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Dissertations / Theses on the topic 'Aqueous precipitation'

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1

Roberts, Kevin Edward. "Precipitation of neptunium dioxide from aqueous solution." Scholarly Commons, 1999. https://scholarlycommons.pacific.edu/uop_etds/2682.

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Tens of thousands of metric tons of highly radioactive, nuclear waste have been generated in the United States. Currently, there is no treatment or disposal facility for these wastes. Of the radioactive elements in high-level nuclear waste, neptunium (Np) is of particular concern because it has a long half-life and may potentially be very mobile in groundwaters associated with a proposed underground disposal site at Yucca Mountain, Nevada. Aqueous Np concentrations observed in previous, short-term solubility experiments led to calculated potential doses exceeding proposed long-term regulatory
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2

Ali, Shahid Jamsheed. "Studies in precipitation of proteins from aqueous solution." Thesis, Teesside University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.279009.

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3

Stellner, Kevin Lance. "Precipitation of surfactants and surfactant mixtures in aqueous solutions /." Full-text version available from OU Domain via ProQuest Digital Dissertations, 1987.

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4

Franz, Eric. "Parameters affecting deposition of electrostatically-charged aqueous sprays." Connect to resource, 1985. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1201634653.

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5

Li, Zhonghao, and Andreas Taubert. "Cellulose/gold nanocrystal hybrids via an ionic liquid/aqueous precipitation route." Universität Potsdam, 2009. http://opus.kobv.de/ubp/volltexte/2010/4504/.

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Injection of a mixture of HAuCl4 and cellulose dissolved in the ionic liquid (IL) 1-butyl-3-methylimidazolium chloride [Bmim]Cl into aqueous NaBH4 leads to colloidal gold nanoparticle/cellulose hybrid precipitates. This process is a model example for a very simple and generic approach towards (noble) metal/cellulose hybrids, which could find applications in sensing, sterile filtration, or as biomaterials.
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6

Tahir, N. M. "The hydrolysis and precipitation of iron(111) in aqueous clay dispersions." Thesis, University of Bristol, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381439.

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7

Xu, Zitong. "Removal of Heavy Metal Ions from Aqueous Solution by Alkaline Filtration." Thesis, Université d'Ottawa / University of Ottawa, 2020. http://hdl.handle.net/10393/40105.

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An innovative approach for the removal of heavy metal ions such as Pb2+ and Cd2+ from aqueous solution was evaluated. It was established that alkaline filtration, which is in essence the combination of alkaline precipitation and membrane filtration, could drastically increase both the efficiency and completeness of Pb2+ or Cd2+ ions removal, producing water whose metal concentration satisfying drinking water standard from a simulation wastewater containing 5 ppm or more Pb2+ or Cd2+ ions. Filtration with three different membranes, including microfiltration (MF), ultrafiltration (UF), and nanof
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8

Hänchen, Markus. "CO storage by aqueous mineral carbonation : olivine dissolution and precipitation of Mg-carbonates." Zürich : ETH, 2007. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=17459.

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9

Hachem, Fatima M. "Hydrophobic behaviour of five model proteins in chromatography : precipitation, aqueous two-phase systems." Thesis, University of Reading, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332801.

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10

Gillespie, Cheska. "The precipitation of candidate drugs on mixing DMSO stock solutions with aqueous buffers." Thesis, University of Strathclyde, 2013. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=25548.

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The precipitation of candidate drugs from dimethylsulfoxide (DMSO) stock solutions and buffer mixtures has practical importance within the pharmaceutical industry. At the drug discovery stage, mixing of drug DMSO stocks and aqueous buffer is a common procedure for many analyses, such as bioassay screening and some solubility screens. Precipitation from these mixtures, whilst a recognised issue, has little in the way of published work. This thesis explores in detail the precipitation of three poorly water soluble, commercially available drug molecules, namely amiodarone HCl, clotrimazole and to
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11

Esalah, Jamaleddin. "Removal of heavy metals from aqueous solutions by precipitation with sodium di-(n-octyl) phosphinate." Thesis, McGill University, 1997. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=37715.

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Two organophosphorus compounds: sodium di-(n-octyl) phosphinate and sodium di-(n-dodecyl) phosphinate, were synthesized and purified. Sodium di-(n-octyl) phosphinate was used both as a surfactant to form reverse micelles and as a precipitating agent to remove heavy metals from aqueous nitrate and chloride solutions.<br>The heavy metals lead, cadmium, and zinc were precipitated from aqueous solutions with sodium di-(n-octyl) phosphinate (NaL) in the form of PbL 2(s), CdL2(s), and ZnL2(s). The mole ratio of NaL to lead in the feed was varied from 0.1 to 6.5, depending on the acidity of the feed.
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12

Hock, Sebastian. "Precipitation of hematite and recovery of hydrochloric acid from aqueous iron(II, III) chloride solutions by hydrothermal processing." Thesis, McGill University, 2009. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=66966.

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Regeneration of HCl from process solutions is an important unit operation in chloride hydrometallurgy. Currently, it is accomplished by the highly capital and energy intensive technology of pyrohydrolysis. The research described in this thesis, has focused on an alternative HCl regeneration system from iron(II, III) chloride solutions that has been coined "Hydrolytic Distillation". This system relates to the earlier developed (in the 1970s) PORI Process. Basically this system involves two steps: (1) the oxidation of ferrous chloride solution by oxygen sparging under reflux co
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13

Ramli, Muhd Harris Bin. "Dynamic Effects on Migration of Light Non-Aqueous Phase Liquids in Subsurface." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/189380.

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14

Blais, Derek. "Behavior of gold (111) chloride during the precipitation of iron (111)/arsenic (V) in aqueous media under atmospheric and pressure conditions." Thesis, McGill University, 2011. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=96946.

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This research has focused on the behavior of gold (III) chloride in acidic solutions containing dissolved iron (III) sulphate and arsenic (V) that have been subjected to neutralization or hydrothermal treatments. In particular, the scope of the research was the study of the co-precipitation behavior of gold (III) chloride with various iron (III) – arsenic (V) precipitates that form either in pressure oxidation and leaching autoclaves, or during the neutralization of pressure oxidation/leaching discharge solutions.Gold (III) chloride (5x10-4 M in 0.05 M HCl) was found to co-precipitate with fer
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15

Sansotta, Stefano [Verfasser], Dirk [Akademischer Betreuer] Zahn, Dirk [Gutachter] Zahn, and Bernd [Gutachter] Meyer. "Molecular Simulations Study of Silver Precipitation from Aqueous Solution and on Silica Substrate / Stefano Sansotta ; Gutachter: Dirk Zahn, Bernd Meyer ; Betreuer: Dirk Zahn." Erlangen : Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 2021. http://d-nb.info/1234513528/34.

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16

Ioanovici, Teodora. "Contribuții la sinteza de hidroxiapatită dopată cu magneziu și cercetări asupra proprietăților mecanice în vederea utilizării ei în implanturi osoase." Thesis, Artois, 2012. http://www.theses.fr/2012ARTO0208/document.

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Pour le comblement d'une perte de tissu, la greffe reste une méthode usitée en chirurgie osseuse mais une lacune importante conduit à l'emploi de matériaux artificiels. Alternative aux implants métalliques, les substituts osseux biocéramiques ont une efficacité insuffisante dans de nombreuses indications : problème d'intégration d'un volume important, résistance inadéquate à long terme, faible bioréactivité. Doper ces biocéramiques est une voie intéressante mais nombre de dopants ont abouti à des effets cytotoxiques voire à la dégradation des propriétés mécaniques. Le magnésium a été étudié co
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17

Aguilar, Ivette. "Batteries aqueuses Zn-MnO2 : études mécanistiques et pistes de développement pour des dispositifs réversibles à haute énergie." Electronic Thesis or Diss., Sorbonne université, 2022. http://www.theses.fr/2022SORUS506.

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Les batteries Li-ion occupent une place prédominante sur le marché de l'électronique portable en raison de leur densité d'énergie élevée et de leur durée de vie importante. Cependant, leur durabilité doit encore être améliorée. Dans cette optique, on constate un intérêt croissant pour les batteries aqueuses. Des efforts considérables sont par exemple déployés pour rendre rechargeables les piles alcalines Zn-MnO2. Cela s'avère être une tâche colossale en raison de la complexité de la chimie du système Zn-MnO2 qui, malgré plusieurs décennies de recherches, n'est pas encore entièrement rationalis
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18

Sansotta, Stefano [Verfasser], Dirk [Akademischer Betreuer] Zahn, Dirk [Gutachter] Zahn, and Bernd [Gutachter] Meyer. "Molecular Simulations Study of Silver Precipitation from Aqueous Solution and on Silica Substrate. Control of Shape and Charge via Redox Condition / Stefano Sansotta ; Gutachter: Dirk Zahn, Bernd Meyer ; Betreuer: Dirk Zahn." Erlangen : Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 2020. http://d-nb.info/1219303453/34.

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19

Galinier, Colette. "Dissolution et precipitation des solutions solides (ba, sr)so:(4) en solution aqueuse." Toulouse 3, 1988. http://www.theses.fr/1988TOU30091.

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20

Vayssières, Lionel. "Precipitation en milieu aqueux de nanoparticules d'oxydes : modelisation de l'interface et controle de la croissance." Paris 6, 1995. http://www.theses.fr/1995PA066747.

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Le controle des conditions de precipitation en milieu aqueux (ph, force ionique) de la magnetite permet de maitriser la taille de particules nanometriques et d'eviter les phenomenes de vieillissement. On montre que la taille moyenne des particules s'abaisse a mesure que le ph et la force ionique s'elevent. Cette variation est correlee a l'augmentation de la densite de charge electrostatique de surface des particules. Dans les conditions ou la charge de surface est maximale et l'interface electrostatiquement saturee, les equilibres de dissolution-cristallisation impliques dans le veillissement
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21

POTTIER, AGNES. "Precipitation de cations metalliques en solution aqueuse. Influence de l'acidite sur les caracteristiques des particules d'oxyde." Paris 6, 1999. http://www.theses.fr/1999PA066414.

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L'objectif de ce travail est l'etude des mecanismes mis en jeu lors de la precipitation de cations en solution aqueuse afin d'interpreter l'influence de l'acidite sur les caracteristiques physico-chimiques des particules. L'etude de cations de degre d'oxydation variable (mg 2 +, cr 3 +, ti 4 + et fe 3 +/m 2 + m = co, ni, mn) a permis de considerer diverses phases solides. Lorsque la precipitation du cation forme initialement une phase amorphe ou metastable, l'evolution peut proceder selon deux mecanismes : dissolution/cristallisation et/ou organisation a l'etat solide due a la deshydratation c
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22

Manfoumbi, Christian. "Précipitation des gels de silice en solution aqueuse sursaturée à forte acidité : mécanismes et mésostructures, application à la filtrabilité des pulpes dans les procédés hydrométallurgiques." Thesis, Toulouse 3, 2017. http://www.theses.fr/2017TOU30251/document.

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La formation de gels de silice dans les procédés hydrométallurgiques est très souvent problématique pour la performance des étapes de séparation solide-liquide, en raison du colmatage des filtres. Ces étapes interviennent en aval des étapes de lixiviation visant à mettre en solution les éléments d'intérêts, notamment dans des milieux à forte acidité. Egalement mis en solution au cours de ces attaques acides, le silicium précipite alors sous forme d'oxyde de silicium et forme des gels extrêmement préjudiciables à la filtration. Dans le cadre d'une collaboration avec ERAMET Research, centre de r
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23

Hanhoun, Mary. "Analyse et modélisation de la précipitation de struvite : vers le traitement d'effluents aqueux industriels." Thesis, Toulouse, INPT, 2011. http://www.theses.fr/2011INPT0037/document.

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La réduction des apports phosphorés des eaux usées régie par la Directive Européenne de 1991 (91/271/EEC) est considérée comme le facteur clé de la lutte contre la pollution des rivières et des lacs. Ces travaux concernent exclusivement l'étude de la formation maîtrisée de struvite (MgNH4PO4.6H2O) par précipitation comme alternative originale de récupération du phosphore et, par voie de conséquence, de l'ammonium à partir d'eaux usées. Un atout de ce procédé concerne la valorisation du précipité en tant que fertilisant. Dans ce contexte général, l'objectif consiste à développer une démarche co
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24

Calzavara, Yoann. "Liens entre évolution structurale et propriétés physiques de fluides autour de leur point critique par absorption X et diffusion X aux petits angles." Université Joseph Fourier (Grenoble ; 1971-2015), 2001. http://www.theses.fr/2001GRE10086.

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Cette these a pour but l'etude de l'evolution electronique et structurale a l'echelle microscopique de fluides au voisinage de leur point critique par absorption x ou diffusion x aux petits angles. Les experiences ont ete effectuees grace a un appareillage specifique hautes temperatures / pressions installees sur les lignes bm32 et bm2 de l'esrf de grenoble, synchrotron de 3 e m e generation. Nous nous sommes tout d'abord interesses a un systeme fondamental, le selenium, qui est un liquide covalent presentant une transition electronique semiconducteur-metal-isolant au voisinage du point critiq
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25

Chang, Yu-Chen, and 張玉珍. "Precipitation Mechanisms of Hydroxyapatite Powder in the Different Aqueous Solutions." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/35320200352568319513.

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碩士<br>義守大學<br>材料科學與工程學系碩士班<br>94<br>Hydroxyapatite powder were prepared from the aqueous solution of 0.5M Ca(OH)2/0.3M H3PO4, with different additives, 0.1M, 0.73M, and 1.5M sucrose, 0.1M KOH, 0.1M NaOH, 0.1M glycerol or low-fat milk. The formation mechanism of hydroxyapatite precipitate was studied by varying the processing factors, such as temperature, pH, solution additive, and aging time. The processing factors for coprecipitation were set at T=25℃ and 60℃, t=0~24h, and pH=8~13 in this study. With an initial solution of 0.5 Ca(OH)2/0.3M H3PO4, and solution additives, 0.1M KOH, 0.1M NaOH,
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26

Moshashaee, S., M. Bisrat, Robert T. Forbes, Ellis A. Quinn, H. Nyqvist, and Peter York. "Supercritical fluid processing of proteins: lysozyme precipitation from aqueous solution." 2003. http://hdl.handle.net/10454/3486.

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No<br>Aqueous solutions of hen egg lysozyme (3% w/v) were dispersed and precipitated by a homogenous mixture of supercritical carbon dioxide-ethanol using the Solution Enhanced Dispersion by Supercritical fluid (SEDS) process. The effects of different working conditions, such as temperature, pressure and the flow rates of the solution and ethanol, on the particle-formation process were studied The morphology, particle size and size distribution and biological activity of the protein were determined The precipitates were examined with high-sensitivity differential scanning calorimetry (HSDSC) a
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27

Gupta, Vandana. "Probing protein-polymer interactions in precipitation and aqueous two-phase partioning." Thesis, 2001. http://localhost:8080/xmlui/handle/12345678/2740.

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28

Sookkumnerd, Terasut. "Protein fractionation by aqueous two-phase systems and differential ammonium sulfate precipitation /." Diss., 2000. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:9995539.

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29

SINGH, GYAN PRAKASH. "SYNTHESIS OF YELLOWISH GREEN BIOCOMPATIBLE HYDROXYAPATITE PHOSPHOR VIA SURFACTANT ASSISTED AQUEOUS PRECIPITATION METHOD." Thesis, 2013. http://dspace.dtu.ac.in:8080/jspui/handle/repository/16130.

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Terbium doped hydroxyapatite (THA), Tb:Ca10(PO4)6(OH)2 phosphors synthesized via surfactant (CTAB) assisted aqueous precipitation method. It is basically a room temperature synthesis excluding the sintering at 550o C, which was performed just for the removal of residual organic template. The phase, morphology, luminescent properties of THA powders were examined by usingX-ray diffraction, scanning electron microscopy (SEM), excitation and emission spectra. XRD analysis reveals the nanocrystalline nature of THA with crystallite size 48 nm. SEM images indicate the formationof ‘micro-
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30

Chen, Xiaoxia. "Nanoparticle engineering processes: evaporative precipitation into aqueous solution (EPAS) and antisolvent precipitation to enhance the dissolution rates of poorly water soluble drugs." Thesis, 2004. http://hdl.handle.net/2152/1164.

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31

Chen, Xiaoxia Johnston Keith P. Williams Robert Oddy. "Nanoparticle engineering processes evaporative precipitation into aqueous solution (EPAS) and antisolvent precipitation to enhance the dissolution rates of poorly water soluble drugs /." 2004. http://wwwlib.umi.com/cr/utexas/fullcit?p3142708.

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32

Matteucci, Michal Elizabeth 1977. "Highly supersaturated aqueous solutions by design of amorphous pharmaceutical nanoparticles." 2007. http://hdl.handle.net/2152/16019.

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For 40% of currently discovered drugs which are poorly water soluble, engineering amorphous nanoparticles with rapid dissolution and enhanced solubility can improve their absorption. Antisolvent precipitation by mixing organic drug solutions with aqueous solutions produced sub-300 nm amorphous nanoparticle dispersions. Polymeric stabilizers increased the nucleation rate by lowering the interfacial tension and adsorbed to particle surfaces to inhibit growth by condensation and coagulation. An increase in the stabilizer concentration decreased the average particle size until reaching a thresh
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33

Chien, Feng-Lung, and 簡豐隆. "Purification of proteins with affinity precipitation and affini- ty partition in aqueous two-phase systems." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/61995261831712939096.

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碩士<br>國立成功大學<br>化學工程研究所<br>82<br>Macroligands were synthesized by attaching ligands(Cibacron blue 3GA and Soybean Trypsin Inhibitor to a reversibly soluble polymer(AS-L,hydroxypropyl methylcellulose acetate succinate). Ma- croligands with such reversibly soluble characteristics may be used for affinity precipitation and affinity partition in aqueous two-phase systems for purification of proteins. This research contains three parts: (1) The reversibly soluble polymer ligand(Cibacronblue 3GA
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34

Chen, Yuan-Chang, and 陳元章. "Predicting Recovery of Light Non-aqueous Phase Liquids Improved by Precipitation-Application of Immiscible Displacement Theory." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/a56r3g.

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碩士<br>國立成功大學<br>資源工程學系碩博士班<br>90<br>Oil leakage occurred at point 322.5K of the National Highway in Taiwan and was discovered in March 1998. Since the discovery, free product recovery started and lasted until June 2000. Field data showed that oil recovery rate correlated with precipitation. Every year the oil recovery rate during rainy season is higher than that of the previous dry season. This phenomenon is similar to the oil recovery by waterflooding used in the petroleum industries. The paper first utilized the data from soil boring, soil gas and monitoring well surveys to build a conc
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35

Yang, Zhi-Feng, and 楊志鋒. "Preparation of Magnetic Fe3O4/Carbon Nanocomposites by Co-precipitation Method for Removal of Copper Ions from Aqueous Solution." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/09366709340664966772.

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碩士<br>元智大學<br>化學工程與材料科學學系<br>105<br>With the rapid development of semiconductor manufacturing, the treatment of liquid waste in the production process cause increasingly the attention of the enterprises. In this reaserch, the magnetic Fe3O4/Carbon nanocomposites prepared by co-precipitation method was used as absorbent for the absorption of copper ions. The efficient separation of the absorbent and absorbate and the recycling of absorbent were realized by the magnetic propert. In this reaserch, XRD, XPS, FTIR, TEM and SEM were used to analyze the micromorphology and component of the pruducts.
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Mohebbinia, Saeedeh. "Advanced equation of state modeling for compositional simulation of gas floods." 2013. http://hdl.handle.net/2152/23098.

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Multiple hydrocarbon phases are observed during miscible gas floods. The possible phases that result from a gas flood include a vapor phase, an oleic phase, a solvent-rich phase, a solid phase, and an aqueous phase. The solid phase primarily consists of aggregated asphaltene particles. Asphaltenes can block pore throats or change the formation wettability, and thereby reduce the hydrocarbon mobility. The dissolution of injected gas into the aqueous phase can also affect the gas flooding recovery because it reduces the amount of gas available to contact oil. This is more important in CO₂ floodi
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Agyei, Nana Mensah. "The removal of phosphate ions from aqueous solution by fly ash, slag, ordinary Portland cement and related blends." Thesis, 2004. http://hdl.handle.net/2263/29682.

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駱建樹. "Removal of Copper from Aqueous Amminecopper(II)Solution by Precipitation, Adsorption with Metal Hydroxide and Foam Flotation, and Removal of Cadmium and Nickel in Solution of High Ionic Strength by Coflotation with Ferrous Hydroxide." Thesis, 1992. http://ndltd.ncl.edu.tw/handle/43723912001179054530.

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