Academic literature on the topic 'Arene functionalization'

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Journal articles on the topic "Arene functionalization"

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Gagnon, Jonathan, Martin Vézina, Marc Drouin, and Pierre D. Harvey. "Regioselective upper-rim functionalizations of calix[4]arene by diphenylphosphino groups." Canadian Journal of Chemistry 79, no. 10 (2001): 1439–46. http://dx.doi.org/10.1139/v01-161.

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The regioselective upper-rim functionalization of calix[4]arene have been performed to prepare all the multisubstituted diphenylphosphine derivatives. In addition, the X-ray structures of 5,17-dibromo-11,23-bis(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene and 5,11,17,23-tetrakis(diphenylphosphino)-25,26,27,28-tetra-i-propoxy-calix[4]arene have been determined. Regioselective functionalizations have been achieved using methods that involve appropriate choices of bases, alkyllithium-solvent systems, stoichiometry, and reaction times. A new and convenient method for selectively pre
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Barluenga, J., E. Campos-Gómez, A. Minatti, D. Rodríguez, and J. González. "Iodonium Ion Triggered Arene Functionalization." Synfacts 2009, no. 12 (2009): 1342. http://dx.doi.org/10.1055/s-0029-1218180.

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Wang, Xia, Ya-Fei Han, Xuan-Hui Ouyang, Ren-Jie Song, and Jin-Heng Li. "The photoredox alkylarylation of styrenes with alkyl N-hydroxyphthalimide esters and arenes involving C–H functionalization." Chemical Communications 55, no. 97 (2019): 14637–40. http://dx.doi.org/10.1039/c9cc07494e.

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The In(OTf)<sub>3</sub>-promoted three-component photoredox alkylarylation of styrenes with alkyl NHP esters and arenes to access alkylated arene derivatives through C–C bond cleavage and C–H functionalization is reported.
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Nierengarten, Iwona, Michel Holler, Marine Rémy, et al. "Grafting Dendrons onto Pillar[5]Arene Scaffolds." Molecules 26, no. 8 (2021): 2358. http://dx.doi.org/10.3390/molecules26082358.

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With their ten peripheral substituents, pillar[5]arenes are attractive compact scaffolds for the construction of nanomaterials with a controlled number of functional groups distributed around the macrocyclic core. This review paper is focused on the functionalization of pillar[5]arene derivatives with small dendrons to generate dendrimer-like nanomaterials and bioactive compounds. Examples include non-viral gene vectors, bioactive glycoclusters, and liquid-crystalline materials.
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Tarnovskiy, Andriy, Alexander Shivanyuk, and Vladimir V. Rozhkov. "Selective functionalization of a resorcin[6]arene." Tetrahedron 67, no. 50 (2011): 9715–18. http://dx.doi.org/10.1016/j.tet.2011.10.043.

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Wang, Guo, Hui Qiang, Yun-Zhe Guo, Jie Yang, Ke Wen, and Wei-Bo Hu. "Systematic rim cyano-functionalization of pillar[5]arene and corresponding host–guest property varieties." Organic & Biomolecular Chemistry 17, no. 18 (2019): 4600–4604. http://dx.doi.org/10.1039/c9ob00396g.

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Synthetic investigation of the systematic replacement of alkoxy groups in pillar[5]arene by cyano ones was carried out. Host–guest property studies of nCN-pillar[5]arenes and 1,4-dicyanobutane showed the functionization number related host–guest interaction varieties.
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Olteanu, Marius, Raluca Septelean, Ovidiu Nemes, et al. "Functionalization of Mesoporous Silica Materials Using Calix[4]arenes." Materiale Plastice 56, no. 3 (2019): 554–58. http://dx.doi.org/10.37358/mp.19.3.5228.

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\Six new products were obtained by deposition of para-tert-butylcalix[4]arene (t-Bu-C4OH), calix[4]arene (C4OH) and tetra-methoxy-calix[4]arene (C4OMe) on two types of SBA-15 mesoporous silica. All the products were characterized through thermogravimetric methods and SEM microscopy. The obtained results confirm the functionalization of the silica materials with the calixarene macrocycles. Considering all the obtained products, the thermal analysis suggests the strongest connectivity to form between the C4OMe systems and mesoporous silica substrate.
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NAM, K. C., and K. S. PARK. "ChemInform Abstract: Selective Functionalization of Calix(6)arene." ChemInform 26, no. 45 (2010): no. http://dx.doi.org/10.1002/chin.199545121.

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Dutta, Uttam, Sudip Maiti, Trisha Bhattacharya, and Debabrata Maiti. "Arene diversification through distal C(sp2)−H functionalization." Science 372, no. 6543 (2021): eabd5992. http://dx.doi.org/10.1126/science.abd5992.

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Transition metal–catalyzed aryl C−H activation is a powerful synthetic tool as it offers step and atom-economical routes to site-selective functionalization. Compared with proximal ortho-C−H activation, distal (meta- and/or para-) C−H activation remains more challenging due to the inaccessibility of these sites in the formation of energetically favorable organometallic pretransition states. Directing the catalyst toward the distal C−H bonds requires judicious template engineering and catalyst design, as well as prudent choice of ligands. This review aims to summarize the recent elegant discove
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Al-Azemi, Talal F., Mickey Vinodh, Fatemeh H. Alipour, and Abdirahman A. Mohamod. "Synthesis, functionalization, and isolation of planar-chiral pillar[5]arenes with bulky substituents using a chiral derivatization agent." RSC Advances 9, no. 40 (2019): 23295–301. http://dx.doi.org/10.1039/c9ra03135a.

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Bulky perneopentyloxy-pillar[5]arene was synthesized. Complexation behavior and conformational mobility were investigated using <sup>1</sup>H NMR spectroscopy. Isolation of planar-chiral pillar[5]arenes using a chiral derivatization agent were carried out.
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Dissertations / Theses on the topic "Arene functionalization"

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Angueira, Ernesto J. "Novel Superacidic Ionic Liquid Catalysts for Arene Functionalization." Diss., Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/7651.

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There is a continuing interest in the subject of arene carbonylation, especially in strong acids and environmentally-benign alternatives are sought to HF/BF3 and to AlCl3 as conversion agents. Ionic liquids offer a powerful solvent for useful conversion agents such as aluminum chloride. The ILs permit AlCl3 to be used at lower HCl partial pressures than with other solvents. The superior reactivity demonstrated by acidic, chloroaluminate ILs is probably due to their enhanced solvation power for HCl and CO. Addition of HCl gas increased reactivity of the system by forming Brnsted acids, and
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Brown, Alec Nathaniel. "Late-Stage Functionalization of 1,2-Dihydro-1,2-Azaborines." Thesis, Boston College, 2015. http://hdl.handle.net/2345/bc-ir:104564.

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Thesis advisor: Shih-Yuan Liu<br>Described herein are two distinct research projects focused on the development of metal-catalyzed late-stage functionalization strategies for 1,2-dihydro-1,2-azaborines separated into three chapters. The first chapter discusses the development, synthesis, and recent contributions to the field of azaborine chemistry. The second chapter details the development of rhodium catalyzed B-H bond activation for the synthesis of a new class of BN-stilbenes as well as the discovery of a novel B-H to B-Cl transformation that is successful both with B-H azaborines as well a
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Brugnara, Andrea. "Contrôle cavitaire de la réactivité redox d'un ion métallique (Cu) dans un environnement biomimétique." Thesis, Paris 5, 2013. http://www.theses.fr/2013PA05P625/document.

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La molécule X6TMPA, constituée d’une unité TMPA (tris(2-pyridylméthyl)amine) greffée de façon covalente à trois des six unités aromatiques du calix[6]arène, permet de coordiner et stabiliser un ion cuivre (Cu+ et Cu2+) dans un environnement mononucléaire. Ces composés possèdent des propriétés uniques en chimie hôte-invité ainsi qu’en réactivité redox. De tels systèmes présentent cependant des limitations car : – le macrocycle et les complexes métalliques associés ne sont solubles qu’en milieu organique ; – le complexe cuivreux obtenu avec un tel macrocycle n’est réactif vis-à-vis de l’oxygène
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De, Leener Gaël. "Nouveaux complexes biomimétiques dérivés de calix[6]azacryptands : étude des effets de seconde sphère et greffage sur surface." Thesis, Sorbonne Paris Cité, 2016. http://www.theses.fr/2016USPCB024/document.

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Plus de 30% des enzymes présentent un ion métallique dans leur site actif qui est la clé pour les réactions de catalyse. Une sous-famille d’enzymes comporte un site actif où un seul ion métallique (Zn2+ ou Cun+) est coordiné à un cœur polyhistidine. L’élaboration de composés modèles est important pour la compréhension des mécanismes fondamentaux impliqués dans le cycle biocatalytique de ces enzymes mononucléaires. Dans ce contexte, nous avons développé des ligands basés sur des calix[6]arènes présentant un chapeau polyazoté lié de manière covalente au macrocycle. Ces ligands offrent un site de
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Orkun, Cevheroglu. "Unexpected Cyclization Of Dipyrilydl-glycoluril In The Presence Of Formaldehyde And Strong Acid: A New Scaffold With A Potential As A Receptor And Synthesis Of Vairous Calixarene Precursors." Master's thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/12606423/index.pdf.

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This thesis covers combination of two independent works accomplished throughout the study. One part research is about the unexpected cyclization of Dipyridyl-glycoluril, and the other part is about synthesis of precursor calix[4]arene derivatives. In an attempted synthesis of peripherally pyridine substituted cucurbituril, an unexpected cyclized product was obtained. A careful NMR analysis followed by mass spectrometry and preliminary crystallographic analyses, helped us in resolving the structure. The structure has two quaternized pyridine functionalities and a groove suitable as a potential
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Macarov, Cristina-Adriana. "Investigation of resorcin[4]arenes upper rim functionalization." Thesis, University of East Anglia, 2018. https://ueaeprints.uea.ac.uk/67867/.

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The research in this thesis depicts aspects in the area of resorcin[4]arenes upper rim functionalization and presents the importance of this type of structures. The first chapter covers past and present literature regarding general background and synthetic approaches towards building these cage-like cyclic oligomers, and discusses the possible applications as synthetic enzymes. Chapter two is separated into two main research areas; (i) preparation of a series of monofunctionalized substrates, attaching on each ring desired groups, such as: amines, esters, ethers, carboxylic acids, alcohols, bo
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Devaraj, Karthik. "Ruthenium-catalyzed C-H Functionalization of (Hetero)arenes." Doctoral thesis, Uppsala universitet, Organisk kemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-310998.

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This thesis concerned about the Ru-catalyzed C-H functionalizations on the synthesis of 2-arylindole unit, silylation of heteroarenes and preparation of aryne precursor. In the first project, we developed the Ru-catalyzed C2-H arylation of N-(2-pyrimidyl) indoles and pyrroles with nucleophilic arylboronic acids under oxidative conditions. Wide variety of arylboronic acids afforded the desired product in excellent yield regardless of the substituents or functional group electronic nature. Electron-rich heteroarenes are well suited for this method than electron-poor heteroarenes. Halides such as
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Inthasot, Alex. "Nouveaux récepteurs cavitaires dérivés de calix[6]arènes : fonctionnalisation sélective, chimie de coordination et reconnaissance moléculaire dans l’eau." Doctoral thesis, Universite Libre de Bruxelles, 2016. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/224570.

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L’élaboration de récepteurs artificiels pouvant reconnaître soit des ions métalliques soit des molécules chargées ou neutres avec une haute affinité et une grande sélectivité est l’un des objectifs majeurs de la chimie supramoléculaire. En effet, de tels récepteurs ont de potentielles applications dans de nombreux domaines comme en imagerie médicale ou en analyse environnementale. Afin de pouvoir obtenir des récepteurs sophistiqués, il faut cependant généralement passer par une étape d’ingénierie de la molécule dont la conception concrète nécessite une fonctionnalisation ad hoc. Cela requiert
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Fosu, Stacy C. "Functionalization of Arenes, Amines, Alkenes, and Alkynes Mediated by Radical Pathways." The Ohio State University, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=osu1555514456659022.

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Okumura, Shogo. "Studies on Site-selective C-H Alkylation of Arenes with Alkenes." Kyoto University, 2019. http://hdl.handle.net/2433/242514.

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Book chapters on the topic "Arene functionalization"

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Emmert, Marion H., and Christopher J. Legacy. "Chelate-Assisted Arene C-H Bond Functionalization." In Arene Chemistry. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch23.

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Poblador-Bahamonde, Amalia Isabel. "Functionalization of Arenes Via C-H Bond Activation Catalysed by Transition Metal Complexes." In Arene Chemistry. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch25.

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Hari, Durga Prasad, Thea Hering, and Burkhard König. "Arene Functionalization by Visible Light Photoredox Catalysis." In Visible Light Photocatalysis in Organic Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527674145.ch8.

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Cacchi, Sandro, Giancarlo Fabrizi, and Antonella Goggiamani. "Copper Catalysis in Arene and Heteroarene Functionalization through C-H Bond Activation." In Innovative Catalysis in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527646586.ch10.

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Kalyani, Dipannita, and Elodie E. Marlier. "Reactivity and Selectivity in Transition Metal-Catalyzed, Nondirected Arene Functionalizations." In Arene Chemistry. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch24.

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Zhao, Da. "1,3-Dehydro-o-Carborane: Generation and Reaction with Arenes." In Functionalization of Carborane via Carboryne Intermediates. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1569-4_5.

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Gallardo, Iluminada, and Gonzalo Guirado. "Electrochemical C–H Functionalization of Arenes and Heteroarenes." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2013. http://dx.doi.org/10.1007/7081_2013_118.

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Hartwig, John F. "Catalytic, Thermal, Regioselective Functionalization of Alkanes and Arenes with Borane Reagents." In ACS Symposium Series. American Chemical Society, 2004. http://dx.doi.org/10.1021/bk-2004-0885.ch008.

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Dixneuf, Pierre H., and Jean-François Soulé. "Functionalization of C(sp2)–H Bonds of Arenes and Heteroarenes Assisted by Photoredox Catalysts for the C–C Bond Formation." In Organometallics for Green Catalysis. Springer International Publishing, 2018. http://dx.doi.org/10.1007/3418_2018_22.

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Dixneuf, Pierre H., and Jean-François Soulé. "Correction to: Functionalization of C(sp2)–H Bonds of Arenes and Heteroarenes Assisted by Photoredox Catalysts for the C–C Bond Formation." In Organometallics for Green Catalysis. Springer International Publishing, 2018. http://dx.doi.org/10.1007/3418_2018_25.

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Conference papers on the topic "Arene functionalization"

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Gallardo-Donaire, Joan, and Ruben Martin. "Cu-catalyzed Mild C(sp2)-H Functionalization Assisted by Carboxylic Acids En Route to Hydroxylated Arenes." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013618124023.

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Reports on the topic "Arene functionalization"

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Nilova, Aleksandra. Aryne-Guided C-H Functionalization of Benzenoid Rings Using Diaryliodonium Salts. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.7474.

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