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1

Kleib, Joelle, Mouhamadou Amar, Georges Aouad, Xavier Bourbon, Mahfoud Benzerzour, and Nor-Edine Abriak. "The Use of Callovo-Oxfordian Argillite as a Raw Material for Portland Cement Clinker Production." Buildings 12, no. 9 (2022): 1421. http://dx.doi.org/10.3390/buildings12091421.

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Excavated soils and rocks are materials obtained in construction works that could represent an ecological issue if a durable and efficient reuse process is not set. The radioactive waste disposal planned by the French National Radioactive Waste Management Agency will generate large quantities of excavated soil (mainly as Callovo-Oxfordian argillite). The re-use of excavated soils is a recent question. There is a lack in the literature concerning the recycling of such materials. Therefore, this paper aims to investigate the possibility of using Callovo-Oxfordian argillite (COx argillite from th
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2

Liu, Jiang-Feng, Yang Song, Frédéric Skoczylas, and Jian Liu. "Gas migration through water-saturated bentonite–sand mixtures, COx argillite, and their interfaces." Canadian Geotechnical Journal 53, no. 1 (2016): 60–71. http://dx.doi.org/10.1139/cgj-2014-0412.

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France’s deep-seated nuclear waste repository consists of a natural barrier located at a depth of 500 m in a Callovo-Oxfordian clayey formation. This repository has artificial barriers that include plugs of swelling clay (MX80 bentonite – sand mixtures) for sealing purposes. This paper focuses on the gas migration properties of water-saturated bentonite–sand mixtures and their interfaces with COx argillite. The main contribution of our study is the identification of a preferential gas migration pathway by measuring the downstream gas breakthrough pressures and gas flow rates. The water permeab
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3

Boulin, Pierre Francois, Rafael Angulo-Jaramillo, Jean-Francois Daian, Jean Talandier, and Philippe Berne. "Pore gas connectivity analysis in Callovo-Oxfordian argillite." Applied Clay Science 42, no. 1-2 (2008): 276–83. http://dx.doi.org/10.1016/j.clay.2008.01.014.

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4

Tran, Huy T. "Analysis of Mechanical Behavior of the Callovo-Oxfordian Argillite." IOP Conference Series: Earth and Environmental Science 143 (April 2018): 012040. http://dx.doi.org/10.1088/1755-1315/143/1/012040.

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5

de Combarieu, G., P. Barboux, and Y. Minet. "Iron corrosion in Callovo–Oxfordian argilite: From experiments to thermodynamic/kinetic modelling." Physics and Chemistry of the Earth, Parts A/B/C 32, no. 1-7 (2007): 346–58. http://dx.doi.org/10.1016/j.pce.2006.04.019.

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6

Mohajerani, M., P. Delage, M. Monfared, A. M. Tang, J. Sulem, and B. Gatmiri. "Oedometric compression and swelling behaviour of the Callovo-Oxfordian argillite." International Journal of Rock Mechanics and Mining Sciences 48, no. 4 (2011): 606–15. http://dx.doi.org/10.1016/j.ijrmms.2011.02.016.

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7

Montes, H. G., J. Duplay, L. Martinez, S. Escoffier, and D. Rousset. "Structural modifications of Callovo-Oxfordian argillite under hydration/dehydration conditions." Applied Clay Science 25, no. 3-4 (2004): 187–94. http://dx.doi.org/10.1016/j.clay.2003.10.004.

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8

Guéry, Ariane Abou-Chakra, Fabrice Cormery, Jian-Fu Shao, and Djimedo Kondo. "Micromechanics based modeling of the Callovo-Oxfordian argillite mechanical behavior." Mécanique & Industries 8, no. 3 (2007): 225–34. http://dx.doi.org/10.1051/meca:2007042.

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9

Mahjoub, Mohamed, Ahmed Rouabhi, Michel Tijani, Sylvie Granet, Sofia M’Jahad, and Jean Talandier. "Numerical Study of Callovo-Oxfordian Argillite Expansion due to Gas Injection." International Journal of Geomechanics 18, no. 1 (2018): 04017134. http://dx.doi.org/10.1061/(asce)gm.1943-5622.0001050.

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10

Zeng, T., J. F. Shao, and Y. Yao. "An upscaled model for elastoplastic behavior of the Callovo-Oxfordian argillite." Computers and Geotechnics 112 (August 2019): 81–92. http://dx.doi.org/10.1016/j.compgeo.2019.04.003.

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11

Boulin, Pierre Francois, Rafael Angulo-Jaramillo, Jean-Francois Daian, Jean Talandier, and Philippe Berne. "Experiments to estimate gas intrusion in Callovo-oxfordian argillites." Physics and Chemistry of the Earth, Parts A/B/C 33 (January 2008): S225—S230. http://dx.doi.org/10.1016/j.pce.2008.10.004.

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12

Di Donna, Alice, Pascal Charrier, Simon Salager, and Pierre Bésuelle. "Self-sealing capacity of argillite samples." E3S Web of Conferences 92 (2019): 03005. http://dx.doi.org/10.1051/e3sconf/20199203005.

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Many countries are currently facing the issue of finding a proper solution to store radioactive wastes coming from nuclear energy production plants. The possibility to store them in underground tunnels is largely considered and investigated. In France, Andra (Agence Nationale pour la gestion des Déchets Radioactifs) selected the Callovo-Oxfordian rock clay (COx) situated in the Meuse/Haute Marne site (France) between 400 and 600 m depth as possible host rock deposit. The excavation of the storage tunnels is expected to create a fractured zone around galleries. However, the factures will be the
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13

Descostes, M., V. Blin, F. Bazer-Bachi, et al. "Diffusion of anionic species in Callovo-Oxfordian argillites and Oxfordian limestones (Meuse/Haute–Marne, France)." Applied Geochemistry 23, no. 4 (2008): 655–77. http://dx.doi.org/10.1016/j.apgeochem.2007.11.003.

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14

Descostes, M., and E. Tevissen. "Definition of an equilibration protocol for batch experiments on Callovo-Oxfordian argillite." Physics and Chemistry of the Earth, Parts A/B/C 29, no. 1 (2004): 79–90. http://dx.doi.org/10.1016/j.pce.2003.11.010.

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15

David, Christian, Philippe Robion, and Beatriz Menéndez. "Anisotropy of elastic, magnetic and microstructural properties of the Callovo-Oxfordian argillite." Physics and Chemistry of the Earth, Parts A/B/C 32, no. 1-7 (2007): 145–53. http://dx.doi.org/10.1016/j.pce.2005.11.003.

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16

Zhang, Chunliang, and Tilmann Rothfuchs. "Experimental study of the hydro-mechanical behaviour of the Callovo-Oxfordian argillite." Applied Clay Science 26, no. 1-4 (2004): 325–36. http://dx.doi.org/10.1016/j.clay.2003.12.025.

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17

Rousseau-Gueutin, P., J. Gonçalvès, and S. Violette. "Osmotic efficiency in Callovo-Oxfordian argillites: Experimental vs. theoretical models." Physics and Chemistry of the Earth, Parts A/B/C 33 (January 2008): S106—S113. http://dx.doi.org/10.1016/j.pce.2008.10.064.

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18

Zhang, F., Y. Jia, H. B. Bian, and G. Duveau. "Modeling the influence of water content on the mechanical behavior of Callovo–Oxfordian argillite." Physics and Chemistry of the Earth, Parts A/B/C 65 (January 2013): 79–89. http://dx.doi.org/10.1016/j.pce.2013.05.007.

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19

Charlier, Robert, Frédéric Collin, Benoît Pardoen, Jean Talandier, Jean-Pol Radu, and Pierre Gerard. "An unsaturated hydro-mechanical modelling of two in-situ experiments in Callovo-Oxfordian argillite." Engineering Geology 165 (October 2013): 46–63. http://dx.doi.org/10.1016/j.enggeo.2013.05.021.

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20

Cariou, S., L. Dormieux, and F. Skoczylas. "An original constitutive law for Callovo-Oxfordian argillite, a two-scale double-porosity material." Applied Clay Science 80-81 (August 2013): 18–30. http://dx.doi.org/10.1016/j.clay.2013.05.003.

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21

Schäfer, T., P. Michel, F. Claret, T. Beetz, S. Wirick, and C. Jacobsen. "Radiation sensitivity of natural organic matter: Clay mineral association effects in the Callovo-Oxfordian argillite." Journal of Electron Spectroscopy and Related Phenomena 170, no. 1-3 (2009): 49–56. http://dx.doi.org/10.1016/j.elspec.2008.05.007.

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22

Zhang, Xiang, Gilles Duveau, and Jean-Baptiste Colliat. "Numerical prediction of gas migration properties in Callovo-Oxfordian (COx) argillite using morpho-mathematical operations." International Journal for Numerical and Analytical Methods in Geomechanics 42, no. 10 (2018): 1125–43. http://dx.doi.org/10.1002/nag.2776.

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23

Zeng, Tao, Jian‐Fu Shao, and Yao Yao. "A micromechanical‐based elasto‐viscoplastic model for the Callovo‐Oxfordian argillite: Algorithms, validations, and applications." International Journal for Numerical and Analytical Methods in Geomechanics 44, no. 2 (2019): 183–207. http://dx.doi.org/10.1002/nag.3006.

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24

Esteban, Lionel, Jean Luc Bouchez, and Alain Trouiller. "The Callovo-Oxfordian argillites from the eastern Paris Basin: Magnetic data and petrofabrics." Comptes Rendus Geoscience 338, no. 12-13 (2006): 867–81. http://dx.doi.org/10.1016/j.crte.2006.03.011.

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25

Lassin, Arnault, Nicolas Marty, Benoît Henry, et al. "Equilibrium Partial Pressure of CO2 in the Callovo-Oxfordian Argillite as a Function of Relative Humidity." Procedia Earth and Planetary Science 7 (2013): 459–62. http://dx.doi.org/10.1016/j.proeps.2013.03.083.

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26

Jia, Y., H. B. Bian, G. Duveau, K. Su, and J. F. Shao. "Numerical modelling of in situ behaviour of the Callovo–Oxfordian argillite subjected to the thermal loading." Engineering Geology 109, no. 3-4 (2009): 262–72. http://dx.doi.org/10.1016/j.enggeo.2009.08.012.

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27

Bazer-Bachi, F., E. Tevissen, M. Descostes, et al. "Characterization of iodide retention on Callovo-Oxfordian argillites and its influence on iodide migration." Physics and Chemistry of the Earth, Parts A/B/C 31, no. 10-14 (2006): 517–22. http://dx.doi.org/10.1016/j.pce.2006.04.015.

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28

Jougnot, D., and A. Revil. "Thermal conductivity of unsaturated clay-rocks." Hydrology and Earth System Sciences Discussions 5, no. 4 (2008): 2409–23. http://dx.doi.org/10.5194/hessd-5-2409-2008.

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Abstract. The thermal conductivity of porous materials can be related to the electrical conductivity and therefore electrical resistivity tomography can be used to map the thermal conductivity of porous rocks. In this paper, a relationship is developed to connect the thermal conductivity of unsaturated clay-rocks to the thermal conductivity of the different phases of the porous composite, a textural parameter called the thermal formation factor, and the tortuosity of the water phase. The thermal formation factor is related to the electrical formation factor and to the first Archie's first expo
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29

Bazer-Bachi, F., M. Descostes, E. Tevissen, et al. "Characterization of sulphate sorption on Callovo-Oxfordian argillites by batch, column and through-diffusion experiments." Physics and Chemistry of the Earth, Parts A/B/C 32, no. 8-14 (2007): 552–58. http://dx.doi.org/10.1016/j.pce.2006.01.010.

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30

Lassin, Arnault, Nicolas C. M. Marty, Hélène Gailhanou, et al. "Equilibrium partial pressure of CO2 in Callovian–Oxfordian argillite as a function of relative humidity: Experiments and modelling." Geochimica et Cosmochimica Acta 186 (August 2016): 91–104. http://dx.doi.org/10.1016/j.gca.2016.04.028.

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31

Pazdniakou, Aliaksei, and Magdalena Dymitrowska. "Migration of Gas in Water Saturated Clays by Coupled Hydraulic-Mechanical Model." Geofluids 2018 (2018): 1–25. http://dx.doi.org/10.1155/2018/6873298.

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Understanding the gas migration in highly water saturated sedimentary rock formations is of great importance for safety of radioactive waste repositories which may use these host rocks as barrier. Recent experiments on drainage in argillite samples have demonstrated that they cannot be represented in terms of standard two-phase flow Darcy model. It has been suggested that gas flows along highly localized dilatant pathways. Due to very small pore size and the opacity of the material, it is not possible to observe this two-phase flow directly. In order to better understand the gas transport, a n
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32

Savoye, Sébastien, Jacques Page, Céline Puente, Christophe Imbert, and Daniel Coelho. "New Experimental Approach for Studying Diffusion through an Intact and Unsaturated Medium: A Case Study with Callovo-Oxfordian Argillite." Environmental Science & Technology 44, no. 10 (2010): 3698–704. http://dx.doi.org/10.1021/es903738t.

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33

Dupuy, C., A. Gharzouni, I. Sobrados, et al. "Formulation of an alkali-activated grout based on Callovo-Oxfordian argillite for an application in geological radioactive waste disposal." Construction and Building Materials 232 (January 2020): 117170. http://dx.doi.org/10.1016/j.conbuildmat.2019.117170.

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34

Kedziorek, Monika A. M., Alain C. M. Bourg, and Eric Giffaut. "Hydrogeochemistry of Sn(IV) in the context of radioactive waste disposal: Solubility and adsorption on MX-80 bentonite and Callovo-Oxfordian argilite." Physics and Chemistry of the Earth, Parts A/B/C 32, no. 8-14 (2007): 568–72. http://dx.doi.org/10.1016/j.pce.2005.12.005.

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35

Kazmierczak, J. B., F. Laouafa, M. Ghoreychi, P. Lebon, and J. D. Barnichon. "Influence of creep on water pressure measured from borehole tests in the Meuse/Haute-Marne Callovo-Oxfordian argillites." Physics and Chemistry of the Earth, Parts A/B/C 32, no. 8-14 (2007): 917–21. http://dx.doi.org/10.1016/j.pce.2006.01.008.

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36

Landrein, Philippe, Georges Vigneron, Jacques Delay, Patrick Lebon, and Maurice Pagel. "Lithologie, hydrodynamisme et thermicité dans le système sédimentaire multicouche recoupé par les forages Andra de Montiers-sur-Saulx (Meuse)." Bulletin de la Société Géologique de France 184, no. 6 (2013): 519–43. http://dx.doi.org/10.2113/gssgfbull.184.6.519.

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AbstractDans le cadre du choix d’un site de stockage de déchets radioactifs de haute et moyenne activité à vie longue dans les argilites du Callovo-Oxfordien de Meuse/Haute-Marne, l’Andra (Agence nationale pour la gestion des déchets radioactifs) a réalisé 3 forages (EST431, EST432 et EST433) à partir d’une plate-forme implantée sur la commune de Montiers-sur-Saulx (Meuse) en position centrale d’une zone d’environ 250 km2 dite ≪ zone de transposition ≫.Les objectifs principaux des investigations ont été d’apporter des éléments pour la localisation du stockage potentiel et compléter les connais
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37

Claret, Francis, Thorsten Schäfer, Thomas Rabung, Manfred Wolf, Andreas Bauer, and Gunnar Buckau. "Differences in properties and Cm(III) complexation behavior of isolated humic and fulvic acid derived from Opalinus clay and Callovo-Oxfordian argillite." Applied Geochemistry 20, no. 6 (2005): 1158–68. http://dx.doi.org/10.1016/j.apgeochem.2005.01.008.

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38

Ababou, Rachid, Israel Cañamón Valera, and Adrien Poutrel. "Macro-permeability distribution and anisotropy in a 3D fissured and fractured clay rock: ‘Excavation Damaged Zone’ around a cylindrical drift in Callovo-Oxfordian Argilite (Bure)." Physics and Chemistry of the Earth, Parts A/B/C 36, no. 17-18 (2011): 1932–48. http://dx.doi.org/10.1016/j.pce.2011.07.032.

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39

Deniau, I., I. Devol-Brown, S. Derenne, F. Behar, and C. Largeau. "Comparison of the bulk geochemical features and thermal reactivity of kerogens from Mol (Boom Clay), Bure (Callovo–Oxfordian argillite) and Tournemire (Toarcian shales) underground research laboratories." Science of The Total Environment 389, no. 2-3 (2008): 475–85. http://dx.doi.org/10.1016/j.scitotenv.2007.09.013.

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40

Lassin, A., M. Dymitrowska, and M. Azaroual. "Hydrogen solubility in pore water of partially saturated argillites: Application to Callovo-Oxfordian clayrock in the context of a nuclear waste geological disposal." Physics and Chemistry of the Earth, Parts A/B/C 36, no. 17-18 (2011): 1721–28. http://dx.doi.org/10.1016/j.pce.2011.07.092.

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41

Distinguin, Marc, and Jean-Marc Lavanchy. "Determination of hydraulic properties of the Callovo-Oxfordian argillite at the bure site: Synthesis of the results obtained in deep boreholes using several in situ investigation techniques." Physics and Chemistry of the Earth, Parts A/B/C 32, no. 1-7 (2007): 379–92. http://dx.doi.org/10.1016/j.pce.2006.02.056.

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42

Bénet, Luc-Vincent, Étienne Blaud, and Jacques Wendling. "Modelling of water and gas flow through an excavation damaged zone in the Callovo-Oxfordian argillites in the framework of a single porosity model." Geological Society, London, Special Publications 443, no. 1 (2016): 319–32. http://dx.doi.org/10.1144/sp443.6.

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43

Prinzhofer, Alain, Jean Pierre Girard, Stéphane Buschaert, Yvon Huiban, and Sonia Noirez. "Chemical and isotopic characterization of hydrocarbon gas traces in porewater of very low permeability rocks: The example of the Callovo-Oxfordian argillites of the eastern part of the Paris Basin." Chemical Geology 260, no. 3-4 (2009): 269–77. http://dx.doi.org/10.1016/j.chemgeo.2008.12.021.

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44

Menut, Denis, Michael Descostes, Patrick Meier, Jean Radwan, Patrick Mauchien, and Christophe Poinssot. "Europium migration in Argilaceous Rocks : on the use of Micro Laser-Induced Breakdown Spectroscopy (micro LIBS) as a Microanalysis Tool." MRS Proceedings 932 (2006). http://dx.doi.org/10.1557/proc-932-20.1.

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ABSTRACTEu migration in a Callovo-Oxfordian argilite sample was studied using the micro LIBS technique. Quantitative elemental mapping were made by micro LIBS that showed the actual distribution of the various micro areas observed on the Callovo-Oxfordian sample's surface. Calcite, dolomite, alumino-silicates, quartz, pyrite and iron oxides were identified and their statistical distribution was determined. Experimental Eu profiles observed are consistent with diffusion process accompanied by heterogeneous sorption on alumino-silicate surface.
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45

Descostes, M., V. Blin, B. Grenut, P. Meier, and E. Tevissen. "HTO Diffusion in Oxfordian Limestone and Callovo-Oxfordian Argillite Formations." MRS Proceedings 824 (2004). http://dx.doi.org/10.1557/proc-824-cc8.29.

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AbstractDiffusion coefficients and accessible porosities for HTO were measured on 30 samples from the Andra Underground Rock Laboratory in Meuse/Haute-Marne (France) using the through diffusion technique. Two distinct geological formations were studied: Oxfordian limestone and Callovo-oxfordian argillite between 166 and 477 m depth. The experiences were carried out with synthetic pore-water from each formation. The measured values of the effective diffusion coefficients (De) are ranging from 2.6× 10-12 to 12.4 × 10-11 m2 s-1 while accessible porosities (ε) are between 2.4 and 24%. Good correla
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46

Revil, A. "Characterization of transport properties of argillaceous sediments: Application to the Callovo-Oxfordian argillite." Journal of Geophysical Research 110, B6 (2005). http://dx.doi.org/10.1029/2004jb003442.

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47

Dahhaoui, Hachimi, Naïma Belayachi, and Abdeldjalil Zadjaoui. "Modeling of Creep Behavior of an Argillaceous Rock by Numerical Homogenization Method." Periodica Polytechnica Civil Engineering, January 15, 2018. http://dx.doi.org/10.3311/ppci.11697.

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This paper is devoted to modeling the creep behavior of argillaceous rock and a comparison with experimental and numerical results from literature. The proposed time dependent modeling is based on a numerical homogenization method, matrix-inclusion material microstructure and a creep micromechanical model. The nonlinear viscosity of the argillaceous matrix is described by the creep model “Modified Time Hardening”, while classical linear elasticity is applied for the calcite and quartz inclusions. The simulation accuracy was analyzed under single and multistage creep test. A satisfactory agreem
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48

Plas, Frederic, and Jacques WENDLING. "The geological research in France - The Dosssier 2005 Argile." MRS Proceedings 985 (2006). http://dx.doi.org/10.1557/proc-985-0985-nn13-01.

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AbstractAt the end of fifteen years of researchs defined by the French act of December 30, 1991 on radwaste management, Andra gave a report, “Dossier Argile 2005”, which concluded with the feasibility of a reversible disposal in the argillaceous Callovo-Oxfordien formation studied by means of an underground research laboratory at Meuse/Haute-Marne site. Starting from source data like the characteristics of the geological medium and the waste inventory, the process followed by Andra to achieve at this conclusion is of type sequential and iterative between concept design, scientific knowledge, i
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49

Latrille, C., J. Ly, and M. Herbette. "Retention of Sn(IV) and Pu(IV) onto four argillites from the Callovo–Oxfordian level at Bure (France) from eight equilibrated sedimentary waters." Radiochimica Acta 94, no. 8 (2006). http://dx.doi.org/10.1524/ract.2006.94.8.421.

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SummaryWithin the framework of studies concerning the migration of radionuclides in a potential nuclear waste disposal host rock, the retention properties of clayey materials towards Sn(IV) and Pu(IV) are approached. Chemical sorption is quantified with the partitioning coefficient
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