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Relevant bibliographies by topics / Aryl halide

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Academic literature on the topic 'Aryl halide'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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Journal articles on the topic "Aryl halide"

1

Baik, Woonphil, Wanqiang Luan, Hyun Joo Lee, Cheol Hun Yoon, Sangho Koo, and Byeong Hyo Kim. "Efficient one-pot transformation of aminoarenes to haloarenes using halodimethylisulfonium halides generated in situ." Canadian Journal of Chemistry 83, no. 3 (2005): 213–19. http://dx.doi.org/10.1139/v05-026.

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Halodimethylsulfonium halide 1, which is readily formed in situ from hydrohaloic acid and DMSO, is a good nucleophilic halide. This activated nucleophilic halide rapidly converts aryldiazonium salt prepared in situ by the same hydrohaloic acid and nitrite ion to aryl chlorides, bromides, or iodides in good yield. The combined action of nitrite ion and hydrohaloic acid in DMSO is required for the direct transformation of aromatic amines, which results in the production of aryl halides within 1 h. Substituted compounds with electron-donating or -withdrawing groups or sterically hindered aromatic

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2

Nelson, David J., and Feliu Maseras. "Steric effects determine the mechanisms of reactions between bis(N-heterocyclic carbene)-nickel(0) complexes and aryl halides." Chemical Communications 54, no. 75 (2018): 10646–49. http://dx.doi.org/10.1039/c8cc06379f.

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Liu, Xiaosong, Yunfei Song, Wei Zhang, et al. "Correction: Tracking intramolecular energy redistribution dynamics in aryl halides: the effect of halide mass." RSC Advances 8, no. 55 (2018): 31303. http://dx.doi.org/10.1039/c8ra90073f.

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4

Kabalka, G. W., Z. Wu, and Y. Ju. "Use of organoboron halides in organic synthesis." Pure and Applied Chemistry 75, no. 9 (2003): 1231–37. http://dx.doi.org/10.1351/pac200375091231.

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Several new organic transformations have been achieved utilizing boron halide reagents. Aryl aldehydes are conveniently converted to gem-dichloromethylbenzenes using boron trichloride. Aryl aldehydes are alkylated by alkylboron chlorides in a Grignard-like fashion to generate the corresponding arylalkanols or alkylboron chlorides. Aryl aldehydes react with divinylboron halides (generated via the haloboration of alkynes) to produce 1,5-di-halo-1,4-dienes in excellent yields.

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Leadbeater, Nicholas E., and Riina K. Arvela. "Fast and Easy Halide Exchangein Aryl Halides." Synlett, no. 8 (2003): 1145–48. http://dx.doi.org/10.1055/s-2003-39887.

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Brian, Ptoton Mnangat, and Peter Musau. "Synthesis, Reactivity and Stability of Aryl Halide Protecting Groups towards Di-Substituted Pyridines." Indonesian Journal of Chemistry 16, no. 1 (2018): 53. http://dx.doi.org/10.22146/ijc.21177.

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This paper reports the synthesis and reactivity of different Benzyl derivative protecting groups. The synthesis and stability of Benzyl halides, 4-methoxybenzyl halides, 3,5-dimethoxybenzyl halides, 3,4-dimethoxybenzyl halides, 3,4,5-trimethoxybenzyl halide protecting groups and their reactivity towards nitrogen atom of a di-substituted pyridine ring in formation of pyridinium salts is also reported.

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Fan, Guo Zhi, Zhen Xiao Duan, and Min Wang. "Suzuki Reaction Catalyzed by Pd(II) Anchored on Polymer in Supercritical Carbon Dioxide." Advanced Materials Research 466-467 (February 2012): 216–19. http://dx.doi.org/10.4028/www.scientific.net/amr.466-467.216.

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Palladium chloride anchored on polystyrene modified by 5-amino-1,10-phenanthroline was prepared and used as catalysts for the Suzuki cross-coupling reactions of aryl halide with arylboronic acid in supercritical carbon dioxide without use of organic solvent. The heterogeneous catalyst revealed excellent and recoverable catalytic performance for a wide range of aryl halides substrates. It can be easily separated from the reaction mixture and reused for six recycles without significant loss of catalytic activity.

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Bhat, Balkrishen, and A. P. Bhaduri. "Grignard Reaction of 2-Substituted-3-Cyanoquinolines." Zeitschrift für Naturforschung B 40, no. 7 (1985): 990–95. http://dx.doi.org/10.1515/znb-1985-0724.

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Abstract Grignard reactions of 2-morpholino and 2-methylthio-3-cyanoquinoline, 2-chloro-3-cyanoquinoline, 2-chloro-3-cyano-6-methoxyquinoline and 2-chloro-3-cyano-7-methylquinoline with alkyl or aryl magnesium halides have been studied. It was found that 2-morpholino and 2-methylthio- 3-cyanoquinolines gave 1,4-addition products followed by rapid aromatisation. 2-Chloro-3- cyanoquinoline with alkyl magnesium halides furnished 1,4-addition products but with aryl magnesium halides 1,4- and 1,2-addition products were obtained. The cyano group of 4-aryl-2-chloro- 3-cyano-1,4-dihydroquinolines was

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Yu, Yang, Yong-Sheng Li, and Julius Rebek. "Binding of alkyl halides in water-soluble cavitands with urea rims." New Journal of Chemistry 42, no. 12 (2018): 9945–48. http://dx.doi.org/10.1039/c8nj01567h.

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Steller, Beate G., Berenike Doler, and Roland C. Fischer. "Diaryltin Dihydrides and Aryltin Trihydrides with Intriguing Stability." Molecules 25, no. 5 (2020): 1076. http://dx.doi.org/10.3390/molecules25051076.

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In the last few decades, organotin hydrides have proven their potential as building blocks for a great variety of organometallic compounds. In this context, organotin hydrides with sterically shielding aryl substituents have attracted special interest, as these ligands can kinetically stabilize metastable products. The selective synthesis of aryltin halide compounds Ar*2SnCl2 and Ar*SnI3 featuring the highly sterically encumbered aryl ligand Ar* (iPrAr* = 2,6-(Ph2CH)2-4-iPrC6H2; MeAr* = 2,6-(Ph2CH)2-4-MeC6H2) is presented. These aryltin halides were converted into corresponding aryltin hydride

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Dissertations / Theses on the topic "Aryl halide"

1

Font, Molins Marc. "Model aryl halide macrocyclic substrates for the elucidation of coinage metal catalysed cross-coupling reaction mechanism." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/285975.

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Aryl-Cu(III) species have been often implicated as the intermediate species that operate Ullmann-type couplings. However, such species have long remained elusive and the fundamental pathways that govern Ullmann-type couplings, first discovered in the beginning of the last century, are still under debate. The first part of this thesis deals with the reactivity of a well-defined aryl-Cu(III) complex in the presence of sulphur, selenium and phosphorus-based nucleophiles. The results obtained demonstrate the plausibility of Cu(I)/Cu(III) redox cycles in copper-catalysed C-S, C-Se and C-P cross-cou

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2

Cox, Robert John. "Ullmann etherification." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/25968.

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Formation of the diaryl ether moiety remains a challenging target for organic synthesis despite modern technologies, however, better understanding of older techniques often leads to improvements. The copper-catalysed Ullmann ether synthesis, whilst attractive in many ways, is frequently problematic due to the inherent irreproducibility of the reaction on scale up. Little is yet known about the mechanism of the reaction and conflicting views are rife within the scientific community. In a well-studied example, we show that the potassium iodide formed during the reaction slows catalysis. Addition

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Cui, Chunming. "Aluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structures." Doctoral thesis, [S.l. : s.n.], 2001. http://webdoc.sub.gwdg.de/diss/2001/cui/cui.pdf.

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Paleologou, Michael. "Aryl halides and metabolites : new approaches to quantitation." Thesis, McGill University, 1990. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=74598.

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A novel reaction for the dehalogenation of aryl halides is discussed in terms of its stoichiometry, mechanism, yields and potential for analytical purposes. The active dehalogenation reagent can be prepared through the reaction of molten potassium with polyethylene glycols (MW $>$ 200), in the absence of oxygen, to form the corresponding potassium glycolate, a powerful nucleophilic agent. This reaction is applied to the determination of PCBs in waste oils. Following dechlorination, the reaction sample is analyzed for chloride using a flow-injection analysis system employing a novel thin-layer

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Chen, Lu. "Palladium-catalysed C-C bond construction in virtue of C-H functionalisation : direct arylation of heteroaromatics tolerant to reactive functional groups." Thesis, Rennes 1, 2013. http://www.theses.fr/2013REN1S011.

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Durant ma thèse, j'ai recherché les conditions pour l'activation / fonctionnalisation de liaisons C-H pour la construction de bi(hétéro)aryles tolérant des groupement fonctionnels réactifs tels que des silyles, des alcènes, des esters ou encore des amides. Par rapport aux protocoles de couplage classiques tels que les réactions de Suzuki, Stille ou Negishi, la fonctionalisation de liaisons C-H fournit des procédures moins coûteuses et plus écologiques si elle tolère des groupements utiles en synthèse. D'abord, nous avons observé que les thiophènes substitués par des silyles en C2 peuvent être

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6

Cropper, Paul Edward. "A kinetic template effect in arylphosphonium salt formation." Thesis, Sheffield Hallam University, 1988. http://shura.shu.ac.uk/19513/.

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This thesis describes studies of a "kinetic template effect" which assists the formation of arylphosphonium salts from aryl halides and tertiary phosphines in the presence of a transition metal halide catalyst in refluxing ethanol. The "kinetic template effect" arises from the presence in the aryl halide of a limited range of orthosubstituents capable of intramolecular coordination with the metal at a critical stage of the reaction. In Chapter One, the "kinetic template effect" is compared with the better known "thermodynamic template effect". Earlier work on related "kinetic template effects"

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Mo, Jun. "Palladium catalyzed heck arylation of electron-rich olefins by aryl halides." Thesis, University of Liverpool, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433729.

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Ferretti, Antonio. "Kinetic and mechanistic studies of Pd-catalyzed amination of aryl halides." Thesis, Imperial College London, 2009. http://hdl.handle.net/10044/1/5483.

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The Pd-catalyzed amination of aryl halides (Buchwald-Hartwig amination) has become a versatile and widely used technology to synthesize and produce aromatic amines relevant in pharmaceutical and agrochemical industries. The aim of the work presented in this thesis is to achieve a better mechanistic understanding of this reaction. The methodologies used were not traditional and focused on kinetic studies, carried out using in-situ tools, mainly reaction calorimetry. Reactions using different amines have been considered: the kinetic behaviour of a straight-chain primary amine (n-hexylamine) was

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Piller, Fabian Michel. "LiCl-Mediated Direct Insertion of Magnesium Into Aryl, Heteroaryl and Benzylic Halides." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-114123.

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Kuvayskaya, Anastasia, and Aleksey Vasiliev. "Use of Suzuki Coupling Reaction for Synthesis of Functionalized Materials." Digital Commons @ East Tennessee State University, 2019. https://dc.etsu.edu/asrf/2019/schedule/162.

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Hybrid materials synthesized by grafting of organic molecules onto silica surface have found numerous applications in chemistry, biochemistry, and chemical engineering. In particular, the functionalization of silica gel can be accomplished by various surface reactions of immobilized boronic acids. Suzuki coupling has been chosen due to several advantages, such as mild reaction conditions, tolerance to the aqueous environment, and high yields of the products. The objective of this work was to determine the most effective reaction conditions for modifying porous hybrid materials with large speci

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Books on the topic "Aryl halide"

1

Zou, Dong. Nucleophilic substitution at the spp2s carbon of aryl halides by using nickel acylate complexes. 1994.

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2

White, William. The application of polystyrene bound tin hydride to a continuous flow reactor system for the reduction of alkyl and aryl halides. 1990.

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Book chapters on the topic "Aryl halide"

1

Skelton, Victoria, Gillian M. Greenway, Stephen J. Haswell, Peter Styring, and David O. Morgan. "Micro-reactor synthesis: synthesis of cyanobiphenyls using a modified Suzuki coupling of an aryl halide and aryl boronic acid." In Microreaction Technology: Industrial Prospects. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-642-59738-1_23.

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2

Röschenthaler, G. V. "From Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch127.

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Huber, F. "By Reaction with Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch151.

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Kanner, B. "By Reaction with Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch76.

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Kanner, B. "By Reaction with Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch98.

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Schareina, Thomas, and Matthias Beller. "Copper-Catalyzed Cyanations of Aryl Halides and Related Compounds." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch9.

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7

Yamamoto, Yoshihiko. "Catalytic Alkyne Hydroarylation Using Arylboron Reagents, Aryl Halides, and Congeners." In Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds. Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527697649.ch8.

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Poller, R. C. "By Reaction with Alkyl Halides Having Alkenyl or Aryl Substituents." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch120.

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9

Alayrac, Carole, and Annie-Claude Gaumont. "Copper-Catalyzed Formation of C-P Bonds with Aryl Halides." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch3.

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Brill, T. B. "By Oxidative Addition of Alkyl and Aryl Halides to the Metals." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch96.

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Conference papers on the topic "Aryl halide"

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Nunes, Vanessa Lóren, (PG) Ingryd Cristina de Oliveira, and Olga S. do Rêgo Barros. "Copper(I)-Senelenophene-2-carboxylate Catalyzed Cross- Coupling of Aryl or alkyl Thiols And Aryl Halides." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0177-1.

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