Academic literature on the topic 'Aqueous catalysis'

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Dissertations / Theses on the topic "Aqueous catalysis"

1

Arhancet, Juan P. "Supported aqueous phase catalysis." Diss., Virginia Polytechnic Institute and State University, 1989. http://hdl.handle.net/10919/54759.

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This work describes a novel family of catalysts denoted Supported Aqueous Phase Catalysts (S.A.P.C.). These catalysts consist of a water-soluble organometallic complex supported in a thin film of water residing on a high surface area hydrophilic solid; the reaction takes place at the water-organic interface where the organic contains the reactants and products. This novel type of catalysis is demonstrated by liquid phase hydroformylation. The support chosen is CPG-240, a porous glass with a narrow pore volume distribution. The catalytic species, HRh(CO)[m-P(PhSO₃Na)₃]₃ was synthesized from Rh
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2

Mirza, Amin Ruhul. "Developments in supported aqueous-phase catalysis." Thesis, University of Bath, 1999. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311179.

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Schmitke, Jennifer L. (Jennifer Louise) 1971. "Subtilisin structure and catalysis in non-aqueous media." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/50375.

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4

Chen, Si. "New approach to aqueous biphasic catalysis through catalyst confinement in nanoscopic core-shell polymers." Thesis, Toulouse 3, 2015. http://www.theses.fr/2015TOU30163/document.

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Les catalyseurs sont indispensables à l'industrie chimique moderne. La récupération des catalyseurs est nécessaire d'un point de vue économique et environnemental lorsqu'elle fait appel à des métaux coûteux et/ou toxiques. L'utilisation de la catalyse micellaire est un bon choix d'un point de vue de l'activité, du transfert de masse, et de recyclage mais comporte les problèmes de la formation d'émulsions stables liée au gonflement excessif et la perte physique du tensioactif libre en équilibre avec les micelles. L'objectif de ma thèse est réticuler les micelles au cœur pour éliminer ces problè
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5

Li, Yin. "Catalysis of colloidal transition metal nanoparticles in aqueous medium." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/30541.

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6

Matsinha, Leah Charlie. "Aqueous phase catalysis using mono- and bimetallic transition metal complexes." Doctoral thesis, University of Cape Town, 2015. http://hdl.handle.net/11427/16704.

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Includes bibliographical references<br>The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. A
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Soegiaman, Selvia Kurniawati. "Kinetics of the laccase-catalyzed oxidation of aqueous phenol." Thesis, McGill University, 2006. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=103010.

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Laccase (E.C 1.10.3.2) catalyzes the oxidation of aromatic substrates with the simultaneous reduction of molecular oxygen to water. It has significant potential for use in many applications due to its high reaction rates, broad substrate-specificity, and use of oxygen as an inexpensive co-factor. The objective of this research was to investigate the ability of laccase from Trametes versicolor to catalyze oxidation reactions under a variety of reaction conditions and to model the kinetics of these transformations. Phenol was selected as a model substrate.<br>Laccase was very stable when incubat
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8

Desset, Simon L. "New strategies for the rhodium-catalysed aqueous-biphasic hydroformylation of medium chain alkenes." Thesis, University of St Andrews, 2009. http://hdl.handle.net/10023/842.

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Aqueous-biphasic organometallic catalysis is, as illustrated by the industrial hydroformylation of propene and butene, one of the most promising ways to overcome the intrinsic problem of catalyst separation in organometallic catalysis. However, for poorly water-soluble substrates, mass transfer limitations bring the reaction rate below any that could be economically viable, greatly limiting the scope of this elegant technology. We have studied three different strategies to overcome this limitation. We developed additives that speed up the reaction whilst retaining fast phase separation and goo
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Breno, Kerry L. "Organometallic catalysis in aqueous solution : reactions and mechanisms of water-soluble molybdocenes /." view abstract or download file of text, 2004. http://wwwlib.umi.com/cr/uoregon/fullcit?p3120612.

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Thesis (Ph. D.)--University of Oregon, 2004.<br>Typescript. Includes vita and abstract. Includes bibliographical references (leaves 213-252). Also available for download via the World Wide Web; free to University of Oregon users.
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10

Wang, Demin. "Reduction of perchlorate by indirect electrochemical & catalytic hydrogen processes in dilute aqueous solutions." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 243 p, 2008. http://proquest.umi.com/pqdweb?did=1456290951&sid=10&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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