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1

Siddique, Tawsif, Sheeana Gangadoo, Duy Quang Pham, Naba K. Dutta, and Namita Roy Choudhury. "Antifouling and Antimicrobial Study of Nanostructured Mixed-Matrix Membranes for Arsenic Filtration." Nanomaterials 13, no. 4 (2023): 738. http://dx.doi.org/10.3390/nano13040738.

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Membrane fouling is a major drawback in the membrane filtration industry for water treatment. Mixed-matrix membranes (MMMs) are well known for their enhanced antifouling and antibacterial properties, which could offer potential benefits for membrane filtration processes in the water treatment field. In this work, three electrospun nanofibrous MMMs (P, CP, and MCP, which were, respectively, the pristine polysulfone membrane and mixed-matrix membranes (MMMs) consisting of GO–ZnO and GO–ZnO–iron oxides) were studied for antifouling and antibacterial properties with respect to the arsenic nanofilt
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2

Al Harby, Nouf F., Mervette El-Batouti, and Mahmoud M. Elewa. "Prospects of Polymeric Nanocomposite Membranes for Water Purification and Scalability and their Health and Environmental Impacts: A Review." Nanomaterials 12, no. 20 (2022): 3637. http://dx.doi.org/10.3390/nano12203637.

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Water shortage is a major worldwide issue. Filtration using genuine polymeric membranes demonstrates excellent pollutant separation capabilities; however, polymeric membranes have restricted uses. Nanocomposite membranes, which are produced by integrating nanofillers into polymeric membrane matrices, may increase filtration. Carbon-based nanoparticles and metal/metal oxide nanoparticles have received the greatest attention. We evaluate the antifouling and permeability performance of nanocomposite membranes and their physical and chemical characteristics and compare nanocomposite membranes to b
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Abu-Zurayk, Rund, Nour Alnairat, Aya Khalaf, Abed Alqader Ibrahim, and Ghada Halaweh. "Cellulose Acetate Membranes: Fouling Types and Antifouling Strategies—A Brief Review." Processes 11, no. 2 (2023): 489. http://dx.doi.org/10.3390/pr11020489.

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Cellulose acetate (CA) is a semisynthetic, biodegradable polymer. Due to its characteristics, CA has several applications, including water membranes, filament-forming matrices, biomedical nanocomposites, household tools, and photographic films. This review deals with topics related to the CA membranes, which are prepared using different techniques, such as the phase inversion technique. CA membranes are considered very important since they can be used as microfiltration membranes (MF), ultrafiltration membranes (UF), nanofiltration membranes (NF), reverse osmosis (RO) membranes, and forward os
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4

Nguyen, Hoan Thi Vuong, Thu Hong Anh Ngo, Khai Dinh Do, et al. "Preparation and Characterization of a Hydrophilic Polysulfone Membrane Using Graphene Oxide." Journal of Chemistry 2019 (June 13, 2019): 1–10. http://dx.doi.org/10.1155/2019/3164373.

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In general, the polysulfone (PSf) membranes are popular choices for water treatment because they have high thermal stability and good chemical resistance. On the other hand, the filtration capacity of the polysulfone membrane is limited because of its low water flux and poor antifouling ability, which are caused by the low surface hydrophilicity of the membranes. In this research, blending of graphene oxide (GO) or graphene oxide-titanium dioxide (GO-TiO2) mixture into the polysulfone matrix had been carried out through the phase inversion method to enhance the hydrophilic and antifouling prop
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5

Pramono, Edi, Gadis Prihatin Wahyu Sejati, Sayekti Wahyuningsih, and Candra Purnawan. "Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration." Indonesian Journal of Chemistry 23, no. 2 (2023): 425. http://dx.doi.org/10.22146/ijc.78979.

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This research studied the impact of silanized clay modification on performance and antifouling Poly(vinylidene fluoride) (PVDF) membrane toward humic acid and methylene blue filtration. Clay modification was carried out by using 3-aminopropyltriethoxysilane (APS) to produce modified clay (Clay-APS). Hybrid membranes were prepared by phase inversion for humic acid and methylene blue filtration. Hybrid membranes were characterized by measuring surface hydrophilicity, water flux, rejection, and antifouling properties. Clay and Clay-APS modification increased hybrid membrane surface hydrophilicity
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6

Geleta, Tesfaye Abebe, Irish Valerie Maggay, Yung Chang, and Antoine Venault. "Recent Advances on the Fabrication of Antifouling Phase-Inversion Membranes by Physical Blending Modification Method." Membranes 13, no. 1 (2023): 58. http://dx.doi.org/10.3390/membranes13010058.

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Membrane technology is an essential tool for water treatment and biomedical applications. Despite their extensive use in these fields, polymeric-based membranes still face several challenges, including instability, low mechanical strength, and propensity to fouling. The latter point has attracted the attention of numerous teams worldwide developing antifouling materials for membranes and interfaces. A convenient method to prepare antifouling membranes is via physical blending (or simply blending), which is a one-step method that consists of mixing the main matrix polymer and the antifouling ma
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Shen, Zhen, Wei Chen, Hang Xu, et al. "Fabrication of a Novel Antifouling Polysulfone Membrane with in Situ Embedment of Mxene Nanosheets." International Journal of Environmental Research and Public Health 16, no. 23 (2019): 4659. http://dx.doi.org/10.3390/ijerph16234659.

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Membrane fouling is still a critical issue for the application of ultrafiltration, which has been widely used in water treatment due to its efficiency and simplicity. In order to improve the antifouling property, a new 2D material MXene was used to fabricate composite ultrafiltration membrane with the approach of in situ embedment during the phase inversion process in this study. Scanning electron microscopy (SEM), atomic force microscopy (AFM), thermogravimetric analysis (TGA), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), water contact angle, bovine se
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8

Akbari, Ahmad, Vahid Reza Abbaspour, and Seyed Majid Mojallali Rostami. "Tabas coal preparation plant wastewater treatment with membrane technology." Water Science and Technology 74, no. 2 (2016): 333–42. http://dx.doi.org/10.2166/wst.2016.192.

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The goal of the present work is the Tabas coal preparation plant wastewater treatment using membrane technology. Polyacrylonitrile membrane was prepared through phase inversion method and then developed by annealing process. Also, high fouling resistance membranes were prepared by the embedding of TiO2 nanoparticles using self-assembling and blending methods. The effect of immersion time and TiO2 nanoparticles concentration was investigated using two techniques. The chemical structure, morphology, hydrophilicity, molecular weight cut-off and antifouling properties of membranes were characteriz
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9

Chen, Kaikai, Wei Zhao, Changfa Xiao, Hui Zhu, and Qiming Wang. "Membrane Fouling Mechanism of HTR-PVDF and HMR-PVDF Hollow Fiber Membranes in MBR System." Water 14, no. 16 (2022): 2576. http://dx.doi.org/10.3390/w14162576.

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Membrane fouling has attracted a lot of attention in the membrane separation field. Herein, we selected the homogeneous-reinforced polyvinylidene fluoride (HMR-PVDF) and heterogeneous-reinforced polyvinylidene fluoride (HTR-PVDF) hollow fiber membranes to investigate the fouling mechanism of membranes in membrane bioreactor (MBR) systems. The filtration models, membrane adsorption experiment, and membrane resistance distribution after a long or short time operation were assessed to compare their antifouling properties in order to verify the optimal membrane. The outer surface, shown by an SEM
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10

Liu, Yan Jun, Chun Ying Lv, and Jia Yang. "Studies of Protein Absorption and Fouling Behavior on Amphoteric Charged Polypropylene Microfiltration Membrane." Key Engineering Materials 467-469 (February 2011): 2024–29. http://dx.doi.org/10.4028/www.scientific.net/kem.467-469.2024.

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To improve the antifouling property of PP membrane, a series of amphoteric charged membranes was prepared by the introduction of cysteine on polypropylene membrane. The modified membrane presents higher water flux than original membrane due to the improved hydrophilicity. It was proved by zeta potential that modified membrane inherited the amphoteric characteristic from cysteine. The isoelectric point of modified membranes are at pH 7.2 and 6.5 for 7.6% and 16.1% grafted membranes respectively. Due to the amphoteric characteristic of both modified membrane and BSA, electrical repulsion exsists
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11

Asif Khan, Raja Muhammad, Nasir M. Ahmad, Habib Nasir, Azhar Mahmood, Mudassir Iqbal, and Hussnain A. Janjua. "Antifouling and Water Flux Enhancement in Polyethersulfone Ultrafiltration Membranes by Incorporating Water-Soluble Cationic Polymer of Poly [2-(Dimethyl amino) ethyl Methacrylate]." Polymers 15, no. 13 (2023): 2868. http://dx.doi.org/10.3390/polym15132868.

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Novel ultrafiltration (UF) polymer membranes were prepared to enhance the antifouling features and filtration performance. Several ultrafiltration polymer membranes were prepared by incorporating different concentrations of water-soluble cationic poly [2-(dimethyl amino) ethyl methacrylate] (PDMAEMA) into a homogenous casting solution of polyethersulfone (PES). After adding PDMAEMA, the effects on morphology, hydrophilicity, thermal stability, mechanical strength, antifouling characteristics, and filtration performance of these altered blended membranes were investigated. It was observed that
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12

Tan, Yong Zen, Nur Hashimah Alias, Mohd Haiqal Abd Aziz, Juhana Jaafar, Faten Ermala Che Othman, and Jia Wei Chew. "Progress on Improved Fouling Resistance-Nanofibrous Membrane for Membrane Distillation: A Mini-Review." Membranes 13, no. 8 (2023): 727. http://dx.doi.org/10.3390/membranes13080727.

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Nanofibrous membranes for membrane distillation (MD) have demonstrated promising results in treating various water and wastewater streams. Significant progress has been made in recent decades because of the development of sophisticated membrane materials, such as superhydrophobic, omniphobic and Janus membranes. However, fouling and wetting remain crucial issues for long-term operation. This mini-review summarizes ideas as well as their limitations in understanding the fouling in membrane distillation, comprising organic, inorganic and biofouling. This review also provides progress in developi
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13

Nurbayani, Nurbayani, Aulia Ambarita, and Sri Mulyati. "Vanillin from food flavoring products as a cheaper alternative hydrophilic agent for modifying PVDF membranes in the treatment of organic compounds in water." Jurnal Rekayasa Kimia & Lingkungan 19, no. 2 (2024): 212–19. https://doi.org/10.23955/rkl.v19i2.40061.

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Membrane fouling is an unavoidable challenge in ultrafiltration, resulting in reduced flux and increased operating costs. Surface modification of polyvinylidene fluoride (PVDF) membranes can improve hydrophilicity and extend membrane lifetime. This study investigates vanillin from food flavoring product (VFFP) as a hydrophilic additive for PVDF membranes to enhance antifouling properties. The immersion precipitation phase inversion method was used to prepare membranes with 0-3% (w/w) vanillin. The results of FTIR analysis of VFFP show similarity in absorption peaks with commercial vanillin. Th
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14

Berta, Díez, Sotto Arcadio, Martín Antonio, Arsuaga Jesús, and Rosal Roberto. "Poly(vinyl chloride)-hyperbranched polyamidoamine ultrafiltration membranes with antifouling and antibiofouling properties." Reactive and Functional Polymers 154 (September 1, 2020): 104669. https://doi.org/10.1016/j.reactfunctpolym.2020.104669.

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Poly(vinyl chloride) (PVC) ultrafiltration membranes with improved antifouling and antibiofouling properties were prepared by non-solvent induced phase inversion using a hyperbranched polyamidoamine as additive. PVC reacted into the casting solution with the commercial polyamidoamine nanomaterial Helux-3316 by means of a nucleophilic substitution reaction. The composition of neat and functionalized membranes was studied by ATR-FTIR and elemental composition. Amino groups were tracked using the fluorescent dye fluorescamine. Surface ζ-potential and water contact angles were used to measure
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15

AlSawaftah, Nour, Waad Abuwatfa, Naif Darwish, and Ghaleb Husseini. "A Comprehensive Review on Membrane Fouling: Mathematical Modelling, Prediction, Diagnosis, and Mitigation." Water 13, no. 9 (2021): 1327. http://dx.doi.org/10.3390/w13091327.

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Membrane-based separation has gained increased popularity over the past few decades, particularly reverse osmosis (RO). A major impediment to the improved performance of membrane separation processes, in general, is membrane fouling. Fouling has detrimental effects on the membrane’s performance and integrity, as the deposition and accumulation of foulants on its surface and/or within its pores leads to a decline in the permeate flux, deterioration of selectivity, and permeability, as well as a significantly reduced lifespan. Several factors influence the fouling-propensity of a membrane, such
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16

Xie, Manman, Guolan Huan, Weiwei Xia, Xia Feng, Li Chen, and Yiping Zhao. "Preparation and performance optimization of PVDF anti-fouling membrane modified by chitin." Journal of Polymer Engineering 38, no. 2 (2018): 179–86. http://dx.doi.org/10.1515/polyeng-2016-0372.

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Abstract The poly(vinylidene fluoride) (PVDF)/chitin (CH) blend membranes were prepared by the immersion phase inversion method using N,N-dimethylacetamide (DMAc)/lithium chloride (LiCl) as the co-solvent. It was found that blending CH with PVDF allowed membranes to have a better hydrophilicity, penetrability, antifouling and antibacterial performance. In order to improve the performance of PVDF/CH blend membranes further, water/ethanoic acid (HAc) solutions with different compositions were employed as coagulation baths. The effects of HAc volume percentage in coagulation baths on the surface
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17

Wang, Meng, Tingting Huang, Meng Shan, Mei Sun, Shasha Liu, and Hai Tang. "Zwitterionic Tröger’s Base Microfiltration Membrane Prepared via Vapor-Induced Phase Separation with Improved Demulsification and Antifouling Performance." Molecules 29, no. 5 (2024): 1001. http://dx.doi.org/10.3390/molecules29051001.

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The fouling of separation membranes has consistently been a primary factor contributing to the decline in membrane performance. Enhancing the surface hydrophilicity of the membrane proves to be an effective strategy in mitigating membrane fouling in water treatment processes. Zwitterionic polymers (containing an equimolar number of homogeneously distributed anionic and cationic groups on the polymer chains) have been used extensively as one of the best antifouling materials for surface modification. The conventional application of zwitterionic compounds as surface modifiers is intricate and in
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18

Ngo, Thu Hong Anh, Chau Thi Minh Nguyen, Khai Dinh Do, et al. "Improvement of Hydrophilicity for Polyamide Composite Membrane by Incorporation of Graphene Oxide-Titanium Dioxide Nanoparticles." Journal of Analytical Methods in Chemistry 2020 (December 30, 2020): 1–8. http://dx.doi.org/10.1155/2020/6641225.

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In this work, the polyamide (PA) membrane surface has been modified by coating of nanomaterials including graphene oxide (GO) and titanium dioxide (TiO2) to enhance membrane separation and antifouling properties. The influence of surface modification conditions on membrane characteristics has been investigated and compared with a base membrane. Membrane surface properties were determined through scanning electron microscope (SEM) images and Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy. Membrane separation performance was determined through the possibility for
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19

Wang, Zirui, Shusu Shen, Linbin Zhang, Abdessamad Ben Hida, and Ganwei Zhang. "Hydrophilic and Positively Charged Polyvinylidene Fluoride Membranes for Water Treatment with Excellent Anti-Oil and Anti-Biocontamination Properties." Membranes 12, no. 4 (2022): 438. http://dx.doi.org/10.3390/membranes12040438.

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Membrane fouling limits the rapid development of membrane separations. In this study, a blend membrane containing polycationic liquid (P(BVImBr1-co-PEGMA1)) is presented that can improve the antifouling performance of polyvinylidene fluoride (PVDF) membranes. By mixing the polycationic liquid into PVDF, an improved membrane-surface hydrophilicity and enlarged membrane porosity were detected. The water contact angle decreased from 82° to 67°, the porosity enlarged from 7.22% to 89.74%, and the pure water flux improved from 0 to 631.68 L m−2 h−1. The blend membrane surfaces were found to be alwa
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20

Abood, Tamara Wahid, Kadhum M. Shabeeb, Aseel B. Alzubaydi, Hasan Sh Majdi, Raed A. Al-Juboori, and Qusay F. Alsalhy. "Effect of MAX Phase Ti3ALC2 on the Ultrafiltration Membrane Properties and Performance." Membranes 13, no. 5 (2023): 456. http://dx.doi.org/10.3390/membranes13050456.

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Membrane fouling remains a major obstacle to ultrafiltration. Due to their effectiveness and minimal energy demand, membranes have been extensively employed in water treatment. To improve the antifouling property of the PVDF membrane, a composite ultrafiltration membrane was created employing the in-situ embedment approach throughout the phase inversion process and utilizing a new 2D material, MAX phase Ti3ALC2. The membranes were described using FTIR (Fourier transform infrared spectroscopy), EDS (energy dispersive spectroscopy), CA (water contact angle), and porosity measurements. Additional
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Li, Dalong, Changlu Gao, Xinyue Wang, et al. "Zwitterionic Polysulfone Copolymer/Polysulfone Blended Ultrafiltration Membranes with Excellent Thermostability and Antifouling Properties." Membranes 11, no. 12 (2021): 932. http://dx.doi.org/10.3390/membranes11120932.

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Membrane fouling has been one of the most important challenges in membrane separation operations. In this study, we report a facile strategy to prepare antifouling polysulfone (PSf) UF membranes by blending amphiphilic zwitterion polysulfone-co-sulfobetaine polysulfone (PSf-co-SBPSf) copolymer. The copolymer chemical structure was characterized by 1HNMR spectroscopy. The PSf/PSf-co-SBPSf blend membranes with various zwitterionic SBPSf segment contents exhibited better surface hydrophilicity and excellent antifouling ability compared to PSf and PSf/PEG membranes. The significant increase of bot
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Zatadini, Reza, Aldita Fatchul Ni’mah, Yudi Setiawan, et al. "Improvement of Selectivity and Antifouling Properties of Chitosan-modified Polyvinylidene Fluoride (PVDF) Membrane for Protein Filtration." ALCHEMY Jurnal Penelitian Kimia 19, no. 2 (2023): 210. http://dx.doi.org/10.20961/alchemy.19.2.72110.210-222.

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<p>Protein with high purity is currently a valuable commercial commodity, prized for its high value and application in specialized functions. PVDF-based membrane technology has found widespread use in protein purification processes. However, the issue of fouling on the membrane surface frequently hampers the performance of PVDF membranes. The present study aims to enhance PVDF membranes' selectivity and antifouling properties through chitosan modification, thereby optimizing protein filtration. PVDF and PVDF/Chitosan membranes were fabricated using the phase inversion technique, followed
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Abid, Zubia, Asad Abbas, Azhar Mahmood, et al. "Water Treatment Using High Performance Antifouling Ultrafiltration Polyether Sulfone Membranes Incorporated with Activated Carbon." Polymers 14, no. 11 (2022): 2264. http://dx.doi.org/10.3390/polym14112264.

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Membrane fouling is a continued critical challenge for ultrafiltration membranes performance. In this work, polyether sulfone (PES) ultrafiltration (UF) membranes were fabricated via phase-inversion method by incorporating varying concentrations of APTMS modified activated carbon (mAC). The mAC was thoroughly characterized and the fabricated membranes were studied for their surface morphology, functional groups, contact angle, water retention, swelling (%) porosity, and water flux. The hydrophilicity of mAC membranes also resulted in lower contact angle and higher values of porosity, roughness
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Park, Shinyun, Eunmok Yang, Hosik Park, and Heechul Choi. "Fabrication of functionalized halloysite nanotube blended ultrafiltration membranes for high flux and fouling resistance." Environmental Engineering Research 25, no. 5 (2019): 771–78. http://dx.doi.org/10.4491/eer.2019.402.

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Halloysite nanotubes (HNTs) were functionalized using 3-aminopropyltriethoxysilane (APTES) and incorporated into polyethersulfone (PES) membranes to improve the hydrophilicity of the membranes as well as the interfacial interaction between HNTs and the polymer matrix. The intrinsic properties, permeability, and selectivity of the prepared membranes were analyzed to evaluate the membrane performance. In addition, humic acid (HA) fouling experiments were conducted to measure the antifouling properties of the fabricated membranes. As HNTs and functionalized HNTs (f-HNTs) contents are increased, h
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Zahedipoor, Ahmadreza, Mehdi Faramarzi, Amir Mansourizadeh, Abdolmohammad Ghaedi, and Daryoush Emadzadeh. "Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process." Membranes 13, no. 6 (2023): 577. http://dx.doi.org/10.3390/membranes13060577.

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This study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m2/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membranes using polysulfone (PSf) as the polymer. The synthesized nanoparticles and membranes were analyzed using various techniques, including BET, TEM, XRD, AFM, FESEM, FTIR, and contact angle measurements. The membrane’s performance and antifouling properties were also assessed using bovine serum albumin (BSA) as a simulated
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U. Fathanah, I. Machdar, M. Riza, et al. "EFFECT OF HYBRID Mg(OH)2/CHITOSAN ON THE HYDROPHILICITY AND ANTIFOULING OF POLYETHERSULFONE (PES) MEMBRANE." RASAYAN Journal of Chemistry 15, no. 02 (2022): 813–23. http://dx.doi.org/10.31788/rjc.2022.1526582.

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This work presents the preparation and modification of hybrid Mg(OH)2/chitosan blended PES membranes with the aim of improving the hydrophilic, antifouling and performance of the resulting membranes. The deposition of additives by blending the polymer with a concentration of 1%, 3%, 5%, and 7% on PES membranes. The influences from varying concentrations of additives were evaluated by analyzing changes in chemical groups, changes in morphological structure, hydrophilicity degree, porosity, filtration properties, and the antifouling propensity of the fabricated membrane. PES membranes with the a
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Liu, Dapeng, Junzhi Zheng, Xin Wang, Xinwu Lu, Jing Zhu, and Chunju He. "Low-fouling PES membranes fabricated via in situ copolymerization mediated surface zwitterionicalization." New Journal of Chemistry 42, no. 3 (2018): 2248–59. http://dx.doi.org/10.1039/c7nj03437g.

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Sisay, Elias Jigar, Ákos Ferenc Fazekas, Tamás Gyulavári, et al. "Investigation of Photocatalytic PVDF Membranes Containing Inorganic Nanoparticles for Model Dairy Wastewater Treatment." Membranes 13, no. 7 (2023): 656. http://dx.doi.org/10.3390/membranes13070656.

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Membrane separation processes are promising methods for wastewater treatment. Membrane fouling limits their wider use; however, this may be mitigated using photocatalytic composite materials for membrane preparation. This study aimed to investigate photocatalytic polyvinylidene fluoride (PVDF)-based nanocomposite membranes for treating model dairy wastewater containing bovine serum albumin (BSA). Membranes were fabricated via physical coating (with TiO2, and/or carbon nanotubes, and/or BiVO4) and blending (with TiO2). Another objective of this study was to compare membranes of identical compos
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Choi, Youngmin, and Changwoo Nam. "Fabrication of PVDF Membranes with a PVA Layer for the Effective Removal of Volatile Organic Compounds in Semiconductor Wastewater." Polymers 17, no. 10 (2025): 1332. https://doi.org/10.3390/polym17101332.

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Through the application of advanced membrane modification strategies, high-performance membranes have been developed to effectively remove organic contaminants such as toluene and xylene from wastewater. These membranes demonstrate superior antifouling resistance and long-term operational stability, offering a competitive advantage for semiconductor wastewater treatment. This study introduces a novel approach to membrane fabrication using polyvinylidene fluoride (PVDF), recognized for its cost-effectiveness and distinct antifouling properties in contaminant removal. To enhance the performance
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Phuphuak, Yupin, and Thidarat Loythaworn. "Antifouling Property and Morphology of Polyethersulfone Membranes Blended with Bio-Based Amphiphilic Polymer Additives." Key Engineering Materials 824 (October 2019): 38–44. http://dx.doi.org/10.4028/www.scientific.net/kem.824.38.

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In this work, polyethersulfone (PES) was blended with bio-based polymers, PLA (hydrophobic polymer) and PEG (hydrophilic polymer), in order to improve the antifouling properties of PES membranes. This was done by way of non-solvent induced phase separation. Membrane properties such as morphology, hydrophilicity/hydrophobicity, adsorption fouling and mechanical properties were characterized. All blended membranes displayed higher hydrophilicity than that of pristine PES. This was confirmed by lower water contact angle and higher water adsorption. It was found that membranes with 5 wt% PLA/PEG g
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Aini, Hana Nur, Irish Maggay, Yung Chang, and Antoine Venault. "A Green Stable Antifouling PEGylated PVDF Membrane Prepared by Vapor-Induced Phase Separation." Membranes 12, no. 12 (2022): 1277. http://dx.doi.org/10.3390/membranes12121277.

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While green solvents are being implemented in the fabrication of polyvinylidene fluoride (PVDF) membranes, most are not compatible with the vapor-induced phase separation (VIPS) process for which relatively low dissolution temperatures are required. Additionally, preparing antifouling green membranes in one step by blending the polymer with an antifouling material before inducing phase separation remains extremely challenging due to the solubility issues. Here, the green solvent triethyl phosphate (TEP) was used to solubilize both PVDF and a copolymer (synthesized from styrene monomer and poly
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32

Zhang, Heng, Jiyong Zheng, Cunguo Lin, and Shiling Yuan. "Molecular Dynamics Study on Properties of Hydration Layers above Polymer Antifouling Membranes." Molecules 27, no. 10 (2022): 3074. http://dx.doi.org/10.3390/molecules27103074.

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Zwitterionic polymers as crucial antifouling materials exhibit excellent antifouling performance due to their strong hydration ability. The structure–property relationship at the molecular level still remains to be elucidated. In this work, the surface hydration ability of three antifouling polymer membranes grafting on polysiloxane membranes Poly(sulfobetaine methacrylate) (T4-SB), poly(3-(methacryloyloxy)propane-1-sulfonate) (T4-SP), and poly(2-(dimethylamino)ethyl methacrylate) (T4-DM) was investigated. An orderly packed, and tightly bound surface hydration layer above T4-SP and T4-SB antif
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Luthfiana, Anisa, Sri Mulyati, Nasrul Arahman, Aulia Cintia Ambarita, and Muhammad Prayogie Aulia. "Cigarette Filter-Based Membranes with Tannin and FeCl₃ Additives for Enhancing the Antifouling Properties of Oil Emulsion Filtration." Jurnal Kimia Sains dan Aplikasi 27, no. 12 (2024): 580–89. https://doi.org/10.14710/jksa.27.12.580-589.

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Industries in Indonesia significantly contribute to the economy by increasing foreign exchange earnings and creating job opportunities. However, industrial activities also negatively impact the environment, particularly water pollution caused by liquid waste containing oil emulsions. This research aims to develop a membrane based on cigarette filters as an alternative to cellulose acetate for separating oil emulsions in water. Cigarette filters were processed into membranes with tannic acid (TA) and ferric chloride (FeCl3) as additives using a vacuum-filtration coating technique. The resulting
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Liu, Yuan, Yanlei Su, Yafei Li, Xueting Zhao, and Zhongyi Jiang. "Improved antifouling property of PVDF membranes by incorporating an amphiphilic block-like copolymer for oil/water emulsion separation." RSC Advances 5, no. 27 (2015): 21349–59. http://dx.doi.org/10.1039/c4ra16290k.

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35

Ehsani, Masoume, Denis Kalugin, Huu Doan, Ali Lohi, and Amira Abdelrasoul. "Bio-Sourced and Biodegradable Membranes." Applied Sciences 12, no. 24 (2022): 12837. http://dx.doi.org/10.3390/app122412837.

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Biodegradable membranes with innovative antifouling properties are emerging as possible substitutes for conventional membranes. These types of membranes have the potential to be applied in a wide range of applications, from water treatment to food packaging and energy production. Nevertheless, there are several existing challenges and limitations associated with the use of biodegradable membranes in large scale applications, and further studies are required to determine the degradation mechanisms and their scalability. Biodegradable membranes can be produced from either renewable natural resou
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Nguyen, Thi Minh Chau, Thi Hue Luu, Hong Anh Thu Ngo, and Thi Dung Tran. "Characterisation of membrane prepared from cellulose acetate and polyguanidine." Ministry of Science and Technology, Vietnam 64, no. 11 (2022): 5–10. http://dx.doi.org/10.31276/vjst.64(11).05-10.

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In this study, membranes were prepared from hydrophilic cellulose acetate (CA) and antibacterial polyhexamethylene guanidine hydrochloride (PHMG) by phase inversion method to improve membrane separation and antifouling capacities. The influence of preparation conditions on membrane structure and separation performance has been investigated and evaluated. The experimental results indicated that the CA membranes prepared by the phase inversion method have an asymmetric structure with a dense top layer located onto a porous supporting layer. The concentration of CA in casting solution highly infl
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Tayel, Amr, Ahmed B. Abdelaal, Amal M. K. Esawi, and Adham R. Ramadan. "Thin-Film Nanocomposite (TFN) Membranes for Water Treatment Applications: Characterization and Performance." Membranes 13, no. 5 (2023): 477. http://dx.doi.org/10.3390/membranes13050477.

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Thin-film nanocomposite (TFN) membranes have been widely investigated for water treatment applications due to their promising performance in terms of flux, salt rejection, and their antifouling properties. This review article provides an overview of the TFN membrane characterization and performance. It presents different characterization techniques that have been used to analyze these membranes and the nanofillers within them. The techniques comprise structural and elemental analysis, surface and morphology analysis, compositional analysis, and mechanical properties. Additionally, the fundamen
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Mallah, Nabi Bakhsh, Ayaz Ali Shah, Abdul Majeed Pirzada, et al. "Advanced Control Strategies of Membrane Fouling in Wastewater Treatment: A Review." Processes 12, no. 12 (2024): 2681. http://dx.doi.org/10.3390/pr12122681.

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Reverse osmosis and microfiltration are two membrane-based separation techniques that have gained popularity over the past few decades. A fundamental barrier to improving the overall efficiency of membrane separation is membrane fouling. The accumulation of foulants causes a reduction in permeate flux, a loss of selectivity and permeability, and a reduction in the membrane’s lifespan. Numerous chemical and physical surface changes have been studied to enhance membrane antifouling properties. Additionally, research has concentrated on creating membranes that use cutting-edge materials to improv
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Febriasari, Arifina, Huriya, Annisa Hasna Ananto, Meri Suhartini, and Sutrasno Kartohardjono. "Polysulfone–Polyvinyl Pyrrolidone Blend Polymer Composite Membranes for Batik Industrial Wastewater Treatment." Membranes 11, no. 1 (2021): 66. http://dx.doi.org/10.3390/membranes11010066.

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Batik wastewater, in general, is colored and has high concentrations of BOD (biological oxygen demand), COD (chemical oxygen demand), and dissolved and suspended solids. Polysulfone (PSf)-based membranes with the addition of polyvinyl pyrrolidone (PVP) were prepared to treat batik industrial wastewater. PSf/PVP membranes were prepared using the phase inversion method with N-methyl-2 pyrrolidone (NMP) as the solvent. Based on the membrane characterization through FESEM, water contact angle, porosity, and mechanical tests showed a phenomenon where the addition of PVP provided thermodynamic and k
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Chen, Yichen, Wenmeng Yu, and Hu Cao. "Arginine-Functionalized Thin Film Composite Forward Osmosis Membrane Integrating Antifouling and Antibacterial Effects." Membranes 13, no. 9 (2023): 760. http://dx.doi.org/10.3390/membranes13090760.

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Membrane fouling is an inevitable obstacle of polyamide composite forward osmosis (FO) membranes in oily wastewater treatment. In this study, zwitterionic arginine (Arg) is grafted onto nascent self-made FO polyamide poly(ether sulfone) (PA-PES) membrane, imparting superior hydrophilic, antifouling, and antibacterial properties to the membrane. Detailed characterizations revealed that the Arg-modified (Arg-PES) membrane presented obviously surface positively charged and unique morphology. Results showed that our strategy endowed the optimized membrane, the water flux increased by 113.2% compar
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Xie, Yinshan, Xinning Wang, Hulin Li, Tao Wang, Wei Feng, and Jian Li. "PAN/TiO2 Ultrafiltration Membrane for Enhanced BSA Removal and Antifouling Performance." Catalysts 13, no. 10 (2023): 1320. http://dx.doi.org/10.3390/catal13101320.

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Membrane separation has been widely utilized to eliminate pollutants from wastewater. Among them, a polyacrylonitrile (PAN) ultrafiltration (UF) membrane has presented outstanding stability, and distinguished chemical and thermal properties. However, UF membranes inevitably incur fouling issues during their operation procedure caused by contaminant adhesion on the membrane surface, which would restrict the operational efficiency and increase the maintenance cost. The conventional physical and chemical cleaning is not an effective technique to reduce the fouling due to the additional chemical a
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Jin, Huichao, Wei Bing, Limei Tian, Peng Wang, and Jie Zhao. "Combined Effects of Color and Elastic Modulus on Antifouling Performance: A Study of Graphene Oxide/Silicone Rubber Composite Membranes." Materials 12, no. 16 (2019): 2608. http://dx.doi.org/10.3390/ma12162608.

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Biofouling is a significant maritime problem because the growth of fouling organisms on the hulls of ships leads to very high economic losses every year. Inspired by the soft skins of dolphins, we prepared graphene oxide/silicone rubber composite membranes in this study. These membranes have low surface free energies and adjustable elastic moduli, which are beneficial for preventing biofouling. Diatom attachment studies under static conditions revealed that color has no effect on antifouling behavior, whereas the studies under hydrodynamic conditions revealed that the combined effects of color
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Ma, Wen, Md Saifur Rahaman, and Heloise Therien-Aubin. "Controlling biofouling of reverse osmosis membranes through surface modification via grafting patterned polymer brushes." Journal of Water Reuse and Desalination 5, no. 3 (2015): 326–34. http://dx.doi.org/10.2166/wrd.2015.114.

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Thin film composite (TFC) polyamide membranes are extensively used as selective barriers in reverse osmosis processes. The major challenge faced with TFC membranes is significant fouling on the surface, which restricts the overall purification performance. To address the fouling problem, we developed novel fouling-resistant surface coatings via polyelectrolyte [poly(allylamine hydrochloride)/poly(styrene sulfonate)] layer-by-layer self-assembly, functionalized with patterned antimicrobial and antifouling/fouling-release polymer brushes. Two types of different polymer brushes, among antimicrobi
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Orooji, Ghasali, Emami, Noorisafa, and Razmjou. "ANOVA Design for the Optimization of TiO2 Coating on Polyether Sulfone Membranes." Molecules 24, no. 16 (2019): 2924. http://dx.doi.org/10.3390/molecules24162924.

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There have been developments in the optimization of polyether sulfone (PES) membranes, to provide antifouling and mechanically stable surfaces which are vital to water purification applications. There is a variety of approaches to prepare nanocomposite PES membranes. However, an optimized condition for making such membranes is in high demand. Using experimental design and statistical analysis (one-half fractional factorial design), this study investigates the effect of different parameters featured in the fabrication of membranes, as well as on the performance of a nanocomposite PES/TiO2 membr
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Zhu, Haiyang, JinLei Wang, Tianhao Li, et al. "Performance optimization of forward osmosis membranes modified with TA/FE3+ complexes." Journal of Physics: Conference Series 3009, no. 1 (2025): 012008. https://doi.org/10.1088/1742-6596/3009/1/012008.

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Abstract The active surface layer plays a crucial role in the performance of forward osmosis membranes. This study introduced tannic acid-ferric ion (TA/Fe3+) complexes to modify the surface of the polyamide selective layer in forward osmosis (FO) membranes, aiming to enhance their separation and antifouling performance. Modified membranes were fabricated by depositing TA/Fe3+ coordination layers in varying numbers (1.5, 2.5, and 3.5 layers) and systematically characterized. The results demonstrated that the PES-PA-(TA/Fe3+)2.5 (modified membrane) exhibited optimal performance, with its contac
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Ahmad, Nor Naimah Rosyadah, Abdul Wahab Mohammad, Ebrahim Mahmoudi, Wei Lun Ang, Choe Peng Leo, and Yeit Haan Teow. "An Overview of the Modification Strategies in Developing Antifouling Nanofiltration Membranes." Membranes 12, no. 12 (2022): 1276. http://dx.doi.org/10.3390/membranes12121276.

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Freshwater deficiency has become a significant issue affecting many nations’ social and economic development because of the fast-growing demand for water resources. Nanofiltration (NF) is one of the promising technologies for water reclamation application, particularly in desalination, water, and wastewater treatment fields. Nevertheless, membrane fouling remains a significant concern since it can reduce the NF membrane performance and increase operating expenses. Consequently, numerous studies have focused on improving the NF membrane’s resistance to fouling. This review highlights the recent
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Mahdi, Kumar, Goswami, Perdicakis, Shankar, and Sadrzadeh. "Robust Polymer Nanocomposite Membranes Incorporating Discrete TiO2 Nanotubes for Water Treatment." Nanomaterials 9, no. 9 (2019): 1186. http://dx.doi.org/10.3390/nano9091186.

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Polyethersulfone (PES) is a polymeric permeable material used in ultrafiltration (UF) membranes due to its high thermomechanical and chemical stability. The hydrophobic nature of PES membranes renders them prone to fouling and restricts the practical applications of PES in the fabrication of water treatment membranes. The present study demonstrates a non-solvent-induced phase separation (NIPS) approach to modifying PES membranes with different concentrations of discrete TiO2 nanotubes (TNTs). Zeta potential and contact angle measurements showed enhanced hydrophilicity and surface negative char
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Ji, Keyu, Chengkun Liu, Haijun He, et al. "Research Progress of Water Treatment Technology Based on Nanofiber Membranes." Polymers 15, no. 3 (2023): 741. http://dx.doi.org/10.3390/polym15030741.

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In the field of water purification, membrane separation technology plays a significant role. Electrospinning has emerged as a primary method to produce nanofiber membranes due to its straightforward, low cost, functional diversity, and process controllability. It is possible to flexibly control the structural characteristics of electrospun nanofiber membranes as well as carry out various membrane material combinations to make full use of their various properties, including high porosity, high selectivity, and microporous permeability to obtain high-performance water treatment membranes. These
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49

Zatadini, Reza, Aldita Fatchul Ni’mah, Yudi Setiawan, et al. "Improvement of Selectivity and Antifouling Properties of Chitosan-modified Polyvinylidene Fluoride (PVDF) Membrane for Protein Filtration." ALCHEMY Jurnal Penelitian Kimia 19, no. 2 (2023): 210. http://dx.doi.org/10.20961/alchemy.19.2.72110.210-222.

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<p>Protein with high purity is currently a valuable commercial commodity, prized for its high value and application in specialized functions. PVDF-based membrane technology has found widespread use in protein purification processes. However, the issue of fouling on the membrane surface frequently hampers the performance of PVDF membranes. The present study aims to enhance PVDF membranes' selectivity and antifouling properties through chitosan modification, thereby optimizing protein filtration. PVDF and PVDF/Chitosan membranes were fabricated using the phase inversion technique, followed
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Wang, H., H. Chen, Y. Zeng, G. R. Chen, and M. B. Cui. "Hydrophilic modification and anti-fouling properties of PVDF ultrafiltration membrane via blending of nano-particle MIL-101 MOFs." Digest Journal of Nanomaterials and Biostructures 16, no. 2 (2021): 515–26. http://dx.doi.org/10.15251/djnb.2021.162.515.

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In this work, a new hydrophilic Polyvinylidene fluoride (PVDF) ultrafiltration membrane was prepared by blending of Metal-Organic frameworks (MOFs) -MIL-101 using the phase inversion method. The effect of the MIL-101 on the morphology and efficiency of the modified membranes was researched. The nano-particle and prepared membranes were all characterized by various physicochemical techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), atomic force microscopy (AFM) and water contact angle. The experimental results showed that the modified membranes showed high hydrophili
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