based semiconductors are materials that have generated great interest primarily because of their structural planarity, potential for strong intermolecular interactions, air stability and ideal frontier mo
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22

Ji, Ming Chao. "Molecular relaxation dynamics of Anthracene cations studied in an electrostatic storage ring." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10051.

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Les molécules hydrocarbures aromatiques polycycliques (HAP) sont à l'heure actuelle considérées comme probablement responsables des bandes d'émission infrarouge non identifiées du milieu interstellaire (MIS). La dynamique de refroidissement des molécules HAP est essentielle pour estimer leur photo-stabilité, leur durée de vie et les distributions de taille dans le MIS. Au cours des dernières années, les expériences s'appuyant sur le stockage électrostatique d'ions moléculaires ou d'agrégats sont devenus des outils puissants pour étudier leur refroidissement dans une large gamme de temps allant
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23

Tongpim, Saowanit. "Isolation, growth and metabolism of Rhodococcus strain S1 on anthracene." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/nq23079.pdf.

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24

Al-Isaee, Sulaiman. "Development of anthracene-based conjugated polymers for solar cells applications." Thesis, University of Sheffield, 2017. http://etheses.whiterose.ac.uk/16554/.

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25

Furlong, Patrick Joseph. "Design and synthesis of novel sulphur containing anthracene-9,10-diones." Thesis, Swansea University, 2003. https://cronfa.swan.ac.uk/Record/cronfa42568.

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It is well established that certain anthracene-9,10-diones such as Mitoxantrone (24b) and Amentantrone (24a) are potent anticancer drugs but suffer from the disadvantage that they are also cardiotoxic. Few suffer containing anthracene-9,10-diones have been researched for their biological activity, and the current studies were aimed to synthesise a series of anthracene-9,10-dione derivatives containing both as substituted and as part of the ring system in an endeavour to conserve their anticancer activity but reduce their cardiotoxicity. A series of twenty four anthracene-9,10-diones were synth
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26

Li, Hao. "Anaerobic biodegradation of naphthalene and anthracene using different terminal electron acceptors." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/mq55916.pdf.

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27

Hasbullah, Siti Aishah Binti. "Evaluating the use of chiral anthracene templates to access pyroglutamic acid." Thesis, University of Sheffield, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.556737.

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Approaches to prepare pyroglutamic acid derivatives using a chiral anthracene moiety have been carried out using a nucleophilic carboxylic acid synthon. A model study to prepare five membered ring lactams bearing a quaternary centre via a Ugi-3CR reaction using commercially available levulinic acid 162 was successful, giving the five-membered ring lactams 164a -164g in 72 - 86% yield. A Pd catalysed ring opening of an anthracene anhydride 184 cycloadduct was used to prepare a key keto-acid that unfortunately was a poor substrate for the Ugi reaction due to the geometry of keto acid to give alk
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28

Elsunaki, Tareg Mohamed. "Preparation of polycyclic frameworks by asymmetric transformations of anthracene maleimide cycloadducts." Thesis, University of Sheffield, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.537965.

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29

Finkelmeier, Nils. "Synthesis and Fluorescence Properties of Anthracene Derivatives and their Metal Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2013. http://hdl.handle.net/11858/00-1735-0000-0023-994A-7.

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30

McSkimming, Gordon. "Photo-active anthracene receptors for s-block and d-block metals." Thesis, University of Exeter, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341162.

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31

Transue, Wesley J. "Liberation of low-coordinate phosphorus species from anthracene-based molecular precursors." Thesis, Massachusetts Institute of Technology, 2018. http://hdl.handle.net/1721.1/120876.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemistry, 2018.<br>This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.<br>Page 467 blank. Cataloged from student-submitted PDF version of thesis.<br>Includes bibliographical references.<br>The study of heavier p-block analogs to unsaturated organic small molecules is of fundamental importance, allowing insight into the differing bonding and reactivity patterns that control their synthetic utility. A major complication in this pursu
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32

Entezami, Azam A. (Azam Alsadat). "Aquatic Heterotrophic Bacteria Active in the Biotransformation of Anthracene and Pentachlorophenol." Thesis, North Texas State University, 1985. https://digital.library.unt.edu/ark:/67531/metadc504319/.

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Dominant genera of bacteria were isolated from three river waters during anthracene and pentachlorophenol biotransformation studies. The genera Pseudomonas, Acinetobacter, Micrococcus, Chromobacterium, Alcaligenes, Azomonos, Bacillus, and Flavobacterium were capable of biotransforming one or both of these compounds. These isolates were subjected to further biotransformation tests, including river water and a basal salt medium with and without additional glucose. The results of these experiments were evaluated statistically. It was concluded that only a limited number of the bacteria identified
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33

Kislyak, Anastasia. "In-depth kinetic understanding and design of [4+4] anthracene photocycloadditions." Thesis, Queensland University of Technology, 2021. https://eprints.qut.edu.au/226945/1/Anastasia_Kislyak_Thesis.pdf.

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This thesis pioneers the development of a model to correlate dynamic polymer network structures and their molecular changes in the presence of a light stimulus with the observed mechanical properties. Initially, a reversible anthracene photocycloaddition reaction model is introduced for predicting experimental data in solution and is subsequently extended towards the intramolecular crosslinking of single polymer chains. The model can predict the reaction progress and the radius of gyration of the folded polymers by using chemical reactivities corrected for confinement effects. Finally, the the
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34

Yospanya, Wijak. "Studies on supramolecular photochirogenesis mediated by synthetic antibody and chiral silica-organic hybrid nanoribbons." Thesis, Bordeaux, 2020. http://www.theses.fr/2020BORD0088.

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Dû à l’augmentation de la demande de nouveaux matériaux chiraux, la préparation de molécules chirales est actuellement l'un des domaines les plus essentiels de la chimie synthèse chimique. La photoréaction supramoléculaire est une stratégie efficace de photoréaction régio- et énantio-sélective qui permet d’éviter le problème de la courte durée de vie de l’état excité de la molécule clé-intermédiaire, ainsi que des faibles interactions dues aux états excités. Cette thèse décrit, la photocyclodimérisation supramoléculaire du 2-anthracènecarboxylate à l’aide de deux procédés différents dans l'eau
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35

McElroy, Anne Elizabeth. "Benz(a)anthracene in benthic marine environments : bioavailability, metabolism, and physiological effects on the polychaete Nereis virens /." Woods Hole, Mass. : Woods Hole Oceanographic Institution, 1985. http://hdl.handle.net/1912/3134.

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36

Deeyaa, Blessing D. "DNA Photocleavage by 9-Aminomethylanthracene Dyes at pH 7.0: Ionic Strength Effects." Digital Archive @ GSU, 2011. http://digitalarchive.gsu.edu/chemistry_theses/39.

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DNA photosensitizers are compounds that are capable of binding in to DNA strands through groove binding, intercalation, or electrostatic interactions. Excitation of these agents by light generates reactive oxygen species which causes extensive photo-oxidative damage to genomic DNA. Physiological concentrations of NaCl and KCl are ~ 150 mM and 260 mM within the cell nucleus where DNA is contained. Unfortunately, the ability of most photosensitizers to bind to double-helical DNA is reduced and photocleavage yields are diminished as concentrations of salt increase. The aim of this project is t
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37

Kriegel, Robert Michael. "Anthracene containing polyesters : Homopolymers, copolymers and chain extension via Diels-Alder reactions." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/27265.

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38

Valette, Damien. "Studies into asymmetric Diels-Alder reactions of anthracene derivatives using cationic oxazaborolidines." Thesis, University of Sheffield, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.544175.

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39

Niermeier, Philipp [Verfasser]. "Poly-Akzeptor-Verbindungen auf Basis funktionalisierter Anthracene und ihrer Photodimere / Philipp Niermeier." Bielefeld : Universitätsbibliothek Bielefeld, 2019. http://d-nb.info/1196639531/34.

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40

Vance, David Howard. "Convergency in the synthesis of anthracene-based fluorescent chemosensors and Dephosphorylation reagents /." The Ohio State University, 1993. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487847309050039.

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41

Hosler, Kevin Robert. "A comparison of treatments for anthracene using two bench-scale treatability test methods." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/MQ40418.pdf.

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42

Mohebbi, Ali Reza [Verfasser]. "Synthesis of tubular and belt-like aromatics having anthracene units / Ali Reza Mohebbi." Kiel : Universitätsbibliothek Kiel, 2009. http://d-nb.info/1019867981/34.

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43

Neesu, Rachana. "Fused Arene-Based Molecular Systems as Additives for Organic Photovoltaics." TopSCHOLAR®, 2015. http://digitalcommons.wku.edu/theses/1471.

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Organic photovoltaics (OPVs) are mainly based on organic semiconducting small molecules, macromolecules, and polymers, which form an active layer in photovoltaics. They act as an active material in absorbing light and causing charge mobility to generate electricity from sunlight. This thesis describes the molecular systems derived from fused arenes such as anthracene, pyrene, carbazole and thiophene for use as either a donor or an acceptor component of the active layer of OPVs. Two novel molecular systems (9- anthracenecarboxy-1-methylpyrene, (1) and Py-bi-TH-ANT, (2) were prepared using Stegl
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44

Sathiosatham, Muhunthan. "The synthesis and noncovalent electron-transfer studies of anthracene and dimethylaniline substituted nucleic acid bases and G-quartet formation in the absence of templating metal ions." Digital version:, 2000. http://wwwlib.umi.com/cr/utexas/fullcit?p9992906.

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45

Ozhathil, Lijo Cherian. "A structural and functional insight into TMEM16B, a calcium-activated chloride channel." Doctoral thesis, SISSA, 2014. http://hdl.handle.net/20.500.11767/3921.

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TMEM16B, also known as anoctamin 2 has been recently identified as a calcium-activated chloride channel. It is expressed at the synaptic terminals of photoreceptors, in hippocampal cells, in the cilia of olfactory sensory neurons and in the microvilli of vomeronasal sensory neurons. TMEM16B, as its most known cousin TMEM16A, is activated both by calcium and voltage. When this thesis was started there was no available data correlating the gating function and protein structure in TMEM16B. In our first manuscript, we show a coupling between calcium and voltage in TMEM16B activation. Primary seq
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46

Qasemian, Leila. "Caractérisation du potentiel de dégradation de matières organiques naturelle (litière) et anthropique (HAP) par les communautés microbiennes issue du milieu littoral méditerranéen." Thesis, Aix-Marseille, 2012. http://www.theses.fr/2012AIXM4794/document.

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Les écosystèmes méditerranéens littoraux sont soumis à divers stress environnementaux naturels (stress hydrique et halin) et anthropiques susceptibles de s'intensifier dans les prochaines décennies. Dans ce contexte, le fonctionnement des communautés microbiennes - encore très peu étudiés dans de tels milieux - était important à préciser. L'effet du stress halin sur la transformation de la matière organique dans la litière de pin d'Alep issues des calanques de Marseille a été estimé ainsi que le potentiel de biodégradation d'un polluant chronique, l'anthracène, un Hydrocarbures Aromatiques Pol
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47

Wongwitwichote, Wongwit. "Synthesis and Spectroscopy of Cofacial Distilbenes and Aggregated 9-Substituted Anthracenes." University of Akron / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=akron1285256001.

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48

Islangulov, Radiy Rashitovich. "Low Power Photoluminescence and Photochemical Upconversion." Bowling Green State University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1162244082.

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49

Constable, Thomas. "Developments towards novel dense polymer brushes for device applications." Thesis, Loughborough University, 2015. https://dspace.lboro.ac.uk/2134/17901.

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The research project aimed to synthesise semiconducting polymer brushes (polymer chains densely grafted to a surface) utilising simple and efficient organic chemistry methods, with a view to use in molecular-level electronic applications. Conjugated polymers were initially chosen for their ability to conduct electrical charge along a polymer chain by facilitating electron transfer between π-bonds. Polymers also aimed to be living , which could allow for further chain growth at a later point in time. This could lead to the production of various useful brush block co-polymers, with different blo
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50

Lavie-cambot, Aurélie. "Synthèses et études de récepteurs photomodulables et échangeurs d'ions moléculaires." Thesis, Bordeaux 1, 2010. http://www.theses.fr/2010BOR14128.

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Cette thèse se focalise sur la synthèse multi-étape et l’étude par différentesspectroscopies de plusieurs systèmes supramoléculaires photoactifs. Des sondes fluorescentesmoléculaires capables d’éjecter le Ca2+ de façon réversible ont été élaborées afin de modulerl’arrivée et le départ d’ions Ca2+ dans un milieu. Ces photoéjecteurs basés sur le récepteur àCa2+ BAPTA (l’acide 1,2-bis(2-aminophénoxy)éthane-N,N,N’,N’-tetraacétique) et sur desfluorophores photodimérisables, ont été synthétisés. Leurs comportements photochimiquesont été testés. Ensuite, des échangeurs d’ions moléculaires ont été dév
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